KR100611031B1 - 플루오로 중합체와 폴리아크릴레이트와의 혼합물을 함유하는 층을 갖는 필름의 제조방법 및 당해 방법으로 제조한 필름 - Google Patents
플루오로 중합체와 폴리아크릴레이트와의 혼합물을 함유하는 층을 갖는 필름의 제조방법 및 당해 방법으로 제조한 필름 Download PDFInfo
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- KR100611031B1 KR100611031B1 KR1020017007882A KR20017007882A KR100611031B1 KR 100611031 B1 KR100611031 B1 KR 100611031B1 KR 1020017007882 A KR1020017007882 A KR 1020017007882A KR 20017007882 A KR20017007882 A KR 20017007882A KR 100611031 B1 KR100611031 B1 KR 100611031B1
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/911—Cooling
- B29C48/9135—Cooling of flat articles, e.g. using specially adapted supporting means
- B29C48/914—Cooling of flat articles, e.g. using specially adapted supporting means cooling drums
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/80—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders
- B29C48/83—Heating or cooling the cylinders
- B29C48/832—Heating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
- B29K2027/12—Use of polyvinylhalogenides or derivatives thereof as moulding material containing fluorine
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31935—Ester, halide or nitrile of addition polymer
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Medicinal Preparation (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19859393.7 | 1998-12-22 | ||
| DE19859393A DE19859393A1 (de) | 1998-12-22 | 1998-12-22 | Verfahren zur Herstellung von Folien |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20010092753A KR20010092753A (ko) | 2001-10-26 |
| KR100611031B1 true KR100611031B1 (ko) | 2006-08-10 |
Family
ID=7892213
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020017007882A KR100611031B1 (ko) | 1998-12-22 | 1999-12-03 | 플루오로 중합체와 폴리아크릴레이트와의 혼합물을 함유하는 층을 갖는 필름의 제조방법 및 당해 방법으로 제조한 필름 |
Country Status (26)
| Country | Link |
|---|---|
| US (1) | US6420033B1 (de) |
| EP (1) | EP1140465B1 (de) |
| JP (1) | JP4307737B2 (de) |
| KR (1) | KR100611031B1 (de) |
| CN (1) | CN1130284C (de) |
| AT (1) | ATE294691T1 (de) |
| AU (1) | AU749491B2 (de) |
| BR (1) | BR9916498B1 (de) |
| CA (1) | CA2356338C (de) |
| CZ (1) | CZ298439B6 (de) |
| DE (2) | DE19859393A1 (de) |
| DK (1) | DK1140465T3 (de) |
| EE (1) | EE04805B1 (de) |
| ES (1) | ES2241355T3 (de) |
| HK (1) | HK1041667B (de) |
| HR (1) | HRP20010459B1 (de) |
| HU (1) | HU226764B1 (de) |
| ID (1) | ID28983A (de) |
| IL (1) | IL143571A (de) |
| MX (1) | MXPA01006445A (de) |
| PL (1) | PL191442B1 (de) |
| PT (1) | PT1140465E (de) |
| RU (1) | RU2254238C2 (de) |
| SK (1) | SK285992B6 (de) |
| WO (1) | WO2000037237A1 (de) |
| ZA (1) | ZA200105047B (de) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1060209B1 (de) * | 1997-12-05 | 2004-06-02 | Röhm GmbH & Co. KG | Verfahren zur herstellung von oberflächenharten, im "film-insert-moulding"-verfahren handhabbaren, beidseitig hochglänzenden, gelkörperfreien pmma-folien |
| US6863854B2 (en) * | 2000-02-25 | 2005-03-08 | General Electric | Insert mold decorating film for thermoplastic resin and methods for making |
| US20030180564A1 (en) * | 2001-12-14 | 2003-09-25 | Torsten Marquardt | Surface film for laminating on to a substrate |
| FR2842530B1 (fr) * | 2002-07-17 | 2004-09-03 | Atofina | Composition coextrudable avec le pvdf |
| FR2852961B1 (fr) * | 2003-03-26 | 2006-07-07 | Atofina | Nouveau procede de synthese/fabrication de films acryliques |
| WO2004109034A1 (en) * | 2003-06-02 | 2004-12-16 | Avery Dennison Corporation | Cool roof covering |
| EP1505117A1 (de) * | 2003-08-01 | 2005-02-09 | Arkema | PTC-Effectlacke auf Basis von PVDF und ihre Anwendungen für selbstregulierende Heizsysteme |
| DE10345045A1 (de) * | 2003-09-26 | 2005-04-14 | Röhm GmbH & Co. KG | Verfahren zur Oberflächenvergütung von Werkstoffen durch Aufbringen insbesondere transparenter Schichten auf Basis von Polymethacrylaten |
| DE102004024429A1 (de) * | 2004-05-14 | 2005-12-08 | Röhm GmbH & Co. KG | Formkörper, enthaltend eine Polymermischung aus schlagzähmodifizierten Poly(meth)-acrylat und Fluorpolymer |
| US7811659B2 (en) | 2006-01-27 | 2010-10-12 | Arkema France | High optical purity copolymer film |
| CN101117393B (zh) * | 2006-08-04 | 2011-03-16 | 上海尚聚化工科技有限公司 | 多层核壳结构的含氟聚合物颗粒及含有它的热塑性聚烯烃制品 |
| KR101780925B1 (ko) * | 2007-06-15 | 2017-10-10 | 알케마 인코포레이티드 | 폴리비닐리덴 플루오라이드 배면시트를 구비한 태양광 모듈 |
| DE102007029263A1 (de) * | 2007-06-22 | 2008-12-24 | Evonik Röhm Gmbh | PMMA/PVDF-Folie mit besonders hoher Witterungsbeständigkeit und hoher UV-Schutzwirkung |
| KR100796351B1 (ko) * | 2007-07-11 | 2008-01-21 | 주식회사 원풍 | 열 가소성 폴리올레핀계 타포린 및 그의 제조방법 |
| KR101004912B1 (ko) * | 2008-03-17 | 2010-12-28 | 주식회사 엘지화학 | 발열체 및 이의 제조방법 |
| CN102056984B (zh) * | 2008-06-10 | 2014-07-16 | 株式会社钟化 | 氟树脂膜和氟树脂层叠丙烯酸类树脂膜 |
| GB0918115D0 (en) * | 2009-10-16 | 2009-12-02 | Musion Ip Ltd | A method of manufacturing foil for producing a pepper's ghost illusion |
| JP2012516565A (ja) * | 2009-02-02 | 2012-07-19 | エルジー・ケム・リミテッド | 太陽電池バックシート及びその製造方法 |
| DE102009028937A1 (de) | 2009-08-27 | 2011-03-03 | Evonik Röhm Gmbh | Schild für KFZ-Kennzeichen umfassend mindestens eine transluzente, retroreflektierende Schicht |
| KR101752178B1 (ko) * | 2009-11-30 | 2017-06-29 | 덴카 주식회사 | 폴리불화비닐리덴계 수지조성물, 필름, 백시트 및 태양전지 모듈 |
| US20120261182A1 (en) * | 2010-06-09 | 2012-10-18 | The Board Of Trustees Of The University Of Illinois | Liquid-repellent, large-area, electrically-conducting polymer composite coatings |
| EP2813540B1 (de) * | 2012-02-08 | 2020-01-15 | LG Chem, Ltd. | Mehrschichtige folie und verfahren zur herstellung davon |
| CN102643450B (zh) * | 2012-04-23 | 2013-12-18 | 深圳华粤宝电池有限公司 | 一种微孔复合聚合物电池隔膜的制备工艺 |
| US20140272153A1 (en) * | 2013-03-13 | 2014-09-18 | William J. Buehne | Free standing polymeric films |
| PL3353238T3 (pl) * | 2016-12-07 | 2019-05-31 | Evonik Roehm Gmbh | Wytłaczana matowa folia o ulepszonych właściwościach mechanicznych i wysokiej odporności na warunki atmosferyczne |
| US11401389B2 (en) | 2018-05-24 | 2022-08-02 | E. I. Du Pont De Nemours And Company | Transparent fluoropolymer films |
| WO2023211468A1 (en) * | 2022-04-29 | 2023-11-02 | Amcor Flexibles North America, Inc. | Multilayer packaging film |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3253060A (en) * | 1964-08-03 | 1966-05-24 | Pennsalt Chemicals Corp | Molding compositions comprising polyvinylidene fluoride and polymethyl methacrylate |
| GB1065780A (en) * | 1965-02-15 | 1967-04-19 | American Cyanamid Co | Poly(vinylidene fluoride) compositions |
| IT1119928B (it) | 1978-09-25 | 1986-03-19 | Ugine Kuhlmann | Materiale composito di polifluoruro di vinilidene e di polimero termoplastico incompatibile e procedimento per la sua fabbricazione |
| JPS57142359A (en) | 1981-02-28 | 1982-09-03 | Kureha Chemical Ind Co Ltd | Extruded laminate |
| US4860509A (en) * | 1987-05-18 | 1989-08-29 | Laaly Heshmat O | Photovoltaic cells in combination with single ply roofing membranes |
| JPH0252720A (ja) | 1988-08-16 | 1990-02-22 | Denki Kagaku Kogyo Kk | フツ素樹脂系耐候フイルムの製法 |
| US5256472A (en) | 1988-12-05 | 1993-10-26 | Denki Kagaku Kogyo Kabushiki Kaisha | Fluorine resin type weather-resistant film |
| KR920007285B1 (ko) | 1989-03-10 | 1992-08-29 | 구레하 가가꾸 고오교 가부시끼가이샤 | 광학 위상차판 및 그 제조 방법 |
| JPH03110121A (ja) | 1989-09-25 | 1991-05-10 | Shin Etsu Chem Co Ltd | 透明性に優れたフッ化ビニリデン系樹脂フィルムの製造方法 |
| ZA964731B (en) | 1995-06-07 | 1997-01-07 | Avery Dennison Corp A Legal Bo | Extrusion coating process for making protective and decorative films |
-
1998
- 1998-12-22 DE DE19859393A patent/DE19859393A1/de not_active Ceased
-
1999
- 1999-01-06 US US09/225,453 patent/US6420033B1/en not_active Expired - Fee Related
- 1999-12-03 CZ CZ20012146A patent/CZ298439B6/cs not_active IP Right Cessation
- 1999-12-03 EE EEP200100338A patent/EE04805B1/xx not_active IP Right Cessation
- 1999-12-03 ID IDW00200101395A patent/ID28983A/id unknown
- 1999-12-03 MX MXPA01006445A patent/MXPA01006445A/es not_active IP Right Cessation
- 1999-12-03 EP EP99963387A patent/EP1140465B1/de not_active Expired - Lifetime
- 1999-12-03 KR KR1020017007882A patent/KR100611031B1/ko not_active IP Right Cessation
- 1999-12-03 AU AU19704/00A patent/AU749491B2/en not_active Ceased
- 1999-12-03 ES ES99963387T patent/ES2241355T3/es not_active Expired - Lifetime
- 1999-12-03 PT PT99963387T patent/PT1140465E/pt unknown
- 1999-12-03 HU HU0104945A patent/HU226764B1/hu not_active IP Right Cessation
- 1999-12-03 DE DE59912027T patent/DE59912027D1/de not_active Expired - Lifetime
- 1999-12-03 JP JP2000589331A patent/JP4307737B2/ja not_active Expired - Fee Related
- 1999-12-03 CA CA002356338A patent/CA2356338C/en not_active Expired - Fee Related
- 1999-12-03 CN CN99814998A patent/CN1130284C/zh not_active Expired - Fee Related
- 1999-12-03 WO PCT/EP1999/009489 patent/WO2000037237A1/de active IP Right Grant
- 1999-12-03 RU RU2001120708/12A patent/RU2254238C2/ru not_active IP Right Cessation
- 1999-12-03 PL PL348978A patent/PL191442B1/pl not_active IP Right Cessation
- 1999-12-03 IL IL14357199A patent/IL143571A/xx not_active IP Right Cessation
- 1999-12-03 AT AT99963387T patent/ATE294691T1/de active
- 1999-12-03 BR BRPI9916498-1A patent/BR9916498B1/pt not_active IP Right Cessation
- 1999-12-03 SK SK874-2001A patent/SK285992B6/sk unknown
- 1999-12-03 DK DK99963387T patent/DK1140465T3/da active
-
2001
- 2001-06-18 HR HR20010459A patent/HRP20010459B1/xx not_active IP Right Cessation
- 2001-06-20 ZA ZA200105047A patent/ZA200105047B/en unknown
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2002
- 2002-05-03 HK HK02103335.6A patent/HK1041667B/zh not_active IP Right Cessation
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