KR102106763B1 - 알칸 및 올레움으로부터 알칸설폰산류를 제조하기 위한 신규 개시제 - Google Patents

알칸 및 올레움으로부터 알칸설폰산류를 제조하기 위한 신규 개시제 Download PDF

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KR102106763B1
KR102106763B1 KR1020167012178A KR20167012178A KR102106763B1 KR 102106763 B1 KR102106763 B1 KR 102106763B1 KR 1020167012178 A KR1020167012178 A KR 1020167012178A KR 20167012178 A KR20167012178 A KR 20167012178A KR 102106763 B1 KR102106763 B1 KR 102106763B1
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reactor
acid
compound according
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alkaline earth
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KR20160086832A (ko
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티모 오트
잉고 비르튐펠
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바스프 에스이
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/63—Esters of sulfonic acids
    • C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
    • C07C309/65—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/42—Peroxy compounds containing sulfur atoms
    • C07C409/44—Peroxy compounds containing sulfur atoms with sulfur atoms directly bound to the —O—O— groups, e.g. persulfonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
    • C07C303/06—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/26—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/42—Separation; Purification; Stabilisation; Use of additives
    • C07C303/44—Separation; Purification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/06—Zinc compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/069—Aluminium compounds without C-aluminium linkages

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020167012178A 2013-11-18 2014-11-17 알칸 및 올레움으로부터 알칸설폰산류를 제조하기 위한 신규 개시제 Active KR102106763B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13193349.1 2013-11-18
EP13193349 2013-11-18
PCT/EP2014/074747 WO2015071455A1 (en) 2013-11-18 2014-11-17 Novel initiator for preparing alkanesulfonic acids from alkane and oleum

Publications (2)

Publication Number Publication Date
KR20160086832A KR20160086832A (ko) 2016-07-20
KR102106763B1 true KR102106763B1 (ko) 2020-05-06

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Country Status (8)

Country Link
US (2) US10329251B2 (https=)
EP (1) EP3071549B1 (https=)
JP (1) JP6412570B2 (https=)
KR (1) KR102106763B1 (https=)
CN (1) CN105705486B (https=)
MY (1) MY179376A (https=)
SG (1) SG11201607264XA (https=)
WO (1) WO2015071455A1 (https=)

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EP3068760B1 (en) 2013-11-13 2023-06-07 Grillo Chemie GmbH Process for preparing alkanesulfonic acids from sulfur trioxide and an alkane
MY179376A (en) 2013-11-18 2020-11-05 Basf Se Novel initiator for preparing alkanesulfonic acids from alkane and oleum
MY191259A (en) * 2016-11-28 2022-06-11 Basf Se Solvent-free alkane sulfonation
US20200115332A1 (en) * 2017-02-07 2020-04-16 Grillo-Werke Ag Method for the production of alkane sulfonic acids
US10899703B2 (en) * 2017-03-10 2021-01-26 Veolia North American Regeneration Services, LLC Radical initiators and chain extenders for converting methane gas into methane-sulfonic acid
US10995063B2 (en) 2017-03-10 2021-05-04 Veolia North America Regeneration Services, Llc Integrated processing system with continuous acid loop for converting methane to methane-sulfonic acid
TW201841881A (zh) * 2017-04-18 2018-12-01 德商巴斯夫歐洲公司 純化烷烴磺酸酐的方法及使用純化的烷烴磺酸酐製造烷烴磺酸的方法
EP3634597B1 (en) * 2017-05-11 2023-01-11 Arkema Inc. Processes and systems for recovering methanesulfonic acid in purified form
CN110678443B (zh) * 2017-05-30 2022-10-25 巴斯夫欧洲公司 制造甲磺酸的方法
TW201904938A (zh) 2017-06-30 2019-02-01 德商葛里洛沃克股份有限公司 用於生產烷磺酸的調節劑
MY201566A (en) * 2018-02-07 2024-02-29 Basf Se Process for the manufacturing of alkanesulfonic acids
FR3077817B1 (fr) * 2018-02-14 2020-02-28 Arkema France Procede de synthese industrielle en continu d'acide alcane-sulfonique
TWI714964B (zh) 2018-02-16 2021-01-01 巴斯夫歐洲公司 用於烷磺酸之合成的催化劑
EP4159714A1 (en) * 2018-03-10 2023-04-05 Veolia North America Regeneration Services, LLC Compounds, processes, and machinery for converting methane gas into methane sulfonic acid
EP3802485A1 (en) * 2018-05-25 2021-04-14 Grillo-Werke AG Process for the preparation of haloalkanesulfonic acids from sulfur trioxide and a haloalkane
WO2020048965A1 (en) * 2018-09-04 2020-03-12 Basf Se Method for the production of alkane sulfonic acids
WO2020064466A1 (en) 2018-09-25 2020-04-02 Basf Se Catalyst for the synthesis of alkanesulfonic acids
SG11202102866QA (en) 2018-09-25 2021-04-29 Basf Se Cations as catalyst in the production of alkane sulfonic acids
WO2020064573A1 (en) 2018-09-25 2020-04-02 Basf Se Catalysts for the synthesis of alkanesulfonic acids
WO2020126855A1 (en) 2018-12-21 2020-06-25 Basf Se Mixture comprising methanesulfonic acid and sulfuric acid
MY204480A (en) 2019-03-21 2024-08-30 Basf Se Method for the purification of alkanes
SG11202110959WA (en) 2019-04-18 2021-11-29 Basf Se Process for the production of anhydrous methanesulfonic acid from methane and so3
EP3763701A1 (en) 2019-07-10 2021-01-13 Grillo-Werke AG Improved process for the purification of methane sulfonic acid
ES2966787T3 (es) 2019-07-10 2024-04-24 Basf Se Procedimiento para reducir la concentración de SO3 en una mezcla de reacción que comprende ácido metano sulfónico y SO3
KR102943995B1 (ko) 2019-08-07 2026-03-25 바스프 에스이 알칸술폰산의 제조 방법
WO2021023582A1 (en) 2019-08-07 2021-02-11 Basf Se Recovery of water-free methanesulfonic acid from the bottom stream of a distillation column
EP3782981A1 (en) 2019-08-20 2021-02-24 Basf Se Catalysts for the synthesis of alkanesulfonic acids
KR102886810B1 (ko) * 2019-10-01 2025-11-14 바스프 에스이 알칸설폰산의 제조 공정
CN114423737B (zh) 2019-10-02 2024-11-19 巴斯夫欧洲公司 制备链烷磺酸的方法
CN111302978A (zh) * 2020-04-17 2020-06-19 凯瑞环保科技股份有限公司 一种烷基磺酸的合成装置及合成方法
WO2022046543A1 (en) * 2020-08-24 2022-03-03 University Of Kansas Alkane multi-sulfonic acids, compositions thereof, and related methods

Citations (3)

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US5304360A (en) 1990-10-27 1994-04-19 Interox Chemicals Limited Peroxoacid manufacture
US20050070614A1 (en) 2003-06-21 2005-03-31 Richards Alan K. Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds
WO2007136425A2 (en) 2006-05-19 2007-11-29 Richards, Alan, K. Manufacture of dimethyl ether or olefins from methane, using di(methyl-sulfonyl) peroxide as radical initiator

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US2493038A (en) * 1946-05-31 1950-01-03 Houdry Process Corp Reaction of methane with sulfur trioxide
US2619507A (en) 1951-01-05 1952-11-25 Dow Chemical Co Di(methanesulfonyl) peroxide and its preparation
US4680095A (en) 1986-11-03 1987-07-14 Pennwalt Corporation Continuous preparation of dialkanesulfonyl peroxide
FR2610320A1 (fr) 1987-02-03 1988-08-05 Atochem Composes peroxydes renfermant l'isotope 17o
US4910335A (en) 1989-08-01 1990-03-20 Pennwalt Corporation Decolorization of alkanesulfonic and arenesulfonic acids
WO2004041399A2 (en) 2002-11-05 2004-05-21 Richards Alan K Anhydrous conversion of methane and other light alkanes into methanol and other derivatives, using radical pathways and chain reactions with minimal waste products
CN1318361C (zh) 2002-11-05 2007-05-30 艾伦·K·理查兹 使用自由基路线和链反应,在最小废物的情况下,使甲烷和其它轻质烷烃无水转化成甲醇和其它衍生物
US20080161591A1 (en) * 2003-06-21 2008-07-03 Richards Alan K Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds
US7119226B2 (en) 2004-04-20 2006-10-10 The Penn State Research Foundation Process for the conversion of methane
JP5068813B2 (ja) 2006-05-24 2012-11-07 ライブニッツ インスティトゥート フォー ナチュラル プロダクト リサーチ アンド インフェクション バイオロジー エー．ファウ． ハンス−クネル−インスティトゥート（ハーカーイー） 新規なベンゾチアジノン誘導体、及び抗菌剤としてのその使用
WO2015071351A1 (en) 2013-11-13 2015-05-21 Grillo Chemie Gmbh Process for preparing bis(alkanesulfonyl peroxide)
WO2015071371A1 (en) 2013-11-13 2015-05-21 Grillo Chemie Gmbh Process for preparing bis(alkanesulfonyl) peroxide by oxidation
EP3068760B1 (en) 2013-11-13 2023-06-07 Grillo Chemie GmbH Process for preparing alkanesulfonic acids from sulfur trioxide and an alkane
MY179376A (en) 2013-11-18 2020-11-05 Basf Se Novel initiator for preparing alkanesulfonic acids from alkane and oleum

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5304360A (en) 1990-10-27 1994-04-19 Interox Chemicals Limited Peroxoacid manufacture
US20050070614A1 (en) 2003-06-21 2005-03-31 Richards Alan K. Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds
WO2007136425A2 (en) 2006-05-19 2007-11-29 Richards, Alan, K. Manufacture of dimethyl ether or olefins from methane, using di(methyl-sulfonyl) peroxide as radical initiator

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US10329251B2 (en) 2019-06-25
US20160289181A1 (en) 2016-10-06
US11180448B2 (en) 2021-11-23
JP6412570B2 (ja) 2018-10-24
EP3071549B1 (en) 2017-10-18
WO2015071455A1 (en) 2015-05-21
JP2016540743A (ja) 2016-12-28
CN105705486A (zh) 2016-06-22
EP3071549A1 (en) 2016-09-28
SG11201607264XA (en) 2016-10-28
US20190256461A1 (en) 2019-08-22
CN105705486B (zh) 2019-03-01
KR20160086832A (ko) 2016-07-20
MY179376A (en) 2020-11-05

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