KR100503706B1 - 아세트산의제조를위한이리듐촉매카르보닐화방법 - Google Patents

아세트산의제조를위한이리듐촉매카르보닐화방법 Download PDF

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Publication number
KR100503706B1
KR100503706B1 KR1019970070795A KR19970070795A KR100503706B1 KR 100503706 B1 KR100503706 B1 KR 100503706B1 KR 1019970070795 A KR1019970070795 A KR 1019970070795A KR 19970070795 A KR19970070795 A KR 19970070795A KR 100503706 B1 KR100503706 B1 KR 100503706B1
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concentration
iridium
water
liquid reaction
reaction composition
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Korean (ko)
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KR19980064381A (ko
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존 글렌 썬리
로버트 존 와트
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비피 케미칼즈 리미티드
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1019970070795A 1996-12-19 1997-12-19 아세트산의제조를위한이리듐촉매카르보닐화방법 Expired - Fee Related KR100503706B1 (ko)

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Application Number Priority Date Filing Date Title
GBGB9626428.8A GB9626428D0 (en) 1996-12-19 1996-12-19 Process
GB9626428.8 1996-12-19

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KR19980064381A KR19980064381A (ko) 1998-10-07
KR100503706B1 true KR100503706B1 (ko) 2005-09-26

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US (1) US5883295A (enExample)
EP (1) EP0849251B1 (enExample)
JP (1) JP4017725B2 (enExample)
KR (1) KR100503706B1 (enExample)
CN (1) CN1121370C (enExample)
AR (1) AR010831A1 (enExample)
BR (1) BR9706698A (enExample)
CA (1) CA2225142C (enExample)
DE (1) DE69716860T2 (enExample)
GB (1) GB9626428D0 (enExample)
ID (1) ID19222A (enExample)
MX (1) MX9710428A (enExample)
MY (1) MY118787A (enExample)
NO (1) NO975918L (enExample)
NZ (1) NZ329434A (enExample)
SA (1) SA98190162B1 (enExample)
SG (1) SG73485A1 (enExample)
TW (1) TW412524B (enExample)
UA (1) UA52606C2 (enExample)
ZA (1) ZA9711262B (enExample)

Families Citing this family (75)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2746795B1 (fr) * 1996-03-27 1998-06-19 Rhone Poulenc Chimie Procede de preparation d'acide acetique et/ou d'acetate de methyle par isomerisation et carbonylation
FR2746794B1 (fr) * 1996-03-27 1998-06-12 Rhone Poulenc Chimie Procede de preparation d'acide acetique et/ou d'acetate de methyle par isomerisation de formiate de methyle
US6211405B1 (en) 1998-10-23 2001-04-03 Celanese International Corporation Addition of iridium to the rhodium/inorganic iodide catalyst system
US6552221B1 (en) 1998-12-18 2003-04-22 Millenium Petrochemicals, Inc. Process control for acetic acid manufacture
US6232352B1 (en) 1999-11-01 2001-05-15 Acetex Limited Methanol plant retrofit for acetic acid manufacture
US6781014B1 (en) 1999-11-01 2004-08-24 Acetex (Cyprus) Limited Methanol plant retrofit for manufacture of acetic acid
US6274096B1 (en) 1999-11-01 2001-08-14 Acetex (Cyprus) Limited Methanol plant retrofit
US6458995B1 (en) 2000-03-31 2002-10-01 Celanese International Corporation Catalytic composition for carbonylation including iridium and pyridine polymers
KR20030016370A (ko) * 2000-07-06 2003-02-26 밀레니엄 페트로케미칼스 인코포레이티드 초산 제조를 위한 공정 제어 방법
US6627770B1 (en) 2000-08-24 2003-09-30 Celanese International Corporation Method and apparatus for sequesting entrained and volatile catalyst species in a carbonylation process
US6531630B2 (en) 2000-12-29 2003-03-11 Kenneth Ebenes Vidalin Bimodal acetic acid manufacture
US7005541B2 (en) * 2002-12-23 2006-02-28 Celanese International Corporation Low water methanol carbonylation process for high acetic acid production and for water balance control
US6846951B1 (en) 2003-10-09 2005-01-25 Acetex (Cyprus) Limited Integrated process for acetic acid and methanol
MY146697A (en) 2004-07-09 2012-09-14 Acetex Cyprus Ltd Preparation of syngas for acetic acid synthesis by partial oxidation of methanol feedstock
CA2496839A1 (en) 2004-07-19 2006-01-19 Woodland Chemical Systems Inc. Process for producing ethanol from synthesis gas rich in carbon monoxide
KR20080108605A (ko) * 2006-04-05 2008-12-15 우드랜드 바이오퓨엘스 인크. 합성 가스에 의해 바이오매스를 에탄올로 전환시키는 시스템 및 방법
US7902398B2 (en) 2007-04-25 2011-03-08 Celanese International Corporation Method and apparatus for carbonylation with reduced catalyst loss
US7989659B2 (en) 2007-05-17 2011-08-02 Celanese International Corporation Method and apparatus for making acetic acid with improved light ends column productivity
US7619113B2 (en) * 2007-09-27 2009-11-17 Celanese International Corporation Method and apparatus for making acetic acid with improved purification
US7902397B2 (en) * 2007-10-11 2011-03-08 Celanese International Corporation Method and apparatus for making acetic acid with improved productivity
US7820855B2 (en) * 2008-04-29 2010-10-26 Celanese International Corporation Method and apparatus for carbonylating methanol with acetic acid enriched flash stream
MX2010011850A (es) 2008-04-29 2010-11-30 Celanese Int Corp Sistema de carbonilacion de metanol que tiene un absorbedor con multiples opciones de disolvente.
US7884237B2 (en) * 2008-11-07 2011-02-08 Celanese International Corp. Methanol carbonylation with improved aldehyde removal
US8168822B2 (en) 2009-07-07 2012-05-01 Celanese International Corporation Acetic acid production by way of carbonylation with enhanced reaction and flashing
US8455685B2 (en) * 2009-07-07 2013-06-04 Celanese International Corporation Acetic anhydride production by way of carbonylation with enhanced reaction and flashing
US8575403B2 (en) 2010-05-07 2013-11-05 Celanese International Corporation Hydrolysis of ethyl acetate in ethanol separation process
US8569551B2 (en) 2010-05-07 2013-10-29 Celanese International Corporation Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process
WO2012148509A1 (en) 2011-04-26 2012-11-01 Celanese International Corporation Process for producing ethanol using a stacked bed reactor
US8710279B2 (en) 2010-07-09 2014-04-29 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US8859827B2 (en) 2011-11-18 2014-10-14 Celanese International Corporation Esterifying acetic acid to produce ester feed for hydrogenolysis
US9272970B2 (en) 2010-07-09 2016-03-01 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US8664454B2 (en) 2010-07-09 2014-03-04 Celanese International Corporation Process for production of ethanol using a mixed feed using copper containing catalyst
US8378141B2 (en) 2010-08-16 2013-02-19 Celanese International Corporation Process and system for supplying vapor from drying column to light ends column
US8530696B2 (en) 2010-09-24 2013-09-10 Celanese International Corporation Pump around reactor for production of acetic acid
US8877963B2 (en) 2010-09-28 2014-11-04 Celanese International Corporation Production of acetic acid with high conversion rate
US8394988B2 (en) 2010-09-28 2013-03-12 Celanese International Corporation Production of acetic acid with high conversion rate
US8461379B2 (en) 2010-10-12 2013-06-11 Celanese International Corporation Production of acetic acid comprising feeding at least one reactant to a recycle stream
CN102442897B (zh) * 2010-10-13 2014-05-28 中国石油化工股份有限公司 一种羰基化反应制备乙酸的方法
CN103153932A (zh) 2010-10-13 2013-06-12 国际人造丝公司 回收卤素促进剂和除去高锰酸盐还原化合物的方法
US8637698B2 (en) 2010-11-19 2014-01-28 Celanese International Corporation Production of acetic acid with an increased production rate
US8563773B2 (en) 2010-12-16 2013-10-22 Celanese International Corporation Eductor-based reactor and pump around loops for production of acetic acid
TW201302684A (zh) 2011-04-26 2013-01-16 Celanese Int Corp 由醋酸進料及再循環醋酸乙酯進料生產乙醇之製程
US8686199B2 (en) 2011-04-26 2014-04-01 Celanese International Corporation Process for reducing the concentration of acetic acid in a crude alcohol product
US8884081B2 (en) 2011-04-26 2014-11-11 Celanese International Corporation Integrated process for producing acetic acid and alcohol
US8754268B2 (en) 2011-04-26 2014-06-17 Celanese International Corporation Process for removing water from alcohol mixtures
US9073816B2 (en) 2011-04-26 2015-07-07 Celanese International Corporation Reducing ethyl acetate concentration in recycle streams for ethanol production processes
US8592635B2 (en) 2011-04-26 2013-11-26 Celanese International Corporation Integrated ethanol production by extracting halides from acetic acid
US8697908B2 (en) 2011-05-05 2014-04-15 Celanese International Corporation Removal of amine compounds from carbonylation process stream containing corrosion metal contaminants
WO2012151377A1 (en) 2011-05-05 2012-11-08 Celanese International Corporation Removal of aromatics from carbonylation process
US8895786B2 (en) 2011-08-03 2014-11-25 Celanese International Corporation Processes for increasing alcohol production
US9663437B2 (en) 2011-09-13 2017-05-30 Celanese International Corporation Production of acetic acid with high conversion rate
US8686201B2 (en) 2011-11-09 2014-04-01 Celanese International Corporation Integrated acid and alcohol production process having flashing to recover acid production catalyst
WO2013070210A1 (en) 2011-11-09 2013-05-16 Celanese International Corporation Integrated carbonylation and hydrogenation process to obtain ethanol having flashing to recover acid production catalyst
US8614359B2 (en) 2011-11-09 2013-12-24 Celanese International Corporation Integrated acid and alcohol production process
WO2013070209A1 (en) 2011-11-09 2013-05-16 Celanese International Corporation Integrated carbonylation and hydrogenation process to obtain ethanol
US8748673B2 (en) 2011-11-18 2014-06-10 Celanese International Corporation Process of recovery of ethanol from hydrogenolysis process
WO2013078207A1 (en) 2011-11-22 2013-05-30 Celanese International Corporation Esterifying an ethanol and acetic acid mixture to produce an ester feed for hydrogenolysis
WO2013078212A1 (en) 2011-11-22 2013-05-30 Celanese International Corporation Hydrogenating acetic acid to produce ethyl acetate and reducing ethyl acetate to ethanol
US9029614B2 (en) 2011-12-14 2015-05-12 Celanese International Corporation Phasing reactor product from hydrogenating acetic acid into ethyl acetate feed to produce ethanol
US20130172633A1 (en) 2011-12-29 2013-07-04 Celanese International Corporation Process For Producing Ethanol From Impure Methanol
BR112013007324B1 (pt) 2012-02-08 2020-10-20 Celanese International Corporation produção de ácido acético com alta taxa de conversão
US8859810B2 (en) 2012-08-21 2014-10-14 Celanese International Corporation Process for recovering permanganate reducing compounds from an acetic acid production process
WO2014143840A2 (en) 2013-03-15 2014-09-18 Celanese International Corporation Process for separating product gas using carbonylation processes
US9505691B2 (en) 2014-10-02 2016-11-29 Celanese International Corporation Process for producing acetic acid
US9260369B1 (en) 2014-11-14 2016-02-16 Celanese International Corporation Processes for producing acetic acid product having low butyl acetate content
US9302975B1 (en) 2015-07-01 2016-04-05 Celanese International Corporation Process for flashing a reaction medium
US9487464B2 (en) 2015-01-30 2016-11-08 Celanese International Corporation Processes for producing acetic acid
US9561994B2 (en) 2015-01-30 2017-02-07 Celanese International Corporation Processes for producing acetic acid
US9505696B2 (en) 2015-02-04 2016-11-29 Celanese International Corporation Process to control HI concentration in residuum stream
US9382183B1 (en) 2015-07-01 2016-07-05 Celanese International Corporation Process for flashing a reaction medium
US9302974B1 (en) 2015-07-01 2016-04-05 Celanese International Corporation Process for producing acetic acid
CN108137468B (zh) 2015-10-02 2021-04-13 国际人造丝公司 使用水的再循环生产乙酸的方法
US9908835B2 (en) 2015-11-13 2018-03-06 Celanese International Corporation Processes for purifying acetic and hydrating anhydride
US9957216B2 (en) 2015-11-13 2018-05-01 Celanese International Corporation Processes for producing acetic acid
MX2022015387A (es) 2020-06-03 2023-01-16 Celanese Int Corp Produccion y purificacion de acido acetico.

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE364254B (enExample) * 1967-04-05 1974-02-18 Monsanto Co
GB9306409D0 (en) * 1993-03-26 1993-05-19 Bp Chem Int Ltd Process
FR2725443B1 (fr) * 1994-10-05 1996-12-20 Rhone Poulenc Chimie Preparation d'acides carboxyliques ou des esters correspondants par carbonylation en presence d'iridium

Also Published As

Publication number Publication date
AR010831A1 (es) 2000-07-12
GB9626428D0 (en) 1997-02-05
SG73485A1 (en) 2000-06-20
CN1121370C (zh) 2003-09-17
DE69716860D1 (de) 2002-12-12
JPH10310549A (ja) 1998-11-24
TW412524B (en) 2000-11-21
CN1187483A (zh) 1998-07-15
BR9706698A (pt) 1999-05-18
KR19980064381A (ko) 1998-10-07
NO975918D0 (no) 1997-12-16
CA2225142C (en) 2006-12-05
NZ329434A (en) 2000-05-26
ID19222A (id) 1998-06-28
ZA9711262B (en) 1999-06-15
MY118787A (en) 2005-01-31
EP0849251A1 (en) 1998-06-24
MX9710428A (es) 1998-09-30
NO975918L (no) 1998-06-22
SA98190162B1 (ar) 2006-09-09
UA52606C2 (uk) 2003-01-15
EP0849251B1 (en) 2002-11-06
US5883295A (en) 1999-03-16
DE69716860T2 (de) 2003-07-31
CA2225142A1 (en) 1998-06-19
JP4017725B2 (ja) 2007-12-05

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