JP2005068424A - 触媒組成物およびその調製およびエチレン性不飽和モノマーからポリマーを調製するための使用 - Google Patents

触媒組成物およびその調製およびエチレン性不飽和モノマーからポリマーを調製するための使用 Download PDF

Info

Publication number
JP2005068424A
JP2005068424A JP2004240323A JP2004240323A JP2005068424A JP 2005068424 A JP2005068424 A JP 2005068424A JP 2004240323 A JP2004240323 A JP 2004240323A JP 2004240323 A JP2004240323 A JP 2004240323A JP 2005068424 A JP2005068424 A JP 2005068424A
Authority
JP
Japan
Prior art keywords
pair
metal
metal atom
complex
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2004240323A
Other languages
English (en)
Japanese (ja)
Other versions
JP2005068424A5 (enExample
Inventor
Brian Leslie Goodall
ブライアン・レスリー・グッダル
Jennifer Lynn Petoff
ジェニファー・リン・ペトフ
Han Shen
ハン・シェン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Publication of JP2005068424A publication Critical patent/JP2005068424A/ja
Publication of JP2005068424A5 publication Critical patent/JP2005068424A5/ja
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/50Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkaline earth metals, zinc, cadmium, mercury, copper or silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04Nickel compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/12Esters of monohydric alcohols or phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03Multinuclear procatalyst, i.e. containing two or more metals, being different or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
JP2004240323A 2003-08-21 2004-08-20 触媒組成物およびその調製およびエチレン性不飽和モノマーからポリマーを調製するための使用 Pending JP2005068424A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US49687303P 2003-08-21 2003-08-21
US55924304P 2004-04-02 2004-04-02
US10/857,330 US7087687B2 (en) 2003-08-21 2004-05-28 Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers

Publications (2)

Publication Number Publication Date
JP2005068424A true JP2005068424A (ja) 2005-03-17
JP2005068424A5 JP2005068424A5 (enExample) 2008-03-13

Family

ID=34069126

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004240323A Pending JP2005068424A (ja) 2003-08-21 2004-08-20 触媒組成物およびその調製およびエチレン性不飽和モノマーからポリマーを調製するための使用

Country Status (6)

Country Link
US (1) US7087687B2 (enExample)
EP (1) EP1508577A1 (enExample)
JP (1) JP2005068424A (enExample)
KR (1) KR100560061B1 (enExample)
CN (1) CN1267460C (enExample)
TW (1) TWI262196B (enExample)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006009003A (ja) * 2004-06-14 2006-01-12 Rohm & Haas Co 触媒組成物およびその調製ならびにエチレン性不飽和モノマーからポリマーを調製するための使用
JP2006233214A (ja) * 2005-02-22 2006-09-07 Rohm & Haas Co 保護された触媒組成物およびその製造およびエチレン性不飽和モノマーからポリマーを製造するための使用
JP2007063470A (ja) * 2005-09-01 2007-03-15 Kuraray Co Ltd 金属化合物、金属化合物を含むビニル系モノマー重合用触媒組成物およびそのビニル系モノマーの重合への使用
JP2007063469A (ja) * 2005-09-01 2007-03-15 Kuraray Co Ltd 金属化合物、金属化合物を含むビニルエステル系モノマー重合用触媒組成物およびそのビニルエステル系モノマーの重合への使用
JP2009096970A (ja) * 2007-01-31 2009-05-07 Sumitomo Bakelite Co Ltd 環状オレフィン系ポリマーの製造方法
JP2009203479A (ja) * 2005-05-27 2009-09-10 Rohm & Haas Co 触媒組成物およびその製造ならびにエチレン性不飽和モノマーからポリマーを製造するための使用
JP2009535444A (ja) * 2006-04-28 2009-10-01 エルジー・ケム・リミテッド アルケン−アクリレート−ノルボルネン3元共重合体及びその製造方法
JP2010509484A (ja) * 2006-11-14 2010-03-25 ユニベーション・テクノロジーズ・エルエルシー 触媒系及び重合方法
JP2011179012A (ja) * 2011-05-20 2011-09-15 Kuraray Co Ltd ビニル系モノマー重合用触媒組成物および該組成物を用いたビニル系モノマーの重合への使用
JP2012077284A (ja) * 2010-09-10 2012-04-19 Showa Denko Kk ノルボルネン系モノマー重合用触媒及びノルボルネン系重合体の製造方法
WO2012057135A1 (ja) * 2010-10-26 2012-05-03 昭和電工株式会社 ノルボルネン系モノマー重合用触媒及びノルボルネン系重合体の製造方法
JP2012121956A (ja) * 2010-12-07 2012-06-28 Sumitomo Bakelite Co Ltd 付加型ノルボルネン系樹脂、その製造方法、該樹脂を含む樹脂組成物、ならびに該樹脂を含む成形体および該成形体を含む複合部材

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7087687B2 (en) * 2003-08-21 2006-08-08 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7208541B2 (en) * 2003-08-22 2007-04-24 National Starch And Chemical Investment Holding Corporation Hot melt adhesive
US7199074B2 (en) * 2004-06-14 2007-04-03 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7595369B2 (en) * 2004-11-10 2009-09-29 Lg Chem, Ltd. Method of polymerizing cyclic olefins and vinyl olefins, copolymer produced by the method and optical anisotropic film comprising the same
US7635739B2 (en) 2005-08-31 2009-12-22 Rohm And Haas Company Substantially linear polymers and methods of making and using same
US20080118570A1 (en) * 2006-11-20 2008-05-22 Zhi Liu Polymer coated drug-ion exchange resins and methods
CA2620884C (en) * 2007-02-28 2011-07-12 Rohm And Haas Company Composition and method for preparing copolymers of polar and non-polar olefins substantially free of free radical intiated polymer
JP5016512B2 (ja) 2007-02-28 2012-09-05 ローム アンド ハース カンパニー 実質的に線状のコポリマーおよびその製造方法
JP5111145B2 (ja) 2007-02-28 2012-12-26 ローム アンド ハース カンパニー 非環式脂肪族オレフィンの重合
CA2620852A1 (en) 2007-02-28 2008-08-28 Rohm And Haas Company A porous linear polymer composition and method of making same
FR2937643B1 (fr) * 2008-10-27 2011-10-14 Arkema France Nouveaux copolymeres a blocs d'olefines polaires et apolaires
WO2012164574A1 (en) 2011-05-09 2012-12-06 Reliance Industries Limited Nitrogen containing external donor system for propylene polymerization
EP2980107B1 (en) 2013-03-27 2018-10-24 Japan Polyethylene Corporation Polar-group-containing olefin copolymer, adhesive and layered product comprising same
CN103360544B (zh) * 2013-07-26 2015-07-01 宁波工程学院 降冰片烯类、丙烯酸酯类和戊烯类共聚用催化剂及共聚方法
CN111868064A (zh) * 2017-10-31 2020-10-30 陶氏环球技术有限责任公司 包括碳硼烷助催化剂的催化剂体系
CN113877551B (zh) * 2021-10-25 2023-12-29 湖北科技学院 重金属和放射性金属离子吸附材料及其制备方法

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU432769A1 (ru) 1970-07-13 1974-12-15 Способ получения линейных полимеров
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
JP3388828B2 (ja) 1992-09-21 2003-03-24 モンテル・テクノロジー・カンパニー・ベー・ベー 重合方法
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
US6232417B1 (en) 1996-03-07 2001-05-15 The B. F. Goodrich Company Photoresist compositions comprising polycyclic polymers with acid labile pendant groups
US6265506B1 (en) 1997-06-09 2001-07-24 The B. F. Goodrich Company Method for the preparation of copolymers of ethylene/norbornene-type monomers with cationic palladium catalysts
US5929181A (en) 1997-06-09 1999-07-27 The B.F.Goodrich Co. Method for preparation of copolymers of ethylene/norbornene-type monomers with nickel catalysts
US6593440B2 (en) 1997-06-18 2003-07-15 Penn State Research Foundation Palladium (II) catalyzed polymerization of norbornene and acrylates
US6111041A (en) 1997-06-18 2000-08-29 The Penn State Research Foundation Palladium (II) catalyized polymerization of norbornene and acrylates
US7087691B2 (en) 1997-06-18 2006-08-08 Promerus Llc Photo-imageable compositions of norbornene and acrylate copolymers and use thereof
ATE222917T1 (de) * 1997-09-15 2002-09-15 Dow Chemical Co Bimetallische komplexe und diese enthaltende polymerisationskatalysatoren
US6037297A (en) 1997-12-16 2000-03-14 Exxon Research And Engineering Co. Catalyst complexes and polymers therefrom
US6417303B1 (en) 1997-12-16 2002-07-09 Exxonmobil Research And Engineering Company Substantially linear copolymers
AU4826399A (en) 1998-07-01 2000-01-24 B.F. Goodrich Company, The Polycyclic copolymer compositions
SG72966A1 (en) * 1998-07-08 2000-05-23 Sumitomo Chemical Co Transition metal compound olefin polymerization catalyst component olefin polymerization catalyst and process for producing olefin polymer
CA2338847A1 (en) 1998-07-27 2000-02-10 Basell Technology Company B.V. A polymerization process
EP1034196B1 (en) 1998-10-05 2005-01-12 Promerus LLC Catalyst and methods for polymerizing cycloolefins
DE69925939T2 (de) 1998-12-09 2006-05-04 Sumitomo Bakelite Co. Ltd. Additionspolymerisation in einer form unter benutzung von polymeren des norbornentyps mit gruppe-3-metallkomplexen
US6544919B1 (en) 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions
KR20030005432A (ko) 2000-05-31 2003-01-17 이 아이 듀폰 디 네모아 앤드 캄파니 올레핀의 중합
CN100369940C (zh) 2000-05-31 2008-02-20 纳幕尔杜邦公司 烯烃聚合催化剂
US20030144441A1 (en) 2001-11-13 2003-07-31 Ayusman Sen Controlled copolymerization of methyl acrylate with olefins under mild conditions
US6730757B2 (en) 2002-03-08 2004-05-04 Exxonmobil Research And Engineering Company Sulfur-containing and sulfur-nitrogen-containing catalysts for polymerization of olefins and polar monomers
WO2003102038A1 (en) 2002-06-04 2003-12-11 Thales Technologies, Ag Polymerization catalysts
KR100576971B1 (ko) 2002-09-13 2006-05-10 금호석유화학 주식회사 올레핀 중합용 이핵 전이금속 화합물의 제조 방법
US6677419B1 (en) 2002-11-13 2004-01-13 International Business Machines Corporation Preparation of copolymers
US7087687B2 (en) * 2003-08-21 2006-08-08 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006009003A (ja) * 2004-06-14 2006-01-12 Rohm & Haas Co 触媒組成物およびその調製ならびにエチレン性不飽和モノマーからポリマーを調製するための使用
JP2009108332A (ja) * 2004-06-14 2009-05-21 Rohm & Haas Co 触媒組成物およびその調製ならびにエチレン性不飽和モノマーからポリマーを調製するための使用
JP2006233214A (ja) * 2005-02-22 2006-09-07 Rohm & Haas Co 保護された触媒組成物およびその製造およびエチレン性不飽和モノマーからポリマーを製造するための使用
JP2009203479A (ja) * 2005-05-27 2009-09-10 Rohm & Haas Co 触媒組成物およびその製造ならびにエチレン性不飽和モノマーからポリマーを製造するための使用
JP2007063470A (ja) * 2005-09-01 2007-03-15 Kuraray Co Ltd 金属化合物、金属化合物を含むビニル系モノマー重合用触媒組成物およびそのビニル系モノマーの重合への使用
JP2007063469A (ja) * 2005-09-01 2007-03-15 Kuraray Co Ltd 金属化合物、金属化合物を含むビニルエステル系モノマー重合用触媒組成物およびそのビニルエステル系モノマーの重合への使用
JP2012237006A (ja) * 2006-04-28 2012-12-06 Lg Chem Ltd アルケン−アクリレート−ノルボルネン3元共重合体及びその製造方法
JP2009535444A (ja) * 2006-04-28 2009-10-01 エルジー・ケム・リミテッド アルケン−アクリレート−ノルボルネン3元共重合体及びその製造方法
JP2010509484A (ja) * 2006-11-14 2010-03-25 ユニベーション・テクノロジーズ・エルエルシー 触媒系及び重合方法
JP2009096970A (ja) * 2007-01-31 2009-05-07 Sumitomo Bakelite Co Ltd 環状オレフィン系ポリマーの製造方法
JP2012077284A (ja) * 2010-09-10 2012-04-19 Showa Denko Kk ノルボルネン系モノマー重合用触媒及びノルボルネン系重合体の製造方法
WO2012057135A1 (ja) * 2010-10-26 2012-05-03 昭和電工株式会社 ノルボルネン系モノマー重合用触媒及びノルボルネン系重合体の製造方法
US8835580B2 (en) 2010-10-26 2014-09-16 Showa Denko K.K. Catalyst for norbornene monomer polymerization and method for producing norbornene polymer
JP5834017B2 (ja) * 2010-10-26 2015-12-16 昭和電工株式会社 ノルボルネン系モノマー重合用触媒及びノルボルネン系重合体の製造方法
JP2012121956A (ja) * 2010-12-07 2012-06-28 Sumitomo Bakelite Co Ltd 付加型ノルボルネン系樹脂、その製造方法、該樹脂を含む樹脂組成物、ならびに該樹脂を含む成形体および該成形体を含む複合部材
JP2011179012A (ja) * 2011-05-20 2011-09-15 Kuraray Co Ltd ビニル系モノマー重合用触媒組成物および該組成物を用いたビニル系モノマーの重合への使用

Also Published As

Publication number Publication date
KR100560061B1 (ko) 2006-03-13
CN1267460C (zh) 2006-08-02
CN1597709A (zh) 2005-03-23
KR20050020725A (ko) 2005-03-04
TWI262196B (en) 2006-09-21
US20050043494A1 (en) 2005-02-24
EP1508577A1 (en) 2005-02-23
TW200514795A (en) 2005-05-01
US7087687B2 (en) 2006-08-08

Similar Documents

Publication Publication Date Title
KR100560061B1 (ko) 에틸렌계 불포화 단량체로부터의 중합체 제조용 촉매조성물, 이의 제조 및 용도
JP2009108332A (ja) 触媒組成物およびその調製ならびにエチレン性不飽和モノマーからポリマーを調製するための使用
JP2009108329A (ja) 触媒組成物およびその調製ならびにエチレン性不飽和モノマーからポリマーを調製するための使用
JP5173932B2 (ja) 触媒組成物およびその製造ならびにエチレン性不飽和モノマーからポリマーを製造するための使用
US5705503A (en) Addition polymers of polycycloolefins containing functional substituents
KR101218310B1 (ko) Pd 촉매된 노르보넨 폴리머의 분자량 및 광학밀도를 조절하기 위한 조합 사슬 전달 및 활성화제의 용도
JP6511153B2 (ja) 触媒組成物およびこれを用いたポリオレフィンの製造方法
US6803433B2 (en) Catalyst for olefin polymerization and method for preparing polyolefins
Wu Novel α-Diimine Ni Complexes to Synthesize Polyethylene with Controlled Microstructures and Morphology
KR100431444B1 (ko) 폴리올레핀 제조용 촉매 및 이를 이용한 폴리올레핀의제조방법
JP2005154629A (ja) オレフィン重合用触媒及びポリオレフィンの製造方法

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20050118

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20060222

RD02 Notification of acceptance of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7422

Effective date: 20061016

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20070724

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20070726

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20070823

RD02 Notification of acceptance of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7422

Effective date: 20070823

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20070907

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20080128

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20080703