KR100531533B1 - 가교결합된 비스(아릴아미도) 4족 촉매 화합물로부터 제조된올레핀 공중합체 - Google Patents

가교결합된 비스(아릴아미도) 4족 촉매 화합물로부터 제조된올레핀 공중합체 Download PDF

Info

Publication number
KR100531533B1
KR100531533B1 KR10-1999-7007627A KR19997007627A KR100531533B1 KR 100531533 B1 KR100531533 B1 KR 100531533B1 KR 19997007627 A KR19997007627 A KR 19997007627A KR 100531533 B1 KR100531533 B1 KR 100531533B1
Authority
KR
South Korea
Prior art keywords
group
substituted
olefin
olefins
hydrocarbyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR10-1999-7007627A
Other languages
English (en)
Korean (ko)
Other versions
KR20000075567A (ko
Inventor
섀퍼티모씨다니엘
스퀴어케빈리차드
Original Assignee
엑손모빌 케미칼 패턴츠 인코포레이티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 엑손모빌 케미칼 패턴츠 인코포레이티드 filed Critical 엑손모빌 케미칼 패턴츠 인코포레이티드
Publication of KR20000075567A publication Critical patent/KR20000075567A/ko
Application granted granted Critical
Publication of KR100531533B1 publication Critical patent/KR100531533B1/ko
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/08Butenes
    • C08F10/10Isobutene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02Monomers containing only one unsaturated aliphatic radical
    • C08F12/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06Hydrocarbons
    • C08F12/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14Monomers containing five or more carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR10-1999-7007627A 1997-02-24 1998-02-23 가교결합된 비스(아릴아미도) 4족 촉매 화합물로부터 제조된올레핀 공중합체 Expired - Fee Related KR100531533B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US08/803,687 US6100354A (en) 1997-02-24 1997-02-24 Olefin copolymers from bridged bis(arylamido) Group 4 catalyst compounds
US08/803,687 1997-02-24
US8/803,687 1997-02-24
PCT/US1998/003499 WO1998037109A1 (en) 1997-02-24 1998-02-23 Olefin copolymers from bridged bis(arylamido) group 4 catalyst compounds

Publications (2)

Publication Number Publication Date
KR20000075567A KR20000075567A (ko) 2000-12-15
KR100531533B1 true KR100531533B1 (ko) 2005-11-28

Family

ID=25187182

Family Applications (1)

Application Number Title Priority Date Filing Date
KR10-1999-7007627A Expired - Fee Related KR100531533B1 (ko) 1997-02-24 1998-02-23 가교결합된 비스(아릴아미도) 4족 촉매 화합물로부터 제조된올레핀 공중합체

Country Status (10)

Country Link
US (1) US6100354A (https=)
EP (1) EP0963384B1 (https=)
JP (1) JP2001512521A (https=)
KR (1) KR100531533B1 (https=)
CN (1) CN100389131C (https=)
BR (1) BR9807851A (https=)
CA (1) CA2278282C (https=)
DE (1) DE69817542T2 (https=)
ES (1) ES2201445T3 (https=)
WO (1) WO1998037109A1 (https=)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ID20751A (id) * 1997-02-07 1999-02-25 Mitsui Chemicals Inc Katalis polimerisasi olefin dan proses pembuatan polimer olefin
US6124513A (en) 1997-06-20 2000-09-26 Pennzoil-Quaker State Company Ethylene-alpha-olefin polymers, processes and uses
US6586646B1 (en) 1997-06-20 2003-07-01 Pennzoil-Quaker State Company Vinylidene-containing polymers and uses thereof
US6511936B1 (en) 1998-02-12 2003-01-28 University Of Delaware Catalyst compounds with β-diminate anionic ligands and processes for polymerizing olefins
AU751049B2 (en) * 1998-04-15 2002-08-08 Shell Internationale Research Maatschappij B.V. Catalyst system for alpha-olefin oligomerization
US6271325B1 (en) 1999-05-17 2001-08-07 Univation Technologies, Llc Method of polymerization
US6624107B2 (en) 1999-10-22 2003-09-23 Univation Technologies, Llc Transition metal catalyst compounds having deuterium substituted ligand and catalyst systems thereof
US6417304B1 (en) 1999-11-18 2002-07-09 Univation Technologies, Llc Method of polymerization and polymer produced therefrom
US6380328B1 (en) 1999-12-10 2002-04-30 Univation Technologies, Llc Catalyst systems and their use in a polymerization process
US6271323B1 (en) 1999-10-28 2001-08-07 Univation Technologies, Llc Mixed catalyst compounds, catalyst systems and their use in a polymerization process
US6300439B1 (en) 1999-11-08 2001-10-09 Univation Technologies, Llc Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6265505B1 (en) 1999-11-18 2001-07-24 Univation Technologies, Llc Catalyst system and its use in a polymerization process
US6300438B1 (en) 1999-10-22 2001-10-09 Univation Technolgies, Llc Hafnium transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6822057B2 (en) 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
US6281306B1 (en) * 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
BR0016495A (pt) 1999-12-20 2002-09-17 Exxon Chemical Patents Inc Processos para a preparação de resinas poliolefìnicas usando catalisadores iÈnicos suportados
KR20010082913A (ko) * 2000-02-22 2001-08-31 박찬구 아미도계 iv족 금속 착화합물을 이용한 폴리이소부텐의제조방법
GB0102440D0 (en) 2001-01-31 2001-03-14 Borealis Tech Oy Catalyst
US7037989B2 (en) * 2003-05-27 2006-05-02 Exxonmobil Chemical Patents Inc. Copolymers of ethylene and/or α-olefins and vicinally disubstituted olefins
EP1788002A4 (en) * 2004-08-27 2009-08-19 Mitsui Chemicals Inc OLEFINIC POLYMERIZATION CATALYSTS, PROCESS FOR PRODUCING OLEFIN POLYMERS, OLEFIN COPOLYMERS, NEW TRANSITION METAL COMPOUNDS, AND PROCESSES FOR PRODUCING TRANSITION METAL COMPOUNDS

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS573804A (en) * 1980-06-10 1982-01-09 Mitsui Petrochem Ind Ltd Production of ethylene copolymer
JPH0710900B2 (ja) * 1982-06-18 1995-02-08 エクソン リサーチ アンド エンヂニアリング コムパニー 中級蒸留物燃料油用流動性改良剤
US4397394A (en) * 1982-07-19 1983-08-09 Ex-Cell-O Corporation Liquid container with straw opening means
DE3444111A1 (de) * 1984-12-04 1986-06-05 Basf Ag, 6700 Ludwigshafen Anorganische fuellstoffe fuer reaktivkunststoffsysteme
US4774301A (en) * 1987-06-08 1988-09-27 The Dow Chemical Company Zirconium containing catalysts and method of use
US5039766A (en) * 1988-06-28 1991-08-13 Sumitomo Chemical Company, Limited Liquid catalyst component, catalyst system containing said component and process for producing ethylene-alpha-olefin copolymer using said catalyst system
ATE135358T1 (de) * 1990-12-27 1996-03-15 Exxon Chemical Patents Inc Übergangsmetall-amidoverbindung und katalysatorsystem zur herstellung von isotaktischem propylen
ES2109473T3 (es) * 1991-12-13 1998-01-16 Exxon Chemical Patents Inc Copolimeros de etileno/alfa-olefinas superiores.
ES2126647T3 (es) * 1992-04-20 1999-04-01 Exxon Chemical Patents Inc Copolimeros de etileno/olefinas ramificadas.
US5486585A (en) * 1993-08-26 1996-01-23 Exxon Chemical Patents Inc. Amidosilyldiyl bridged catalysts and method of polymerization using said catalysts.
US6008307A (en) * 1994-04-28 1999-12-28 Exxon Chemical Patents Inc Process for producing olefin polymers using cationic catalysts
US5448001A (en) * 1994-10-07 1995-09-05 Queen's University At Kingston Polymerization of iso-butylene
US5763556A (en) * 1996-05-21 1998-06-09 Exxon Chemical Patents Inc. Copolymers of ethylene and geminally disubstituted olefins

Also Published As

Publication number Publication date
EP0963384A1 (en) 1999-12-15
CA2278282A1 (en) 1998-08-27
KR20000075567A (ko) 2000-12-15
CN100389131C (zh) 2008-05-21
WO1998037109A1 (en) 1998-08-27
US6100354A (en) 2000-08-08
EP0963384B1 (en) 2003-08-27
ES2201445T3 (es) 2004-03-16
JP2001512521A (ja) 2001-08-21
DE69817542T2 (de) 2004-06-24
CA2278282C (en) 2007-07-31
BR9807851A (pt) 2000-02-22
CN1257511A (zh) 2000-06-21
DE69817542D1 (de) 2003-10-02

Similar Documents

Publication Publication Date Title
KR100531533B1 (ko) 가교결합된 비스(아릴아미도) 4족 촉매 화합물로부터 제조된올레핀 공중합체
EP0900242B1 (en) Copolymers of ethylene and geminally disubstituted olefins
US5470927A (en) Ionic metallocene catalyst compositions
US5198401A (en) Ionic metallocene catalyst compositions
KR100482480B1 (ko) 고온올레핀중합방법
EP1056792B1 (en) Ethylene copolymerization process
US5907021A (en) High temperature olefin polymerization process
EP0468537B1 (en) Catalysts, method of preparing these catalysts and method of using said catalysts
WO2004106394A1 (en) COPOLYMERS OF ETHYLENE AND/OR α-OLEFINS AND VICINALLY DISUBSTITUTED OLEFINS
EP3431516A1 (en) Polypropylene
KR102579813B1 (ko) 혼성 전이금속 화합물을 포함하는 촉매, 이를 이용하여 제조된 올레핀계 중합체 및 이들의 제조방법
EP0708117A1 (en) Process for producing copolymer rubber
KR100494255B1 (ko) 에틸렌및동일자리이치환된올레핀의공중합체
KR100209859B1 (ko) 폴리에틸렌 공중합체의 제조방법
MXPA99007805A (es) Copolimeros de olefina a partir de compuestos catalizadores de bis (arilamido) grupo 4 puenteados
MXPA00007972A (en) Ethylene copolymerization process

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

PN2301 Change of applicant

St.27 status event code: A-3-3-R10-R13-asn-PN2301

St.27 status event code: A-3-3-R10-R11-asn-PN2301

A201 Request for examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

FPAY Annual fee payment

Payment date: 20081007

Year of fee payment: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20091122

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20091122

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000