CN101479283B - 作为复分解反应催化剂的钌络合物 - Google Patents

作为复分解反应催化剂的钌络合物 Download PDF

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Publication number
CN101479283B
CN101479283B CN2007800245149A CN200780024514A CN101479283B CN 101479283 B CN101479283 B CN 101479283B CN 2007800245149 A CN2007800245149 A CN 2007800245149A CN 200780024514 A CN200780024514 A CN 200780024514A CN 101479283 B CN101479283 B CN 101479283B
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China
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alkyl
mmol
compound
toluene
formula
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CN2007800245149A
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Chinese (zh)
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CN101479283A (zh
Inventor
K·普恩特纳
M·司佳隆
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Ascletis Pharmacuticals Co ltd
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F Hoffmann La Roche AG
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyrrole Compounds (AREA)
CN2007800245149A 2006-06-30 2007-06-18 作为复分解反应催化剂的钌络合物 Active CN101479283B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP06116373.9 2006-06-30
EP06116373 2006-06-30
PCT/EP2007/055995 WO2008000644A1 (en) 2006-06-30 2007-06-18 New ruthenium complexes as catalysts for metahesis reactions

Publications (2)

Publication Number Publication Date
CN101479283A CN101479283A (zh) 2009-07-08
CN101479283B true CN101479283B (zh) 2012-07-04

Family

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Family Applications (1)

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CN2007800245149A Active CN101479283B (zh) 2006-06-30 2007-06-18 作为复分解反应催化剂的钌络合物

Country Status (15)

Country Link
US (1) US7781586B2 (enExample)
EP (1) EP2044095B1 (enExample)
JP (1) JP5323691B2 (enExample)
KR (1) KR101461682B1 (enExample)
CN (1) CN101479283B (enExample)
AT (1) ATE440852T1 (enExample)
AU (1) AU2007263808B2 (enExample)
BR (1) BRPI0713871B1 (enExample)
CA (1) CA2655575C (enExample)
DE (1) DE602007002199D1 (enExample)
ES (1) ES2329424T3 (enExample)
IL (1) IL195868A (enExample)
MX (1) MX2008016069A (enExample)
TW (1) TWI422430B (enExample)
WO (1) WO2008000644A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2280033B1 (en) * 2008-05-22 2014-03-12 Limited Liability Company "United Research and Development Centre" Dicyclopentadiene metathesis polymerisation catalyst
US8809563B2 (en) 2009-11-09 2014-08-19 Exxonmobil Chemical Patents Inc. Metathesis catalyst and process for use thereof
US9024034B2 (en) 2009-11-09 2015-05-05 Exxonmobil Chemical Patents Inc. Metathesis catalysts and processes for use thereof
CA2785897C (en) * 2010-02-12 2014-01-28 Exxonmobil Chemical Patents Inc. Metathesis catalyst and process for use thereof
WO2012167171A2 (en) * 2011-06-03 2012-12-06 Massachusetts Institute Of Technology Z-selective ring-closing metathesis reactions
EP2639219B1 (en) * 2012-03-14 2016-08-10 Umicore AG & Co. KG Ruthenium-based metathesis catalysts and precursors for their preparation
CN104394987A (zh) * 2012-06-28 2015-03-04 埃克森美孚化学专利公司 复分解催化剂及其使用方法
EP3008078B1 (en) 2013-06-12 2018-12-19 Trustees of Boston College Catalysts for efficient z-selective metathesis
WO2019105338A1 (zh) * 2017-12-01 2019-06-06 天地融科技股份有限公司 数据发送电路、数据接收电路以及装置

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX210210B (es) * 1997-06-27 2002-09-06 Ciba Sc Holding Ag Nuevos catalizadores
CN1213032C (zh) 1999-05-24 2005-08-03 加州理工学院 咪唑烷基金属卡宾易位催化剂
CA2419485C (en) 2000-08-10 2007-10-30 The Trustees Of Boston College Recyclable metathesis catalysts
PL199412B1 (pl) 2002-10-15 2008-09-30 Boehringer Ingelheim Int Nowe kompleksy rutenu jako (pre)katalizatory reakcji metatezy, pochodne 2-alkoksy-5-nitrostyrenu jako związki pośrednie i sposób ich wytwarzania
WO2005016524A2 (de) * 2003-08-11 2005-02-24 Merck Patent Gmbh Immobilisierte immidazole und ruthenium-katalysatoren
WO2005094345A2 (en) * 2004-03-29 2005-10-13 California Institute Of Technology Latent, high-activity olefin metathesis catalysts containing an n-heterocyclic carbene ligand

Also Published As

Publication number Publication date
EP2044095A1 (en) 2009-04-08
BRPI0713871A2 (pt) 2012-12-18
US20080021219A1 (en) 2008-01-24
BRPI0713871B1 (pt) 2016-12-06
ES2329424T3 (es) 2009-11-25
US7781586B2 (en) 2010-08-24
DE602007002199D1 (de) 2009-10-08
TW200810832A (en) 2008-03-01
ATE440852T1 (de) 2009-09-15
TWI422430B (zh) 2014-01-11
CA2655575A1 (en) 2008-01-03
IL195868A (en) 2013-02-28
KR20090024737A (ko) 2009-03-09
IL195868A0 (en) 2009-09-01
MX2008016069A (es) 2009-01-15
AU2007263808A1 (en) 2008-01-03
JP2009541414A (ja) 2009-11-26
AU2007263808B2 (en) 2012-04-19
CA2655575C (en) 2014-07-29
EP2044095B1 (en) 2009-08-26
WO2008000644A1 (en) 2008-01-03
JP5323691B2 (ja) 2013-10-23
CN101479283A (zh) 2009-07-08
KR101461682B1 (ko) 2014-11-13

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Application publication date: 20090708

Assignee: ASCLETIS BIOSCIENCE Co.,Ltd.

Assignor: F. HOFFMANN-LA ROCHE AG

Contract record no.: 2015990000084

Denomination of invention: New ruthenium complexes as catalysts for metahesis reactions

Granted publication date: 20120704

License type: Exclusive License

Record date: 20150227

TR01 Transfer of patent right

Effective date of registration: 20201203

Address after: No.1 Yunhai Road, Lihai Town, Binhai New Town, Shaoxing City, Zhejiang Province

Patentee after: ASCLETIS PHARMACUTICALS Co.,Ltd.

Address before: Basel, Switzerland

Patentee before: F. HOFFMANN-LA ROCHE AG

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Effective date of registration: 20240506

Granted publication date: 20120704

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Granted publication date: 20120704