KR100635314B1 - 이소부텐의 선택적 이량체화 방법 - Google Patents

이소부텐의 선택적 이량체화 방법 Download PDF

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Publication number
KR100635314B1
KR100635314B1 KR1020027008135A KR20027008135A KR100635314B1 KR 100635314 B1 KR100635314 B1 KR 100635314B1 KR 1020027008135 A KR1020027008135 A KR 1020027008135A KR 20027008135 A KR20027008135 A KR 20027008135A KR 100635314 B1 KR100635314 B1 KR 100635314B1
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KR
South Korea
Prior art keywords
isobutene
weight
beta
trimethylpentene
zeolite
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Expired - Fee Related
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KR1020027008135A
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English (en)
Korean (ko)
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KR20020081231A (ko
Inventor
다카지하드엠.
길렌마르크
앨런폴더블유.
마티스게오르게스엠.케이.
Original Assignee
엑손모빌 케미칼 패턴츠 인코포레이티드
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Publication of KR20020081231A publication Critical patent/KR20020081231A/ko
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Publication of KR100635314B1 publication Critical patent/KR100635314B1/ko
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C9/00—Aliphatic saturated hydrocarbons
    • C07C9/14—Aliphatic saturated hydrocarbons with five to fifteen carbon atoms
    • C07C9/16—Branched-chain hydrocarbons
    • C07C9/21—2, 2, 4-Trimethylpentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020027008135A 1999-12-23 2000-12-20 이소부텐의 선택적 이량체화 방법 Expired - Fee Related KR100635314B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9930402.4A GB9930402D0 (en) 1999-12-23 1999-12-23 Selective removal of isobutene from C4 olefinic feedstocks
GB9930402.4 1999-12-23

Publications (2)

Publication Number Publication Date
KR20020081231A KR20020081231A (ko) 2002-10-26
KR100635314B1 true KR100635314B1 (ko) 2006-10-18

Family

ID=10866875

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020027008135A Expired - Fee Related KR100635314B1 (ko) 1999-12-23 2000-12-20 이소부텐의 선택적 이량체화 방법

Country Status (14)

Country Link
EP (1) EP1242342B1 (enExample)
JP (1) JP4691303B2 (enExample)
KR (1) KR100635314B1 (enExample)
CN (1) CN1221497C (enExample)
AR (1) AR027087A1 (enExample)
AT (1) ATE273259T1 (enExample)
AU (1) AU782012B2 (enExample)
BR (1) BR0016719A (enExample)
CA (1) CA2394030C (enExample)
DE (1) DE60012979T2 (enExample)
GB (1) GB9930402D0 (enExample)
MX (1) MXPA02006200A (enExample)
MY (1) MY125097A (enExample)
WO (1) WO2001046095A1 (enExample)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1184361B1 (en) * 2000-08-29 2004-05-19 BP Köln GmbH Process for the selective preparation of di-isobutylene from an i-butene-containing C4 stream
DE10250468A1 (de) * 2002-10-30 2004-05-19 Basf Ag Verfahren zur Herstellung von Oligomeren abgeleitet von Butenen
DE10302457B3 (de) * 2003-01-23 2004-10-07 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Butenoligomeren und tert.-Butylethern aus Isobuten-haltigen C4-Strömen
US7196238B2 (en) 2003-03-10 2007-03-27 Fortum Oyj Process for dimerizing light olefins
US7227047B2 (en) 2003-08-22 2007-06-05 Exxonmobil Chemical Patents Inc. Butadiene and isobutylene removal from olefinic streams
US7012167B2 (en) * 2003-10-08 2006-03-14 Lyondell Chemical Technology, L.P. Diisobutylene process
US7329788B2 (en) 2003-12-22 2008-02-12 Neste Oil Oyj Process for producing gasoline components
US20060111598A1 (en) * 2004-11-22 2006-05-25 Shaw-Chan Lin Diisobutylene process
US8299312B2 (en) 2005-10-28 2012-10-30 Neste Oil Oyj Process for dimerizing olefins
CN100430353C (zh) * 2006-12-26 2008-11-05 南京石油化工股份有限公司 从c4馏分中分离丁烯－1的方法
JP5767875B2 (ja) * 2011-06-29 2015-08-26 出光興産株式会社 混合ｃ４留分を原料とするジイソブチレンの製造方法
US8999013B2 (en) * 2011-11-01 2015-04-07 Saudi Arabian Oil Company Method for contemporaneously dimerizing and hydrating a feed having butene
US11613717B2 (en) 2017-07-27 2023-03-28 Sabic Global Technologies B.V. Method of producing a fuel additive
SG11202008334VA (en) 2018-03-19 2020-09-29 Sabic Global Technologies Bv Method of producing a fuel additive
WO2019180584A1 (en) * 2018-03-19 2019-09-26 Sabic Global Technologies B.V. Method of producing a fuel additive
SG11202008333XA (en) 2018-04-19 2020-09-29 Sabic Global Technologies Bv Method of producing a fuel additive
CN112020547A (zh) 2018-05-07 2020-12-01 沙特基础工业全球技术有限公司 生产燃料添加剂的方法
SG11202009479UA (en) 2018-05-07 2020-10-29 Sabic Global Technologies Bv Method of producing a fuel additive
CN112135809A (zh) 2018-05-18 2020-12-25 沙特基础工业全球技术有限公司 利用水合单元生产燃料添加剂的方法
EP3853192B1 (en) 2018-09-18 2024-03-13 SABIC Global Technologies B.V. Process for the production of fuel additives
US20210395178A1 (en) * 2018-10-31 2021-12-23 Lummus Technology Llc Selective dimerization and etherification of isobutylene via catalytic distillation
EP3883909A1 (en) 2018-11-20 2021-09-29 SABIC Global Technologies B.V. Process and system for producing ethylene and at least one of butanol and an alkyl tert-butyl ether
EP3917899A1 (en) * 2019-01-31 2021-12-08 Basf Se Catalyzed process for the dimerization of alkenes
US12264123B2 (en) 2019-03-08 2025-04-01 Sabic Global Technologies B.V. Method of producing a fuel additive
CN111675592A (zh) * 2020-05-31 2020-09-18 南京克米斯璀新能源科技有限公司 一种碳四烯烃中异丁烯选择性叠合的方法及设备
US20240166776A1 (en) * 2022-11-23 2024-05-23 Braskem S.A. Use of proton-form zeolite catalyst to produce light-polyisobutylene

Family Cites Families (15)

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US2276199A (en) * 1940-11-22 1942-03-10 Universal Oil Prod Co Production of iso-octane
JPS54138507A (en) * 1978-04-17 1979-10-27 Kuraray Co Ltd Preparation of diisobutene
US4324940A (en) * 1980-04-09 1982-04-13 Mobil Oil Corporation Shape selective acid catalyzed reactions of olefins over crystalline zeolites
JPS57108023A (en) * 1980-12-26 1982-07-05 Toa Nenryo Kogyo Kk Oligomerization catalyst for isobutene
JPS58164523A (ja) * 1982-03-26 1983-09-29 Toa Nenryo Kogyo Kk イソブテンの低重合方法
JPS59227830A (ja) * 1983-06-10 1984-12-21 Toa Nenryo Kogyo Kk イソブテンの低重合法
JPH03152242A (ja) * 1989-11-06 1991-06-28 Nissan Motor Co Ltd 複数幅取り織機の緯糸張力緩和装置
GB9012725D0 (en) * 1990-06-07 1990-08-01 Exxon Chemical Patents Inc Process for catalytic conversion of olefins
US5091590A (en) * 1990-08-22 1992-02-25 Mobil Oil Corporation Ether production with staged reaction of olefins
CA2128624C (en) * 1992-01-30 2001-11-20 Georges M. K. Mathys Alkene oligomerization
US5401429A (en) * 1993-04-01 1995-03-28 Minnesota Mining And Manufacturing Company Azeotropic compositions containing perfluorinated cycloaminoether
US5618878A (en) * 1995-04-07 1997-04-08 Dow Corning Corporation Hydrogen silsesquioxane resin coating composition
AU2680497A (en) * 1996-03-27 1997-10-17 Airedale Sports & Technology, Inc. Table tennis rubber solvent and adhesive systems
ES2205253T3 (es) * 1996-09-09 2004-05-01 Catalytic Distillation Technologies Alquilacion de compuestos aromaticos organicos usando catalizadores de zeolitas beta.
CN1203031C (zh) * 1998-10-16 2005-05-25 福图石油及煤气公司 烯烃原料二聚和制造燃料组分的方法

Also Published As

Publication number Publication date
AU2447601A (en) 2001-07-03
MY125097A (en) 2006-07-31
CN1221497C (zh) 2005-10-05
ATE273259T1 (de) 2004-08-15
KR20020081231A (ko) 2002-10-26
EP1242342B1 (en) 2004-08-11
EP1242342A1 (en) 2002-09-25
DE60012979D1 (de) 2004-09-16
GB9930402D0 (en) 2000-02-16
CA2394030A1 (en) 2001-06-28
DE60012979T2 (de) 2005-07-28
CN1433390A (zh) 2003-07-30
AR027087A1 (es) 2003-03-12
BR0016719A (pt) 2002-09-03
CA2394030C (en) 2009-01-20
MXPA02006200A (es) 2004-02-26
WO2001046095A1 (en) 2001-06-28
JP2004505008A (ja) 2004-02-19
JP4691303B2 (ja) 2011-06-01
AU782012B2 (en) 2005-06-30

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