KR101799718B1 - 에폭시화 촉매의 제조 방법 - Google Patents

에폭시화 촉매의 제조 방법 Download PDF

Info

Publication number
KR101799718B1
KR101799718B1 KR1020167021598A KR20167021598A KR101799718B1 KR 101799718 B1 KR101799718 B1 KR 101799718B1 KR 1020167021598 A KR1020167021598 A KR 1020167021598A KR 20167021598 A KR20167021598 A KR 20167021598A KR 101799718 B1 KR101799718 B1 KR 101799718B1
Authority
KR
South Korea
Prior art keywords
catalyst
solid
column
produce
titanium tetrachloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020167021598A
Other languages
English (en)
Korean (ko)
Other versions
KR20160111941A (ko
Inventor
로저 그레이
데브라 잭슨
다니엘 에프. 화이트
샌더 나지
Original Assignee
라이온델 케미칼 테크놀로지, 엘.피.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 라이온델 케미칼 테크놀로지, 엘.피. filed Critical 라이온델 케미칼 테크놀로지, 엘.피.
Publication of KR20160111941A publication Critical patent/KR20160111941A/ko
Application granted granted Critical
Publication of KR101799718B1 publication Critical patent/KR101799718B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B01J35/10—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020167021598A 2014-01-22 2015-01-22 에폭시화 촉매의 제조 방법 Active KR101799718B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201461930192P 2014-01-22 2014-01-22
US61/930,192 2014-01-22
PCT/US2015/012382 WO2015112672A1 (en) 2014-01-22 2015-01-22 Method of preparing epoxidation catalysts

Publications (2)

Publication Number Publication Date
KR20160111941A KR20160111941A (ko) 2016-09-27
KR101799718B1 true KR101799718B1 (ko) 2017-11-20

Family

ID=53681920

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020167021598A Active KR101799718B1 (ko) 2014-01-22 2015-01-22 에폭시화 촉매의 제조 방법

Country Status (10)

Country Link
US (1) US9433925B2 (https=)
EP (1) EP3096879B1 (https=)
JP (1) JP6301482B2 (https=)
KR (1) KR101799718B1 (https=)
CN (1) CN105916581A (https=)
BR (1) BR112016016282B1 (https=)
ES (1) ES3024465T3 (https=)
SA (1) SA516371507B1 (https=)
SG (1) SG11201605483XA (https=)
WO (1) WO2015112672A1 (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106582809B (zh) * 2016-12-22 2019-08-30 红宝丽集团股份有限公司 一种烯烃环氧化催化剂及其制备方法
JP7128884B2 (ja) * 2018-03-15 2022-08-31 住友化学株式会社 チタン含有珪素酸化物成型体の製造方法、及びチタン含有珪素酸化物成型体
CN109675566A (zh) * 2019-01-30 2019-04-26 兰州城市学院 一种Co-Ti双金属有序介孔催化剂及其制备方法和应用
WO2021060263A1 (ja) * 2019-09-25 2021-04-01 住友化学株式会社 プロピレンオキサイドの製造方法
US20210129113A1 (en) * 2019-11-04 2021-05-06 Lyondell Chemical Technology, L.P. Titanated catalysts, methods of preparing titanated catalysts, and methods of epoxidation

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005279587A (ja) * 2004-03-30 2005-10-13 Mitsubishi Chemicals Corp 水添触媒およびその製造方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4367342A (en) 1969-04-02 1983-01-04 Shell Oil Company Olefin epoxidation
US4021454A (en) 1971-08-19 1977-05-03 Shell Oil Company Olefin epoxidation
JP3658790B2 (ja) * 1995-03-30 2005-06-08 住友化学株式会社 触媒及びオキシラン化合物の製造方法
US6011162A (en) * 1997-05-05 2000-01-04 Arco Chemical Technology, L.P. Epoxidation process using improved heterogeneous catalyst composition
WO1998050374A2 (en) * 1997-05-05 1998-11-12 Arco Chemical Technology, L.P. Epoxidation process using improved heterogeneous catalyst composition
US6114552A (en) 1999-09-28 2000-09-05 Arco Chemical Technology, L.P. Heterogeneous epoxidation catalyst
MY131860A (en) * 2000-06-21 2007-09-28 Shell Int Research Process for preparation of catalyst and use there of
US20050014960A1 (en) 2003-06-30 2005-01-20 Buijink Jan Karel Frederik Catalyst preparation
US7276464B2 (en) * 2004-06-17 2007-10-02 Lyondell Chemical Technology, L.P. Titanium zeolite catalysts
JP5346469B2 (ja) * 2004-12-17 2013-11-20 揚子石油化工股▲分▼有限公司 担持非メタロセンオレフィン重合触媒、その調製方法及び使用方法
ATE539815T1 (de) * 2007-11-30 2012-01-15 Borealis Tech Oy Verfahren zur herstellung von random- propylencopolymeren
JP2009274062A (ja) * 2008-04-17 2009-11-26 Sumitomo Chemical Co Ltd チタノシリケート
EP2504098B1 (en) * 2009-11-27 2016-07-06 Basf Se Process for the preparation of a titanium zeolite catalyst
US8932980B2 (en) * 2010-07-20 2015-01-13 Council Of Scientific & Industrial Research Ordered mesoporous titanosilicate and the process for the preparation thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005279587A (ja) * 2004-03-30 2005-10-13 Mitsubishi Chemicals Corp 水添触媒およびその製造方法

Also Published As

Publication number Publication date
WO2015112672A1 (en) 2015-07-30
JP6301482B2 (ja) 2018-03-28
ES3024465T3 (en) 2025-06-04
KR20160111941A (ko) 2016-09-27
US20150375200A1 (en) 2015-12-31
SA516371507B1 (ar) 2018-06-27
JP2017505223A (ja) 2017-02-16
EP3096879B1 (en) 2025-04-02
US9433925B2 (en) 2016-09-06
SG11201605483XA (en) 2016-08-30
EP3096879A1 (en) 2016-11-30
BR112016016282B1 (pt) 2024-01-16
EP3096879A4 (en) 2017-09-27
BR112016016282A2 (https=) 2017-08-08
CN105916581A (zh) 2016-08-31

Similar Documents

Publication Publication Date Title
KR100638174B1 (ko) 불균일 에폭시화 촉매
JP2909911B2 (ja) オキシラン化合物の製造方法
KR100449207B1 (ko) 불균일 촉매 재생방법
JP3658790B2 (ja) 触媒及びオキシラン化合物の製造方法
KR101799718B1 (ko) 에폭시화 촉매의 제조 방법
US6011162A (en) Epoxidation process using improved heterogeneous catalyst composition
JP2009535206A (ja) チタン触媒、これの調製およびエポキシ化反応におけるこれの使用
JP4251666B2 (ja) 改良された不均一触媒組成物を用いるエポキシ化法
US20130116454A1 (en) Epoxidation process
JP2006500204A (ja) 不均一系触媒の再生
JP4834982B2 (ja) チタン含有珪素酸化物触媒の製造方法及び触媒
JP3788107B2 (ja) チタン含有珪素酸化物触媒、該触媒の製造方法及びプロピレンオキサイドの製造方法
WO2006062111A1 (ja) チタン含有珪素酸化物触媒の製造方法、該触媒及び該触媒を用いるオレフィンオキサイド化合物の製造方法
JP6970739B2 (ja) チタン含有珪素酸化物の製造方法、エポキシドの製造方法、及びチタン含有珪素酸化物
JP7803854B2 (ja) チタン化触媒、チタン化触媒を調製する方法、及びエポキシ化の方法
EP2859945A1 (en) Process for the preparation of a heterogeneous epoxidation catalyst
EP2859946A1 (en) Process for regenerating heterogeneous epoxidation catalysts and their use to catalyze epoxidation reactions
JP2007186467A (ja) エポキシドの製造方法
JP2008062177A (ja) 触媒の再生方法
JP2005536474A (ja) 担持酸化ニオブ触媒を使用するエポキシ化方法
MXPA99005742A (en) Heterogeneous catalyst regeneration

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

AMND Amendment
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
A302 Request for accelerated examination
AMND Amendment
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

PA0302 Request for accelerated examination

St.27 status event code: A-1-2-D10-D17-exm-PA0302

St.27 status event code: A-1-2-D10-D16-exm-PA0302

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

E601 Decision to refuse application
PE0601 Decision on rejection of patent

St.27 status event code: N-2-6-B10-B15-exm-PE0601

X091 Application refused [patent]
AMND Amendment
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PX0901 Re-examination

St.27 status event code: A-2-3-E10-E12-rex-PX0901

PX0701 Decision of registration after re-examination

St.27 status event code: A-3-4-F10-F13-rex-PX0701

X701 Decision to grant (after re-examination)
GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

FPAY Annual fee payment

Payment date: 20201005

Year of fee payment: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

FPAY Annual fee payment

Payment date: 20210929

Year of fee payment: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

FPAY Annual fee payment

Payment date: 20220921

Year of fee payment: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 8

R18 Changes to party contact information recorded

Free format text: ST27 STATUS EVENT CODE: A-5-5-R10-R18-OTH-X000 (AS PROVIDED BY THE NATIONAL OFFICE)

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 9

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-OTH-PR1001 (AS PROVIDED BY THE NATIONAL OFFICE)

Year of fee payment: 9