CN101568383B - 负载型茂金属催化剂 - Google Patents

负载型茂金属催化剂 Download PDF

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Publication number
CN101568383B
CN101568383B CN2008800011831A CN200880001183A CN101568383B CN 101568383 B CN101568383 B CN 101568383B CN 2008800011831 A CN2008800011831 A CN 2008800011831A CN 200880001183 A CN200880001183 A CN 200880001183A CN 101568383 B CN101568383 B CN 101568383B
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melt flow
ethylene
alkyl
propylene copolymer
group
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Expired - Fee Related
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English (en)
Chinese (zh)
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CN101568383A (zh
Inventor
W·戈捷
D·劳舍尔
J·田
N·威廉姆斯
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Fina Technology Inc
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Fina Technology Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN2008800011831A 2007-05-18 2008-05-13 负载型茂金属催化剂 Expired - Fee Related CN101568383B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/804,483 US20080287619A1 (en) 2007-05-18 2007-05-18 Supported metallocene catalysts
US11/804,483 2007-05-18
PCT/US2008/063513 WO2008144303A1 (en) 2007-05-18 2008-05-13 Supported metallocene catalysts

Publications (2)

Publication Number Publication Date
CN101568383A CN101568383A (zh) 2009-10-28
CN101568383B true CN101568383B (zh) 2013-03-20

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CN2008800011831A Expired - Fee Related CN101568383B (zh) 2007-05-18 2008-05-13 负载型茂金属催化剂

Country Status (8)

Country Link
US (1) US20080287619A1 (https=)
EP (1) EP2155389A4 (https=)
JP (1) JP2010528126A (https=)
KR (1) KR20100016614A (https=)
CN (1) CN101568383B (https=)
CA (1) CA2677773A1 (https=)
MX (1) MX2009005467A (https=)
WO (1) WO2008144303A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8299188B2 (en) * 2007-05-18 2012-10-30 Fina Technology, Inc. Supported metallocene catalysts
TWI555574B (zh) * 2011-03-09 2016-11-01 亞比馬利股份有限公司 含有碳陽離子劑之鋁氧烷催化活性劑及其於聚烯烴催化劑中之用途
EP3013870B1 (en) * 2013-06-24 2023-10-25 Saudi Basic Industries Corporation Process for making a blow molded article based on high density polyethylene prepared with titanated chromium-based catalysts

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1434061A (zh) * 1996-12-20 2003-08-06 弗纳技术股份有限公司 丙烯的聚合催化剂
CN1795211A (zh) * 2003-04-11 2006-06-28 弗纳技术股份有限公司 负载型茂金属催化剂
CN1816571A (zh) * 2003-07-04 2006-08-09 托塔尔石油化学产品研究弗吕公司 无规烯烃共聚物

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US5643847A (en) * 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
EP0818475A1 (en) * 1996-07-11 1998-01-14 Fina Research S.A. Syndiotactic/atactic block polyolefins, catalysts and processes for producing the same
EP0881237A1 (en) * 1997-05-26 1998-12-02 Fina Research S.A. Process to produce bimodal polyolefins with metallocene catalysts using two reaction zones
US6090325A (en) * 1997-09-24 2000-07-18 Fina Technology, Inc. Biaxially-oriented metallocene-based polypropylene films
EP0967234A1 (en) * 1998-06-24 1999-12-29 Fina Research S.A. Production of polyethylene
US6515086B1 (en) * 1999-02-19 2003-02-04 Fina Research, S.A. Polyolefin production
DE60034308T2 (de) * 1999-10-08 2007-12-20 Mitsui Chemicals, Inc. Metallocene, ein Verfahren zur deren Herstellung, Olefinpolymerisationskatalysator, und ein Verfahren zur Herstellung von Polyolefinen
US6443095B1 (en) * 2000-12-07 2002-09-03 Mcmahon Linda Live insect bird feeder and method
US6984698B2 (en) * 2001-01-31 2006-01-10 Fina Technology, Inc. Polyethylene films for barrier applications
US6777366B2 (en) * 2001-02-13 2004-08-17 Fina Technology, Inc. Method for the preparation of metallocene catalysts
US6777367B2 (en) * 2001-02-13 2004-08-17 Fina Technology, Inc. Method for the preparation of metallocene catalysts
US20030236365A1 (en) * 2002-06-24 2003-12-25 Fina Technology, Inc. Polyolefin production with a high performance support for a metallocene catalyst system
TWI296270B (en) * 2002-07-19 2008-05-01 Mitsui Chemicals Inc Propylene copolymer, polypropylene composition and its usage, and transition metal compound, catalyst for olefinic polymerization
US6716936B1 (en) * 2002-12-16 2004-04-06 Equistar Chemicals L.P. Cascaded boiling pool slurry reactors for producing bimodal low to medium density polyethylene polymers
TWI247756B (en) * 2003-08-22 2006-01-21 Mitsui Chemicals Inc Propylene random copolymers, use thereof and manufacturing method of the same
US7034157B2 (en) * 2003-10-23 2006-04-25 Fina Technology, Inc. Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins
US20050234198A1 (en) * 2004-04-20 2005-10-20 Fina Technology, Inc. Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system
JP2006008983A (ja) * 2004-05-28 2006-01-12 Mitsui Chemicals Inc プロピレン系重合体
JP4327043B2 (ja) * 2004-08-11 2009-09-09 三井化学株式会社 プロピレン系重合体およびシュリンクフィルムへの応用
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US7446216B2 (en) * 2004-12-16 2008-11-04 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
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US7514510B2 (en) * 2006-07-25 2009-04-07 Fina Technology, Inc. Fluorenyl catalyst compositions and olefin polymerization process
WO2008029809A1 (fr) * 2006-09-05 2008-03-13 Prime Polymer Co., Ltd. Matériau creux étiré multicouche
KR20090067171A (ko) * 2006-09-12 2009-06-24 미쓰이 가가쿠 가부시키가이샤 폴리프로필렌 수지 및 블로우 용기

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1434061A (zh) * 1996-12-20 2003-08-06 弗纳技术股份有限公司 丙烯的聚合催化剂
CN1795211A (zh) * 2003-04-11 2006-06-28 弗纳技术股份有限公司 负载型茂金属催化剂
CN1816571A (zh) * 2003-07-04 2006-08-09 托塔尔石油化学产品研究弗吕公司 无规烯烃共聚物

Also Published As

Publication number Publication date
EP2155389A4 (en) 2012-06-27
CA2677773A1 (en) 2008-11-27
US20080287619A1 (en) 2008-11-20
WO2008144303A1 (en) 2008-11-27
EP2155389A1 (en) 2010-02-24
MX2009005467A (es) 2009-06-02
CN101568383A (zh) 2009-10-28
JP2010528126A (ja) 2010-08-19
KR20100016614A (ko) 2010-02-12

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