JPWO2022138968A5 - - Google Patents
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- JPWO2022138968A5 JPWO2022138968A5 JP2022571721A JP2022571721A JPWO2022138968A5 JP WO2022138968 A5 JPWO2022138968 A5 JP WO2022138968A5 JP 2022571721 A JP2022571721 A JP 2022571721A JP 2022571721 A JP2022571721 A JP 2022571721A JP WO2022138968 A5 JPWO2022138968 A5 JP WO2022138968A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- photochromic
- general formula
- electron
- compound represented
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 150000001875 compounds Chemical class 0.000 claims description 35
- 125000001424 substituent group Chemical group 0.000 claims description 16
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- -1 dimethylamino, pyrrolidino, piperidino, morpholino Chemical group 0.000 claims description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 4
- 125000005505 thiomorpholino group Chemical group 0.000 claims description 4
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 claims description 3
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 claims description 3
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 claims description 3
- 125000000587 piperidin-1-yl group Chemical group [H]C1([H])N(*)C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 claims description 3
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 3
- WLJDEYGNLXUZNB-UHFFFAOYSA-N CCOC(OC)(OC1=CC=CC=C1)SC(OC)(OCC)OC1=CC=CC=C1 Chemical compound CCOC(OC)(OC1=CC=CC=C1)SC(OC)(OCC)OC1=CC=CC=C1 WLJDEYGNLXUZNB-UHFFFAOYSA-N 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 125000005509 dibenzothiophenyl group Chemical group 0.000 claims description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 2
- 125000006217 methyl sulfide group Chemical group [H]C([H])([H])S* 0.000 claims description 2
- 125000001624 naphthyl group Chemical group 0.000 claims description 2
- 125000006575 electron-withdrawing group Chemical group 0.000 claims 10
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 8
- 229910052731 fluorine Inorganic materials 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 125000003277 amino group Chemical group 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 125000003914 fluoranthenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC=C4C1=C23)* 0.000 claims 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 125000005062 perfluorophenyl group Chemical group FC1=C(C(=C(C(=C1F)F)F)F)* 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 230000003381 solubilizing effect Effects 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 125000000641 acridinyl group Chemical group C1(=CC=CC2=NC3=CC=CC=C3C=C12)* 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 description 1
- 125000006165 cyclic alkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- LJSQFQKUNVCTIA-UHFFFAOYSA-N diethyl sulfide Chemical compound CCSCC LJSQFQKUNVCTIA-UHFFFAOYSA-N 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 125000001791 phenazinyl group Chemical group C1(=CC=CC2=NC3=CC=CC=C3N=C12)* 0.000 description 1
- 125000001484 phenothiazinyl group Chemical group C1(=CC=CC=2SC3=CC=CC=C3NC12)* 0.000 description 1
- 125000001644 phenoxazinyl group Chemical group C1(=CC=CC=2OC3=CC=CC=C3NC12)* 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2024146374A JP2024167317A (ja) | 2020-12-24 | 2024-08-28 | フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2020215158 | 2020-12-24 | ||
| JP2020215159 | 2020-12-24 | ||
| JP2020215158 | 2020-12-24 | ||
| JP2020215159 | 2020-12-24 | ||
| JP2021018610 | 2021-02-08 | ||
| JP2021018610 | 2021-02-08 | ||
| PCT/JP2021/048401 WO2022138968A1 (ja) | 2020-12-24 | 2021-12-24 | フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2024146374A Division JP2024167317A (ja) | 2020-12-24 | 2024-08-28 | フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPWO2022138968A1 JPWO2022138968A1 (https=) | 2022-06-30 |
| JPWO2022138968A5 true JPWO2022138968A5 (https=) | 2023-09-05 |
| JP7547510B2 JP7547510B2 (ja) | 2024-09-09 |
Family
ID=82158206
Family Applications (8)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022571718A Active JP7639026B2 (ja) | 2020-12-24 | 2021-12-24 | フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
| JP2022571720A Active JP7334368B2 (ja) | 2020-12-24 | 2021-12-24 | フォトクロミック化合物、フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
| JP2022571721A Active JP7547510B2 (ja) | 2020-12-24 | 2021-12-24 | フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
| JP2022571719A Active JP7290809B2 (ja) | 2020-12-24 | 2021-12-24 | フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
| JP2023090581A Active JP7741131B2 (ja) | 2020-12-24 | 2023-06-01 | フォトクロミック物品及び眼鏡 |
| JP2023132427A Pending JP2023175687A (ja) | 2020-12-24 | 2023-08-16 | フォトクロミック化合物、フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
| JP2024146374A Pending JP2024167317A (ja) | 2020-12-24 | 2024-08-28 | フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
| JP2025024849A Pending JP2025081515A (ja) | 2020-12-24 | 2025-02-19 | フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022571718A Active JP7639026B2 (ja) | 2020-12-24 | 2021-12-24 | フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
| JP2022571720A Active JP7334368B2 (ja) | 2020-12-24 | 2021-12-24 | フォトクロミック化合物、フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
Family Applications After (5)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022571719A Active JP7290809B2 (ja) | 2020-12-24 | 2021-12-24 | フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
| JP2023090581A Active JP7741131B2 (ja) | 2020-12-24 | 2023-06-01 | フォトクロミック物品及び眼鏡 |
| JP2023132427A Pending JP2023175687A (ja) | 2020-12-24 | 2023-08-16 | フォトクロミック化合物、フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
| JP2024146374A Pending JP2024167317A (ja) | 2020-12-24 | 2024-08-28 | フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
| JP2025024849A Pending JP2025081515A (ja) | 2020-12-24 | 2025-02-19 | フォトクロミック組成物、フォトクロミック物品及び眼鏡 |
Country Status (7)
| Country | Link |
|---|---|
| US (5) | US20240103200A1 (https=) |
| EP (6) | EP4549533A1 (https=) |
| JP (8) | JP7639026B2 (https=) |
| KR (5) | KR102877222B1 (https=) |
| CN (2) | CN116323577A (https=) |
| ES (3) | ES3060286T3 (https=) |
| WO (4) | WO2022138965A1 (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES3060286T3 (en) * | 2020-12-24 | 2026-03-25 | Hoya Lens Thailand Ltd | Photochromic composition, photochromic article, and glasses |
| JP7805443B2 (ja) | 2022-03-31 | 2026-01-23 | ホヤ レンズ タイランド リミテッド | 光学物品用重合性組成物および光学物品 |
| CN119096174A (zh) | 2022-03-31 | 2024-12-06 | 豪雅镜片泰国有限公司 | 光学物品用聚合性组合物及光学物品 |
| US20260070881A1 (en) * | 2022-08-30 | 2026-03-12 | Transitions Optical, Ltd. | Photochromic Indeno-Fused Naphthopyran Compounds, Compositions, and Articles Containing Same |
| JPWO2024181425A1 (https=) | 2023-02-28 | 2024-09-06 | ||
| JPWO2024181424A1 (https=) | 2023-02-28 | 2024-09-06 | ||
| JP2024143167A (ja) | 2023-03-30 | 2024-10-11 | ホヤ レンズ タイランド リミテッド | フォトクロミック物品、眼鏡およびフォトクロミック物品の製造方法 |
| KR102694698B1 (ko) | 2023-04-21 | 2024-08-14 | 에이치디한국조선해양 주식회사 | 다중연료 엔진시스템 및 그 제어방법 |
Family Cites Families (48)
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| JP4157245B2 (ja) * | 2000-02-21 | 2008-10-01 | 株式会社トクヤマ | クロメン化合物 |
| US7320826B2 (en) * | 2003-03-20 | 2008-01-22 | Ppg Industries Ohio, Inc. | Photochromic articles with reduced temperature dependency and methods for preparation |
| US8545984B2 (en) * | 2003-07-01 | 2013-10-01 | Transitions Optical, Inc. | Photochromic compounds and compositions |
| US20110140056A1 (en) * | 2003-07-01 | 2011-06-16 | Transitions Optical, Inc. | Indeno-fused ring compounds |
| US8698117B2 (en) * | 2003-07-01 | 2014-04-15 | Transitions Optical, Inc. | Indeno-fused ring compounds |
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| US8147725B2 (en) * | 2005-04-08 | 2012-04-03 | Transitions Optical, Inc | Photochromic materials having extended pi-conjugated systems and compositions and articles including the same |
| US20060228557A1 (en) | 2005-04-08 | 2006-10-12 | Beon-Kyu Kim | Photochromic materials having extended pi-conjugated systems and compositions and articles including the same |
| US9028728B2 (en) * | 2005-04-08 | 2015-05-12 | Transitions Optical, Inc. | Photochromic materials that include indeno-fused naphthopyrans |
| US8647538B2 (en) * | 2005-04-08 | 2014-02-11 | Transitions Optical, Inc. | Photochromic compounds having at least two photochromic moieties |
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| MX2012001414A (es) * | 2009-08-04 | 2012-03-26 | Tokuyama Corp | Compuesto de cromeno. |
| BR112012006058A2 (pt) * | 2009-09-18 | 2015-09-08 | Tokuyama Corp | composto, composição fotocrômica curável, e, artigo óptico. |
| US8518305B2 (en) * | 2009-10-28 | 2013-08-27 | Transitions Optical, Inc. | Photochromic materials |
| JP2013035877A (ja) * | 2009-12-10 | 2013-02-21 | Tokuyama Corp | フォトクロミック組成物 |
| KR101097618B1 (ko) * | 2010-04-15 | 2011-12-22 | 한남대학교 산학협력단 | 신규한 페닐아잔디일기를 포함하는 인데노-융합된 나프토피란계 광변색 화합물 및 이의 제조방법 |
| US8535577B2 (en) * | 2010-04-30 | 2013-09-17 | Transitions Optical, Inc. | Photochromic materials that include 6-amino substituted indeno-fused naphthopyrans |
| US9034219B2 (en) * | 2010-12-16 | 2015-05-19 | Transitions Optical, Inc. | Photochromic compounds and compositions |
| US8920928B2 (en) * | 2010-12-16 | 2014-12-30 | Transitions Optical, Inc. | Photochromic compounds and compositions |
| PT2759543T (pt) * | 2011-09-22 | 2017-10-19 | Tokuyama Corp | Composto de cromeno e composição curável |
| WO2014151543A1 (en) * | 2013-03-15 | 2014-09-25 | Ppg Industries Ohio, Inc. | Controlled radical polymerization initiators |
| EP3071401B9 (en) * | 2013-11-20 | 2018-03-14 | Transitions Optical, Inc. | Method of forming a photochromic segmented multifocal lens |
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| JP7152173B2 (ja) * | 2018-04-17 | 2022-10-12 | 株式会社トクヤマ | フォトクロミック硬化体の製造方法 |
| JP7195209B2 (ja) * | 2018-04-17 | 2022-12-23 | 株式会社トクヤマ | フォトクロミック化合物、該フォトクロミック化合物を含む硬化性組成物、及び該硬化性組成物からなるフォトクロミック硬化体 |
| WO2019203205A1 (ja) * | 2018-04-17 | 2019-10-24 | 株式会社トクヤマ | フォトクロミック化合物、該フォトクロミック化合物を含む硬化性組成物及び光学物品 |
| US11518751B2 (en) | 2018-05-28 | 2022-12-06 | Transitions Optical, Ltd. | Photochromic indeno-fused naphthopyran compounds with reduced temperature dependence |
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| JP7149892B2 (ja) * | 2019-03-29 | 2022-10-07 | ホヤ レンズ タイランド リミテッド | 光学物品用コーティング組成物、眼鏡レンズ、眼鏡および眼鏡レンズの製造方法、ならびに光学物品および光学物品の製造方法 |
| JP7274911B2 (ja) * | 2019-03-29 | 2023-05-17 | ホヤ レンズ タイランド リミテッド | 光学物品用コーティング組成物、眼鏡レンズ、眼鏡および眼鏡レンズの製造方法、ならびに光学物品および光学物品の製造方法 |
| JP2021134330A (ja) * | 2020-02-28 | 2021-09-13 | 株式会社トクヤマ | フォトクロミック化合物、及び該フォトクロミック化合物を含む硬化性組成物 |
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| CN116194515A (zh) * | 2020-08-06 | 2023-05-30 | 株式会社德山 | 光致变色化合物、光致变色固化性组合物、固化物、透镜以及眼镜 |
| ES3060286T3 (en) * | 2020-12-24 | 2026-03-25 | Hoya Lens Thailand Ltd | Photochromic composition, photochromic article, and glasses |
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2021
- 2021-12-24 ES ES21911102T patent/ES3060286T3/es active Active
- 2021-12-24 KR KR1020237021233A patent/KR102877222B1/ko active Active
- 2021-12-24 EP EP25150422.1A patent/EP4549533A1/en active Pending
- 2021-12-24 EP EP26159718.1A patent/EP4733304A2/en active Pending
- 2021-12-24 WO PCT/JP2021/048398 patent/WO2022138965A1/ja not_active Ceased
- 2021-12-24 WO PCT/JP2021/048401 patent/WO2022138968A1/ja not_active Ceased
- 2021-12-24 JP JP2022571718A patent/JP7639026B2/ja active Active
- 2021-12-24 US US18/269,003 patent/US20240103200A1/en active Pending
- 2021-12-24 KR KR1020237009358A patent/KR102786669B1/ko active Active
- 2021-12-24 KR KR1020237009357A patent/KR102780823B1/ko active Active
- 2021-12-24 US US18/269,005 patent/US20240059959A1/en active Pending
- 2021-12-24 CN CN202180064027.5A patent/CN116323577A/zh active Pending
- 2021-12-24 ES ES21911103T patent/ES3014883T3/es active Active
- 2021-12-24 WO PCT/JP2021/048400 patent/WO2022138967A1/ja not_active Ceased
- 2021-12-24 EP EP21911103.6A patent/EP4198583B1/en active Active
- 2021-12-24 EP EP21911102.8A patent/EP4270067B1/en active Active
- 2021-12-24 WO PCT/JP2021/048399 patent/WO2022138966A1/ja not_active Ceased
- 2021-12-24 CN CN202180064029.4A patent/CN116323857A/zh active Pending
- 2021-12-24 ES ES21911105T patent/ES3058414T3/es active Active
- 2021-12-24 JP JP2022571720A patent/JP7334368B2/ja active Active
- 2021-12-24 EP EP21911105.1A patent/EP4269532B1/en active Active
- 2021-12-24 KR KR1020237021232A patent/KR102877221B1/ko active Active
- 2021-12-24 EP EP21911104.4A patent/EP4198102B1/en active Active
- 2021-12-24 KR KR1020257009298A patent/KR20250044801A/ko active Pending
- 2021-12-24 JP JP2022571721A patent/JP7547510B2/ja active Active
- 2021-12-24 JP JP2022571719A patent/JP7290809B2/ja active Active
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2023
- 2023-03-17 US US18/122,949 patent/US20230227717A1/en active Pending
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2024
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2025
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