KR100368692B1 - 반경 방향으로 변화하는 물성을 지니는 봉형 고분자 모재,그의 제조방법 및 이에 사용되는 장치 - Google Patents
반경 방향으로 변화하는 물성을 지니는 봉형 고분자 모재,그의 제조방법 및 이에 사용되는 장치 Download PDFInfo
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- KR100368692B1 KR100368692B1 KR10-2000-0014204A KR20000014204A KR100368692B1 KR 100368692 B1 KR100368692 B1 KR 100368692B1 KR 20000014204 A KR20000014204 A KR 20000014204A KR 100368692 B1 KR100368692 B1 KR 100368692B1
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- 238000000034 method Methods 0.000 title claims abstract description 49
- 229920000642 polymer Polymers 0.000 title claims abstract description 38
- 230000008569 process Effects 0.000 title description 22
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- 239000000203 mixture Substances 0.000 claims description 26
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- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 11
- 230000003287 optical effect Effects 0.000 claims description 9
- XLKWQAQYRNTVKF-UHFFFAOYSA-N 1,1,2,3,3,4,5-heptafluoro-5-(1,2,3,3,4,5,5-heptafluoropenta-1,4-dienoxy)penta-1,4-diene Chemical compound FC(F)=C(F)C(F)(F)C(F)=C(F)OC(F)=C(F)C(F)(F)C(F)=C(F)F XLKWQAQYRNTVKF-UHFFFAOYSA-N 0.000 claims description 8
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 8
- JMGNVALALWCTLC-UHFFFAOYSA-N 1-fluoro-2-(2-fluoroethenoxy)ethene Chemical compound FC=COC=CF JMGNVALALWCTLC-UHFFFAOYSA-N 0.000 claims description 8
- YSYRISKCBOPJRG-UHFFFAOYSA-N 4,5-difluoro-2,2-bis(trifluoromethyl)-1,3-dioxole Chemical compound FC1=C(F)OC(C(F)(F)F)(C(F)(F)F)O1 YSYRISKCBOPJRG-UHFFFAOYSA-N 0.000 claims description 8
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 claims description 8
- 239000011159 matrix material Substances 0.000 claims description 8
- 229920000570 polyether Polymers 0.000 claims description 8
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 8
- -1 propylene, trifluoroethylene Chemical group 0.000 claims description 7
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 claims description 4
- 229920001897 terpolymer Polymers 0.000 claims description 4
- CLISWDZSTWQFNX-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)C(F)(F)F CLISWDZSTWQFNX-UHFFFAOYSA-N 0.000 claims description 2
- VIEHKBXCWMMOOU-UHFFFAOYSA-N 2,2,3,3,4,4,4-heptafluorobutyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)C(F)(F)C(F)(F)F VIEHKBXCWMMOOU-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 claims description 2
- 125000004206 2,2,2-trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 claims 1
- 239000006185 dispersion Substances 0.000 abstract description 5
- 239000012535 impurity Substances 0.000 abstract description 3
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 15
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- 229920000297 Rayon Polymers 0.000 description 2
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- LBHPSYROQDMVBS-UHFFFAOYSA-N (1-methylcyclohexyl) 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1(C)CCCCC1 LBHPSYROQDMVBS-UHFFFAOYSA-N 0.000 description 1
- FOEQQJNHGXZVLE-UHFFFAOYSA-N (1-phenylcyclohexyl) 2-methylprop-2-enoate Chemical compound C=1C=CC=CC=1C1(OC(=O)C(=C)C)CCCCC1 FOEQQJNHGXZVLE-UHFFFAOYSA-N 0.000 description 1
- OFZRSOGEOFHZKS-UHFFFAOYSA-N (2,3,4,5,6-pentabromophenyl) 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br OFZRSOGEOFHZKS-UHFFFAOYSA-N 0.000 description 1
- AYYISYPLHCSQGL-UHFFFAOYSA-N (2,3,4,5,6-pentachlorophenyl) 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl AYYISYPLHCSQGL-UHFFFAOYSA-N 0.000 description 1
- IWTINSUNRUQBBO-UHFFFAOYSA-N 1,2-diphenylethyl 2-methylprop-2-enoate Chemical compound C=1C=CC=CC=1C(OC(=O)C(=C)C)CC1=CC=CC=C1 IWTINSUNRUQBBO-UHFFFAOYSA-N 0.000 description 1
- BQMWZHUIGYNOAL-UHFFFAOYSA-N 1-phenylethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)C1=CC=CC=C1 BQMWZHUIGYNOAL-UHFFFAOYSA-N 0.000 description 1
- QTKPMCIBUROOGY-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)F QTKPMCIBUROOGY-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- DQVUUGHMHQPVSI-UHFFFAOYSA-N [chloro(phenyl)methyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(Cl)C1=CC=CC=C1 DQVUUGHMHQPVSI-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- AVXYPAZKABBYHD-UHFFFAOYSA-N benzhydryl 2-methylprop-2-enoate Chemical compound C=1C=CC=CC=1C(OC(=O)C(=C)C)C1=CC=CC=C1 AVXYPAZKABBYHD-UHFFFAOYSA-N 0.000 description 1
- VUQZZYCIFMNCRQ-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate;methyl 2-methylprop-2-enoate Chemical compound COC(=O)C(C)=C.CC(=C)C(=O)OCC1=CC=CC=C1 VUQZZYCIFMNCRQ-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 229910000856 hastalloy Inorganic materials 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
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- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 230000008054 signal transmission Effects 0.000 description 1
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- 229910001220 stainless steel Inorganic materials 0.000 description 1
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- 238000005979 thermal decomposition reaction Methods 0.000 description 1
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- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00663—Production of light guides
- B29D11/00721—Production of light guides involving preforms for the manufacture of light guides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/02—Polymerisation in bulk
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Ophthalmology & Optometry (AREA)
- Mechanical Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
Abstract
Description
Claims (18)
- 관형 반응기에 모재 원료물질을 투입하고, 상기 반응기를 회전시키면서 가열하여 원료물질을 반응시키고, 상기 원료물질 투입 및 반응 공정을 2회 이상 반복함으로써 봉형 고분자 모재를 제조하는 방법에 있어서, 상기 원료물질 투입 및 반응 공정의 각 단계에 투입되는 원료물질을 그의 종류 및 성분을 변화시키고, 상기 원료물질 투입 및 반응 공정의 연속된 두 단계에 있어서 이전 단계용 원료 물질의 전환이 완결되기 전에 후속 단계용 원료물질을 투입하는 것을 특징으로 하는, 횡단면 중심으로부터 방사형으로 물성이 변화되는 봉형 고분자 모재의 제조방법.
- 제 1 항에 있어서,상기 고분자 모재의 횡단면이 원형, 타원형, 다각형 또는 기하학적 모양인 것을 특징으로 하는 방법.
- 제 1 항에 있어서,상기 반응기를 10 내지 2,000rpm의 속도로 회전시키는 것을 특징으로 하는 방법.
- 삭제
- 삭제
- 삭제
- 제 1 항에 있어서,상기 모재 원료물질이, 메틸메타크릴레이트(MMA)-벤질메타크릴레이트(BMA)공중합체, 스티렌-아크릴로니트릴 공중합체(SAN), MMA-TFEMA (2,2,2-트리플루오로에틸메타크릴레이트) 공중합체, MMA-PFPMA (2,2,3,3,3-펜타플루오로프로필메타크릴레이트) 공중합체, MMA-HFIPMA (1,1,1,3,3,3-헥사플루오로이소메타크릴레이트) 공중합체, MMA-HFBMA (2,2,3,3,4,4,4-헵타플루오로부틸메타크릴레이트) 공중합체, TFEMA-PFPMA 공중합체, TFEMA-HFIPMA 공중합체, 및 TFEMA-HFBMA 공중합체로 이루어진 군으로부터 선택되는 것을 특징으로 하는 방법.
- 제 1 항에 있어서,상기 모재 원료물질이, 제1 단량체인 퍼플루오로-2,2-디메틸-1,3-다이옥솔(PDD)과, 테트라플루오로에틸렌, 클로로트리플루오로에틸렌, 비닐리덴플로라이드, 헥사플루오로프로필렌, 트리플루오로에틸렌, 퍼플루오로알릴비닐에테르, 플루오로비닐에테르 중에서 선택된 제2 단량체와의 중합에 의해서 형성되는 폴리에테르 형태의 공중합체; 제1 단량체인 퍼플루오로-2,2-디메틸-1,3-다이옥솔(PDD)과, 테트라플루오로에틸렌, 클로로트리플루오로에틸렌, 비닐리덴플로라이드, 헥사플루오로프로필렌, 트리플루오로에틸렌, 퍼플루오로알릴비닐에테르, 플루오로비닐에테르 중에서 선택된 제2 및 제3 단량체와의 중합에 의해서 형성되는 폴리에테르 형태의 삼원공중합체; 제1 단량체인 퍼플루오로알릴비닐에테르와, 퍼플루오로-2,2-디메틸-1,3-다이옥솔(PDD), 테트라플루오로에틸렌, 클로로트리플루오로에틸렌, 비닐리덴플로라이드, 헥사플루오로프로필렌, 트리플루오로에틸렌, 플루오로비닐에테르 중에서 선택된 제2 단량체와의 중합에 의해서 형성되는 폴리에테르 형태의 공중합체; 및 제1 단량체인 퍼플루오로알릴비닐에테르와 퍼플루오로-2,2-디메틸-1,3-다이옥솔(PDD), 테트라플루오로에틸렌, 클로로트리플루오로에틸렌, 비닐리덴플로라이드, 헥사플루오로프로필렌, 트라이플루오로에틸렌, 플루오로비닐에테르 중에서 선택된 제2 및 제3 단량체와의 중합에 의해서 형성되는 폴리에테르 형태의 삼원 공중합체로 이루어진 군으로부터 선택되는 것을 특징으로 하는 방법.
- 제 1 항에 있어서,상기 물성이 광학적 성질인 것을 특징으로 하는 방법.
- 제 9 항에 있어서,상기 광학적 성질이 굴절율인 것을 특징으로 하는 방법.
- 삭제
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- 제 1 항 내지 제 3 항 및 제 7 항 내지 제 10 항의 어느 한 항의 방법에 의해 제조되는, 횡단면 중심으로부터 방사형으로 물성이 변화되는 봉형 고분자 모재.
- 제 14 항의 모재를 연신가공하여 제조된 고분자 광섬유.
- 제 15 항에 있어서,상기 광섬유가 스텝-인덱스(SI), 멀티스텝-인덱스 또는 그레이디드-인덱스(GI) 형태인 것을 특징으로 하는 고분자 광섬유.
- 제 14 항의 모재를 절삭가공하여 제조된 광학 렌즈.
- 제 17 항에 있어서, 멀티스텝-인덱스 또는 그레이디드-인덱스(GI) 형태인 것을 특징으로 하는 광학 렌즈.
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2000-0014204A KR100368692B1 (ko) | 2000-03-21 | 2000-03-21 | 반경 방향으로 변화하는 물성을 지니는 봉형 고분자 모재,그의 제조방법 및 이에 사용되는 장치 |
CN01806890A CN1419568A (zh) | 2000-03-21 | 2001-03-21 | 具有变化径向性能的棒形聚合物预制体,其制备方法和所用装置 |
PCT/KR2001/000445 WO2001070823A1 (en) | 2000-03-21 | 2001-03-21 | Rod type polymer preform having radially-varying properties, process for the preparation thereof and apparatus therefor |
EP01922075A EP1268560A4 (en) | 2000-03-21 | 2001-03-21 | BAR-TYPE POLYMERIC PREFORM HAVING RADIAL VARIATION PROPERTIES, PROCESS FOR PREPARING THE SAME AND DEVICE THEREFOR |
US10/221,595 US20030091306A1 (en) | 2000-03-21 | 2001-03-21 | Rod type polymer preform having radially-varying properties, process for the preparation thereof and apparatus therefor |
AU2001248860A AU2001248860A1 (en) | 2000-03-21 | 2001-03-21 | Rod type polymer preform having radially-varying properties, process for the preparation thereof and apparatus therefor |
Applications Claiming Priority (1)
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KR10-2000-0014204A KR100368692B1 (ko) | 2000-03-21 | 2000-03-21 | 반경 방향으로 변화하는 물성을 지니는 봉형 고분자 모재,그의 제조방법 및 이에 사용되는 장치 |
Publications (2)
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KR20010092159A KR20010092159A (ko) | 2001-10-24 |
KR100368692B1 true KR100368692B1 (ko) | 2003-01-24 |
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KR10-2000-0014204A KR100368692B1 (ko) | 2000-03-21 | 2000-03-21 | 반경 방향으로 변화하는 물성을 지니는 봉형 고분자 모재,그의 제조방법 및 이에 사용되는 장치 |
Country Status (6)
Country | Link |
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US (1) | US20030091306A1 (ko) |
EP (1) | EP1268560A4 (ko) |
KR (1) | KR100368692B1 (ko) |
CN (1) | CN1419568A (ko) |
AU (1) | AU2001248860A1 (ko) |
WO (1) | WO2001070823A1 (ko) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100437281B1 (ko) * | 2002-07-16 | 2004-06-23 | 에스케이씨 주식회사 | 플라스틱 광섬유 모재 내부 첨가 물질의 열 확산을 이용한유사 포물선형 굴절률 분포 제조방법 및 가열기 |
WO2004072697A1 (en) * | 2003-02-10 | 2004-08-26 | Nanoptics, Incorporated | Method and apparatus for manufacturing plastic optical transmission medium |
KR20050051118A (ko) * | 2003-11-27 | 2005-06-01 | 삼성전자주식회사 | 플라스틱 광섬유, 플라스틱 광섬유용 모재 및 그제조방법 |
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-
2000
- 2000-03-21 KR KR10-2000-0014204A patent/KR100368692B1/ko active IP Right Grant
-
2001
- 2001-03-21 AU AU2001248860A patent/AU2001248860A1/en not_active Abandoned
- 2001-03-21 US US10/221,595 patent/US20030091306A1/en not_active Abandoned
- 2001-03-21 WO PCT/KR2001/000445 patent/WO2001070823A1/en not_active Application Discontinuation
- 2001-03-21 EP EP01922075A patent/EP1268560A4/en not_active Withdrawn
- 2001-03-21 CN CN01806890A patent/CN1419568A/zh active Pending
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EP0130838A2 (en) * | 1983-07-02 | 1985-01-09 | Nippon Sheet Glass Co., Ltd. | Method and apparatus for producing light transmitting article of synthetic resin |
US5378776A (en) * | 1991-12-26 | 1995-01-03 | Nippon Petrochemicals Company, Limited | Method for preparing optical polymer with radial transition in refractive index |
JPH08304634A (ja) * | 1995-05-12 | 1996-11-22 | Sumitomo Electric Ind Ltd | プラスチック光ファイバ母材の製造方法及びプラスチック光ファイバ |
EP0835744A1 (en) * | 1996-10-09 | 1998-04-15 | Rohm And Haas Company | Process for gradient refractive index optical objects |
KR100285152B1 (ko) * | 1999-03-24 | 2001-03-15 | 윤종용 | 물성이 반경방향으로 변하는 물체와 그 제조장치 및 제조방법 |
Also Published As
Publication number | Publication date |
---|---|
KR20010092159A (ko) | 2001-10-24 |
US20030091306A1 (en) | 2003-05-15 |
EP1268560A1 (en) | 2003-01-02 |
CN1419568A (zh) | 2003-05-21 |
AU2001248860A1 (en) | 2001-10-03 |
WO2001070823A1 (en) | 2001-09-27 |
EP1268560A4 (en) | 2003-06-04 |
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