KR101461682B1 - 메타세시스 반응용 촉매로서의 신규한 루테늄 착체 - Google Patents

메타세시스 반응용 촉매로서의 신규한 루테늄 착체 Download PDF

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Publication number
KR101461682B1
KR101461682B1 KR1020087031644A KR20087031644A KR101461682B1 KR 101461682 B1 KR101461682 B1 KR 101461682B1 KR 1020087031644 A KR1020087031644 A KR 1020087031644A KR 20087031644 A KR20087031644 A KR 20087031644A KR 101461682 B1 KR101461682 B1 KR 101461682B1
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KR
South Korea
Prior art keywords
alkyl
mmol
rucl
formula
imh
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KR1020087031644A
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English (en)
Korean (ko)
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KR20090024737A (ko
Inventor
쿠르트 퓐테너
미켈란젤로 스칼로네
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에프. 호프만-라 로슈 아게
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyrrole Compounds (AREA)
KR1020087031644A 2006-06-30 2007-06-18 메타세시스 반응용 촉매로서의 신규한 루테늄 착체 Expired - Fee Related KR101461682B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP06116373.9 2006-06-30
EP06116373 2006-06-30
PCT/EP2007/055995 WO2008000644A1 (en) 2006-06-30 2007-06-18 New ruthenium complexes as catalysts for metahesis reactions

Publications (2)

Publication Number Publication Date
KR20090024737A KR20090024737A (ko) 2009-03-09
KR101461682B1 true KR101461682B1 (ko) 2014-11-13

Family

ID=38475927

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020087031644A Expired - Fee Related KR101461682B1 (ko) 2006-06-30 2007-06-18 메타세시스 반응용 촉매로서의 신규한 루테늄 착체

Country Status (15)

Country Link
US (1) US7781586B2 (enExample)
EP (1) EP2044095B1 (enExample)
JP (1) JP5323691B2 (enExample)
KR (1) KR101461682B1 (enExample)
CN (1) CN101479283B (enExample)
AT (1) ATE440852T1 (enExample)
AU (1) AU2007263808B2 (enExample)
BR (1) BRPI0713871B1 (enExample)
CA (1) CA2655575C (enExample)
DE (1) DE602007002199D1 (enExample)
ES (1) ES2329424T3 (enExample)
IL (1) IL195868A (enExample)
MX (1) MX2008016069A (enExample)
TW (1) TWI422430B (enExample)
WO (1) WO2008000644A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5314753B2 (ja) * 2008-05-22 2013-10-16 リミテッド・ライアビリティ・カンパニー・”ユナイテッド・リサーチ・アンド・デベロップメント・センター” ジシクロペンタジエンのメタセシス重合触媒、その製造方法および重合方法
US9024034B2 (en) 2009-11-09 2015-05-05 Exxonmobil Chemical Patents Inc. Metathesis catalysts and processes for use thereof
US8809563B2 (en) 2009-11-09 2014-08-19 Exxonmobil Chemical Patents Inc. Metathesis catalyst and process for use thereof
BR112012020146A2 (pt) * 2010-02-12 2020-08-18 Exxonmobil Chemical Patents Inc catalisador de metátese e processos para uso do mesmo.
HK1197066A1 (zh) * 2011-06-03 2015-01-02 Massachusetts Institute Of Technology Z選擇性關環複分解反應
EP2639219B1 (en) * 2012-03-14 2016-08-10 Umicore AG & Co. KG Ruthenium-based metathesis catalysts and precursors for their preparation
EP2866936A4 (en) * 2012-06-28 2016-04-06 Exxonmobil Chem Patents Inc METATHESIS CATALYST AND METHOD FOR ITS USE
US9938253B2 (en) 2013-06-12 2018-04-10 Trustees Of Boston College Catalysts for efficient Z-selective metathesis
WO2019105338A1 (zh) * 2017-12-01 2019-06-06 天地融科技股份有限公司 数据发送电路、数据接收电路以及装置

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010014234A (ko) * 1997-06-27 2001-02-26 에프. 아. 프라저, 에른스트 알테르 (에. 알테르), 한스 페터 비틀린 (하. 페. 비틀린), 피. 랍 보프, 브이. 스펜글러, 페. 아에글러 루테늄 및 오스뮴 촉매
WO2005094345A2 (en) * 2004-03-29 2005-10-13 California Institute Of Technology Latent, high-activity olefin metathesis catalysts containing an n-heterocyclic carbene ligand

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100823365B1 (ko) 1999-05-24 2008-04-17 캘리포니아 인스티튜트 오브 테크놀로지 이미다졸리딘계 금속 카르벤 복분해 촉매
WO2002014376A2 (en) 2000-08-10 2002-02-21 Trustees Of Boston College Recyclable metathesis catalysts
PL199412B1 (pl) 2002-10-15 2008-09-30 Boehringer Ingelheim Int Nowe kompleksy rutenu jako (pre)katalizatory reakcji metatezy, pochodne 2-alkoksy-5-nitrostyrenu jako związki pośrednie i sposób ich wytwarzania
WO2005016524A2 (de) * 2003-08-11 2005-02-24 Merck Patent Gmbh Immobilisierte immidazole und ruthenium-katalysatoren

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010014234A (ko) * 1997-06-27 2001-02-26 에프. 아. 프라저, 에른스트 알테르 (에. 알테르), 한스 페터 비틀린 (하. 페. 비틀린), 피. 랍 보프, 브이. 스펜글러, 페. 아에글러 루테늄 및 오스뮴 촉매
WO2005094345A2 (en) * 2004-03-29 2005-10-13 California Institute Of Technology Latent, high-activity olefin metathesis catalysts containing an n-heterocyclic carbene ligand

Also Published As

Publication number Publication date
EP2044095B1 (en) 2009-08-26
CA2655575C (en) 2014-07-29
TWI422430B (zh) 2014-01-11
BRPI0713871A2 (pt) 2012-12-18
IL195868A (en) 2013-02-28
MX2008016069A (es) 2009-01-15
CN101479283B (zh) 2012-07-04
ATE440852T1 (de) 2009-09-15
EP2044095A1 (en) 2009-04-08
KR20090024737A (ko) 2009-03-09
DE602007002199D1 (de) 2009-10-08
JP5323691B2 (ja) 2013-10-23
US7781586B2 (en) 2010-08-24
BRPI0713871B1 (pt) 2016-12-06
AU2007263808A1 (en) 2008-01-03
AU2007263808B2 (en) 2012-04-19
CA2655575A1 (en) 2008-01-03
US20080021219A1 (en) 2008-01-24
TW200810832A (en) 2008-03-01
ES2329424T3 (es) 2009-11-25
IL195868A0 (en) 2009-09-01
CN101479283A (zh) 2009-07-08
JP2009541414A (ja) 2009-11-26
WO2008000644A1 (en) 2008-01-03

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