JP6301482B2 - エポキシ化触媒の調製方法 - Google Patents

エポキシ化触媒の調製方法 Download PDF

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JP6301482B2
JP6301482B2 JP2016544863A JP2016544863A JP6301482B2 JP 6301482 B2 JP6301482 B2 JP 6301482B2 JP 2016544863 A JP2016544863 A JP 2016544863A JP 2016544863 A JP2016544863 A JP 2016544863A JP 6301482 B2 JP6301482 B2 JP 6301482B2
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solid
catalyst
titanium tetrachloride
column
produce
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JP2017505223A (ja
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ロジャー・グレイ
デブラ・ジャクソン
ダニエル・エフ・ホワイト
サンドラ・ナギー
Original Assignee
ライオンデル ケミカル テクノロジー、エル．ピー．
ライオンデル ケミカル テクノロジー、エル．ピー．
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2016544863A 2014-01-22 2015-01-22 エポキシ化触媒の調製方法 Active JP6301482B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201461930192P 2014-01-22 2014-01-22
US61/930,192 2014-01-22
PCT/US2015/012382 WO2015112672A1 (en) 2014-01-22 2015-01-22 Method of preparing epoxidation catalysts

Publications (2)

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JP2017505223A JP2017505223A (ja) 2017-02-16
JP6301482B2 true JP6301482B2 (ja) 2018-03-28

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JP2016544863A Active JP6301482B2 (ja) 2014-01-22 2015-01-22 エポキシ化触媒の調製方法

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Country Link
US (1) US9433925B2 (https=)
EP (1) EP3096879B1 (https=)
JP (1) JP6301482B2 (https=)
KR (1) KR101799718B1 (https=)
CN (1) CN105916581A (https=)
BR (1) BR112016016282B1 (https=)
ES (1) ES3024465T3 (https=)
SA (1) SA516371507B1 (https=)
SG (1) SG11201605483XA (https=)
WO (1) WO2015112672A1 (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106582809B (zh) * 2016-12-22 2019-08-30 红宝丽集团股份有限公司 一种烯烃环氧化催化剂及其制备方法
WO2019176951A1 (ja) * 2018-03-15 2019-09-19 住友化学株式会社 チタン含有珪素酸化物成型体の製造方法、及びチタン含有珪素酸化物成型体
CN109675566A (zh) * 2019-01-30 2019-04-26 兰州城市学院 一种Co-Ti双金属有序介孔催化剂及其制备方法和应用
ES3063934T3 (en) * 2019-09-25 2026-04-21 Sumitomo Chemical Company Ltd Method for producing propylene oxide
EP4054759B1 (en) * 2019-11-04 2026-04-08 Lyondell Chemical Technology, L.P. Titanated catalysts, methods of preparing titanated catalysts, and methods of epoxidation

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4367342A (en) 1969-04-02 1983-01-04 Shell Oil Company Olefin epoxidation
US4021454A (en) 1971-08-19 1977-05-03 Shell Oil Company Olefin epoxidation
JP3658790B2 (ja) * 1995-03-30 2005-06-08 住友化学株式会社 触媒及びオキシラン化合物の製造方法
KR100592442B1 (ko) 1997-05-05 2006-06-22 아르코 케미컬 테크날러쥐. 엘.피. 개선된 불균일 촉매 조성물을 이용하는 에폭시화물 제조방법
US6011162A (en) * 1997-05-05 2000-01-04 Arco Chemical Technology, L.P. Epoxidation process using improved heterogeneous catalyst composition
US6114552A (en) 1999-09-28 2000-09-05 Arco Chemical Technology, L.P. Heterogeneous epoxidation catalyst
MY131860A (en) * 2000-06-21 2007-09-28 Shell Int Research Process for preparation of catalyst and use there of
RU2006102493A (ru) * 2003-06-30 2006-06-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Получение катализатора
JP4599868B2 (ja) * 2004-03-30 2010-12-15 三菱化学株式会社 水添触媒およびその製造方法
US7276464B2 (en) * 2004-06-17 2007-10-02 Lyondell Chemical Technology, L.P. Titanium zeolite catalysts
KR101075404B1 (ko) * 2004-12-17 2011-10-24 양지 페트로케미컬 컴퍼니 코., 리미티드. 지지된 비메탈로센 올레핀 중합 촉매, 제조 방법 및 그용도
EP2065087B1 (en) * 2007-11-30 2012-01-04 Borealis Technology OY Process for the preparation of propylene random copolymers
JP2009274062A (ja) * 2008-04-17 2009-11-26 Sumitomo Chemical Co Ltd チタノシリケート
ES2596223T3 (es) * 2009-11-27 2017-01-05 Basf Se Proceso para la preparación de un catalizador de zeolita de titanio
EP2595921A1 (en) * 2010-07-20 2013-05-29 Council of Scientific & Industrial Research Ordered mesoporous titanosilicate and the process for the preparation thereof

Also Published As

Publication number Publication date
JP2017505223A (ja) 2017-02-16
BR112016016282B1 (pt) 2024-01-16
KR101799718B1 (ko) 2017-11-20
US9433925B2 (en) 2016-09-06
BR112016016282A2 (https=) 2017-08-08
SG11201605483XA (en) 2016-08-30
CN105916581A (zh) 2016-08-31
EP3096879B1 (en) 2025-04-02
ES3024465T3 (en) 2025-06-04
US20150375200A1 (en) 2015-12-31
WO2015112672A1 (en) 2015-07-30
KR20160111941A (ko) 2016-09-27
EP3096879A4 (en) 2017-09-27
EP3096879A1 (en) 2016-11-30
SA516371507B1 (ar) 2018-06-27

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