KR100630979B1 - 1,3-프로판디올의 정제 방법 - Google Patents

1,3-프로판디올의 정제 방법 Download PDF

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Publication number
KR100630979B1
KR100630979B1 KR1020017002079A KR20017002079A KR100630979B1 KR 100630979 B1 KR100630979 B1 KR 100630979B1 KR 1020017002079 A KR1020017002079 A KR 1020017002079A KR 20017002079 A KR20017002079 A KR 20017002079A KR 100630979 B1 KR100630979 B1 KR 100630979B1
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KR
South Korea
Prior art keywords
propanediol
acid catalyst
acid
impurities
catalyst
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Expired - Fee Related
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KR1020017002079A
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English (en)
Korean (ko)
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KR20010072753A (ko
Inventor
하리 바부 선카라
로버트 존2세 우마일
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이 아이 듀폰 디 네모아 앤드 캄파니
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Publication of KR20010072753A publication Critical patent/KR20010072753A/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/88—Separation; Purification; Use of additives, e.g. for stabilisation by treatment giving rise to a chemical modification of at least one compound

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyethers (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
KR1020017002079A 1998-08-18 1999-08-18 1,3-프로판디올의 정제 방법 Expired - Fee Related KR100630979B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US9693998P 1998-08-18 1998-08-18
US60/096,939 1998-08-18

Publications (2)

Publication Number Publication Date
KR20010072753A KR20010072753A (ko) 2001-07-31
KR100630979B1 true KR100630979B1 (ko) 2006-10-04

Family

ID=22259837

Family Applications (1)

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KR1020017002079A Expired - Fee Related KR100630979B1 (ko) 1998-08-18 1999-08-18 1,3-프로판디올의 정제 방법

Country Status (15)

Country Link
US (1) US6235948B1 (enExample)
EP (1) EP1105363B1 (enExample)
JP (1) JP2003526605A (enExample)
KR (1) KR100630979B1 (enExample)
CN (1) CN1190399C (enExample)
AR (1) AR020217A1 (enExample)
AT (1) ATE259341T1 (enExample)
AU (1) AU5490199A (enExample)
BR (1) BR9914293A (enExample)
CA (1) CA2339185A1 (enExample)
DE (1) DE69914773T2 (enExample)
ES (1) ES2214043T3 (enExample)
TR (1) TR200100559T2 (enExample)
TW (1) TW506963B (enExample)
WO (1) WO2000010953A1 (enExample)

Families Citing this family (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6342646B1 (en) 1999-07-30 2002-01-29 E. I. Du Pont De Nemours And Company Catalytic hydrogenation of 3-hydroxypropanal to 1,3-propanediol
CA2389578C (en) * 1999-12-17 2010-08-03 E.I. Du Pont De Nemours And Company Production of polytrimethylene ether glycol and copolymers thereof
DE60030880T2 (de) 1999-12-17 2007-04-26 E.I. Dupont De Nemours And Co., Wilmington Kontinuierliches verfahren zur herstellung von polytrimethylenetherglykol
US6562457B1 (en) 2001-10-31 2003-05-13 E. I. Du Pont De Nemours And Company Polyether ester elastomer comprising polytrimethylene ether ester soft segment and tetramethylene ester hard segment
US6599625B2 (en) 2001-10-31 2003-07-29 E. I. Du Pont De Nemours And Company Polyether ester elastomer comprising polytrimethylene ether ester soft segment and trimethylene ester hard segment
US6693222B2 (en) 2002-02-12 2004-02-17 E. I. Du Pont De Nemours And Company Process for splitting water-soluble ethers
US6852823B2 (en) 2002-08-09 2005-02-08 E. I. Du Pont De Nemours And Company Polyurethane and polyurethane-urea elastomers from polytrimethylene ether glycol
US6972346B2 (en) * 2002-11-01 2005-12-06 Shell Oil Company Solid acid catalyzed reactive stripping of impurities formed during the production of 1, 3-propanediol
US6969779B2 (en) * 2002-11-01 2005-11-29 Shell Oil Company Method for removal of MW176 cyclic acetal formed during the production of 1,3-propanediol
WO2004061169A1 (en) * 2002-12-23 2004-07-22 E. I. Du Pont De Nemours And Company Poly(trimethylene terephthalate) bicomponent fiber process
US20040225107A1 (en) * 2003-05-06 2004-11-11 Sunkara Hari Babu Polytrimethylene ether glycol with excellent quality from biochemically-derived 1,3-propanediol
CA2522774A1 (en) * 2003-05-06 2004-11-25 E. I. Du Pont De Nemours And Company Hydrogenation of biochemically derived 1,3-propanediol
US7323539B2 (en) 2003-05-06 2008-01-29 E. I. Du Pont De Nemours And Company Polytrimethylene ether glycol and polytrimethylene ether ester with excellent quality
US7009082B2 (en) * 2003-05-06 2006-03-07 E.I. Du Pont De Nemours And Company Removal of color bodies from polytrimethylene ether glycol polymers
US7745668B2 (en) * 2003-05-06 2010-06-29 E. I. Du Pont De Nemours And Company Processes for reducing color in polytrimethylene ether glycol polymers
US7084311B2 (en) * 2003-05-06 2006-08-01 E. I. Du Pont De Nemours And Company Hydrogenation of chemically derived 1,3-propanediol
WO2004099110A1 (ja) * 2003-05-08 2004-11-18 Mitsubishi Chemical Corporation １,３−プロパンジオールの製造方法
US20070035057A1 (en) * 2003-06-26 2007-02-15 Chang Jing C Poly(trimethylene terephthalate) bicomponent fiber process
US20080103217A1 (en) * 2006-10-31 2008-05-01 Hari Babu Sunkara Polyether ester elastomer composition
US7074969B2 (en) * 2004-06-18 2006-07-11 E.I. Du Pont De Nemours And Company Process for preparation of polytrimethylene ether glycols
US20060041039A1 (en) * 2004-08-20 2006-02-23 Gyorgyi Fenyvesi Fluorescent poly(alkylene terephthalate) compositions
US7358211B2 (en) * 2004-11-24 2008-04-15 E.I. Du Pont De Nemours And Company Catalyst for the production of 1,3-propanediol by catalytic hydrogenation of 3-hydroxypropanal
EP2270065A3 (en) 2004-12-21 2011-03-09 E. I. du Pont de Nemours and Company Poly(trimethylene terephthalate) composition and shaped articles prepared therefrom
US7244790B2 (en) * 2005-05-02 2007-07-17 E.I. Du Pont De Nemours And Company Thermoplastic elastomer blend, method of manufacture and use thereof
US20060247378A1 (en) * 2005-05-02 2006-11-02 Sunkara Hari B Thermoplastic elastomer blend, method of manufacture and use thereof
US7161045B1 (en) 2005-08-16 2007-01-09 E. I. Du Pont De Nemours And Company Process for manufacture of polytrimethylene ether glycol
US7157607B1 (en) 2005-08-16 2007-01-02 E. I. Du Pont De Nemours And Company Manufacture of polytrimethylene ether glycol
US7357985B2 (en) * 2005-09-19 2008-04-15 E.I. Du Pont De Nemours And Company High crimp bicomponent fibers
US7238772B2 (en) 2005-09-22 2007-07-03 E. I. Du Pont De Nemours And Company Preparation of polytrimethylene ether glycol and copolymers thereof
US20070129524A1 (en) * 2005-12-06 2007-06-07 Sunkara Hari B Thermoplastic polyurethanes comprising polytrimethylene ether soft segments
US20070128459A1 (en) * 2005-12-07 2007-06-07 Kurian Joseph V Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) films
US20070129503A1 (en) * 2005-12-07 2007-06-07 Kurian Joseph V Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) molded, shaped articles
US7666501B2 (en) * 2005-12-07 2010-02-23 E. I. Du Pont De Nemours And Company Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) bi-constituent filaments
US7164046B1 (en) 2006-01-20 2007-01-16 E. I. Du Pont De Nemours And Company Manufacture of polytrimethylene ether glycol
US7388115B2 (en) * 2006-01-20 2008-06-17 E. I. Du Pont De Nemours And Company Manufacture of polytrimethylene ether glycol
CN100347138C (zh) * 2006-01-23 2007-11-07 上海华谊丙烯酸有限公司 一种脱除1,3—丙二醇中微量醛的方法
US20070203371A1 (en) * 2006-01-23 2007-08-30 Sunkara Hari B Process for producing polytrimethylene ether glycol
US20080039582A1 (en) * 2006-07-28 2008-02-14 Hari Babu Sunkara Polytrimethylene ether-based polyurethane ionomers
US7531593B2 (en) * 2006-10-31 2009-05-12 E.I. Du Pont De Nemours And Company Thermoplastic elastomer blend composition
US20080108845A1 (en) * 2006-11-07 2008-05-08 Hari Babu Sunkara Polytrimethylene ether glycol esters
US20080135662A1 (en) * 2006-12-06 2008-06-12 Chang Jing C Melt-spun elastoester multifilament yarns
US7714174B2 (en) * 2007-03-27 2010-05-11 E. I. Du Pont De Nemours And Company Lower-color polytrimethylene ether glycol using hydride compounds
US20090054282A1 (en) * 2007-08-24 2009-02-26 E.I. Dupont De Nemours And Company Lubrication oil compositions
WO2009029482A1 (en) * 2007-08-24 2009-03-05 E. I. Du Pont De Nemours And Company Lubrication oil compositions
MX2010002154A (es) * 2007-08-24 2010-03-18 Du Pont Composiciones de aceite de lubricacion.
US8703681B2 (en) 2007-08-24 2014-04-22 E I Du Pont De Nemours And Company Lubrication oil compositions
JP5470249B2 (ja) * 2007-08-24 2014-04-16 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 潤滑油組成物
US7919017B2 (en) * 2007-11-12 2011-04-05 E. I. Du Pont De Nemours And Company Electrical insulation fluids for use in electrical apparatus
US20100267994A1 (en) * 2009-04-16 2010-10-21 E. I. Du Pont De Nemours And Company Processes for preparing polytrimethylene glycol using ion exchange resins
US20110172360A1 (en) * 2009-07-22 2011-07-14 E.I. Du Pont De Nemours And Company Methods for synthesizing polyether diols and polyester diols
WO2011041348A2 (en) 2009-09-30 2011-04-07 E. I. Du Pont De Nemours And Company Polytrimethylene ether glycol or copolymers thereof having improved color and processes for their preparation
CN102040475B (zh) * 2009-10-21 2013-07-24 中国石油化工股份有限公司 一种提纯1,3-丙二醇的方法
KR101791711B1 (ko) * 2009-12-21 2017-10-30 이 아이 듀폰 디 네모아 앤드 캄파니 폴리트라이메틸렌 에테르 글리콜 및 그의 공중합체의 생성 방법
US8247526B2 (en) 2010-12-20 2012-08-21 E I Du Pont De Nemours And Company Process for the preparation of polyalkylene ether glycol
US8759559B2 (en) 2012-04-18 2014-06-24 E I Du Pont De Nemours And Company Processes for preparing polytrimethylene ether glycol esters
CN114230440B (zh) * 2022-01-06 2024-02-23 江苏扬农化工集团有限公司 一种连续进行二元醇水溶液脱水除醛的方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5527973A (en) * 1994-12-16 1996-06-18 Kelsey; Donald R. Purification of 1,3-propanediol

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2520733A (en) 1946-08-26 1950-08-29 Shell Dev Polymers of trimethylene glycol
US3326985A (en) 1964-12-29 1967-06-20 Shell Oil Co Polytrimethylene glycol
DE3632397A1 (de) 1986-09-24 1988-03-31 Ruhrchemie Ag Verfahren zur reinigung von propandiol-1,3
US4970295A (en) 1989-02-27 1990-11-13 Arco Chemical Technology, Inc. Preparation of oxetane polyether polyols using a bleaching earth catalyst
US4937314A (en) 1989-02-28 1990-06-26 E. I. Du Pont De Nemours And Company Copolyetherester elastomer with poly(1,3-propylene terephthalate) hard segment
US5194159A (en) 1989-12-27 1993-03-16 Union Carbide Chemicals & Plastics Technology Corporation Treatment of lower glycol-containing operative fluids
EP0559739B1 (en) 1990-11-27 1998-03-18 Commonwealth Scientific And Industrial Research Organisation Verfahren zur herstellung von poly(alkylene) oxides
US5128185A (en) 1991-08-29 1992-07-07 E. I. Du Pont De Nemours And Company Copolyetherester elastomer with poly(1,3-propylenebibenzoate) hard segment
DE4222708A1 (de) 1992-07-10 1994-01-13 Degussa Verfahren zur Herstellung von 1,3-Propandiol
US5659089A (en) 1996-05-22 1997-08-19 Arco Chemical Technology, L.P. Process for making poly(2-methyl-1,3-propanediol)

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5527973A (en) * 1994-12-16 1996-06-18 Kelsey; Donald R. Purification of 1,3-propanediol

Also Published As

Publication number Publication date
AU5490199A (en) 2000-03-14
KR20010072753A (ko) 2001-07-31
TR200100559T2 (tr) 2002-04-22
CA2339185A1 (en) 2000-03-02
EP1105363A1 (en) 2001-06-13
TW506963B (en) 2002-10-21
EP1105363B1 (en) 2004-02-11
JP2003526605A (ja) 2003-09-09
WO2000010953A1 (en) 2000-03-02
DE69914773T2 (de) 2004-12-30
AR020217A1 (es) 2002-05-02
ATE259341T1 (de) 2004-02-15
ES2214043T3 (es) 2004-09-01
CN1313843A (zh) 2001-09-19
DE69914773D1 (de) 2004-03-18
CN1190399C (zh) 2005-02-23
US6235948B1 (en) 2001-05-22
BR9914293A (pt) 2001-10-16

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