JPWO2011096464A1 - 導電性エンドレスベルト - Google Patents
導電性エンドレスベルト Download PDFInfo
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- JPWO2011096464A1 JPWO2011096464A1 JP2011552813A JP2011552813A JPWO2011096464A1 JP WO2011096464 A1 JPWO2011096464 A1 JP WO2011096464A1 JP 2011552813 A JP2011552813 A JP 2011552813A JP 2011552813 A JP2011552813 A JP 2011552813A JP WO2011096464 A1 JPWO2011096464 A1 JP WO2011096464A1
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- Prior art keywords
- acrylate
- resin
- endless belt
- mass
- meth
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- 239000011347 resin Substances 0.000 claims abstract description 98
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- 229920000642 polymer Polymers 0.000 claims abstract description 26
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 claims abstract description 15
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 150000003242 quaternary ammonium salts Chemical group 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 6
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
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- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical group C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 description 3
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- 239000002923 metal particle Substances 0.000 description 3
- 125000001624 naphthyl group Chemical group 0.000 description 3
- 229920003986 novolac Polymers 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
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Images
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G15/00—Apparatus for electrographic processes using a charge pattern
- G03G15/14—Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base
- G03G15/16—Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base of a toner pattern, e.g. a powder pattern, e.g. magnetic transfer
- G03G15/1605—Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base of a toner pattern, e.g. a powder pattern, e.g. magnetic transfer using at least one intermediate support
- G03G15/162—Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base of a toner pattern, e.g. a powder pattern, e.g. magnetic transfer using at least one intermediate support details of the the intermediate support, e.g. chemical composition
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G15/00—Apparatus for electrographic processes using a charge pattern
- G03G15/01—Apparatus for electrographic processes using a charge pattern for producing multicoloured copies
- G03G15/0142—Structure of complete machines
- G03G15/0178—Structure of complete machines using more than one reusable electrographic recording member, e.g. one for every monocolour image
- G03G15/0189—Structure of complete machines using more than one reusable electrographic recording member, e.g. one for every monocolour image primary transfer to an intermediate transfer belt
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G2215/00—Apparatus for electrophotographic processes
- G03G2215/01—Apparatus for electrophotographic processes for producing multicoloured copies
- G03G2215/0103—Plural electrographic recording members
- G03G2215/0119—Linear arrangement adjacent plural transfer points
- G03G2215/0122—Linear arrangement adjacent plural transfer points primary transfer to an intermediate transfer belt
- G03G2215/0125—Linear arrangement adjacent plural transfer points primary transfer to an intermediate transfer belt the linear arrangement being horizontal or slanted
- G03G2215/0129—Linear arrangement adjacent plural transfer points primary transfer to an intermediate transfer belt the linear arrangement being horizontal or slanted horizontal medium transport path at the secondary transfer
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Electrostatic Charge, Transfer And Separation In Electrography (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
Description
前記基層が、熱可塑性樹脂を含有し、
前記樹脂硬化層が、紫外線硬化型樹脂と、イオン導電剤と、1,4−ブタンジオールアクリレートおよびポリテトラメチレングリコールアクリレートのうち少なくとも一種と、エチレンオキサイドを有するポリマーと、を含有し、
前記イオン導電剤の含有量が、紫外線硬化型樹脂と、1,4−ブタンジオールアクリレートおよびポリテトラメチレングリコールアクリレートのうち少なくとも一種と、エチレンオキサイドを有するポリマーと、の総含有量100質量部に対し、0.5〜5質量部であることを特徴とするものである。
(式中、R1は炭素数1〜30のアルキル基、炭素数6〜30のアリール基または炭素数7〜30のアラルキル基を表し、R2、R3およびR4は、夫々独立に炭素数1〜6のアルキル基を表し、Xn−はn価の陰イオンを表し、nは1〜6の整数である)で表わされることが好ましい。
導電性エンドレスベルトには、一般に、ジョイントありのものとジョイントなしのもの(いわゆるシームレスベルト)とがあるが、本発明においてはいずれのものであってもよく、好ましくはシームレスベルトである。本発明の導電性エンドレスベルトは、前述したように、タンデム方式および中間転写方式の転写部材等として用いることができるものである。
(上記式(2)中、R1はメチル基またはブチル基であり、R2は前記式(1)で示される官能基である)で示される構造を有する)である。
(式中、R1は炭素数1〜30のアルキル基、炭素数6〜30のアリール基または炭素数7〜30のアラルキル基を表し、R2、R3およびR4は、夫々独立に炭素数1〜6のアルキル基を表し、Xn−はn価の陰イオンを表し、nは1〜6の整数である)で表わされるものであることがさらに好ましい。
(実施例1〜9、比較例1〜6)
下記の表6〜8中に夫々示す配合になるように、各実施例および比較例の導電性エンドレスベルトを作製した。具体的には、まず、各表中に示すベルト基体の各配合成分を二軸混練機により溶融混練して、得られた混練物を環状ダイスを用いて押出し成形することにより、内径220mm、厚さ100μm、幅250mmの寸法を有する基層101を作製した。その後、この基層101上に、各表中に示す配合材料を用いてメチルエチルケトンを溶剤として作製した樹脂層の溶剤塗工液を、スプレーを用いて、乾燥後の膜厚が2μmとなるよう塗工した。塗工後のベルト100を回転させながら、ウシオ電機(株)製 ユニキュアUVH−0252C装置を用いて、照度400mW,積算光量1000mJ/cm2で紫外線を照射し、樹脂層102の塗膜を硬化させることにより、導電性エンドレスベルト100を得た。
各ベルトから長さ100mm、幅15mmの試験片を切り出し、東洋精機(株)製のMIT耐揉疲労試験機を用いて、折り曲げ速度175回/min、回転角度135度、引張荷重14.7N(1.5kgf)の条件で耐折り曲げ回数(耐折れ回数:回)を測定した。なお、基層のみの場合の耐折れ回数は、3000回である。
各ベルトを感光体ドラムに荷重1kgにて押し付け、40℃×95%の高温高湿下で一週間放置した。その後、各ベルトを取り出し、感光体ドラムとの接触部について目視確認を行って、感光体ドラムの汚染が見られなかった場合を○、汚染が若干見られた場合を△、ベルト表面にブリードが生じて感光体ドラムの汚染が見られたものを×とした。
各ベルトを図3に示す中間転写ベルトを用いた中間転写方式のカラーレーザープリンターに装着し、印字試験を行った。印字された画像について、初期の画像不良の評価(初期画像評価)を行った。画像不良を生じない場合を○、やや生じた場合を△、生じた場合を×とした。また、5000枚印字試験後の画像不良の評価(5K画像評価)を行った。画像不良を生じない場合を○、やや生じた場合を△、生じた場合を×とした。
*2)1,4−BDA:1,4−ブタンジオールアクリレート
*3)PEGジアクリレート:ポリエチレングリコールジアクリレート
*4)第4級アンモニウム塩:ラウリルジメチルエチルアンモニウムエチルサルフェート無水物(日油(株)製,エレガン26)
*5)金属微粒子:石原産業(株)製、SN−100P
*6)PPS:ポリプラスチックス(株)製、フォートロンW2204
*7)カーボンブラック:電気化学工業(株)製、商品名 電化ブラック
*9)ウレタンアクリレート:ペンタエリスリトールトリアクリレートヘキサメチレンジイソシアネートウレタンプレポリマー(共栄社化学(株)製,UA−306H)
*10)PTMGA:ポリテトラメチレングリコールジアクリレート(共栄社化学(株)製,ライトアクリレートPTMGA−250)
*11)PBT:ポリブチレンテレフタレート(ポリプラスチックス(株)製,ジュラネックス800FP)
*12)12−Ny:ポリアミド12(宇部興産(株)製,ウベスタレジン3024U C01)
2、7 帯電ロール
3 現像ロール
4 現像ブレード
5 トナー供給ロール
6 クリーニングブレード
8 除電ロール
9、30、55 駆動ローラ(駆動部材)
10 転写搬送ベルト
12 一次帯電器
13 画像露光
14、35 クリーニング装置
19 給紙カセット
20、50 中間転写部材
25 転写ローラ
26、53 記録媒体
29、61 電源
41、42、43、44 現像器
54a〜54d 第1現像部〜第4現像部
56 2次転写ローラ
57 記録媒体送り装置
58 定着装置
100 導電性エンドレスベルト
101 基層
102 樹脂硬化層
Claims (5)
- 画像形成装置に用いられる無端ベルト状で、少なくとも基層と樹脂硬化層とを内側から順次備える積層構造を有する導電性エンドレスベルトにおいて、
前記基層が、熱可塑性樹脂を含有し、
前記樹脂硬化層が、紫外線硬化型樹脂と、イオン導電剤と、1,4−ブタンジオールアクリレートおよびポリテトラメチレングリコールアクリレートのうち少なくとも一種と、エチレンオキサイドを有するポリマーと、を含有し、
前記イオン導電剤の含有量が、紫外線硬化型樹脂と、1,4−ブタンジオールアクリレートおよびポリテトラメチレングリコールアクリレートのうち少なくとも一種と、エチレンオキサイドを有するポリマーと、の総含有量100質量部に対し、0.5〜5質量部であることを特徴とする導電性エンドレスベルト。 - 前記イオン導電剤が、第4級アンモニウム塩である請求項1記載の導電性エンドレスベルト。
- 前記1,4−ブタンジオールアクリレートおよびポリテトラメチレングリコールアクリレートのうち少なくとも一種の含有量が、紫外線硬化型樹脂100質量部に対し、10〜30質量部である請求項1記載の導電性エンドレスベルト。
- 前記エチレンオキサイドを有するポリマーの含有量が、紫外線硬化型樹脂100質量部に対し、10〜30質量部である請求項1記載の導電性エンドレスベルト。
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