KR101006989B1 - 우수한 내수성을 갖는 자외선 경화형 코팅 조성물 및 이를이용한 광섬유 - Google Patents

우수한 내수성을 갖는 자외선 경화형 코팅 조성물 및 이를이용한 광섬유 Download PDF

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KR101006989B1
KR101006989B1 KR1020080070232A KR20080070232A KR101006989B1 KR 101006989 B1 KR101006989 B1 KR 101006989B1 KR 1020080070232 A KR1020080070232 A KR 1020080070232A KR 20080070232 A KR20080070232 A KR 20080070232A KR 101006989 B1 KR101006989 B1 KR 101006989B1
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South Korea
Prior art keywords
coating composition
curable coating
independently
formula
acrylate
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KR1020080070232A
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English (en)
Korean (ko)
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KR20100009379A (ko
Inventor
김상환
김용민
최영진
민경범
최해욱
김민정
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에스에스씨피 주식회사
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Priority to KR1020080070232A priority Critical patent/KR101006989B1/ko
Priority to EP09798104A priority patent/EP2318359A4/de
Priority to PCT/KR2009/003893 priority patent/WO2010008201A2/en
Priority to CN2009801364500A priority patent/CN102159538A/zh
Publication of KR20100009379A publication Critical patent/KR20100009379A/ko
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C271/00Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06Esters of carbamic acids
    • C07C271/08Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C271/00Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06Esters of carbamic acids
    • C07C271/08Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/10Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C271/20Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by nitrogen atoms not being part of nitro or nitroso groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C271/00Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06Esters of carbamic acids
    • C07C271/08Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/24Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a ring other than a six-membered aromatic ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C271/00Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06Esters of carbamic acids
    • C07C271/08Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/26Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring
    • C07C271/28Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring to a carbon atom of a non-condensed six-membered aromatic ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/022Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polycondensates with side or terminal unsaturations
    • C08F299/024Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polycondensates with side or terminal unsaturations the unsaturation being in acrylic or methacrylic groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67Unsaturated compounds having active hydrogen
    • C08G18/671Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7621Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/045Light guides
    • G02B1/048Light guides characterised by the cladding material

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Optics & Photonics (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
  • Paints Or Removers (AREA)
KR1020080070232A 2008-07-18 2008-07-18 우수한 내수성을 갖는 자외선 경화형 코팅 조성물 및 이를이용한 광섬유 KR101006989B1 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
KR1020080070232A KR101006989B1 (ko) 2008-07-18 2008-07-18 우수한 내수성을 갖는 자외선 경화형 코팅 조성물 및 이를이용한 광섬유
EP09798104A EP2318359A4 (de) 2008-07-18 2009-07-15 Uv-härtbare beschichtungszusammensetzung mit erhöhter wasserfestigkeit und glasfaser damit
PCT/KR2009/003893 WO2010008201A2 (en) 2008-07-18 2009-07-15 Uv-curable coating composition having improved water resistance and optical fiber using the same
CN2009801364500A CN102159538A (zh) 2008-07-18 2009-07-15 具有改进的耐水性的可紫外线固化的涂料组合物和使用该组合物的光学纤维

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020080070232A KR101006989B1 (ko) 2008-07-18 2008-07-18 우수한 내수성을 갖는 자외선 경화형 코팅 조성물 및 이를이용한 광섬유

Publications (2)

Publication Number Publication Date
KR20100009379A KR20100009379A (ko) 2010-01-27
KR101006989B1 true KR101006989B1 (ko) 2011-01-12

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KR1020080070232A KR101006989B1 (ko) 2008-07-18 2008-07-18 우수한 내수성을 갖는 자외선 경화형 코팅 조성물 및 이를이용한 광섬유

Country Status (4)

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EP (1) EP2318359A4 (de)
KR (1) KR101006989B1 (de)
CN (1) CN102159538A (de)
WO (1) WO2010008201A2 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101256456B1 (ko) * 2011-01-31 2013-04-19 에스에스씨피 주식회사 무용매 자외선 경화형 코팅 조성물 및 이를 이용한 접착제
CN103833956A (zh) * 2014-03-03 2014-06-04 黎明化工研究设计院有限责任公司 一种大分子量聚氨酯丙烯酸酯树脂及其制备方法
CN108603975B (zh) * 2015-12-16 2020-12-22 普睿司曼股份公司 具有提高的耐高温性的光纤

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050154076A1 (en) 2004-01-09 2005-07-14 Bayer Materialscience Llc UV curable coating composition
US20050209361A1 (en) 2004-03-17 2005-09-22 Bayer Materialscience Ag Preparation of new radiation-curing binders
US20060051591A1 (en) 2004-09-09 2006-03-09 Jan Weikard Radiation-curing binders and a process for their preparation
US20090324961A1 (en) 2005-05-02 2009-12-31 Victor Lu Radiation curable urethane (meth)acrylate polymer and adhesives formulated with them

Family Cites Families (11)

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Publication number Priority date Publication date Assignee Title
DE2064079C2 (de) * 1970-12-28 1982-09-09 Hoechst Ag, 6000 Frankfurt Photopolymerisierbares Gemisch
GB1428672A (en) * 1972-04-25 1976-03-17 Amalgamated Dental Co Ltd Polymerizable compositions suitable for dental use
DE3710279A1 (de) * 1987-03-28 1988-10-06 Hoechst Ag Polymerisierbare verbindungen und diese enthaltendes durch strahlung polymerisierbares gemisch
US5536529A (en) * 1989-05-11 1996-07-16 Borden, Inc. Ultraviolet radiation-curable coatings for optical fibers and optical fibers coated therewith
JP2893135B2 (ja) * 1990-10-19 1999-05-17 ジェイエスアール株式会社 光ファイバー被覆用液状硬化性樹脂組成物
JPH07138528A (ja) * 1993-11-16 1995-05-30 Dai Ichi Kogyo Seiyaku Co Ltd 放射線硬化性塗料組成物
JP3503740B2 (ja) * 1999-03-04 2004-03-08 住友ベークライト株式会社 異方導電性接着剤及びそれを用いた電子機器
JP2002220550A (ja) * 2001-01-26 2002-08-09 Jsr Corp 光ファイバ被覆用硬化性樹脂組成物およびその硬化物
JP4187566B2 (ja) * 2003-03-31 2008-11-26 三菱レイヨン株式会社 光ディスク用活性エネルギー線硬化性組成物、及び光ディスク
JP2005263988A (ja) * 2004-03-18 2005-09-29 Fuji Photo Film Co Ltd 重合性組成物及びそれを用いた画像記録材料
JP5419356B2 (ja) * 2008-01-11 2014-02-19 Jsr株式会社 光ファイバアップジャケット用液状硬化性樹脂組成物

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050154076A1 (en) 2004-01-09 2005-07-14 Bayer Materialscience Llc UV curable coating composition
US20050209361A1 (en) 2004-03-17 2005-09-22 Bayer Materialscience Ag Preparation of new radiation-curing binders
US20060051591A1 (en) 2004-09-09 2006-03-09 Jan Weikard Radiation-curing binders and a process for their preparation
US20090324961A1 (en) 2005-05-02 2009-12-31 Victor Lu Radiation curable urethane (meth)acrylate polymer and adhesives formulated with them

Also Published As

Publication number Publication date
KR20100009379A (ko) 2010-01-27
CN102159538A (zh) 2011-08-17
WO2010008201A3 (en) 2010-05-14
EP2318359A4 (de) 2011-08-10
WO2010008201A2 (en) 2010-01-21
EP2318359A2 (de) 2011-05-11

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