KR100460363B1 - 결정성의미세다공성및메조다공성금속규산염의제조방법,이러한방법에의해수득된금속규산염으로이루어진성형체및당해금속규산염을촉매로서사용하는방법 - Google Patents

결정성의미세다공성및메조다공성금속규산염의제조방법,이러한방법에의해수득된금속규산염으로이루어진성형체및당해금속규산염을촉매로서사용하는방법 Download PDF

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Publication number
KR100460363B1
KR100460363B1 KR1019970025617A KR19970025617A KR100460363B1 KR 100460363 B1 KR100460363 B1 KR 100460363B1 KR 1019970025617 A KR1019970025617 A KR 1019970025617A KR 19970025617 A KR19970025617 A KR 19970025617A KR 100460363 B1 KR100460363 B1 KR 100460363B1
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South Korea
Prior art keywords
metal silicate
metal
sio
mixed oxide
mesoporous
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KR1019970025617A
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English (en)
Korean (ko)
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KR980001826A (ko
Inventor
슈테펜 하젠찰
헬무트 망골트
액케하르트 롤란트
마리오 숄츠
게오르크 틸레
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데구사 아게
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Publication of KR980001826A publication Critical patent/KR980001826A/ko
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1019970025617A 1996-06-19 1997-06-19 결정성의미세다공성및메조다공성금속규산염의제조방법,이러한방법에의해수득된금속규산염으로이루어진성형체및당해금속규산염을촉매로서사용하는방법 KR100460363B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19624340.8 1996-06-19
DE19624340A DE19624340A1 (de) 1996-06-19 1996-06-19 Verfahren zur Herstellung von kristallinen mikro- und mesoporösen Metallsilicaten, verfahrensgemäß erhältliche Produkte und deren Verwendung

Publications (2)

Publication Number Publication Date
KR980001826A KR980001826A (ko) 1998-03-30
KR100460363B1 true KR100460363B1 (ko) 2005-02-03

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019970025617A KR100460363B1 (ko) 1996-06-19 1997-06-19 결정성의미세다공성및메조다공성금속규산염의제조방법,이러한방법에의해수득된금속규산염으로이루어진성형체및당해금속규산염을촉매로서사용하는방법

Country Status (14)

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EP (1) EP0814058B1 (US07943777-20110517-C00090.png)
JP (1) JP3166904B2 (US07943777-20110517-C00090.png)
KR (1) KR100460363B1 (US07943777-20110517-C00090.png)
CN (1) CN1094899C (US07943777-20110517-C00090.png)
AR (1) AR013582A1 (US07943777-20110517-C00090.png)
BR (1) BR9703631A (US07943777-20110517-C00090.png)
DE (2) DE19624340A1 (US07943777-20110517-C00090.png)
ES (1) ES2132984T3 (US07943777-20110517-C00090.png)
ID (1) ID17360A (US07943777-20110517-C00090.png)
IN (1) IN191885B (US07943777-20110517-C00090.png)
MY (1) MY115092A (US07943777-20110517-C00090.png)
SG (1) SG52988A1 (US07943777-20110517-C00090.png)
TW (1) TW416866B (US07943777-20110517-C00090.png)
ZA (1) ZA975388B (US07943777-20110517-C00090.png)

Cited By (3)

* Cited by examiner, † Cited by third party
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KR101080523B1 (ko) * 2006-04-15 2011-11-04 에보니크 데구사 게엠베하 규소-티탄 혼합 산화물 분말, 그의 분산액 및 그로부터 제조된 티탄-함유 제올라이트
KR101156885B1 (ko) * 2007-10-16 2012-07-13 에보니크 데구사 게엠베하 규소-티타늄 혼합 산화물 분말, 이의 분산액 및 이로부터 제조된 티타늄 함유 제올라이트
KR20200096525A (ko) * 2017-12-07 2020-08-12 에보닉 오퍼레이션스 게엠베하 화염 분무 열분해에 의한 미분, 다공성 결정질 금속 실리케이트의 제조

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EP0987220A1 (en) * 1998-09-17 2000-03-22 Technische Universiteit Delft Mesoporous amorphous silicate materials and process for the preparation thereof
DE19731627A1 (de) 1997-07-23 1999-01-28 Degussa Granulate, enthaltend Titansilikalit-l
US7608747B2 (en) 1999-09-07 2009-10-27 Lummus Technology Inc. Aromatics hydrogenolysis using novel mesoporous catalyst system
US6906208B2 (en) * 1999-09-07 2005-06-14 Abb Lummus Global Inc. Mesoporous material and use thereof for the selective oxidation of organic compounds
IT1314001B1 (it) * 1999-11-19 2002-12-03 Enichem Spa Metodo per la rimozione del templante da zeoliti sintetiche
CA2496898C (en) * 2002-08-28 2011-10-18 Albemarle Netherlands B.V. Process for the preparation of doped pentasil-type zeolites using a doped reactant
US6969692B2 (en) 2002-08-28 2005-11-29 Albemarle Netherlands B.V. Process for the preparation of doped pentasil-type zeolites using a doped reactant
DE102006017700A1 (de) 2006-04-15 2007-10-25 Degussa Gmbh Silicium-Titan-Mischoxid enthaltende Dispersion zur Herstellung titanhaltiger Zeolithe
DE102007049742A1 (de) 2007-10-16 2009-04-23 Evonik Degussa Gmbh Verfahren zur Herstellung einer Titan-Silicium-Mischoxid enthaltenden Dispersion
CN101659417B (zh) * 2008-08-28 2011-06-22 中国科学院合肥物质科学研究院 多孔硅酸盐纳米空心颗粒及其制备方法
CZ304248B6 (cs) * 2009-07-28 2014-01-29 Výzkumný ústav anorganické chemie, a. s. Způsob výroby titanosilikátu Ti-ZSM-5 s MFI strukturou
CZ302444B6 (cs) * 2010-04-01 2011-05-18 Výzkumný ústav anorganické chemie, a.s. Zpusob výroby titanosilikátu Ti-ZSM-5 z polotovaru
SG11201406841SA (en) * 2012-04-24 2014-11-27 Basf Se Zeolitic materials and methods for their preparation using alkenyltrialkylammonium compounds
RU2014146902A (ru) * 2012-04-24 2016-06-10 Басф Се Каталитически активное тело для синтеза диметилового эфира из синтез-газа
US9475041B2 (en) 2012-04-24 2016-10-25 Basf Se Zeolitic materials and methods for their preparation using alkenyltrialkylammonium compounds
KR101771387B1 (ko) 2014-07-29 2017-08-24 에보닉 데구사 게엠베하 올레핀의 에폭시화 방법
EP3056501A1 (de) 2015-02-13 2016-08-17 Evonik Degussa GmbH Titanathaltige, wässerige Lösung und Dispersion
WO2016173887A1 (en) 2015-04-28 2016-11-03 Evonik Degussa Gmbh Process for the epoxidation of propene
CN110167886B (zh) 2017-01-09 2022-05-24 赢创运营有限公司 借助喷雾热解法制备金属氧化物的方法
EP3438101A1 (en) 2017-08-01 2019-02-06 Evonik Degussa GmbH Process for the epoxidation of propene
EP3628642A1 (en) * 2018-09-25 2020-04-01 Evonik Operations GmbH Process for the manufacture of pulverulent, porous crystalline metal silicates employing flame spray pyrolysis

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EP0311983A2 (en) * 1987-10-12 1989-04-19 Enichem Anic S.r.l. Method for the preparation of titanium-silicalites
EP0712852A1 (en) * 1994-11-16 1996-05-22 ARCO Chemical Technology, L.P. Improved process for titanium silicalite-catalyzed epoxidation
US5525563A (en) * 1993-07-12 1996-06-11 Degussa Aktiengesellschaft Structured catalyst including microporous oxides of silicon, aluminum and titianium
US5599955A (en) * 1996-02-22 1997-02-04 Uop Process for producing propylene oxide

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DE3021580A1 (de) * 1980-06-07 1981-12-24 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von zeolithen und verwendung derselben als katalysatoren
DE3031557C2 (de) * 1980-08-21 1986-05-22 Basf Ag, 6700 Ludwigshafen Kristalliner Borsilikatzeolith ZBM-30 und Verfahren zu seiner Herstellung
FR2582639B1 (fr) * 1985-05-28 1987-08-28 Centre Nat Rech Scient Nouveau procede de synthese de zeolites du type borosilicate, produits ainsi obtenus et leur utilisation
EP0292363B1 (fr) * 1987-05-22 1993-04-21 Rhone-Poulenc Chimie Zéolites de structures MFI à base de silice et d'oxyde de titane et procédé de synthèse de celles-ci
IT1222022B (it) * 1987-07-14 1990-08-31 Montedipe Spa Metodo per la preparazione di un catalizzatore per l' ammossimazione di composti carbonilici
DE4138155A1 (de) * 1991-11-21 1993-05-27 Basf Ag Verfahren zur herstellung von im wesentlichen alkalifreien titansilikat-kristallen mit zeolithstruktur

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Publication number Priority date Publication date Assignee Title
EP0311983A2 (en) * 1987-10-12 1989-04-19 Enichem Anic S.r.l. Method for the preparation of titanium-silicalites
US5525563A (en) * 1993-07-12 1996-06-11 Degussa Aktiengesellschaft Structured catalyst including microporous oxides of silicon, aluminum and titianium
US5637715A (en) * 1993-07-12 1997-06-10 Degussa Aktiengesellschaft Process for preparing an oxime a structured catalyst including microporous oxides of silicon, aluminum and titanium
EP0712852A1 (en) * 1994-11-16 1996-05-22 ARCO Chemical Technology, L.P. Improved process for titanium silicalite-catalyzed epoxidation
US5599955A (en) * 1996-02-22 1997-02-04 Uop Process for producing propylene oxide

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101080523B1 (ko) * 2006-04-15 2011-11-04 에보니크 데구사 게엠베하 규소-티탄 혼합 산화물 분말, 그의 분산액 및 그로부터 제조된 티탄-함유 제올라이트
KR101156885B1 (ko) * 2007-10-16 2012-07-13 에보니크 데구사 게엠베하 규소-티타늄 혼합 산화물 분말, 이의 분산액 및 이로부터 제조된 티타늄 함유 제올라이트
KR20200096525A (ko) * 2017-12-07 2020-08-12 에보닉 오퍼레이션스 게엠베하 화염 분무 열분해에 의한 미분, 다공성 결정질 금속 실리케이트의 제조
KR102646969B1 (ko) 2017-12-07 2024-03-12 에보닉 오퍼레이션스 게엠베하 화염 분무 열분해에 의한 미분, 다공성 결정질 금속 실리케이트의 제조

Also Published As

Publication number Publication date
KR980001826A (ko) 1998-03-30
JP3166904B2 (ja) 2001-05-14
BR9703631A (pt) 1998-11-10
DE59700056D1 (de) 1999-02-04
ZA975388B (en) 1998-01-05
DE19624340A1 (de) 1998-01-08
JPH1095610A (ja) 1998-04-14
ID17360A (id) 1997-12-24
ES2132984T3 (es) 1999-08-16
EP0814058A1 (de) 1997-12-29
IN191885B (US07943777-20110517-C00090.png) 2004-01-10
TW416866B (en) 2001-01-01
SG52988A1 (en) 1998-09-28
AR013582A1 (es) 2001-01-10
CN1094899C (zh) 2002-11-27
EP0814058B1 (de) 1998-12-23
CN1168860A (zh) 1997-12-31
MY115092A (en) 2003-03-31

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