KR20040039405A - 저광택 ａｓａ 수지 - Google Patents
저광택 ａｓａ 수지 Download PDFInfo
- Publication number
- KR20040039405A KR20040039405A KR10-2004-7004262A KR20047004262A KR20040039405A KR 20040039405 A KR20040039405 A KR 20040039405A KR 20047004262 A KR20047004262 A KR 20047004262A KR 20040039405 A KR20040039405 A KR 20040039405A
- Authority
- KR
- South Korea
- Prior art keywords
- thermoplastic molding
- molding composition
- per molecule
- groups per
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 229920005989 resin Polymers 0.000 title description 21
- 239000011347 resin Substances 0.000 title description 21
- 239000000203 mixture Substances 0.000 claims abstract description 58
- 150000001875 compounds Chemical class 0.000 claims abstract description 27
- 238000009757 thermoplastic moulding Methods 0.000 claims abstract description 25
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 20
- 229920001971 elastomer Polymers 0.000 claims abstract description 14
- 125000003277 amino group Chemical group 0.000 claims abstract description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 10
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 10
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 10
- 239000005060 rubber Substances 0.000 claims abstract description 9
- 239000004593 Epoxy Substances 0.000 claims description 33
- -1 ethylene, propylene, styrene Chemical class 0.000 claims description 16
- 125000000524 functional group Chemical group 0.000 claims description 15
- 229920002554 vinyl polymer Polymers 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 10
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 229920000098 polyolefin Polymers 0.000 claims description 6
- 229920001451 polypropylene glycol Polymers 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920001897 terpolymer Polymers 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 3
- 238000009472 formulation Methods 0.000 claims 2
- 239000000155 melt Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000007669 thermal treatment Methods 0.000 abstract 1
- 229920002877 acrylic styrene acrylonitrile Polymers 0.000 description 24
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 13
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 239000011258 core-shell material Substances 0.000 description 5
- 239000000806 elastomer Substances 0.000 description 5
- 229920001169 thermoplastic Polymers 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- 239000004609 Impact Modifier Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 150000003141 primary amines Chemical group 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- ACYXOHNDKRVKLH-UHFFFAOYSA-N 5-phenylpenta-2,4-dienenitrile prop-2-enoic acid Chemical compound OC(=O)C=C.N#CC=CC=CC1=CC=CC=C1 ACYXOHNDKRVKLH-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 229920001893 acrylonitrile styrene Polymers 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- YAAQEISEHDUIFO-UHFFFAOYSA-N C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 Chemical compound C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 YAAQEISEHDUIFO-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- ZPOLOEWJWXZUSP-AATRIKPKSA-N bis(prop-2-enyl) (e)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C\C(=O)OCC=C ZPOLOEWJWXZUSP-AATRIKPKSA-N 0.000 description 1
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Road Signs Or Road Markings (AREA)
- Dental Preparations (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/965,711 US6395828B1 (en) | 2001-09-26 | 2001-09-26 | Low gloss ASA resin |
| US09/965,711 | 2001-09-26 | ||
| PCT/US2002/030655 WO2003027181A2 (en) | 2001-09-26 | 2002-09-23 | Low gloss asa resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20040039405A true KR20040039405A (ko) | 2004-05-10 |
Family
ID=25510373
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR10-2004-7004262A Ceased KR20040039405A (ko) | 2001-09-26 | 2002-09-23 | 저광택 ａｓａ 수지 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6395828B1 (enExample) |
| EP (1) | EP1444296B1 (enExample) |
| JP (1) | JP2005528462A (enExample) |
| KR (1) | KR20040039405A (enExample) |
| CN (1) | CN1294200C (enExample) |
| AT (1) | ATE382070T1 (enExample) |
| AU (1) | AU2002341852A1 (enExample) |
| CA (1) | CA2461234A1 (enExample) |
| DE (1) | DE60224300D1 (enExample) |
| MX (1) | MXPA04002596A (enExample) |
| WO (1) | WO2003027181A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018124517A1 (ko) * | 2017-01-02 | 2018-07-05 | (주) 엘지화학 | 열가소성 수지 조성물, 이의 제조방법 및 이를 포함하여 제조되는 성형품 |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6849687B2 (en) * | 2002-08-01 | 2005-02-01 | Bayer Polymers Llc | Thermoplastic composition having low gloss appearance |
| US6812282B2 (en) * | 2002-09-10 | 2004-11-02 | Bayer Polymers Llc | Thermoplastic compositions providing matt surface |
| US8436095B2 (en) * | 2005-06-23 | 2013-05-07 | Ppg Industries Ohio, Inc. | Powder coating compositions, mid-gloss range coatings, related methods and substrates |
| AU2008295553B2 (en) * | 2007-08-31 | 2012-09-06 | Swimc Llc | Amine functional adducts and curable compositions comprising same |
| KR100998875B1 (ko) * | 2008-10-29 | 2010-12-08 | 제일모직주식회사 | 저광 특성이 우수한 내후성 열가소성 수지 및 그 제조 방법 |
| KR101286503B1 (ko) * | 2009-12-31 | 2013-07-16 | 제일모직주식회사 | 저광 특성이 우수한 내후성 열가소성 수지 조성물 및 그 제조 방법 |
| EP2341090B1 (en) * | 2009-12-31 | 2012-09-12 | Cheil Industries Inc. | Weatherable thermoplastic resin having excellent low gloss characteristic and method of preparing the same |
| KR20120076301A (ko) | 2010-12-29 | 2012-07-09 | 제일모직주식회사 | 내열성과 내후성이 우수한 저광 열가소성 수지 조성물 |
| KR101469263B1 (ko) | 2011-12-22 | 2014-12-05 | 제일모직주식회사 | 열가소성 수지 조성물 및 그 성형품 |
| KR101884972B1 (ko) | 2015-12-04 | 2018-08-02 | 주식회사 엘지화학 | 무광 및 유광이 우수한 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5688460A (en) | 1979-11-26 | 1981-07-17 | Mitsubishi Rayon Co Ltd | Matte thermoplastic resin composition |
| US4894416A (en) | 1988-12-27 | 1990-01-16 | General Electric Company | Low gloss thermoplastic blends |
| ES2078388T3 (es) * | 1991-06-19 | 1995-12-16 | Gen Electric | Mezcla basada en un polimero de un carbonato aromatico con poco brillo. |
| TW222660B (enExample) | 1992-02-25 | 1994-04-21 | Gen Electric | |
| US5262476A (en) * | 1992-03-10 | 1993-11-16 | The Dow Chemical Company | Polycarbonate/polyester blends modified with poly(phenylene ether) |
| ES2175061T3 (es) * | 1995-11-29 | 2002-11-16 | Vantico Ag | Particulas nucleo-cascara (core-shell) y composiciones que contienen estas resinas epoxireticulables. |
| DE19614844A1 (de) * | 1996-04-15 | 1997-10-16 | Basf Ag | Formmassen zur Herstellung von Formteilen mit vermindertem Oberflächenglanz |
| DE19614846A1 (de) * | 1996-04-15 | 1997-10-16 | Basf Ag | Verfahren zur Herstellung von mit Acrylkautschuk modifizierten Formmassen und so erhältliche Formmassen |
-
2001
- 2001-09-26 US US09/965,711 patent/US6395828B1/en not_active Expired - Fee Related
-
2002
- 2002-09-23 CA CA002461234A patent/CA2461234A1/en not_active Abandoned
- 2002-09-23 AT AT02776007T patent/ATE382070T1/de not_active IP Right Cessation
- 2002-09-23 KR KR10-2004-7004262A patent/KR20040039405A/ko not_active Ceased
- 2002-09-23 DE DE60224300T patent/DE60224300D1/de not_active Expired - Lifetime
- 2002-09-23 MX MXPA04002596A patent/MXPA04002596A/es active IP Right Grant
- 2002-09-23 JP JP2003530762A patent/JP2005528462A/ja active Pending
- 2002-09-23 WO PCT/US2002/030655 patent/WO2003027181A2/en not_active Ceased
- 2002-09-23 AU AU2002341852A patent/AU2002341852A1/en not_active Abandoned
- 2002-09-23 EP EP02776007A patent/EP1444296B1/en not_active Expired - Lifetime
- 2002-09-23 CN CNB028190114A patent/CN1294200C/zh not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018124517A1 (ko) * | 2017-01-02 | 2018-07-05 | (주) 엘지화학 | 열가소성 수지 조성물, 이의 제조방법 및 이를 포함하여 제조되는 성형품 |
| KR20180080382A (ko) * | 2017-01-02 | 2018-07-12 | 주식회사 엘지화학 | 열가소성 수지 조성물, 이의 제조방법 및 이를 포함하여 제조되는 성형품 |
| US10647847B2 (en) | 2017-01-02 | 2020-05-12 | Lg Chem, Ltd. | Thermoplastic resin composition, method of preparing the same, and molded part manufactured using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| DE60224300D1 (de) | 2008-02-07 |
| CN1608107A (zh) | 2005-04-20 |
| EP1444296B1 (en) | 2007-12-26 |
| JP2005528462A (ja) | 2005-09-22 |
| MXPA04002596A (es) | 2004-06-18 |
| CA2461234A1 (en) | 2003-04-03 |
| WO2003027181A3 (en) | 2003-05-30 |
| AU2002341852A1 (en) | 2003-04-07 |
| WO2003027181A2 (en) | 2003-04-03 |
| EP1444296A2 (en) | 2004-08-11 |
| ATE382070T1 (de) | 2008-01-15 |
| US6395828B1 (en) | 2002-05-28 |
| CN1294200C (zh) | 2007-01-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
Patent event date: 20040324 Patent event code: PA01051R01D Comment text: International Patent Application |
|
| PG1501 | Laying open of application | ||
| A201 | Request for examination | ||
| PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 20070911 Comment text: Request for Examination of Application |
|
| N231 | Notification of change of applicant | ||
| PN2301 | Change of applicant |
Patent event date: 20080319 Comment text: Notification of Change of Applicant Patent event code: PN23011R01D |
|
| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
Comment text: Notification of reason for refusal Patent event date: 20080529 Patent event code: PE09021S01D |
|
| E601 | Decision to refuse application | ||
| PE0601 | Decision on rejection of patent |
Patent event date: 20080821 Comment text: Decision to Refuse Application Patent event code: PE06012S01D Patent event date: 20080529 Comment text: Notification of reason for refusal Patent event code: PE06011S01I |