KR20120037487A - 반방향족 폴리아미드 수지 조성물, 그 제조 방법, 및 그 물품 - Google Patents
반방향족 폴리아미드 수지 조성물, 그 제조 방법, 및 그 물품 Download PDFInfo
- Publication number
- KR20120037487A KR20120037487A KR1020127004046A KR20127004046A KR20120037487A KR 20120037487 A KR20120037487 A KR 20120037487A KR 1020127004046 A KR1020127004046 A KR 1020127004046A KR 20127004046 A KR20127004046 A KR 20127004046A KR 20120037487 A KR20120037487 A KR 20120037487A
- Authority
- KR
- South Korea
- Prior art keywords
- composition
- lubricant
- weight
- semiaromatic polyamide
- total
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000011342 resin composition Substances 0.000 title claims abstract description 16
- 229920006012 semi-aromatic polyamide Polymers 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000000203 mixture Substances 0.000 claims abstract description 52
- 239000000314 lubricant Substances 0.000 claims abstract description 34
- -1 polyethylene Polymers 0.000 claims abstract description 32
- 239000004698 Polyethylene Substances 0.000 claims abstract description 25
- 229920000573 polyethylene Polymers 0.000 claims abstract description 25
- 238000002844 melting Methods 0.000 claims abstract description 10
- 230000008018 melting Effects 0.000 claims abstract description 10
- 229920006122 polyamide resin Polymers 0.000 claims abstract description 7
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 16
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical group NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 16
- 239000008188 pellet Substances 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 7
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 6
- 239000000155 melt Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 239000003365 glass fiber Substances 0.000 claims description 4
- 239000012760 heat stabilizer Substances 0.000 claims description 3
- 239000004611 light stabiliser Substances 0.000 claims description 3
- 239000004609 Impact Modifier Substances 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 claims 2
- 230000000996 additive effect Effects 0.000 claims 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims 1
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
- 239000010456 wollastonite Substances 0.000 claims 1
- 229910052882 wollastonite Inorganic materials 0.000 claims 1
- 239000004610 Internal Lubricant Substances 0.000 abstract description 7
- 230000008021 deposition Effects 0.000 description 10
- 238000000465 moulding Methods 0.000 description 10
- 239000001993 wax Substances 0.000 description 7
- 239000004952 Polyamide Substances 0.000 description 6
- 229920002647 polyamide Polymers 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 229920006111 poly(hexamethylene terephthalamide) Polymers 0.000 description 5
- 229920001684 low density polyethylene Polymers 0.000 description 4
- 239000004702 low-density polyethylene Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 description 3
- 239000004605 External Lubricant Substances 0.000 description 3
- 229920002302 Nylon 6,6 Polymers 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000004700 high-density polyethylene Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229920006106 Zytel® HTN Polymers 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- FIASKJZPIYCESA-UHFFFAOYSA-L calcium;octacosanoate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O FIASKJZPIYCESA-UHFFFAOYSA-L 0.000 description 2
- 125000002843 carboxylic acid group Chemical group 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 125000001841 imino group Chemical group [H]N=* 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
- 239000002952 polymeric resin Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- DMHHYBUEZRZGDK-UHFFFAOYSA-N 2-(3,5-ditert-butyl-4-hydroxyphenyl)propanamide Chemical compound NC(=O)C(C)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 DMHHYBUEZRZGDK-UHFFFAOYSA-N 0.000 description 1
- AIBRSVLEQRWAEG-UHFFFAOYSA-N 3,9-bis(2,4-ditert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical group CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP1OCC2(COP(OC=3C(=CC(=CC=3)C(C)(C)C)C(C)(C)C)OC2)CO1 AIBRSVLEQRWAEG-UHFFFAOYSA-N 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 235000013873 oxidized polyethylene wax Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/30—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by oxidation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US22634609P | 2009-07-17 | 2009-07-17 | |
| US61/226,346 | 2009-07-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20120037487A true KR20120037487A (ko) | 2012-04-19 |
Family
ID=42562871
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020127004046A Withdrawn KR20120037487A (ko) | 2009-07-17 | 2010-07-19 | 반방향족 폴리아미드 수지 조성물, 그 제조 방법, 및 그 물품 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20110015328A1 (enExample) |
| EP (1) | EP2454322A1 (enExample) |
| JP (1) | JP5647241B2 (enExample) |
| KR (1) | KR20120037487A (enExample) |
| CN (1) | CN102482491B (enExample) |
| BR (1) | BR112012001130A2 (enExample) |
| WO (1) | WO2011009111A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20140086739A (ko) * | 2012-12-28 | 2014-07-08 | 제일모직주식회사 | 폴리아미드 수지 조성물 및 이를 포함한 성형품 |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006055727A1 (de) * | 2006-11-25 | 2008-05-29 | Evonik Degussa Gmbh | Verwendung eines synthetischen Wachsoxidats als Verarbeitungshilfsmittel für transparente polare Polymere |
| US9890247B2 (en) * | 2010-04-29 | 2018-02-13 | Dsm Ip Assets B.V. | Semi-aromatic polyamide |
| TWI563034B (en) | 2011-05-13 | 2016-12-21 | Dsm Ip Assets Bv | Flame retardant semi-aromatic polyamide composition and moulded products made therefrom |
| KR101908167B1 (ko) | 2011-07-27 | 2018-10-15 | 디에스엠 아이피 어셋츠 비.브이. | 난연성 폴리아미드 조성물 |
| WO2013160454A2 (en) * | 2012-04-27 | 2013-10-31 | Dsm Ip Assets B.V. | Electrically conductive polyamide substrate |
| CN103571180A (zh) * | 2012-08-12 | 2014-02-12 | 宁波信高塑化有限公司 | 一种耐高温尼龙66及其制备方法 |
| WO2014151735A1 (en) | 2013-03-15 | 2014-09-25 | Ascend Performance Materials Operations Llc | Polymerization coupled compounding process |
| GB202115260D0 (en) | 2021-10-22 | 2021-12-08 | Invista Textiles Uk Ltd | Process for consecutive batch production of polyamide |
| WO2023086359A1 (en) * | 2021-11-09 | 2023-05-19 | Ascend Performance Materials Operations Llc | Polyamide formulations for long term high temperature performance |
| CN114015171B (zh) * | 2021-12-15 | 2022-07-29 | 中国科学院兰州化学物理研究所 | 一种核壳结构润滑剂及其在mc尼龙中的应用 |
| WO2025216269A1 (ja) * | 2024-04-09 | 2025-10-16 | 旭化成株式会社 | ポリアミド樹脂組成物及びポリアミド樹脂組成物の製造方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4438437A (en) | 1981-09-14 | 1984-03-20 | Hazeltine Corporation | Dual mode blade antenna |
| NL8603245A (nl) * | 1986-12-20 | 1988-07-18 | Stamicarbon | Thermoplastische polymeermengsels. |
| US5500473A (en) | 1993-04-30 | 1996-03-19 | E. I. Du Pont De Nemours And Company | Mineral filled copolyamide compositions |
| JPH08134315A (ja) * | 1994-11-02 | 1996-05-28 | Japan Synthetic Rubber Co Ltd | 熱可塑性重合体組成物 |
| DE19742884A1 (de) * | 1997-09-29 | 1999-04-01 | Ticona Polymerwerke Gmbh | Thermoplastische Formmasse |
| TWI281485B (en) * | 2002-06-28 | 2007-05-21 | Mitsui Chemicals Inc | Polyamide resin composition and molding therefrom |
| JP2004083880A (ja) * | 2002-06-28 | 2004-03-18 | Mitsui Chemicals Inc | ポリアミド樹脂組成物およびその成形品 |
| DE102004035837A1 (de) * | 2004-07-23 | 2006-02-16 | Clariant Gmbh | Verwendung von Polyolefinwachsen in Polykondensaten |
| JP4589734B2 (ja) * | 2005-01-13 | 2010-12-01 | 三菱エンジニアリングプラスチックス株式会社 | ポリアミド樹脂組成物 |
| CN101200591B (zh) * | 2006-12-15 | 2011-04-13 | 上海杰事杰新材料股份有限公司 | 一种快速流动的耐高温尼龙复合材料 |
-
2010
- 2010-07-16 US US12/837,533 patent/US20110015328A1/en not_active Abandoned
- 2010-07-19 WO PCT/US2010/042389 patent/WO2011009111A1/en not_active Ceased
- 2010-07-19 JP JP2012520832A patent/JP5647241B2/ja active Active
- 2010-07-19 KR KR1020127004046A patent/KR20120037487A/ko not_active Withdrawn
- 2010-07-19 CN CN201080038665.1A patent/CN102482491B/zh active Active
- 2010-07-19 EP EP10736933A patent/EP2454322A1/en not_active Withdrawn
- 2010-07-19 BR BR112012001130A patent/BR112012001130A2/pt not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20140086739A (ko) * | 2012-12-28 | 2014-07-08 | 제일모직주식회사 | 폴리아미드 수지 조성물 및 이를 포함한 성형품 |
| US9321904B2 (en) | 2012-12-28 | 2016-04-26 | Cheil Industries Inc. | Polyamide resin compositions and articles including the same |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2011009111A1 (en) | 2011-01-20 |
| CN102482491B (zh) | 2014-10-29 |
| JP2012533658A (ja) | 2012-12-27 |
| EP2454322A1 (en) | 2012-05-23 |
| BR112012001130A2 (pt) | 2016-02-23 |
| JP5647241B2 (ja) | 2014-12-24 |
| US20110015328A1 (en) | 2011-01-20 |
| CN102482491A (zh) | 2012-05-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
Patent event date: 20120216 Patent event code: PA01051R01D Comment text: International Patent Application |
|
| PG1501 | Laying open of application | ||
| PC1203 | Withdrawal of no request for examination | ||
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |