KR101237261B1 - 단일 반응기 내에서 메탈로센 및 신규 단일 부위 촉매성분으로 제조된 폴리올레핀 - Google Patents
단일 반응기 내에서 메탈로센 및 신규 단일 부위 촉매성분으로 제조된 폴리올레핀 Download PDFInfo
- Publication number
- KR101237261B1 KR101237261B1 KR1020077008279A KR20077008279A KR101237261B1 KR 101237261 B1 KR101237261 B1 KR 101237261B1 KR 1020077008279 A KR1020077008279 A KR 1020077008279A KR 20077008279 A KR20077008279 A KR 20077008279A KR 101237261 B1 KR101237261 B1 KR 101237261B1
- Authority
- KR
- South Korea
- Prior art keywords
- substituted
- catalyst
- metallocene
- component
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
- C08F4/80—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04105218.4 | 2004-10-21 | ||
| EP04105218A EP1650231A1 (en) | 2004-10-21 | 2004-10-21 | Polyolefins prepared from a metallocene and a new single site catalyst components in a single reactor |
| PCT/EP2005/055398 WO2006045738A1 (en) | 2004-10-21 | 2005-10-20 | Polyolefins prepared from a metallocene and a new single site catalyst components in a single reactor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20070068363A KR20070068363A (ko) | 2007-06-29 |
| KR101237261B1 true KR101237261B1 (ko) | 2013-02-27 |
Family
ID=34929742
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020077008279A Expired - Fee Related KR101237261B1 (ko) | 2004-10-21 | 2005-10-20 | 단일 반응기 내에서 메탈로센 및 신규 단일 부위 촉매성분으로 제조된 폴리올레핀 |
Country Status (7)
| Country | Link |
|---|---|
| US (3) | US8178634B2 (https=) |
| EP (2) | EP1650231A1 (https=) |
| JP (1) | JP2008517131A (https=) |
| KR (1) | KR101237261B1 (https=) |
| CN (1) | CN101044171A (https=) |
| EA (1) | EA017068B1 (https=) |
| WO (1) | WO2006045738A1 (https=) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1650236A1 (en) * | 2004-10-21 | 2006-04-26 | Total Petrochemicals Research Feluy | Activating agents for hafnium based metallocene components |
| KR101092572B1 (ko) | 2006-12-21 | 2011-12-13 | 주식회사 엘지화학 | 담지촉매를 이용한 폴리올레핀의 제조방법 |
| EP2003166A1 (en) * | 2007-06-12 | 2008-12-17 | Repsol Ypf S.A. | Polyethylene compositions and their use in the manufacture of pipes |
| EP2039720A1 (en) * | 2007-09-21 | 2009-03-25 | Total Petrochemicals Research Feluy | Pipes for transporting water containing chlorine. |
| US8436114B2 (en) | 2010-10-21 | 2013-05-07 | Exxonmobil Chemical Patents Inc. | Polyethylene and process for production thereof |
| US8507103B2 (en) | 2007-12-18 | 2013-08-13 | Exxonmobil Chemical Patents Inc. | Polyethylene and process for production thereof |
| US8431661B2 (en) | 2010-10-21 | 2013-04-30 | Exxonmobil Chemical Patents Inc. | Polyethylene and process for production thereof |
| KR101205473B1 (ko) | 2008-09-18 | 2012-11-27 | 주식회사 엘지화학 | 파이프용 올레핀계 중합체 수지 조성물 및 이로부터 제조되는 파이프 |
| KR20110061584A (ko) * | 2008-09-25 | 2011-06-09 | 바젤 폴리올레핀 게엠베하 | 내충격성 lldpe 조성물 및 이것으로 제조된 필름 |
| EP2382248B1 (en) | 2009-12-18 | 2012-11-28 | Total Research & Technology Feluy | Process for preparing a bimodal polyethylene product in a single loop reactor |
| CN102656198B (zh) | 2009-12-18 | 2014-05-28 | 道达尔石油化学产品研究弗吕公司 | 颗粒状双峰聚乙烯产物的制备方法 |
| WO2012096698A2 (en) * | 2010-10-21 | 2012-07-19 | Exxonmobil Chemical Patents Inc. | Polyethylene and process for production thereof |
| CN104072646B (zh) * | 2013-03-28 | 2016-11-02 | 中国石油天然气股份有限公司 | 一种乙烯气相聚合或共聚合催化剂组合物及其制备和应用 |
| WO2018046567A1 (en) | 2016-09-08 | 2018-03-15 | Total Research & Technology Feluy | Process for preparing polyethylene |
| EP3538569B1 (en) | 2016-11-08 | 2021-12-01 | Univation Technologies, LLC | Polyethylene composition |
| EP3538570B1 (en) | 2016-11-08 | 2022-05-18 | Univation Technologies, LLC | Polyethylene composition |
| SG11202002090SA (en) | 2017-09-11 | 2020-04-29 | Univation Tech Llc | Carbon black-containing bimodal polyethylene composition |
| US11302459B2 (en) | 2017-10-06 | 2022-04-12 | Exxonmobil Chemical Patents Inc. | Polyethylene extrudates and methods of making the same |
| KR102363189B1 (ko) | 2018-01-11 | 2022-02-15 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조 방법 |
| WO2019190898A1 (en) | 2018-03-28 | 2019-10-03 | Univation Technologies, Llc | Multimodal polyethylene composition |
| BR112022019213A2 (pt) | 2020-04-01 | 2022-11-08 | Dow Global Technologies Llc | Copolímero de polietileno de baixa densidade linear bimodal, filme, e, método para produzir o copolímero de polietileno de baixa densidade linear bimodal |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09291107A (ja) * | 1995-12-27 | 1997-11-11 | Basf Ag | ルイス塩基を含むメタロセン触媒系 |
| US6407188B1 (en) * | 1999-09-29 | 2002-06-18 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| WO2004060932A1 (ja) * | 2002-12-27 | 2004-07-22 | Mitsui Chemicals, Inc. | エチレン系重合体及びこれから得られる成形体 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| ES2071888T3 (es) * | 1990-11-12 | 1995-07-01 | Hoechst Ag | Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas. |
| ES2158567T3 (es) * | 1996-06-17 | 2001-09-01 | Exxonmobil Chem Patents Inc | Sistemas cataliticos de metales de transicion mixtos para la polimerizacion de olefinas. |
| DE19707236A1 (de) * | 1997-02-24 | 1998-08-27 | Targor Gmbh | Katalysatorzusammensetzung |
| DE19757540A1 (de) * | 1997-12-23 | 1999-06-24 | Hoechst Ag | Geträgertes Katalysatorsystem zur Polymerisation von Olefinen |
| ID26574A (id) * | 1998-03-12 | 2001-01-18 | Bp Chem Int Ltd | Katalis-katalis polimerisasi |
| CA2324310A1 (en) * | 1998-03-30 | 1999-10-07 | E.I. Du Pont De Nemours And Company | Polymerization of olefins |
| US6297338B1 (en) * | 1998-03-30 | 2001-10-02 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| DE19823871A1 (de) * | 1998-05-28 | 1999-12-02 | Aventis Res & Tech Gmbh & Co | Suspensionsphasenverfahren für die Polymerisation von Ethylen |
| JP2000191719A (ja) * | 1998-12-28 | 2000-07-11 | Mitsui Chemicals Inc | オレフィン重合用触媒並びにオレフィンの重合方法 |
| US6620896B1 (en) * | 1999-02-23 | 2003-09-16 | Eastman Chemical Company | Mixed olefin polymerization catalysts, processes employing such catalysts, and polymers obtained therefrom |
| GB9906296D0 (en) * | 1999-03-18 | 1999-05-12 | Bp Chem Int Ltd | Polymerisation catalysts |
| CN1939934B (zh) * | 1999-09-29 | 2010-09-01 | 纳幕尔杜邦公司 | 聚乙烯的制备 |
| JP4629939B2 (ja) * | 1999-09-29 | 2011-02-09 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 重合用二金属触媒系を用いたオレフィンの重合 |
| DE19960123A1 (de) * | 1999-12-13 | 2001-06-21 | Basf Ag | Verfahren zur homogenkatalytischen Herstellung von hochverzweigten amorphen Polyolefinen |
| GB0003363D0 (en) * | 2000-02-14 | 2000-04-05 | Bp Chem Int Ltd | Polymer blends |
| DE10017663A1 (de) * | 2000-04-08 | 2001-10-11 | Basf Ag | Verfahren zur Herstellung eines geträgerten Katalysators zur Polymerisation von Olefinen |
| EP1399491B1 (en) * | 2001-04-30 | 2006-08-23 | W.R. Grace & Co.-Conn. | Supported dual transition metal catalyst systems |
| US6815074B2 (en) * | 2001-05-30 | 2004-11-09 | Novartis Ag | Polymeric materials for making contact lenses |
| EP1403288A1 (en) * | 2002-09-27 | 2004-03-31 | ATOFINA Research | Dual site catalyst system comprising a hafnocene component for the production of bimodal polyolefins |
| ATE361323T1 (de) * | 2004-03-12 | 2007-05-15 | Saudi Basic Ind Corp | Katalysatorzusammensetzung für die polymerisation von olefinen und polymerisationsverfahren unter dessen verwendung |
| DE102004020524A1 (de) * | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| EP1650236A1 (en) * | 2004-10-21 | 2006-04-26 | Total Petrochemicals Research Feluy | Activating agents for hafnium based metallocene components |
-
2004
- 2004-10-21 EP EP04105218A patent/EP1650231A1/en not_active Withdrawn
-
2005
- 2005-10-20 US US11/665,716 patent/US8178634B2/en not_active Expired - Fee Related
- 2005-10-20 EA EA200700679A patent/EA017068B1/ru not_active IP Right Cessation
- 2005-10-20 WO PCT/EP2005/055398 patent/WO2006045738A1/en not_active Ceased
- 2005-10-20 CN CNA2005800362232A patent/CN101044171A/zh active Pending
- 2005-10-20 EP EP05799106A patent/EP1809675B1/en not_active Expired - Lifetime
- 2005-10-20 JP JP2007537275A patent/JP2008517131A/ja not_active Ceased
- 2005-10-20 KR KR1020077008279A patent/KR101237261B1/ko not_active Expired - Fee Related
-
2012
- 2012-03-28 US US13/433,025 patent/US8455386B2/en not_active Expired - Fee Related
-
2013
- 2013-04-24 US US13/869,528 patent/US8637421B2/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09291107A (ja) * | 1995-12-27 | 1997-11-11 | Basf Ag | ルイス塩基を含むメタロセン触媒系 |
| US6407188B1 (en) * | 1999-09-29 | 2002-06-18 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| WO2004060932A1 (ja) * | 2002-12-27 | 2004-07-22 | Mitsui Chemicals, Inc. | エチレン系重合体及びこれから得られる成形体 |
| KR20050091004A (ko) * | 2002-12-27 | 2005-09-14 | 미쓰이 가가쿠 가부시키가이샤 | 에틸렌계 중합체 및 그것으로부터 얻어지는 성형체 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1650231A1 (en) | 2006-04-26 |
| EP1809675B1 (en) | 2013-04-03 |
| EP1809675A1 (en) | 2007-07-25 |
| US8455386B2 (en) | 2013-06-04 |
| EA200700679A1 (ru) | 2007-10-26 |
| WO2006045738A1 (en) | 2006-05-04 |
| JP2008517131A (ja) | 2008-05-22 |
| KR20070068363A (ko) | 2007-06-29 |
| US20120245021A1 (en) | 2012-09-27 |
| CN101044171A (zh) | 2007-09-26 |
| EA017068B1 (ru) | 2012-09-28 |
| US8637421B2 (en) | 2014-01-28 |
| US8178634B2 (en) | 2012-05-15 |
| US20080108766A1 (en) | 2008-05-08 |
| US20130237405A1 (en) | 2013-09-12 |
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