KR101539843B1 - 고밀도 음극 활물질 및 이의 제조방법 - Google Patents

고밀도 음극 활물질 및 이의 제조방법 Download PDF

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KR101539843B1
KR101539843B1 KR1020130066228A KR20130066228A KR101539843B1 KR 101539843 B1 KR101539843 B1 KR 101539843B1 KR 1020130066228 A KR1020130066228 A KR 1020130066228A KR 20130066228 A KR20130066228 A KR 20130066228A KR 101539843 B1 KR101539843 B1 KR 101539843B1
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metal oxide
lithium metal
lithium
negative electrode
active material
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KR20140009921A (ko
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오병훈
김제영
윤현웅
김예리
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주식회사 엘지화학
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Priority to BR112014001839A priority Critical patent/BR112014001839B8/pt
Priority to CN201380002401.4A priority patent/CN103733394B/zh
Priority to JP2014527108A priority patent/JP5888418B2/ja
Priority to PCT/KR2013/006216 priority patent/WO2014010970A1/ko
Priority to EP13806058.7A priority patent/EP2722914B1/en
Priority to TW102125067A priority patent/TWI502796B/zh
Priority to US14/012,347 priority patent/US9608260B2/en
Publication of KR20140009921A publication Critical patent/KR20140009921A/ko
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G1/00—Methods of preparing compounds of metals not covered by subclasses C01B, C01C, C01D, or C01F, in general
    • C01G1/02—Oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/02—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/003—Titanates
    • C01G23/005—Alkali titanates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0416—Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0419—Methods of deposition of the material involving spraying
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
KR1020130066228A 2012-07-13 2013-06-11 고밀도 음극 활물질 및 이의 제조방법 Active KR101539843B1 (ko)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CN201380002401.4A CN103733394B (zh) 2012-07-13 2013-07-11 具有高密度的负极活性材料及其制备方法
JP2014527108A JP5888418B2 (ja) 2012-07-13 2013-07-11 負極活物質、負極活物質の製造方法、負極および二次電池
PCT/KR2013/006216 WO2014010970A1 (ko) 2012-07-13 2013-07-11 고밀도 음극 활물질 및 이의 제조방법
EP13806058.7A EP2722914B1 (en) 2012-07-13 2013-07-11 High density anode active material and preparation method thereof
BR112014001839A BR112014001839B8 (pt) 2012-07-13 2013-07-11 Material ativo do anodo tendo alta densidade e seu método de preparação
TW102125067A TWI502796B (zh) 2012-07-13 2013-07-12 具有高密度之陽極活性材料及其製法
US14/012,347 US9608260B2 (en) 2012-07-13 2013-08-28 Anode active material having high density and preparation method thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20120076905 2012-07-13
KR1020120076905 2012-07-13

Publications (2)

Publication Number Publication Date
KR20140009921A KR20140009921A (ko) 2014-01-23
KR101539843B1 true KR101539843B1 (ko) 2015-07-27

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Country Link
US (1) US9608260B2 (enExample)
EP (1) EP2722914B1 (enExample)
JP (1) JP5888418B2 (enExample)
KR (1) KR101539843B1 (enExample)
CN (1) CN103733394B (enExample)
BR (1) BR112014001839B8 (enExample)
TW (1) TWI502796B (enExample)
WO (1) WO2014010970A1 (enExample)

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US20160181604A1 (en) * 2014-09-12 2016-06-23 Johnson Controls Technology Company Systems and methods for lithium titanate oxide (lto) anode electrodes for lithium ion battery cells
US20160181603A1 (en) * 2014-09-12 2016-06-23 Johnson Controls Technology Company Systems and methods for lithium titanate oxide (lto) anode electrodes for lithium ion battery cells
CN104282906B (zh) * 2014-09-19 2017-04-12 清华大学深圳研究生院 微纳结构的钛酸锂材料及其制备方法
KR101631386B1 (ko) * 2014-11-21 2016-06-17 경북대학교 산학협력단 리튬-티타늄 산화물을 이용한 리튬 이차전지용 음극 활물질 및 그의 제조방법
WO2016117950A1 (ko) 2015-01-21 2016-07-28 주식회사 엘지화학 출력특성이 향상된 리튬이차전지
EP3279146A4 (en) * 2015-03-31 2018-12-05 Hitachi, Ltd. Lithium-containing transition metal oxide and lithium ion secondary cell using same
JP6523115B2 (ja) 2015-09-16 2019-05-29 株式会社東芝 電池用活物質、負極、非水電解質電池、電池パック及び車
WO2017111566A1 (ko) * 2015-12-24 2017-06-29 주식회사 엘지화학 출력 특성이 향상된 음극 활물질 상기 음극 활물질을 포함하는 전기화학소자용 전극
WO2017135758A1 (ko) * 2016-02-05 2017-08-10 주식회사 엘지화학 음극 활물질, 이를 포함하는 음극 및 리튬 이차전지
KR101847769B1 (ko) * 2016-02-05 2018-04-10 주식회사 엘지화학 음극 활물질, 이를 포함하는 음극 및 리튬 이차전지
CN106783207B (zh) * 2016-12-27 2019-05-07 宁波中车新能源科技有限公司 (Li4Ti5O12-Li2TiO3)/(AC-Li2MnO4)混合超级电容器
CN110291667B (zh) 2017-03-13 2022-09-23 株式会社Lg新能源 具有高输出特性的负极活性材料和包含所述材料的锂二次电池
CN109565044B (zh) * 2017-03-21 2022-07-12 株式会社Lg新能源 具有高输出特性的负极活性材料和包含其的锂二次电池
US11271202B2 (en) * 2018-08-22 2022-03-08 Samsung Sdi Co., Ltd. Positive active material, method of manufacturing the same, and positive electrode and rechargeable lithium battery including the same
WO2020162504A1 (ja) * 2019-02-08 2020-08-13 三洋電機株式会社 円筒形電池
CN115677435B (zh) * 2021-07-28 2023-11-28 北京理工大学 一种微纳球形高能钝感cl-20/rdx共晶炸药及其制备方法

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Also Published As

Publication number Publication date
EP2722914A4 (en) 2014-09-24
US20140017567A1 (en) 2014-01-16
JP5888418B2 (ja) 2016-03-22
CN103733394A (zh) 2014-04-16
KR20140009921A (ko) 2014-01-23
BR112014001839B8 (pt) 2023-03-21
EP2722914A1 (en) 2014-04-23
TW201421785A (zh) 2014-06-01
JP2014524653A (ja) 2014-09-22
EP2722914B1 (en) 2015-10-21
WO2014010970A1 (ko) 2014-01-16
TWI502796B (zh) 2015-10-01
BR112014001839B1 (pt) 2020-12-29
BR112014001839A2 (pt) 2017-02-21
CN103733394B (zh) 2018-06-22
US9608260B2 (en) 2017-03-28

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