KR101354345B1 - 자외선-차단제용 첨가제 - Google Patents
자외선-차단제용 첨가제 Download PDFInfo
- Publication number
- KR101354345B1 KR101354345B1 KR1020077009828A KR20077009828A KR101354345B1 KR 101354345 B1 KR101354345 B1 KR 101354345B1 KR 1020077009828 A KR1020077009828 A KR 1020077009828A KR 20077009828 A KR20077009828 A KR 20077009828A KR 101354345 B1 KR101354345 B1 KR 101354345B1
- Authority
- KR
- South Korea
- Prior art keywords
- alkyl
- formula
- polymer particles
- group
- ultraviolet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- GAKJJENIQZWNKM-UHFFFAOYSA-N C=Cc1ccc(COc(cc2)ccc2-c2nc3ccccc3[o]2)cc1 Chemical compound C=Cc1ccc(COc(cc2)ccc2-c2nc3ccccc3[o]2)cc1 GAKJJENIQZWNKM-UHFFFAOYSA-N 0.000 description 1
- KIYDBSJJIUBVEG-UHFFFAOYSA-N CC(C(OCC(COc(cc1)ccc1-c1nc2ccccc2[o]1)O)=O)=C Chemical compound CC(C(OCC(COc(cc1)ccc1-c1nc2ccccc2[o]1)O)=O)=C KIYDBSJJIUBVEG-UHFFFAOYSA-N 0.000 description 1
- UAIPWTHUKCAMEF-UHFFFAOYSA-N CC(C(Oc(cc1)ccc1-c1nc2ccccc2[o]1)=O)=C Chemical compound CC(C(Oc(cc1)ccc1-c1nc2ccccc2[o]1)=O)=C UAIPWTHUKCAMEF-UHFFFAOYSA-N 0.000 description 1
- COMQDHAIBGMIGD-UHFFFAOYSA-N CCC(C)(C)c1ccc2[o]c(-c(cc3)ccc3OC(C(C)=C)=O)nc2c1 Chemical compound CCC(C)(C)c1ccc2[o]c(-c(cc3)ccc3OC(C(C)=C)=O)nc2c1 COMQDHAIBGMIGD-UHFFFAOYSA-N 0.000 description 1
- VGYBFZKDBMRAHU-UHFFFAOYSA-N CCC(C)(C)c1ccc2[o]c(-c(cc3)ccc3OCC(COC(C(C)=C)=O)O)nc2c1 Chemical compound CCC(C)(C)c1ccc2[o]c(-c(cc3)ccc3OCC(COC(C(C)=C)=O)O)nc2c1 VGYBFZKDBMRAHU-UHFFFAOYSA-N 0.000 description 1
- UGQBESQZVQLRAZ-UHFFFAOYSA-N CCC(C)(C)c1ccc2[o]c(-c(cc3)ccc3OCc3ccc(C=C)cc3)nc2c1 Chemical compound CCC(C)(C)c1ccc2[o]c(-c(cc3)ccc3OCc3ccc(C=C)cc3)nc2c1 UGQBESQZVQLRAZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- A61K8/8117—Homopolymers or copolymers of aromatic olefines, e.g. polystyrene; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
- C08F220/36—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/57—Compounds covalently linked to a(n inert) carrier molecule, e.g. conjugates, pro-fragrances
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04025930.1 | 2004-11-02 | ||
| EP04025930 | 2004-11-02 | ||
| PCT/EP2005/011458 WO2006048159A1 (en) | 2004-11-02 | 2005-10-26 | Additive for uv-sunscreen preparations |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20070083873A KR20070083873A (ko) | 2007-08-24 |
| KR101354345B1 true KR101354345B1 (ko) | 2014-01-22 |
Family
ID=35587533
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020077009828A Expired - Fee Related KR101354345B1 (ko) | 2004-11-02 | 2005-10-26 | 자외선-차단제용 첨가제 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8828365B2 (https=) |
| EP (1) | EP1807452B1 (https=) |
| JP (1) | JP2008518988A (https=) |
| KR (1) | KR101354345B1 (https=) |
| CN (1) | CN101052659B (https=) |
| AU (1) | AU2005300835B2 (https=) |
| BR (1) | BRPI0517930A (https=) |
| WO (1) | WO2006048159A1 (https=) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101395370B1 (ko) | 2004-01-22 | 2014-05-14 | 유니버시티 오브 마이애미 | 국소용 코-엔자임 큐10 제형 및 그의 사용 방법 |
| MX337408B (es) | 2007-03-22 | 2016-03-03 | Berg Llc | Formulaciones topicas que tienen biodisponibilidad aumentada. |
| FR2918269B1 (fr) * | 2007-07-06 | 2016-11-25 | Oreal | Composition de protection solaire contenant l'association d'un polymere semi-cristallin et de particules de latex creuses. |
| JP5109085B2 (ja) * | 2007-09-12 | 2012-12-26 | 旭硝子株式会社 | 蛍光発光性化合物、蛍光発光性重合体およびその製造方法 |
| MX2010011032A (es) | 2008-04-11 | 2011-03-01 | Cytotech Labs Llc Star | Metodos y uso de induccion de apoptosis en celulas cancerigenas. |
| US8394969B2 (en) | 2008-09-26 | 2013-03-12 | Merck Sharp & Dohme Corp. | Cyclic benzimidazole derivatives useful as anti-diabetic agents |
| EP2348857B1 (en) | 2008-10-22 | 2016-02-24 | Merck Sharp & Dohme Corp. | Novel cyclic benzimidazole derivatives useful anti-diabetic agents |
| EP2352374B1 (en) | 2008-10-29 | 2014-09-24 | Merck Sharp & Dohme Corp. | Novel cyclic benzimidazole derivatives useful anti-diabetic agents |
| US8329914B2 (en) | 2008-10-31 | 2012-12-11 | Merck Sharp & Dohme Corp | Cyclic benzimidazole derivatives useful as anti-diabetic agents |
| EP2416754A4 (en) * | 2009-04-10 | 2015-04-15 | Oréal L | UV-PROTECTION COMPOSITION AND METHOD OF USE |
| CN102481271A (zh) | 2009-05-11 | 2012-05-30 | 博格生物系统有限责任公司 | 利用表观代谢转变剂、多维细胞内分子或环境影响剂治疗代谢障碍的方法 |
| FR2948562B1 (fr) * | 2009-07-30 | 2011-09-23 | Prod Dentaires Pierre Rolland | Composition pour barriere dentaire comprenant au moins un monomere, au moins un systeme initiateur de polymerisation, et au moins un indicateur permettant le suivi de la reaction de polymerisation |
| TWI496587B (zh) * | 2009-09-29 | 2015-08-21 | Shiseido Co Ltd | Water-based emulsified composition |
| RU2500382C2 (ru) * | 2009-09-29 | 2013-12-10 | Шисейдо Компани Лтд. | Эмульсионная композиция "масло в воде" |
| JP2013520502A (ja) | 2010-02-25 | 2013-06-06 | メルク・シャープ・エンド・ドーム・コーポレイション | 有用な抗糖尿病薬である新規な環状ベンズイミダゾール誘導体 |
| SG10202010355PA (en) | 2010-03-12 | 2020-11-27 | Berg Llc | Intravenous formulations of coenzyme q10 (coq10) and methods of use thereof |
| EP3238704A1 (en) * | 2011-03-31 | 2017-11-01 | Rohm and Haas Company | Suncare compositions and methods |
| CA2832324C (en) | 2011-04-04 | 2022-03-15 | Berg Llc | Methods of treating central nervous system tumors |
| EP2720680B1 (en) | 2011-06-17 | 2020-02-12 | Berg LLC | Inhalable pharmaceutical compositions |
| US9255180B2 (en) | 2012-06-28 | 2016-02-09 | Johnson & Johnson Consumer Inc. | Ultraviolet radiation absorbing polyethers |
| US9469725B2 (en) * | 2012-06-28 | 2016-10-18 | Johnson & Johnson Consumer Inc. | Ultraviolet radiation absorbing polymers |
| US20140004057A1 (en) | 2012-06-28 | 2014-01-02 | Johnson & Johnson Consumer Companies, Inc. | Sunscreen compositions containing an ultraviolet radiation-absorbing polyester |
| CA2874898C (en) | 2012-06-28 | 2020-10-13 | Johnson & Johnson Consumer Companies, Inc. | Sunscreen compositions comprising a chromophore-functionalized polyehter, an anionic emulsifier, and a non-ionic emulsifier |
| BR102013007969A2 (pt) | 2013-04-03 | 2014-11-11 | Isp Do Brasil Ltda | Composições cosméticas e uso de ciclodextrina |
| NZ713868A (en) | 2013-04-08 | 2021-12-24 | Berg Llc | Treatment of cancer using coenzyme q10 combination therapies |
| KR102370843B1 (ko) | 2013-09-04 | 2022-03-04 | 버그 엘엘씨 | 코엔자임 q10의 연속주입에 의한 암치료 방법 |
| US9731151B2 (en) | 2014-04-08 | 2017-08-15 | Honeywell International Inc. | Sprayable sunscreen compositions and methods |
| US10874603B2 (en) | 2014-05-12 | 2020-12-29 | Johnson & Johnson Consumer Inc. | Sunscreen compositions containing a UV-absorbing polyglycerol and a non-UV-absorbing polyglycerol |
| US9744111B2 (en) * | 2014-07-11 | 2017-08-29 | Mary Kay Inc. | Sunscreen compositions and methods of their use |
| WO2016200394A1 (en) | 2015-06-12 | 2016-12-15 | Transitions Optical, Inc. | Alignment polymers |
| US10875833B2 (en) * | 2015-06-12 | 2020-12-29 | Transitions Optical, Inc. | Alignment compounds |
| EP3331489A1 (en) * | 2015-08-07 | 2018-06-13 | Rohm and Haas Company | Compositions containing voided latex particles and inorganic metal oxides |
| WO2017087576A1 (en) | 2015-11-16 | 2017-05-26 | Berg Llc | Methods of treatment of temozolomide-resistant glioma using coenzyme q10 |
| CN108367044A (zh) * | 2015-12-16 | 2018-08-03 | 帝斯曼知识产权资产管理有限公司 | 新用途 |
| CN105586769A (zh) * | 2016-02-29 | 2016-05-18 | 苏州纺友新材料有限公司 | 一种苯并唑类防紫外线整理剂及其制备方法 |
| US20190175468A1 (en) | 2016-06-16 | 2019-06-13 | Johnson & Johnson Consumer Inc. | Sunscreen compositions containing a combination of a linear ultraviolet radiation-absorbing polyether and other ultraviolet-screening compounds |
| US10596087B2 (en) | 2016-10-05 | 2020-03-24 | Johnson & Johnson Consumer Inc. | Ultraviolet radiation absorbing polymer composition |
| KR102067514B1 (ko) * | 2017-02-16 | 2020-01-17 | 가톨릭대학교 산학협력단 | 생체 적합성 자외선 차단 고분자, 이를 포함하는 조성물 및 이의 제조방법 |
| CN107032743A (zh) * | 2017-05-06 | 2017-08-11 | 安徽绿风环保节能材料有限公司 | 一种露天游泳池地砖 |
| KR101857974B1 (ko) * | 2017-05-19 | 2018-06-29 | 주식회사 넥스필 | 자외선을 차단하는 필름의 제조방법 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4233430A (en) * | 1973-06-26 | 1980-11-11 | L'oreal | Anti-solar acrylamide derivative polymers, method of making the same and cosmetic compositions containing the same |
| US6123928A (en) * | 1992-12-21 | 2000-09-26 | Biophysica, Inc. | Sunblocking polymers and their novel formulations |
| WO2003068183A1 (en) | 2002-02-12 | 2003-08-21 | Dsm Ip Assets B.V. | Sunscreen compositions as well as dihydropyridines and dihydropyranes |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4115348A (en) * | 1974-09-03 | 1978-09-19 | Eastman Kodak Company | Multichromophoric ultraviolet stabilizers and their use in organic compositions |
| CA1043495A (fr) | 1976-07-29 | 1978-11-28 | Bernard Jacquet | Polymeres anti-solaires et compositions cosmetiques les contenant |
| FR2597336B1 (fr) * | 1986-01-10 | 1988-12-09 | Oreal | Nouvelles compositions de polymeres derives d'acrylamide substitue par des composes absorbant les radiations ultraviolettes, et leur application notamment dans la realisation de compositions cosmetiques destinees a proteger la peau contre les effets indesires des radiations ultraviolettes. |
| JPH03220213A (ja) * | 1988-08-30 | 1991-09-27 | Dainippon Ink & Chem Inc | 紫外線吸収剤共重合型非造膜性樹脂エマルジョンの製法ならびに該樹脂を含有する化粧料 |
| JP2784773B2 (ja) * | 1988-09-27 | 1998-08-06 | ナトコペイント株式会社 | 化粧料用紫外線吸収性重合体微粒子および該重合体微粒子の製造方法 |
| DE3922294C1 (https=) * | 1989-07-07 | 1991-01-03 | Eska Medical Luebeck Medizintechnik Gmbh & Co, 2400 Luebeck, De | |
| JPH0539327A (ja) * | 1991-08-02 | 1993-02-19 | Tokyo Keikaku:Kk | 水に良好に分散する紫外線吸収能を有する樹脂 |
| JPH05255655A (ja) * | 1992-03-12 | 1993-10-05 | Kanebo Ltd | 紫外線吸収剤 |
| JP3465031B2 (ja) * | 1994-04-28 | 2003-11-10 | 綜研化学株式会社 | 被覆顔料および化粧料 |
| GB9525513D0 (en) * | 1995-12-14 | 1996-02-14 | Lion Lab Plc | Measuring devices |
| KR20050025608A (ko) * | 2002-07-16 | 2005-03-14 | 디에스엠 아이피 어셋츠 비.브이. | 일광차단제 |
| EP1722863B1 (en) * | 2003-12-04 | 2012-02-08 | DSM IP Assets B.V. | Microcapsules with uv filter activity and process for producing them |
| EP1700825A1 (de) | 2004-12-23 | 2006-09-13 | Degussa AG | Oberflächenmodifizierte, strukturmodifizierte Titandioxide |
-
2005
- 2005-10-26 WO PCT/EP2005/011458 patent/WO2006048159A1/en not_active Ceased
- 2005-10-26 AU AU2005300835A patent/AU2005300835B2/en not_active Ceased
- 2005-10-26 CN CN2005800375533A patent/CN101052659B/zh not_active Expired - Fee Related
- 2005-10-26 JP JP2007539502A patent/JP2008518988A/ja active Pending
- 2005-10-26 KR KR1020077009828A patent/KR101354345B1/ko not_active Expired - Fee Related
- 2005-10-26 BR BRPI0517930-0A patent/BRPI0517930A/pt not_active IP Right Cessation
- 2005-10-26 EP EP05798132.6A patent/EP1807452B1/en not_active Expired - Lifetime
- 2005-10-26 US US11/666,666 patent/US8828365B2/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4233430A (en) * | 1973-06-26 | 1980-11-11 | L'oreal | Anti-solar acrylamide derivative polymers, method of making the same and cosmetic compositions containing the same |
| US6123928A (en) * | 1992-12-21 | 2000-09-26 | Biophysica, Inc. | Sunblocking polymers and their novel formulations |
| WO2003068183A1 (en) | 2002-02-12 | 2003-08-21 | Dsm Ip Assets B.V. | Sunscreen compositions as well as dihydropyridines and dihydropyranes |
Also Published As
| Publication number | Publication date |
|---|---|
| US8828365B2 (en) | 2014-09-09 |
| WO2006048159A1 (en) | 2006-05-11 |
| EP1807452B1 (en) | 2013-05-08 |
| AU2005300835B2 (en) | 2011-01-20 |
| US20080089852A1 (en) | 2008-04-17 |
| AU2005300835A1 (en) | 2006-05-11 |
| CN101052659A (zh) | 2007-10-10 |
| EP1807452A1 (en) | 2007-07-18 |
| KR20070083873A (ko) | 2007-08-24 |
| BRPI0517930A (pt) | 2008-10-21 |
| JP2008518988A (ja) | 2008-06-05 |
| CN101052659B (zh) | 2011-11-23 |
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