CA2461234A1 - Low gloss asa resin - Google Patents
Low gloss asa resin Download PDFInfo
- Publication number
- CA2461234A1 CA2461234A1 CA002461234A CA2461234A CA2461234A1 CA 2461234 A1 CA2461234 A1 CA 2461234A1 CA 002461234 A CA002461234 A CA 002461234A CA 2461234 A CA2461234 A CA 2461234A CA 2461234 A1 CA2461234 A1 CA 2461234A1
- Authority
- CA
- Canada
- Prior art keywords
- thermoplastic molding
- molding composition
- per molecule
- groups per
- functional groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229920005989 resin Polymers 0.000 title description 21
- 239000011347 resin Substances 0.000 title description 21
- 239000000203 mixture Substances 0.000 claims abstract description 57
- 150000001875 compounds Chemical class 0.000 claims abstract description 27
- 238000009757 thermoplastic moulding Methods 0.000 claims abstract description 26
- 229920001971 elastomer Polymers 0.000 claims abstract description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 11
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 11
- 125000003277 amino group Chemical group 0.000 claims abstract description 10
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000004593 Epoxy Substances 0.000 claims description 36
- -1 polyethylene Polymers 0.000 claims description 21
- 125000000524 functional group Chemical group 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- 229920001451 polypropylene glycol Polymers 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920001897 terpolymer Polymers 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 2
- 239000003638 chemical reducing agent Substances 0.000 abstract description 19
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- 229920002877 acrylic styrene acrylonitrile Polymers 0.000 description 24
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 11
- 229920002554 vinyl polymer Polymers 0.000 description 11
- 239000000178 monomer Substances 0.000 description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 8
- 229920001169 thermoplastic Polymers 0.000 description 6
- 239000004416 thermosoftening plastic Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000011258 core-shell material Substances 0.000 description 5
- 239000000806 elastomer Substances 0.000 description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 150000003141 primary amines Chemical group 0.000 description 4
- 150000004985 diamines Chemical class 0.000 description 3
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- ACYXOHNDKRVKLH-UHFFFAOYSA-N 5-phenylpenta-2,4-dienenitrile prop-2-enoic acid Chemical compound OC(=O)C=C.N#CC=CC=CC1=CC=CC=C1 ACYXOHNDKRVKLH-UHFFFAOYSA-N 0.000 description 2
- 239000004609 Impact Modifier Substances 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 229920001893 acrylonitrile styrene Polymers 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229920006163 vinyl copolymer Polymers 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- YAAQEISEHDUIFO-UHFFFAOYSA-N C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 Chemical compound C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 YAAQEISEHDUIFO-UHFFFAOYSA-N 0.000 description 1
- BRDWIEOJOWJCLU-LTGWCKQJSA-N GS-441524 Chemical compound C=1C=C2C(N)=NC=NN2C=1[C@]1(C#N)O[C@H](CO)[C@@H](O)[C@H]1O BRDWIEOJOWJCLU-LTGWCKQJSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229920007019 PC/ABS Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ZPOLOEWJWXZUSP-AATRIKPKSA-N bis(prop-2-enyl) (e)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C\C(=O)OCC=C ZPOLOEWJWXZUSP-AATRIKPKSA-N 0.000 description 1
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000016507 interphase Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Road Signs Or Road Markings (AREA)
- Dental Preparations (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/965,711 | 2001-09-26 | ||
| US09/965,711 US6395828B1 (en) | 2001-09-26 | 2001-09-26 | Low gloss ASA resin |
| PCT/US2002/030655 WO2003027181A2 (en) | 2001-09-26 | 2002-09-23 | Low gloss asa resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2461234A1 true CA2461234A1 (en) | 2003-04-03 |
Family
ID=25510373
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002461234A Abandoned CA2461234A1 (en) | 2001-09-26 | 2002-09-23 | Low gloss asa resin |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6395828B1 (enExample) |
| EP (1) | EP1444296B1 (enExample) |
| JP (1) | JP2005528462A (enExample) |
| KR (1) | KR20040039405A (enExample) |
| CN (1) | CN1294200C (enExample) |
| AT (1) | ATE382070T1 (enExample) |
| AU (1) | AU2002341852A1 (enExample) |
| CA (1) | CA2461234A1 (enExample) |
| DE (1) | DE60224300D1 (enExample) |
| MX (1) | MXPA04002596A (enExample) |
| WO (1) | WO2003027181A2 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6849687B2 (en) * | 2002-08-01 | 2005-02-01 | Bayer Polymers Llc | Thermoplastic composition having low gloss appearance |
| US6812282B2 (en) * | 2002-09-10 | 2004-11-02 | Bayer Polymers Llc | Thermoplastic compositions providing matt surface |
| US8436095B2 (en) * | 2005-06-23 | 2013-05-07 | Ppg Industries Ohio, Inc. | Powder coating compositions, mid-gloss range coatings, related methods and substrates |
| MX342510B (es) * | 2007-08-31 | 2016-10-03 | Sherwin Williams Co | Aductos funcionales de amina y composiciones curables que comprenden la misma. |
| KR100998875B1 (ko) * | 2008-10-29 | 2010-12-08 | 제일모직주식회사 | 저광 특성이 우수한 내후성 열가소성 수지 및 그 제조 방법 |
| EP2341090B1 (en) * | 2009-12-31 | 2012-09-12 | Cheil Industries Inc. | Weatherable thermoplastic resin having excellent low gloss characteristic and method of preparing the same |
| KR101286503B1 (ko) * | 2009-12-31 | 2013-07-16 | 제일모직주식회사 | 저광 특성이 우수한 내후성 열가소성 수지 조성물 및 그 제조 방법 |
| KR20120076301A (ko) | 2010-12-29 | 2012-07-09 | 제일모직주식회사 | 내열성과 내후성이 우수한 저광 열가소성 수지 조성물 |
| KR101469263B1 (ko) | 2011-12-22 | 2014-12-05 | 제일모직주식회사 | 열가소성 수지 조성물 및 그 성형품 |
| KR101884972B1 (ko) * | 2015-12-04 | 2018-08-02 | 주식회사 엘지화학 | 무광 및 유광이 우수한 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
| KR102066598B1 (ko) * | 2017-01-02 | 2020-01-16 | 주식회사 엘지화학 | 열가소성 수지 조성물, 이의 제조방법 및 이를 포함하여 제조되는 성형품 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5688460A (en) | 1979-11-26 | 1981-07-17 | Mitsubishi Rayon Co Ltd | Matte thermoplastic resin composition |
| US4894416A (en) | 1988-12-27 | 1990-01-16 | General Electric Company | Low gloss thermoplastic blends |
| EP0519098B1 (en) * | 1991-06-19 | 1995-09-20 | General Electric Company | Aromatic carbonate polymer based blend with low gloss |
| TW222660B (enExample) | 1992-02-25 | 1994-04-21 | Gen Electric | |
| US5262476A (en) * | 1992-03-10 | 1993-11-16 | The Dow Chemical Company | Polycarbonate/polyester blends modified with poly(phenylene ether) |
| EP0776917B1 (de) * | 1995-11-29 | 2002-05-29 | Vantico AG | Core/Shell-Partikel und diese enthaltende härtbare Epoxidharzzusammensetzungen |
| DE19614844A1 (de) * | 1996-04-15 | 1997-10-16 | Basf Ag | Formmassen zur Herstellung von Formteilen mit vermindertem Oberflächenglanz |
| DE19614846A1 (de) * | 1996-04-15 | 1997-10-16 | Basf Ag | Verfahren zur Herstellung von mit Acrylkautschuk modifizierten Formmassen und so erhältliche Formmassen |
-
2001
- 2001-09-26 US US09/965,711 patent/US6395828B1/en not_active Expired - Fee Related
-
2002
- 2002-09-23 EP EP02776007A patent/EP1444296B1/en not_active Expired - Lifetime
- 2002-09-23 CA CA002461234A patent/CA2461234A1/en not_active Abandoned
- 2002-09-23 DE DE60224300T patent/DE60224300D1/de not_active Expired - Lifetime
- 2002-09-23 AT AT02776007T patent/ATE382070T1/de not_active IP Right Cessation
- 2002-09-23 CN CNB028190114A patent/CN1294200C/zh not_active Expired - Fee Related
- 2002-09-23 AU AU2002341852A patent/AU2002341852A1/en not_active Abandoned
- 2002-09-23 JP JP2003530762A patent/JP2005528462A/ja active Pending
- 2002-09-23 KR KR10-2004-7004262A patent/KR20040039405A/ko not_active Ceased
- 2002-09-23 WO PCT/US2002/030655 patent/WO2003027181A2/en not_active Ceased
- 2002-09-23 MX MXPA04002596A patent/MXPA04002596A/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| EP1444296A2 (en) | 2004-08-11 |
| AU2002341852A1 (en) | 2003-04-07 |
| US6395828B1 (en) | 2002-05-28 |
| JP2005528462A (ja) | 2005-09-22 |
| WO2003027181A3 (en) | 2003-05-30 |
| ATE382070T1 (de) | 2008-01-15 |
| MXPA04002596A (es) | 2004-06-18 |
| EP1444296B1 (en) | 2007-12-26 |
| KR20040039405A (ko) | 2004-05-10 |
| WO2003027181A2 (en) | 2003-04-03 |
| DE60224300D1 (de) | 2008-02-07 |
| CN1294200C (zh) | 2007-01-10 |
| CN1608107A (zh) | 2005-04-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |