CN105916581A - 环氧化催化剂的制备方法 - Google Patents

环氧化催化剂的制备方法 Download PDF

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Publication number
CN105916581A
CN105916581A CN201580004451.5A CN201580004451A CN105916581A CN 105916581 A CN105916581 A CN 105916581A CN 201580004451 A CN201580004451 A CN 201580004451A CN 105916581 A CN105916581 A CN 105916581A
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CN
China
Prior art keywords
solid
catalyst
titanium tetrachloride
produce
column
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201580004451.5A
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English (en)
Chinese (zh)
Inventor
R·格雷
D·杰克逊
D·F·怀特
S·纳吉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lyondell Chemical Technology LP
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Lyondell Chemical Technology LP
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Filing date
Publication date
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Publication of CN105916581A publication Critical patent/CN105916581A/zh
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201580004451.5A 2014-01-22 2015-01-22 环氧化催化剂的制备方法 Pending CN105916581A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201461930192P 2014-01-22 2014-01-22
US61/930192 2014-01-22
PCT/US2015/012382 WO2015112672A1 (en) 2014-01-22 2015-01-22 Method of preparing epoxidation catalysts

Publications (1)

Publication Number Publication Date
CN105916581A true CN105916581A (zh) 2016-08-31

Family

ID=53681920

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201580004451.5A Pending CN105916581A (zh) 2014-01-22 2015-01-22 环氧化催化剂的制备方法

Country Status (10)

Country Link
US (1) US9433925B2 (https=)
EP (1) EP3096879B1 (https=)
JP (1) JP6301482B2 (https=)
KR (1) KR101799718B1 (https=)
CN (1) CN105916581A (https=)
BR (1) BR112016016282B1 (https=)
ES (1) ES3024465T3 (https=)
SA (1) SA516371507B1 (https=)
SG (1) SG11201605483XA (https=)
WO (1) WO2015112672A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106582809A (zh) * 2016-12-22 2017-04-26 红宝丽集团股份有限公司 一种烯烃环氧化催化剂及其制备方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7128884B2 (ja) * 2018-03-15 2022-08-31 住友化学株式会社 チタン含有珪素酸化物成型体の製造方法、及びチタン含有珪素酸化物成型体
CN109675566A (zh) * 2019-01-30 2019-04-26 兰州城市学院 一种Co-Ti双金属有序介孔催化剂及其制备方法和应用
WO2021060263A1 (ja) * 2019-09-25 2021-04-01 住友化学株式会社 プロピレンオキサイドの製造方法
US20210129113A1 (en) * 2019-11-04 2021-05-06 Lyondell Chemical Technology, L.P. Titanated catalysts, methods of preparing titanated catalysts, and methods of epoxidation

Citations (3)

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Publication number Priority date Publication date Assignee Title
US5840650A (en) * 1995-03-30 1998-11-24 Sumitomo Chemical Company, Limited Process of making a catalyst for producing oxirane compounds
CN1438919A (zh) * 2000-06-21 2003-08-27 国际壳牌研究有限公司 催化剂组合物、其制备方法及用途
CN1894030A (zh) * 2003-06-30 2007-01-10 国际壳牌研究有限公司 催化剂制备

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US4367342A (en) 1969-04-02 1983-01-04 Shell Oil Company Olefin epoxidation
US4021454A (en) 1971-08-19 1977-05-03 Shell Oil Company Olefin epoxidation
US6011162A (en) * 1997-05-05 2000-01-04 Arco Chemical Technology, L.P. Epoxidation process using improved heterogeneous catalyst composition
WO1998050374A2 (en) * 1997-05-05 1998-11-12 Arco Chemical Technology, L.P. Epoxidation process using improved heterogeneous catalyst composition
US6114552A (en) 1999-09-28 2000-09-05 Arco Chemical Technology, L.P. Heterogeneous epoxidation catalyst
JP4599868B2 (ja) * 2004-03-30 2010-12-15 三菱化学株式会社 水添触媒およびその製造方法
US7276464B2 (en) * 2004-06-17 2007-10-02 Lyondell Chemical Technology, L.P. Titanium zeolite catalysts
JP5346469B2 (ja) * 2004-12-17 2013-11-20 揚子石油化工股▲分▼有限公司 担持非メタロセンオレフィン重合触媒、その調製方法及び使用方法
ATE539815T1 (de) * 2007-11-30 2012-01-15 Borealis Tech Oy Verfahren zur herstellung von random- propylencopolymeren
JP2009274062A (ja) * 2008-04-17 2009-11-26 Sumitomo Chemical Co Ltd チタノシリケート
EP2504098B1 (en) * 2009-11-27 2016-07-06 Basf Se Process for the preparation of a titanium zeolite catalyst
US8932980B2 (en) * 2010-07-20 2015-01-13 Council Of Scientific & Industrial Research Ordered mesoporous titanosilicate and the process for the preparation thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5840650A (en) * 1995-03-30 1998-11-24 Sumitomo Chemical Company, Limited Process of making a catalyst for producing oxirane compounds
CN1438919A (zh) * 2000-06-21 2003-08-27 国际壳牌研究有限公司 催化剂组合物、其制备方法及用途
CN1894030A (zh) * 2003-06-30 2007-01-10 国际壳牌研究有限公司 催化剂制备

Non-Patent Citations (1)

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Title
宁桂玲主编: "《化学与应用化学研究生教学用书 高等无机合成》", 30 September 2007, 华东理工大学出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106582809A (zh) * 2016-12-22 2017-04-26 红宝丽集团股份有限公司 一种烯烃环氧化催化剂及其制备方法

Also Published As

Publication number Publication date
WO2015112672A1 (en) 2015-07-30
JP6301482B2 (ja) 2018-03-28
ES3024465T3 (en) 2025-06-04
KR20160111941A (ko) 2016-09-27
US20150375200A1 (en) 2015-12-31
SA516371507B1 (ar) 2018-06-27
JP2017505223A (ja) 2017-02-16
EP3096879B1 (en) 2025-04-02
US9433925B2 (en) 2016-09-06
SG11201605483XA (en) 2016-08-30
EP3096879A1 (en) 2016-11-30
KR101799718B1 (ko) 2017-11-20
BR112016016282B1 (pt) 2024-01-16
EP3096879A4 (en) 2017-09-27
BR112016016282A2 (https=) 2017-08-08

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Application publication date: 20160831