KR102403518B1 - 에틸렌계 중합체를 제조하기 위한 고압, 자유 라디칼 중합 - Google Patents

에틸렌계 중합체를 제조하기 위한 고압, 자유 라디칼 중합 Download PDF

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KR102403518B1
KR102403518B1 KR1020197001375A KR20197001375A KR102403518B1 KR 102403518 B1 KR102403518 B1 KR 102403518B1 KR 1020197001375 A KR1020197001375 A KR 1020197001375A KR 20197001375 A KR20197001375 A KR 20197001375A KR 102403518 B1 KR102403518 B1 KR 102403518B1
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ethylene
mwd
polymer
reaction zone
fed
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KR20190021330A (ko
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오토 제이. 벌비
니 티. 와이. 당
조아퀸 플로레스
코넬리스 제이 에프 호스만
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다우 글로벌 테크놀로지스 엘엘씨
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00—Characteristics for processes of polymerization
    • C08F2400/02—Control or adjustment of polymerization parameters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/08—Low density, i.e. < 0.91 g/cm3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18—Bulk density
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR1020197001375A 2016-06-24 2017-06-22 에틸렌계 중합체를 제조하기 위한 고압, 자유 라디칼 중합 Active KR102403518B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16382297.6 2016-06-24
EP16382297.6A EP3260473A1 (en) 2016-06-24 2016-06-24 High pressure, free radical polymerizations to produce ethylene-based polymers
PCT/US2017/038777 WO2017223329A1 (en) 2016-06-24 2017-06-22 High pressure, free radical polymerizations to produce ethylene-based polymers

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KR20190021330A KR20190021330A (ko) 2019-03-05
KR102403518B1 true KR102403518B1 (ko) 2022-06-02

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US (1) US10774159B2 (https=)
EP (2) EP3260473A1 (https=)
JP (2) JP7495207B2 (https=)
KR (1) KR102403518B1 (https=)
CN (1) CN109312008B (https=)
ES (1) ES2842551T3 (https=)
WO (1) WO2017223329A1 (https=)

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WO2021067007A1 (en) * 2019-09-30 2021-04-08 Exxonmobil Chemical Patents Inc. High pressure polyethylene tubular reactor processes for improved wire coating product
EP4396245A1 (en) * 2021-09-01 2024-07-10 ExxonMobil Chemical Patents Inc. Variable temperature tubular reactor profiles and intermediate density polyethylene compositions produced therefrom
WO2024002393A1 (zh) * 2022-07-01 2024-01-04 中国石油化工股份有限公司 烯烃自由基聚合的方法与烯烃自由基聚合装置
EP4375304A1 (en) 2022-11-28 2024-05-29 International Technical Excellence Centers, Llc Process for producing ethylene copolymers at high pressure in a tubular reactor
CN120112569A (zh) 2022-10-26 2025-06-06 国际技术卓越中心股份有限公司 在管式反应器中高压生产乙烯共聚物的工艺
CN121889437A (zh) * 2023-09-29 2026-04-17 陶氏环球技术有限责任公司 用于改善ldpe产品性能和工厂产能的高压自由基管式反应器配置
WO2025181065A1 (en) * 2024-02-29 2025-09-04 Basell Polyolefine Gmbh Film with high weathering resistance

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JP2022064936A (ja) 2022-04-26
US20190177443A1 (en) 2019-06-13
JP7495207B2 (ja) 2024-06-04
US10774159B2 (en) 2020-09-15
WO2017223329A1 (en) 2017-12-28
EP3475316A1 (en) 2019-05-01
EP3260473A1 (en) 2017-12-27
CN109312008A (zh) 2019-02-05
CN109312008B (zh) 2021-04-09
JP2019518842A (ja) 2019-07-04
KR20190021330A (ko) 2019-03-05
EP3475316B1 (en) 2020-11-18
ES2842551T3 (es) 2021-07-14

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