KR101809567B1 - 모노머, 포토레지스트 조성물 및 포토리소그래피 패턴의 형성 방법 - Google Patents
모노머, 포토레지스트 조성물 및 포토리소그래피 패턴의 형성 방법 Download PDFInfo
- Publication number
- KR101809567B1 KR101809567B1 KR1020120000213A KR20120000213A KR101809567B1 KR 101809567 B1 KR101809567 B1 KR 101809567B1 KR 1020120000213 A KR1020120000213 A KR 1020120000213A KR 20120000213 A KR20120000213 A KR 20120000213A KR 101809567 B1 KR101809567 B1 KR 101809567B1
- Authority
- KR
- South Korea
- Prior art keywords
- layer
- photoresist
- polymer
- photoresist composition
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 0 C*C(C)(C*)C(OC(C1OC2(CCCC2)OC1)C1OC2(CCCC2)OC1)=O Chemical compound C*C(C)(C*)C(OC(C1OC2(CCCC2)OC1)C1OC2(CCCC2)OC1)=O 0.000 description 4
- DPKAMABLFBOADL-UHFFFAOYSA-N CC(C)(OC1)OC1C(C1OC(C)(C)OC1)OC(C(C)=C)=O Chemical compound CC(C)(OC1)OC1C(C1OC(C)(C)OC1)OC(C(C)=C)=O DPKAMABLFBOADL-UHFFFAOYSA-N 0.000 description 1
- OKUJAEWECJMLCT-UHFFFAOYSA-N CC(C)(OC1)OC1C(C1OC(C)(C)OC1)OC(CCOC(C(C)=C)=O)=O Chemical compound CC(C)(OC1)OC1C(C1OC(C)(C)OC1)OC(CCOC(C(C)=C)=O)=O OKUJAEWECJMLCT-UHFFFAOYSA-N 0.000 description 1
- CPWOPEXMRRXJDF-UHFFFAOYSA-N CC(C)(OC1)OC1C(C1OC(C)(C)OC1)OC(COC(C(C)=C)=O)=O Chemical compound CC(C)(OC1)OC1C(C1OC(C)(C)OC1)OC(COC(C(C)=C)=O)=O CPWOPEXMRRXJDF-UHFFFAOYSA-N 0.000 description 1
- GONNPXUNEFEXDJ-UHFFFAOYSA-N CC(C)(OC1)OC1C(C1OC(C)(C)OC1)OCCOC(C(C)=C)=O Chemical compound CC(C)(OC1)OC1C(C1OC(C)(C)OC1)OCCOC(C(C)=C)=O GONNPXUNEFEXDJ-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/93—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems condensed with a ring other than six-membered
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
- C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
- C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D317/18—Radicals substituted by singly bound oxygen or sulfur atoms
- C07D317/24—Radicals substituted by singly bound oxygen or sulfur atoms esterified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F24/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a heterocyclic ring containing oxygen
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/0045—Photosensitive materials with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
- G03F7/0382—Macromolecular compounds which are rendered insoluble or differentially wettable the macromolecular compound being present in a chemically amplified negative photoresist composition
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/039—Macromolecular compounds which are photodegradable, e.g. positive electron resists
- G03F7/0392—Macromolecular compounds which are photodegradable, e.g. positive electron resists the macromolecular compound being present in a chemically amplified positive photoresist composition
- G03F7/0397—Macromolecular compounds which are photodegradable, e.g. positive electron resists the macromolecular compound being present in a chemically amplified positive photoresist composition the macromolecular compound having an alicyclic moiety in a side chain
-
- G—PHYSICS
- G06—COMPUTING OR CALCULATING; COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F7/00—Methods or arrangements for processing data by operating upon the order or content of the data handled
- G06F7/38—Methods or arrangements for performing computations using exclusively denominational number representation, e.g. using binary, ternary, decimal representation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/1053—Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
- Y10S430/1055—Radiation sensitive composition or product or process of making
- Y10S430/106—Binder containing
- Y10S430/111—Polymer of unsaturated acid or ester
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Theoretical Computer Science (AREA)
- Computational Mathematics (AREA)
- Mathematical Analysis (AREA)
- Mathematical Optimization (AREA)
- Pure & Applied Mathematics (AREA)
- General Engineering & Computer Science (AREA)
- Computing Systems (AREA)
- Materials For Photolithography (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
- Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201061429101P | 2010-12-31 | 2010-12-31 | |
| US61/429,101 | 2010-12-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20120078673A KR20120078673A (ko) | 2012-07-10 |
| KR101809567B1 true KR101809567B1 (ko) | 2017-12-15 |
Family
ID=45491284
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020120000213A Expired - Fee Related KR101809567B1 (ko) | 2010-12-31 | 2012-01-02 | 모노머, 포토레지스트 조성물 및 포토리소그래피 패턴의 형성 방법 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8771917B2 (enExample) |
| EP (1) | EP2472324A1 (enExample) |
| JP (1) | JP6080358B2 (enExample) |
| KR (1) | KR101809567B1 (enExample) |
| CN (1) | CN102603701B (enExample) |
| TW (1) | TWI428356B (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5947028B2 (ja) * | 2010-12-02 | 2016-07-06 | ローム アンド ハース エレクトロニック マテリアルズ エルエルシーRohm and Haas Electronic Materials LLC | ポリマー、フォトレジスト組成物、およびフォトリソグラフィパターンを形成する方法 |
| EP2472326A1 (en) * | 2010-12-31 | 2012-07-04 | Rohm and Haas Electronic Materials LLC | Polymers, photoresist compositions and methods of forming photolithographic patterns |
| EP2492749A1 (en) * | 2011-02-28 | 2012-08-29 | Rohm and Haas Electronic Materials LLC | Photoresist compositions and methods of forming photolithographic patterns |
| EP2698388B1 (en) * | 2011-04-15 | 2015-12-09 | Zeon Corporation | Polymerizable compound, polymerizable composition, polymer, and optically anisotropic body |
| JP2013225094A (ja) * | 2011-10-07 | 2013-10-31 | Jsr Corp | フォトレジスト組成物及びレジストパターン形成方法 |
| JP5923423B2 (ja) * | 2011-10-13 | 2016-05-24 | 住友化学株式会社 | 化合物、樹脂、レジスト組成物及びレジストパターンの製造方法 |
| JP5682542B2 (ja) * | 2011-11-17 | 2015-03-11 | 信越化学工業株式会社 | ネガ型パターン形成方法 |
| JP6213016B2 (ja) * | 2012-08-01 | 2017-10-18 | 住友化学株式会社 | レジスト組成物及びレジストパターンの製造方法 |
| JP6063264B2 (ja) * | 2012-09-13 | 2017-01-18 | 東京エレクトロン株式会社 | 被処理基体を処理する方法、及びプラズマ処理装置 |
| JP6327036B2 (ja) * | 2013-07-24 | 2018-05-23 | Jsr株式会社 | 感放射線性樹脂組成物、レジストパターン形成方法、重合体、化合物及び化合物の製造方法 |
| CN103400750A (zh) * | 2013-08-19 | 2013-11-20 | 中国科学院高能物理研究所 | 一种在硅衬底表面涂覆光刻胶的方法 |
| JP5963730B2 (ja) * | 2013-10-17 | 2016-08-03 | シャープ株式会社 | 通信システム及び通信装置 |
| JP6252154B2 (ja) * | 2013-12-13 | 2017-12-27 | 住友化学株式会社 | レジスト組成物及びレジストパターンの製造方法 |
| US9229321B2 (en) * | 2013-12-13 | 2016-01-05 | Sumitomo Chemical Company, Limited | Salt and photoresist composition comprising the same |
| US9581901B2 (en) | 2013-12-19 | 2017-02-28 | Rohm And Haas Electronic Materials Llc | Photoacid-generating copolymer and associated photoresist composition, coated substrate, and method of forming an electronic device |
| US9229319B2 (en) | 2013-12-19 | 2016-01-05 | Rohm And Haas Electronic Materials Llc | Photoacid-generating copolymer and associated photoresist composition, coated substrate, and method of forming an electronic device |
| US10685846B2 (en) * | 2014-05-16 | 2020-06-16 | Taiwan Semiconductor Manufacturing Company, Ltd. | Semiconductor integrated circuit fabrication with pattern-reversing process |
| JP6319001B2 (ja) * | 2014-09-08 | 2018-05-09 | Jsr株式会社 | 感放射線性樹脂組成物及びレジストパターン形成方法 |
| EP3067381A1 (en) * | 2015-03-12 | 2016-09-14 | Basf Se | Coated silicon surfaces, their manufacture and application |
| KR101697336B1 (ko) * | 2016-03-03 | 2017-01-17 | 주식회사 엘지화학 | 액정 배향막의 제조방법 |
| CN105566552B (zh) * | 2016-03-04 | 2019-05-17 | 江南大学 | 一种丙烯酸酯共聚物及其制成的248nm光刻胶组合物 |
| US11480878B2 (en) * | 2016-08-31 | 2022-10-25 | Rohm And Haas Electronic Materials Korea Ltd. | Monomers, polymers and photoresist compositions |
| US11574805B2 (en) * | 2019-09-12 | 2023-02-07 | Brewer Science, Inc. | Selective liquiphobic surface modification of substrates |
| CN110724216B (zh) * | 2019-11-05 | 2021-12-31 | 浙江展宇新材料有限公司 | 一种阻隔红外节能的pmma板材及其制备方法 |
| TWI887523B (zh) * | 2021-03-02 | 2025-06-21 | 日商Jsr股份有限公司 | 感放射線性樹脂組成物、抗蝕劑圖案的形成方法、聚合物及化合物 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1990011306A1 (en) | 1989-03-28 | 1990-10-04 | Ciba-Geigy Ag | Hydrogels based on sugar alcohol monomers |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5865411A (ja) * | 1981-10-15 | 1983-04-19 | Toyo Contact Lens Co Ltd | コンタクトレンズの製造法 |
| AU550604B2 (en) * | 1981-05-01 | 1986-03-27 | Menicon Co., Ltd | Water absorptive contact lens |
| JPS57181524A (en) * | 1981-05-01 | 1982-11-09 | Toyo Contact Lens Co Ltd | Contact lens and its manufacture |
| JPS58176618A (ja) * | 1982-04-10 | 1983-10-17 | Toyo Contact Lens Co Ltd | 含水性コンタクトレンズおよびその製造法 |
| JPS61190507A (ja) * | 1985-02-19 | 1986-08-25 | Toyo Contact Lens Co Ltd | 医用材料 |
| US5275909A (en) * | 1992-06-01 | 1994-01-04 | Ocg Microelectronic Materials, Inc. | Positive-working radiation sensitive mixtures and articles containing alkali-soluble binder, o-quinonediazide photoactive compound and BLANKOPHOR FBW acting dye |
| JP2715881B2 (ja) | 1993-12-28 | 1998-02-18 | 日本電気株式会社 | 感光性樹脂組成物およびパターン形成方法 |
| JPH0950126A (ja) | 1995-08-08 | 1997-02-18 | Fujitsu Ltd | レジスト組成物及びレジストパターン形成方法 |
| WO1997033198A1 (en) | 1996-03-07 | 1997-09-12 | The B.F. Goodrich Company | Photoresist compositions comprising polycyclic polymers with acid labile pendant groups |
| TWI234567B (en) * | 1998-11-27 | 2005-06-21 | Hyundai Electronics Ind | Cross-linker for photoresist, and photoresist composition comprising the same |
| TWI291953B (enExample) * | 2001-10-23 | 2008-01-01 | Mitsubishi Rayon Co | |
| DE10308504A1 (de) | 2003-02-26 | 2004-09-09 | Basf Ag | Enzymatische Herstellung von (Meth)acrylsäureestern |
| KR20060066932A (ko) | 2004-12-14 | 2006-06-19 | 주식회사 하이닉스반도체 | 포토레지스트 중합체 및 이를 함유하는 포토레지스트 조성물 |
| US8034547B2 (en) | 2007-04-13 | 2011-10-11 | Fujifilm Corporation | Pattern forming method, resist composition to be used in the pattern forming method, negative developing solution to be used in the pattern forming method and rinsing solution for negative development to be used in the pattern forming method |
| KR20090059650A (ko) | 2007-12-07 | 2009-06-11 | 삼성전자주식회사 | 이머전 리소그래피용 포토레지스트 조성물 및 이를 이용한포토레지스트 패턴의 형성 방법 |
| JP5775701B2 (ja) | 2010-02-26 | 2015-09-09 | 富士フイルム株式会社 | パターン形成方法及びレジスト組成物 |
-
2011
- 2011-12-23 EP EP11195165A patent/EP2472324A1/en not_active Withdrawn
- 2011-12-29 TW TW100149506A patent/TWI428356B/zh not_active IP Right Cessation
- 2011-12-31 US US13/341,931 patent/US8771917B2/en not_active Expired - Fee Related
- 2011-12-31 CN CN201110463333.4A patent/CN102603701B/zh not_active Expired - Fee Related
-
2012
- 2012-01-02 KR KR1020120000213A patent/KR101809567B1/ko not_active Expired - Fee Related
- 2012-01-04 JP JP2012000218A patent/JP6080358B2/ja not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1990011306A1 (en) | 1989-03-28 | 1990-10-04 | Ciba-Geigy Ag | Hydrogels based on sugar alcohol monomers |
Non-Patent Citations (1)
| Title |
|---|
| Liebigs Ann. Chem. 1991, 1079-1081 (1991.10.16.)* |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI428356B (zh) | 2014-03-01 |
| TW201238984A (en) | 2012-10-01 |
| CN102603701A (zh) | 2012-07-25 |
| EP2472324A1 (en) | 2012-07-04 |
| KR20120078673A (ko) | 2012-07-10 |
| CN102603701B (zh) | 2014-11-12 |
| US8771917B2 (en) | 2014-07-08 |
| JP6080358B2 (ja) | 2017-02-15 |
| US20130011783A1 (en) | 2013-01-10 |
| JP2012162707A (ja) | 2012-08-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
St.27 status event code: A-0-1-A10-A12-nap-PA0109 |
|
| P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
|
| P13-X000 | Application amended |
St.27 status event code: A-2-2-P10-P13-nap-X000 |
|
| R15-X000 | Change to inventor requested |
St.27 status event code: A-3-3-R10-R15-oth-X000 |
|
| R16-X000 | Change to inventor recorded |
St.27 status event code: A-3-3-R10-R16-oth-X000 |
|
| PG1501 | Laying open of application |
St.27 status event code: A-1-1-Q10-Q12-nap-PG1501 |
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