CN103140464B - 通过绝热硝化生产硝基苯的方法 - Google Patents

通过绝热硝化生产硝基苯的方法 Download PDF

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Publication number
CN103140464B
CN103140464B CN201180036942.XA CN201180036942A CN103140464B CN 103140464 B CN103140464 B CN 103140464B CN 201180036942 A CN201180036942 A CN 201180036942A CN 103140464 B CN103140464 B CN 103140464B
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China
Prior art keywords
benzene
mirbane
oil
quality
water
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Expired - Fee Related
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CN201180036942.XA
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English (en)
Chinese (zh)
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CN103140464A (zh
Inventor
T.克瑙夫
A.拉科埃斯
A.K.劳施
D.武尔夫
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Covestro Deutschland AG
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Bayer Pharma AG
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/08—Preparation of nitro compounds by substitution of hydrogen atoms by nitro groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/16—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/06—Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/325—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups reduction by other means than indicated in C07C209/34 or C07C209/36
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/45—Monoamines
    • C07C211/46—Aniline

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201180036942.XA 2010-07-28 2011-07-26 通过绝热硝化生产硝基苯的方法 Expired - Fee Related CN103140464B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102010038519A DE102010038519A1 (de) 2010-07-28 2010-07-28 Verfahren zur Herstellung von Nitrobenzol durch adiabate Nitrierung
DE102010038519.0 2010-07-28
PCT/EP2011/062827 WO2012013672A2 (de) 2010-07-28 2011-07-26 Verfahren zur herstellung von nitrobenzol durch adiabate nitrierung

Publications (2)

Publication Number Publication Date
CN103140464A CN103140464A (zh) 2013-06-05
CN103140464B true CN103140464B (zh) 2014-12-03

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CN201180036942.XA Expired - Fee Related CN103140464B (zh) 2010-07-28 2011-07-26 通过绝热硝化生产硝基苯的方法

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US (1) US8729309B2 (enExample)
EP (1) EP2598473B1 (enExample)
JP (1) JP5886284B2 (enExample)
KR (1) KR101929059B1 (enExample)
CN (1) CN103140464B (enExample)
DE (1) DE102010038519A1 (enExample)
PT (1) PT2598473T (enExample)
WO (1) WO2012013672A2 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106316858B (zh) * 2016-08-24 2018-08-31 康乃尔化学工业股份有限公司 一种稀硝酸加热工艺及其装置

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104066709B (zh) * 2012-01-31 2016-08-24 科思创德国股份有限公司 用于生产硝基苯的方法和设备
CN102675118A (zh) * 2012-04-25 2012-09-19 中国石油化工股份有限公司 一种硝基苯洗涤、分离方法
WO2014177450A1 (de) * 2013-04-29 2014-11-06 Bayer Materialscience Ag Verfahren zur herstellung von nitrobenzol durch adiabate nitrierung
US9346012B2 (en) * 2014-06-10 2016-05-24 Covestro Llc Method and apparatus for denenoxing waste gases from nitration
CN115193366B (zh) * 2021-04-09 2024-04-09 万华化学集团股份有限公司 一种硝化反应装置及利用该反应装置进行硝化反应的方法
CN115745804B (zh) * 2021-09-03 2024-04-09 万华化学（宁波）有限公司 一种降低粗硝基苯中二硝基苯含量的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1260958A (en) * 1985-11-01 1989-09-26 Earl G. Adams Co-production of an aromatic monoamine and an aromatic diamine directly from benzene or a benzene derivative through controlled nitration
CN1295059A (zh) * 1999-11-09 2001-05-16 拜尔公司 3,4－二氯硝基苯的绝热制备方法
EP1593654A1 (de) * 2004-04-10 2005-11-09 Bayer MaterialScience AG Verfahren zur Aufarbeitung von aromatische Nitroverbindungen enthaltenen Abwässern
CN101613285A (zh) * 2008-06-25 2009-12-30 中国科学院大连化学物理研究所 一种硝基苯合成方法及专用装备

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2256999A (en) 1939-03-08 1941-09-23 Du Pont Nitration of organic compounds
US3928475A (en) 1974-08-09 1975-12-23 Du Pont Azeotropic nitration of benzene
US3981935A (en) 1975-12-10 1976-09-21 E. I. Du Pont De Nemours And Company Azeotropic nitration of benzene
US4091042A (en) 1977-08-19 1978-05-23 American Cyanamid Company Continuous adiabatic process for the mononitration of benzene
US5313009A (en) 1990-01-04 1994-05-17 Nrm International Technologies C.V. Nitration process
DE4428017A1 (de) 1994-08-08 1996-02-15 Bayer Ag Verfahren zur Herstellung von aromatischen Aminen
DE4428459A1 (de) * 1994-08-11 1996-02-15 Bayer Ag Verfahren zur Herstellung von Dinitrotoluol
DE4428460A1 (de) * 1994-08-11 1996-02-15 Bayer Ag Verfahren zur Herstellung von Nitroaromaten
DE19539205A1 (de) 1995-10-22 1997-04-24 Meissner Gmbh & Co Kg Josef Verfahren zur Aromatennitrierung
US6079227A (en) 1997-06-05 2000-06-27 Nippon Sheet Glass Co., Ltd. Method for manufacturing bent and tempered glass sheet and apparatus for manufacturing the same
DE102006004943A1 (de) * 2006-02-03 2007-08-09 Bayer Materialscience Ag Verfahren zur Herstellung von Nitrobenzol
DE102006035203A1 (de) 2006-07-29 2008-01-31 Bayer Materialscience Ag Verfahren zur Herstellung von aromatischen Aminen
DE102007059513A1 (de) * 2007-12-11 2009-06-18 Bayer Materialscience Ag Verfahren zur Herstellung von Nitrobenzol durch adiabate Nitrierung
DE102008048713A1 (de) 2008-09-24 2010-03-25 Bayer Materialscience Ag Verfahren zur kontinuierlichen Herstellung von Nitrobenzol
DE102009005324B4 (de) 2009-01-16 2014-04-03 Plinke Gmbh Verfahren zur adiabatischen Nitrierung von Benzol

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1260958A (en) * 1985-11-01 1989-09-26 Earl G. Adams Co-production of an aromatic monoamine and an aromatic diamine directly from benzene or a benzene derivative through controlled nitration
CN1295059A (zh) * 1999-11-09 2001-05-16 拜尔公司 3,4－二氯硝基苯的绝热制备方法
EP1593654A1 (de) * 2004-04-10 2005-11-09 Bayer MaterialScience AG Verfahren zur Aufarbeitung von aromatische Nitroverbindungen enthaltenen Abwässern
CN101613285A (zh) * 2008-06-25 2009-12-30 中国科学院大连化学物理研究所 一种硝基苯合成方法及专用装备

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106316858B (zh) * 2016-08-24 2018-08-31 康乃尔化学工业股份有限公司 一种稀硝酸加热工艺及其装置

Also Published As

Publication number Publication date
EP2598473A2 (de) 2013-06-05
WO2012013672A2 (de) 2012-02-02
PT2598473T (pt) 2017-02-16
JP2013535459A (ja) 2013-09-12
KR20130129893A (ko) 2013-11-29
WO2012013672A3 (de) 2012-04-26
EP2598473B1 (de) 2016-11-16
DE102010038519A1 (de) 2012-02-02
CN103140464A (zh) 2013-06-05
JP5886284B2 (ja) 2016-03-16
KR101929059B1 (ko) 2018-12-13
US8729309B2 (en) 2014-05-20
US20130197268A1 (en) 2013-08-01

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