KR102096979B1 - 경질 폴리우레탄 발포체의 제조 - Google Patents
경질 폴리우레탄 발포체의 제조 Download PDFInfo
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- KR102096979B1 KR102096979B1 KR1020147034736A KR20147034736A KR102096979B1 KR 102096979 B1 KR102096979 B1 KR 102096979B1 KR 1020147034736 A KR1020147034736 A KR 1020147034736A KR 20147034736 A KR20147034736 A KR 20147034736A KR 102096979 B1 KR102096979 B1 KR 102096979B1
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- flame retardant
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 36
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- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 17
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- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 16
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- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 14
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 14
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- 125000001931 aliphatic group Chemical group 0.000 claims description 12
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 12
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 claims description 12
- 239000000047 product Substances 0.000 claims description 11
- GTRSAMFYSUBAGN-UHFFFAOYSA-N tris(2-chloropropyl) phosphate Chemical compound CC(Cl)COP(=O)(OCC(C)Cl)OCC(C)Cl GTRSAMFYSUBAGN-UHFFFAOYSA-N 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 8
- 150000002009 diols Chemical class 0.000 claims description 7
- YWWVWXASSLXJHU-AATRIKPKSA-N (9E)-tetradecenoic acid Chemical compound CCCC\C=C\CCCCCCCC(O)=O YWWVWXASSLXJHU-AATRIKPKSA-N 0.000 claims description 6
- DTOSIQBPPRVQHS-PDBXOOCHSA-N (Z,Z,Z)-Octadeca-9,12,15-trienoic acid Natural products CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 claims description 6
- AATNZNJRDOVKDD-UHFFFAOYSA-N 1-[ethoxy(ethyl)phosphoryl]oxyethane Chemical compound CCOP(=O)(CC)OCC AATNZNJRDOVKDD-UHFFFAOYSA-N 0.000 claims description 6
- YWDFOLFVOVCBIU-UHFFFAOYSA-N 1-dimethoxyphosphorylpropane Chemical compound CCCP(=O)(OC)OC YWDFOLFVOVCBIU-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 claims description 6
- XMNDMAQKWSQVOV-UHFFFAOYSA-N (2-methylphenyl) diphenyl phosphate Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 XMNDMAQKWSQVOV-UHFFFAOYSA-N 0.000 claims description 5
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 claims description 5
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 5
- 239000004359 castor oil Substances 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 5
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- 229960003656 ricinoleic acid Drugs 0.000 claims description 5
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000003549 soybean oil Substances 0.000 claims description 5
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- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 4
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- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
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- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 claims description 3
- OPGOLNDOMSBSCW-CLNHMMGSSA-N Fursultiamine hydrochloride Chemical compound Cl.C1CCOC1CSSC(\CCO)=C(/C)N(C=O)CC1=CN=C(C)N=C1N OPGOLNDOMSBSCW-CLNHMMGSSA-N 0.000 claims description 3
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0038—Use of organic additives containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/18—Binary blends of expanding agents
- C08J2203/184—Binary blends of expanding agents of chemical foaming agent and physical blowing agent, e.g. azodicarbonamide and fluorocarbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
- C08K5/5333—Esters of phosphonic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (3)
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| EP12169980 | 2012-05-30 | ||
| EP12169980.5 | 2012-05-30 | ||
| PCT/EP2013/061022 WO2013178657A1 (de) | 2012-05-30 | 2013-05-29 | Verfahren zur herstellung von polyurethan-hartschaumstoffen |
Publications (2)
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| KR20150023372A KR20150023372A (ko) | 2015-03-05 |
| KR102096979B1 true KR102096979B1 (ko) | 2020-04-03 |
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| KR1020147034736A Active KR102096979B1 (ko) | 2012-05-30 | 2013-05-29 | 경질 폴리우레탄 발포체의 제조 |
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| SI (1) | SI2855551T1 (enExample) |
| WO (1) | WO2013178657A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US9757885B2 (en) | 2012-09-28 | 2017-09-12 | Basf Se | Process for producing composite profiles |
| US9475220B2 (en) | 2013-02-13 | 2016-10-25 | Basf Se | Process for producing composite elements |
| CN104191768A (zh) * | 2014-08-26 | 2014-12-10 | 上海爱逸建筑科技有限公司 | 一种硬质聚氨酯与聚苯乙烯泡沫塑料复合型吸能材料 |
| CN105859998B (zh) * | 2015-01-22 | 2018-07-10 | 万华化学（宁波）容威聚氨酯有限公司 | 用于聚氨酯发泡的组合物，聚氨酯泡沫及其用途 |
| CN104829810B (zh) * | 2015-04-28 | 2018-02-06 | 绍兴市长丰聚氨酯有限公司 | 一种低气味聚氨酯泡沫制品及其制备方法 |
| CN106560480A (zh) * | 2016-08-03 | 2017-04-12 | 广州艾科新材料股份有限公司 | 一种高流动性可降解聚氨酯鞋材的配方及制备方法 |
| CN110271245B (zh) * | 2019-06-26 | 2021-06-08 | 山东宏鑫源钢板有限公司 | 聚氨酯彩钢板及其制备方法 |
| CN110218293B (zh) * | 2019-06-26 | 2021-07-23 | 山东宏鑫源钢板有限公司 | 铝镁锰聚氨酯屋面板及其制备工艺 |
| JP7511460B2 (ja) * | 2020-12-16 | 2024-07-05 | 株式会社イノアックコーポレーション | ポリウレタンフォーム |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005307144A (ja) * | 2003-06-30 | 2005-11-04 | Bridgestone Corp | 硬質ポリウレタンフォーム |
| JP2009138134A (ja) | 2007-12-07 | 2009-06-25 | Bridgestone Corp | ポリウレタンフォーム |
| WO2011131682A1 (de) | 2010-04-23 | 2011-10-27 | Basf Se | Verfahren zur herstellung von polyurethan-hartschaumstoffen |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| RU2184127C2 (ru) * | 1996-11-04 | 2002-06-27 | Хантсмэн Интернэшнл Ллс | Жесткие полиуретановые пенопласты |
| AU3827999A (en) | 1998-05-21 | 1999-12-13 | Huntsman Ici Chemicals Llc | Hydrocarbon blown rigid polyurethane foams having improved flammability performance |
| EP1435366B1 (en) | 2003-01-03 | 2008-08-13 | Dow Global Technologies Inc. | Polyisocyanurate foam and process for its preparation |
| JP2005307143A (ja) * | 2003-06-30 | 2005-11-04 | Bridgestone Corp | 硬質ポリウレタンフォーム |
| JP2005307147A (ja) * | 2003-06-30 | 2005-11-04 | Bridgestone Corp | 吹付け断熱材 |
| DE102004044915A1 (de) * | 2004-09-14 | 2006-03-16 | Basf Ag | Polyurethanhartschaumstoffe |
| DE102005041763A1 (de) * | 2005-09-01 | 2007-03-08 | Basf Ag | Polyisocyanurat Hartschaum und Verfahren zur Herstellung |
| JP5451380B2 (ja) * | 2006-05-15 | 2014-03-26 | ブロマイン コンパウンズ リミテッド | 難燃剤組成物 |
| IL175638A0 (en) * | 2006-05-15 | 2007-08-19 | Bromine Compounds Ltd | Flame retardant composition |
| ITMI20081480A1 (it) | 2008-08-06 | 2010-02-06 | Dow Global Technologies Inc | Poliesteri aromatici, miscele palioliche che li comprendono e prodotti risultanti |
| SI2340269T1 (sl) * | 2008-10-15 | 2013-01-31 | Basf Se | Poliesterski polioli na bazi terefthalične kisline |
| EP2184305A1 (de) * | 2008-11-07 | 2010-05-12 | Bayer MaterialScience AG | PIR-Hartschaumstoffe, ein Verfahren zu deren Herstellung und deren Verwendung |
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2013
- 2013-05-29 HU HUE13725672A patent/HUE029630T2/en unknown
- 2013-05-29 BR BR112014029720A patent/BR112014029720A2/pt not_active IP Right Cessation
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- 2013-05-29 WO PCT/EP2013/061022 patent/WO2013178657A1/de not_active Ceased
- 2013-05-29 HR HRP20160571TT patent/HRP20160571T1/hr unknown
- 2013-05-29 EP EP13725672.3A patent/EP2855551B1/de active Active
- 2013-05-29 SI SI201330183A patent/SI2855551T1/sl unknown
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- 2013-05-29 RU RU2014153666A patent/RU2638924C2/ru active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005307144A (ja) * | 2003-06-30 | 2005-11-04 | Bridgestone Corp | 硬質ポリウレタンフォーム |
| JP2009138134A (ja) | 2007-12-07 | 2009-06-25 | Bridgestone Corp | ポリウレタンフォーム |
| WO2011131682A1 (de) | 2010-04-23 | 2011-10-27 | Basf Se | Verfahren zur herstellung von polyurethan-hartschaumstoffen |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013178657A1 (de) | 2013-12-05 |
| EP2855551B1 (de) | 2016-03-09 |
| EP2855551A1 (de) | 2015-04-08 |
| CA2875176A1 (en) | 2013-12-05 |
| JP6324949B2 (ja) | 2018-05-16 |
| ES2573817T3 (es) | 2016-06-10 |
| KR20150023372A (ko) | 2015-03-05 |
| AU2013269724B2 (en) | 2016-06-02 |
| CN104507993B (zh) | 2016-09-21 |
| MX357983B (es) | 2018-08-01 |
| CA2875176C (en) | 2020-02-18 |
| PL2855551T3 (pl) | 2016-09-30 |
| DK2855551T3 (en) | 2016-06-06 |
| CN104507993A (zh) | 2015-04-08 |
| HRP20160571T1 (hr) | 2016-06-17 |
| SI2855551T1 (sl) | 2016-10-28 |
| AU2013269724A1 (en) | 2014-12-18 |
| JP2015519449A (ja) | 2015-07-09 |
| RU2638924C2 (ru) | 2017-12-19 |
| HUE029630T2 (en) | 2017-03-28 |
| RU2014153666A (ru) | 2016-07-20 |
| MX2014014616A (es) | 2015-08-06 |
| RS54818B1 (sr) | 2016-10-31 |
| AU2013269724C1 (en) | 2016-09-29 |
| BR112014029720A2 (pt) | 2017-07-25 |
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