KR101768238B1 - 폴리우레탄 코팅물의 제조에 있어서의 주석 촉매의 용도 - Google Patents

폴리우레탄 코팅물의 제조에 있어서의 주석 촉매의 용도 Download PDF

Info

Publication number
KR101768238B1
KR101768238B1 KR1020127010688A KR20127010688A KR101768238B1 KR 101768238 B1 KR101768238 B1 KR 101768238B1 KR 1020127010688 A KR1020127010688 A KR 1020127010688A KR 20127010688 A KR20127010688 A KR 20127010688A KR 101768238 B1 KR101768238 B1 KR 101768238B1
Authority
KR
South Korea
Prior art keywords
aromatic
aliphatic
radical
independently
polyisocyanate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020127010688A
Other languages
English (en)
Korean (ko)
Other versions
KR20120101360A (ko
Inventor
프랑크 리흐터
라울 피레스
슈테판 라이터
옌스 크라우제
클라우스 유르크샤트
류바 이오브코바
마르쿠스 쉬르만
게리트 브라트묄러
Original Assignee
코베스트로 도이칠란드 아게
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 코베스트로 도이칠란드 아게 filed Critical 코베스트로 도이칠란드 아게
Publication of KR20120101360A publication Critical patent/KR20120101360A/ko
Application granted granted Critical
Publication of KR101768238B1 publication Critical patent/KR101768238B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/28—Di-epoxy compounds containing acyclic nitrogen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/282—Alkanols, cycloalkanols or arylalkanols including terpenealcohols
    • C08G18/2825—Alkanols, cycloalkanols or arylalkanols including terpenealcohols having at least 6 carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
KR1020127010688A 2009-10-30 2010-10-26 폴리우레탄 코팅물의 제조에 있어서의 주석 촉매의 용도 Active KR101768238B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102009051445.7 2009-10-30
DE102009051445A DE102009051445A1 (de) 2009-10-30 2009-10-30 Verwendung spezieller Katalysatoren für die Herstellung von Polyurethanbeschichtungen
PCT/EP2010/066104 WO2011051247A1 (de) 2009-10-30 2010-10-26 Verwendung von zinn- katalysatoren für die herstellung von polyurethanbeschichtungen

Publications (2)

Publication Number Publication Date
KR20120101360A KR20120101360A (ko) 2012-09-13
KR101768238B1 true KR101768238B1 (ko) 2017-08-14

Family

ID=43417044

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020127010688A Active KR101768238B1 (ko) 2009-10-30 2010-10-26 폴리우레탄 코팅물의 제조에 있어서의 주석 촉매의 용도

Country Status (11)

Country Link
US (1) US8946372B2 (enExample)
EP (1) EP2493948B1 (enExample)
JP (1) JP5615928B2 (enExample)
KR (1) KR101768238B1 (enExample)
CN (1) CN102574971B (enExample)
DE (1) DE102009051445A1 (enExample)
DK (1) DK2493948T3 (enExample)
ES (1) ES2435632T3 (enExample)
PL (1) PL2493948T3 (enExample)
RU (1) RU2564662C2 (enExample)
WO (1) WO2011051247A1 (enExample)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008021980A1 (de) * 2008-05-02 2009-11-05 Bayer Materialscience Ag Neue Katalysatoren und deren Einsatz bei der Herstellung von Polyurethanen
CN104640896B (zh) * 2012-09-25 2019-03-15 科思创德国股份有限公司 多异氰酸酯加聚产物
WO2014048854A1 (de) 2012-09-25 2014-04-03 Bayer Materialscience Ag Polyisocyanat-polyadditionsprodukte
EP2772496A1 (de) * 2013-02-28 2014-09-03 Bayer MaterialScience AG Direktsynthese von Zinn(II)- und Zinn(IV)-Alkoxiden aus elementarem Zinn und Alkoholen in Gegenwart von Aktivierungsreagenzien
EP2990381A1 (de) 2014-08-29 2016-03-02 Covestro Deutschland AG Verfahren zur Herstellung von Zinnverbindungen
DE102014226277A1 (de) 2014-12-17 2016-06-23 Henkel Ag & Co. Kgaa Zwei-Komponenten-Polyurethan-Klebstoff zum Verkleben von Faserformteilen
EP3245240B1 (de) * 2015-01-14 2024-07-03 Covestro Deutschland AG Zusammensetzung für transparente formkörper auf polyurethanbasis
CN107743510A (zh) * 2015-06-15 2018-02-27 巴斯夫涂料有限公司 涂覆轮辋的方法及以此得到的防污和防制动粉尘的涂层
JP6608462B2 (ja) 2015-06-15 2019-11-20 ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング ポリウレタン被覆剤組成物及び多層被覆塗装系を製造するためのその使用
US11559958B2 (en) 2015-07-23 2023-01-24 Bridgestone Americas Tire Operations, Llc Degradable foam-containing tires, related methods and kits for adding degradable foam to tires
US20180320019A1 (en) * 2015-11-20 2018-11-08 Covestro Deutschland Ag Multi-layer coating structure having a thermally latent catalyst
JP7163188B2 (ja) * 2016-04-22 2022-10-31 コベストロ、ドイチュラント、アクチエンゲゼルシャフト 熱潜在性に触媒された二成分系
TWI601571B (zh) 2016-12-07 2017-10-11 財團法人工業技術研究院 觸媒及以此觸媒合成環狀碳酸酯的方法
EP3381959A1 (de) * 2017-03-27 2018-10-03 Covestro Deutschland AG Dual cure-verfahren unter verwendung von thermisch latenten zinnkatalysatoren
CN110799566A (zh) * 2017-06-30 2020-02-14 科思创德国股份有限公司 使用热塑性的可自由基交联构建材料的增材制造方法
EP3428213A1 (de) 2017-07-12 2019-01-16 Covestro Deutschland AG Anorganische zinnverbindungen und ihre verwendung
US10773243B2 (en) 2017-09-07 2020-09-15 Ppg Industries Ohio, Inc. Thermolatent catalyst and its use in curable compositions
ES2909407T3 (es) * 2017-12-21 2022-05-06 Covestro Deutschland Ag Compuestos de poliuretano a base de catalizadores termolatentes
EP3502185A1 (de) 2017-12-22 2019-06-26 Covestro Deutschland AG Feuchtigkeitshärtende zusammensetzungen
EP3626201A1 (de) 2018-09-20 2020-03-25 Covestro Deutschland AG 3d-gedruckte kieferorthopädische zahnschiene aus vernetzten polymeren
CN113825782B (zh) 2019-04-18 2024-01-09 陶氏环球技术有限责任公司 粘合剂组合物
EP3770198A1 (de) 2019-07-26 2021-01-27 Covestro Intellectual Property GmbH & Co. KG Verfahren zur herstellung und aufarbeitung von katalysatorlösungen
EP3922636A1 (de) 2020-06-08 2021-12-15 Covestro Deutschland AG Herstellungsprozess für aminoalkoholate
EP4001334A1 (de) 2020-11-16 2022-05-25 Covestro Deutschland AG Verwendung spezieller katalysatoren für die herstellung von polyurethanbeschichtungen
EP4169962A1 (en) 2021-10-21 2023-04-26 Covestro Deutschland AG Encapsulated polyurethane polymerization catalyst and latent reactive polyurethane composition
EP4234602A1 (de) 2022-02-28 2023-08-30 Covestro Deutschland AG Verwendung spezieller katalysatoren für die herstellung von polyurethanbeschichtungen
WO2025168572A1 (en) 2024-02-08 2025-08-14 Allnex Netherlands B.V. Non-aqueous crosslinkable composition

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002037834A (ja) 2000-07-31 2002-02-06 National Institute Of Advanced Industrial & Technology 頭−尾定序性ポリウレタンの製造法
WO2007075561A1 (en) 2005-12-16 2007-07-05 E. I. Du Pont De Nemours And Company Protected air-activated organotin catalysts for polyurethane synthesis and processes therefore

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB899948A (enExample) 1900-01-01
BE586595A (enExample) 1959-01-17
US4430456A (en) 1981-02-02 1984-02-07 Air Products And Chemicals, Inc. Polyurethane-forming process using amino and amido dialkyl tin carboxylates
US4549945A (en) 1984-01-11 1985-10-29 Phillips Petroleum Company UV Cured polyurethanes using organotin promoters
DD242617A1 (de) 1985-11-13 1987-02-04 Akad Wissenschaften Ddr Verfahren zur herstellung von polyurethanen und polyurethanharnstoffen
RU2042691C1 (ru) * 1993-06-22 1995-08-27 Самигуллин Фаат Кафизович Способ получения раствора полиэфируретана в этилацетате
US5661219A (en) * 1993-09-06 1997-08-26 Nof Corporation Curable composition, thermal latent acid catalyst, method of coating, coated article, method of molding and molded article
FR2716124B1 (fr) 1994-02-11 1996-06-28 Rhone Poulenc Chimie Utilisation de dérivés de l'étain comme catalyseurs latents de polycondensation et prémélange en contenant.
MXPA05000007A (es) * 2002-06-21 2005-04-08 Recticel Material de poliuretano fotoestable microcelular o no celular y metodo para produccion del mismo.
GB0329272D0 (en) 2003-12-18 2004-01-21 Johnson Matthey Plc Catalyst and method of making polyurethane materials
JP4755598B2 (ja) * 2004-11-16 2011-08-24 三井化学株式会社 金属含有化合物から得られる樹脂およびその用途
EP1934270A2 (en) 2005-09-13 2008-06-25 Dow Gloval Technologies Inc. Distannoxane catalysts for silane crosslinking and condensation reactions
US20070141386A1 (en) * 2005-12-16 2007-06-21 Jerald Feldman Protected air-activated organotin catalysts for polyurethane synthesis
DE102008021980A1 (de) * 2008-05-02 2009-11-05 Bayer Materialscience Ag Neue Katalysatoren und deren Einsatz bei der Herstellung von Polyurethanen

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002037834A (ja) 2000-07-31 2002-02-06 National Institute Of Advanced Industrial & Technology 頭−尾定序性ポリウレタンの製造法
WO2007075561A1 (en) 2005-12-16 2007-07-05 E. I. Du Pont De Nemours And Company Protected air-activated organotin catalysts for polyurethane synthesis and processes therefore

Also Published As

Publication number Publication date
PL2493948T3 (pl) 2014-01-31
ES2435632T3 (es) 2013-12-20
JP5615928B2 (ja) 2014-10-29
KR20120101360A (ko) 2012-09-13
RU2012122000A (ru) 2013-12-10
JP2013509473A (ja) 2013-03-14
US20120220717A1 (en) 2012-08-30
DK2493948T3 (da) 2013-11-04
US8946372B2 (en) 2015-02-03
RU2564662C2 (ru) 2015-10-10
DE102009051445A1 (de) 2011-05-05
WO2011051247A1 (de) 2011-05-05
EP2493948A1 (de) 2012-09-05
EP2493948B1 (de) 2013-10-02
HK1172634A1 (en) 2013-04-26
CN102574971A (zh) 2012-07-11
CN102574971B (zh) 2014-12-03

Similar Documents

Publication Publication Date Title
KR101768238B1 (ko) 폴리우레탄 코팅물의 제조에 있어서의 주석 촉매의 용도
CN104640896B (zh) 多异氰酸酯加聚产物
CN104640897B (zh) 多异氰酸酯加聚产物
US9416215B2 (en) Catalysts and use thereof in the production of polyurethanes
WO2009135600A1 (de) Katalysatoren zur synthese von polyurethanen
CA3008399C (en) Acrylic polyurethane coatings including polyether polyols
EP2698200B1 (de) Thermolatente Katalysatoren, deren Herstellung und Verwendung
JP2025506839A (ja) ポリウレタンコーティングの調製のための特定の触媒の使用
HK1172634B (en) Use of tin catalysts for producing polyurethane coatings
EP4001334A1 (de) Verwendung spezieller katalysatoren für die herstellung von polyurethanbeschichtungen
JP2013509472A (ja) 触媒およびそれらの使用

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

R15-X000 Change to inventor requested

St.27 status event code: A-3-3-R10-R15-oth-X000

R16-X000 Change to inventor recorded

St.27 status event code: A-3-3-R10-R16-oth-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 8

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 9