KR20100106297A - Led leadframe package, led package using the same, and method of fabricating the led package - Google Patents
Led leadframe package, led package using the same, and method of fabricating the led package Download PDFInfo
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- KR20100106297A KR20100106297A KR1020107005556A KR20107005556A KR20100106297A KR 20100106297 A KR20100106297 A KR 20100106297A KR 1020107005556 A KR1020107005556 A KR 1020107005556A KR 20107005556 A KR20107005556 A KR 20107005556A KR 20100106297 A KR20100106297 A KR 20100106297A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/483—Containers
- H01L33/486—Containers adapted for surface mounting
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/44—Structure, shape, material or disposition of the wire connectors prior to the connecting process
- H01L2224/45—Structure, shape, material or disposition of the wire connectors prior to the connecting process of an individual wire connector
- H01L2224/45001—Core members of the connector
- H01L2224/45099—Material
- H01L2224/451—Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof
- H01L2224/45138—Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof the principal constituent melting at a temperature of greater than or equal to 950°C and less than 1550°C
- H01L2224/45144—Gold (Au) as principal constituent
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/4805—Shape
- H01L2224/4809—Loop shape
- H01L2224/48091—Arched
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2933/00—Details relating to devices covered by the group H01L33/00 but not provided for in its subgroups
- H01L2933/0008—Processes
- H01L2933/0033—Processes relating to semiconductor body packages
- H01L2933/005—Processes relating to semiconductor body packages relating to encapsulations
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/50—Wavelength conversion elements
- H01L33/507—Wavelength conversion elements the elements being in intimate contact with parts other than the semiconductor body or integrated with parts other than the semiconductor body
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/52—Encapsulations
- H01L33/54—Encapsulations having a particular shape
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/64—Heat extraction or cooling elements
- H01L33/642—Heat extraction or cooling elements characterized by the shape
Abstract
Description
The present invention relates to an LED lead frame package, an LED package using the same, and a method of manufacturing the LED package. More particularly, an LED lead frame package that can be easily manufactured and can reduce manufacturing costs, an LED package using the same, and the LED A method for manufacturing a package.
As semiconductor lighting devices, LEDs have many advantages over traditional lighting devices such as incandescent and fluorescent lamps. For example, LEDs have long life, small size, low power consumption, and no mercury pollution. Accordingly, recently, LED is mainly used as a new lighting device to replace the existing lighting device.
In order to improve the light output of the LED package, a convex lens structure is generally introduced into the outer optical layer of the LED package. In conventional LED packages, such convex lens structures are made separately beforehand and mounted on the LED packages. Due to this additional manufacturing and assembly process of the convex lens structure, additional manufacturing and assembly devices are required. In addition, in the process of mounting a previously made convex lens structure on the LED package, an unwanted air layer may be formed between the convex lens structure and the encapsulation layer already formed on the LED package. Also, in the case of the prior art, it is not easy to create convex curvature on the outer surface of the encapsulation layer in the process of forming an encapsulation layer for protecting the LED die on the LED die. Therefore, the conventional LED package manufacturing method has a relatively low production yield and a relatively high production cost.
On the other hand, in order to provide a white LED that generates white light, a method of applying a fluorescent layer directly on a blue or UV LED die is typically used. For example, when using a blue LED die, light of various wavelengths generated in the phosphor material may be mixed with each other or light of the various wavelengths may be mixed with blue excitation light from the blue LED die to emit white light. However, in the case of directly applying a fluorescent layer on the LED die, since the LED die and the fluorescent layer is very close, there may be a problem that the light generated from the phosphor material proceeds to the LED die and absorbed in the LED die.
Accordingly, a technique of providing a transparent spacer between the LED die and the fluorescent layer has been proposed to reduce the possibility that light generated in the fluorescent layer is incident on and absorbed by the LED die or a substrate around the LED die. For example, FIG. 1 shows an example of such a technique disclosed in US Pat. No. 5,959,316. Referring to FIG. 1, an
An object of the present invention is to provide an LED lead frame package and an LED package using the same, which is easy to manufacture and can reduce the manufacturing cost.
It is another object of the present invention to provide an LED package capable of reducing the light absorption loss in which light generated from the phosphor material is incident on and absorbed by the LED die.
Still another object of the present invention is to provide a method of manufacturing an LED package which can be easily manufactured and can reduce manufacturing costs.
A lead frame package according to one type of the present invention includes a heat dissipation base; A plurality of electrodes disposed around the heat dissipation base; An insulating support part surrounding and surrounding the heat dissipation base and the plurality of electrodes; At least two ring-shaped protrusions formed to circumscribe over an upper surface of the insulating support; And at least one ring groove formed between the ring protrusions.
For example, the insulating support may be made of PPA plastic.
The plurality of electrodes may be disposed such that one end thereof faces the side of the heat dissipation base and the other end thereof protrudes from an outer wall of the insulating support.
The heat dissipation base may include a reflective cup having a bottom surface coated with a reflective material.
The at least two ring-shaped protrusions may be formed with pointed upper edges and inclined sidewalls.
The heat dissipation base, the plurality of electrodes, and the insulating support may be integrally formed through an injection molding process.
The ring-shaped protrusions and ring-shaped grooves may be formed on the upper surface of the insulating support through a transfer molding process.
In addition, the LED package according to one type of the present invention may include a lead frame package having the above-described structure.
Specifically, the LED package, at least one LED die (die) attached on the bottom surface of the heat dissipation base; A plurality of wires electrically connecting the LED die and the plurality of electrodes; And an encapsulation layer structure having at least one layer having a convex outer surface formed to cover the LED die. Here, an edge of each of the at least one layer of the encapsulation layer structure may extend to a corresponding one of the at least two ring-shaped protrusions.
The LED die may include at least one of, for example, a UV LED, a blue LED, a green LED, and a red LED.
The encapsulation layer structure can have, for example, only one transparent encapsulation layer.
According to the invention, the curvature of the top surface of the at least one layer can be determined by adjusting the amount of layer material provided in at least one layer of the encapsulation layer structure.
In addition, the encapsulation layer structure, the transparent first encapsulation layer formed to directly cover the LED die; A fluorescent layer covering the first encapsulation layer; And an optical lens layer covering the fluorescent layer.
Here, the effective refractive index of the first encapsulation layer may be smaller than the effective refractive index of the fluorescent layer in the wavelength band of visible light.
In addition, the encapsulation layer structure may further include a transparent second encapsulation layer formed between the first encapsulation layer and the fluorescent layer.
The effective refractive index of the second encapsulation layer may be smaller than the effective refractive index of the first encapsulation layer and the effective refractive index of the fluorescent layer in the wavelength band of visible light.
For example, the fluorescent layer may be formed by uniformly mixing the phosphor material with glass, PC, PMMA, or silicone resin.
The phosphor material may be excited by, for example, UV light, blue light or green light to generate visible light.
For example, the phosphor material may include at least one kind of phosphor material that is excited by UV light, blue light or green light to generate visible light of different wavelengths, respectively.
On the other hand, the manufacturing method of the LED package according to another type of the present invention, a heat dissipation base, a plurality of electrodes disposed around the heat dissipation base, an insulating support for enclosing and fixing the heat dissipation base and the plurality of electrodes, an upper portion of the insulating support Providing a lead frame package comprising at least two ring-shaped protrusions formed around the surface and at least one ring-shaped groove formed between the ring-shaped protrusions; Attaching at least one LED die on an upper surface of the heat dissipation base; Electrically connecting the LED die and the plurality of electrodes; And forming an encapsulation layer structure having at least one layer having a convex outer surface to cover the LED die. Here, an edge of each of the at least one layer of the encapsulation layer structure may extend to a corresponding one of the at least two ring-shaped protrusions.
In addition, the forming of the encapsulation layer structure may include providing a liquid transparent resin material over a heat dissipation base to cover the LED die; And curing the liquid transparent resin material to form a first encapsulation layer. Here, the first encapsulation layer may have a convex outer surface formed by surface tension within the pointed upper edge of the first ring-shaped protrusion of the ring-shaped protrusions.
In addition, the manufacturing method of the LED package, the step of providing a transparent transparent resin material over the first encapsulation layer to cover the first encapsulation layer; Curing the liquid transparent resin material on the first encapsulation layer to form a second encapsulation layer; Providing a liquid transparent resin material in which a phosphor material is uniformly mixed on the second encapsulation layer so as to cover the second encapsulation layer; Curing the liquid transparent resin material mixed with the phosphor material to form a phosphor layer; Providing a liquid transparent resin material over the fluorescent layer to cover the fluorescent layer; And curing the liquid transparent resin material on the fluorescent layer to form an optical lens layer.
Wherein the second encapsulation layer has a convex outer surface formed by surface tension within the pointed upper edge of the second ring-shaped protrusion of the ring-shaped protrusions, and the fluorescent layer has a pointed top of the third ring-shaped protrusion of the ring-shaped protrusions. It has a convex outer surface formed by surface tension in the edge, and the optical lens layer may have a convex outer surface formed by surface tension in the pointed upper edge of the fourth ring-shaped protrusion of the ring-shaped protrusions.
In addition, the manufacturing method of the LED package, comprising: providing a liquid transparent resin material in which the phosphor material is uniformly mixed on the first encapsulation layer to cover the first encapsulation layer; Curing the liquid transparent resin material mixed with the phosphor material to form a phosphor layer; Providing a liquid transparent resin material over the fluorescent layer to cover the fluorescent layer; And curing the liquid transparent resin material on the fluorescent layer to form an optical lens layer.
Wherein the fluorescent layer has a convex outer surface formed by surface tension within a pointed upper edge of a second ring-shaped protrusion of the ring-shaped protrusions, and the optical lens layer has a pointed top edge of a third ring-shaped protrusion of the ring-shaped protrusions. It may have a convex outer surface formed by surface tension within.
According to the present invention, in manufacturing an LED package, a surface is provided by providing a liquid transparent resin material over at least two ring-shaped protrusions having pointed top edges and inclined sidewalls and at least one ring-shaped groove formed between the ring-shaped protrusions. The tension can be used to easily form an encapsulation layer having a convex curved surface in a single process.
1 is a cross-sectional view schematically showing the structure of one example of the conventional white LEDs.
2 is a perspective view schematically showing the structure of the LED lead frame package according to an embodiment of the present invention.
3 is a plan view schematically showing the structure of the LED lead frame package shown in FIG.
FIG. 4 is a perspective view schematically illustrating an arrangement relationship between a heat dissipation base and a plurality of electrodes except for an insulating support in the LED lead frame package shown in FIG. 2.
FIG. 5 is a cross-sectional view schematically illustrating the structure of the LED lead frame package shown in FIG. 2.
6 is a cross-sectional view schematically showing the structure of an LED package according to an embodiment of the present invention.
7 is a schematic cross-sectional view of a structure of an LED package according to another embodiment of the present invention.
8 and 9 are cross-sectional views schematically illustrating the principle of the LED package manufacturing method according to the present invention.
Hereinafter, an LED lead frame package, an LED package using the same, and a manufacturing method of the LED package according to an embodiment of the present invention will be described in detail with reference to the accompanying drawings. In the drawings, like reference numerals refer to like elements, and the size of each element in the drawings may be exaggerated for clarity and convenience of description.
2 is a perspective view schematically showing the structure of the LED
Referring to FIG. 3, which is a plan view schematically showing the structure of the LED
Also, referring to FIG. 4, the
In the state where the
In addition, referring to the perspective view of FIG. 5 and FIG. 2, which schematically illustrates the cross-sectional structure of the LED
The plurality of ring-shaped
The LED
Here, the LED die 4 may be fixed to the bottom surface of the
The
The
The
Meanwhile, according to the present invention, the
Hereinafter, a method of manufacturing the
Next, the liquid transparent resin material is filled in the reflecting
Thereafter, a liquid transparent resin material in which a phosphor material is uniformly mixed is provided on the
Finally, a liquid transparent resin material is provided over the
7 is a cross-sectional view schematically showing the structure of the LED package 40 according to another embodiment of the present invention. Unlike the
Referring to FIG. 7, the
As shown in FIG. 7, the edge of the
The manufacturing method for the encapsulation layer structure of the LED package 40 shown in FIG. 7 may be applied to the manufacturing method of the
Until now, the
For example, the
Alternatively, the
When manufacturing a white light LED package, as described above, a multilayer encapsulation layer structure including the
So far, exemplary embodiments of an LED lead frame package, an LED package using the same, and a method of manufacturing the LED package have been described and illustrated in the accompanying drawings in order to help understanding of the present invention. However, it should be understood that such embodiments are merely illustrative of the invention and do not limit it. And it is to be understood that the invention is not limited to the details shown and described. This is because various other modifications may occur to those skilled in the art.
Claims (25)
A plurality of electrodes disposed around the heat dissipation base;
An insulating support part surrounding and surrounding the heat dissipation base and the plurality of electrodes;
At least two ring-shaped protrusions formed to circumscribe over an upper surface of the insulating support; And
And at least one ring groove formed between the ring protrusions.
The insulating support portion is a lead frame package made of PPA plastic.
The plurality of electrodes is a lead frame package is disposed so that one end is opposed to the side of the heat dissipation base and the other end protrudes from the outer wall of the insulating support.
And the heat dissipation base has a reflective cup coated with a reflective material on a bottom surface thereof.
Wherein said at least two ring-shaped protrusions have sharp top edges and inclined sidewalls.
The heat dissipation base, the plurality of electrodes and the insulating support are integrally formed through an injection molding process.
The ring-shaped protrusion and the ring-shaped groove are formed on the upper surface of the insulating support through a transfer molding process.
The LED package is:
At least one LED die attached to a bottom surface of the heat dissipation base;
A plurality of wires electrically connecting the LED die and the plurality of electrodes; And
An encapsulation layer structure formed to cover the LED die, the encapsulation layer structure having at least one layer having a convex outer surface,
An edge of each of the at least one layer of the encapsulation layer structure extends to a corresponding one of the at least two ring-shaped protrusions.
The LED die comprises at least one of a UV LED, a blue LED, a green LED and a red LED.
The encapsulation layer structure has only one transparent encapsulation layer.
The curvature of the top surface of the at least one layer is determined by adjusting the amount of layer material provided in at least one layer of the encapsulation layer structure.
The encapsulation layer structure is:
A transparent first encapsulation layer formed to directly cover the LED die;
A fluorescent layer covering the first encapsulation layer; And
LED package comprising an optical lens layer covering the fluorescent layer.
The effective refractive index of the first encapsulation layer is less than the effective refractive index of the fluorescent layer in the wavelength band of visible light.
The encapsulation layer structure further includes a transparent second encapsulation layer formed between the first encapsulation layer and the fluorescent layer.
The effective refractive index of the second encapsulation layer is less than the effective refractive index of the first encapsulation layer and the effective refractive index of the fluorescent layer in the wavelength band of visible light.
The fluorescent layer is a LED package formed by uniformly mixing the phosphor material in glass, PC, PMMA, or silicone resin.
Wherein said phosphor material is excited by UV light, blue light or green light to generate visible light.
Wherein said phosphor material comprises at least one type of phosphor material that is excited by UV light, blue light or green light to generate visible light of different wavelengths, respectively.
Attaching at least one LED die on a bottom surface of the heat dissipation base;
Electrically connecting the LED die and the plurality of electrodes; And
Forming an encapsulation layer structure having at least one layer having a convex outer surface to cover said LED die,
An edge of each of the at least one layer of the encapsulation layer structure extends to a corresponding one of the at least two ring-shaped protrusions.
Forming the encapsulation layer structure is:
Providing a liquid transparent resin material over a heat dissipation base to cover the LED die; And
Curing the liquid transparent resin material to form a first encapsulation layer,
And wherein the first encapsulation layer has a convex outer surface formed by surface tension within a pointed upper edge of the first ring-shaped protrusions of the ring-shaped protrusions.
Providing a liquid transparent resin material over the first encapsulation layer to cover the first encapsulation layer;
Curing the liquid transparent resin material on the first encapsulation layer to form a second encapsulation layer;
Providing a liquid transparent resin material in which a phosphor material is uniformly mixed on the second encapsulation layer so as to cover the second encapsulation layer;
Curing the liquid transparent resin material mixed with the phosphor material to form a phosphor layer;
Providing a liquid transparent resin material over the fluorescent layer to cover the fluorescent layer; And
And curing the liquid transparent resin material on the fluorescent layer to form an optical lens layer.
The second encapsulation layer has a convex outer surface formed by surface tension in the pointed upper edge of the second ring-shaped protrusion of the ring-shaped protrusions, and the fluorescent layer is in the pointed top edge of the third ring-shaped protrusion of the ring-shaped protrusions. And a convex outer surface formed by surface tension, and wherein the optical lens layer has a convex outer surface formed by surface tension within a pointed upper edge of a fourth ring-shaped protrusion of the ring-shaped protrusions.
Providing a liquid transparent resin material in which a phosphor material is uniformly mixed on the first encapsulation layer so as to cover the first encapsulation layer;
Curing the liquid transparent resin material mixed with the phosphor material to form a phosphor layer;
Providing a liquid transparent resin material over the fluorescent layer to cover the fluorescent layer; And
And curing the liquid transparent resin material on the fluorescent layer to form an optical lens layer.
The fluorescent layer has a convex outer surface formed by surface tension in the pointed upper edge of the second ring-shaped protrusion of the ring-shaped protrusions, and the optical lens layer is in the pointed top edge of the third ring-shaped protrusion of the ring-shaped protrusions. A method of manufacturing an LED package having a convex outer surface formed by surface tension.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
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US12/381,409 | 2009-03-10 | ||
US12/381,408 | 2009-03-10 | ||
US12/381,408 US8058667B2 (en) | 2009-03-10 | 2009-03-10 | Leadframe package for light emitting diode device |
US12/381,409 US8039862B2 (en) | 2009-03-10 | 2009-03-10 | White light emitting diode package having enhanced white lighting efficiency and method of making the same |
PCT/KR2010/001134 WO2010104276A2 (en) | 2009-03-10 | 2010-02-24 | Led leadframe package, led package using the same, and method of manufacturing the led package |
Publications (2)
Publication Number | Publication Date |
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KR20100106297A true KR20100106297A (en) | 2010-10-01 |
KR101111256B1 KR101111256B1 (en) | 2012-02-22 |
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KR1020107005556A KR101111256B1 (en) | 2009-03-10 | 2010-02-24 | LED leadframe package, LED package using the same, and method of fabricating the LED package |
Country Status (9)
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EP (1) | EP2406835A4 (en) |
JP (1) | JP2012520565A (en) |
KR (1) | KR101111256B1 (en) |
CN (1) | CN102318091A (en) |
AU (1) | AU2010221920A1 (en) |
RU (1) | RU2488195C2 (en) |
SG (1) | SG173518A1 (en) |
TW (1) | TW201044646A (en) |
WO (1) | WO2010104276A2 (en) |
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2010
- 2010-02-24 RU RU2011134604/28A patent/RU2488195C2/en not_active IP Right Cessation
- 2010-02-24 AU AU2010221920A patent/AU2010221920A1/en not_active Abandoned
- 2010-02-24 EP EP10750967.1A patent/EP2406835A4/en not_active Withdrawn
- 2010-02-24 CN CN2010800077963A patent/CN102318091A/en active Pending
- 2010-02-24 WO PCT/KR2010/001134 patent/WO2010104276A2/en active Application Filing
- 2010-02-24 KR KR1020107005556A patent/KR101111256B1/en not_active IP Right Cessation
- 2010-02-24 JP JP2011553937A patent/JP2012520565A/en active Pending
- 2010-02-24 SG SG2011055852A patent/SG173518A1/en unknown
- 2010-03-04 TW TW99106287A patent/TW201044646A/en unknown
Cited By (8)
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KR101148780B1 (en) * | 2011-11-16 | 2012-05-24 | 김종율 | A led package and a manufacturing method therefor |
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US9923128B2 (en) | 2013-08-27 | 2018-03-20 | Lumens Co., Ltd. | Light emitting device package and backlight unit having the same |
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KR102634521B1 (en) | 2023-10-31 | 2024-02-07 | 장연식 | Medicine injection system |
Also Published As
Publication number | Publication date |
---|---|
JP2012520565A (en) | 2012-09-06 |
SG173518A1 (en) | 2011-09-29 |
WO2010104276A3 (en) | 2010-11-25 |
EP2406835A4 (en) | 2013-09-18 |
TW201044646A (en) | 2010-12-16 |
RU2011134604A (en) | 2013-04-20 |
WO2010104276A2 (en) | 2010-09-16 |
RU2488195C2 (en) | 2013-07-20 |
CN102318091A (en) | 2012-01-11 |
KR101111256B1 (en) | 2012-02-22 |
EP2406835A2 (en) | 2012-01-18 |
AU2010221920A1 (en) | 2011-09-29 |
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