DE102010038519A1 - Verfahren zur Herstellung von Nitrobenzol durch adiabate Nitrierung - Google Patents

Verfahren zur Herstellung von Nitrobenzol durch adiabate Nitrierung Download PDF

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Publication number
DE102010038519A1
DE102010038519A1 DE102010038519A DE102010038519A DE102010038519A1 DE 102010038519 A1 DE102010038519 A1 DE 102010038519A1 DE 102010038519 A DE102010038519 A DE 102010038519A DE 102010038519 A DE102010038519 A DE 102010038519A DE 102010038519 A1 DE102010038519 A1 DE 102010038519A1
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Germany
Prior art keywords
nitrobenzene
benzene
mass
separation
water
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DE102010038519A
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German (de)
English (en)
Inventor
Dr. Knauf Thomas
Alexandre Racoes
Dr. Rausch Andreas Karl
Dr. Wulf Dietrich
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Covestro Deutschland AG
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Bayer MaterialScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer MaterialScience AG filed Critical Bayer MaterialScience AG
Priority to DE102010038519A priority Critical patent/DE102010038519A1/de
Priority to JP2013521112A priority patent/JP5886284B2/ja
Priority to EP11743990.1A priority patent/EP2598473B1/de
Priority to PT117439901T priority patent/PT2598473T/pt
Priority to CN201180036942.XA priority patent/CN103140464B/zh
Priority to US13/812,653 priority patent/US8729309B2/en
Priority to KR1020137002064A priority patent/KR101929059B1/ko
Priority to PCT/EP2011/062827 priority patent/WO2012013672A2/de
Publication of DE102010038519A1 publication Critical patent/DE102010038519A1/de
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/08—Preparation of nitro compounds by substitution of hydrogen atoms by nitro groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/16—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/06—Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/325—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups reduction by other means than indicated in C07C209/34 or C07C209/36
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/45—Monoamines
    • C07C211/46—Aniline

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE102010038519A 2010-07-28 2010-07-28 Verfahren zur Herstellung von Nitrobenzol durch adiabate Nitrierung Withdrawn DE102010038519A1 (de)

Priority Applications (8)

Application Number Priority Date Filing Date Title
DE102010038519A DE102010038519A1 (de) 2010-07-28 2010-07-28 Verfahren zur Herstellung von Nitrobenzol durch adiabate Nitrierung
JP2013521112A JP5886284B2 (ja) 2010-07-28 2011-07-26 断熱ニトロ化によるニトロベンゼンの製造方法
EP11743990.1A EP2598473B1 (de) 2010-07-28 2011-07-26 Verfahren zur herstellung von nitrobenzol durch adiabate nitrierung
PT117439901T PT2598473T (pt) 2010-07-28 2011-07-26 Processo para a produção de nitrobenzeno através de nitração adiabática
CN201180036942.XA CN103140464B (zh) 2010-07-28 2011-07-26 通过绝热硝化生产硝基苯的方法
US13/812,653 US8729309B2 (en) 2010-07-28 2011-07-26 Method for producing nitrobenzene by adiabatic nitriding
KR1020137002064A KR101929059B1 (ko) 2010-07-28 2011-07-26 단열 질화에 의한 니트로벤젠의 생성 방법
PCT/EP2011/062827 WO2012013672A2 (de) 2010-07-28 2011-07-26 Verfahren zur herstellung von nitrobenzol durch adiabate nitrierung

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102010038519A DE102010038519A1 (de) 2010-07-28 2010-07-28 Verfahren zur Herstellung von Nitrobenzol durch adiabate Nitrierung

Publications (1)

Publication Number Publication Date
DE102010038519A1 true DE102010038519A1 (de) 2012-02-02

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Family Applications (1)

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DE102010038519A Withdrawn DE102010038519A1 (de) 2010-07-28 2010-07-28 Verfahren zur Herstellung von Nitrobenzol durch adiabate Nitrierung

Country Status (8)

Country Link
US (1) US8729309B2 (enExample)
EP (1) EP2598473B1 (enExample)
JP (1) JP5886284B2 (enExample)
KR (1) KR101929059B1 (enExample)
CN (1) CN103140464B (enExample)
DE (1) DE102010038519A1 (enExample)
PT (1) PT2598473T (enExample)
WO (1) WO2012013672A2 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115745804A (zh) * 2021-09-03 2023-03-07 万华化学（宁波）有限公司 一种降低粗硝基苯中二硝基苯含量的方法

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PT2809644T (pt) * 2012-01-31 2016-12-29 Covestro Deutschland Ag Método e instalação para o fabrico de nitrobenzeno
CN102675118A (zh) * 2012-04-25 2012-09-19 中国石油化工股份有限公司 一种硝基苯洗涤、分离方法
KR20160003084A (ko) * 2013-04-29 2016-01-08 코베스트로 도이칠란트 아게 단열 니트로화에 의한 니트로벤젠의 제조 방법
US9346012B2 (en) * 2014-06-10 2016-05-24 Covestro Llc Method and apparatus for denenoxing waste gases from nitration
CN106316858B (zh) * 2016-08-24 2018-08-31 康乃尔化学工业股份有限公司 一种稀硝酸加热工艺及其装置
CN115193366B (zh) * 2021-04-09 2024-04-09 万华化学集团股份有限公司 一种硝化反应装置及利用该反应装置进行硝化反应的方法

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2256999A (en) 1939-03-08 1941-09-23 Du Pont Nitration of organic compounds
US3928475A (en) 1974-08-09 1975-12-23 Du Pont Azeotropic nitration of benzene
US3981935A (en) 1975-12-10 1976-09-21 E. I. Du Pont De Nemours And Company Azeotropic nitration of benzene
US4091042A (en) 1977-08-19 1978-05-23 American Cyanamid Company Continuous adiabatic process for the mononitration of benzene
US5313009A (en) 1990-01-04 1994-05-17 Nrm International Technologies C.V. Nitration process
US5763697A (en) 1995-10-22 1998-06-09 Josef Meissner Gmbh & Co. Process for the nitration of aromatic compounds
EP0882681A1 (en) 1997-06-05 1998-12-09 Nippon Sheet Glass Co., Ltd. Method for manufacturing bent and tempered glass sheets and apparatus for manufacturing the same
EP0696573B1 (de) 1994-08-08 1999-03-31 Bayer Ag Verfahren zur Herstellung von aromatischen Aminen
EP1816117A1 (de) 2006-02-03 2007-08-08 Bayer MaterialScience AG Verfahren zur Herstellung von Nitrobenzol
EP2070907A1 (de) 2007-12-11 2009-06-17 Bayer MaterialScience AG Verfahren zur Herstellung von Nitrobenzol durch adiabate Nitrierung
DE102008048713A1 (de) 2008-09-24 2010-03-25 Bayer Materialscience Ag Verfahren zur kontinuierlichen Herstellung von Nitrobenzol

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4740621A (en) 1985-11-01 1988-04-26 First Chemical Corporation Co-production of an aromatic monoamine and an aromatic diamine directly from benzene or a benzene derivative through controlled nitration
DE4428459A1 (de) * 1994-08-11 1996-02-15 Bayer Ag Verfahren zur Herstellung von Dinitrotoluol
DE4428460A1 (de) * 1994-08-11 1996-02-15 Bayer Ag Verfahren zur Herstellung von Nitroaromaten
DE19953722A1 (de) * 1999-11-09 2001-05-10 Bayer Ag Verfahren zur adiabatischen Herstellung von 3,4-Dichlornitrobenzol
DE102004017628A1 (de) * 2004-04-10 2005-11-03 Bayer Materialscience Ag Verfahren zur Aufarbeitung von aromatische Nitroverbindungen enthaltenden Abwässern
DE102006035203A1 (de) 2006-07-29 2008-01-31 Bayer Materialscience Ag Verfahren zur Herstellung von aromatischen Aminen
CN101613285B (zh) * 2008-06-25 2012-12-05 中国科学院大连化学物理研究所 一种硝基苯合成方法及专用装备
DE102009005324B4 (de) 2009-01-16 2014-04-03 Plinke Gmbh Verfahren zur adiabatischen Nitrierung von Benzol

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2256999A (en) 1939-03-08 1941-09-23 Du Pont Nitration of organic compounds
US3928475A (en) 1974-08-09 1975-12-23 Du Pont Azeotropic nitration of benzene
US3981935A (en) 1975-12-10 1976-09-21 E. I. Du Pont De Nemours And Company Azeotropic nitration of benzene
US4091042A (en) 1977-08-19 1978-05-23 American Cyanamid Company Continuous adiabatic process for the mononitration of benzene
US5313009A (en) 1990-01-04 1994-05-17 Nrm International Technologies C.V. Nitration process
EP0696573B1 (de) 1994-08-08 1999-03-31 Bayer Ag Verfahren zur Herstellung von aromatischen Aminen
US5763697A (en) 1995-10-22 1998-06-09 Josef Meissner Gmbh & Co. Process for the nitration of aromatic compounds
EP0882681A1 (en) 1997-06-05 1998-12-09 Nippon Sheet Glass Co., Ltd. Method for manufacturing bent and tempered glass sheets and apparatus for manufacturing the same
EP1816117A1 (de) 2006-02-03 2007-08-08 Bayer MaterialScience AG Verfahren zur Herstellung von Nitrobenzol
EP2070907A1 (de) 2007-12-11 2009-06-17 Bayer MaterialScience AG Verfahren zur Herstellung von Nitrobenzol durch adiabate Nitrierung
DE102008048713A1 (de) 2008-09-24 2010-03-25 Bayer Materialscience Ag Verfahren zur kontinuierlichen Herstellung von Nitrobenzol

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
P. Hochstrasser, A. Renken, Chem.-Ing.-Tech. 59 (1987), Nr. 2, S. 172-173

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115745804A (zh) * 2021-09-03 2023-03-07 万华化学（宁波）有限公司 一种降低粗硝基苯中二硝基苯含量的方法
CN115745804B (zh) * 2021-09-03 2024-04-09 万华化学（宁波）有限公司 一种降低粗硝基苯中二硝基苯含量的方法

Also Published As

Publication number Publication date
KR20130129893A (ko) 2013-11-29
CN103140464B (zh) 2014-12-03
PT2598473T (pt) 2017-02-16
CN103140464A (zh) 2013-06-05
WO2012013672A3 (de) 2012-04-26
KR101929059B1 (ko) 2018-12-13
WO2012013672A2 (de) 2012-02-02
JP2013535459A (ja) 2013-09-12
US20130197268A1 (en) 2013-08-01
JP5886284B2 (ja) 2016-03-16
EP2598473A2 (de) 2013-06-05
US8729309B2 (en) 2014-05-20
EP2598473B1 (de) 2016-11-16

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R081 Change of applicant/patentee

Owner name: COVESTRO DEUTSCHLAND AG, DE

Free format text: FORMER OWNER: BAYER MATERIALSCIENCE AKTIENGESELLSCHAFT, 51373 LEVERKUSEN, DE

Effective date: 20140317

Owner name: BAYER INTELLECTUAL PROPERTY GMBH, DE

Free format text: FORMER OWNER: BAYER MATERIALSCIENCE AKTIENGESELLSCHAFT, 51373 LEVERKUSEN, DE

Effective date: 20140317

R081 Change of applicant/patentee

Owner name: COVESTRO DEUTSCHLAND AG, DE

Free format text: FORMER OWNER: BAYER INTELLECTUAL PROPERTY GMBH, 40789 MONHEIM, DE

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