KR100625370B1 - 고도로 핵형성화된 열가소성 제품 - Google Patents
고도로 핵형성화된 열가소성 제품 Download PDFInfo
- Publication number
- KR100625370B1 KR100625370B1 KR1020037012383A KR20037012383A KR100625370B1 KR 100625370 B1 KR100625370 B1 KR 100625370B1 KR 1020037012383 A KR1020037012383 A KR 1020037012383A KR 20037012383 A KR20037012383 A KR 20037012383A KR 100625370 B1 KR100625370 B1 KR 100625370B1
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- South Korea
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- polyolefin
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- thermoplastic
- compounds
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- Expired - Lifetime
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- 229920001169 thermoplastic Polymers 0.000 title claims description 41
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 40
- 229920000098 polyolefin Polymers 0.000 claims abstract description 74
- 239000000203 mixture Substances 0.000 claims abstract description 73
- 150000001875 compounds Chemical class 0.000 claims abstract description 72
- 239000000654 additive Substances 0.000 claims abstract description 37
- 238000000034 method Methods 0.000 claims abstract description 25
- 230000000996 additive effect Effects 0.000 claims abstract description 22
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 10
- 229920000642 polymer Polymers 0.000 claims description 32
- 150000001768 cations Chemical class 0.000 claims description 15
- 239000011575 calcium Substances 0.000 claims description 13
- 229920000728 polyester Polymers 0.000 claims description 12
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 11
- 229910052791 calcium Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 8
- 229910052744 lithium Inorganic materials 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 150000003973 alkyl amines Chemical class 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
- 229910052712 strontium Inorganic materials 0.000 claims description 6
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 125000005529 alkyleneoxy group Chemical group 0.000 claims description 5
- 125000002837 carbocyclic group Chemical group 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 4
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 229910052788 barium Inorganic materials 0.000 claims description 4
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- 239000002516 radical scavenger Substances 0.000 claims description 4
- 229910052701 rubidium Inorganic materials 0.000 claims description 4
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 4
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- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
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- 239000008188 pellet Substances 0.000 claims description 3
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- 239000003086 colorant Substances 0.000 claims description 2
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- 239000004611 light stabiliser Substances 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 239000012815 thermoplastic material Substances 0.000 claims 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 229910052725 zinc Inorganic materials 0.000 claims 2
- 239000011701 zinc Substances 0.000 claims 2
- 239000003242 anti bacterial agent Substances 0.000 claims 1
- 238000002425 crystallisation Methods 0.000 abstract description 38
- 230000008025 crystallization Effects 0.000 abstract description 38
- 230000006911 nucleation Effects 0.000 abstract description 37
- 238000010899 nucleation Methods 0.000 abstract description 37
- 150000003839 salts Chemical class 0.000 abstract description 25
- 238000009472 formulation Methods 0.000 abstract description 21
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 abstract description 16
- 239000008116 calcium stearate Substances 0.000 abstract description 14
- 235000013539 calcium stearate Nutrition 0.000 abstract description 14
- 238000003860 storage Methods 0.000 abstract description 10
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- KYQRDNYMKKJUTH-UHFFFAOYSA-N bicyclo[2.2.1]heptane-3,4-dicarboxylic acid Chemical class C1CC2(C(O)=O)C(C(=O)O)CC1C2 KYQRDNYMKKJUTH-UHFFFAOYSA-N 0.000 abstract description 3
- 239000008187 granular material Substances 0.000 abstract description 2
- 239000004743 Polypropylene Substances 0.000 description 61
- 239000002667 nucleating agent Substances 0.000 description 61
- -1 diester salts Chemical class 0.000 description 56
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- 239000000835 fiber Substances 0.000 description 29
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 20
- 239000000243 solution Substances 0.000 description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 229920005989 resin Polymers 0.000 description 19
- 239000011347 resin Substances 0.000 description 19
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- 238000012360 testing method Methods 0.000 description 13
- ZHROMWXOTYBIMF-UHFFFAOYSA-M sodium;1,3,7,9-tetratert-butyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C ZHROMWXOTYBIMF-UHFFFAOYSA-M 0.000 description 12
- 238000004458 analytical method Methods 0.000 description 11
- 238000001125 extrusion Methods 0.000 description 11
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- 238000002347 injection Methods 0.000 description 11
- 239000007924 injection Substances 0.000 description 11
- 238000002844 melting Methods 0.000 description 11
- 230000008018 melting Effects 0.000 description 11
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 10
- 238000001816 cooling Methods 0.000 description 10
- 229920006395 saturated elastomer Polymers 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 8
- 239000013078 crystal Substances 0.000 description 8
- FXDGCBFGSXNGQD-UHFFFAOYSA-L disodium;bicyclo[2.2.1]heptane-2,3-dicarboxylate Chemical compound [Na+].[Na+].C1CC2C(C([O-])=O)C(C(=O)[O-])C1C2 FXDGCBFGSXNGQD-UHFFFAOYSA-L 0.000 description 8
- 239000010408 film Substances 0.000 description 8
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 8
- 229960005069 calcium Drugs 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 238000001746 injection moulding Methods 0.000 description 7
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- 235000013305 food Nutrition 0.000 description 6
- 230000006872 improvement Effects 0.000 description 6
- 230000000704 physical effect Effects 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 6
- 235000010234 sodium benzoate Nutrition 0.000 description 6
- 239000004299 sodium benzoate Substances 0.000 description 6
- 239000000600 sorbitol Substances 0.000 description 6
- YWEWWNPYDDHZDI-JJKKTNRVSA-N (1r)-1-[(4r,4ar,8as)-2,6-bis(3,4-dimethylphenyl)-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C1=C(C)C(C)=CC=C1C1O[C@H]2[C@@H]([C@H](O)CO)OC(C=3C=C(C)C(C)=CC=3)O[C@H]2CO1 YWEWWNPYDDHZDI-JJKKTNRVSA-N 0.000 description 5
- FMZUHGYZWYNSOA-VVBFYGJXSA-N (1r)-1-[(4r,4ar,8as)-2,6-diphenyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C([C@@H]1OC(O[C@@H]([C@@H]1O1)[C@H](O)CO)C=2C=CC=CC=2)OC1C1=CC=CC=C1 FMZUHGYZWYNSOA-VVBFYGJXSA-N 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910021645 metal ion Inorganic materials 0.000 description 5
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- 229910052763 palladium Inorganic materials 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 125000002619 bicyclic group Chemical group 0.000 description 4
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
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- LQOPXMZSGSTGMF-UHFFFAOYSA-N 6004-79-1 Chemical compound C1CC2C3C(=O)OC(=O)C3C1C2 LQOPXMZSGSTGMF-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 150000008065 acid anhydrides Chemical class 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
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- 229940087101 dibenzylidene sorbitol Drugs 0.000 description 3
- XVIQUULQQQZUDW-UHFFFAOYSA-L disodium;bicyclo[2.2.1]hept-2-ene-3,4-dicarboxylate Chemical compound [Na+].[Na+].C1CC2(C([O-])=O)C(C(=O)[O-])=CC1C2 XVIQUULQQQZUDW-UHFFFAOYSA-L 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- ADIMAYPTOBDMTL-UHFFFAOYSA-N oxazepam Chemical compound C12=CC(Cl)=CC=C2NC(=O)C(O)N=C1C1=CC=CC=C1 ADIMAYPTOBDMTL-UHFFFAOYSA-N 0.000 description 3
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- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
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- LWOVDHGNKPBMHF-UHFFFAOYSA-N 3-octadecoxycarbonylbicyclo[2.2.1]heptane-2-carboxylic acid Chemical compound C1CC2C(C(O)=O)C(C(=O)OCCCCCCCCCCCCCCCCCC)C1C2 LWOVDHGNKPBMHF-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
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- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 2
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- 150000001241 acetals Chemical class 0.000 description 2
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- 159000000007 calcium salts Chemical class 0.000 description 2
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- 235000012000 cholesterol Nutrition 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- HMGUIQPKFUZDPV-UHFFFAOYSA-L disodium;bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate Chemical compound [Na+].[Na+].C1C2C=CC1C(C(=O)[O-])C2C([O-])=O HMGUIQPKFUZDPV-UHFFFAOYSA-L 0.000 description 2
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- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 2
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- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- 150000002892 organic cations Chemical class 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
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- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 2
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- 229960002675 xylitol Drugs 0.000 description 2
- 0 *C(*)(C1(*)*)C(*)(*2C(O)=O)C(*)(*)C1(*)C2(*)C(O)=O Chemical compound *C(*)(C1(*)*)C(*)(*2C(O)=O)C(*)(*)C1(*)C2(*)C(O)=O 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
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- 229910018512 Al—OH Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
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- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
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- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
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- 125000003118 aryl group Chemical group 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- PQPCAWBIIFEKIF-UHFFFAOYSA-L barium(2+);bicyclo[2.2.1]heptane-3,4-dicarboxylate Chemical compound [Ba+2].C1CC2(C([O-])=O)C(C(=O)[O-])CC1C2 PQPCAWBIIFEKIF-UHFFFAOYSA-L 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 125000000649 benzylidene group Chemical group [H]C(=[*])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- IVVOCRBADNIWDM-UHFFFAOYSA-N bicyclo[2.2.1]heptane-2,3-dicarboxylic acid Chemical compound C1CC2C(C(O)=O)C(C(=O)O)C1C2 IVVOCRBADNIWDM-UHFFFAOYSA-N 0.000 description 1
- NVBVFOCGFIGQPK-UHFFFAOYSA-L bicyclo[2.2.1]heptane-3,4-dicarboxylate;rubidium(1+) Chemical compound [Rb+].[Rb+].C1CC2(C([O-])=O)C(C(=O)[O-])CC1C2 NVBVFOCGFIGQPK-UHFFFAOYSA-L 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- LLSDKQJKOVVTOJ-UHFFFAOYSA-L calcium chloride dihydrate Chemical compound O.O.[Cl-].[Cl-].[Ca+2] LLSDKQJKOVVTOJ-UHFFFAOYSA-L 0.000 description 1
- 229940052299 calcium chloride dihydrate Drugs 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- MIHDGSOYBPAAHC-UHFFFAOYSA-L calcium;bicyclo[2.2.1]heptane-2,3-dicarboxylate Chemical compound [Ca+2].C1CC2C(C([O-])=O)C(C(=O)[O-])C1C2 MIHDGSOYBPAAHC-UHFFFAOYSA-L 0.000 description 1
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- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0083—Nucleating agents promoting the crystallisation of the polymer matrix
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C61/12—Saturated polycyclic compounds
- C07C61/125—Saturated polycyclic compounds having a carboxyl group bound to a condensed ring system
- C07C61/13—Saturated polycyclic compounds having a carboxyl group bound to a condensed ring system having two rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
- C07C2602/42—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
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- Chemical Kinetics & Catalysis (AREA)
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| US09/995,315 | 2001-11-27 | ||
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| US6599971B2 (en) * | 2001-03-29 | 2003-07-29 | Milliken & Company | Metals salts of hexahydrophthalic acid as nucleating additives for crystalline thermoplastics |
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| US20030134082A1 (en) * | 2001-12-21 | 2003-07-17 | Morin Brian G. | Carpet comprising a low-shrink backing of polypropylene tape fibers |
| US20030134118A1 (en) * | 2001-12-21 | 2003-07-17 | Morin Brian G. | Low-shrink polypropylene tape fibers |
| WO2003075838A2 (en) * | 2002-03-05 | 2003-09-18 | M.C.W Research Foundation, Inc. | Methods and compositions for pharmacological and toxicological evaluation of test agents |
| US20050197435A1 (en) * | 2002-06-14 | 2005-09-08 | Dotson Darin L. | Polymer additive compositions for bimolecular nucleation in thermoplastics |
| US20040084802A1 (en) * | 2002-11-02 | 2004-05-06 | Morin Brian G. | Method of producing low-shrink polypropylene tape fibers comprising high amounts of nucleating agents |
| US6887567B2 (en) * | 2002-11-02 | 2005-05-03 | Milliken & Company | Low-shrink polypropylene tape fibers comprising high amounts of nucleating agents |
| US6863976B2 (en) | 2002-11-16 | 2005-03-08 | Milliken & Company | Polypropylene monofilament and tape fibers exhibiting certain creep-strain characteristics and corresponding crystalline configurations |
| US6759124B2 (en) | 2002-11-16 | 2004-07-06 | Milliken & Company | Thermoplastic monofilament fibers exhibiting low-shrink, high tenacity, and extremely high modulus levels |
| US20040096639A1 (en) * | 2002-11-16 | 2004-05-20 | Morin Brian G. | Uniform production methods for colored and non-colored polypropylene fibers |
| US20040152815A1 (en) * | 2002-11-17 | 2004-08-05 | Morin Brian G. | High speed spinning procedures for the manufacture of low denier polypropylene fibers and yarns |
| US20040096621A1 (en) * | 2002-11-17 | 2004-05-20 | Dai Weihua Sonya | High denier textured polypropylene fibers and yarns |
| US7041368B2 (en) * | 2002-11-17 | 2006-05-09 | Milliken & Company | High speed spinning procedures for the manufacture of high denier polypropylene fibers and yarns |
| US6849330B1 (en) | 2003-08-30 | 2005-02-01 | Milliken & Company | Thermoplastic fibers exhibiting durable high color strength characteristics |
| US20050048281A1 (en) * | 2003-08-30 | 2005-03-03 | Royer Joseph R. | Thermoplastic fibers exhibiting durable high color strength characteristics |
| US20050046065A1 (en) * | 2003-08-30 | 2005-03-03 | Cowan Martin E. | Thermoplastic fibers exhibiting durable high color strength characteristics |
| US7700802B2 (en) | 2003-09-03 | 2010-04-20 | Hitachi Chemical Co., Ltd. | Method of separating stereoisomers of dicarboxylic acid having norbornene or norbornane structure, or derivative thereof |
| US6936650B2 (en) * | 2003-10-03 | 2005-08-30 | Milliken & Company | Nucleating additive formulations of bicyclo[2.2.1]heptane dicarboxylate salts |
| US6946507B2 (en) * | 2003-10-03 | 2005-09-20 | Milliken & Company | Nucleating additive formulations of bicyclo[2.2.1]heptane dicarboxylate salts |
| EP1668071B1 (en) * | 2003-10-03 | 2016-12-28 | Milliken & Company | Improved nucleating additive formulations of bicyclo 2.2.1 heptane dicarboxylate salts |
| US6995202B2 (en) * | 2003-11-07 | 2006-02-07 | Milliken & Company | Methods of nucleating thermoplastics using concentrates of saturated bicyclic dicarboxylate salts |
| US7078450B2 (en) * | 2003-11-07 | 2006-07-18 | Milliken & Company | Concentrates of saturated bicyclic dicarboxylate salts to facilitate use thereof as polymer nucleation additives |
| JP2006117776A (ja) * | 2004-10-21 | 2006-05-11 | Sumitomo Chemical Co Ltd | ポリプロピレン系樹脂組成物 |
| US7074483B2 (en) * | 2004-11-05 | 2006-07-11 | Innegrity, Llc | Melt-spun multifilament polyolefin yarn formation processes and yarns formed therefrom |
| CA2592026C (en) * | 2004-12-22 | 2010-11-30 | Advantage Polymers, Llc | Thermoplastic compositions and method of use thereof for molded articles |
| US20060148920A1 (en) * | 2004-12-30 | 2006-07-06 | Fina Technology, Inc. | Foamed polypropylene with improved cell structure |
| EP1661935B2 (en) † | 2005-05-12 | 2012-05-30 | Borealis Technology Oy | Transparent easy tearable film |
| US7445834B2 (en) | 2005-06-10 | 2008-11-04 | Morin Brian G | Polypropylene fiber for reinforcement of matrix materials |
| US7648607B2 (en) * | 2005-08-17 | 2010-01-19 | Innegrity, Llc | Methods of forming composite materials including high modulus polyolefin fibers |
| US8057887B2 (en) | 2005-08-17 | 2011-11-15 | Rampart Fibers, LLC | Composite materials including high modulus polyolefin fibers |
| US7892633B2 (en) * | 2005-08-17 | 2011-02-22 | Innegrity, Llc | Low dielectric composite materials including high modulus polyolefin fibers |
| US7786203B2 (en) * | 2005-09-16 | 2010-08-31 | Milliken & Company | Polymer compositions comprising nucleating or clarifying agents and articles made using such compositions |
| JP2009510251A (ja) * | 2005-10-04 | 2009-03-12 | タイコ・ヘルスケアー・グループ・エルピー | プロピレン共重合体組成物 |
| US20100160518A1 (en) * | 2006-03-21 | 2010-06-24 | Basell Poliolefine Italia S.R.L. | Controlled Nucleated Polymer Composition |
| JP4223520B2 (ja) * | 2006-06-19 | 2009-02-12 | 中本パックス株式会社 | 耐熱透明容器 |
| JP5602352B2 (ja) | 2007-09-21 | 2014-10-08 | 住友化学株式会社 | 光安定化ポリプロピレン |
| JP2009220402A (ja) * | 2008-03-17 | 2009-10-01 | Sekisui Film Kk | フィルム |
| US8026305B2 (en) * | 2008-10-01 | 2011-09-27 | Fina Technology Inc | Articles formed from nucleated polyethylene |
| US8378045B2 (en) * | 2008-12-31 | 2013-02-19 | Dow Global Technologies Llc | Thermoformed article with high stiffness and good optics |
| MX2011007139A (es) | 2008-12-31 | 2011-09-27 | Dow Global Technologies Llc | Composicion de procatalizador con donador interno de diéster aromático de 1,2-fenileno sustituido y método. |
| SG172819A1 (en) | 2008-12-31 | 2011-08-29 | Dow Global Technologies Llc | Enhanced procatalyst composition and process |
| US20120190780A1 (en) * | 2011-01-25 | 2012-07-26 | Danielson Todd D | Additive compositions and thermoplastic polymer compositions comprising the same |
| EP2906628B1 (en) | 2012-10-15 | 2017-07-26 | Saudi Basic Industries Corporation | Polyethylene compositions comprising polypropylene |
| CN110105623B (zh) | 2012-12-21 | 2021-05-25 | 美利肯公司 | 添加剂组合物和其使用方法 |
| WO2014100862A1 (pt) * | 2012-12-26 | 2014-07-03 | Braskem S.A. | Composição de prolipropileno e seu uso, peça de polipropileno, combinação de aditivos e resina de polipropileno. |
| US10266668B2 (en) | 2014-10-01 | 2019-04-23 | Colormatrix Holdings, Inc. | Nucleating agent additive compositions for polymeric materials |
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| US9994695B2 (en) | 2014-11-25 | 2018-06-12 | Milliken & Company | Process for extruding polypropylene |
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| ES2680625T3 (es) * | 2015-06-23 | 2018-09-10 | Omya International Ag | Producto material de carga tratado superficialmente para alfa-nucleación de poliolefinas |
| WO2017009193A1 (en) | 2015-07-13 | 2017-01-19 | Sabic Global Technologies B.V. | Composition comprising heterophasic propylene copolymer |
| CN108026340A (zh) | 2015-09-09 | 2018-05-11 | Sabic环球技术有限责任公司 | 聚烯烃组合物 |
| WO2017144466A1 (en) | 2016-02-22 | 2017-08-31 | Sabic Global Technologies B.V. | Composition comprising heterophasic propylene copolymer |
| CN106147045B (zh) * | 2016-07-07 | 2019-07-30 | 山西省化工研究所（有限公司） | 一种等规聚丁烯-1与二元酸金属盐类成核剂的组合物及其制备 |
| JP6916161B2 (ja) * | 2018-02-20 | 2021-08-11 | インディアン オイル コーポレーション リミテッド | ポリオレフィンポリマー用添加剤および熱可塑性組成物 |
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| CN110128264A (zh) * | 2019-06-17 | 2019-08-16 | 山西省化工研究所（有限公司） | 不饱和脂环二羧酸铝盐成核剂及其制备方法 |
| CN110684288B (zh) * | 2019-11-11 | 2021-12-10 | 太原科技大学 | 一种用于提高聚丁烯-1晶型转化速率的专用助剂制备方法及专用助剂的应用 |
| CN114193888A (zh) * | 2021-12-04 | 2022-03-18 | 宁波盈瑞聚合科技有限公司 | 一种可提高冲击强度的bopet薄膜的生产方法 |
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| DE3141119A1 (de) * | 1981-10-16 | 1983-04-28 | Bayer Ag, 5090 Leverkusen | Schaedlingsbekaempfungsmittel |
| US4532280A (en) | 1984-06-11 | 1985-07-30 | New Japan Chemical Co., Ltd. | Crystalline polyolefin-type resin compositions |
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| JP3046428B2 (ja) | 1991-12-05 | 2000-05-29 | 旭電化工業株式会社 | 結晶性合成樹脂組成物 |
| DE4213219A1 (de) * | 1992-04-22 | 1993-10-28 | Hoechst Ag | Polymerlegierungen aus Cycloolefinpolymeren und Polyolefinen |
| US5981636A (en) | 1996-12-27 | 1999-11-09 | 3M Innovative Properties Company | Modifying agents for polyolefins |
| US5922793A (en) | 1996-12-27 | 1999-07-13 | Minnesota Mining And Manufacturing Company | Modifying agents for polyolefins |
| US5929146A (en) | 1996-12-27 | 1999-07-27 | Minnesota Mining And Manufacturing Company | Modifying agents for polyolefins |
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-
2001
- 2001-11-27 US US09/995,315 patent/US6534574B1/en not_active Expired - Lifetime
-
2002
- 2002-03-05 BR BR0208340-0A patent/BR0208340A/pt not_active IP Right Cessation
- 2002-03-05 KR KR1020037012383A patent/KR100625370B1/ko not_active Expired - Lifetime
- 2002-03-05 WO PCT/US2002/006493 patent/WO2002077092A1/en not_active Ceased
- 2002-03-05 CN CNB028071883A patent/CN1240757C/zh not_active Expired - Lifetime
- 2002-03-05 RU RU2003131268/04A patent/RU2289597C2/ru active
- 2002-03-05 AT AT02725071T patent/ATE407920T1/de not_active IP Right Cessation
- 2002-03-05 EP EP08002524A patent/EP1921059A3/en not_active Withdrawn
- 2002-03-05 JP JP2002576546A patent/JP3973559B2/ja not_active Expired - Lifetime
- 2002-03-05 EP EP02725071A patent/EP1373396B1/en not_active Expired - Lifetime
- 2002-03-18 AR ARP020100960A patent/AR033050A1/es unknown
- 2002-03-19 TW TW091105170A patent/TWI255828B/zh not_active IP Right Cessation
- 2002-03-22 MY MYPI20021025A patent/MY143271A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN1240757C (zh) | 2006-02-08 |
| ATE407920T1 (de) | 2008-09-15 |
| TWI255828B (en) | 2006-06-01 |
| JP2004530006A (ja) | 2004-09-30 |
| BR0208340A (pt) | 2004-03-23 |
| AR033050A1 (es) | 2003-12-03 |
| KR20040012734A (ko) | 2004-02-11 |
| EP1373396A4 (en) | 2006-04-19 |
| JP3973559B2 (ja) | 2007-09-12 |
| RU2003131268A (ru) | 2005-03-20 |
| US6534574B1 (en) | 2003-03-18 |
| CN1498245A (zh) | 2004-05-19 |
| MY143271A (en) | 2011-04-15 |
| EP1373396A1 (en) | 2004-01-02 |
| RU2289597C2 (ru) | 2006-12-20 |
| EP1373396B1 (en) | 2008-09-10 |
| WO2002077092A1 (en) | 2002-10-03 |
| EP1921059A2 (en) | 2008-05-14 |
| EP1921059A3 (en) | 2008-07-09 |
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