TWI262196B - A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers - Google Patents

A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers Download PDF

Info

Publication number
TWI262196B
TWI262196B TW093123928A TW93123928A TWI262196B TW I262196 B TWI262196 B TW I262196B TW 093123928 A TW093123928 A TW 093123928A TW 93123928 A TW93123928 A TW 93123928A TW I262196 B TWI262196 B TW I262196B
Authority
TW
Taiwan
Prior art keywords
group
metal
complex
ligand
pair
Prior art date
Application number
TW093123928A
Other languages
English (en)
Chinese (zh)
Other versions
TW200514795A (en
Inventor
Brian Leslie Goodall
Jennifer Lynn Petoff
Han Shen
Original Assignee
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm & Haas filed Critical Rohm & Haas
Publication of TW200514795A publication Critical patent/TW200514795A/zh
Application granted granted Critical
Publication of TWI262196B publication Critical patent/TWI262196B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/50—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkaline earth metals, zinc, cadmium, mercury, copper or silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
TW093123928A 2003-08-21 2004-08-10 A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers TWI262196B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US49687303P 2003-08-21 2003-08-21
US55924304P 2004-04-02 2004-04-02
US10/857,330 US7087687B2 (en) 2003-08-21 2004-05-28 Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers

Publications (2)

Publication Number Publication Date
TW200514795A TW200514795A (en) 2005-05-01
TWI262196B true TWI262196B (en) 2006-09-21

Family

ID=34069126

Family Applications (1)

Application Number Title Priority Date Filing Date
TW093123928A TWI262196B (en) 2003-08-21 2004-08-10 A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers

Country Status (6)

Country Link
US (1) US7087687B2 (enExample)
EP (1) EP1508577A1 (enExample)
JP (1) JP2005068424A (enExample)
KR (1) KR100560061B1 (enExample)
CN (1) CN1267460C (enExample)
TW (1) TWI262196B (enExample)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7087687B2 (en) * 2003-08-21 2006-08-08 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7208541B2 (en) * 2003-08-22 2007-04-24 National Starch And Chemical Investment Holding Corporation Hot melt adhesive
US7199074B2 (en) 2004-06-14 2007-04-03 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7172986B2 (en) 2004-06-14 2007-02-06 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7595369B2 (en) * 2004-11-10 2009-09-29 Lg Chem, Ltd. Method of polymerizing cyclic olefins and vinyl olefins, copolymer produced by the method and optical anisotropic film comprising the same
US7749934B2 (en) * 2005-02-22 2010-07-06 Rohm And Haas Company Protected catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7435701B2 (en) * 2005-05-27 2008-10-14 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7635739B2 (en) 2005-08-31 2009-12-22 Rohm And Haas Company Substantially linear polymers and methods of making and using same
JP2007063470A (ja) * 2005-09-01 2007-03-15 Kuraray Co Ltd 金属化合物、金属化合物を含むビニル系モノマー重合用触媒組成物およびそのビニル系モノマーの重合への使用
JP4855740B2 (ja) * 2005-09-01 2012-01-18 株式会社クラレ 金属化合物、金属化合物を含むビニルエステル系モノマー重合用触媒組成物およびそのビニルエステル系モノマーの重合への使用
KR100882315B1 (ko) * 2006-04-28 2009-02-10 주식회사 엘지화학 루이스 산을 이용한 α-올레핀-아크릴레이트-노보넨 3원공중합체 제조방법 및 이에 의해 제조된 공중합체
US8088871B2 (en) * 2006-11-14 2012-01-03 Univation Technologies, Llc Catalyst systems and polymerization processes
US20080118570A1 (en) * 2006-11-20 2008-05-22 Zhi Liu Polymer coated drug-ion exchange resins and methods
JP2009096970A (ja) * 2007-01-31 2009-05-07 Sumitomo Bakelite Co Ltd 環状オレフィン系ポリマーの製造方法
JP5111145B2 (ja) 2007-02-28 2012-12-26 ローム アンド ハース カンパニー 非環式脂肪族オレフィンの重合
CA2620884C (en) * 2007-02-28 2011-07-12 Rohm And Haas Company Composition and method for preparing copolymers of polar and non-polar olefins substantially free of free radical intiated polymer
CA2620852A1 (en) 2007-02-28 2008-08-28 Rohm And Haas Company A porous linear polymer composition and method of making same
JP5016512B2 (ja) 2007-02-28 2012-09-05 ローム アンド ハース カンパニー 実質的に線状のコポリマーおよびその製造方法
FR2937643B1 (fr) * 2008-10-27 2011-10-14 Arkema France Nouveaux copolymeres a blocs d'olefines polaires et apolaires
JP5738097B2 (ja) * 2010-09-10 2015-06-17 昭和電工株式会社 ノルボルネン系重合体の製造方法
CN103189397B (zh) * 2010-10-26 2015-06-10 昭和电工株式会社 降冰片烯系单体聚合用催化剂及降冰片烯系聚合物的制造方法
JP2012121956A (ja) * 2010-12-07 2012-06-28 Sumitomo Bakelite Co Ltd 付加型ノルボルネン系樹脂、その製造方法、該樹脂を含む樹脂組成物、ならびに該樹脂を含む成形体および該成形体を含む複合部材
US8809221B2 (en) 2011-05-09 2014-08-19 Reliance Industries Limited Nitrogen containing external donor system for propylene polymerization
JP5575702B2 (ja) * 2011-05-20 2014-08-20 株式会社クラレ ビニル系モノマー重合用触媒組成物および該組成物を用いたビニル系モノマーの重合への使用
US20160046842A1 (en) 2013-03-27 2016-02-18 Japan Polyethylene Corporation Polar-group-containing olefin copolymer, polar-group-containing multinary olefin copolymer, olefin-based resin composition, and adhesive and layered product each using the same
CN103360544B (zh) * 2013-07-26 2015-07-01 宁波工程学院 降冰片烯类、丙烯酸酯类和戊烯类共聚用催化剂及共聚方法
WO2019089715A1 (en) * 2017-10-31 2019-05-09 Dow Global Technologies, Llc Catalyst systems comprising carborane cocatalysts
CN113877551B (zh) * 2021-10-25 2023-12-29 湖北科技学院 重金属和放射性金属离子吸附材料及其制备方法

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU432769A1 (ru) * 1970-07-13 1974-12-15 Способ получения линейных полимеров
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
EP0589527B1 (en) 1992-09-21 1999-07-28 Montell Technology Company bv Polymerization process
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
US6232417B1 (en) * 1996-03-07 2001-05-15 The B. F. Goodrich Company Photoresist compositions comprising polycyclic polymers with acid labile pendant groups
US5929181A (en) * 1997-06-09 1999-07-27 The B.F.Goodrich Co. Method for preparation of copolymers of ethylene/norbornene-type monomers with nickel catalysts
EP0988331B1 (en) * 1997-06-09 2004-09-01 Promerus LLC Method for the preparation of copolymers of ethylene/norbornene-type monomers with cationic palladium catalysts
US6593440B2 (en) * 1997-06-18 2003-07-15 Penn State Research Foundation Palladium (II) catalyzed polymerization of norbornene and acrylates
US7087691B2 (en) * 1997-06-18 2006-08-08 Promerus Llc Photo-imageable compositions of norbornene and acrylate copolymers and use thereof
US6111041A (en) * 1997-06-18 2000-08-29 The Penn State Research Foundation Palladium (II) catalyized polymerization of norbornene and acrylates
BR9812308A (pt) * 1997-09-15 2000-09-05 Dow Chemical Co Complexos bimetálicos, catalisadores feitos destes
US6037297A (en) * 1997-12-16 2000-03-14 Exxon Research And Engineering Co. Catalyst complexes and polymers therefrom
US6417303B1 (en) * 1997-12-16 2002-07-09 Exxonmobil Research And Engineering Company Substantially linear copolymers
CN1307603A (zh) * 1998-07-01 2001-08-08 B·F·谷德里奇公司 多环共聚物组合物
SG72966A1 (en) * 1998-07-08 2000-05-23 Sumitomo Chemical Co Transition metal compound olefin polymerization catalyst component olefin polymerization catalyst and process for producing olefin polymer
CA2338847A1 (en) 1998-07-27 2000-02-10 Basell Technology Company B.V. A polymerization process
AU6291999A (en) * 1998-10-05 2000-04-26 B.F. Goodrich Company, The Catalyst and methods for polymerizing cycloolefins
KR100739482B1 (ko) * 1998-12-09 2007-07-13 스미토모 베이클라이트 가부시키가이샤 제 10족 금속 착물을 사용하는 노르보르넨형 단량체의 몰드내 첨가 중합반응
US6544919B1 (en) * 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions
US20020028897A1 (en) 2000-05-31 2002-03-07 Johnson Lynda Kaye Copolymers of ethylene and selected acrylate esters
WO2001092348A2 (en) * 2000-05-31 2001-12-06 E.I. Du Pont De Nemours And Company Polymerization of olefins
US20030144441A1 (en) * 2001-11-13 2003-07-31 Ayusman Sen Controlled copolymerization of methyl acrylate with olefins under mild conditions
US6730757B2 (en) * 2002-03-08 2004-05-04 Exxonmobil Research And Engineering Company Sulfur-containing and sulfur-nitrogen-containing catalysts for polymerization of olefins and polar monomers
AU2003241078A1 (en) 2002-06-04 2003-12-19 Thales Technologies, Ag Polymerization catalysts
KR100576971B1 (ko) * 2002-09-13 2006-05-10 금호석유화학 주식회사 올레핀 중합용 이핵 전이금속 화합물의 제조 방법
US6677419B1 (en) * 2002-11-13 2004-01-13 International Business Machines Corporation Preparation of copolymers
US7087687B2 (en) * 2003-08-21 2006-08-08 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers

Also Published As

Publication number Publication date
US20050043494A1 (en) 2005-02-24
JP2005068424A (ja) 2005-03-17
KR100560061B1 (ko) 2006-03-13
US7087687B2 (en) 2006-08-08
CN1267460C (zh) 2006-08-02
KR20050020725A (ko) 2005-03-04
CN1597709A (zh) 2005-03-23
TW200514795A (en) 2005-05-01
EP1508577A1 (en) 2005-02-23

Similar Documents

Publication Publication Date Title
TWI262196B (en) A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
TWI246520B (en) Processes for olefin polymerization
Britovsek et al. Bis (imino) pyridyl iron and cobalt complexes: the effect of nitrogen substituents on ethylene oligomerisation and polymerisation
Makio et al. FI Catalysts for olefin polymerization A comprehensive treatment
Ittel et al. Late-metal catalysts for ethylene homo-and copolymerization
TWI322035B (en) A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
Fokken et al. Nine-membered titanacyclic complexes based on an ethylene-bridged bis (phenolato) ligand: Synthesis, structure, and olefin polymerization activity
TW534914B (en) Cyclopentaphenanthreneyl metal complexes and polymerization process
Ma et al. Vanadium-Catalyzed Ethylene− Propylene Copolymerization: The Question of the Metal Oxidation State in Ziegler− Natta Polymerization Promoted by (β-diketonate) 3V
TW500631B (en) Catalyst component comprising magnesium, titanium, a halogen and an electron donor, its preparation and use
JPS62187707A (ja) オレフィンの立体規則性重合用触媒
Zhang et al. Synthesis and reactivity of rare-earth-metal monoalkyl complexes supported by bidentate indolyl ligands and their high performance in isoprene 1, 4-cis polymerization
TW201204747A (en) Polypropylene-based polymer, polypropylene-based compositions and uses thereof
Hessen Monocyclopentadienyl titanium catalysts: ethene polymerisation versus ethene trimerisation
Michiue et al. Synthesis, structures, and olefin polymerization behavior of sterically crowded tris (pyrazolyl) borate zirconium and hafnium complexes
JP2009108332A (ja) 触媒組成物およびその調製ならびにエチレン性不飽和モノマーからポリマーを調製するための使用
TW200904835A (en) Use of a combination chain transfer and activating agent to control molecular weight and optical density of Pd catalyzed norbornene polymers
JP2009108329A (ja) 触媒組成物およびその調製ならびにエチレン性不飽和モノマーからポリマーを調製するための使用
Zhai et al. Rare-earth-metal complexes bearing an iminodibenzyl-PNP pincer ligand: Synthesis and reactivity toward 3, 4-selective polymerization of 1, 3-dienes
JPS59138206A (ja) オレフィン重合用触媒成分の製造方法
Kober et al. Oxidation of 1-Methyl-1-phenylhydrazine with Oxidovanadium (V)–Salan Complexes: Insight into the Pathway to the Formation of Hydrazine by Vanadium Nitrogenase
Phillips X β-Diketiminato complexes of groups 3 to 5
WO2000069869A1 (en) Polymerisation catalysts
TWI324605B (enExample)
US7153916B2 (en) Transition metal compound, catalyst for polymerization of olefin, and process for polymerization of ofelin using the catalyst

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees