KR101593259B1 - 공정 스트림으로부터 균일 촉매를 농축하는 방법 - Google Patents
공정 스트림으로부터 균일 촉매를 농축하는 방법 Download PDFInfo
- Publication number
- KR101593259B1 KR101593259B1 KR1020117019820A KR20117019820A KR101593259B1 KR 101593259 B1 KR101593259 B1 KR 101593259B1 KR 1020117019820 A KR1020117019820 A KR 1020117019820A KR 20117019820 A KR20117019820 A KR 20117019820A KR 101593259 B1 KR101593259 B1 KR 101593259B1
- Authority
- KR
- South Korea
- Prior art keywords
- membrane
- catalyst
- high boiling
- boiling point
- stream
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
- B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Polyethers (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009001225A DE102009001225A1 (de) | 2009-02-27 | 2009-02-27 | Verfahren zur Anreicherung eines Homogenkatalysators aus einem Prozessstrom |
| DE102009001225.7 | 2009-02-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20110124759A KR20110124759A (ko) | 2011-11-17 |
| KR101593259B1 true KR101593259B1 (ko) | 2016-02-12 |
Family
ID=42144907
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020117019820A Expired - Fee Related KR101593259B1 (ko) | 2009-02-27 | 2010-02-23 | 공정 스트림으로부터 균일 촉매를 농축하는 방법 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US8969628B2 (enExample) |
| EP (1) | EP2401078B1 (enExample) |
| JP (1) | JP5623435B2 (enExample) |
| KR (1) | KR101593259B1 (enExample) |
| CN (1) | CN102333593B (enExample) |
| BR (1) | BRPI1009755B1 (enExample) |
| DE (1) | DE102009001225A1 (enExample) |
| ES (1) | ES2442769T3 (enExample) |
| MX (1) | MX2011009008A (enExample) |
| MY (1) | MY153102A (enExample) |
| PL (1) | PL2401078T3 (enExample) |
| RU (1) | RU2011139168A (enExample) |
| SG (1) | SG174170A1 (enExample) |
| WO (1) | WO2010097376A1 (enExample) |
| ZA (1) | ZA201105351B (enExample) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007054885A1 (de) * | 2007-11-15 | 2009-05-20 | Evonik Degussa Gmbh | Verfahren zur Fraktionierung oxidischer Nanopartikel durch Querstrom-Membranfiltration |
| DE102008043422B3 (de) | 2008-11-03 | 2010-01-07 | Evonik Degussa Gmbh | Verfahren zur Aufreinigung niedermolekularer Hydridosilane |
| DE102009001230A1 (de) | 2009-02-27 | 2010-09-02 | Evonik Oxeno Gmbh | Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen |
| US20120123079A1 (en) | 2009-07-23 | 2012-05-17 | Evonik Fibres Gmbh | Polyimide membranes made of polymerization solutions |
| DE102009047351A1 (de) | 2009-12-01 | 2011-06-09 | Evonik Goldschmidt Gmbh | Komposit-Siliconmembranen mit hoher Trennwirkung |
| DE102011082441A1 (de) | 2011-09-09 | 2013-03-14 | Evonik Oxeno Gmbh | Strahlschlaufenreaktor mit Nanofiltration |
| GB201117950D0 (en) | 2011-10-18 | 2011-11-30 | Imp Innovations Ltd | Membranes for separation |
| DE102012202779A1 (de) * | 2012-02-23 | 2013-08-29 | Evonik Oxeno Gmbh | Verfahren und Vorrichtung zur technischen Hydroformylierung von Isobuten und zum Auftrennen des Produktgemisches |
| MX2015004527A (es) | 2012-10-12 | 2015-07-14 | Evonik Degussa Gmbh | Mezcla de bisfosfitos y su uso como mezcla catalizadora en la hidroformilacion. |
| DE102012223572A1 (de) | 2012-12-18 | 2014-06-18 | Evonik Industries Ag | Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren |
| DE102013203117A1 (de) | 2013-02-26 | 2014-08-28 | Evonik Industries Ag | Optimierte Trenntechnik zur Aufarbeitung von homogen katalysierten Hydroformylierungsmischungen |
| KR102126255B1 (ko) | 2013-03-29 | 2020-06-24 | 제이에스알 가부시끼가이샤 | 조성물, 패턴이 형성된 기판의 제조 방법, 막 및 그의 형성 방법, 및 화합물 |
| DE102013215004A1 (de) * | 2013-07-31 | 2015-02-05 | Evonik Industries Ag | Membrankaskade mit sinkender Trenntemperatur |
| DE102014209421A1 (de) | 2014-05-19 | 2015-11-19 | Evonik Degussa Gmbh | Membrangestützte Katalysatorabtrennung bei der Epoxidierung von cyclischen, ungesättigten C12-Verbindungen zum Beispiel Cyclododecen (CDEN) |
| US9920168B2 (en) | 2015-03-17 | 2018-03-20 | Dow Global Technologies Llc | Polymers of intrinsic microporosity |
| DE112016002429T5 (de) | 2015-05-29 | 2018-02-22 | Dow Global Technologies Llc | Isatincopolymere mit intrinsischer microporosität |
| WO2016206008A1 (en) | 2015-06-24 | 2016-12-29 | Dow Global Technologies Llc | Isatin copolymers having intrinsic microporosity |
| WO2017091357A1 (en) | 2015-11-24 | 2017-06-01 | Dow Global Technologies Llc | Troger's base polymers having intrinsic microporosity |
| RU2741385C2 (ru) * | 2016-03-07 | 2021-01-25 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ извлечения металлического компонента |
| EP3510080A1 (en) | 2016-09-12 | 2019-07-17 | Dow Global Technologies, LLC | Polymer including troger's base and isatin moieties and having intrinsic microporosity |
| CN109689731A (zh) * | 2016-09-20 | 2019-04-26 | 陶氏环球技术有限责任公司 | 包括具有特勒格碱和螺双茚部分的子单元的具有固有微孔性的聚合物 |
| EP3762391A4 (en) | 2018-03-08 | 2022-08-03 | ExxonMobil Technology and Engineering Company | SPIROCENTRIC COMPOUNDS AND POLYMERS THEREOF |
| US20210013536A1 (en) * | 2018-06-29 | 2021-01-14 | Sepion Technologies, Inc. | Membranes for aqueous redox flow batteries |
| CN120049075A (zh) | 2018-07-27 | 2025-05-27 | 福恩能源公司 | 用于电化学电池的负电极 |
| DE202019001414U1 (de) | 2019-02-01 | 2019-04-12 | Evonik Canada Inc. | Vorrichtung zum Trennen von Gaskomponenten aus einem Gasstrom mit veränderlicher Zusammensetzung oder Strömungsrate |
| CN115066429A (zh) | 2020-02-11 | 2022-09-16 | 巴斯夫欧洲公司 | 二异丁烯的低压醛化 |
| EP4183900B1 (en) * | 2020-07-17 | 2025-12-10 | Panasonic Intellectual Property Management Co., Ltd. | Electrode catalyst for water electrolysis cells, water electrolysis cell, and water electrolysis device |
| WO2022014243A1 (ja) * | 2020-07-17 | 2022-01-20 | パナソニックIpマネジメント株式会社 | 水電解セルの電極触媒、水電解セル、及び水電解装置 |
| ES2974422T3 (es) | 2020-07-30 | 2024-06-27 | Evonik Oxeno Gmbh & Co Kg | Procedimiento para la preparación de aldehídos y separación del sistema catalítico mediante separación por membrana |
| ES2992645T3 (en) | 2021-11-19 | 2024-12-16 | Evonik Oxeno Gmbh & Co Kg | Process for producing aldehydes and cooling a mass flow |
| ES2992663T3 (en) | 2021-11-19 | 2024-12-16 | Evonik Oxeno Gmbh & Co Kg | Process for producing aldehydes and cooling a mass flow |
| EP4223737A1 (de) * | 2022-02-08 | 2023-08-09 | Evonik Operations GmbH | Optimierte thermische trennung durch vorherigen gasaustausch |
| CN119775550B (zh) * | 2024-11-01 | 2025-10-10 | 山东大学 | 一种可溶性单位点的钌基自具微孔聚合物催化剂及其制备方法和应用 |
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| GB0411463D0 (en) | 2004-05-22 | 2004-06-23 | Univ Manchester | Thin layer composite membrane |
| DE102005001041A1 (de) | 2005-01-07 | 2006-07-20 | Goldschmidt Gmbh | Neuartige Siloxanblockcopolymere |
| DE102005001039B4 (de) | 2005-01-07 | 2017-11-09 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Äquilibrierungsprodukten von Organosiloxanen und die so erhältlichen Organopolysiloxane |
| DE102005004706A1 (de) | 2005-02-02 | 2006-08-10 | Goldschmidt Gmbh | UV-Licht absorbierende quaternäre Polysiloxane |
| DE102005043742A1 (de) | 2005-09-14 | 2007-03-22 | Goldschmidt Gmbh | Verwendung von Epoxy-funktionellen Silanen als Haftungsadditiv für kationisch strahlenhärtende Silikontrennbeschichtungen |
| DE102005046250B4 (de) * | 2005-09-27 | 2020-10-08 | Evonik Operations Gmbh | Anlage zur Abtrennung von organischen Übergangsmetallkomplexkatalysatoren |
| DE102005051939A1 (de) | 2005-10-29 | 2007-05-03 | Goldschmidt Gmbh | Verfahren zur Herstellung von organisch modifizierten Polyorganosiloxanen |
| DE102005056246A1 (de) | 2005-11-25 | 2007-06-06 | Goldschmidt Gmbh | Gepfropfte Polyether-Copolymerisate und deren Verwendung zur Stabilisierung von Schaumstoffen |
| DE102005060784A1 (de) | 2005-12-16 | 2007-06-28 | Basf Ag | Verfahren zur Rückgewinnung eines an Hydroformylierungskatalysator angereicherten Stroms |
| DE102005061782A1 (de) | 2005-12-23 | 2007-06-28 | Goldschmidt Gmbh | Silikonhaltige Pfropfmischpolymere auf Basis styroloxidbasierter Silikonpolyether |
| DE102006003618A1 (de) * | 2006-01-26 | 2007-08-02 | Oxeno Olefinchemie Gmbh | Verfahren zur Abtrennung von Metall-Komplexkatalysatoren aus Telomerisationsgemischen |
| DE102006005100A1 (de) | 2006-02-04 | 2007-08-09 | Goldschmidt Gmbh | Verfahren zur Herstellung organomodifizierter Siloxane |
| DE102006008387A1 (de) | 2006-02-21 | 2007-08-30 | Goldschmidt Gmbh | Verfahren zur Herstellung von siloxanhaltigen Trennbeschichtungen |
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| DE102007044148A1 (de) | 2007-09-15 | 2009-03-26 | Evonik Goldschmidt Gmbh | Neuartige siloxanhaltige Blockcopolymere, Verfahren zu deren Herstellung und deren Verwendung für Schmiermittel |
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| DE102008000287A1 (de) | 2008-02-13 | 2009-08-20 | Evonik Goldschmidt Gmbh | Reaktives, flüssiges Keramikbindemittel |
| DE102008001786A1 (de) | 2008-05-15 | 2009-11-26 | Evonik Goldschmidt Gmbh | Verwendung organomodifizierter Siloxanblockcopolymere als Pflegewirkstoff zur Pflege von menschlichen oder tierischen Körperteilen |
| DE102008001788A1 (de) | 2008-05-15 | 2009-11-26 | Evonik Goldschmidt Gmbh | Verwendung organomodifizierter Siloxanblockcopolymere zur Herstellung kosmetischer oder pharmazeutischer Zusammensetzungen |
| DE102008040986A1 (de) | 2008-08-05 | 2010-02-11 | Evonik Goldschmidt Gmbh | Hydrophobierung von Bauelementen aus Mineralfasern |
| DE102008041601A1 (de) | 2008-08-27 | 2010-03-04 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung verzweigter SiH-funtioneller Polysiloxane und deren Verwendung zur Herstellung flüssiger, SiC- oder SiOC-verknüpfter, verzweigter organomodifizierter Polysiloxane |
| DE102008041652A1 (de) | 2008-08-28 | 2010-03-04 | Evonik Oxeno Gmbh | Vorrichtung und Verfahren für die kontinuierliche Umsetzung einer Flüssigkeit mit einem Gas |
| DE102008041870A1 (de) | 2008-09-08 | 2010-03-11 | Evonik Degussa Gmbh | Reaktor mit Titansilikat-Rezyklierung |
| DE102008042381A1 (de) | 2008-09-26 | 2010-04-01 | Evonik Goldschmidt Gmbh | Emulgator-Systeme für kosmetische und pharmazeutische Öl-in-Wasser-Emulsionen |
| EP2334172B1 (en) | 2008-10-17 | 2015-01-21 | Evonik Degussa GmbH | Agrochemical oil compositions comprising alkylpolysiloxane adjuvants of high silicone character |
| DE102008043422B3 (de) | 2008-11-03 | 2010-01-07 | Evonik Degussa Gmbh | Verfahren zur Aufreinigung niedermolekularer Hydridosilane |
| DE102009001230A1 (de) | 2009-02-27 | 2010-09-02 | Evonik Oxeno Gmbh | Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen |
| DE102009015211A1 (de) | 2009-03-31 | 2010-10-14 | Evonik Goldschmidt Gmbh | Selbstvernetzende Polysiloxane in Beschichtungen von Enzymimmobilisaten |
| DE102009002415A1 (de) | 2009-04-16 | 2010-10-21 | Evonik Goldschmidt Gmbh | Emulgator enthaltend glycerinmodifizierte Organopolysiloxane |
| DE102009003275A1 (de) | 2009-05-20 | 2010-11-25 | Evonik Goldschmidt Gmbh | Verzweigte Polydimethylsiloxan-Polyoxyalkylen Copolymere, ein Verfahren zu ihrer Herstellung und ihre Verwendung als Anti-Vernebelungsadditiv in UV-härtenden Silikonen |
| DE102009028636A1 (de) | 2009-08-19 | 2011-02-24 | Evonik Goldschmidt Gmbh | Neuartige Urethangruppen enthaltende silylierte Präpolymere und Verfahren zu deren Herstellung |
| DE102009028640A1 (de) | 2009-08-19 | 2011-02-24 | Evonik Goldschmidt Gmbh | Härtbare Masse enthaltend Urethangruppen aufweisende silylierte Polymere und deren Verwendung in Dicht- und Klebstoffen, Binde- und/oder Oberflächenmodifizierungsmitteln |
| DE102010002178A1 (de) | 2010-02-22 | 2011-08-25 | Evonik Goldschmidt GmbH, 45127 | Verfahren zur Herstellung von Amin-Amid-funktionellen Siloxanen |
| DE102010002180A1 (de) | 2010-02-22 | 2011-08-25 | Evonik Goldschmidt GmbH, 45127 | Stickstoffhaltige silizium-organische Pfropfmischpolymere |
| DE102010031087A1 (de) | 2010-07-08 | 2012-01-12 | Evonik Goldschmidt Gmbh | Neuartige polyestermodifizierte Organopolysiloxane |
-
2009
- 2009-02-27 DE DE102009001225A patent/DE102009001225A1/de not_active Withdrawn
-
2010
- 2010-02-23 WO PCT/EP2010/052242 patent/WO2010097376A1/de not_active Ceased
- 2010-02-23 CN CN201080009645.1A patent/CN102333593B/zh not_active Expired - Fee Related
- 2010-02-23 ES ES10711629.5T patent/ES2442769T3/es active Active
- 2010-02-23 EP EP10711629.5A patent/EP2401078B1/de not_active Not-in-force
- 2010-02-23 BR BRPI1009755-4A patent/BRPI1009755B1/pt not_active IP Right Cessation
- 2010-02-23 MX MX2011009008A patent/MX2011009008A/es active IP Right Grant
- 2010-02-23 MY MYPI2011004020 patent/MY153102A/en unknown
- 2010-02-23 US US13/203,639 patent/US8969628B2/en not_active Expired - Fee Related
- 2010-02-23 PL PL10711629T patent/PL2401078T3/pl unknown
- 2010-02-23 JP JP2011551482A patent/JP5623435B2/ja not_active Expired - Fee Related
- 2010-02-23 RU RU2011139168/04A patent/RU2011139168A/ru not_active Application Discontinuation
- 2010-02-23 KR KR1020117019820A patent/KR101593259B1/ko not_active Expired - Fee Related
- 2010-02-23 SG SG2011062072A patent/SG174170A1/en unknown
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2011
- 2011-07-20 ZA ZA2011/05351A patent/ZA201105351B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP2401078A1 (de) | 2012-01-04 |
| PL2401078T3 (pl) | 2014-03-31 |
| KR20110124759A (ko) | 2011-11-17 |
| CN102333593B (zh) | 2014-08-27 |
| US20120046503A1 (en) | 2012-02-23 |
| JP2012519061A (ja) | 2012-08-23 |
| JP5623435B2 (ja) | 2014-11-12 |
| RU2011139168A (ru) | 2013-04-10 |
| BRPI1009755B1 (pt) | 2018-02-14 |
| SG174170A1 (en) | 2011-10-28 |
| ZA201105351B (en) | 2012-10-31 |
| DE102009001225A1 (de) | 2010-09-02 |
| BRPI1009755A2 (pt) | 2016-03-15 |
| ES2442769T3 (es) | 2014-02-13 |
| CN102333593A (zh) | 2012-01-25 |
| MX2011009008A (es) | 2011-11-29 |
| MY153102A (en) | 2014-12-31 |
| WO2010097376A1 (de) | 2010-09-02 |
| US8969628B2 (en) | 2015-03-03 |
| EP2401078B1 (de) | 2013-10-23 |
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