KR101461682B1 - 메타세시스 반응용 촉매로서의 신규한 루테늄 착체 - Google Patents

메타세시스 반응용 촉매로서의 신규한 루테늄 착체 Download PDF

Info

Publication number
KR101461682B1
KR101461682B1 KR1020087031644A KR20087031644A KR101461682B1 KR 101461682 B1 KR101461682 B1 KR 101461682B1 KR 1020087031644 A KR1020087031644 A KR 1020087031644A KR 20087031644 A KR20087031644 A KR 20087031644A KR 101461682 B1 KR101461682 B1 KR 101461682B1
Authority
KR
South Korea
Prior art keywords
alkyl
mmol
rucl
formula
imh
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020087031644A
Other languages
English (en)
Korean (ko)
Other versions
KR20090024737A (ko
Inventor
쿠르트 퓐테너
미켈란젤로 스칼로네
Original Assignee
에프. 호프만-라 로슈 아게
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 에프. 호프만-라 로슈 아게 filed Critical 에프. 호프만-라 로슈 아게
Publication of KR20090024737A publication Critical patent/KR20090024737A/ko
Application granted granted Critical
Publication of KR101461682B1 publication Critical patent/KR101461682B1/ko
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046Ruthenium compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2265Carbenes or carbynes, i.e.(image)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2265Carbenes or carbynes, i.e.(image)
    • B01J31/2269Heterocyclic carbenes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2265Carbenes or carbynes, i.e.(image)
    • B01J31/2269Heterocyclic carbenes
    • B01J31/2273Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00Preparation of carboxylic acid nitriles
    • C07C253/30Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54Metathesis reactions, e.g. olefin metathesis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/821Ruthenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyrrole Compounds (AREA)
KR1020087031644A 2006-06-30 2007-06-18 메타세시스 반응용 촉매로서의 신규한 루테늄 착체 Expired - Fee Related KR101461682B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP06116373 2006-06-30
EP06116373.9 2006-06-30
PCT/EP2007/055995 WO2008000644A1 (en) 2006-06-30 2007-06-18 New ruthenium complexes as catalysts for metahesis reactions

Publications (2)

Publication Number Publication Date
KR20090024737A KR20090024737A (ko) 2009-03-09
KR101461682B1 true KR101461682B1 (ko) 2014-11-13

Family

ID=38475927

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020087031644A Expired - Fee Related KR101461682B1 (ko) 2006-06-30 2007-06-18 메타세시스 반응용 촉매로서의 신규한 루테늄 착체

Country Status (15)

Country Link
US (1) US7781586B2 (enExample)
EP (1) EP2044095B1 (enExample)
JP (1) JP5323691B2 (enExample)
KR (1) KR101461682B1 (enExample)
CN (1) CN101479283B (enExample)
AT (1) ATE440852T1 (enExample)
AU (1) AU2007263808B2 (enExample)
BR (1) BRPI0713871B1 (enExample)
CA (1) CA2655575C (enExample)
DE (1) DE602007002199D1 (enExample)
ES (1) ES2329424T3 (enExample)
IL (1) IL195868A (enExample)
MX (1) MX2008016069A (enExample)
TW (1) TWI422430B (enExample)
WO (1) WO2008000644A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5314753B2 (ja) * 2008-05-22 2013-10-16 リミテッド・ライアビリティ・カンパニー・”ユナイテッド・リサーチ・アンド・デベロップメント・センター” ジシクロペンタジエンのメタセシス重合触媒、その製造方法および重合方法
US8809563B2 (en) 2009-11-09 2014-08-19 Exxonmobil Chemical Patents Inc. Metathesis catalyst and process for use thereof
US9024034B2 (en) 2009-11-09 2015-05-05 Exxonmobil Chemical Patents Inc. Metathesis catalysts and processes for use thereof
WO2011100022A2 (en) * 2010-02-12 2011-08-18 Exxonmobil Chemical Patents Inc. Metathesis catalyst and process for use thereof
WO2012167171A2 (en) * 2011-06-03 2012-12-06 Massachusetts Institute Of Technology Z-selective ring-closing metathesis reactions
EP2639219B1 (en) * 2012-03-14 2016-08-10 Umicore AG & Co. KG Ruthenium-based metathesis catalysts and precursors for their preparation
WO2014004089A1 (en) * 2012-06-28 2014-01-03 Exxonmobil Chemical Patents Inc. Metathesis catalyst and process for use thereof
EP3008078B1 (en) 2013-06-12 2018-12-19 Trustees of Boston College Catalysts for efficient z-selective metathesis
CA3079768C (en) * 2017-12-01 2024-03-19 Tendyron Corporation Data transmitting circuit and apparatus, and data receiving circuit and apparatus

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010014234A (ko) * 1997-06-27 2001-02-26 에프. 아. 프라저, 에른스트 알테르 (에. 알테르), 한스 페터 비틀린 (하. 페. 비틀린), 피. 랍 보프, 브이. 스펜글러, 페. 아에글러 루테늄 및 오스뮴 촉매
WO2005094345A2 (en) * 2004-03-29 2005-10-13 California Institute Of Technology Latent, high-activity olefin metathesis catalysts containing an n-heterocyclic carbene ligand

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR0010389B1 (pt) 1999-05-24 2011-05-17 catalisadores de metátese de carbeno metálico a base de imidazolidina.
WO2002014376A2 (en) 2000-08-10 2002-02-21 Trustees Of Boston College Recyclable metathesis catalysts
PL199412B1 (pl) 2002-10-15 2008-09-30 Boehringer Ingelheim Int Nowe kompleksy rutenu jako (pre)katalizatory reakcji metatezy, pochodne 2-alkoksy-5-nitrostyrenu jako związki pośrednie i sposób ich wytwarzania
JP2007501695A (ja) * 2003-08-11 2007-02-01 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング 固定化イミダゾールおよびルテニウム触媒

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010014234A (ko) * 1997-06-27 2001-02-26 에프. 아. 프라저, 에른스트 알테르 (에. 알테르), 한스 페터 비틀린 (하. 페. 비틀린), 피. 랍 보프, 브이. 스펜글러, 페. 아에글러 루테늄 및 오스뮴 촉매
WO2005094345A2 (en) * 2004-03-29 2005-10-13 California Institute Of Technology Latent, high-activity olefin metathesis catalysts containing an n-heterocyclic carbene ligand

Also Published As

Publication number Publication date
US20080021219A1 (en) 2008-01-24
TWI422430B (zh) 2014-01-11
CN101479283A (zh) 2009-07-08
EP2044095B1 (en) 2009-08-26
BRPI0713871B1 (pt) 2016-12-06
IL195868A0 (en) 2009-09-01
WO2008000644A1 (en) 2008-01-03
CA2655575A1 (en) 2008-01-03
TW200810832A (en) 2008-03-01
BRPI0713871A2 (pt) 2012-12-18
AU2007263808B2 (en) 2012-04-19
CA2655575C (en) 2014-07-29
ATE440852T1 (de) 2009-09-15
AU2007263808A1 (en) 2008-01-03
JP2009541414A (ja) 2009-11-26
EP2044095A1 (en) 2009-04-08
US7781586B2 (en) 2010-08-24
KR20090024737A (ko) 2009-03-09
CN101479283B (zh) 2012-07-04
JP5323691B2 (ja) 2013-10-23
DE602007002199D1 (de) 2009-10-08
ES2329424T3 (es) 2009-11-25
MX2008016069A (es) 2009-01-15
IL195868A (en) 2013-02-28

Similar Documents

Publication Publication Date Title
KR101461682B1 (ko) 메타세시스 반응용 촉매로서의 신규한 루테늄 착체
JP5546861B2 (ja) 新規メタセシス触媒
KR101216900B1 (ko) 복분해 반응을 위한 촉매로서의 신규 루테늄 착물
AU2008340430A1 (en) Process for the preparation of a macrocycle
Ruiz et al. Ru-catalyzed CH functionalization of phenylglycine derivatives: Synthesis of isoquinoline-1-carboxylates and isoindoline-1-carboxylates
JP5414889B2 (ja) ルテニウムメタセシス錯体触媒の製造方法
Lin et al. Asymmetric synthesis of chiral β-hydroxy-α-amino acid derivatives by organocatalytic aldol reactions of isocyanoesters with β, γ-unsaturated α-ketoesters
JP2015532268A (ja) メタセシス反応における低い触媒充填
Müller et al. Desymmetrization of spiro-activated meso-cyclopropanes via nucleophilic substitution
CA2604257A1 (en) Process for the preparation of 9,10-dehydro-12,13-desoxyepothilone derivatives
JP4586195B2 (ja) 光学活性リン化合物及びその製造方法
EP1489106A1 (en) Arene-ruthenium complexes immobilized on polymers, catalysts consisting of the complexes, and processes for organic syntheses with the same

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

A201 Request for examination
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E90F Notification of reason for final refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

FPAY Annual fee payment

Payment date: 20170929

Year of fee payment: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

FPAY Annual fee payment

Payment date: 20180928

Year of fee payment: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20211108

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20211108

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000