KR20130041183A - LiPO2F2의 제조법 및 결정형 LiPO2F2 - Google Patents
LiPO2F2의 제조법 및 결정형 LiPO2F2 Download PDFInfo
- Publication number
- KR20130041183A KR20130041183A KR1020137003205A KR20137003205A KR20130041183A KR 20130041183 A KR20130041183 A KR 20130041183A KR 1020137003205 A KR1020137003205 A KR 1020137003205A KR 20137003205 A KR20137003205 A KR 20137003205A KR 20130041183 A KR20130041183 A KR 20130041183A
- Authority
- KR
- South Korea
- Prior art keywords
- carbonate
- lipo
- ethylene carbonate
- solvent
- fluoro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 229910012258 LiPO Inorganic materials 0.000 claims abstract description 88
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 22
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 15
- 239000003960 organic solvent Substances 0.000 claims abstract description 15
- 239000011541 reaction mixture Substances 0.000 claims abstract description 15
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- QTJOIXXDCCFVFV-UHFFFAOYSA-N [Li].[O] Chemical compound [Li].[O] QTJOIXXDCCFVFV-UHFFFAOYSA-N 0.000 claims abstract description 9
- JDZCKJOXGCMJGS-UHFFFAOYSA-N [Li].[S] Chemical compound [Li].[S] JDZCKJOXGCMJGS-UHFFFAOYSA-N 0.000 claims abstract description 9
- 150000005677 organic carbonates Chemical class 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims description 58
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 39
- -1 cyclic organic carbonates Chemical class 0.000 claims description 28
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 24
- 239000008151 electrolyte solution Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 19
- 239000000243 solution Substances 0.000 claims description 17
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 14
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 12
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 12
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 12
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 11
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 10
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 9
- SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical compound FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 claims description 8
- 125000001153 fluoro group Chemical group F* 0.000 claims description 7
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- 125000004216 fluoromethyl group Chemical group [H]C([H])(F)* 0.000 claims description 5
- 239000003495 polar organic solvent Substances 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 abstract description 14
- 239000003792 electrolyte Substances 0.000 abstract description 7
- 239000000654 additive Substances 0.000 abstract description 6
- 230000000996 additive effect Effects 0.000 abstract description 5
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 32
- 229940021013 electrolyte solution Drugs 0.000 description 19
- 229910013870 LiPF 6 Inorganic materials 0.000 description 15
- 238000000605 extraction Methods 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000002955 isolation Methods 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 6
- 125000002947 alkylene group Chemical group 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 229910003002 lithium salt Inorganic materials 0.000 description 5
- 159000000002 lithium salts Chemical class 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- 239000011877 solvent mixture Substances 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 150000002825 nitriles Chemical class 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000002798 polar solvent Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000003586 protic polar solvent Substances 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical group O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 description 2
- 125000004206 2,2,2-trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- 229910018119 Li 3 PO 4 Inorganic materials 0.000 description 2
- 229910000792 Monel Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000000010 aprotic solvent Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- LVYPNDZTRXRBNM-UHFFFAOYSA-N bis(trifluoromethyl) carbonate Chemical compound FC(F)(F)OC(=O)OC(F)(F)F LVYPNDZTRXRBNM-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- PMGNOQUKCGLETL-UHFFFAOYSA-N carbonic acid 1,2-difluoroethene Chemical compound C(O)(O)=O.FC=CF PMGNOQUKCGLETL-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000000806 fluorine-19 nuclear magnetic resonance spectrum Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229910001867 inorganic solvent Inorganic materials 0.000 description 2
- 239000003049 inorganic solvent Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000001394 phosphorus-31 nuclear magnetic resonance spectrum Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 150000003462 sulfoxides Chemical class 0.000 description 2
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 1
- WXBWKMLIVXELSF-UHFFFAOYSA-N 2,2,2-trifluoro-n,n-dimethylacetamide Chemical compound CN(C)C(=O)C(F)(F)F WXBWKMLIVXELSF-UHFFFAOYSA-N 0.000 description 1
- LRTRRTZWJXMMGS-UHFFFAOYSA-N 2,2-difluoroethyl ethenyl carbonate Chemical compound FC(F)COC(=O)OC=C LRTRRTZWJXMMGS-UHFFFAOYSA-N 0.000 description 1
- WXVCMUWGHFXASO-UHFFFAOYSA-N 2,2-difluoroethyl ethyl carbonate Chemical compound CCOC(=O)OCC(F)F WXVCMUWGHFXASO-UHFFFAOYSA-N 0.000 description 1
- VGKKQOMMALQKIC-UHFFFAOYSA-N 2,2-difluoroethyl fluoromethyl carbonate Chemical compound FCOC(=O)OCC(F)F VGKKQOMMALQKIC-UHFFFAOYSA-N 0.000 description 1
- 125000004778 2,2-difluoroethyl group Chemical group [H]C([H])(*)C([H])(F)F 0.000 description 1
- QOARFWDBTJVWJG-UHFFFAOYSA-N 2,2-difluoroethyl methyl carbonate Chemical compound COC(=O)OCC(F)F QOARFWDBTJVWJG-UHFFFAOYSA-N 0.000 description 1
- ZJVUKUFQQGRGIJ-UHFFFAOYSA-N 2,2-difluoroethyl phenyl carbonate Chemical compound FC(F)COC(=O)OC1=CC=CC=C1 ZJVUKUFQQGRGIJ-UHFFFAOYSA-N 0.000 description 1
- CXCMIWOFWYPWSS-UHFFFAOYSA-N 2-(2,2,2-trifluoroacetyl)oxyethyl 2,2,2-trifluoroacetate Chemical compound FC(F)(F)C(=O)OCCOC(=O)C(F)(F)F CXCMIWOFWYPWSS-UHFFFAOYSA-N 0.000 description 1
- IZXIZTKNFFYFOF-UHFFFAOYSA-N 2-Oxazolidone Chemical compound O=C1NCCO1 IZXIZTKNFFYFOF-UHFFFAOYSA-N 0.000 description 1
- XVUMEEAIPCCPHI-UHFFFAOYSA-N 2-fluoroethyl fluoromethyl carbonate Chemical compound FCCOC(=O)OCF XVUMEEAIPCCPHI-UHFFFAOYSA-N 0.000 description 1
- NOLGJZJMWUDWQW-UHFFFAOYSA-N 2-fluoroethyl methyl carbonate Chemical compound COC(=O)OCCF NOLGJZJMWUDWQW-UHFFFAOYSA-N 0.000 description 1
- UKJOHKQKTGJHRX-UHFFFAOYSA-N 2-fluoroethyl phenyl carbonate Chemical compound FCCOC(=O)OC1=CC=CC=C1 UKJOHKQKTGJHRX-UHFFFAOYSA-N 0.000 description 1
- VUZHZBFVQSUQDP-UHFFFAOYSA-N 4,4,5,5-tetrafluoro-1,3-dioxolan-2-one Chemical compound FC1(F)OC(=O)OC1(F)F VUZHZBFVQSUQDP-UHFFFAOYSA-N 0.000 description 1
- CRJXZTRTJWAKMU-UHFFFAOYSA-N 4,4,5-trifluoro-1,3-dioxolan-2-one Chemical compound FC1OC(=O)OC1(F)F CRJXZTRTJWAKMU-UHFFFAOYSA-N 0.000 description 1
- BUPLCMMXKFWTTA-UHFFFAOYSA-N 4-methylidene-1,3-dioxetan-2-one Chemical compound C=C1OC(=O)O1 BUPLCMMXKFWTTA-UHFFFAOYSA-N 0.000 description 1
- 229910015015 LiAsF 6 Inorganic materials 0.000 description 1
- 229910013188 LiBOB Inorganic materials 0.000 description 1
- 229910013684 LiClO 4 Inorganic materials 0.000 description 1
- 229910013131 LiN Inorganic materials 0.000 description 1
- 229910013528 LiN(SO2 CF3)2 Inorganic materials 0.000 description 1
- 229910013385 LiN(SO2C2F5)2 Inorganic materials 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- CSCPPACGZOOCGX-WFGJKAKNSA-N acetone d6 Chemical compound [2H]C([2H])([2H])C(=O)C([2H])([2H])[2H] CSCPPACGZOOCGX-WFGJKAKNSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000005910 alkyl carbonate group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- WLLOZRDOFANZMZ-UHFFFAOYSA-N bis(2,2,2-trifluoroethyl) carbonate Chemical compound FC(F)(F)COC(=O)OCC(F)(F)F WLLOZRDOFANZMZ-UHFFFAOYSA-N 0.000 description 1
- UYFISINJOLGYBJ-UHFFFAOYSA-N bis(2,2-difluoroethyl) carbonate Chemical compound FC(F)COC(=O)OCC(F)F UYFISINJOLGYBJ-UHFFFAOYSA-N 0.000 description 1
- JKJWYKGYGWOAHT-UHFFFAOYSA-N bis(prop-2-enyl) carbonate Chemical compound C=CCOC(=O)OCC=C JKJWYKGYGWOAHT-UHFFFAOYSA-N 0.000 description 1
- AWAAXGSYKBMTQM-UHFFFAOYSA-N but-2-ene;carbonic acid Chemical compound CC=CC.OC(O)=O AWAAXGSYKBMTQM-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- ZFTFAPZRGNKQPU-UHFFFAOYSA-L carboxylato carbonate Chemical compound [O-]C(=O)OC([O-])=O ZFTFAPZRGNKQPU-UHFFFAOYSA-L 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- CSANCJZZMDBNPU-UHFFFAOYSA-N difluoromethyl 2-fluoroethyl carbonate Chemical compound FCCOC(=O)OC(F)F CSANCJZZMDBNPU-UHFFFAOYSA-N 0.000 description 1
- VWCDXEKXDIWXKI-UHFFFAOYSA-N difluoromethyl ethyl carbonate Chemical compound CCOC(=O)OC(F)F VWCDXEKXDIWXKI-UHFFFAOYSA-N 0.000 description 1
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- DPGXGQNEWAAUKM-UHFFFAOYSA-N ethenyl 2,2,2-trifluoroethyl carbonate Chemical compound FC(F)(F)COC(=O)OC=C DPGXGQNEWAAUKM-UHFFFAOYSA-N 0.000 description 1
- JCBADTLNWNTCNV-UHFFFAOYSA-N ethenyl 2-fluoroethyl carbonate Chemical compound FCCOC(=O)OC=C JCBADTLNWNTCNV-UHFFFAOYSA-N 0.000 description 1
- BDNXATXQVYVLCI-UHFFFAOYSA-N ethenyl fluoromethyl carbonate Chemical compound FCOC(=O)OC=C BDNXATXQVYVLCI-UHFFFAOYSA-N 0.000 description 1
- FXPHJTKVWZVEGA-UHFFFAOYSA-N ethenyl hydrogen carbonate Chemical class OC(=O)OC=C FXPHJTKVWZVEGA-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- XLHKMGHXUXYDQJ-UHFFFAOYSA-N ethyl 2-fluoroethyl carbonate Chemical compound CCOC(=O)OCCF XLHKMGHXUXYDQJ-UHFFFAOYSA-N 0.000 description 1
- UHHPUKUEMKPCII-UHFFFAOYSA-N ethyl fluoromethyl carbonate Chemical compound CCOC(=O)OCF UHHPUKUEMKPCII-UHFFFAOYSA-N 0.000 description 1
- ZPBVUMUIOIGYRV-UHFFFAOYSA-N ethyl trifluoromethyl carbonate Chemical compound CCOC(=O)OC(F)(F)F ZPBVUMUIOIGYRV-UHFFFAOYSA-N 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- KUPHFFIERSZZDV-UHFFFAOYSA-N fluoromethyl phenyl carbonate Chemical compound FCOC(=O)OC1=CC=CC=C1 KUPHFFIERSZZDV-UHFFFAOYSA-N 0.000 description 1
- 150000003948 formamides Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910003473 lithium bis(trifluoromethanesulfonyl)imide Inorganic materials 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- GBPVMEKUJUKTBA-UHFFFAOYSA-N methyl 2,2,2-trifluoroethyl carbonate Chemical compound COC(=O)OCC(F)(F)F GBPVMEKUJUKTBA-UHFFFAOYSA-N 0.000 description 1
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 description 1
- AJFDBNQQDYLMJN-UHFFFAOYSA-N n,n-diethylacetamide Chemical compound CCN(CC)C(C)=O AJFDBNQQDYLMJN-UHFFFAOYSA-N 0.000 description 1
- 125000004971 nitroalkyl group Chemical group 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- NGGUSKNBBASYGO-UHFFFAOYSA-N phenyl 2,2,2-trifluoroethyl carbonate Chemical compound FC(F)(F)COC(=O)OC1=CC=CC=C1 NGGUSKNBBASYGO-UHFFFAOYSA-N 0.000 description 1
- QIIPQYDSKRYMFG-UHFFFAOYSA-N phenyl hydrogen carbonate Chemical class OC(=O)OC1=CC=CC=C1 QIIPQYDSKRYMFG-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- QSPSCCUUGYIQCI-UHFFFAOYSA-N trifluoromethyl hydrogen carbonate Chemical compound OC(=O)OC(F)(F)F QSPSCCUUGYIQCI-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/455—Phosphates containing halogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0563—Liquid materials, e.g. for Li-SOCl2 cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/02—Details
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/002—Inorganic electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10168890 | 2010-07-08 | ||
| EP10168890.1 | 2010-07-08 | ||
| PCT/EP2011/061030 WO2012004188A1 (en) | 2010-07-08 | 2011-06-30 | Manufacture of lipo2f2 and crystalline lipo2f2 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20130041183A true KR20130041183A (ko) | 2013-04-24 |
Family
ID=42731769
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020137003205A Withdrawn KR20130041183A (ko) | 2010-07-08 | 2011-06-30 | LiPO2F2의 제조법 및 결정형 LiPO2F2 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20130108933A1 (https=) |
| EP (1) | EP2590896A1 (https=) |
| JP (1) | JP2013534511A (https=) |
| KR (1) | KR20130041183A (https=) |
| CN (1) | CN102985361A (https=) |
| TW (1) | TW201219298A (https=) |
| WO (1) | WO2012004188A1 (https=) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015102202A1 (ko) * | 2013-12-31 | 2015-07-09 | 삼성정밀화학 주식회사 | 리튬 이차전지용 비수 전해액 및 이를 포함하는 리튬 이차전지 |
| WO2020027415A1 (ko) * | 2018-08-02 | 2020-02-06 | 주식회사 천보 | 디플루오로인산리튬염 결정체를 고순도로 제조하는 방법 및 이를 이용한 2차 전지용 비수계 전해액 |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130115522A1 (en) * | 2010-07-08 | 2013-05-09 | Solvay Sa | Manufacture of LiPO2F2 |
| CN103052592B (zh) | 2010-08-04 | 2016-02-24 | 索尔维公司 | 从POF3或PF5制造LiPO2F2 |
| CN103636052A (zh) * | 2011-04-26 | 2014-03-12 | 索尔维公司 | 锂空气电池组电池 |
| WO2013023902A1 (en) * | 2011-08-16 | 2013-02-21 | Solvay Sa | Manufacture of mixtures comprising lipo2f2 and lipf6 |
| EP2712843A1 (de) | 2012-09-28 | 2014-04-02 | LANXESS Deutschland GmbH | Herstellung von hochreinem Lithiumdifluorphosphat |
| CN103259040B (zh) * | 2013-03-25 | 2016-01-13 | 中山市华玮新能源科技有限公司 | 利用有机锡氟化物制备高纯度二氟磷酸锂的方法 |
| EP2881366A1 (en) * | 2013-12-04 | 2015-06-10 | Solvay SA | Method for manufacturing NaPO2F2 |
| CN105731412B (zh) * | 2015-12-29 | 2018-02-23 | 中国科学院宁波材料技术与工程研究所 | 一种二氟磷酸盐的制备方法 |
| KR102294409B1 (ko) * | 2017-01-20 | 2021-08-25 | 미쓰이 가가쿠 가부시키가이샤 | 다이플루오로인산리튬의 제조 방법 |
| CN109283286A (zh) * | 2017-07-21 | 2019-01-29 | 天津金牛电源材料有限责任公司 | 一种二氟氧磷锂的检测方法 |
| CN109509912A (zh) * | 2017-09-15 | 2019-03-22 | 浙江省化工研究院有限公司 | 一种抑制金属锂枝晶生长的方法 |
| CN108178139A (zh) * | 2018-02-09 | 2018-06-19 | 天津金牛电源材料有限责任公司 | 一种在制备二氟磷酸锂过程中提高产品收率的方法 |
| CN110176632A (zh) | 2018-02-20 | 2019-08-27 | 三星Sdi株式会社 | 用于锂二次电池的非水电解质和具有其的锂二次电池 |
| CN110176633A (zh) | 2018-02-20 | 2019-08-27 | 三星Sdi株式会社 | 用于可再充电的电池的非水电解质溶液、具有其的可再充电的电池 |
| JP7655726B2 (ja) * | 2018-11-01 | 2025-04-02 | 株式会社Ｇｓユアサ | 非水電解液二次電池 |
| CN113184824B (zh) * | 2021-05-12 | 2022-10-11 | 湖南法恩莱特新能源科技有限公司 | 一种二氟磷酸锂的制备方法 |
| CN115477297B (zh) * | 2022-10-18 | 2023-06-20 | 山东海科创新研究院有限公司 | 一种二氟磷酸锂的制备方法及其所得产品 |
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| DE2736765A1 (de) * | 1977-08-16 | 1979-03-01 | Hoechst Ag | Vorrichtung zur herstellung von hexagonalem phosphorpentoxid |
| JPS61227911A (ja) * | 1985-04-01 | 1986-10-11 | Teikoku Kako Kk | リン酸アルミニウムの製造法 |
| US4880714A (en) | 1989-02-27 | 1989-11-14 | Duracell Inc. | Method for preparing non-aqueous electrolytes |
| JP3173225B2 (ja) | 1993-05-26 | 2001-06-04 | ソニー株式会社 | 非水電解液二次電池 |
| CA2104718C (en) | 1993-08-24 | 1999-11-16 | Huanyu Mao | Simplified preparation of lipf6 based electrolyte for non-aqueous batteries |
| JPH07254415A (ja) | 1993-12-20 | 1995-10-03 | Wilson Greatbatch Ltd | 電気化学電池およびその電圧遅延を減少させる方法 |
| JP2000109307A (ja) * | 1998-10-02 | 2000-04-18 | Chisso Corp | Ｖｉ型ポリリン酸アンモニウムの製造方法 |
| DE10016816A1 (de) | 2000-04-05 | 2001-10-11 | Solvay Fluor & Derivate | Verwendung von Alkoxyestern |
| US8076033B2 (en) * | 2004-10-19 | 2011-12-13 | Mitsubishi Chemical Corporation | Method for producing difluorophosphate, nonaqueous electrolyte solution for secondary battery and nonaqueous electrolyte secondary battery |
| KR101285000B1 (ko) * | 2005-06-20 | 2013-07-10 | 미쓰비시 가가꾸 가부시키가이샤 | 디플루오로인산염의 제조 방법, 2 차 전지용 비수계 전해액및 비수계 전해액 2 차 전지 |
| KR101495012B1 (ko) | 2006-08-22 | 2015-02-24 | 미쓰비시 가가꾸 가부시키가이샤 | 2 불화 인산 리튬, 2 불화 인산 리튬 함유 전해액, 2 불화 인산 리튬의 제조 방법, 비수계 전해액의 제조 방법, 비수계 전해액 및 그것을 사용한 비수계 전해액 2 차 전지 |
| JP5277550B2 (ja) | 2007-03-12 | 2013-08-28 | セントラル硝子株式会社 | ジフルオロリン酸リチウムの製造方法及びこれを用いた非水電解液電池 |
| JP5504616B2 (ja) * | 2008-12-02 | 2014-05-28 | 三菱化学株式会社 | 二次電池用非水系電解液の製造方法 |
| WO2010064637A1 (ja) * | 2008-12-02 | 2010-06-10 | ステラケミファ株式会社 | ジフルオロリン酸塩の製造方法、非水系電解液及び非水系電解液二次電池 |
| JP4616925B2 (ja) * | 2008-12-02 | 2011-01-19 | ステラケミファ株式会社 | ジフルオロリン酸塩の製造方法 |
| JP5471967B2 (ja) * | 2009-08-21 | 2014-04-16 | 三菱化学株式会社 | ジフルオロリン酸塩組成物及びそれからなる非水系電解液用添加剤、並びにそれを用いた二次電池用非水系電解液及び非水系電解液二次電池 |
-
2011
- 2011-06-30 US US13/808,242 patent/US20130108933A1/en not_active Abandoned
- 2011-06-30 KR KR1020137003205A patent/KR20130041183A/ko not_active Withdrawn
- 2011-06-30 EP EP11728291.3A patent/EP2590896A1/en not_active Withdrawn
- 2011-06-30 JP JP2013517301A patent/JP2013534511A/ja active Pending
- 2011-06-30 WO PCT/EP2011/061030 patent/WO2012004188A1/en not_active Ceased
- 2011-06-30 CN CN2011800332302A patent/CN102985361A/zh active Pending
- 2011-06-30 TW TW100123103A patent/TW201219298A/zh unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015102202A1 (ko) * | 2013-12-31 | 2015-07-09 | 삼성정밀화학 주식회사 | 리튬 이차전지용 비수 전해액 및 이를 포함하는 리튬 이차전지 |
| WO2020027415A1 (ko) * | 2018-08-02 | 2020-02-06 | 주식회사 천보 | 디플루오로인산리튬염 결정체를 고순도로 제조하는 방법 및 이를 이용한 2차 전지용 비수계 전해액 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012004188A1 (en) | 2012-01-12 |
| US20130108933A1 (en) | 2013-05-02 |
| JP2013534511A (ja) | 2013-09-05 |
| TW201219298A (en) | 2012-05-16 |
| EP2590896A1 (en) | 2013-05-15 |
| CN102985361A (zh) | 2013-03-20 |
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