KR20100016614A - 지지된 메탈로센 촉매 - Google Patents

지지된 메탈로센 촉매 Download PDF

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Publication number
KR20100016614A
KR20100016614A KR1020097023925A KR20097023925A KR20100016614A KR 20100016614 A KR20100016614 A KR 20100016614A KR 1020097023925 A KR1020097023925 A KR 1020097023925A KR 20097023925 A KR20097023925 A KR 20097023925A KR 20100016614 A KR20100016614 A KR 20100016614A
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South Korea
Prior art keywords
group
ethylene
substituent
propylene copolymer
isotactic
Prior art date
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KR1020097023925A
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English (en)
Korean (ko)
Inventor
윌리엄 가우디어
데이비드 라우슈어
준 티안
나단 윌리엄스
Original Assignee
피나 테크놀러지, 인코포레이티드
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Publication of KR20100016614A publication Critical patent/KR20100016614A/ko
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR1020097023925A 2007-05-18 2008-05-13 지지된 메탈로센 촉매 Ceased KR20100016614A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/804,483 US20080287619A1 (en) 2007-05-18 2007-05-18 Supported metallocene catalysts
US11/804,483 2007-05-18

Publications (1)

Publication Number Publication Date
KR20100016614A true KR20100016614A (ko) 2010-02-12

Family

ID=40028164

Family Applications (1)

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KR1020097023925A Ceased KR20100016614A (ko) 2007-05-18 2008-05-13 지지된 메탈로센 촉매

Country Status (8)

Country Link
US (1) US20080287619A1 (https=)
EP (1) EP2155389A4 (https=)
JP (1) JP2010528126A (https=)
KR (1) KR20100016614A (https=)
CN (1) CN101568383B (https=)
CA (1) CA2677773A1 (https=)
MX (1) MX2009005467A (https=)
WO (1) WO2008144303A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8299188B2 (en) * 2007-05-18 2012-10-30 Fina Technology, Inc. Supported metallocene catalysts
TWI555574B (zh) * 2011-03-09 2016-11-01 亞比馬利股份有限公司 含有碳陽離子劑之鋁氧烷催化活性劑及其於聚烯烴催化劑中之用途
EP3013870B1 (en) * 2013-06-24 2023-10-25 Saudi Basic Industries Corporation Process for making a blow molded article based on high density polyethylene prepared with titanated chromium-based catalysts

Family Cites Families (28)

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US5643847A (en) * 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
EP0818475A1 (en) * 1996-07-11 1998-01-14 Fina Research S.A. Syndiotactic/atactic block polyolefins, catalysts and processes for producing the same
US5847059A (en) * 1996-12-20 1998-12-08 Fina Technology, Inc. Catalyst yield from supported metallocene catalysts
EP0881237A1 (en) * 1997-05-26 1998-12-02 Fina Research S.A. Process to produce bimodal polyolefins with metallocene catalysts using two reaction zones
US6090325A (en) * 1997-09-24 2000-07-18 Fina Technology, Inc. Biaxially-oriented metallocene-based polypropylene films
EP0967234A1 (en) * 1998-06-24 1999-12-29 Fina Research S.A. Production of polyethylene
US6515086B1 (en) * 1999-02-19 2003-02-04 Fina Research, S.A. Polyolefin production
DE60034308T2 (de) * 1999-10-08 2007-12-20 Mitsui Chemicals, Inc. Metallocene, ein Verfahren zur deren Herstellung, Olefinpolymerisationskatalysator, und ein Verfahren zur Herstellung von Polyolefinen
US6443095B1 (en) * 2000-12-07 2002-09-03 Mcmahon Linda Live insect bird feeder and method
US6984698B2 (en) * 2001-01-31 2006-01-10 Fina Technology, Inc. Polyethylene films for barrier applications
US6777366B2 (en) * 2001-02-13 2004-08-17 Fina Technology, Inc. Method for the preparation of metallocene catalysts
US6777367B2 (en) * 2001-02-13 2004-08-17 Fina Technology, Inc. Method for the preparation of metallocene catalysts
US20030236365A1 (en) * 2002-06-24 2003-12-25 Fina Technology, Inc. Polyolefin production with a high performance support for a metallocene catalyst system
TWI296270B (en) * 2002-07-19 2008-05-01 Mitsui Chemicals Inc Propylene copolymer, polypropylene composition and its usage, and transition metal compound, catalyst for olefinic polymerization
US6716936B1 (en) * 2002-12-16 2004-04-06 Equistar Chemicals L.P. Cascaded boiling pool slurry reactors for producing bimodal low to medium density polyethylene polymers
US6855783B2 (en) * 2003-04-11 2005-02-15 Fina Technology, Inc. Supported metallocene catalysts
EP1493759A1 (en) * 2003-07-04 2005-01-05 Total Petrochemicals Research Feluy Polymerisation process
TWI247756B (en) * 2003-08-22 2006-01-21 Mitsui Chemicals Inc Propylene random copolymers, use thereof and manufacturing method of the same
US7034157B2 (en) * 2003-10-23 2006-04-25 Fina Technology, Inc. Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins
US20050234198A1 (en) * 2004-04-20 2005-10-20 Fina Technology, Inc. Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system
JP2006008983A (ja) * 2004-05-28 2006-01-12 Mitsui Chemicals Inc プロピレン系重合体
JP4327043B2 (ja) * 2004-08-11 2009-09-09 三井化学株式会社 プロピレン系重合体およびシュリンクフィルムへの応用
US7879960B2 (en) * 2004-08-30 2011-02-01 Mitsui Chemicals, Inc. Process for producing propylene polymer
US7446216B2 (en) * 2004-12-16 2008-11-04 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7220806B2 (en) * 2005-04-29 2007-05-22 Fina Technology, Inc. Process for increasing ethylene incorporation into random copolymers
US7514510B2 (en) * 2006-07-25 2009-04-07 Fina Technology, Inc. Fluorenyl catalyst compositions and olefin polymerization process
WO2008029809A1 (fr) * 2006-09-05 2008-03-13 Prime Polymer Co., Ltd. Matériau creux étiré multicouche
KR20090067171A (ko) * 2006-09-12 2009-06-24 미쓰이 가가쿠 가부시키가이샤 폴리프로필렌 수지 및 블로우 용기

Also Published As

Publication number Publication date
EP2155389A4 (en) 2012-06-27
CA2677773A1 (en) 2008-11-27
US20080287619A1 (en) 2008-11-20
WO2008144303A1 (en) 2008-11-27
EP2155389A1 (en) 2010-02-24
MX2009005467A (es) 2009-06-02
CN101568383B (zh) 2013-03-20
CN101568383A (zh) 2009-10-28
JP2010528126A (ja) 2010-08-19

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