KR101929059B1 - 단열 질화에 의한 니트로벤젠의 생성 방법 - Google Patents

단열 질화에 의한 니트로벤젠의 생성 방법 Download PDF

Info

Publication number
KR101929059B1
KR101929059B1 KR1020137002064A KR20137002064A KR101929059B1 KR 101929059 B1 KR101929059 B1 KR 101929059B1 KR 1020137002064 A KR1020137002064 A KR 1020137002064A KR 20137002064 A KR20137002064 A KR 20137002064A KR 101929059 B1 KR101929059 B1 KR 101929059B1
Authority
KR
South Korea
Prior art keywords
nitrobenzene
benzene
purified
water
distillation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020137002064A
Other languages
English (en)
Korean (ko)
Other versions
KR20130129893A (ko
Inventor
토마스 크나우프
알렉산드르 라코에스
안드레아스 칼 라우쉬
디트리히 울프
Original Assignee
바이엘 인텔렉쳐 프로퍼티 게엠베하
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 바이엘 인텔렉쳐 프로퍼티 게엠베하 filed Critical 바이엘 인텔렉쳐 프로퍼티 게엠베하
Publication of KR20130129893A publication Critical patent/KR20130129893A/ko
Application granted granted Critical
Publication of KR101929059B1 publication Critical patent/KR101929059B1/ko
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/08—Preparation of nitro compounds by substitution of hydrogen atoms by nitro groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/16—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/06—Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/325—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups reduction by other means than indicated in C07C209/34 or C07C209/36
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/45—Monoamines
    • C07C211/46—Aniline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020137002064A 2010-07-28 2011-07-26 단열 질화에 의한 니트로벤젠의 생성 방법 Expired - Fee Related KR101929059B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102010038519A DE102010038519A1 (de) 2010-07-28 2010-07-28 Verfahren zur Herstellung von Nitrobenzol durch adiabate Nitrierung
DE102010038519.0 2010-07-28
PCT/EP2011/062827 WO2012013672A2 (de) 2010-07-28 2011-07-26 Verfahren zur herstellung von nitrobenzol durch adiabate nitrierung

Publications (2)

Publication Number Publication Date
KR20130129893A KR20130129893A (ko) 2013-11-29
KR101929059B1 true KR101929059B1 (ko) 2018-12-13

Family

ID=44630370

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020137002064A Expired - Fee Related KR101929059B1 (ko) 2010-07-28 2011-07-26 단열 질화에 의한 니트로벤젠의 생성 방법

Country Status (8)

Country Link
US (1) US8729309B2 (enExample)
EP (1) EP2598473B1 (enExample)
JP (1) JP5886284B2 (enExample)
KR (1) KR101929059B1 (enExample)
CN (1) CN103140464B (enExample)
DE (1) DE102010038519A1 (enExample)
PT (1) PT2598473T (enExample)
WO (1) WO2012013672A2 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104066709B (zh) * 2012-01-31 2016-08-24 科思创德国股份有限公司 用于生产硝基苯的方法和设备
CN102675118A (zh) * 2012-04-25 2012-09-19 中国石油化工股份有限公司 一种硝基苯洗涤、分离方法
WO2014177450A1 (de) * 2013-04-29 2014-11-06 Bayer Materialscience Ag Verfahren zur herstellung von nitrobenzol durch adiabate nitrierung
US9346012B2 (en) * 2014-06-10 2016-05-24 Covestro Llc Method and apparatus for denenoxing waste gases from nitration
CN106316858B (zh) * 2016-08-24 2018-08-31 康乃尔化学工业股份有限公司 一种稀硝酸加热工艺及其装置
CN115193366B (zh) * 2021-04-09 2024-04-09 万华化学集团股份有限公司 一种硝化反应装置及利用该反应装置进行硝化反应的方法
CN115745804B (zh) * 2021-09-03 2024-04-09 万华化学（宁波）有限公司 一种降低粗硝基苯中二硝基苯含量的方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2256999A (en) 1939-03-08 1941-09-23 Du Pont Nitration of organic compounds
US3928475A (en) 1974-08-09 1975-12-23 Du Pont Azeotropic nitration of benzene
US3981935A (en) 1975-12-10 1976-09-21 E. I. Du Pont De Nemours And Company Azeotropic nitration of benzene
US4091042A (en) 1977-08-19 1978-05-23 American Cyanamid Company Continuous adiabatic process for the mononitration of benzene
US4740621A (en) 1985-11-01 1988-04-26 First Chemical Corporation Co-production of an aromatic monoamine and an aromatic diamine directly from benzene or a benzene derivative through controlled nitration
US5313009A (en) 1990-01-04 1994-05-17 Nrm International Technologies C.V. Nitration process
DE4428017A1 (de) 1994-08-08 1996-02-15 Bayer Ag Verfahren zur Herstellung von aromatischen Aminen
DE4428459A1 (de) * 1994-08-11 1996-02-15 Bayer Ag Verfahren zur Herstellung von Dinitrotoluol
DE4428460A1 (de) * 1994-08-11 1996-02-15 Bayer Ag Verfahren zur Herstellung von Nitroaromaten
DE19539205A1 (de) 1995-10-22 1997-04-24 Meissner Gmbh & Co Kg Josef Verfahren zur Aromatennitrierung
US6079227A (en) 1997-06-05 2000-06-27 Nippon Sheet Glass Co., Ltd. Method for manufacturing bent and tempered glass sheet and apparatus for manufacturing the same
DE19953722A1 (de) * 1999-11-09 2001-05-10 Bayer Ag Verfahren zur adiabatischen Herstellung von 3,4-Dichlornitrobenzol
DE102004017628A1 (de) * 2004-04-10 2005-11-03 Bayer Materialscience Ag Verfahren zur Aufarbeitung von aromatische Nitroverbindungen enthaltenden Abwässern
DE102006004943A1 (de) * 2006-02-03 2007-08-09 Bayer Materialscience Ag Verfahren zur Herstellung von Nitrobenzol
DE102006035203A1 (de) 2006-07-29 2008-01-31 Bayer Materialscience Ag Verfahren zur Herstellung von aromatischen Aminen
DE102007059513A1 (de) * 2007-12-11 2009-06-18 Bayer Materialscience Ag Verfahren zur Herstellung von Nitrobenzol durch adiabate Nitrierung
CN101613285B (zh) * 2008-06-25 2012-12-05 中国科学院大连化学物理研究所 一种硝基苯合成方法及专用装备
DE102008048713A1 (de) 2008-09-24 2010-03-25 Bayer Materialscience Ag Verfahren zur kontinuierlichen Herstellung von Nitrobenzol
DE102009005324B4 (de) 2009-01-16 2014-04-03 Plinke Gmbh Verfahren zur adiabatischen Nitrierung von Benzol

Also Published As

Publication number Publication date
EP2598473A2 (de) 2013-06-05
WO2012013672A2 (de) 2012-02-02
PT2598473T (pt) 2017-02-16
CN103140464B (zh) 2014-12-03
JP2013535459A (ja) 2013-09-12
KR20130129893A (ko) 2013-11-29
WO2012013672A3 (de) 2012-04-26
EP2598473B1 (de) 2016-11-16
DE102010038519A1 (de) 2012-02-02
CN103140464A (zh) 2013-06-05
JP5886284B2 (ja) 2016-03-16
US8729309B2 (en) 2014-05-20
US20130197268A1 (en) 2013-08-01

Similar Documents

Publication Publication Date Title
KR101929059B1 (ko) 단열 질화에 의한 니트로벤젠의 생성 방법
JP7062686B2 (ja) 精製された形態でメタンスルホン酸を回収するための方法及びシステム
US7988942B2 (en) Method and system for concentrating waste sulphuric acids from nitration processes
KR20080106079A (ko) 알칼리 금속 알콕사이드의 제조 방법
US9284255B2 (en) Method for producing nitrobenzene by adiabatic nitriding
KR20150036532A (ko) 단열 니트로화에 의한 니트로벤젠의 제조방법
CN104487414B (zh) 通过绝热硝化制备硝基苯的方法
TW201119983A (en) Process and apparatus for preparing alkylene oxides and alkylene glycols
CN105263865B (zh) 后处理来自硝基苯制备的废水的方法
EP2521710B1 (en) A urea stripping process for the production of urea
CN103724205B (zh) 连续生产硝基苯的方法
CN105246833B (zh) 后处理来自硝基苯制备的废水的方法
CA3148004A1 (en) Recovery of water-free methanesulfonic acid from the bottom stream of a distillation column
CN113710650A (zh) 由甲烷和so3生产无水甲磺酸的方法
JP6062527B2 (ja) 気相水素化からのアニリンの精製方法
RU2404952C1 (ru) Способ получения метилхлорида
US9133094B2 (en) Apparatus and process for nitration selectivity flexibility enabled by azeotropic distillation
KR102597388B1 (ko) 니트로벤젠의 제조 방법

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

R15-X000 Change to inventor requested

St.27 status event code: A-3-3-R10-R15-oth-X000

R16-X000 Change to inventor recorded

St.27 status event code: A-3-3-R10-R16-oth-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20211208

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20211208