KR100560061B1 - 에틸렌계 불포화 단량체로부터의 중합체 제조용 촉매조성물, 이의 제조 및 용도 - Google Patents

에틸렌계 불포화 단량체로부터의 중합체 제조용 촉매조성물, 이의 제조 및 용도 Download PDF

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KR100560061B1
KR100560061B1 KR1020040066197A KR20040066197A KR100560061B1 KR 100560061 B1 KR100560061 B1 KR 100560061B1 KR 1020040066197 A KR1020040066197 A KR 1020040066197A KR 20040066197 A KR20040066197 A KR 20040066197A KR 100560061 B1 KR100560061 B1 KR 100560061B1
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metal
pair
complex
metal atom
norbornene
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KR20050020725A (ko
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구달브라이언레슬리
페토프제니퍼린
센한
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롬 앤드 하스 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/50—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkaline earth metals, zinc, cadmium, mercury, copper or silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
KR1020040066197A 2003-08-21 2004-08-21 에틸렌계 불포화 단량체로부터의 중합체 제조용 촉매조성물, 이의 제조 및 용도 Expired - Fee Related KR100560061B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US49687303P 2003-08-21 2003-08-21
US60/496,873 2003-08-21
US55924304P 2004-04-02 2004-04-02
US60/559,243 2004-04-02
US10/857,330 US7087687B2 (en) 2003-08-21 2004-05-28 Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US10/857,330 2004-05-28

Publications (2)

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KR20050020725A KR20050020725A (ko) 2005-03-04
KR100560061B1 true KR100560061B1 (ko) 2006-03-13

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Country Link
US (1) US7087687B2 (enExample)
EP (1) EP1508577A1 (enExample)
JP (1) JP2005068424A (enExample)
KR (1) KR100560061B1 (enExample)
CN (1) CN1267460C (enExample)
TW (1) TWI262196B (enExample)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7087687B2 (en) * 2003-08-21 2006-08-08 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7208541B2 (en) * 2003-08-22 2007-04-24 National Starch And Chemical Investment Holding Corporation Hot melt adhesive
US7172986B2 (en) * 2004-06-14 2007-02-06 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7199074B2 (en) * 2004-06-14 2007-04-03 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7595369B2 (en) * 2004-11-10 2009-09-29 Lg Chem, Ltd. Method of polymerizing cyclic olefins and vinyl olefins, copolymer produced by the method and optical anisotropic film comprising the same
US7749934B2 (en) * 2005-02-22 2010-07-06 Rohm And Haas Company Protected catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7435701B2 (en) * 2005-05-27 2008-10-14 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7635739B2 (en) 2005-08-31 2009-12-22 Rohm And Haas Company Substantially linear polymers and methods of making and using same
JP4855740B2 (ja) * 2005-09-01 2012-01-18 株式会社クラレ 金属化合物、金属化合物を含むビニルエステル系モノマー重合用触媒組成物およびそのビニルエステル系モノマーの重合への使用
JP2007063470A (ja) * 2005-09-01 2007-03-15 Kuraray Co Ltd 金属化合物、金属化合物を含むビニル系モノマー重合用触媒組成物およびそのビニル系モノマーの重合への使用
KR100882315B1 (ko) * 2006-04-28 2009-02-10 주식회사 엘지화학 루이스 산을 이용한 α-올레핀-아크릴레이트-노보넨 3원공중합체 제조방법 및 이에 의해 제조된 공중합체
KR101540820B1 (ko) * 2006-11-14 2015-07-30 유니베이션 테크놀로지즈, 엘엘씨 촉매계 및 중합 방법
US20080118570A1 (en) * 2006-11-20 2008-05-22 Zhi Liu Polymer coated drug-ion exchange resins and methods
JP2009096970A (ja) * 2007-01-31 2009-05-07 Sumitomo Bakelite Co Ltd 環状オレフィン系ポリマーの製造方法
CA2620884C (en) * 2007-02-28 2011-07-12 Rohm And Haas Company Composition and method for preparing copolymers of polar and non-polar olefins substantially free of free radical intiated polymer
JP5016512B2 (ja) 2007-02-28 2012-09-05 ローム アンド ハース カンパニー 実質的に線状のコポリマーおよびその製造方法
JP5111145B2 (ja) 2007-02-28 2012-12-26 ローム アンド ハース カンパニー 非環式脂肪族オレフィンの重合
CA2620852A1 (en) 2007-02-28 2008-08-28 Rohm And Haas Company A porous linear polymer composition and method of making same
FR2937643B1 (fr) * 2008-10-27 2011-10-14 Arkema France Nouveaux copolymeres a blocs d'olefines polaires et apolaires
JP5738097B2 (ja) * 2010-09-10 2015-06-17 昭和電工株式会社 ノルボルネン系重合体の製造方法
JP5834017B2 (ja) * 2010-10-26 2015-12-16 昭和電工株式会社 ノルボルネン系モノマー重合用触媒及びノルボルネン系重合体の製造方法
JP2012121956A (ja) * 2010-12-07 2012-06-28 Sumitomo Bakelite Co Ltd 付加型ノルボルネン系樹脂、その製造方法、該樹脂を含む樹脂組成物、ならびに該樹脂を含む成形体および該成形体を含む複合部材
WO2012164574A1 (en) 2011-05-09 2012-12-06 Reliance Industries Limited Nitrogen containing external donor system for propylene polymerization
JP5575702B2 (ja) * 2011-05-20 2014-08-20 株式会社クラレ ビニル系モノマー重合用触媒組成物および該組成物を用いたビニル系モノマーの重合への使用
EP2980107B1 (en) 2013-03-27 2018-10-24 Japan Polyethylene Corporation Polar-group-containing olefin copolymer, adhesive and layered product comprising same
CN103360544B (zh) * 2013-07-26 2015-07-01 宁波工程学院 降冰片烯类、丙烯酸酯类和戊烯类共聚用催化剂及共聚方法
CN111868064A (zh) * 2017-10-31 2020-10-30 陶氏环球技术有限责任公司 包括碳硼烷助催化剂的催化剂体系
CN113877551B (zh) * 2021-10-25 2023-12-29 湖北科技学院 重金属和放射性金属离子吸附材料及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
WO1999014222A1 (en) * 1997-09-15 1999-03-25 The Dow Chemical Company Bimetallic complexes and polymerization catalysts therefrom
WO2003102038A1 (en) * 2002-06-04 2003-12-11 Thales Technologies, Ag Polymerization catalysts
EP1508577A1 (en) * 2003-08-21 2005-02-23 Rohm And Haas Company A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU432769A1 (ru) 1970-07-13 1974-12-15 Способ получения линейных полимеров
JP3388828B2 (ja) 1992-09-21 2003-03-24 モンテル・テクノロジー・カンパニー・ベー・ベー 重合方法
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
US6232417B1 (en) 1996-03-07 2001-05-15 The B. F. Goodrich Company Photoresist compositions comprising polycyclic polymers with acid labile pendant groups
US6265506B1 (en) 1997-06-09 2001-07-24 The B. F. Goodrich Company Method for the preparation of copolymers of ethylene/norbornene-type monomers with cationic palladium catalysts
US5929181A (en) 1997-06-09 1999-07-27 The B.F.Goodrich Co. Method for preparation of copolymers of ethylene/norbornene-type monomers with nickel catalysts
US6593440B2 (en) 1997-06-18 2003-07-15 Penn State Research Foundation Palladium (II) catalyzed polymerization of norbornene and acrylates
US6111041A (en) 1997-06-18 2000-08-29 The Penn State Research Foundation Palladium (II) catalyized polymerization of norbornene and acrylates
US7087691B2 (en) 1997-06-18 2006-08-08 Promerus Llc Photo-imageable compositions of norbornene and acrylate copolymers and use thereof
US6037297A (en) 1997-12-16 2000-03-14 Exxon Research And Engineering Co. Catalyst complexes and polymers therefrom
US6417303B1 (en) 1997-12-16 2002-07-09 Exxonmobil Research And Engineering Company Substantially linear copolymers
AU4826399A (en) 1998-07-01 2000-01-24 B.F. Goodrich Company, The Polycyclic copolymer compositions
SG72966A1 (en) * 1998-07-08 2000-05-23 Sumitomo Chemical Co Transition metal compound olefin polymerization catalyst component olefin polymerization catalyst and process for producing olefin polymer
CA2338847A1 (en) 1998-07-27 2000-02-10 Basell Technology Company B.V. A polymerization process
EP1034196B1 (en) 1998-10-05 2005-01-12 Promerus LLC Catalyst and methods for polymerizing cycloolefins
DE69925939T2 (de) 1998-12-09 2006-05-04 Sumitomo Bakelite Co. Ltd. Additionspolymerisation in einer form unter benutzung von polymeren des norbornentyps mit gruppe-3-metallkomplexen
US6544919B1 (en) 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions
KR20030005432A (ko) 2000-05-31 2003-01-17 이 아이 듀폰 디 네모아 앤드 캄파니 올레핀의 중합
CN100369940C (zh) 2000-05-31 2008-02-20 纳幕尔杜邦公司 烯烃聚合催化剂
US20030144441A1 (en) 2001-11-13 2003-07-31 Ayusman Sen Controlled copolymerization of methyl acrylate with olefins under mild conditions
US6730757B2 (en) 2002-03-08 2004-05-04 Exxonmobil Research And Engineering Company Sulfur-containing and sulfur-nitrogen-containing catalysts for polymerization of olefins and polar monomers
KR100576971B1 (ko) 2002-09-13 2006-05-10 금호석유화학 주식회사 올레핀 중합용 이핵 전이금속 화합물의 제조 방법
US6677419B1 (en) 2002-11-13 2004-01-13 International Business Machines Corporation Preparation of copolymers

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
WO1999014222A1 (en) * 1997-09-15 1999-03-25 The Dow Chemical Company Bimetallic complexes and polymerization catalysts therefrom
WO2003102038A1 (en) * 2002-06-04 2003-12-11 Thales Technologies, Ag Polymerization catalysts
EP1508577A1 (en) * 2003-08-21 2005-02-23 Rohm And Haas Company A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers

Also Published As

Publication number Publication date
CN1267460C (zh) 2006-08-02
CN1597709A (zh) 2005-03-23
KR20050020725A (ko) 2005-03-04
TWI262196B (en) 2006-09-21
JP2005068424A (ja) 2005-03-17
US20050043494A1 (en) 2005-02-24
EP1508577A1 (en) 2005-02-23
TW200514795A (en) 2005-05-01
US7087687B2 (en) 2006-08-08

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