KR20060127408A - 난융 산화물 지지체 상부에 형성된 탄소나노튜브의 정제방법 - Google Patents
난융 산화물 지지체 상부에 형성된 탄소나노튜브의 정제방법 Download PDFInfo
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- KR20060127408A KR20060127408A KR1020067011326A KR20067011326A KR20060127408A KR 20060127408 A KR20060127408 A KR 20060127408A KR 1020067011326 A KR1020067011326 A KR 1020067011326A KR 20067011326 A KR20067011326 A KR 20067011326A KR 20060127408 A KR20060127408 A KR 20060127408A
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- South Korea
- Prior art keywords
- water
- carbon
- carbon nanotube
- mixture
- contacting step
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 147
- 239000002041 carbon nanotube Substances 0.000 title claims abstract description 126
- 229910021393 carbon nanotube Inorganic materials 0.000 title claims abstract description 126
- 238000000034 method Methods 0.000 title claims description 75
- 238000000746 purification Methods 0.000 title claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 99
- 239000000463 material Substances 0.000 claims abstract description 97
- 229910001868 water Inorganic materials 0.000 claims abstract description 90
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 89
- 239000003054 catalyst Substances 0.000 claims abstract description 70
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- 229910052751 metal Inorganic materials 0.000 claims abstract description 58
- 239000002184 metal Substances 0.000 claims abstract description 58
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 44
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 44
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 37
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims abstract description 24
- 150000001875 compounds Chemical class 0.000 claims abstract description 15
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- 238000010438 heat treatment Methods 0.000 claims description 7
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- 239000003638 chemical reducing agent Substances 0.000 claims description 6
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- 150000001412 amines Chemical class 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims 2
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- QWDJLDTYWNBUKE-UHFFFAOYSA-L magnesium bicarbonate Chemical compound [Mg+2].OC([O-])=O.OC([O-])=O QWDJLDTYWNBUKE-UHFFFAOYSA-L 0.000 description 10
- 239000002370 magnesium bicarbonate Substances 0.000 description 10
- 229910000022 magnesium bicarbonate Inorganic materials 0.000 description 10
- 235000014824 magnesium bicarbonate Nutrition 0.000 description 10
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 10
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- -1 oleum Chemical compound 0.000 description 3
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- 150000003624 transition metals Chemical class 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
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- 238000000921 elemental analysis Methods 0.000 description 2
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- 229940093915 gynecological organic acid Drugs 0.000 description 2
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- 150000002506 iron compounds Chemical class 0.000 description 2
- 235000013980 iron oxide Nutrition 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- MFUVDXOKPBAHMC-UHFFFAOYSA-N magnesium;dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MFUVDXOKPBAHMC-UHFFFAOYSA-N 0.000 description 2
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- 229910019614 (NH4)6 Mo7 O24.4H2 O Inorganic materials 0.000 description 1
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 1
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- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
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- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 229910000608 Fe(NO3)3.9H2O Inorganic materials 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical group [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
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- FIXLYHHVMHXSCP-UHFFFAOYSA-H azane;dihydroxy(dioxo)molybdenum;trioxomolybdenum;tetrahydrate Chemical compound N.N.N.N.N.N.O.O.O.O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O FIXLYHHVMHXSCP-UHFFFAOYSA-H 0.000 description 1
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- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
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- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
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- QZRHHEURPZONJU-UHFFFAOYSA-N iron(2+) dinitrate nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QZRHHEURPZONJU-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F13/00—Recovery of starting material, waste material or solvents during the manufacture of artificial filaments or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/168—After-treatment
- C01B32/17—Purification
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
- Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/84—Manufacture, treatment, or detection of nanostructure
- Y10S977/842—Manufacture, treatment, or detection of nanostructure for carbon nanotubes or fullerenes
- Y10S977/845—Purification or separation of fullerenes or nanotubes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Textile Engineering (AREA)
- Composite Materials (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Carbon And Carbon Compounds (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US52801803P | 2003-12-09 | 2003-12-09 | |
| US60/528,018 | 2003-12-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20060127408A true KR20060127408A (ko) | 2006-12-12 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020067011326A Withdrawn KR20060127408A (ko) | 2003-12-09 | 2004-12-03 | 난융 산화물 지지체 상부에 형성된 탄소나노튜브의 정제방법 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US7488875B2 (https=) |
| EP (1) | EP1701911A1 (https=) |
| JP (1) | JP4797122B2 (https=) |
| KR (1) | KR20060127408A (https=) |
| WO (1) | WO2005056474A1 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101443223B1 (ko) * | 2008-04-04 | 2014-09-24 | 삼성전자주식회사 | 인덕터 및 그 동작방법 |
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|---|---|---|---|---|
| US6723299B1 (en) | 2001-05-17 | 2004-04-20 | Zyvex Corporation | System and method for manipulating nanotubes |
| US6905667B1 (en) | 2002-05-02 | 2005-06-14 | Zyvex Corporation | Polymer and method for using the polymer for noncovalently functionalizing nanotubes |
| US20040034177A1 (en) | 2002-05-02 | 2004-02-19 | Jian Chen | Polymer and method for using the polymer for solubilizing nanotubes |
| JP2007516314A (ja) | 2003-05-22 | 2007-06-21 | ザイベックス コーポレーション | ナノコンポジットおよびナノコンポジットに関する方法 |
| US7618300B2 (en) * | 2003-12-24 | 2009-11-17 | Duke University | Method of synthesizing small-diameter carbon nanotubes with electron field emission properties |
| US20050221016A1 (en) * | 2003-12-31 | 2005-10-06 | Glatkowski Paul J | Methods for modifying carbon nanotube structures to enhance coating optical and electronic properties of transparent conductive coatings |
| US7296576B2 (en) | 2004-08-18 | 2007-11-20 | Zyvex Performance Materials, Llc | Polymers for enhanced solubility of nanomaterials, compositions and methods therefor |
| EP1782884A1 (en) * | 2005-11-07 | 2007-05-09 | Research Institute of Petroleum Industry (RIPI) | Catalyst based on MgO or alumina nanoporous support and preparation of the same |
| JP2007145678A (ja) * | 2005-11-30 | 2007-06-14 | Mitsubishi Heavy Ind Ltd | ナノカーボン材料の製造方法 |
| US8182783B2 (en) * | 2006-11-16 | 2012-05-22 | New Jersey Institute Of Technology | Rapid microwave process for purification of nanocarbon preparations |
| US7868333B2 (en) * | 2006-12-21 | 2011-01-11 | E.I. Du Pont De Nemours And Company | Process for demetallization of carbon nanotubes |
| US7727505B2 (en) * | 2008-05-21 | 2010-06-01 | International Business Machines Corporation | Methods for separating carbon nanotubes by enhancing the density differential |
| EP2196260A1 (en) * | 2008-12-02 | 2010-06-16 | Research Institute of Petroleum Industry (RIPI) | Hydrodesulphurization nanocatalyst, its use and a process for its production |
| KR100976174B1 (ko) * | 2009-02-13 | 2010-08-16 | 금호석유화학 주식회사 | 얇은 다중벽 탄소나노튜브 제조용 촉매조성물 및 이의 제조방법 |
| US10069072B2 (en) * | 2010-09-20 | 2018-09-04 | Nantero, Inc. | Nanotube solutions with high concentration and low contamination and methods for purifiying nanotube solutions |
| JP5885463B2 (ja) * | 2010-11-02 | 2016-03-15 | 三菱マテリアル株式会社 | カーボンナノファイバー分散液、ならびに塗料組成物およびペースト組成物 |
| EP2751027A4 (en) * | 2011-09-02 | 2015-05-13 | Ecospec Global Technology Pte Ltd | METHOD FOR GASKING CARBON DIOXIDE AND ITS USE |
| JP5875312B2 (ja) * | 2011-09-30 | 2016-03-02 | 三菱マテリアル株式会社 | カーボンナノファイバーの精製方法および用途 |
| EP2825505A1 (en) * | 2012-03-16 | 2015-01-21 | Carbodeon Ltd Oy | Detonation nanodiamond material purification method and product thereof |
| TWI627130B (zh) | 2012-04-18 | 2018-06-21 | 美商艾克頌美孚上游研究公司 | 由連續反應器流出物移出碳奈米管之方法 |
| WO2015034469A2 (en) * | 2013-09-03 | 2015-03-12 | Aneeve Nanotechnologies, Llc | A process for cleaning carbon nanotubes and other nanostructured films |
| CN103817107B (zh) * | 2014-02-28 | 2016-05-18 | 北京宝塔三聚能源科技有限公司 | 高效粉体清洗设备 |
| WO2018022999A1 (en) | 2016-07-28 | 2018-02-01 | Seerstone Llc. | Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same |
| EP4211078A4 (en) * | 2020-09-09 | 2025-07-16 | Dickinson Corp | EVOLUTIONARY SYNTHESIS OF PERIMORPHIC CARBONS |
| CN116654909A (zh) * | 2023-07-10 | 2023-08-29 | 河南克莱威纳米碳材料有限公司 | 一种晶须碳纳米管的提纯方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB477744A (en) | 1937-04-14 | 1938-01-05 | Maxence Drujon | Process for the manufacture of alkali metal and magnesium salts |
| DE3227745A1 (de) * | 1982-07-24 | 1984-01-26 | Basf Ag, 6700 Ludwigshafen | Verfahren zur entfernung des katalysators aus polyphenylenethern |
| JPH072994B2 (ja) * | 1989-01-14 | 1995-01-18 | 住友軽金属工業株式会社 | 金属材料の表面浄化法 |
| DE69332689T2 (de) * | 1992-05-22 | 2003-12-18 | Hyperion Catalysis International, Inc. | Verbesserte methoden und katalysatoren zur herstellung von kohlenstoffibrillen |
| DE19620310C2 (de) * | 1996-05-10 | 1999-12-16 | Voest Alpine Ind Anlagen | Verfahren zum Behandeln von Waschwasser aus der Gaswäsche einer Eisenerzreduktionsanlage |
| CN101077774B (zh) | 1998-09-18 | 2013-11-06 | 威廉马歇莱思大学 | 碳毫微管绳和碳毫微管的制造方法 |
| US6413487B1 (en) * | 2000-06-02 | 2002-07-02 | The Board Of Regents Of The University Of Oklahoma | Method and apparatus for producing carbon nanotubes |
| US7090819B2 (en) | 2001-02-12 | 2006-08-15 | William Marsh Rice University | Gas-phase process for purifying single-wall carbon nanotubes and compositions thereof |
| US6752977B2 (en) * | 2001-02-12 | 2004-06-22 | William Marsh Rice University | Process for purifying single-wall carbon nanotubes and compositions thereof |
| JP2003206117A (ja) * | 2002-01-15 | 2003-07-22 | Centre National De La Recherche Scientifique (Cnrs) | 多層カーボンナノチューブの大量生産方法 |
| JP3718775B2 (ja) * | 2002-04-09 | 2005-11-24 | 株式会社日本製鋼所 | カーボンナノチューブの精製方法 |
| US7250148B2 (en) * | 2002-07-31 | 2007-07-31 | Carbon Nanotechnologies, Inc. | Method for making single-wall carbon nanotubes using supported catalysts |
| FR2843382B1 (fr) * | 2002-08-08 | 2005-12-23 | Centre Nat Rech Scient | Procede d'ouverture de nanotubes de carbone a leurs extremites et applications |
| JP3755662B2 (ja) * | 2002-12-04 | 2006-03-15 | 独立行政法人産業技術総合研究所 | カーボンナノチューブの製造方法 |
-
2004
- 2004-12-03 US US11/003,916 patent/US7488875B2/en not_active Expired - Lifetime
- 2004-12-03 JP JP2006543896A patent/JP4797122B2/ja not_active Expired - Fee Related
- 2004-12-03 EP EP04812912A patent/EP1701911A1/en not_active Withdrawn
- 2004-12-03 WO PCT/US2004/040489 patent/WO2005056474A1/en not_active Ceased
- 2004-12-03 KR KR1020067011326A patent/KR20060127408A/ko not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101443223B1 (ko) * | 2008-04-04 | 2014-09-24 | 삼성전자주식회사 | 인덕터 및 그 동작방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| US7488875B2 (en) | 2009-02-10 |
| JP2007513861A (ja) | 2007-05-31 |
| US20060062718A1 (en) | 2006-03-23 |
| JP4797122B2 (ja) | 2011-10-19 |
| EP1701911A1 (en) | 2006-09-20 |
| WO2005056474A1 (en) | 2005-06-23 |
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