JPS64966B2 - - Google Patents
Info
- Publication number
- JPS64966B2 JPS64966B2 JP20684781A JP20684781A JPS64966B2 JP S64966 B2 JPS64966 B2 JP S64966B2 JP 20684781 A JP20684781 A JP 20684781A JP 20684781 A JP20684781 A JP 20684781A JP S64966 B2 JPS64966 B2 JP S64966B2
- Authority
- JP
- Japan
- Prior art keywords
- component
- compound
- ethyl
- polymerization method
- olefin polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 thioalcohols Chemical class 0.000 claims description 54
- 239000010936 titanium Substances 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 35
- 150000001336 alkenes Chemical class 0.000 claims description 34
- 125000002734 organomagnesium group Chemical group 0.000 claims description 34
- 238000006116 polymerization reaction Methods 0.000 claims description 33
- 150000001875 compounds Chemical class 0.000 claims description 31
- 239000003054 catalyst Substances 0.000 claims description 30
- 150000002430 hydrocarbons Chemical group 0.000 claims description 27
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 25
- 125000004432 carbon atom Chemical group C* 0.000 claims description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 19
- 239000011777 magnesium Substances 0.000 claims description 15
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 14
- 150000003609 titanium compounds Chemical class 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 150000001412 amines Chemical class 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- 125000004429 atom Chemical group 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 150000002902 organometallic compounds Chemical class 0.000 claims description 6
- 230000000737 periodic effect Effects 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 150000002170 ethers Chemical class 0.000 claims description 5
- 230000000379 polymerizing effect Effects 0.000 claims description 5
- 150000003377 silicon compounds Chemical class 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 150000002576 ketones Chemical class 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001299 aldehydes Chemical class 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052790 beryllium Inorganic materials 0.000 claims description 3
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- 150000002681 magnesium compounds Chemical class 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 150000003568 thioethers Chemical class 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 150000004678 hydrides Chemical class 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 49
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 29
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 28
- 238000006243 chemical reaction Methods 0.000 description 27
- 229930195733 hydrocarbon Natural products 0.000 description 25
- 229920000642 polymer Polymers 0.000 description 24
- 239000004215 Carbon black (E152) Substances 0.000 description 23
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 23
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 22
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 19
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 19
- 125000000217 alkyl group Chemical group 0.000 description 18
- SLLGVCUQYRMELA-UHFFFAOYSA-N chlorosilicon Chemical compound Cl[Si] SLLGVCUQYRMELA-UHFFFAOYSA-N 0.000 description 17
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 16
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 16
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000005046 Chlorosilane Substances 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 12
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical class Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 10
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 10
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 150000002901 organomagnesium compounds Chemical class 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 125000001931 aliphatic group Chemical group 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- 239000005977 Ethylene Substances 0.000 description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 6
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 6
- 239000002685 polymerization catalyst Substances 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 125000002723 alicyclic group Chemical group 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 5
- 238000000605 extraction Methods 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 5
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 4
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 3
- SHZIWNPUGXLXDT-UHFFFAOYSA-N ethyl hexanoate Chemical compound CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000002195 soluble material Substances 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 3
- 239000005052 trichlorosilane Substances 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- PMBXCGGQNSVESQ-UHFFFAOYSA-N 1-Hexanethiol Chemical compound CCCCCCS PMBXCGGQNSVESQ-UHFFFAOYSA-N 0.000 description 2
- ZRKMQKLGEQPLNS-UHFFFAOYSA-N 1-Pentanethiol Chemical compound CCCCCS ZRKMQKLGEQPLNS-UHFFFAOYSA-N 0.000 description 2
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- JKRZOJADNVOXPM-UHFFFAOYSA-N Oxalic acid dibutyl ester Chemical compound CCCCOC(=O)C(=O)OCCCC JKRZOJADNVOXPM-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
- 150000001733 carboxylic acid esters Chemical class 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- DFGSACBYSGUJDZ-UHFFFAOYSA-M chloro(dihexyl)alumane Chemical compound [Cl-].CCCCCC[Al+]CCCCCC DFGSACBYSGUJDZ-UHFFFAOYSA-M 0.000 description 2
- VJRUISVXILMZSL-UHFFFAOYSA-M dibutylalumanylium;chloride Chemical compound CCCC[Al](Cl)CCCC VJRUISVXILMZSL-UHFFFAOYSA-M 0.000 description 2
- KTQYJQFGNYHXMB-UHFFFAOYSA-N dichloro(methyl)silicon Chemical compound C[Si](Cl)Cl KTQYJQFGNYHXMB-UHFFFAOYSA-N 0.000 description 2
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 2
- TVQGDYNRXLTQAP-UHFFFAOYSA-N ethyl heptanoate Chemical compound CCCCCCC(=O)OCC TVQGDYNRXLTQAP-UHFFFAOYSA-N 0.000 description 2
- JZGZKRJVTIRPOK-UHFFFAOYSA-N ethyl thiophene-2-carboxylate Chemical compound CCOC(=O)C1=CC=CS1 JZGZKRJVTIRPOK-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000012685 gas phase polymerization Methods 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- IUYHWZFSGMZEOG-UHFFFAOYSA-M magnesium;propane;chloride Chemical compound [Mg+2].[Cl-].C[CH-]C IUYHWZFSGMZEOG-UHFFFAOYSA-M 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- JYVLIDXNZAXMDK-UHFFFAOYSA-N pentan-2-ol Chemical compound CCCC(C)O JYVLIDXNZAXMDK-UHFFFAOYSA-N 0.000 description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- SUVIGLJNEAMWEG-UHFFFAOYSA-N propane-1-thiol Chemical compound CCCS SUVIGLJNEAMWEG-UHFFFAOYSA-N 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000011949 solid catalyst Substances 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- CQHYICHMGNSGQH-UHFFFAOYSA-N 1,3-oxazole-2-carboxylic acid Chemical class OC(=O)C1=NC=CO1 CQHYICHMGNSGQH-UHFFFAOYSA-N 0.000 description 1
- IJVLVRYLIMQVDD-UHFFFAOYSA-N 1,3-thiazole-2-carboxylic acid Chemical class OC(=O)C1=NC=CS1 IJVLVRYLIMQVDD-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- SNLMOXFUCILIPL-UHFFFAOYSA-N 1,8-naphthyridine-2-carboxylic acid Chemical compound C1=CC=NC2=NC(C(=O)O)=CC=C21 SNLMOXFUCILIPL-UHFFFAOYSA-N 0.000 description 1
- DYSJMQABFPKAQM-UHFFFAOYSA-N 1-benzothiophene-2-carboxylic acid Chemical class C1=CC=C2SC(C(=O)O)=CC2=C1 DYSJMQABFPKAQM-UHFFFAOYSA-N 0.000 description 1
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- KOPFEFZSAMLEHK-UHFFFAOYSA-N 1h-pyrazole-5-carboxylic acid Chemical class OC(=O)C=1C=CNN=1 KOPFEFZSAMLEHK-UHFFFAOYSA-N 0.000 description 1
- NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
- JDTUPLBMGDDPJS-UHFFFAOYSA-N 2-methoxy-2-phenylethanol Chemical compound COC(CO)C1=CC=CC=C1 JDTUPLBMGDDPJS-UHFFFAOYSA-N 0.000 description 1
- XLKOQFSMGITOGW-UHFFFAOYSA-N 2-methoxycarbonylthiophene-3-carboxylic acid Chemical compound COC(=O)C=1SC=CC=1C(O)=O XLKOQFSMGITOGW-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- OLUUSIGKTFFDPM-UHFFFAOYSA-N 2h-oxazine-3-carboxylic acid Chemical compound OC(=O)C1=CC=CON1 OLUUSIGKTFFDPM-UHFFFAOYSA-N 0.000 description 1
- BNNNRTHFDVJELR-UHFFFAOYSA-N 2h-thiazine-3-carboxylic acid Chemical compound OC(=O)C1=CC=CSN1 BNNNRTHFDVJELR-UHFFFAOYSA-N 0.000 description 1
- RPTUKIAFFBVPLL-UHFFFAOYSA-N 3,4-dihydro-2h-thiochromene-2-carboxylic acid Chemical class C1=CC=C2SC(C(=O)O)CCC2=C1 RPTUKIAFFBVPLL-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- HRAQMGWTPNOILP-UHFFFAOYSA-N 4-Ethoxy ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(OCC)C=C1 HRAQMGWTPNOILP-UHFFFAOYSA-N 0.000 description 1
- GUXKBDHITFXEJG-UHFFFAOYSA-N 5-methoxycarbonylpyridine-3-carboxylic acid Chemical compound COC(=O)C1=CN=CC(C(O)=O)=C1 GUXKBDHITFXEJG-UHFFFAOYSA-N 0.000 description 1
- HYHZGBOWRWIEGW-UHFFFAOYSA-N 5-methoxycarbonylthiophene-2-carboxylic acid Chemical compound COC(=O)C1=CC=C(C(O)=O)S1 HYHZGBOWRWIEGW-UHFFFAOYSA-N 0.000 description 1
- WGEYGSIIKRNPPG-UHFFFAOYSA-N 5-methoxycarbonylthiophene-3-carboxylic acid Chemical compound COC(=O)C1=CC(C(O)=O)=CS1 WGEYGSIIKRNPPG-UHFFFAOYSA-N 0.000 description 1
- VWIOMFMPIVMLIR-UHFFFAOYSA-N 6-methoxycarbonylpyridine-2-carboxylic acid Chemical compound COC(=O)C1=CC=CC(C(O)=O)=N1 VWIOMFMPIVMLIR-UHFFFAOYSA-N 0.000 description 1
- QRSXLMSDECGEOU-UHFFFAOYSA-N 6-methoxycarbonylpyridine-3-carboxylic acid Chemical compound COC(=O)C1=CC=C(C(O)=O)C=N1 QRSXLMSDECGEOU-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- DHHFGQADZVYGIE-UHFFFAOYSA-N 9h-carbazole-1-carboxylic acid Chemical class C12=CC=CC=C2NC2=C1C=CC=C2C(=O)O DHHFGQADZVYGIE-UHFFFAOYSA-N 0.000 description 1
- 229910018516 AlâO Inorganic materials 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- ICMAFTSLXCXHRK-UHFFFAOYSA-N Ethyl pentanoate Chemical compound CCCCC(=O)OCC ICMAFTSLXCXHRK-UHFFFAOYSA-N 0.000 description 1
- 101000687448 Homo sapiens REST corepressor 1 Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- NMMIHXMBOZYNET-UHFFFAOYSA-N Methyl picolinate Chemical compound COC(=O)C1=CC=CC=N1 NMMIHXMBOZYNET-UHFFFAOYSA-N 0.000 description 1
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 102100024864 REST corepressor 1 Human genes 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- NBMJSCRZGGZPGR-UHFFFAOYSA-K [Cl-].[Cl-].[Cl-].C(CCC)O[Ti+3](OCCCC)OCCCC Chemical compound [Cl-].[Cl-].[Cl-].C(CCC)O[Ti+3](OCCCC)OCCCC NBMJSCRZGGZPGR-UHFFFAOYSA-K 0.000 description 1
- GKQZBJMXIUKBGB-UHFFFAOYSA-K [Cl-].[Cl-].[Cl-].CCCO[Ti+3] Chemical compound [Cl-].[Cl-].[Cl-].CCCO[Ti+3] GKQZBJMXIUKBGB-UHFFFAOYSA-K 0.000 description 1
- GUMQWPGMMSFQEQ-UHFFFAOYSA-M [I-].CC(C)(C)[Mg+] Chemical compound [I-].CC(C)(C)[Mg+] GUMQWPGMMSFQEQ-UHFFFAOYSA-M 0.000 description 1
- LQHZUFWVUJVYQR-UHFFFAOYSA-M [I-].CCCC[Mg+] Chemical compound [I-].CCCC[Mg+] LQHZUFWVUJVYQR-UHFFFAOYSA-M 0.000 description 1
- CDKFWIMBZAUBRS-UHFFFAOYSA-M [I-].CC[Mg+] Chemical compound [I-].CC[Mg+] CDKFWIMBZAUBRS-UHFFFAOYSA-M 0.000 description 1
- PDBOLQCPEKXSBW-UHFFFAOYSA-M [Ti]Cl Chemical compound [Ti]Cl PDBOLQCPEKXSBW-UHFFFAOYSA-M 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 description 1
- 239000012346 acetyl chloride Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- TZIHFWKZFHZASV-UHFFFAOYSA-N anhydrous methyl formate Natural products COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- FWCTZJNNLCYVMA-UHFFFAOYSA-L butan-1-ol;dichlorotitanium Chemical compound Cl[Ti]Cl.CCCCO.CCCCO FWCTZJNNLCYVMA-UHFFFAOYSA-L 0.000 description 1
- DEFMLLQRTVNBOF-UHFFFAOYSA-K butan-1-olate;trichlorotitanium(1+) Chemical compound [Cl-].[Cl-].[Cl-].CCCCO[Ti+3] DEFMLLQRTVNBOF-UHFFFAOYSA-K 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- OBNCKNCVKJNDBV-UHFFFAOYSA-N butanoic acid ethyl ester Natural products CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
- YHASWHZGWUONAO-UHFFFAOYSA-N butanoyl butanoate Chemical compound CCCC(=O)OC(=O)CCC YHASWHZGWUONAO-UHFFFAOYSA-N 0.000 description 1
- HOBYQHFDPYPSFU-UHFFFAOYSA-N butyl 1h-pyrrole-2-carboxylate Chemical compound CCCCOC(=O)C1=CC=CN1 HOBYQHFDPYPSFU-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- VUSZPSYSKPXZQL-UHFFFAOYSA-N butyl thiophene-2-carboxylate Chemical compound CCCCOC(=O)C1=CC=CS1 VUSZPSYSKPXZQL-UHFFFAOYSA-N 0.000 description 1
- GESATHABWPMDBO-UHFFFAOYSA-M butyl(ethyl)alumanylium;chloride Chemical compound [Cl-].CCCC[Al+]CC GESATHABWPMDBO-UHFFFAOYSA-M 0.000 description 1
- MOWCKQDNXMYJOF-UHFFFAOYSA-M butyl-chloro-methylalumane Chemical compound CCCC[Al](C)Cl MOWCKQDNXMYJOF-UHFFFAOYSA-M 0.000 description 1
- DVECBJCOGJRVPX-UHFFFAOYSA-N butyryl chloride Chemical compound CCCC(Cl)=O DVECBJCOGJRVPX-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- HYZXMVILOKSUKA-UHFFFAOYSA-K chloro(dimethyl)alumane;dichloro(methyl)alumane Chemical compound C[Al](C)Cl.C[Al](Cl)Cl HYZXMVILOKSUKA-UHFFFAOYSA-K 0.000 description 1
- QABCGOSYZHCPGN-UHFFFAOYSA-N chloro(dimethyl)silicon Chemical compound C[Si](C)Cl QABCGOSYZHCPGN-UHFFFAOYSA-N 0.000 description 1
- IMPYJAYVDUIIJV-UHFFFAOYSA-M chloro-bis(2-ethylhexyl)alumane Chemical compound CCCCC(CC)C[Al](Cl)CC(CC)CCCC IMPYJAYVDUIIJV-UHFFFAOYSA-M 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 125000000853 cresyl group Chemical group C1(=CC=C(C=C1)C)* 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- PFMKUUJQLUQKHT-UHFFFAOYSA-N dichloro(ethyl)silicon Chemical compound CC[Si](Cl)Cl PFMKUUJQLUQKHT-UHFFFAOYSA-N 0.000 description 1
- UWGIJJRGSGDBFJ-UHFFFAOYSA-N dichloromethylsilane Chemical compound [SiH3]C(Cl)Cl UWGIJJRGSGDBFJ-UHFFFAOYSA-N 0.000 description 1
- MPZYOORVNSAACS-UHFFFAOYSA-M didodecylalumanylium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[Al+]CCCCCCCCCCCC MPZYOORVNSAACS-UHFFFAOYSA-M 0.000 description 1
- HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 1
- JJSGABFIILQOEY-UHFFFAOYSA-M diethylalumanylium;bromide Chemical compound CC[Al](Br)CC JJSGABFIILQOEY-UHFFFAOYSA-M 0.000 description 1
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- ZMXPNWBFRPIZFV-UHFFFAOYSA-M dipropylalumanylium;chloride Chemical compound [Cl-].CCC[Al+]CCC ZMXPNWBFRPIZFV-UHFFFAOYSA-M 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 125000004119 disulfanediyl group Chemical group *SS* 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- RMTCVMQBBYEAPC-UHFFFAOYSA-K ethanolate;titanium(4+);trichloride Chemical compound [Cl-].[Cl-].[Cl-].CCO[Ti+3] RMTCVMQBBYEAPC-UHFFFAOYSA-K 0.000 description 1
- VKKVFRWNHZHHQU-UHFFFAOYSA-N ethyl 3-methylpyridine-2-carboxylate Chemical compound CCOC(=O)C1=NC=CC=C1C VKKVFRWNHZHHQU-UHFFFAOYSA-N 0.000 description 1
- ZPUKPAPWEWUPTC-UHFFFAOYSA-N ethyl 4-ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(CC)C=C1 ZPUKPAPWEWUPTC-UHFFFAOYSA-N 0.000 description 1
- RUJPPJYDHHAEEK-UHFFFAOYSA-N ethyl piperidine-4-carboxylate Chemical compound CCOC(=O)C1CCNCC1 RUJPPJYDHHAEEK-UHFFFAOYSA-N 0.000 description 1
- QPNJHVDIRZNKOX-UHFFFAOYSA-N ethyl pyrrolidine-2-carboxylate Chemical compound CCOC(=O)C1CCCN1 QPNJHVDIRZNKOX-UHFFFAOYSA-N 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- UKFXDFUAPNAMPJ-UHFFFAOYSA-N ethylmalonic acid Chemical compound CCC(C(O)=O)C(O)=O UKFXDFUAPNAMPJ-UHFFFAOYSA-N 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QNVRIHYSUZMSGM-UHFFFAOYSA-N hexan-2-ol Chemical compound CCCCC(C)O QNVRIHYSUZMSGM-UHFFFAOYSA-N 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- DQDWATOXYCARFV-UHFFFAOYSA-M magnesium;2-methanidylpropane;bromide Chemical compound [Mg+2].[Br-].CC(C)[CH2-] DQDWATOXYCARFV-UHFFFAOYSA-M 0.000 description 1
- YSMZEMQBSONIMJ-UHFFFAOYSA-M magnesium;2-methanidylpropane;chloride Chemical compound [Mg+2].[Cl-].CC(C)[CH2-] YSMZEMQBSONIMJ-UHFFFAOYSA-M 0.000 description 1
- UKZCGMDMXDLAGZ-UHFFFAOYSA-M magnesium;2-methylpropane;bromide Chemical compound [Mg+2].[Br-].C[C-](C)C UKZCGMDMXDLAGZ-UHFFFAOYSA-M 0.000 description 1
- CQRPUKWAZPZXTO-UHFFFAOYSA-M magnesium;2-methylpropane;chloride Chemical compound [Mg+2].[Cl-].C[C-](C)C CQRPUKWAZPZXTO-UHFFFAOYSA-M 0.000 description 1
- IWCVDCOJSPWGRW-UHFFFAOYSA-M magnesium;benzene;chloride Chemical compound [Mg+2].[Cl-].C1=CC=[C-]C=C1 IWCVDCOJSPWGRW-UHFFFAOYSA-M 0.000 description 1
- WSHFRLGXCNEKRX-UHFFFAOYSA-M magnesium;butane;bromide Chemical compound [Mg+2].[Br-].CC[CH-]C WSHFRLGXCNEKRX-UHFFFAOYSA-M 0.000 description 1
- LWLPYZUDBNFNAH-UHFFFAOYSA-M magnesium;butane;bromide Chemical compound [Mg+2].[Br-].CCC[CH2-] LWLPYZUDBNFNAH-UHFFFAOYSA-M 0.000 description 1
- YNLPNVNWHDKDMN-UHFFFAOYSA-M magnesium;butane;chloride Chemical compound [Mg+2].[Cl-].CC[CH-]C YNLPNVNWHDKDMN-UHFFFAOYSA-M 0.000 description 1
- QUXHCILOWRXCEO-UHFFFAOYSA-M magnesium;butane;chloride Chemical compound [Mg+2].[Cl-].CCC[CH2-] QUXHCILOWRXCEO-UHFFFAOYSA-M 0.000 description 1
- NXPHGHWWQRMDIA-UHFFFAOYSA-M magnesium;carbanide;bromide Chemical compound [CH3-].[Mg+2].[Br-] NXPHGHWWQRMDIA-UHFFFAOYSA-M 0.000 description 1
- CCERQOYLJJULMD-UHFFFAOYSA-M magnesium;carbanide;chloride Chemical compound [CH3-].[Mg+2].[Cl-] CCERQOYLJJULMD-UHFFFAOYSA-M 0.000 description 1
- VXWPONVCMVLXBW-UHFFFAOYSA-M magnesium;carbanide;iodide Chemical compound [CH3-].[Mg+2].[I-] VXWPONVCMVLXBW-UHFFFAOYSA-M 0.000 description 1
- FRIJBUGBVQZNTB-UHFFFAOYSA-M magnesium;ethane;bromide Chemical compound [Mg+2].[Br-].[CH2-]C FRIJBUGBVQZNTB-UHFFFAOYSA-M 0.000 description 1
- YCCXQARVHOPWFJ-UHFFFAOYSA-M magnesium;ethane;chloride Chemical compound [Mg+2].[Cl-].[CH2-]C YCCXQARVHOPWFJ-UHFFFAOYSA-M 0.000 description 1
- LZFCBBSYZJPPIV-UHFFFAOYSA-M magnesium;hexane;bromide Chemical compound [Mg+2].[Br-].CCCCC[CH2-] LZFCBBSYZJPPIV-UHFFFAOYSA-M 0.000 description 1
- GBRJQTLHXWRDOV-UHFFFAOYSA-M magnesium;hexane;chloride Chemical compound [Mg+2].[Cl-].CCCCC[CH2-] GBRJQTLHXWRDOV-UHFFFAOYSA-M 0.000 description 1
- HQDAZWQQKSJCTM-UHFFFAOYSA-M magnesium;octane;chloride Chemical compound [Mg+2].[Cl-].CCCCCCC[CH2-] HQDAZWQQKSJCTM-UHFFFAOYSA-M 0.000 description 1
- UGVPKMAWLOMPRS-UHFFFAOYSA-M magnesium;propane;bromide Chemical compound [Mg+2].[Br-].CC[CH2-] UGVPKMAWLOMPRS-UHFFFAOYSA-M 0.000 description 1
- LVKCSZQWLOVUGB-UHFFFAOYSA-M magnesium;propane;bromide Chemical compound [Mg+2].[Br-].C[CH-]C LVKCSZQWLOVUGB-UHFFFAOYSA-M 0.000 description 1
- XGITVAYMIKUXIN-UHFFFAOYSA-M magnesium;propane;iodide Chemical compound [Mg+2].[I-].C[CH-]C XGITVAYMIKUXIN-UHFFFAOYSA-M 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- KRRAZMUPVIGDCU-UHFFFAOYSA-N methyl 1-benzothiophene-2-carboxylate Chemical compound C1=CC=C2SC(C(=O)OC)=CC2=C1 KRRAZMUPVIGDCU-UHFFFAOYSA-N 0.000 description 1
- FSJAXBXCHWMNAB-UHFFFAOYSA-N methyl 1-benzothiophene-3-carboxylate Chemical compound C1=CC=C2C(C(=O)OC)=CSC2=C1 FSJAXBXCHWMNAB-UHFFFAOYSA-N 0.000 description 1
- WVWZECQNFWFVFW-UHFFFAOYSA-N methyl 2-methylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C WVWZECQNFWFVFW-UHFFFAOYSA-N 0.000 description 1
- ZHHGVIMCXWHRDI-UHFFFAOYSA-N methyl 2-oxo-3-thiophen-2-ylpropanoate Chemical compound COC(=O)C(=O)CC1=CC=CS1 ZHHGVIMCXWHRDI-UHFFFAOYSA-N 0.000 description 1
- KNKIXYMOHMYZJR-UHFFFAOYSA-N methyl 2-thiophen-2-ylacetate Chemical compound COC(=O)CC1=CC=CS1 KNKIXYMOHMYZJR-UHFFFAOYSA-N 0.000 description 1
- ZKUUVVYMPUDTGJ-UHFFFAOYSA-N methyl 5-hydroxy-4-methoxy-2-nitrobenzoate Chemical compound COC(=O)C1=CC(O)=C(OC)C=C1[N+]([O-])=O ZKUUVVYMPUDTGJ-UHFFFAOYSA-N 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- YNBADRVTZLEFNH-UHFFFAOYSA-N methyl nicotinate Chemical compound COC(=O)C1=CC=CN=C1 YNBADRVTZLEFNH-UHFFFAOYSA-N 0.000 description 1
- DDIZAANNODHTRB-UHFFFAOYSA-N methyl p-anisate Chemical compound COC(=O)C1=CC=C(OC)C=C1 DDIZAANNODHTRB-UHFFFAOYSA-N 0.000 description 1
- HCFKYQRXZUNWGW-UHFFFAOYSA-N methyl phenoxathiine-1-carboxylate Chemical compound O1C2=CC=CC=C2SC2=C1C=CC=C2C(=O)OC HCFKYQRXZUNWGW-UHFFFAOYSA-N 0.000 description 1
- 229940017219 methyl propionate Drugs 0.000 description 1
- OLXYLDUSSBULGU-UHFFFAOYSA-N methyl pyridine-4-carboxylate Chemical compound COC(=O)C1=CC=NC=C1 OLXYLDUSSBULGU-UHFFFAOYSA-N 0.000 description 1
- ZTRAEMILTFNZSM-UHFFFAOYSA-N methyl thiophene-3-carboxylate Chemical compound COC(=O)C=1C=CSC=1 ZTRAEMILTFNZSM-UHFFFAOYSA-N 0.000 description 1
- YSTQWZZQKCCBAY-UHFFFAOYSA-L methylaluminum(2+);dichloride Chemical compound C[Al](Cl)Cl YSTQWZZQKCCBAY-UHFFFAOYSA-L 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JXFYSKBUOFPGIW-UHFFFAOYSA-N pentyl thiophene-2-carboxylate Chemical compound CCCCCOC(=O)C1=CC=CS1 JXFYSKBUOFPGIW-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- FSPLJHJDWAPSLK-UHFFFAOYSA-N phenanthridine-1-carboxylic acid Chemical compound C1=CC=CC2=C3C(C(=O)O)=CC=CC3=NC=C21 FSPLJHJDWAPSLK-UHFFFAOYSA-N 0.000 description 1
- XSRBNKKGOKYGNT-UHFFFAOYSA-N phenoxathiine-1-carboxylic acid Chemical class O1C2=CC=CC=C2SC2=C1C=CC=C2C(=O)O XSRBNKKGOKYGNT-UHFFFAOYSA-N 0.000 description 1
- ANRQGKOBLBYXFM-UHFFFAOYSA-M phenylmagnesium bromide Chemical compound Br[Mg]C1=CC=CC=C1 ANRQGKOBLBYXFM-UHFFFAOYSA-M 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical compound OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 description 1
- XIPFMBOWZXULIA-UHFFFAOYSA-N pivalamide Chemical compound CC(C)(C)C(N)=O XIPFMBOWZXULIA-UHFFFAOYSA-N 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- RZWZRACFZGVKFM-UHFFFAOYSA-N propanoyl chloride Chemical compound CCC(Cl)=O RZWZRACFZGVKFM-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- WYVAMUWZEOHJOQ-UHFFFAOYSA-N propionic anhydride Chemical compound CCC(=O)OC(=O)CC WYVAMUWZEOHJOQ-UHFFFAOYSA-N 0.000 description 1
- RUUOPSRRIKJHNH-UHFFFAOYSA-N pyridazine-3-carboxylic acid Chemical compound OC(=O)C1=CC=CN=N1 RUUOPSRRIKJHNH-UHFFFAOYSA-N 0.000 description 1
- ZFCHNZDUMIOWFV-UHFFFAOYSA-N pyrimidine-2-carboxylic acid Chemical class OC(=O)C1=NC=CC=N1 ZFCHNZDUMIOWFV-UHFFFAOYSA-N 0.000 description 1
- WRHZVMBBRYBTKZ-UHFFFAOYSA-N pyrrole-2-carboxylic acid Chemical class OC(=O)C1=CC=CN1 WRHZVMBBRYBTKZ-UHFFFAOYSA-N 0.000 description 1
- DOYOPBSXEIZLRE-UHFFFAOYSA-N pyrrole-3-carboxylic acid Chemical compound OC(=O)C=1C=CNC=1 DOYOPBSXEIZLRE-UHFFFAOYSA-N 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 229920000576 tactic polymer Polymers 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- QERYCTSHXKAMIS-UHFFFAOYSA-N thiophene-2-carboxylic acid Chemical class OC(=O)C1=CC=CS1 QERYCTSHXKAMIS-UHFFFAOYSA-N 0.000 description 1
- UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 description 1
- NLLZTRMHNHVXJJ-UHFFFAOYSA-J titanium tetraiodide Chemical compound I[Ti](I)(I)I NLLZTRMHNHVXJJ-UHFFFAOYSA-J 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- XBEXIHMRFRFRAM-UHFFFAOYSA-N tridodecylalumane Chemical compound CCCCCCCCCCCC[Al](CCCCCCCCCCCC)CCCCCCCCCCCC XBEXIHMRFRFRAM-UHFFFAOYSA-N 0.000 description 1
- NHADXUOUFVKVEB-UHFFFAOYSA-N trihexadecylalumane Chemical compound CCCCCCCCCCCCCCCC[Al](CCCCCCCCCCCCCCCC)CCCCCCCCCCCCCCCC NHADXUOUFVKVEB-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- 125000006617 triphenylamine group Chemical class 0.000 description 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
- USJZIJNMRRNDPO-UHFFFAOYSA-N tris-decylalumane Chemical compound CCCCCCCCCC[Al](CCCCCCCCCC)CCCCCCCCCC USJZIJNMRRNDPO-UHFFFAOYSA-N 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 150000003682 vanadium compounds Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Description
æ¬çºæã¯ããªã¬ãã€ã³ã®ç«äœèŠåæ§éåã®æ°èŠ
ãªæ¹æ³ã«é¢ããããã«è©³ããã¯ããããã¬ã³ãã
ãã³âïŒãïŒâã¡ãã«ããã³âïŒããã³ãã³â
ïŒãïŒâã¡ãã«ãã³ãã³âïŒçããéžã°ããïŒçš®
ã®ãªã¬ãã€ã³ãç«äœèŠåçã«éåãããŸãã¯äžèš
ãªã¬ãã€ã³ããšãã¬ã³ãŸãã¯ä»ã®ãªã¬ãã€ã³ãšå ±
éåãããã®ã«é©ããéåçšè§Šåªã«ããéåæ¹æ³
ã«é¢ãããã®ã§ããã ãªã¬ãã€ã³ã®ç«äœèŠåæ§éå觊åªãšããŠãå çŽ
åšæåŸè¡šç¬¬æã第æã®é·ç§»éå±ååç©ãšå çŽ
åšæåŸè¡šç¬¬æã第æã®ææ©éå±ååç©ãããª
ããããããããŒã°ã©ãŒã»ããã¿è§Šåªç³»ãç¥ãã
ãŠãããäžã§ãããã²ã³åãã¿ã³ãšããªãšãã«ã¢
ã«ãããŠã ãŸãã¯ãžãšãã«ã¢ã«ãããŠã ã¯ãã©ã€
ãã®ãããªææ©ã¢ã«ãããŠã ååç©ãçµåããã
ã®ããç«äœèŠåæ§ããªãªã¬ãã€ã³ã®è£œé çšè§Šåªãš
ããŠå·¥æ¥çã«äœ¿çšãããŠããã ãããã®è§Šåªç³»ã¯ããããã¬ã³çã®ãªã¬ãã€ã³
ã®éåã«ãããŠãããªãé«ãç«äœèŠåæ§éåäœå
çãããªãã¡æ²žéš°ïœâããã¿ã³äžæº¶äœåçããã€
ãããªãªã¬ãã€ã³ãçæãããã®ã§ãããããã®
éå掻æ§ã¯å¿ ãããååæºè¶³ãã¹ããã®ã§ã¯ãª
ãããã®ããçæéåäœãã觊åªæ®æž£ãé€å»ãã
å·¥çšãå¿ èŠãšãªãã ãŸãé«æŽ»æ§ãªã¬ãã€ã³éå觊åªãšããŠãç¡æ©ãŸ
ãã¯ææ©ãã°ãã·ãŠã ååç©ãšãã¿ããŠã ãŸãã¯
ãããžãŠã ååç©ããããã¯äžèšïŒæåããã³é»
åäŸäžäœãããªã觊åªç³»ãå€æ°ææ¡ãããŠããã
ç¡æ©ãã°ãã·ãŠã 系觊åªãšããŠã¯ãããšãã°ã
Polymer LettersãVol.3ãp855ã857ïŒ1965ïŒã«
ããã°ãå¡©åãã°ãã·ãŠã ãšåå¡©åãã¿ã³ãåå¿
ãããåŸãããªãšãã«ã¢ã«ãããŠã ããã³å¿ èŠã«
å¿ããŠæ·»å å€ãå ããŠããããã¬ã³ã®éåãè¡ã
ããšã瀺ãããŠããããã®å Žåãæ·»å å€ãšããŠé ¢
é žãšãã«çã®é»åäŸäžäœãçšãããšãçæããªã
ãŒã®ç«äœèŠåæ§ãåäžããããšãèšèŒãããŠã
ãããŸãç¹å ¬æ39â12105å·å ¬å ±ã«ãããŠå¡©åã
ã°ãã·ãŠã ãå¡©åã³ãã«ãçã®ç²åã«åå¡©åãã¿
ã³çã被èŠããåŸãããªãšãã«ã¢ã«ãããŠã ããž
ãšãã«ã¢ã«ãããŠã ã¯ãã©ã€ãçã®éå±ã¢ã«ãã«
ãçµåããŠéåãè¡ãéã«ãé ¢é žãšãã«çã®æ·»å
å€ãå ããããšã«ãããéåäœã®äžæº¶å«æéãå¢
倧ããããããšã瀺ãããŠããããŸãå¡©åãã°ã
ã·ãŠã çã®éå±å¡©ãæ©ç ããŠçšããããããšãã
ãã³åå¡©åãã¿ã³çã®æº¶æ¶²ãæ æéå±å¡©ã«æ·»å
ãã該混åç©ãå ±ã«æ¯çªããããšã«ãããæ°èŠãª
觊åªã補é ã§ããããšãèšèŒãããŠããã ããŠããäžæ¹ã®æµãã§ããææ©ãã°ãã·ãŠã ç³»
觊åªãšããŠã¯ãç¹å ¬æ46â31968å·ã«ãããŠãã¢
ã«ãããŠã ããã²ã³ååç©ãšãã¿ã³ååç©ãšææ©
ãã°ãã·ãŠã ååç©ãšãæ··åããã«éããŠãæ··å
åãæ··åæãŸãã¯æ··ååŸã«ãã¢ã«ã«ããŒã«ãã¢ã«
ã±ããŒã«ãã¢ã«ã«ãã©ãŒããã¢ã«ã±ãã©ãŒããã«
ã«ãã³é žãã«ã«ãã³é žã®ãšã¹ãã«ãŸãã¯å¡©ãã¢ã«
ããããŸãã¯ã±ãã³ãæ·»å ããŠãã¢ã«ã±ã³é¡ã
110â以äžã§éåããæ¹æ³ãèšèŒãããŠããã ãã®æ¹æ³ã¯ãéååå¿åž¯åã«ãããéåäœæº¶æ¶²
ã®æ»çæéã10åéãç¹ã«ïŒåé以å ã«çããã
ãã«éåãè¡ãããšãã§ãããšããå©ç¹ãæããŠ
ããããçæéåäœã®æ²žéš°ããã¿ã³äžæº¶åã®å²å
ããŸã ååé«ããªããåºäœè§Šåªæååœãã®éåäœ
åéãäžååã§ããã補é ããã»ã¹ã®æ©åšããã³
æåæ©ã®è èãããããããã²ã³ã®éåäœäžã®å«
éãå€ãã補åç©æ§ãååã«æºè¶³ãã¹ãã§ã¯ãª
ãã ç¹éæ53â40696ãå53â70991ãå53â
100986ãå54â5893ãå54â127889ãå54â
136591çã«ãããŠãå¯æº¶æ§ææ©ãã°ãã·ãŠã æå
ãšïŒšâSiçµåãå«æããã¯ãã«ã·ã©ã³ååç©ãã
ã¿ã³ååç©ãé»åäŸäžäœãæ¥è§ŠãããŠåŸãããåº
äœæåãšææ©éå±ååç©ãçµåããããšã«ããã
åªãããªã¬ãã€ã³éå觊åªãåŸãããããšããŸã
ç¹éæ56â26905ãå56â28206ãå56â32504ã
å56â47408ãå56â5905ããã³ç¹é¡æ55â90720
çã®ææ¡ããªãããŠããã ãããŠãäžèšè§Šåªã«ã€ããŠã觊åªåæäžã®ç¹
ã§ãããã«ç°¡ç¥åããããšãæãŸããã æ¬çºæè ãã¯ãäžèšã®ç¹ã«éã¿ããªã¬ãã€ã³ã®
ç«äœèŠåæ§éå觊åªãçšããéåæ¹æ³ã«ã€ããŠé
ææ€èšããçµæãç¹å®ã®ææ©ãã°ãã·ãŠã æåãš
âSiçµåãå«æããã¯ãã«ã·ã©ã³ååç©ãç¡æ©
é žåç©ã®ååšäžåå¿ãããŠåŸãããåå¿æ··åç©
ã«ãç¹å®ã®ãã¿ã³ååç©ãé»åäŸäžäœãæ·»å ããŠ
åŸãããåå¿æ··åç©ãææ©ã¢ã«ãããŠã ååç©ãš
çµåããããšã«ãããåªããããªãªã¬ãã€ã³ã®è£œ
é ã«é©ãã觊åªãåŸãããããšãèŠåºããæ¬çºæ
ã«å°éããã ããªãã¡ãæ¬çºæã¯ããªã¬ãã€ã³ããã°ãã·ãŠ
ã ååç©ããã¿ã³ååç©ãé»åäŸäžäœãææ©ã¢ã«
ãããŠã ååç©ãããªã觊åªãçšããŠéåããæ¹
æ³ã«ãããŠã ãã (1) (i) (a)äžè¬åŒMãMgãR1 pR2 qXrYs
ïŒåŒäžãïŒã¯åšæåŸè¡šç¬¬æã第æã®é
å±ååãαâ§ïŒãβïŒïŒãïœïŒïœïŒr.sã¯
ïŒãŸãã¯ïŒä»¥äžã®æ°ãïœã¯ïŒã®åå䟡ã§ã
ããmαïŒ2βïŒïœïŒïœïŒïœïŒïœã®é¢ä¿ãæ
ããR1ïŒR2ã¯ççŽ æ°ïŒã20ã®åäžãŸãã¯
ç°ãªã€ãçåæ°ŽçŽ åºãïŒïŒ¹ã¯åäžãŸãã¯
ç°ãªã€ãåºã§ãæ°ŽçŽ åºãOR3ïŒ
OSiR4R5R6ãNR7R8ãSR9ãããã²ã³ã
è¡šãããR3ïŒR4ïŒR5ïŒR6ïŒR7ïŒR8ã¯æ°ŽçŽ
åºãŸãã¯çåæ°ŽçŽ åºãè¡šãããR9ã¯çå
æ°ŽçŽ åºãè¡šããïŒã§ç€ºãããçåæ°ŽçŽ å¯æº¶
ã®ææ©ãã°ãã·ãŠã æåïŒã¢ã«ããããã¯
(a)ãš(b)ãšãŒãã«ãããªãšãŒãã«ãã±ãã³ã
ã¢ã«ããããã«ã«ãã³é žãŸãã¯ãã®èªå°äœ
ãããã¯ã¢ã«ã³ãŒã«ãããªã¢ã«ã³ãŒã«ãã¢
ãã³ããéžã°ããé»åäŸäžäœãåå¿ããã
æåïŒã¢ã«ïŒãã°ãã·ãŠã ã«åºã¥ããŠïŒ
ãšã (ii) äžè¬åŒHaSiClbR10 4-(a+b)ïŒåŒäžãR10ã¯ççŽ
æ°ïŒã20ã®çåæ°ŽçŽ åºãè¡šãããïŒïŒïœâŠ
ïŒãïœã¯ïŒãã倧ããæ°ã§ããïŒã§ç€ºãã
ãçªçŽ ååç©0.01ã100ã¢ã«ãã20ã150â
ã®æž©åºŠã§ã(iii)ç¡æ©é žåç©ã®ååšã«ãããŠå
å¿ãããŠåŸãããã¹ã©ãªãŒç¶åå¿æ··åç©
ã«ã (2) äžè¬åŒTiïŒOR11ïŒoZ4-oïŒåŒäžãR11ã¯ççŽ æ°
ïŒã20ã®çåæ°ŽçŽ åºãè¡šãããã¯ããã²ã³
ååãè¡šãããïœã¯ïŒâŠïœâŠïŒãªãæ°ãè¡šã
ãïŒã§ç€ºããããã¿ã³ååç©ã (3) å«ç¡«é»ãªããå«çªçŽ è€çŽ ç°ã«ã«ãã³é žãšã¹
ãã«ããéžã°ããæå ãå ããŠåŸãããã¹ã©ãªãŒç¶è§Šåªæåãããã³ ãã ææ©ã¢ã«ãããŠã ååç© ãããªã觊åªã§ãã€ãŠã(2)ã®ãã¿ã³ååç©ïŒ(3)ã®
ååç©ã®ã¢ã«æ¯ã0.3以äžã§ãã觊åªãããªã¬ã
ã€ã³ãš100â以äžã§æ¥è§ŠãããŠãªãããªãªã¬ãã€
ã³éåæ³ã§ããã æ¬çºæã®ç¹åŸŽã®ç¬¬äžã¯ã觊åªåæãç°¡åã§ãã
ããšã§ãããæ¬çºæã®æ¹æ³ã«ããã°ãåå¿æåã
å ããŠåŸãããåå¿æ··åç©ããã®ãŸãçšããããš
ãã§ããéã也ç¥ãªã©ã®æäœãçµãããšãªãã«
觊åªã®åæãè¡ãããšãã§ããå»æ£ç©ã®çºçãå°
ãªããšããå©ç¹ãæããã æ¬çºæã®ç¹åŸŽã®ç¬¬äºã¯ãåŸãããéåäœã®ç²å
æ§ç¶ãããããšãã«ç²åŸã倧ããããšã§ãããåŸ
è¿°ã®å®æœäŸã§ãæãããªããã«éåäœç²åã®å¹³å
ç²åŸã¯å€§ããã æ¬çºæã®ãã®ä»ã®ç¹åŸŽã¯ãåŸãããããªããŒã®
ç±æ圢æã®è²èª¿ãè¯ãããšãåŸãããããªããŒã®
ïœâããã¿ã³æœåºæ®æž£ã§è¡šããããç«äœèŠåæ§ã
é«ããŸãŸã§ã觊åªå¹çãé«ãã§ããããšã§ããã æ¬çºæã®åºäœè§Šåªã®åæã«çšããããäžè¬åŒ
MãMgãR1 pR2 qXrYsïŒåŒäžãαïŒÎ²ïŒïœïŒïœïŒr.sïŒ
ïŒïŒR1ïŒR2ïŒïŒžïŒïŒ¹ã¯åè¿°ã®æå³ã§ããïŒã®æ
æ©ãã°ãã·ãŠã æå(a)ã«ã€ããŠèª¬æããã ãã®ååç©ã¯ãææ©ãã°ãã·ãŠã ã®é¯ååç©ã®
圢ãšããŠç€ºãããŠããããR2Mgããã³ããããš
ä»éå±ååç©ãšã®é¯äœã®ãã¹ãŠãå å«ãããã®ã§
ãããäžèšåŒäžã®R1ãªããR9ã§è¡šããããçå
æ°ŽçŽ åºã¯ãã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºãŸãã¯
ã¢ãªã«åºã§ãããããšãã°ãã¡ãã«ããšãã«ãã
ããã«ãããã«ãã¢ãã«ãããã·ã«ããã·ã«ãã·
ã¯ãããã·ã«ãããšãã«åºçãæããããç¹ã«
R1ã¯ã¢ã«ãã«åºã§ããããšã奜ãŸããããŸãR3
ãªããR8ã¯æ°ŽçŽ ååã§ããããšã劚ããªãã éå±ååïŒãšããŠã¯ãåšæåŸè¡šç¬¬æãªãã第
æã«å±ããéå±å çŽ ã䜿çšã§ããããšãã°ããª
ããŠã ããããªãŠã ãã«ãªãŠã ãã«ã«ã·ãŠã ãã
ãªãªãŠã ãäºéãããªãŠã ãããŠçŽ ãã¢ã«ãããŠ
ã çãæããããããç¹ã«ãªããŠã ãã¢ã«ãããŠ
ã ãäºéãããŠçŽ ãããªãªãŠã ãçåæ°ŽçŽ å¯æº¶æ§
ææ©ãã°ãã·ãŠã é¯äœãäœãæããç¹ã«å¥œãŸã
ããéå±ååïŒã«å¯Ÿãããã°ãã·ãŠã ã®æ¯Î²ïŒÎ±
ã¯ãä»»æã«èšå®å¯èœã§ãããã奜ãŸããã¯ïŒã
10ãç¹ã«0.5ã10ã®ç¯å²ã®çåæ°ŽçŽ å¯æº¶æ§ã®ææ©
ãã°ãã·ãŠã é¯äœãç¹ã«å¥œãŸããã èšå·Î±ïŒÎ²ïŒïœïŒïœïŒïœïŒïœã®é¢ä¿åŒïœïŒïœïŒ
ïœïŒïœïŒmαïŒ2βã¯ãéå±ååã®åå䟡ãšçœ®æåº
ãšã®ååŠéè«æ§ã瀺ãã奜ãŸããç¯å²ã§ããïŒâŠ
ïŒïœïŒïœïŒïŒïŒÎ±ïŒÎ²ïŒïŒ1.0ã¯ãéå±ååã®åã«
察ããšïŒ¹ã®åãïŒä»¥äžã§1.0ããå°ã§ããããš
ã瀺ããç¹ã«å¥œãŸããç¯å²ã¯ïŒã0.8ã§ããã ãããã®ææ©ãã°ãã·ãŠã ååç©ãããã¯ææ©
ãã°ãã·ãŠã é¯äœã¯ãäžè¬åŒR1MgQãR1 2MgïŒR1
ã¯åè¿°ã®æå³ã§ãããã¯ããã²ã³ã§ããïŒã§ç€º
ãããææ©ãã°ãã·ãŠã ååç©ãšãäžè¬åŒMR2 n
ãŸãã¯MR2 n-1ïŒïŒïŒR2ïŒïœã¯åè¿°ã®æå³ã§ã
ãïŒã§ç€ºãããææ©éå±ååç©ãšãããããµã³ã
ããã¿ã³ãã·ã¯ããããµã³ããã³ãŒã³ããã«ãšã³
çã®äžæŽ»æ§çåæ°ŽçŽ åªäœäžã宀枩ã150âã®éã§
åå¿ãããå¿ èŠãªå Žåã«ã¯ç¶ããŠããããããã«
ã¢ã«ã³ãŒã«ãæ°Žãã·ãããµã³ãã¢ãã³ãã€ãã³ã
ã¡ã«ã«ãã¿ã³ãŸãã¯ãžããªååç©ãšåå¿ãããã
ãšã«ããåæããããããã«ææ©ãã°ãã·ãŠã å
åç©ãããã¯ææ©ãã°ãã·ãŠã é¯äœã¯ãMgX2ïŒ
R1MgXãšMR2 nãMR2 n-1ããŸãã¯R1MgXã
MgR1 2ãšR2 oMXn-oããŸãã¯R1MgXãMgR2ãšYo
MXn-oïŒåŒäžãïŒïŒR1ïŒR2ïŒïŒžïŒïŒ¹ã¯åè¿°ã®ãšã
ãã§ãã€ãŠãïŒïŒ¹ãããã²ã³ã§ããå Žåãå«
ã¿ãïœã¯ïŒãïœã®æ°ã§ããïŒãšã®åå¿ã«ããåæ
ããããšãã§ããã äžè¬çã«ã¯ææ©ãã°ãã·ãŠã ååç©ã¯äžæŽ»æ§ç
åæ°ŽçŽ åªäœã«äžæº¶æ§ã§ãããαïŒïŒã§ãããšãã
ã®ææ©ãã°ãã·ãŠã é¯äœã¯å¯æº¶æ§ã§ããã ãŸããαïŒïŒã§ãããçš®ã®ææ©ãã°ãã·ãŠã å
åç©ãããšãã°secâBu2Mgçã¯çåæ°ŽçŽ åªäœã«
å¯æº¶æ§ã§ããããã®ãããªååç©ãæ¬çºæã«çšã
ãŠå¥œãŸããçµæãäžãã以äžãããã®ææ©ãã°ã
ã·ãŠã ååç©ã«ã€ããŠèª¬æããã äžè¬åŒMgãR1 pR1 pXrYsã«ãããŠãR1ïŒR2ã¯æ¬¡ã®
äžã€ã®çŸ€ïŒïŒïŒïŒïŒïŒïŒïŒã®ããããäžã€ã§ã
ããã®ãšããã ïŒïŒ R1ïŒR2ã®å°ãªããšãäžæ¹ãççŽ ååæ°
ïŒãïŒã§ããäºçŽãŸãã¯äžçŽã®ã¢ã«ãã«åºã§ã
ãããšã奜ãŸããã¯R1ïŒR2ããšãã«ççŽ åå
æ°ïŒãïŒã§ãããå°ãªããšãäžæ¹ãäºçŽãŸãã¯
äžçŽã®ã¢ã«ãã«åºã§ããããšã ïŒïŒ R1ãšR2ãšãççŽ ååæ°ã®äºãã«çžç°ãª
ãã¢ã«ãã«åºã§ããããšã奜ãŸããã¯R1ãç
çŽ æ°ïŒãŸãã¯ïŒã®ã¢ã«ãã«åºã§ãããR2ãç
çŽ æ°ïŒä»¥äžã®ã¢ã«ãã«åºã§ããããšã ïŒïŒ R1ïŒR2ã®å°ãªããšãäžæ¹ãççŽ ååæ°
ïŒä»¥äžã®çåæ°ŽçŽ åºã§ããããšã奜ãŸããã¯
R1ïŒR2ããšãã«ççŽ ååæ°ïŒä»¥äžã®ã¢ã«ãã«
åºã§ããããšã 以äžããããã®åºãå ·äœçã«ç€ºããïŒïŒã«
ãããŠççŽ ååæ°ïŒãïŒã§ããäºçŽãŸãã¯äžçŽ
ã®ã¢ã«ãã«åºãšããŠã¯ãsecâC4H9ïŒtertâ
C4H9ã
ãªæ¹æ³ã«é¢ããããã«è©³ããã¯ããããã¬ã³ãã
ãã³âïŒãïŒâã¡ãã«ããã³âïŒããã³ãã³â
ïŒãïŒâã¡ãã«ãã³ãã³âïŒçããéžã°ããïŒçš®
ã®ãªã¬ãã€ã³ãç«äœèŠåçã«éåãããŸãã¯äžèš
ãªã¬ãã€ã³ããšãã¬ã³ãŸãã¯ä»ã®ãªã¬ãã€ã³ãšå ±
éåãããã®ã«é©ããéåçšè§Šåªã«ããéåæ¹æ³
ã«é¢ãããã®ã§ããã ãªã¬ãã€ã³ã®ç«äœèŠåæ§éå觊åªãšããŠãå çŽ
åšæåŸè¡šç¬¬æã第æã®é·ç§»éå±ååç©ãšå çŽ
åšæåŸè¡šç¬¬æã第æã®ææ©éå±ååç©ãããª
ããããããããŒã°ã©ãŒã»ããã¿è§Šåªç³»ãç¥ãã
ãŠãããäžã§ãããã²ã³åãã¿ã³ãšããªãšãã«ã¢
ã«ãããŠã ãŸãã¯ãžãšãã«ã¢ã«ãããŠã ã¯ãã©ã€
ãã®ãããªææ©ã¢ã«ãããŠã ååç©ãçµåããã
ã®ããç«äœèŠåæ§ããªãªã¬ãã€ã³ã®è£œé çšè§Šåªãš
ããŠå·¥æ¥çã«äœ¿çšãããŠããã ãããã®è§Šåªç³»ã¯ããããã¬ã³çã®ãªã¬ãã€ã³
ã®éåã«ãããŠãããªãé«ãç«äœèŠåæ§éåäœå
çãããªãã¡æ²žéš°ïœâããã¿ã³äžæº¶äœåçããã€
ãããªãªã¬ãã€ã³ãçæãããã®ã§ãããããã®
éå掻æ§ã¯å¿ ãããååæºè¶³ãã¹ããã®ã§ã¯ãª
ãããã®ããçæéåäœãã觊åªæ®æž£ãé€å»ãã
å·¥çšãå¿ èŠãšãªãã ãŸãé«æŽ»æ§ãªã¬ãã€ã³éå觊åªãšããŠãç¡æ©ãŸ
ãã¯ææ©ãã°ãã·ãŠã ååç©ãšãã¿ããŠã ãŸãã¯
ãããžãŠã ååç©ããããã¯äžèšïŒæåããã³é»
åäŸäžäœãããªã觊åªç³»ãå€æ°ææ¡ãããŠããã
ç¡æ©ãã°ãã·ãŠã 系觊åªãšããŠã¯ãããšãã°ã
Polymer LettersãVol.3ãp855ã857ïŒ1965ïŒã«
ããã°ãå¡©åãã°ãã·ãŠã ãšåå¡©åãã¿ã³ãåå¿
ãããåŸãããªãšãã«ã¢ã«ãããŠã ããã³å¿ èŠã«
å¿ããŠæ·»å å€ãå ããŠããããã¬ã³ã®éåãè¡ã
ããšã瀺ãããŠããããã®å Žåãæ·»å å€ãšããŠé ¢
é žãšãã«çã®é»åäŸäžäœãçšãããšãçæããªã
ãŒã®ç«äœèŠåæ§ãåäžããããšãèšèŒãããŠã
ãããŸãç¹å ¬æ39â12105å·å ¬å ±ã«ãããŠå¡©åã
ã°ãã·ãŠã ãå¡©åã³ãã«ãçã®ç²åã«åå¡©åãã¿
ã³çã被èŠããåŸãããªãšãã«ã¢ã«ãããŠã ããž
ãšãã«ã¢ã«ãããŠã ã¯ãã©ã€ãçã®éå±ã¢ã«ãã«
ãçµåããŠéåãè¡ãéã«ãé ¢é žãšãã«çã®æ·»å
å€ãå ããããšã«ãããéåäœã®äžæº¶å«æéãå¢
倧ããããããšã瀺ãããŠããããŸãå¡©åãã°ã
ã·ãŠã çã®éå±å¡©ãæ©ç ããŠçšããããããšãã
ãã³åå¡©åãã¿ã³çã®æº¶æ¶²ãæ æéå±å¡©ã«æ·»å
ãã該混åç©ãå ±ã«æ¯çªããããšã«ãããæ°èŠãª
觊åªã補é ã§ããããšãèšèŒãããŠããã ããŠããäžæ¹ã®æµãã§ããææ©ãã°ãã·ãŠã ç³»
觊åªãšããŠã¯ãç¹å ¬æ46â31968å·ã«ãããŠãã¢
ã«ãããŠã ããã²ã³ååç©ãšãã¿ã³ååç©ãšææ©
ãã°ãã·ãŠã ååç©ãšãæ··åããã«éããŠãæ··å
åãæ··åæãŸãã¯æ··ååŸã«ãã¢ã«ã«ããŒã«ãã¢ã«
ã±ããŒã«ãã¢ã«ã«ãã©ãŒããã¢ã«ã±ãã©ãŒããã«
ã«ãã³é žãã«ã«ãã³é žã®ãšã¹ãã«ãŸãã¯å¡©ãã¢ã«
ããããŸãã¯ã±ãã³ãæ·»å ããŠãã¢ã«ã±ã³é¡ã
110â以äžã§éåããæ¹æ³ãèšèŒãããŠããã ãã®æ¹æ³ã¯ãéååå¿åž¯åã«ãããéåäœæº¶æ¶²
ã®æ»çæéã10åéãç¹ã«ïŒåé以å ã«çããã
ãã«éåãè¡ãããšãã§ãããšããå©ç¹ãæããŠ
ããããçæéåäœã®æ²žéš°ããã¿ã³äžæº¶åã®å²å
ããŸã ååé«ããªããåºäœè§Šåªæååœãã®éåäœ
åéãäžååã§ããã補é ããã»ã¹ã®æ©åšããã³
æåæ©ã®è èãããããããã²ã³ã®éåäœäžã®å«
éãå€ãã補åç©æ§ãååã«æºè¶³ãã¹ãã§ã¯ãª
ãã ç¹éæ53â40696ãå53â70991ãå53â
100986ãå54â5893ãå54â127889ãå54â
136591çã«ãããŠãå¯æº¶æ§ææ©ãã°ãã·ãŠã æå
ãšïŒšâSiçµåãå«æããã¯ãã«ã·ã©ã³ååç©ãã
ã¿ã³ååç©ãé»åäŸäžäœãæ¥è§ŠãããŠåŸãããåº
äœæåãšææ©éå±ååç©ãçµåããããšã«ããã
åªãããªã¬ãã€ã³éå觊åªãåŸãããããšããŸã
ç¹éæ56â26905ãå56â28206ãå56â32504ã
å56â47408ãå56â5905ããã³ç¹é¡æ55â90720
çã®ææ¡ããªãããŠããã ãããŠãäžèšè§Šåªã«ã€ããŠã觊åªåæäžã®ç¹
ã§ãããã«ç°¡ç¥åããããšãæãŸããã æ¬çºæè ãã¯ãäžèšã®ç¹ã«éã¿ããªã¬ãã€ã³ã®
ç«äœèŠåæ§éå觊åªãçšããéåæ¹æ³ã«ã€ããŠé
ææ€èšããçµæãç¹å®ã®ææ©ãã°ãã·ãŠã æåãš
âSiçµåãå«æããã¯ãã«ã·ã©ã³ååç©ãç¡æ©
é žåç©ã®ååšäžåå¿ãããŠåŸãããåå¿æ··åç©
ã«ãç¹å®ã®ãã¿ã³ååç©ãé»åäŸäžäœãæ·»å ããŠ
åŸãããåå¿æ··åç©ãææ©ã¢ã«ãããŠã ååç©ãš
çµåããããšã«ãããåªããããªãªã¬ãã€ã³ã®è£œ
é ã«é©ãã觊åªãåŸãããããšãèŠåºããæ¬çºæ
ã«å°éããã ããªãã¡ãæ¬çºæã¯ããªã¬ãã€ã³ããã°ãã·ãŠ
ã ååç©ããã¿ã³ååç©ãé»åäŸäžäœãææ©ã¢ã«
ãããŠã ååç©ãããªã觊åªãçšããŠéåããæ¹
æ³ã«ãããŠã ãã (1) (i) (a)äžè¬åŒMãMgãR1 pR2 qXrYs
ïŒåŒäžãïŒã¯åšæåŸè¡šç¬¬æã第æã®é
å±ååãαâ§ïŒãβïŒïŒãïœïŒïœïŒr.sã¯
ïŒãŸãã¯ïŒä»¥äžã®æ°ãïœã¯ïŒã®åå䟡ã§ã
ããmαïŒ2βïŒïœïŒïœïŒïœïŒïœã®é¢ä¿ãæ
ããR1ïŒR2ã¯ççŽ æ°ïŒã20ã®åäžãŸãã¯
ç°ãªã€ãçåæ°ŽçŽ åºãïŒïŒ¹ã¯åäžãŸãã¯
ç°ãªã€ãåºã§ãæ°ŽçŽ åºãOR3ïŒ
OSiR4R5R6ãNR7R8ãSR9ãããã²ã³ã
è¡šãããR3ïŒR4ïŒR5ïŒR6ïŒR7ïŒR8ã¯æ°ŽçŽ
åºãŸãã¯çåæ°ŽçŽ åºãè¡šãããR9ã¯çå
æ°ŽçŽ åºãè¡šããïŒã§ç€ºãããçåæ°ŽçŽ å¯æº¶
ã®ææ©ãã°ãã·ãŠã æåïŒã¢ã«ããããã¯
(a)ãš(b)ãšãŒãã«ãããªãšãŒãã«ãã±ãã³ã
ã¢ã«ããããã«ã«ãã³é žãŸãã¯ãã®èªå°äœ
ãããã¯ã¢ã«ã³ãŒã«ãããªã¢ã«ã³ãŒã«ãã¢
ãã³ããéžã°ããé»åäŸäžäœãåå¿ããã
æåïŒã¢ã«ïŒãã°ãã·ãŠã ã«åºã¥ããŠïŒ
ãšã (ii) äžè¬åŒHaSiClbR10 4-(a+b)ïŒåŒäžãR10ã¯ççŽ
æ°ïŒã20ã®çåæ°ŽçŽ åºãè¡šãããïŒïŒïœâŠ
ïŒãïœã¯ïŒãã倧ããæ°ã§ããïŒã§ç€ºãã
ãçªçŽ ååç©0.01ã100ã¢ã«ãã20ã150â
ã®æž©åºŠã§ã(iii)ç¡æ©é žåç©ã®ååšã«ãããŠå
å¿ãããŠåŸãããã¹ã©ãªãŒç¶åå¿æ··åç©
ã«ã (2) äžè¬åŒTiïŒOR11ïŒoZ4-oïŒåŒäžãR11ã¯ççŽ æ°
ïŒã20ã®çåæ°ŽçŽ åºãè¡šãããã¯ããã²ã³
ååãè¡šãããïœã¯ïŒâŠïœâŠïŒãªãæ°ãè¡šã
ãïŒã§ç€ºããããã¿ã³ååç©ã (3) å«ç¡«é»ãªããå«çªçŽ è€çŽ ç°ã«ã«ãã³é žãšã¹
ãã«ããéžã°ããæå ãå ããŠåŸãããã¹ã©ãªãŒç¶è§Šåªæåãããã³ ãã ææ©ã¢ã«ãããŠã ååç© ãããªã觊åªã§ãã€ãŠã(2)ã®ãã¿ã³ååç©ïŒ(3)ã®
ååç©ã®ã¢ã«æ¯ã0.3以äžã§ãã觊åªãããªã¬ã
ã€ã³ãš100â以äžã§æ¥è§ŠãããŠãªãããªãªã¬ãã€
ã³éåæ³ã§ããã æ¬çºæã®ç¹åŸŽã®ç¬¬äžã¯ã觊åªåæãç°¡åã§ãã
ããšã§ãããæ¬çºæã®æ¹æ³ã«ããã°ãåå¿æåã
å ããŠåŸãããåå¿æ··åç©ããã®ãŸãçšããããš
ãã§ããéã也ç¥ãªã©ã®æäœãçµãããšãªãã«
觊åªã®åæãè¡ãããšãã§ããå»æ£ç©ã®çºçãå°
ãªããšããå©ç¹ãæããã æ¬çºæã®ç¹åŸŽã®ç¬¬äºã¯ãåŸãããéåäœã®ç²å
æ§ç¶ãããããšãã«ç²åŸã倧ããããšã§ãããåŸ
è¿°ã®å®æœäŸã§ãæãããªããã«éåäœç²åã®å¹³å
ç²åŸã¯å€§ããã æ¬çºæã®ãã®ä»ã®ç¹åŸŽã¯ãåŸãããããªããŒã®
ç±æ圢æã®è²èª¿ãè¯ãããšãåŸãããããªããŒã®
ïœâããã¿ã³æœåºæ®æž£ã§è¡šããããç«äœèŠåæ§ã
é«ããŸãŸã§ã觊åªå¹çãé«ãã§ããããšã§ããã æ¬çºæã®åºäœè§Šåªã®åæã«çšããããäžè¬åŒ
MãMgãR1 pR2 qXrYsïŒåŒäžãαïŒÎ²ïŒïœïŒïœïŒr.sïŒ
ïŒïŒR1ïŒR2ïŒïŒžïŒïŒ¹ã¯åè¿°ã®æå³ã§ããïŒã®æ
æ©ãã°ãã·ãŠã æå(a)ã«ã€ããŠèª¬æããã ãã®ååç©ã¯ãææ©ãã°ãã·ãŠã ã®é¯ååç©ã®
圢ãšããŠç€ºãããŠããããR2Mgããã³ããããš
ä»éå±ååç©ãšã®é¯äœã®ãã¹ãŠãå å«ãããã®ã§
ãããäžèšåŒäžã®R1ãªããR9ã§è¡šããããçå
æ°ŽçŽ åºã¯ãã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºãŸãã¯
ã¢ãªã«åºã§ãããããšãã°ãã¡ãã«ããšãã«ãã
ããã«ãããã«ãã¢ãã«ãããã·ã«ããã·ã«ãã·
ã¯ãããã·ã«ãããšãã«åºçãæããããç¹ã«
R1ã¯ã¢ã«ãã«åºã§ããããšã奜ãŸããããŸãR3
ãªããR8ã¯æ°ŽçŽ ååã§ããããšã劚ããªãã éå±ååïŒãšããŠã¯ãåšæåŸè¡šç¬¬æãªãã第
æã«å±ããéå±å çŽ ã䜿çšã§ããããšãã°ããª
ããŠã ããããªãŠã ãã«ãªãŠã ãã«ã«ã·ãŠã ãã
ãªãªãŠã ãäºéãããªãŠã ãããŠçŽ ãã¢ã«ãããŠ
ã çãæããããããç¹ã«ãªããŠã ãã¢ã«ãããŠ
ã ãäºéãããŠçŽ ãããªãªãŠã ãçåæ°ŽçŽ å¯æº¶æ§
ææ©ãã°ãã·ãŠã é¯äœãäœãæããç¹ã«å¥œãŸã
ããéå±ååïŒã«å¯Ÿãããã°ãã·ãŠã ã®æ¯Î²ïŒÎ±
ã¯ãä»»æã«èšå®å¯èœã§ãããã奜ãŸããã¯ïŒã
10ãç¹ã«0.5ã10ã®ç¯å²ã®çåæ°ŽçŽ å¯æº¶æ§ã®ææ©
ãã°ãã·ãŠã é¯äœãç¹ã«å¥œãŸããã èšå·Î±ïŒÎ²ïŒïœïŒïœïŒïœïŒïœã®é¢ä¿åŒïœïŒïœïŒ
ïœïŒïœïŒmαïŒ2βã¯ãéå±ååã®åå䟡ãšçœ®æåº
ãšã®ååŠéè«æ§ã瀺ãã奜ãŸããç¯å²ã§ããïŒâŠ
ïŒïœïŒïœïŒïŒïŒÎ±ïŒÎ²ïŒïŒ1.0ã¯ãéå±ååã®åã«
察ããšïŒ¹ã®åãïŒä»¥äžã§1.0ããå°ã§ããããš
ã瀺ããç¹ã«å¥œãŸããç¯å²ã¯ïŒã0.8ã§ããã ãããã®ææ©ãã°ãã·ãŠã ååç©ãããã¯ææ©
ãã°ãã·ãŠã é¯äœã¯ãäžè¬åŒR1MgQãR1 2MgïŒR1
ã¯åè¿°ã®æå³ã§ãããã¯ããã²ã³ã§ããïŒã§ç€º
ãããææ©ãã°ãã·ãŠã ååç©ãšãäžè¬åŒMR2 n
ãŸãã¯MR2 n-1ïŒïŒïŒR2ïŒïœã¯åè¿°ã®æå³ã§ã
ãïŒã§ç€ºãããææ©éå±ååç©ãšãããããµã³ã
ããã¿ã³ãã·ã¯ããããµã³ããã³ãŒã³ããã«ãšã³
çã®äžæŽ»æ§çåæ°ŽçŽ åªäœäžã宀枩ã150âã®éã§
åå¿ãããå¿ èŠãªå Žåã«ã¯ç¶ããŠããããããã«
ã¢ã«ã³ãŒã«ãæ°Žãã·ãããµã³ãã¢ãã³ãã€ãã³ã
ã¡ã«ã«ãã¿ã³ãŸãã¯ãžããªååç©ãšåå¿ãããã
ãšã«ããåæããããããã«ææ©ãã°ãã·ãŠã å
åç©ãããã¯ææ©ãã°ãã·ãŠã é¯äœã¯ãMgX2ïŒ
R1MgXãšMR2 nãMR2 n-1ããŸãã¯R1MgXã
MgR1 2ãšR2 oMXn-oããŸãã¯R1MgXãMgR2ãšYo
MXn-oïŒåŒäžãïŒïŒR1ïŒR2ïŒïŒžïŒïŒ¹ã¯åè¿°ã®ãšã
ãã§ãã€ãŠãïŒïŒ¹ãããã²ã³ã§ããå Žåãå«
ã¿ãïœã¯ïŒãïœã®æ°ã§ããïŒãšã®åå¿ã«ããåæ
ããããšãã§ããã äžè¬çã«ã¯ææ©ãã°ãã·ãŠã ååç©ã¯äžæŽ»æ§ç
åæ°ŽçŽ åªäœã«äžæº¶æ§ã§ãããαïŒïŒã§ãããšãã
ã®ææ©ãã°ãã·ãŠã é¯äœã¯å¯æº¶æ§ã§ããã ãŸããαïŒïŒã§ãããçš®ã®ææ©ãã°ãã·ãŠã å
åç©ãããšãã°secâBu2Mgçã¯çåæ°ŽçŽ åªäœã«
å¯æº¶æ§ã§ããããã®ãããªååç©ãæ¬çºæã«çšã
ãŠå¥œãŸããçµæãäžãã以äžãããã®ææ©ãã°ã
ã·ãŠã ååç©ã«ã€ããŠèª¬æããã äžè¬åŒMgãR1 pR1 pXrYsã«ãããŠãR1ïŒR2ã¯æ¬¡ã®
äžã€ã®çŸ€ïŒïŒïŒïŒïŒïŒïŒïŒã®ããããäžã€ã§ã
ããã®ãšããã ïŒïŒ R1ïŒR2ã®å°ãªããšãäžæ¹ãççŽ ååæ°
ïŒãïŒã§ããäºçŽãŸãã¯äžçŽã®ã¢ã«ãã«åºã§ã
ãããšã奜ãŸããã¯R1ïŒR2ããšãã«ççŽ åå
æ°ïŒãïŒã§ãããå°ãªããšãäžæ¹ãäºçŽãŸãã¯
äžçŽã®ã¢ã«ãã«åºã§ããããšã ïŒïŒ R1ãšR2ãšãççŽ ååæ°ã®äºãã«çžç°ãª
ãã¢ã«ãã«åºã§ããããšã奜ãŸããã¯R1ãç
çŽ æ°ïŒãŸãã¯ïŒã®ã¢ã«ãã«åºã§ãããR2ãç
çŽ æ°ïŒä»¥äžã®ã¢ã«ãã«åºã§ããããšã ïŒïŒ R1ïŒR2ã®å°ãªããšãäžæ¹ãççŽ ååæ°
ïŒä»¥äžã®çåæ°ŽçŽ åºã§ããããšã奜ãŸããã¯
R1ïŒR2ããšãã«ççŽ ååæ°ïŒä»¥äžã®ã¢ã«ãã«
åºã§ããããšã 以äžããããã®åºãå ·äœçã«ç€ºããïŒïŒã«
ãããŠççŽ ååæ°ïŒãïŒã§ããäºçŽãŸãã¯äžçŽ
ã®ã¢ã«ãã«åºãšããŠã¯ãsecâC4H9ïŒtertâ
C4H9ã
ãåŒã
ãåŒã
ãåŒã
ãåŒãçãçšãããã奜ãŸããã¯äº
çŽã®ã¢ã«ãã«åºã§ãããsecâC4H9ã¯ç¹ã«å¥œãŸ
ããã 次ã«ãïŒïŒã«ãããŠççŽ æ°ïŒãŸãã¯ïŒã®ã¢ã«
ãã«åºãšããŠã¯ãšãã«åºããããã«åºãæãã
ãããšãã«åºã¯ç¹ã«å¥œãŸããããŸãççŽ æ°ïŒä»¥äž
ã®ã¢ã«ãã«åºãšããŠã¯ããã«åºãã¢ãã«åºããã
ã·ã«åºããªã¯ãã«åºçãæããããããã«åºãã
ãã·ã«åºã¯ç¹ã«å¥œãŸãããïŒïŒã«ãããŠççŽ å
åæ°ïŒä»¥äžã®çåæ°ŽçŽ åºãšããŠã¯ãããã·ã«åºã
ãªã¯ãã«åºããã·ã«åºãããšãã«åºçãæãã
ããã¢ã«ãã«åºã§ããæ¹ã奜ãŸãããããã·ã«åº
ã¯ç¹ã«å¥œãŸããã æ¬çºæã«çšããããææ©ãã°ãã·ãŠã ååç©
ã¯ãçåæ°ŽçŽ åªäœã«å¯æº¶ã§ããããšãéèŠã§ã
ããã¢ã«ãã«åºã®ççŽ ååæ°ãå¢ããšçåæ°ŽçŽ åª
äœã«æº¶ãæããªããã溶液ã®ç²æ§ãé«ããªãåŸå
ã§ãããå¿ èŠä»¥äžã«é·éã®ã¢ã«ãã«åºãçšããã
ãšã¯åæ±ãäžå¥œãŸãããªãã ãªããäžèšææ©ãã°ãã·ãŠã ååç©ã¯çåæ°ŽçŽ
溶液ãšããŠçšãããããã該溶液äžã«åŸ®éã®ãšãŒ
ãã«ããšã¹ãã«ãã¢ãã³çã®ã³ã³ãã¬ãã¯ã¹åå€
ããããã«å«æããããããã¯æ®åããŠããå Žå
ãããã€ãããªãçšããããšãã§ããã åèšäžè¬åŒäžãαïŒïŒãβïŒïŒãïœïŒïŒãïœïŒ
ïŒãªãææ©ãã°ãã·ãŠã ãã©ã€ãã«ã€ããŠèª¬æã
ãã ãã®ååç©ã¯ãããããã°ãªãã€ãŒååç©ã§ã
ããäžè¬ã«ãã°ãã·ãŠã ããšãŒãã«æº¶æ¶²äžã®ææ©
ããã²ã³åç©ã«åå¿ãããããšã«ãã€ãŠåæãã
ãããšãŒãã«ã®äžååšäžã«ãããŠãçåæ°ŽçŽ åªè³ª
äžã§ãã®åå¿ãè¡ãããããšãç¥ãããŠãããã©
ã¡ãã䜿çšããããšãã§ããã ãããã®äŸãšããŠã¯ãããšãã°ãã¡ãã«ãã°ã
ã·ãŠã ã¯ããªããã¡ãã«ãã°ãã·ãŠã ããããã
ã¡ãã«ãã°ãã·ãŠã ã¢ã€ãªãã€ãããšãã«ãã°ã
ã·ãŠã ã¯ããªãããšãã«ãã°ãã·ãŠã ããããã
ãšãã«ãã°ãã·ãŠã ã¢ã€ãªãã€ããïœâãŸãã¯
isoâãããã«ãã°ãã·ãŠã ã¯ããªããïœâãŸã
ã¯isoâãããã«ãã°ãã·ãŠã ãããããïœâãŸ
ãã¯isoâãããã«ãã°ãã·ãŠã ã¢ã€ãªãã€ãã
ïœâããã«ãã°ãã·ãŠã ã¯ããªããïœâããã«ã
ã°ãã·ãŠã ãããããïœâããã«ãã°ãã·ãŠã ã¢
ã€ãªãã€ããisoâãsecâãããã¯tertâããã«
ãã°ãã·ãŠã ã¯ããªããisoâãsecâãããã¯
tertâããã«ãã°ãã·ãŠã ãããããisoâãsec
âãããã¯tertâããã«ãã°ãã·ãŠã ã¢ã€ãªãã€
ããïœâã¢ãã«ãã°ãã·ãŠã ã¯ããªããïœâã¢ã
ã«ãã°ãã·ãŠã ãããããããã·ã«ãã°ãã·ãŠã
ã¯ããªããããã·ã«ãã°ãã·ãŠã ããããããªã¯
ãã«ãã°ãã·ãŠã ã¯ããªããããšãã«ãã°ãã·ãŠ
ã ã¯ããªããããšãã«ãã°ãã·ãŠã ããããçã®
ååç©ããªãã³ã«ãããã®ãšãŒãã«é¯åäœãæã
ãããšãã§ããããããã®ãšãŒãã«ååç©ãšããŠ
ã¯ãããšãã°ããžã¡ãã«ãšãŒãã«ããžãšãã«ãšãŒ
ãã«ããžã€ãœãããã«ãšãŒãã«ããžããã«ãšãŒã
ã«ããžã¢ãªã«ãšãŒãã«ãããã©ããããã©ã³ããž
ãªããµã³ãã¢ããœãŒã«çã®åçš®ã®ãšãŒãã«ååç©
ãæããããšãã§ããã 次ã«ã(a)ææ©ãã°ãã·ãŠã æåãš(b)é»åäŸäžå
åç©ã®åå¿ã«ã€ããŠèª¬æããã (a)ææ©ãã°ãã·ãŠã æåãšããŠã¯ãåèšã®åæ
åãçšããããšãã§ãããã液çžã§(b)é»åäŸäžå
åç©ãšåå¿ãããã®ã奜ãŸãããçåæ°ŽçŽ ç³»ãã
ãã¯ãšãŒãã«ç³»æº¶åªçã«å¯æº¶ã®ææ©ãã°ãã·ãŠã
æåã奜ãŸããçµæãäžããã (a)ææ©ãã°ãã·ãŠã æåãšåå¿ããã(b)é»åäŸ
äžååç©ã¯æ¬¡ã®ããšããã®ã§ããã äžè¬åŒRORâ²ã§è¡šãããããšãŒãã«ïŒåŒäžã
ããã³Râ²ã¯èèªæãè³éŠæãŸãã¯èç°åŒçåæ°Ž
çŽ åºã§ãããããšãã°ãã¡ãã«ããšãã«ãããã
ã«ãããã«ãã¢ãã«ãããã·ã«ããã·ã«ããªã¯ã
ã«ãããã·ã«ãã·ã¯ãããã·ã«ãããšãã«ããã³
ãžã«çã§ãããïŒ äžè¬åŒRSRâ²ã§è¡šããããããªãšãŒãã«ïŒåŒäžã
ããã³Râ²ã¯èèªæãè³éŠæãŸãã¯èç°åŒçå
æ°ŽçŽ ã§ãããããšãã°ãã¡ãã«ããšãã«ãããã
ã«ãããã«ãã¢ãã«ãããã·ã«ãã·ã¯ãããã·
ã«ãããšãã«çã§ãããïŒ äžè¬åŒRCORâ²ã§è¡šããããã±ãã³ïŒåŒäžã
ããã³Râ²ã¯èèªæãè³éŠæãŸãã¯èç°åŒçåæ°Ž
çŽ åºã§ãããããšãã°ãã¡ãã«ããšãã«ãããã
ã«ãããã«ãã¢ãã«ãããã·ã«ãã·ã¯ãããã·
ã«ãããšãã«çã§ãããç¹ã«ãžã¡ãã«ã±ãã³ããž
ãšãã«ã±ãã³çã奜ãŸãããïŒ èèªæãè³éŠæããã³èç°åŒã¢ã«ããããçå
æ°ŽçŽ ç³»ã«ã«ãã³é žãŸãã¯ãã®èªå°äœãããå ·äœç
ã«ã¯çåæ°ŽçŽ ç³»ã«ã«ãã³é žãçåæ°ŽçŽ ç³»ã«ã«ãã³
é žç¡æ°Žç©ãçåæ°ŽçŽ ç³»ã«ã«ãã³é žãšã¹ãã«ãçå
æ°ŽçŽ ç³»ã«ã«ãã³é žããã²ã³åç©ãçåæ°ŽçŽ ç³»ã«ã«
ãã³é žã¢ããã§ããã 以äžãããã«ã€ããããã«å ·äœçã«èšè¿°ããã çåæ°ŽçŽ ç³»ã«ã«ãã³é žãšããŠã¯ãããšãã°ãã®
é žãé ¢é žãããããªã³é žãé ªé žãåèé žãã·ãŠãŠ
é žãããã³é žãã³ãã¯é žããã¬ã€ã³é žãã¢ã¯ãªã«
é žãå®æ¯éŠé žããã«ã€ã«é žããã¬ãã¿ã«é žçãæ
ãããããã«ã«ãã³é žç¡æ°Žç©ãšããŠã¯ãããšã
ã°ãç¡æ°Žé ¢é žãç¡æ°Žããããªã³é žãç¡æ°Žé ªé žãç¡
æ°Žã³ãã¯é žãç¡æ°Žãã¬ã€ã³é žãç¡æ°Žå®æ¯éŠé žãç¡
æ°Žãã¿ã«é žçãæããããã çåæ°ŽçŽ ç³»ã«ã«ãã³é žãšã¹ãã«ãšããŠã¯ãã®é ž
ã¡ãã«ããã³ãšãã«ãé ¢é žã¡ãã«ããšãã«ããã
ãã«ãããããªã³é žã¡ãã«ããšãã«ããããã«ã
ããã«ãé ªé žãšãã«ãåèé žãšãã«ãã«ããã³é ž
ãšãã«ãïœâããã¿ã³é žãšãã«ãã·ãŠãŠé žãžãã
ã«ãã³ãã¯é žãšãã«ãããã³é žãšãã«ããã¬ã€ã³
é žãžããã«ãã¢ã¯ãªã«é žã¡ãã«ãã¢ã¯ãªã«é žãšã
ã«ãã¡ã¿ã¯ãªã«é žã¡ãã«ãå®æ¯éŠé žã¡ãã«ããšã
ã«ããããã«ãããã«ããã«ã€ã«é žã¡ãã«ããšã
ã«ããããã«ãããã«ãã¢ãã«ãïœâãšãã«å®æ¯
éŠé žã¡ãã«ããã³ãšãã«ãã¢ãã¹é žã¡ãã«ããšã
ã«ããããã«ããã³ããã«ãïœâãšããã·å®æ¯éŠ
é žã¡ãã«ããšãã«ãæããããã çåæ°ŽçŽ ç³»ã«ã«ãã³é žããã²ã³åç©ãšããŠã¯ã
é žå¡©åç©ã奜ãŸãããå¡©åã¢ã»ãã«ãå¡©åããã
ãªãã«ãå¡©åãããªã«ãå¡©åã¹ã¯ã·ãã«ãå¡©åã
ã³ãŸã€ã«ãå¡©åãã«ã€ã«ãæããããã çåæ°ŽçŽ ç³»ã«ã«ãã³é žã¢ãããšããŠã¯ããžã¡ã
ã«ãã«ã ã¢ããããžã¡ãã«ã¢ã»ãã¢ããããžã¡ã
ã«ããããªã³ã¢ããçãæããããã ã¢ã«ã³ãŒã«ãšããŠã¯ãã¡ãã«ã¢ã«ã³ãŒã«ããšã
ã«ã¢ã«ã³ãŒã«ããããã«ã¢ã«ã³ãŒã«ãããã«ã¢ã«
ã³ãŒã«ãã¢ãã«ã¢ã«ã³ãŒã«ãããã·ã«ã¢ã«ã³ãŒ
ã«ãããšããŒã«ãã¯ã¬ãŸãŒã«çãæãããããã
secâãããã«ã¢ã«ã³ãŒã«ãsecâããã«ã¢ã«ã³ãŒ
ã«ãtertâããã«ã¢ã«ã³ãŒã«ãsecâã¢ãã«ã¢ã«
ã³ãŒã«ãtertâã¢ãã«ã¢ã«ã³ãŒã«ãsecâããã·
ã«ã¢ã«ã³ãŒã«ãããšããŒã«ãïœïŒïœãïŒïœâã¯ã¬
ãŸãŒã«çã®äºçŽãäžçŽãªããè³éŠæã¢ã«ã³ãŒã«ã
奜ãŸããã ããªã¢ã«ã³ãŒã«ãšããŠã¯ãã¡ãã«ã¡ã«ã«ãã¿
ã³ããšãã«ã¡ã«ã«ãã¿ã³ããããã«ã¡ã«ã«ãã¿
ã³ãããã«ã¡ã«ã«ãã¿ã³ãã¢ãã«ã¡ã«ã«ãã¿ã³ã
ããã·ã«ã¡ã«ã«ãã¿ã³ãããšãã«ã¡ã«ã«ãã¿ã³ç
ãæããããããäºçŽãäžçŽãªããè³éŠæããªã¢
ã«ã³ãŒã«ã奜ãŸããã ã¢ãã³ãšããŠã¯ãèèªæãèç°åŒãªããè³éŠæ
ã¢ãã³ãæããããããäºçŽãªããäžçŽã¢ãã³ã
ããšãã°ãããªã¢ã«ãã«ã¢ãã³ãããªããšãã«ã¢
ãã³ãããªãžã³çã奜ãŸããçµæãäžããã 次ã«ã(a)ææ©ãã°ãã·ãŠã æåãš(b)é»åäŸäžäœ
ååç©ã®åå¿ã«ã€ããŠã¯ãåå¿ãäžæŽ»æ§åå¿åª
äœãããšãã°ããããµã³ãããã¿ã³ã®ããšãèèª
æçåæ°ŽçŽ ããã³ãŒã³ããã«ãšã³ããã·ã¬ã³çã®
è³éŠæçåæ°ŽçŽ ãã·ã¯ããããµã³ãã¡ãã«ã·ã¯ã
ãããµã³çã®èç°åŒçåæ°ŽçŽ ãããã¯ãšãŒãã«ç³»
溶åªãŸãã¯ãããã®æ··å溶åªäžã§è¡ãããšãã§ã
ããåå¿é äºã«ã€ããŠã¯ãææ©ãã°ãã·ãŠã æå
äžã«é»åäŸäžååç©ãå ããŠããæ¹æ³ïŒïŒãé»
åäŸäžååç©äžã«ææ©ãã°ãã·ãŠã æåãå ããŠ
ããæ¹æ³ïŒïŒãäž¡è ãåæã«å ããŠããæ¹æ³
ïŒïŒãçšããããšãã§ããã ææ©ãã°ãã·ãŠã æåãšé»åäŸäžååç©ã®åå¿
æ¯çã«ã€ããŠã¯ãææ©ãã°ãã·ãŠã æåïŒã¢ã«ã«
ã€ããŠãé»åäŸäžååç©ïŒã¢ã«ä»¥äžã奜ãŸããã¯
0.01ã0.8ã¢ã«ã§ãããç¹ã«å¥œãŸããã¯0.05ã0.5
ã¢ã«ã§ããã 次ã«ã(ii)äžè¬åŒHaSiClbR10 4-(a+b)ïŒåŒäžãïœïŒïœ
ïŒ
R10ã¯åè¿°ã®æå³ã§ããïŒã§ç€ºãããSiâçµå
å«æã¯ãã«ã·ã©ã³ååç©ã«ã€ããŠèª¬æããã äžèšåŒã«ãããŠR10ã§è¡šããããçåæ°ŽçŽ åº
ã¯ãèèªæçåæ°ŽçŽ åºãèç°åŒçåæ°ŽçŽ åºãè³éŠ
æçåæ°ŽçŽ åºã§ãããããšãã°ãã¡ãã«ããšã
ã«ããããã«ãããã«ãã¢ãã«ãããã·ã«ããã·
ã«ãã·ã¯ãããã·ã«ãããšãã«åºçãæãããã
奜ãŸããã¯ççŽ æ°ïŒã10ã®ã¢ã«ãã«åºã§ãããã¡
ãã«ããšãã«ããããã«çã®äœçŽã¢ã«ãã«åºãç¹
ã«å¥œãŸãããïœã®å€ã¯ãïœïŒïŒãïœïŒïœâŠïŒãïŒ
ïŒïœâŠïŒã§ããã0.5âŠïœâŠ1.5ã奜ãŸããã ãããã®ååç©ãšããŠã¯ãHSiCl3ïŒ
HSiCl2CH3ïŒHSiCl2C2H5ïŒHSiCl2nâC3H7ïŒ
HSiCl2isoâC3H7ïŒHSiCl2nâC4H9ïŒ
HSiCl2C6H5ïŒHSiCl2ïŒïŒâClâC6H4ïŒïŒ
HSiCl2CHïŒCH2ïŒHSiCl2CH2C6H5ïŒHSiCl2ïŒïŒ
âC10H7ïŒïŒHSiCl2CH2CHïŒCH2ïŒH2SiClCH3ïŒ
H2SiClC2H5ïŒHSiClïŒCH3ïŒ2ïŒHSiClCH3ïŒisoâ
C3H7ïŒïŒHSiClCH3ïŒC6H5ïŒïŒHSiClïŒC2H5ïŒ2ïŒ
HSiClïŒC6H5ïŒ2çãæãããããããã®ååç©ã
ãã³ãããã®ååç©ããéžã°ããååç©ãšã®æ··å
ç©ãããªãã¯ãã«ã·ã©ã³ååç©ã䜿çšãããããª
ã¯ãã«ã·ã©ã³ãã¢ãã¡ãã«ãžã¯ãã«ã·ã©ã³ããžã¡
ãã«ã¯ãã«ã·ã©ã³ããšãã«ãžã¯ãã«ã·ã©ã³çã奜
ãŸãããããªã¯ãã«ã·ã©ã³ãã¢ãã¡ãã«ãžã¯ãã«
ã·ã©ã³ãç¹ã«å¥œãŸããã (1)â(iii)ã®ç¡æ©é žåç©ãšããŠã¯ãåšæåŸè¡šç¬¬æ
ãªãã第æå çŽ ã®é žåç©ã§ã殺çŒãã·ãªã«ãã¢
ã«ããããã°ãã·ã¢ãããã¯ãããã®è€åäœãæ··
åç©ãæãããããã·ãªã«ãªããã·ãªã«ã»ã¢ã«ã
ãã奜ãŸãããç¹ã«ã·ãªã«ã奜ãŸããããããŠã
ã·ãªã«ã®äžã§ãB.E.T.æ³ã§æž¬å®ãããæ¯è¡šé¢ç©
ã200ã600m2ïŒïœãæ¯å容ç©ãïŒmlïŒïœãå¹³åå
åŸã50ã300â«ã®ãã®ã¯ããã«å¥œãŸããçµæãäž
ãããç¡æ©é žåç©ã¯ãã¢ã«ãŽã³ãçªçŽ ã¬ã¹çã®æ°
æµäžãããã¯ç空äžã«ãããŠãå ç±ä¹Ÿç¥ããŠçšã
ãããšã奜ãŸããã 以äžãææ©ãã°ãã·ãŠã æå(i)ãã¯ãã«ã·ã©ã³
ååç©(ii)ãããã³ç¡æ©é žåç©(iii)ã®åå¿ã«ã€ããŠèª¬
æãããåå¿æ¹æ³ã«ã€ããŠã¯ãïŒçš®æåãåæã«
åå¿åž¯ã«å°å ¥ãã€ã€åå¿ãããåææ·»å ã®æ¹æ³
ïŒæ¹æ³âã€ïŒãææ©ãã°ãã·ãŠã æåãšç¡æ©é žåç©ã
åå¿ãããåŸãã¯ãã«ã·ã©ã³æåãšåå¿ãããæ¹
æ³ïŒæ¹æ³âãïŒãã¯ãã«ã·ã©ã³æåãšç¡æ©é žåç©ã
åå¿ãããåŸãææ©ãã°ãã·ãŠã æåãšåå¿ãã
ãæ¹æ³ïŒæ¹æ³âãïŒãææ©ãã°ãã·ãŠã æåãšã¯ã
ã«ã·ã©ã³æåãåå¿ãããåŸãç¡æ©é žåç©ãšåå¿
ãããæ¹æ³ïŒæ¹æ³âãïŒçãæããããããæ¹æ³
âã€ïŒâãïŒâãã奜ãŸãããç¹ã«æ¹æ³âãã奜ãŸãã
ã ææ©ãã°ãã·ãŠã æåãã¯ãã«ã·ã©ã³ããã³ç¡
æ©é žåç©ã®åå¿ã¯ãäžæŽ»æ§åå¿åªäœãããšãã°ã
ãããµã³ãããã¿ã³ã®åŠãèèªæçåæ°ŽçŽ ããã³
ãŒã³ããã«ãšã³ããã·ã¬ã³ã®ããšãè³éŠæçåæ°Ž
çŽ ãã·ã¯ããããµã³ãã¡ãã«ã·ã¯ããããµã³ã®åŠ
ãèç°åŒçåæ°ŽçŽ ããããã¯ãšãŒãã«ãããã©ã
ãããã©ã³çã®ãšãŒãã«ç³»åªäœããããã¯ããã
ã®æ··ååªäœäžã§è¡ãããšãã§ããã觊åªæ§èœäžã
èèªæçåæ°ŽçŽ åªäœã奜ãŸãããåå¿æž©åºŠã¯20ã
150âã§å®æœãããããã¯ãã«ã·ã©ã³ãåå¿ãã
ãå Žåã¯ãã¯ãã«ã·ã©ã³ã®æ²žç¹ä»¥äžãããã¯40â
以äžã§å®æœãããã åå¿æ¯çã«ã€ããŠã¯ãææ©ãã°ãã·ãŠã æåïŒ
ã¢ã«ã«å¯Ÿããã¯ãã«ã·ã©ã³0.01ã100ã¢ã«ã奜ãŸ
ããã¯0.1ã10ã¢ã«ãç¹ã«å¥œãŸããã¯0.2ãïŒã¢ã«
ã®ç¯å²ã§ãããç¡æ©é žåç©10ïœã10Kgã奜ãŸãã
ã¯100ïœãïŒKgãç¹ã«å¥œãŸããã¯200ïœãïŒKgã®ç¯
å²ã§ããã æ¬çºæã«ãããŠã¯ãææ©ãã°ãã·ãŠã æåãšã¯
ãã«ã·ã©ã³ååç©ããã³ç¡æ©é žåç©ãåå¿ãããŠ
åŸãããåå¿æ··åç©ã«ãéãæŽæ»ãªã©ã®æäœã
å ããããšãªãããã¿ã³ååç©ãè€çŽ ç°ã«ã«ãã³
é žãšã¹ãã«ãããã¯çåæ°ŽçŽ ã«ã«ãã³é žãšã¹ãã«
ãå ããããšã«ãããããæåãåŸãããšãã§
ããã 次ã«ã(2)äžè¬åŒTiïŒOR11ïŒoZ4-oã§ç€ºããããã¿
ã³ååç©ã«ã€ããŠèª¬æããïŒåŒäžãR11ã¯ççŽ æ°
ïŒã20ã®çåæ°ŽçŽ åºããã¯ããã²ã³ååããïœ
ã¯ïŒâŠïœâŠïŒãªãæ°ãè¡šããïŒã äžèšåŒã«ãããŠR11ã§è¡šããããçåæ°ŽçŽ åº
ã¯ãèèªæçåæ°ŽçŽ åºãèç°åŒçåæ°ŽçŽ åºãè³éŠ
æçåæ°ŽçŽ åºã§ãããããšãã°ãã¡ãã«ããšã
ã«ããããã«ãããã«ãã¢ãã«ãããã·ã«ããã
ãã«ããªã¯ãã«ãããã«ããã·ã«ãã»ãã«ãã¹ã
ã¢ãªã«ãïŒâãšãã«ããã·ã«ãã·ã¯ããã³ãã«ã
ã·ã¯ãããã·ã«ãããšãã«ãã¯ã¬ãžã«ããããã«
çãæããããšãã§ããã ããã²ã³ååãšããŠã¯ãå¡©çŽ ãèçŽ ãæ²çŽ ãæ
ãããããïŒïŒïœâŠïŒã§ãããã¿ã³ã®ããã²ã³å
ç©ãšããŠã¯ãåå¡©åãã¿ã³ãåèåãã¿ã³ãåãš
ãŠåãã¿ã³ããšããã·ãã¿ã³ããªã¯ããªãããã
ããã·ãã¿ã³ããªã¯ããªãããããã·ãã¿ã³ããª
ã¯ããªãããžãããã·ãã¿ã³ãžã¯ããªããããªã
ããã·ãã¿ã³ã¢ãã¯ããªãçããã¿ã³ã®ããã²ã³
åç©ãã¢ã«ã³ãã·ããã²ã³åç©ã®åç¬ãŸãã¯æ··å
ç©ãçšããããã奜ãŸããååç©ã¯ããã²ã³ãïŒ
å以äžå«ãååç©ã§ãããç¹ã«å¥œãŸããã¯åå¡©å
ãã¿ã³ã§ããã ïœïŒïŒã§ããååç©ãšããŠã¯ãTiïŒOCH3ïŒ4ïŒ
TiïŒOC2H5ïŒ4ïŒTiïŒOnâC3H7ïŒ4ïŒTiïŒOisoâ
C3H7ïŒ4ïŒTiïŒOnâC4H9ïŒ4ïŒTiïŒOsecâC4H9ïŒ4ïŒ
TiïŒOisoâC4H9ïŒ4ïŒTiïŒOtertâC4H9ïŒ4ïŒTiïŒOn
âC5H11ïŒ4ïŒTiïŒOtertâC5H11ïŒ4ïŒTiïŒOnâ
C6H13ïŒ4ãTiïŒOnâC7H15ïŒ4ïŒTiïŒOnâC8H17ïŒ4ïŒ
TiïŒOisoâC5H11ïŒ4ïŒTiïŒOnâC9H19ïŒ4ïŒTiïŒOnâ
C10H21ïŒ4ïŒTiïŒOnâC16H33ïŒ4ïŒTiïŒOnâ
C18H37ïŒ4ïŒTiïŒOC8H17ïŒ4ãTitanium2ethyl
hexoideããTiïŒOC6H14ïŒ4ïŒTiïŒOC6H5ïŒ4ïŒTi
ïŒOC6H4CH3ïŒ4ïŒTiïŒOC10H7ïŒ4ãçãæãããã
ãããã®ååç©ããã³ãããã®ååç©ããéžã°ã
ãæ··åç©ãããªããã¿ã³ååç©ã䜿çšãããã (3)ã®å«ç¡«é»è€çŽ ç°ã«ã«ãã³é žãšã¹ãã«ãšããŠ
ã¯ãããªããšã³é¡ã«ã«ãã³é žãšã¹ãã«ããã¢ãã
ãã³é¡ã«ã«ãã³é žãšã¹ãã«ãã€ãœãã¢ãããã³é¡
ã«ã«ãã³é žãšã¹ãã«ããã³ãŸããªããšã³é¡ã«ã«ã
ã³é žãšã¹ãã«ãããšãããµãã€ã³é¡ã«ã«ãã³é žãš
ã¹ãã«ããã³ãŸãã¢ã³é¡ã«ã«ãã³é žãšã¹ãã«ãã
ã¢ããµã³ãã³é¡ã«ã«ãã³é žãšã¹ãã«ãããªã€ã³ã
ãã·ã«é¡ã«ã«ãã³é žãšã¹ãã«çãæãããããã
å ·äœçã«æãããšãããªããšã³âïŒâã«ã«ãã³é ž
ã¡ãã«ããšãã«ããããã«ãããã«ããã³ã¢ã
ã«ãããªããšã³âïŒâã«ã«ãã³é žã¡ãã«ããšã
ã«ããããã«ãããã«ããã³ã¢ãã«ãããªããšã³
âïŒïŒïŒâãžã«ã«ãã³é žã¡ãã«ããšãã«ãããªã
ãšã³âïŒïŒïŒâãžã«ã«ãã³é žã¡ãã«ããšãã«ãã
ãªããšã³âïŒïŒïŒâãžã«ã«ãã³é žã¡ãã«ããšã
ã«ãïŒâããšãã«é ¢é žã¡ãã«ããšãã«ãããã
ã«ãããã«ãïŒâããšãã«ã¢ã¯ãªã«é žã¡ãã«ããš
ãã«ãïŒâããšãã«ãã«ãã³é žã¡ãã«ããšãã«ã
ãã¢ãããã³âïŒâã«ã«ãã³é žã¡ãã«ããšãã«ã
ãã¢ãããã³âïŒâã«ã«ãã³é žã¡ãã«ããšãã«ã
ãã¢ãããã³âïŒïŒïŒâãžã«ã«ãã³é žã¡ãã«ããš
ãã«ãïŒâãªãã·âïŒâãã¢ãããã³ã«ã«ãã³é ž
ã¡ãã«ããšãã«ãïŒâãã¢ããããã«é ¢é žã¡ã
ã«ããšãã«ãïŒâãã¢ããããã«é ¢é žã¡ãã«ããš
ãã«ããã³ãŸããªããšã³âïŒâã«ã«ãã³é žã¡ã
ã«ããšãã«ããã³ãŸããªããšã³âïŒâã«ã«ãã³é ž
ã¡ãã«ããšãã«ããã³ãŸãªããšã³âïŒâã«ã«ãã³
é žã¡ãã«ããšãã«ãããšãããµãã€ã³âïŒâã«ã«
ãã³é žã¡ãã«ããšãã«ãããšãããµãã€ã³âïŒâ
ã«ã«ãã³é žã¡ãã«ããšãã«ãããšãããµãã€ã³â
ïŒâã«ã«ãã³é žã¡ãã«ããšãã«çãæããããã
ãã奜ãŸãããã®ãšããŠã¯ãããªããšã³âïŒâã«
ã«ãã³é žã¡ãã«ããšãã«ããããã«ããã³ãã
ã«ãããªããšã³âïŒâã«ã«ãã³é žã¡ãã«ããšã
ã«ãïŒâããšãã«é ¢é žã¡ãã«ããšãã«ãïŒâããš
ãã«ã¢ã¯ãªã«é žã¡ãã«ããšãã«ããã¢ãããã³â
ïŒâã«ã«ãã³é žã¡ãã«ããšãã«çãæããããã å«çªçŽ è€çŽ ç°ã«ã«ãã³é žãšã¹ãã«ãšããŠã¯ãã
ããŒã«é¡ã«ã«ãã³é žãšã¹ãã«ãã€ã³ããŒã«é¡ã«ã«
ãã³é žãšã¹ãã«ãã«ã«ããŸãŒã«é¡ã«ã«ãã³é žãšã¹
ãã«ããªããµãŸãŒã«é¡ã«ã«ãã³é žãšã¹ãã«ããã¢
ãŸãŒã«é¡ã«ã«ãã³é žãšã¹ãã«ãã€ãããŸãŒã«é¡ã«
ã«ãã³é žãšã¹ãã«ããã©ãŸãŒã«é¡ã«ã«ãã³é žãšã¹
ãã«ãããªãžã³é¡ã«ã«ãã³é žãšã¹ãã«ãããšãã³
ããªãžã³é¡ã«ã«ãã³é žãšã¹ãã«ãã¢ã³ãã©ãŸãªã³
é¡ã«ã«ãã³é žãšã¹ãã«ãããšãã³ãããªã³é¡ã«ã«
ãã³é žãšã¹ãã«ãããããªãžã³é¡ã«ã«ãã³é žãšã¹
ãã«ããªããµãžã³ã«ã«ãã³é žãšã¹ãã«ããã¢ãžã³
é¡ã«ã«ãã³é žãšã¹ãã«ãããªããžã³é¡ã«ã«ãã³é ž
ãšã¹ãã«ãããªããžã³é¡ã«ã«ãã³é žãšã¹ãã«ãã
ã©ãžã³é¡ã«ã«ãã³é žãšã¹ãã«ãæãããããã奜
ãŸãããã®ãšããŠããããŒã«âïŒâã«ã«ãã³é žã¡
ãã«ããšãã«ããããã«ãããã³ããã«ããããŒ
ã«âïŒâã«ã«ãã³é žã¡ãã«ããšãã«ããããã«ã
ãã³ããã«ãããªãžã³âïŒâã«ã«ãã³é žã¡ãã«ã
ãšãã«ããããã«ãããã«ããã³ã¢ãã«ãããªãž
ã³âïŒâã«ã«ãã³é žã¡ãã«ããšãã«ããããã«ã
ããã«ããã³ã¢ãã«ãããªãžã³âïŒâã«ã«ãã³é ž
ã¡ãã«ããšãã«ããããã«ãããã«ããã³ã¢ã
ã«ãããªãžã³ãâïŒïŒïŒâãžã«ã«ãã³é žã¡ãã«ã
ãšãã«ãããªãžã³âïŒïŒïŒâãžã«ã«ãã³é žã¡ã
ã«ããšãã«ãããªãžã³âïŒïŒïŒâãžã«ã«ãã³é žã¡
ãã«ããšãã«ãããªãžã³âïŒïŒïŒâãžã«ã«ãã³é ž
ã¡ãã«ããšãã«ããããªã³âïŒâã«ã«ãã³é žã¡ã
ã«ããšãã«ããžã¡ãã«ãããŒã«ã«ã«ãã³é žãšã
ã«ãâã¡ãã«ãããŒã«ã«ã«ãã³é žãšãã«ãïŒâ
ã¡ãã«ããªãžã³ã«ã«ãã³é žãšãã«ããããªãžã³â
ïŒâã«ã«ãã³é žãšãã«ããããªãžã³âïŒâã«ã«ã
ã³é žãšãã«ããããªãžã³âïŒâã«ã«ãã³é žãšãã«
çãæããããã æå(1)ïŒ(2)ããã³(3)ã®åå¿ã«ã€ããŠèª¬æãã
ãšã(i)ãš(ii)ããã³(iii)ã®åå¿ã«ããåºäœæåãçæ
ãããã(i)ãš(ii)ããã³(iii)ã®åå¿çµäºåŸããã®åå¿
ç©ãšãæå(2)ããã³æå(3)ãå ããŠåå¿ãããã
ãšã奜ãŸããã æå(2)ã®äœ¿çšéã¯ã¢ã«æ¯ïŒâŠMgïŒTiâŠ500ã
奜ãŸããã¯10âŠMgïŒTiâŠ100ã®ç¯å²ã§è¡ããå
å¿æº¶æ¶²äžã®Tiã®æ¿åºŠã4molïŒä»¥äžã§è¡ãããš
ãæãŸãããåå¿æž©åºŠã¯ç¹ã«å¶éã¯ãªãããåå¿
é²è¡äžå¥œãŸããã¯50ã150âã®ç¯å²ã§å®æœãããã æå(3)ã®äœ¿çšéã¯æå(2)ãšæå(3)ã®æ¯çãããª
ãã¡ã¢ã«æ¯æå(2)ïŒæå(3)ã0.3以äžãç¹ç¹ã«0.4
以äžã奜ãŸãããåå¿æº¶æ¶²äžã®è€çŽ ç°ã«ã«ãã³é ž
ãšã¹ãã«ã®æ¿åºŠã¯5molïŒä»¥äžã奜ãŸãããå
å¿æž©åºŠã«ã€ããŠã¯40ã160âã®ç¯å²ã§å®æœãããã
ç¹ã«å¥œãŸããã¯50ã150âã®ç¯å²ã§å®æœãããã æå(1)ïŒ(2)ïŒ(3)ãåå¿ãããæ¹æ³ã«ã€ããŠã¯ã
æå(1)ã«ãã¿ã³ååç©(2)ãæ·»å ããåãåŸããŸã
ã¯åæã«è€çŽ ç°ã«ã«ãã³é žãšã¹ãã«(3)ãæ·»å ãã
ããšãã§ããããæå(3)ã¯æå(1)ã«ãã¿ã³ååç©
(2)ãæ·»å ããåãªããåæã«æ·»å ããæ¹æ³ã奜ãŸ
ããã ã(B)ãã®ææ©ã¢ã«ãããŠã ååç©ãšããŠã¯ãã
ãªã¡ãã«ã¢ã«ãããŠã ãããªãšãã«ã¢ã«ãããŠ
ã ãããªâïœâãããã«ã¢ã«ãããŠã ãããªã€ãœ
ãããã«ã¢ã«ãããŠã ãããªâïœâããã«ã¢ã«ã
ããŠã ãããªâïœâããã«ã¢ã«ãããŠã ãããªâ
ïœâããã·ã«ã¢ã«ãããŠã ãããªâïœâãªã¯ãã«
ã¢ã«ãããŠã ãããªâïœâãã·ã«ã¢ã«ãããŠã ã
ããªâïœâããã·ã«ã¢ã«ãããŠã ãããªãããµã
ã·ã«ã¢ã«ãããŠã ãã¢ã«ãããŠã ã€ãœãã¬ãã«ç
ã®ããªã¢ã«ãã«ã¢ã«ãããŠã ãæãããããžãšã
ã«ã¢ã«ãããŠã ãã€ãã©ã€ãããžã€ãœããã«ã¢ã«
ãããŠã ãã€ãã©ã€ããªã©ã®ãžã¢ã«ãã«ã¢ã«ãã
ãŠã ãã€ãã©ã€ãã䜿çšã§ããïŒC2H5ïŒ2Alââ
AlïŒC2H5ïŒ2ã
ããã 次ã«ãïŒïŒã«ãããŠççŽ æ°ïŒãŸãã¯ïŒã®ã¢ã«
ãã«åºãšããŠã¯ãšãã«åºããããã«åºãæãã
ãããšãã«åºã¯ç¹ã«å¥œãŸããããŸãççŽ æ°ïŒä»¥äž
ã®ã¢ã«ãã«åºãšããŠã¯ããã«åºãã¢ãã«åºããã
ã·ã«åºããªã¯ãã«åºçãæããããããã«åºãã
ãã·ã«åºã¯ç¹ã«å¥œãŸãããïŒïŒã«ãããŠççŽ å
åæ°ïŒä»¥äžã®çåæ°ŽçŽ åºãšããŠã¯ãããã·ã«åºã
ãªã¯ãã«åºããã·ã«åºãããšãã«åºçãæãã
ããã¢ã«ãã«åºã§ããæ¹ã奜ãŸãããããã·ã«åº
ã¯ç¹ã«å¥œãŸããã æ¬çºæã«çšããããææ©ãã°ãã·ãŠã ååç©
ã¯ãçåæ°ŽçŽ åªäœã«å¯æº¶ã§ããããšãéèŠã§ã
ããã¢ã«ãã«åºã®ççŽ ååæ°ãå¢ããšçåæ°ŽçŽ åª
äœã«æº¶ãæããªããã溶液ã®ç²æ§ãé«ããªãåŸå
ã§ãããå¿ èŠä»¥äžã«é·éã®ã¢ã«ãã«åºãçšããã
ãšã¯åæ±ãäžå¥œãŸãããªãã ãªããäžèšææ©ãã°ãã·ãŠã ååç©ã¯çåæ°ŽçŽ
溶液ãšããŠçšãããããã該溶液äžã«åŸ®éã®ãšãŒ
ãã«ããšã¹ãã«ãã¢ãã³çã®ã³ã³ãã¬ãã¯ã¹åå€
ããããã«å«æããããããã¯æ®åããŠããå Žå
ãããã€ãããªãçšããããšãã§ããã åèšäžè¬åŒäžãαïŒïŒãβïŒïŒãïœïŒïŒãïœïŒ
ïŒãªãææ©ãã°ãã·ãŠã ãã©ã€ãã«ã€ããŠèª¬æã
ãã ãã®ååç©ã¯ãããããã°ãªãã€ãŒååç©ã§ã
ããäžè¬ã«ãã°ãã·ãŠã ããšãŒãã«æº¶æ¶²äžã®ææ©
ããã²ã³åç©ã«åå¿ãããããšã«ãã€ãŠåæãã
ãããšãŒãã«ã®äžååšäžã«ãããŠãçåæ°ŽçŽ åªè³ª
äžã§ãã®åå¿ãè¡ãããããšãç¥ãããŠãããã©
ã¡ãã䜿çšããããšãã§ããã ãããã®äŸãšããŠã¯ãããšãã°ãã¡ãã«ãã°ã
ã·ãŠã ã¯ããªããã¡ãã«ãã°ãã·ãŠã ããããã
ã¡ãã«ãã°ãã·ãŠã ã¢ã€ãªãã€ãããšãã«ãã°ã
ã·ãŠã ã¯ããªãããšãã«ãã°ãã·ãŠã ããããã
ãšãã«ãã°ãã·ãŠã ã¢ã€ãªãã€ããïœâãŸãã¯
isoâãããã«ãã°ãã·ãŠã ã¯ããªããïœâãŸã
ã¯isoâãããã«ãã°ãã·ãŠã ãããããïœâãŸ
ãã¯isoâãããã«ãã°ãã·ãŠã ã¢ã€ãªãã€ãã
ïœâããã«ãã°ãã·ãŠã ã¯ããªããïœâããã«ã
ã°ãã·ãŠã ãããããïœâããã«ãã°ãã·ãŠã ã¢
ã€ãªãã€ããisoâãsecâãããã¯tertâããã«
ãã°ãã·ãŠã ã¯ããªããisoâãsecâãããã¯
tertâããã«ãã°ãã·ãŠã ãããããisoâãsec
âãããã¯tertâããã«ãã°ãã·ãŠã ã¢ã€ãªãã€
ããïœâã¢ãã«ãã°ãã·ãŠã ã¯ããªããïœâã¢ã
ã«ãã°ãã·ãŠã ãããããããã·ã«ãã°ãã·ãŠã
ã¯ããªããããã·ã«ãã°ãã·ãŠã ããããããªã¯
ãã«ãã°ãã·ãŠã ã¯ããªããããšãã«ãã°ãã·ãŠ
ã ã¯ããªããããšãã«ãã°ãã·ãŠã ããããçã®
ååç©ããªãã³ã«ãããã®ãšãŒãã«é¯åäœãæã
ãããšãã§ããããããã®ãšãŒãã«ååç©ãšããŠ
ã¯ãããšãã°ããžã¡ãã«ãšãŒãã«ããžãšãã«ãšãŒ
ãã«ããžã€ãœãããã«ãšãŒãã«ããžããã«ãšãŒã
ã«ããžã¢ãªã«ãšãŒãã«ãããã©ããããã©ã³ããž
ãªããµã³ãã¢ããœãŒã«çã®åçš®ã®ãšãŒãã«ååç©
ãæããããšãã§ããã 次ã«ã(a)ææ©ãã°ãã·ãŠã æåãš(b)é»åäŸäžå
åç©ã®åå¿ã«ã€ããŠèª¬æããã (a)ææ©ãã°ãã·ãŠã æåãšããŠã¯ãåèšã®åæ
åãçšããããšãã§ãããã液çžã§(b)é»åäŸäžå
åç©ãšåå¿ãããã®ã奜ãŸãããçåæ°ŽçŽ ç³»ãã
ãã¯ãšãŒãã«ç³»æº¶åªçã«å¯æº¶ã®ææ©ãã°ãã·ãŠã
æåã奜ãŸããçµæãäžããã (a)ææ©ãã°ãã·ãŠã æåãšåå¿ããã(b)é»åäŸ
äžååç©ã¯æ¬¡ã®ããšããã®ã§ããã äžè¬åŒRORâ²ã§è¡šãããããšãŒãã«ïŒåŒäžã
ããã³Râ²ã¯èèªæãè³éŠæãŸãã¯èç°åŒçåæ°Ž
çŽ åºã§ãããããšãã°ãã¡ãã«ããšãã«ãããã
ã«ãããã«ãã¢ãã«ãããã·ã«ããã·ã«ããªã¯ã
ã«ãããã·ã«ãã·ã¯ãããã·ã«ãããšãã«ããã³
ãžã«çã§ãããïŒ äžè¬åŒRSRâ²ã§è¡šããããããªãšãŒãã«ïŒåŒäžã
ããã³Râ²ã¯èèªæãè³éŠæãŸãã¯èç°åŒçå
æ°ŽçŽ ã§ãããããšãã°ãã¡ãã«ããšãã«ãããã
ã«ãããã«ãã¢ãã«ãããã·ã«ãã·ã¯ãããã·
ã«ãããšãã«çã§ãããïŒ äžè¬åŒRCORâ²ã§è¡šããããã±ãã³ïŒåŒäžã
ããã³Râ²ã¯èèªæãè³éŠæãŸãã¯èç°åŒçåæ°Ž
çŽ åºã§ãããããšãã°ãã¡ãã«ããšãã«ãããã
ã«ãããã«ãã¢ãã«ãããã·ã«ãã·ã¯ãããã·
ã«ãããšãã«çã§ãããç¹ã«ãžã¡ãã«ã±ãã³ããž
ãšãã«ã±ãã³çã奜ãŸãããïŒ èèªæãè³éŠæããã³èç°åŒã¢ã«ããããçå
æ°ŽçŽ ç³»ã«ã«ãã³é žãŸãã¯ãã®èªå°äœãããå ·äœç
ã«ã¯çåæ°ŽçŽ ç³»ã«ã«ãã³é žãçåæ°ŽçŽ ç³»ã«ã«ãã³
é žç¡æ°Žç©ãçåæ°ŽçŽ ç³»ã«ã«ãã³é žãšã¹ãã«ãçå
æ°ŽçŽ ç³»ã«ã«ãã³é žããã²ã³åç©ãçåæ°ŽçŽ ç³»ã«ã«
ãã³é žã¢ããã§ããã 以äžãããã«ã€ããããã«å ·äœçã«èšè¿°ããã çåæ°ŽçŽ ç³»ã«ã«ãã³é žãšããŠã¯ãããšãã°ãã®
é žãé ¢é žãããããªã³é žãé ªé žãåèé žãã·ãŠãŠ
é žãããã³é žãã³ãã¯é žããã¬ã€ã³é žãã¢ã¯ãªã«
é žãå®æ¯éŠé žããã«ã€ã«é žããã¬ãã¿ã«é žçãæ
ãããããã«ã«ãã³é žç¡æ°Žç©ãšããŠã¯ãããšã
ã°ãç¡æ°Žé ¢é žãç¡æ°Žããããªã³é žãç¡æ°Žé ªé žãç¡
æ°Žã³ãã¯é žãç¡æ°Žãã¬ã€ã³é žãç¡æ°Žå®æ¯éŠé žãç¡
æ°Žãã¿ã«é žçãæããããã çåæ°ŽçŽ ç³»ã«ã«ãã³é žãšã¹ãã«ãšããŠã¯ãã®é ž
ã¡ãã«ããã³ãšãã«ãé ¢é žã¡ãã«ããšãã«ããã
ãã«ãããããªã³é žã¡ãã«ããšãã«ããããã«ã
ããã«ãé ªé žãšãã«ãåèé žãšãã«ãã«ããã³é ž
ãšãã«ãïœâããã¿ã³é žãšãã«ãã·ãŠãŠé žãžãã
ã«ãã³ãã¯é žãšãã«ãããã³é žãšãã«ããã¬ã€ã³
é žãžããã«ãã¢ã¯ãªã«é žã¡ãã«ãã¢ã¯ãªã«é žãšã
ã«ãã¡ã¿ã¯ãªã«é žã¡ãã«ãå®æ¯éŠé žã¡ãã«ããšã
ã«ããããã«ãããã«ããã«ã€ã«é žã¡ãã«ããšã
ã«ããããã«ãããã«ãã¢ãã«ãïœâãšãã«å®æ¯
éŠé žã¡ãã«ããã³ãšãã«ãã¢ãã¹é žã¡ãã«ããšã
ã«ããããã«ããã³ããã«ãïœâãšããã·å®æ¯éŠ
é žã¡ãã«ããšãã«ãæããããã çåæ°ŽçŽ ç³»ã«ã«ãã³é žããã²ã³åç©ãšããŠã¯ã
é žå¡©åç©ã奜ãŸãããå¡©åã¢ã»ãã«ãå¡©åããã
ãªãã«ãå¡©åãããªã«ãå¡©åã¹ã¯ã·ãã«ãå¡©åã
ã³ãŸã€ã«ãå¡©åãã«ã€ã«ãæããããã çåæ°ŽçŽ ç³»ã«ã«ãã³é žã¢ãããšããŠã¯ããžã¡ã
ã«ãã«ã ã¢ããããžã¡ãã«ã¢ã»ãã¢ããããžã¡ã
ã«ããããªã³ã¢ããçãæããããã ã¢ã«ã³ãŒã«ãšããŠã¯ãã¡ãã«ã¢ã«ã³ãŒã«ããšã
ã«ã¢ã«ã³ãŒã«ããããã«ã¢ã«ã³ãŒã«ãããã«ã¢ã«
ã³ãŒã«ãã¢ãã«ã¢ã«ã³ãŒã«ãããã·ã«ã¢ã«ã³ãŒ
ã«ãããšããŒã«ãã¯ã¬ãŸãŒã«çãæãããããã
secâãããã«ã¢ã«ã³ãŒã«ãsecâããã«ã¢ã«ã³ãŒ
ã«ãtertâããã«ã¢ã«ã³ãŒã«ãsecâã¢ãã«ã¢ã«
ã³ãŒã«ãtertâã¢ãã«ã¢ã«ã³ãŒã«ãsecâããã·
ã«ã¢ã«ã³ãŒã«ãããšããŒã«ãïœïŒïœãïŒïœâã¯ã¬
ãŸãŒã«çã®äºçŽãäžçŽãªããè³éŠæã¢ã«ã³ãŒã«ã
奜ãŸããã ããªã¢ã«ã³ãŒã«ãšããŠã¯ãã¡ãã«ã¡ã«ã«ãã¿
ã³ããšãã«ã¡ã«ã«ãã¿ã³ããããã«ã¡ã«ã«ãã¿
ã³ãããã«ã¡ã«ã«ãã¿ã³ãã¢ãã«ã¡ã«ã«ãã¿ã³ã
ããã·ã«ã¡ã«ã«ãã¿ã³ãããšãã«ã¡ã«ã«ãã¿ã³ç
ãæããããããäºçŽãäžçŽãªããè³éŠæããªã¢
ã«ã³ãŒã«ã奜ãŸããã ã¢ãã³ãšããŠã¯ãèèªæãèç°åŒãªããè³éŠæ
ã¢ãã³ãæããããããäºçŽãªããäžçŽã¢ãã³ã
ããšãã°ãããªã¢ã«ãã«ã¢ãã³ãããªããšãã«ã¢
ãã³ãããªãžã³çã奜ãŸããçµæãäžããã 次ã«ã(a)ææ©ãã°ãã·ãŠã æåãš(b)é»åäŸäžäœ
ååç©ã®åå¿ã«ã€ããŠã¯ãåå¿ãäžæŽ»æ§åå¿åª
äœãããšãã°ããããµã³ãããã¿ã³ã®ããšãèèª
æçåæ°ŽçŽ ããã³ãŒã³ããã«ãšã³ããã·ã¬ã³çã®
è³éŠæçåæ°ŽçŽ ãã·ã¯ããããµã³ãã¡ãã«ã·ã¯ã
ãããµã³çã®èç°åŒçåæ°ŽçŽ ãããã¯ãšãŒãã«ç³»
溶åªãŸãã¯ãããã®æ··å溶åªäžã§è¡ãããšãã§ã
ããåå¿é äºã«ã€ããŠã¯ãææ©ãã°ãã·ãŠã æå
äžã«é»åäŸäžååç©ãå ããŠããæ¹æ³ïŒïŒãé»
åäŸäžååç©äžã«ææ©ãã°ãã·ãŠã æåãå ããŠ
ããæ¹æ³ïŒïŒãäž¡è ãåæã«å ããŠããæ¹æ³
ïŒïŒãçšããããšãã§ããã ææ©ãã°ãã·ãŠã æåãšé»åäŸäžååç©ã®åå¿
æ¯çã«ã€ããŠã¯ãææ©ãã°ãã·ãŠã æåïŒã¢ã«ã«
ã€ããŠãé»åäŸäžååç©ïŒã¢ã«ä»¥äžã奜ãŸããã¯
0.01ã0.8ã¢ã«ã§ãããç¹ã«å¥œãŸããã¯0.05ã0.5
ã¢ã«ã§ããã 次ã«ã(ii)äžè¬åŒHaSiClbR10 4-(a+b)ïŒåŒäžãïœïŒïœ
ïŒ
R10ã¯åè¿°ã®æå³ã§ããïŒã§ç€ºãããSiâçµå
å«æã¯ãã«ã·ã©ã³ååç©ã«ã€ããŠèª¬æããã äžèšåŒã«ãããŠR10ã§è¡šããããçåæ°ŽçŽ åº
ã¯ãèèªæçåæ°ŽçŽ åºãèç°åŒçåæ°ŽçŽ åºãè³éŠ
æçåæ°ŽçŽ åºã§ãããããšãã°ãã¡ãã«ããšã
ã«ããããã«ãããã«ãã¢ãã«ãããã·ã«ããã·
ã«ãã·ã¯ãããã·ã«ãããšãã«åºçãæãããã
奜ãŸããã¯ççŽ æ°ïŒã10ã®ã¢ã«ãã«åºã§ãããã¡
ãã«ããšãã«ããããã«çã®äœçŽã¢ã«ãã«åºãç¹
ã«å¥œãŸãããïœã®å€ã¯ãïœïŒïŒãïœïŒïœâŠïŒãïŒ
ïŒïœâŠïŒã§ããã0.5âŠïœâŠ1.5ã奜ãŸããã ãããã®ååç©ãšããŠã¯ãHSiCl3ïŒ
HSiCl2CH3ïŒHSiCl2C2H5ïŒHSiCl2nâC3H7ïŒ
HSiCl2isoâC3H7ïŒHSiCl2nâC4H9ïŒ
HSiCl2C6H5ïŒHSiCl2ïŒïŒâClâC6H4ïŒïŒ
HSiCl2CHïŒCH2ïŒHSiCl2CH2C6H5ïŒHSiCl2ïŒïŒ
âC10H7ïŒïŒHSiCl2CH2CHïŒCH2ïŒH2SiClCH3ïŒ
H2SiClC2H5ïŒHSiClïŒCH3ïŒ2ïŒHSiClCH3ïŒisoâ
C3H7ïŒïŒHSiClCH3ïŒC6H5ïŒïŒHSiClïŒC2H5ïŒ2ïŒ
HSiClïŒC6H5ïŒ2çãæãããããããã®ååç©ã
ãã³ãããã®ååç©ããéžã°ããååç©ãšã®æ··å
ç©ãããªãã¯ãã«ã·ã©ã³ååç©ã䜿çšãããããª
ã¯ãã«ã·ã©ã³ãã¢ãã¡ãã«ãžã¯ãã«ã·ã©ã³ããžã¡
ãã«ã¯ãã«ã·ã©ã³ããšãã«ãžã¯ãã«ã·ã©ã³çã奜
ãŸãããããªã¯ãã«ã·ã©ã³ãã¢ãã¡ãã«ãžã¯ãã«
ã·ã©ã³ãç¹ã«å¥œãŸããã (1)â(iii)ã®ç¡æ©é žåç©ãšããŠã¯ãåšæåŸè¡šç¬¬æ
ãªãã第æå çŽ ã®é žåç©ã§ã殺çŒãã·ãªã«ãã¢
ã«ããããã°ãã·ã¢ãããã¯ãããã®è€åäœãæ··
åç©ãæãããããã·ãªã«ãªããã·ãªã«ã»ã¢ã«ã
ãã奜ãŸãããç¹ã«ã·ãªã«ã奜ãŸããããããŠã
ã·ãªã«ã®äžã§ãB.E.T.æ³ã§æž¬å®ãããæ¯è¡šé¢ç©
ã200ã600m2ïŒïœãæ¯å容ç©ãïŒmlïŒïœãå¹³åå
åŸã50ã300â«ã®ãã®ã¯ããã«å¥œãŸããçµæãäž
ãããç¡æ©é žåç©ã¯ãã¢ã«ãŽã³ãçªçŽ ã¬ã¹çã®æ°
æµäžãããã¯ç空äžã«ãããŠãå ç±ä¹Ÿç¥ããŠçšã
ãããšã奜ãŸããã 以äžãææ©ãã°ãã·ãŠã æå(i)ãã¯ãã«ã·ã©ã³
ååç©(ii)ãããã³ç¡æ©é žåç©(iii)ã®åå¿ã«ã€ããŠèª¬
æãããåå¿æ¹æ³ã«ã€ããŠã¯ãïŒçš®æåãåæã«
åå¿åž¯ã«å°å ¥ãã€ã€åå¿ãããåææ·»å ã®æ¹æ³
ïŒæ¹æ³âã€ïŒãææ©ãã°ãã·ãŠã æåãšç¡æ©é žåç©ã
åå¿ãããåŸãã¯ãã«ã·ã©ã³æåãšåå¿ãããæ¹
æ³ïŒæ¹æ³âãïŒãã¯ãã«ã·ã©ã³æåãšç¡æ©é žåç©ã
åå¿ãããåŸãææ©ãã°ãã·ãŠã æåãšåå¿ãã
ãæ¹æ³ïŒæ¹æ³âãïŒãææ©ãã°ãã·ãŠã æåãšã¯ã
ã«ã·ã©ã³æåãåå¿ãããåŸãç¡æ©é žåç©ãšåå¿
ãããæ¹æ³ïŒæ¹æ³âãïŒçãæããããããæ¹æ³
âã€ïŒâãïŒâãã奜ãŸãããç¹ã«æ¹æ³âãã奜ãŸãã
ã ææ©ãã°ãã·ãŠã æåãã¯ãã«ã·ã©ã³ããã³ç¡
æ©é žåç©ã®åå¿ã¯ãäžæŽ»æ§åå¿åªäœãããšãã°ã
ãããµã³ãããã¿ã³ã®åŠãèèªæçåæ°ŽçŽ ããã³
ãŒã³ããã«ãšã³ããã·ã¬ã³ã®ããšãè³éŠæçåæ°Ž
çŽ ãã·ã¯ããããµã³ãã¡ãã«ã·ã¯ããããµã³ã®åŠ
ãèç°åŒçåæ°ŽçŽ ããããã¯ãšãŒãã«ãããã©ã
ãããã©ã³çã®ãšãŒãã«ç³»åªäœããããã¯ããã
ã®æ··ååªäœäžã§è¡ãããšãã§ããã觊åªæ§èœäžã
èèªæçåæ°ŽçŽ åªäœã奜ãŸãããåå¿æž©åºŠã¯20ã
150âã§å®æœãããããã¯ãã«ã·ã©ã³ãåå¿ãã
ãå Žåã¯ãã¯ãã«ã·ã©ã³ã®æ²žç¹ä»¥äžãããã¯40â
以äžã§å®æœãããã åå¿æ¯çã«ã€ããŠã¯ãææ©ãã°ãã·ãŠã æåïŒ
ã¢ã«ã«å¯Ÿããã¯ãã«ã·ã©ã³0.01ã100ã¢ã«ã奜ãŸ
ããã¯0.1ã10ã¢ã«ãç¹ã«å¥œãŸããã¯0.2ãïŒã¢ã«
ã®ç¯å²ã§ãããç¡æ©é žåç©10ïœã10Kgã奜ãŸãã
ã¯100ïœãïŒKgãç¹ã«å¥œãŸããã¯200ïœãïŒKgã®ç¯
å²ã§ããã æ¬çºæã«ãããŠã¯ãææ©ãã°ãã·ãŠã æåãšã¯
ãã«ã·ã©ã³ååç©ããã³ç¡æ©é žåç©ãåå¿ãããŠ
åŸãããåå¿æ··åç©ã«ãéãæŽæ»ãªã©ã®æäœã
å ããããšãªãããã¿ã³ååç©ãè€çŽ ç°ã«ã«ãã³
é žãšã¹ãã«ãããã¯çåæ°ŽçŽ ã«ã«ãã³é žãšã¹ãã«
ãå ããããšã«ãããããæåãåŸãããšãã§
ããã 次ã«ã(2)äžè¬åŒTiïŒOR11ïŒoZ4-oã§ç€ºããããã¿
ã³ååç©ã«ã€ããŠèª¬æããïŒåŒäžãR11ã¯ççŽ æ°
ïŒã20ã®çåæ°ŽçŽ åºããã¯ããã²ã³ååããïœ
ã¯ïŒâŠïœâŠïŒãªãæ°ãè¡šããïŒã äžèšåŒã«ãããŠR11ã§è¡šããããçåæ°ŽçŽ åº
ã¯ãèèªæçåæ°ŽçŽ åºãèç°åŒçåæ°ŽçŽ åºãè³éŠ
æçåæ°ŽçŽ åºã§ãããããšãã°ãã¡ãã«ããšã
ã«ããããã«ãããã«ãã¢ãã«ãããã·ã«ããã
ãã«ããªã¯ãã«ãããã«ããã·ã«ãã»ãã«ãã¹ã
ã¢ãªã«ãïŒâãšãã«ããã·ã«ãã·ã¯ããã³ãã«ã
ã·ã¯ãããã·ã«ãããšãã«ãã¯ã¬ãžã«ããããã«
çãæããããšãã§ããã ããã²ã³ååãšããŠã¯ãå¡©çŽ ãèçŽ ãæ²çŽ ãæ
ãããããïŒïŒïœâŠïŒã§ãããã¿ã³ã®ããã²ã³å
ç©ãšããŠã¯ãåå¡©åãã¿ã³ãåèåãã¿ã³ãåãš
ãŠåãã¿ã³ããšããã·ãã¿ã³ããªã¯ããªãããã
ããã·ãã¿ã³ããªã¯ããªãããããã·ãã¿ã³ããª
ã¯ããªãããžãããã·ãã¿ã³ãžã¯ããªããããªã
ããã·ãã¿ã³ã¢ãã¯ããªãçããã¿ã³ã®ããã²ã³
åç©ãã¢ã«ã³ãã·ããã²ã³åç©ã®åç¬ãŸãã¯æ··å
ç©ãçšããããã奜ãŸããååç©ã¯ããã²ã³ãïŒ
å以äžå«ãååç©ã§ãããç¹ã«å¥œãŸããã¯åå¡©å
ãã¿ã³ã§ããã ïœïŒïŒã§ããååç©ãšããŠã¯ãTiïŒOCH3ïŒ4ïŒ
TiïŒOC2H5ïŒ4ïŒTiïŒOnâC3H7ïŒ4ïŒTiïŒOisoâ
C3H7ïŒ4ïŒTiïŒOnâC4H9ïŒ4ïŒTiïŒOsecâC4H9ïŒ4ïŒ
TiïŒOisoâC4H9ïŒ4ïŒTiïŒOtertâC4H9ïŒ4ïŒTiïŒOn
âC5H11ïŒ4ïŒTiïŒOtertâC5H11ïŒ4ïŒTiïŒOnâ
C6H13ïŒ4ãTiïŒOnâC7H15ïŒ4ïŒTiïŒOnâC8H17ïŒ4ïŒ
TiïŒOisoâC5H11ïŒ4ïŒTiïŒOnâC9H19ïŒ4ïŒTiïŒOnâ
C10H21ïŒ4ïŒTiïŒOnâC16H33ïŒ4ïŒTiïŒOnâ
C18H37ïŒ4ïŒTiïŒOC8H17ïŒ4ãTitanium2ethyl
hexoideããTiïŒOC6H14ïŒ4ïŒTiïŒOC6H5ïŒ4ïŒTi
ïŒOC6H4CH3ïŒ4ïŒTiïŒOC10H7ïŒ4ãçãæãããã
ãããã®ååç©ããã³ãããã®ååç©ããéžã°ã
ãæ··åç©ãããªããã¿ã³ååç©ã䜿çšãããã (3)ã®å«ç¡«é»è€çŽ ç°ã«ã«ãã³é žãšã¹ãã«ãšããŠ
ã¯ãããªããšã³é¡ã«ã«ãã³é žãšã¹ãã«ããã¢ãã
ãã³é¡ã«ã«ãã³é žãšã¹ãã«ãã€ãœãã¢ãããã³é¡
ã«ã«ãã³é žãšã¹ãã«ããã³ãŸããªããšã³é¡ã«ã«ã
ã³é žãšã¹ãã«ãããšãããµãã€ã³é¡ã«ã«ãã³é žãš
ã¹ãã«ããã³ãŸãã¢ã³é¡ã«ã«ãã³é žãšã¹ãã«ãã
ã¢ããµã³ãã³é¡ã«ã«ãã³é žãšã¹ãã«ãããªã€ã³ã
ãã·ã«é¡ã«ã«ãã³é žãšã¹ãã«çãæãããããã
å ·äœçã«æãããšãããªããšã³âïŒâã«ã«ãã³é ž
ã¡ãã«ããšãã«ããããã«ãããã«ããã³ã¢ã
ã«ãããªããšã³âïŒâã«ã«ãã³é žã¡ãã«ããšã
ã«ããããã«ãããã«ããã³ã¢ãã«ãããªããšã³
âïŒïŒïŒâãžã«ã«ãã³é žã¡ãã«ããšãã«ãããªã
ãšã³âïŒïŒïŒâãžã«ã«ãã³é žã¡ãã«ããšãã«ãã
ãªããšã³âïŒïŒïŒâãžã«ã«ãã³é žã¡ãã«ããšã
ã«ãïŒâããšãã«é ¢é žã¡ãã«ããšãã«ãããã
ã«ãããã«ãïŒâããšãã«ã¢ã¯ãªã«é žã¡ãã«ããš
ãã«ãïŒâããšãã«ãã«ãã³é žã¡ãã«ããšãã«ã
ãã¢ãããã³âïŒâã«ã«ãã³é žã¡ãã«ããšãã«ã
ãã¢ãããã³âïŒâã«ã«ãã³é žã¡ãã«ããšãã«ã
ãã¢ãããã³âïŒïŒïŒâãžã«ã«ãã³é žã¡ãã«ããš
ãã«ãïŒâãªãã·âïŒâãã¢ãããã³ã«ã«ãã³é ž
ã¡ãã«ããšãã«ãïŒâãã¢ããããã«é ¢é žã¡ã
ã«ããšãã«ãïŒâãã¢ããããã«é ¢é žã¡ãã«ããš
ãã«ããã³ãŸããªããšã³âïŒâã«ã«ãã³é žã¡ã
ã«ããšãã«ããã³ãŸããªããšã³âïŒâã«ã«ãã³é ž
ã¡ãã«ããšãã«ããã³ãŸãªããšã³âïŒâã«ã«ãã³
é žã¡ãã«ããšãã«ãããšãããµãã€ã³âïŒâã«ã«
ãã³é žã¡ãã«ããšãã«ãããšãããµãã€ã³âïŒâ
ã«ã«ãã³é žã¡ãã«ããšãã«ãããšãããµãã€ã³â
ïŒâã«ã«ãã³é žã¡ãã«ããšãã«çãæããããã
ãã奜ãŸãããã®ãšããŠã¯ãããªããšã³âïŒâã«
ã«ãã³é žã¡ãã«ããšãã«ããããã«ããã³ãã
ã«ãããªããšã³âïŒâã«ã«ãã³é žã¡ãã«ããšã
ã«ãïŒâããšãã«é ¢é žã¡ãã«ããšãã«ãïŒâããš
ãã«ã¢ã¯ãªã«é žã¡ãã«ããšãã«ããã¢ãããã³â
ïŒâã«ã«ãã³é žã¡ãã«ããšãã«çãæããããã å«çªçŽ è€çŽ ç°ã«ã«ãã³é žãšã¹ãã«ãšããŠã¯ãã
ããŒã«é¡ã«ã«ãã³é žãšã¹ãã«ãã€ã³ããŒã«é¡ã«ã«
ãã³é žãšã¹ãã«ãã«ã«ããŸãŒã«é¡ã«ã«ãã³é žãšã¹
ãã«ããªããµãŸãŒã«é¡ã«ã«ãã³é žãšã¹ãã«ããã¢
ãŸãŒã«é¡ã«ã«ãã³é žãšã¹ãã«ãã€ãããŸãŒã«é¡ã«
ã«ãã³é žãšã¹ãã«ããã©ãŸãŒã«é¡ã«ã«ãã³é žãšã¹
ãã«ãããªãžã³é¡ã«ã«ãã³é žãšã¹ãã«ãããšãã³
ããªãžã³é¡ã«ã«ãã³é žãšã¹ãã«ãã¢ã³ãã©ãŸãªã³
é¡ã«ã«ãã³é žãšã¹ãã«ãããšãã³ãããªã³é¡ã«ã«
ãã³é žãšã¹ãã«ãããããªãžã³é¡ã«ã«ãã³é žãšã¹
ãã«ããªããµãžã³ã«ã«ãã³é žãšã¹ãã«ããã¢ãžã³
é¡ã«ã«ãã³é žãšã¹ãã«ãããªããžã³é¡ã«ã«ãã³é ž
ãšã¹ãã«ãããªããžã³é¡ã«ã«ãã³é žãšã¹ãã«ãã
ã©ãžã³é¡ã«ã«ãã³é žãšã¹ãã«ãæãããããã奜
ãŸãããã®ãšããŠããããŒã«âïŒâã«ã«ãã³é žã¡
ãã«ããšãã«ããããã«ãããã³ããã«ããããŒ
ã«âïŒâã«ã«ãã³é žã¡ãã«ããšãã«ããããã«ã
ãã³ããã«ãããªãžã³âïŒâã«ã«ãã³é žã¡ãã«ã
ãšãã«ããããã«ãããã«ããã³ã¢ãã«ãããªãž
ã³âïŒâã«ã«ãã³é žã¡ãã«ããšãã«ããããã«ã
ããã«ããã³ã¢ãã«ãããªãžã³âïŒâã«ã«ãã³é ž
ã¡ãã«ããšãã«ããããã«ãããã«ããã³ã¢ã
ã«ãããªãžã³ãâïŒïŒïŒâãžã«ã«ãã³é žã¡ãã«ã
ãšãã«ãããªãžã³âïŒïŒïŒâãžã«ã«ãã³é žã¡ã
ã«ããšãã«ãããªãžã³âïŒïŒïŒâãžã«ã«ãã³é žã¡
ãã«ããšãã«ãããªãžã³âïŒïŒïŒâãžã«ã«ãã³é ž
ã¡ãã«ããšãã«ããããªã³âïŒâã«ã«ãã³é žã¡ã
ã«ããšãã«ããžã¡ãã«ãããŒã«ã«ã«ãã³é žãšã
ã«ãâã¡ãã«ãããŒã«ã«ã«ãã³é žãšãã«ãïŒâ
ã¡ãã«ããªãžã³ã«ã«ãã³é žãšãã«ããããªãžã³â
ïŒâã«ã«ãã³é žãšãã«ããããªãžã³âïŒâã«ã«ã
ã³é žãšãã«ããããªãžã³âïŒâã«ã«ãã³é žãšãã«
çãæããããã æå(1)ïŒ(2)ããã³(3)ã®åå¿ã«ã€ããŠèª¬æãã
ãšã(i)ãš(ii)ããã³(iii)ã®åå¿ã«ããåºäœæåãçæ
ãããã(i)ãš(ii)ããã³(iii)ã®åå¿çµäºåŸããã®åå¿
ç©ãšãæå(2)ããã³æå(3)ãå ããŠåå¿ãããã
ãšã奜ãŸããã æå(2)ã®äœ¿çšéã¯ã¢ã«æ¯ïŒâŠMgïŒTiâŠ500ã
奜ãŸããã¯10âŠMgïŒTiâŠ100ã®ç¯å²ã§è¡ããå
å¿æº¶æ¶²äžã®Tiã®æ¿åºŠã4molïŒä»¥äžã§è¡ãããš
ãæãŸãããåå¿æž©åºŠã¯ç¹ã«å¶éã¯ãªãããåå¿
é²è¡äžå¥œãŸããã¯50ã150âã®ç¯å²ã§å®æœãããã æå(3)ã®äœ¿çšéã¯æå(2)ãšæå(3)ã®æ¯çãããª
ãã¡ã¢ã«æ¯æå(2)ïŒæå(3)ã0.3以äžãç¹ç¹ã«0.4
以äžã奜ãŸãããåå¿æº¶æ¶²äžã®è€çŽ ç°ã«ã«ãã³é ž
ãšã¹ãã«ã®æ¿åºŠã¯5molïŒä»¥äžã奜ãŸãããå
å¿æž©åºŠã«ã€ããŠã¯40ã160âã®ç¯å²ã§å®æœãããã
ç¹ã«å¥œãŸããã¯50ã150âã®ç¯å²ã§å®æœãããã æå(1)ïŒ(2)ïŒ(3)ãåå¿ãããæ¹æ³ã«ã€ããŠã¯ã
æå(1)ã«ãã¿ã³ååç©(2)ãæ·»å ããåãåŸããŸã
ã¯åæã«è€çŽ ç°ã«ã«ãã³é žãšã¹ãã«(3)ãæ·»å ãã
ããšãã§ããããæå(3)ã¯æå(1)ã«ãã¿ã³ååç©
(2)ãæ·»å ããåãªããåæã«æ·»å ããæ¹æ³ã奜ãŸ
ããã ã(B)ãã®ææ©ã¢ã«ãããŠã ååç©ãšããŠã¯ãã
ãªã¡ãã«ã¢ã«ãããŠã ãããªãšãã«ã¢ã«ãããŠ
ã ãããªâïœâãããã«ã¢ã«ãããŠã ãããªã€ãœ
ãããã«ã¢ã«ãããŠã ãããªâïœâããã«ã¢ã«ã
ããŠã ãããªâïœâããã«ã¢ã«ãããŠã ãããªâ
ïœâããã·ã«ã¢ã«ãããŠã ãããªâïœâãªã¯ãã«
ã¢ã«ãããŠã ãããªâïœâãã·ã«ã¢ã«ãããŠã ã
ããªâïœâããã·ã«ã¢ã«ãããŠã ãããªãããµã
ã·ã«ã¢ã«ãããŠã ãã¢ã«ãããŠã ã€ãœãã¬ãã«ç
ã®ããªã¢ã«ãã«ã¢ã«ãããŠã ãæãããããžãšã
ã«ã¢ã«ãããŠã ãã€ãã©ã€ãããžã€ãœããã«ã¢ã«
ãããŠã ãã€ãã©ã€ããªã©ã®ãžã¢ã«ãã«ã¢ã«ãã
ãŠã ãã€ãã©ã€ãã䜿çšã§ããïŒC2H5ïŒ2Alââ
AlïŒC2H5ïŒ2ã
ãåŒãã®
ãããªïŒ¯ååãååãä»ããŠçµåããïŒåãŸã
ã¯ãã以äžã®ã¢ã«ãããŠã ååãæããææ©ã¢ã«
ãããŠã ååç©ããžã¡ãã«ã¢ã«ãããŠã ã¯ããª
ãããžãšãã«ã¢ã«ãããŠã ã¯ããªãããžâïœâã
ããã«ã¢ã«ãããŠã ã¯ããªãããžâïœâããã«ã¢
ã«ãããŠã ã¯ããªãããžâïœâããã«ã¢ã«ãããŠ
ã ã¯ããªãããžâïœâããã·ã«ã¢ã«ãããŠã ã¯ã
ãªãããžâïœâããã·ã«ã¢ã«ãããŠã ã¯ããªãã
ãžïŒïŒâãšãã«ããã·ã«ïŒã¢ã«ãããŠã ã¯ããª
ãããžâïœâããã·ã«ã¢ã«ãããŠã ã¯ããªããã¡
ãã«âïœâããã«ã¢ã«ãããŠã ã¯ããªãããšãã«
âïœâããã«ã¢ã«ãããŠã ã¯ããªããã¡ãã«ã¢ã«
ãããŠã ã»ã¹ãã¯ããªãããšãã«ã¢ã«ãããŠã ã»
ã¹ãã¯ããªããïœâããã«ã¢ã«ãããŠã ã»ã¹ãã¯
ããªããã¡ãã«ã¢ã«ãããŠã ãžã¯ããªãããšãã«
ã¢ã«ãããŠã ãžã¯ããªããïœâããã«ã¢ã«ãããŠ
ã ãžã¯ããªãããžãšãã«ã¢ã«ãããŠã ããããã
ãžãšãã«ã¢ã«ãããŠã ã¯ããªãçãæããããã æåããããã³ããã¯éåæ¡ä»¶äžã«éåç³»
å ã«æ·»å ããŠããããããããããéåã«å ç«ã€
ãŠçµåããŠãããããŸããçµåãããäž¡æåã®æ¯
çã¯ãããæåäžã®TiãšïŒããã³ããæåäž
ã®Alã®ã¢ã«æ¯ã§èŠå®ããã奜ãŸããç¯å²ãšããŠ
ã¯ïŒïŒïŒAlïŒïŒTiã3/1ã1000/1ã§ããã æ¬çºæã¯ããªã¬ãã€ã³ã®é«æŽ»æ§ãé«ç«äœèŠåæ§
éåçšè§Šåªã§ãããç¹ã«æ¬çºæã¯ããããã¬ã³ã
ããã³âïŒããã³ãã³âïŒãïŒâã¡ãã«ãã³ãã³
âïŒãïŒâã¡ãã«ããã³âïŒããã³åæ§ã®ãªã¬ã
ã€ã³ãåç¬ã«ç«äœèŠåçã«éåããã®ã«é©ããã
ãŸãã該ãªã¬ãã€ã³ããšãã¬ã³ãããã¯ä»ã®ãªã¬
ãã€ã³ãšå ±éåãããããšãããã«ãšãã¬ã³ãå¹
çããéåãããããšã«ãé©ããããŸããããªã
ãŒã®ååéã調ç¯ããããã«ãæ°ŽçŽ ãããã²ã³å
çåæ°ŽçŽ ããããã¯é£é移åãèµ·ããæãææ©é
å±ååç©ãæ·»å ããããšãå¯èœã§ããã éåæ¹æ³ãšããŠã¯ãéåžžã®æžæ¿éåã液äœã¢ã
ããŒäžã§ã®å¡ç¶éåãæ°çžéåãå¯èœã§ãããæž
æ¿éåã¯ã觊åªãéå溶åªãããšãã°ããããµ
ã³ãããã¿ã³ã®ããšãèèªæçåæ°ŽçŽ ããã³ãŒ
ã³ããã«ãšã³ããã·ã¬ã³ã®ããšãè³éŠæçåæ°Ž
çŽ ãã·ã¯ããããµã³ãã¡ãã«ã·ã¯ããããµã³ã®è
ç°åŒçåæ°ŽçŽ ãšããã«åå¿åšã«å°å ¥ããäžæŽ»æ§é°
å²æ°äžã«ãããã¬ã³çã®ãªã¬ãã€ã³ãïŒã20KgïŒ
cm2ã«å§å ¥ããŠã100â以äžã®æž©åºŠã§éåãè¡ãã
ãšãã§ãããå¡ç¶éåã¯ã觊åªããããã¬ã³çã®
ãªã¬ãã€ã³ã液äœã§ããæ¡ä»¶äžã§ã液ç¶ã®ãªã¬ã
ã€ã³ãéå溶åªãšããŠãªã¬ãã€ã³ã®éåãè¡ãã
ãšãã§ãããããšãã°ãããã¬ã³ã®å Žåã100â
以äžã®æž©åºŠã§ã液äœãããã¬ã³äžã§éåãè¡ãã
ãšãã§ãããäžæ¹ãæ°çžéåã¯ãããã¬ã³çã®ãª
ã¬ãã€ã³ãæ°äœã§ããæ¡ä»¶äžã§ã溶åªã®äžååšäž
ã«ïŒã50KgïŒcm2ã®å§åã§ã100â以äžã®æž©åºŠæ¡ä»¶
ã«ãããŠããããã¬ã³çã®ãªã¬ãã€ã³ãšè§Šåªã®æ¥
觊ãè¯å¥œãšãªãããã«ãæµååºã移ååºãããã
ã¯æ¹ææ©ã«ãã€ãŠæ··åãè¡ãçã®æ段ãæ§ããŠé
åãè¡ãããšãå¯èœã§ããã 以äžã«æ¬çºæãå®æœäŸã«ãã説æããããªãã
å®æœäŸäžã«ãããŠçšãã沞隰ïœâããã¿ã³æœåºæ®
枣ãšã¯ãããªããŒã沞隰ïœâããã¿ã³ã«ããïŒæ
éæœåºããæ®æž£ãæå³ãã溶èææ°ïŒMFIïŒã¯ã
ASTM â1238å·ã«ããã枩床230âãè·é
2.16Kgã®æ¡ä»¶äžã§æž¬å®ãããã®ã§ããããããã
è¡šïŒã®èšå·ã¯ãEtïŒC2H5ãPrïŒC3H7ãBuïŒ
C4H9ãAmïŒC5H11ã®æå³ã§ããã å®æœäŸ ïŒ (1) æåããã®åæ ååã«ä¹Ÿç¥ãã容éïŒã®ãã©ã¹ã³ã«ãçµæ
AlMg4.0ïŒïœâC4H9ïŒ7ïŒOnâC6H13ïŒ4ã®ææ©ãã°
ãã·ãŠã æå10mmolãçªçŽ æ°æµäž200âã§ïŒæ
é也ç¥ããã·ãªã«ïŒDavison瀟補952ïŒïŒïœãã
ã³ïœâãããµã³100mlã秀åãã60âã§ïŒæéå
å¿ãããåŸãããªã¯ãã«ã·ã©ã³ïŒHSiCl3ïŒã®ã
ããµã³æº¶æ¶²ïŒ1molïŒïŒ10mmoläžã«ãäžèšã¹ã©
ãªãŒã滎äžããŠã65âã§ïŒæéããã«åå¿ãã
ãããã®ã¹ã©ãªãŒæ··åç©ã«ããªããšã³âïŒâã«ã«
ãã³é žãšãã«0.6mmolãå ããïŒæéåå¿ããã
åŸãåå¡©åãã¿ã³0.3mmolãå ããïŒæéåå¿ã
ããŠæåãããåŸãã (2) ãããã¬ã³ã®éå (1)ã§åæãã觊åªã¹ã©ãªãŒãããTiã«ããŠ
0.04mmol秀åããããªãšãã«ã¢ã«ãããŠã
0.2mmolãšãããµã³ïŒãšãšãã«ãååã«ä¹Ÿç¥ã
ã容éïŒã®ãªãŒãã¯ã¬ãŒãŽã«å ¥ããå æž©ã60â
ã«ä¿ã¡ãæ°ŽçŽ ãã²ãŒãžå§ã§0.04KgïŒcm2ã«çžåœãã
éå°å ¥ãããããã¬ã³ãã²ãŒãžå§ã§5.0KgïŒcm2ã®
å§åã«å å§ããå šå§ã4.8KgïŒcm2ã²ãŒãžå§ã«ä¿ã¡
ã€ã€ãïŒæééåãè¡ãããããµã³äžæº¶ããªããŒ
260ïœããããµã³å¯æº¶ç©12.0ïœãåŸãã觊åªå¹ç
ã¯136000ïœâppïŒïœâTiããããµã³äžæº¶ããªã
ãŒã®ïœâããã¿ã³æœåºæ®æž£ã¯94.3ïŒ ã§ããããã®
å¹³åç²ååŸã¯20ã¡ãã·ãŠã§ãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã®æåããã®åæã«ãããŠãææ©ã
ã°ãã·ãŠã æåãšããŠAlMg6ïŒC2H5ïŒ3ïŒnC4H9ïŒ
9.0ïŒOSiã»ïŒšã»CH3ã»nC4H9ïŒ3.0ã8mmolãçš
ãããŸããžã¯ãã«ã¡ãã«ã·ã©ã³ïŒHSiCl2CH3ïŒ
16mmolã75âã§åå¿ãããä»ã¯ãå šãŠå®æœäŸïŒ
ãšåæ§ã«ããŠæåãããåæãããããã¬ã³ã®
ã¹ã©ãªãŒéåãè¡ãããããµã³äžæº¶ããªããŒ270
ïœããããµã³å¯æº¶ç©11.7ïœãåŸãã觊åªå¹çã¯
162000ïœïŒâppïŒïœâTiããããµã³äžæº¶ããªã
ãŒã®ïœâããã¿ã³æœåºæ®æž£ã¯94.5ïŒ ã§ãã€ããã
ããµã³äžæº¶ããªããŒå¹³åç²ååŸã¯20ã¡ãã·ãŠã§ã
ã€ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠã·ãªã«ã®ä»£ãã«ã·ãªã«ã»ã¢ã«
ãããçšããä»ã¯ãå šãŠå®æœäŸïŒãšåæ§ã«ããŠæ¬¡
ã®çµæãåŸãããããµã³äžæº¶ããªããŒ250ïœïŒè§Š
åªå¹ç130000ïœâppïŒïœâTiãïœâããã¿ã³æœ
åºæ®æž£94.6ïŒ ãå¹³åç²ååŸ28ã¡ãã·ãŠïŒããããµ
ã³å¯æº¶ç©10.3ïœã å®æœäŸ ïŒãïŒ å®æœäŸïŒã®è§Šåªæåããã®åæã«ãããŠãè¡š
ïŒã«ç€ºãååç©ãçšããä»ã¯ãå šãŠå®æœäŸïŒãšå
æ§ã«ããŠè¡ããè¡šïŒã®çµæãåŸãã
ã¯ãã以äžã®ã¢ã«ãããŠã ååãæããææ©ã¢ã«
ãããŠã ååç©ããžã¡ãã«ã¢ã«ãããŠã ã¯ããª
ãããžãšãã«ã¢ã«ãããŠã ã¯ããªãããžâïœâã
ããã«ã¢ã«ãããŠã ã¯ããªãããžâïœâããã«ã¢
ã«ãããŠã ã¯ããªãããžâïœâããã«ã¢ã«ãããŠ
ã ã¯ããªãããžâïœâããã·ã«ã¢ã«ãããŠã ã¯ã
ãªãããžâïœâããã·ã«ã¢ã«ãããŠã ã¯ããªãã
ãžïŒïŒâãšãã«ããã·ã«ïŒã¢ã«ãããŠã ã¯ããª
ãããžâïœâããã·ã«ã¢ã«ãããŠã ã¯ããªããã¡
ãã«âïœâããã«ã¢ã«ãããŠã ã¯ããªãããšãã«
âïœâããã«ã¢ã«ãããŠã ã¯ããªããã¡ãã«ã¢ã«
ãããŠã ã»ã¹ãã¯ããªãããšãã«ã¢ã«ãããŠã ã»
ã¹ãã¯ããªããïœâããã«ã¢ã«ãããŠã ã»ã¹ãã¯
ããªããã¡ãã«ã¢ã«ãããŠã ãžã¯ããªãããšãã«
ã¢ã«ãããŠã ãžã¯ããªããïœâããã«ã¢ã«ãããŠ
ã ãžã¯ããªãããžãšãã«ã¢ã«ãããŠã ããããã
ãžãšãã«ã¢ã«ãããŠã ã¯ããªãçãæããããã æåããããã³ããã¯éåæ¡ä»¶äžã«éåç³»
å ã«æ·»å ããŠããããããããããéåã«å ç«ã€
ãŠçµåããŠãããããŸããçµåãããäž¡æåã®æ¯
çã¯ãããæåäžã®TiãšïŒããã³ããæåäž
ã®Alã®ã¢ã«æ¯ã§èŠå®ããã奜ãŸããç¯å²ãšããŠ
ã¯ïŒïŒïŒAlïŒïŒTiã3/1ã1000/1ã§ããã æ¬çºæã¯ããªã¬ãã€ã³ã®é«æŽ»æ§ãé«ç«äœèŠåæ§
éåçšè§Šåªã§ãããç¹ã«æ¬çºæã¯ããããã¬ã³ã
ããã³âïŒããã³ãã³âïŒãïŒâã¡ãã«ãã³ãã³
âïŒãïŒâã¡ãã«ããã³âïŒããã³åæ§ã®ãªã¬ã
ã€ã³ãåç¬ã«ç«äœèŠåçã«éåããã®ã«é©ããã
ãŸãã該ãªã¬ãã€ã³ããšãã¬ã³ãããã¯ä»ã®ãªã¬
ãã€ã³ãšå ±éåãããããšãããã«ãšãã¬ã³ãå¹
çããéåãããããšã«ãé©ããããŸããããªã
ãŒã®ååéã調ç¯ããããã«ãæ°ŽçŽ ãããã²ã³å
çåæ°ŽçŽ ããããã¯é£é移åãèµ·ããæãææ©é
å±ååç©ãæ·»å ããããšãå¯èœã§ããã éåæ¹æ³ãšããŠã¯ãéåžžã®æžæ¿éåã液äœã¢ã
ããŒäžã§ã®å¡ç¶éåãæ°çžéåãå¯èœã§ãããæž
æ¿éåã¯ã觊åªãéå溶åªãããšãã°ããããµ
ã³ãããã¿ã³ã®ããšãèèªæçåæ°ŽçŽ ããã³ãŒ
ã³ããã«ãšã³ããã·ã¬ã³ã®ããšãè³éŠæçåæ°Ž
çŽ ãã·ã¯ããããµã³ãã¡ãã«ã·ã¯ããããµã³ã®è
ç°åŒçåæ°ŽçŽ ãšããã«åå¿åšã«å°å ¥ããäžæŽ»æ§é°
å²æ°äžã«ãããã¬ã³çã®ãªã¬ãã€ã³ãïŒã20KgïŒ
cm2ã«å§å ¥ããŠã100â以äžã®æž©åºŠã§éåãè¡ãã
ãšãã§ãããå¡ç¶éåã¯ã觊åªããããã¬ã³çã®
ãªã¬ãã€ã³ã液äœã§ããæ¡ä»¶äžã§ã液ç¶ã®ãªã¬ã
ã€ã³ãéå溶åªãšããŠãªã¬ãã€ã³ã®éåãè¡ãã
ãšãã§ãããããšãã°ãããã¬ã³ã®å Žåã100â
以äžã®æž©åºŠã§ã液äœãããã¬ã³äžã§éåãè¡ãã
ãšãã§ãããäžæ¹ãæ°çžéåã¯ãããã¬ã³çã®ãª
ã¬ãã€ã³ãæ°äœã§ããæ¡ä»¶äžã§ã溶åªã®äžååšäž
ã«ïŒã50KgïŒcm2ã®å§åã§ã100â以äžã®æž©åºŠæ¡ä»¶
ã«ãããŠããããã¬ã³çã®ãªã¬ãã€ã³ãšè§Šåªã®æ¥
觊ãè¯å¥œãšãªãããã«ãæµååºã移ååºãããã
ã¯æ¹ææ©ã«ãã€ãŠæ··åãè¡ãçã®æ段ãæ§ããŠé
åãè¡ãããšãå¯èœã§ããã 以äžã«æ¬çºæãå®æœäŸã«ãã説æããããªãã
å®æœäŸäžã«ãããŠçšãã沞隰ïœâããã¿ã³æœåºæ®
枣ãšã¯ãããªããŒã沞隰ïœâããã¿ã³ã«ããïŒæ
éæœåºããæ®æž£ãæå³ãã溶èææ°ïŒMFIïŒã¯ã
ASTM â1238å·ã«ããã枩床230âãè·é
2.16Kgã®æ¡ä»¶äžã§æž¬å®ãããã®ã§ããããããã
è¡šïŒã®èšå·ã¯ãEtïŒC2H5ãPrïŒC3H7ãBuïŒ
C4H9ãAmïŒC5H11ã®æå³ã§ããã å®æœäŸ ïŒ (1) æåããã®åæ ååã«ä¹Ÿç¥ãã容éïŒã®ãã©ã¹ã³ã«ãçµæ
AlMg4.0ïŒïœâC4H9ïŒ7ïŒOnâC6H13ïŒ4ã®ææ©ãã°
ãã·ãŠã æå10mmolãçªçŽ æ°æµäž200âã§ïŒæ
é也ç¥ããã·ãªã«ïŒDavison瀟補952ïŒïŒïœãã
ã³ïœâãããµã³100mlã秀åãã60âã§ïŒæéå
å¿ãããåŸãããªã¯ãã«ã·ã©ã³ïŒHSiCl3ïŒã®ã
ããµã³æº¶æ¶²ïŒ1molïŒïŒ10mmoläžã«ãäžèšã¹ã©
ãªãŒã滎äžããŠã65âã§ïŒæéããã«åå¿ãã
ãããã®ã¹ã©ãªãŒæ··åç©ã«ããªããšã³âïŒâã«ã«
ãã³é žãšãã«0.6mmolãå ããïŒæéåå¿ããã
åŸãåå¡©åãã¿ã³0.3mmolãå ããïŒæéåå¿ã
ããŠæåãããåŸãã (2) ãããã¬ã³ã®éå (1)ã§åæãã觊åªã¹ã©ãªãŒãããTiã«ããŠ
0.04mmol秀åããããªãšãã«ã¢ã«ãããŠã
0.2mmolãšãããµã³ïŒãšãšãã«ãååã«ä¹Ÿç¥ã
ã容éïŒã®ãªãŒãã¯ã¬ãŒãŽã«å ¥ããå æž©ã60â
ã«ä¿ã¡ãæ°ŽçŽ ãã²ãŒãžå§ã§0.04KgïŒcm2ã«çžåœãã
éå°å ¥ãããããã¬ã³ãã²ãŒãžå§ã§5.0KgïŒcm2ã®
å§åã«å å§ããå šå§ã4.8KgïŒcm2ã²ãŒãžå§ã«ä¿ã¡
ã€ã€ãïŒæééåãè¡ãããããµã³äžæº¶ããªããŒ
260ïœããããµã³å¯æº¶ç©12.0ïœãåŸãã觊åªå¹ç
ã¯136000ïœâppïŒïœâTiããããµã³äžæº¶ããªã
ãŒã®ïœâããã¿ã³æœåºæ®æž£ã¯94.3ïŒ ã§ããããã®
å¹³åç²ååŸã¯20ã¡ãã·ãŠã§ãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã®æåããã®åæã«ãããŠãææ©ã
ã°ãã·ãŠã æåãšããŠAlMg6ïŒC2H5ïŒ3ïŒnC4H9ïŒ
9.0ïŒOSiã»ïŒšã»CH3ã»nC4H9ïŒ3.0ã8mmolãçš
ãããŸããžã¯ãã«ã¡ãã«ã·ã©ã³ïŒHSiCl2CH3ïŒ
16mmolã75âã§åå¿ãããä»ã¯ãå šãŠå®æœäŸïŒ
ãšåæ§ã«ããŠæåãããåæãããããã¬ã³ã®
ã¹ã©ãªãŒéåãè¡ãããããµã³äžæº¶ããªããŒ270
ïœããããµã³å¯æº¶ç©11.7ïœãåŸãã觊åªå¹çã¯
162000ïœïŒâppïŒïœâTiããããµã³äžæº¶ããªã
ãŒã®ïœâããã¿ã³æœåºæ®æž£ã¯94.5ïŒ ã§ãã€ããã
ããµã³äžæº¶ããªããŒå¹³åç²ååŸã¯20ã¡ãã·ãŠã§ã
ã€ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããŠã·ãªã«ã®ä»£ãã«ã·ãªã«ã»ã¢ã«
ãããçšããä»ã¯ãå šãŠå®æœäŸïŒãšåæ§ã«ããŠæ¬¡
ã®çµæãåŸãããããµã³äžæº¶ããªããŒ250ïœïŒè§Š
åªå¹ç130000ïœâppïŒïœâTiãïœâããã¿ã³æœ
åºæ®æž£94.6ïŒ ãå¹³åç²ååŸ28ã¡ãã·ãŠïŒããããµ
ã³å¯æº¶ç©10.3ïœã å®æœäŸ ïŒãïŒ å®æœäŸïŒã®è§Šåªæåããã®åæã«ãããŠãè¡š
ïŒã«ç€ºãååç©ãçšããä»ã¯ãå šãŠå®æœäŸïŒãšå
æ§ã«ããŠè¡ããè¡šïŒã®çµæãåŸãã
ãè¡šã
ãè¡šã
å®æœäŸ ïŒ
å®æœäŸïŒã®éåã«ãããŠããããã¬ã³ã«ãããŠ
ããã³âïŒãçšããä»ã¯ãå šãŠå®æœäŸïŒãšåæ§ã«
ããŠããã³âïŒã®éåãè¡ããçœè²ããªããŒ243
ïœãåŸãã å®æœäŸ ïŒ å®æœäŸïŒã®éåã«ãããŠããããã¬ã³ã«ãããŠ
ïŒâã¡ãã«ãã³ãã³âïŒãçšããä»ã¯ãå šãŠå®æœ
äŸïŒãšåæ§ã«ããŠïŒâã¡ãã«ãã³ãã³âïŒã®éå
ãè¡ããçœè²ããªããŒ93ïœãåŸãã å®æœäŸ 10 å®æœäŸïŒã®éåã«ãããŠããããã¬ã³ã«ãããŠ
ãšãã¬ã³ãïŒã¢ã«ïŒ å«æãããããã¬ã³âãšãã¬
ã³æ··åã¬ã¹ãçšããä»ã¯ãå®æœäŸïŒãšåæ§ã«ãé
åãè¡ããçœè²ããªããŒ275ïœãåŸãã å®æœäŸ 11 å®æœäŸïŒãšåæ§ã«åæããæåãããããªã€
ãœããã«ã¢ã«ãããŠã 1.0mmolããã³ããªããšã³
âïŒâã«ã«ãã³é žãšãã«0.1mmolããè±æ°Žè±æ°ã
ãïœâãããµã³0.8ãšãšãã«ãå éšãç空也ç¥ã
çªçŽ 眮æãã1.5ã®ãªãŒãã¯ã¬ãŒãŽã«å ¥ããå
æž©ã80âã«ä¿ã¡ãæ°ŽçŽ ã1.6KgïŒcm2ã«å å§ãã次
ãã§ãšãã¬ã³ãå ããŠå šå§ãïŒKgïŒcm2ãšãããšã
ã¬ã³ãäŸçµŠããªããïŒæééåããŠãçœè²éåäœ
220ïœãåŸãã
ããã³âïŒãçšããä»ã¯ãå šãŠå®æœäŸïŒãšåæ§ã«
ããŠããã³âïŒã®éåãè¡ããçœè²ããªããŒ243
ïœãåŸãã å®æœäŸ ïŒ å®æœäŸïŒã®éåã«ãããŠããããã¬ã³ã«ãããŠ
ïŒâã¡ãã«ãã³ãã³âïŒãçšããä»ã¯ãå šãŠå®æœ
äŸïŒãšåæ§ã«ããŠïŒâã¡ãã«ãã³ãã³âïŒã®éå
ãè¡ããçœè²ããªããŒ93ïœãåŸãã å®æœäŸ 10 å®æœäŸïŒã®éåã«ãããŠããããã¬ã³ã«ãããŠ
ãšãã¬ã³ãïŒã¢ã«ïŒ å«æãããããã¬ã³âãšãã¬
ã³æ··åã¬ã¹ãçšããä»ã¯ãå®æœäŸïŒãšåæ§ã«ãé
åãè¡ããçœè²ããªããŒ275ïœãåŸãã å®æœäŸ 11 å®æœäŸïŒãšåæ§ã«åæããæåãããããªã€
ãœããã«ã¢ã«ãããŠã 1.0mmolããã³ããªããšã³
âïŒâã«ã«ãã³é žãšãã«0.1mmolããè±æ°Žè±æ°ã
ãïœâãããµã³0.8ãšãšãã«ãå éšãç空也ç¥ã
çªçŽ 眮æãã1.5ã®ãªãŒãã¯ã¬ãŒãŽã«å ¥ããå
æž©ã80âã«ä¿ã¡ãæ°ŽçŽ ã1.6KgïŒcm2ã«å å§ãã次
ãã§ãšãã¬ã³ãå ããŠå šå§ãïŒKgïŒcm2ãšãããšã
ã¬ã³ãäŸçµŠããªããïŒæééåããŠãçœè²éåäœ
220ïœãåŸãã
第ïŒå³ã¯æ¬çºæã«ããã觊åªã®èª¿æŽå·¥çšã瀺ã
ãããŒãã€ãŒãå³ã§ããã
ãããŒãã€ãŒãå³ã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ãªã¬ãã€ã³ããã°ãã·ãŠã ååç©ããã¿ã³å
åç©ãé»åäŸäžäœãææ©éå±ååç©ãå«ãã§ãªã
觊åªãçšããŠéåããæ¹æ³ã«ãããŠã ãã (1) (i) (a)äžè¬åŒMãMgãR1 pR2 qXrYs
ïŒåŒäžãïŒã¯åšæåŸè¡šç¬¬æã第æã®é
å±ååãαâ§ïŒãβïŒïŒãïœïŒïœïŒïœïŒïœ
ã¯ïŒãŸãã¯ïŒä»¥äžã®æ°ãïœã¯ïŒã®åå䟡ã§
ãããmαïŒ2βïŒïœïŒïœïŒïœïŒïœã®é¢ä¿ã
æããR1ïŒR2ã¯ççŽ æ°ïŒã20ã®åäžãŸã
ã¯ç°ãªã€ãçåæ°ŽçŽ åºãïŒïŒ¹ã¯åäžãŸã
ã¯ç°ãªã€ãåºã§ãæ°ŽçŽ åºãOR3ïŒ
OSiR4R5R6ãNR7R8ãSR9ãããã²ã³ã
è¡šãããR3ïŒR4ïŒR5ïŒR6ïŒR7ïŒR8ã¯æ°ŽçŽ
åºãŸãã¯çåæ°ŽçŽ åºãè¡šãããR9ã¯çå
æ°ŽçŽ åºãè¡šããïŒã§ç€ºãããçåæ°ŽçŽ å¯æº¶
ã®ææ©ãã°ãã·ãŠã æåïŒã¢ã«ããããã¯
(a)ãš(b)ãšãŒãã«ãããªãšãŒãã«ãã±ãã³ã
ã¢ã«ããããã«ã«ãã³é žãŸãã¯ãã®èªå°äœ
ãããã¯ã¢ã«ã³ãŒã«ãããªã¢ã«ã³ãŒã«ãã¢
ãã³ããéžã°ããé»åäŸäžäœãåå¿ããã
æåïŒã¢ã«ïŒãã°ãã·ãŠã ã«åºã¥ããŠïŒ
ãšã (ii) äžè¬åŒHaSiClbR10 4-(a+b)ïŒåŒäžãR10ã¯ççŽ
æ°ïŒã20ã®çåæ°ŽçŽ åºãè¡šãããïŒïŒïœâŠ
ïŒãïœã¯ïŒãã倧ãªãæ°ã§ããïŒã§ç€ºãã
ãçªçŽ ååç©0.01ã100ã¢ã«ãã (iii) ç¡æ©é žåç©10ïœã10Kg ã®ååšäžã«ãããŠã20ã150âã®æž©åºŠã§å
å¿ãããŠåŸãããã¹ã©ãªãŒç¶åå¿æ··åç©
ã«ã (2) äžè¬åŒTiïŒOR11ïŒoZ4-oïŒåŒäžãR11ã¯ççŽ æ°
ïŒã20ã®çåæ°ŽçŽ åºãè¡šãããã¯ããã²ã³
ååãè¡šãããïœã¯ïŒâŠïœâŠïŒãªãæ°ãè¡šã
ãïŒã§ç€ºããããã¿ã³ååç©ã (3) å«ç¡«é»ãªããå«çªçŽ è€çŽ ç°ã«ã«ãã³é žãšã¹
ãã«ããéžã°ããæå ãå ããŠåŸãããã¹ã©ãªãŒç¶è§Šåªæåãããã³ ãã ææ©ã¢ã«ãããŠã ååç© ãããªã觊åªã§ãã€ãŠã(2)ã®ãã¿ã³ååç©ïŒ(3)ã®
ååç©ã®ã¢ã«æ¯ã0.3以äžã§ãã觊åªãããªã¬ã
ã€ã³ãš100â以äžã§æ¥è§Šãããããšãç¹åŸŽãšãã
ãªã¬ãã€ã³éåæ³ã ïŒ (1)â(iii)ã®ç¡æ©é žåç©ãã·ãªã«ãŸãã¯ã·ãªã«ã»
ã¢ã«ããã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ãªã¬
ãã€ã³éåæ³ã ïŒ (1)â(i)ã®ææ©ãã°ãã·ãŠã æåã«ãããŠãïœ
ïŒïŒã§ããOR3ãªããOSiR4R5R6ã§ããç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé ãªãã第ïŒé ã®ããããã«èšèŒ
ã®ãªã¬ãã€ã³éåæ³ã ïŒ (1)â(i)ã®ææ©ãã°ãã·ãŠã æåã«ãããŠãïŒ
ããªããŠã ãããªãªãŠã ãããŠçŽ ãã¢ã«ãããŠã
ãããã¯äºéã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãªãã
第ïŒé ã®ããããã«èšèŒã®ãªã¬ãã€ã³éåæ³ã ïŒ (1)â(i)ã®ææ©ãã°ãã·ãŠã æåã«ãããŠãα
ïŒïŒã§ãβïŒÎ±ã0.5ã10ã§ããç¹èš±è«æ±ã®ç¯å²
第ïŒé ãªãã第ïŒé ã®ããããã«èšèŒã®ãªã¬ãã€
ã³éåæ³ã ïŒ (1)â(i)ã®ææ©ãã°ãã·ãŠã æåã«ãããŠãïŒ
âŠïŒïœïŒïœïŒïŒïŒÎ±ïŒÎ²ïŒïŒïŒã§ããç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒé ãªãã第ïŒé ã®ããããã«èšèŒã®ãªã¬ã
ã€ã³éåæ³ã ïŒ (1)â(iii)ã®ããã²ã³åçªçŽ ååç©ãäžè¬åŒHa
SiClbR10 4-(a+b)ïŒåŒäžãR10ã¯ççŽ æ°ïŒã20ã®ççŽ æ°
ãè¡šããã0.5âŠïœâŠ1.5ãïœã¯ïŒãã倧ããæ°ã§
ããïŒã§ç€ºãããçªçŽ ååç©ã§ããç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒé ãªãã第ïŒé ã®ããããã«èšèŒã®ãªã¬ã
ã€ã³éåæ³ã ïŒ ç¡æ©é žåç©ãšææ©ãã°ãã·ãŠã æåãåå¿ã
ããåŸãããã²ã³åçªçŽ ååç©ãšåå¿ãããç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé ãªãã第ïŒé ã®ããããã«èšèŒ
ã®ãªã¬ãã€ã³éåæ³ã ïŒ (3)ã®å«ç¡«é»ãªããå«çªçŽ è€çŽ ç°ã«ã«ãã³é žãš
ã¹ãã«ãççŽ æ°ïŒãïŒã®äœçŽã¢ã«ã³ãŒã«ã®ãšã¹ã
ã«ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãªãã第ïŒé ã®ã
ãããã«èšèŒã®ãªã¬ãã€ã³éåæ³ã ïŒïŒ ããã®ææ©éå±ååç©ãããªã¢ã«ãã«ã¢
ã«ãããŠã ãŸãã¯ãžã¢ã«ãã«ã¢ã«ãããŠã ãã€ã
ã©ã€ãã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãªãã第ïŒïŒ
é ã®ããããã«èšèŒã®ãªã¬ãã€ã³éåæ³ã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20684781A JPS58109506A (ja) | 1981-12-23 | 1981-12-23 | ãªã¬ãã€ã³éåæ³ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20684781A JPS58109506A (ja) | 1981-12-23 | 1981-12-23 | ãªã¬ãã€ã³éåæ³ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58109506A JPS58109506A (ja) | 1983-06-29 |
| JPS64966B2 true JPS64966B2 (ja) | 1989-01-10 |
Family
ID=16530036
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20684781A Granted JPS58109506A (ja) | 1981-12-23 | 1981-12-23 | ãªã¬ãã€ã³éåæ³ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58109506A (ja) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4870040A (en) * | 1987-11-24 | 1989-09-26 | Shell Oil Company | Olefin polymerization catalysts from soluble magnesium alkoxides made from alkyl or aryl magnesium mixed with a branched or aromatic aldehyde |
| US4870039A (en) * | 1987-11-24 | 1989-09-26 | Shell Oil Company | Olefin polymerization catalysts from soluble magnesium alkoxides made from mixed magnesium alkyls and aryls |
| US7371802B2 (en) * | 2003-10-28 | 2008-05-13 | Basell Poliolefine Italia S.R.L. | Components and catalysts for the polymerization of olefins |
-
1981
- 1981-12-23 JP JP20684781A patent/JPS58109506A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58109506A (ja) | 1983-06-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4159963A (en) | Catalyst for producing polyolefins | |
| US4526941A (en) | Polymerization of olefins | |
| JPH04306203A (ja) | æ¹è¯ããããªã¬ãã£ã³éåçšä¹Ÿç¥è§Šåª | |
| JPH0343285B2 (ja) | ||
| JPS6366843B2 (ja) | ||
| JP2888552B2 (ja) | ãªã¬ãã£ã³éåçšè§Šåª | |
| US4255280A (en) | Catalyst for polymerization of olefins | |
| US4330650A (en) | Catalyst for polymerization of olefins | |
| JPH0125763B2 (ja) | ||
| US4533706A (en) | Catalyst and process using same for producing olefin polymer | |
| JPS64966B2 (ja) | ||
| JPS5846129B2 (ja) | é«çµæ¶æ§ãªã¬ãã£ã³éåäœã®è£œé æ³ | |
| JPS6354722B2 (ja) | ||
| JPS64408B2 (ja) | ||
| JP3253650B2 (ja) | ãšãã¬ã³ïŒå ±ïŒéåäœã®è£œé æ¹æ³ | |
| JPS643210B2 (ja) | ||
| JPS643209B2 (ja) | ||
| JPS6366322B2 (ja) | ||
| JPS643203B2 (ja) | ||
| JPH0128049B2 (ja) | ||
| JPS6410529B2 (ja) | ||
| JP2660967B2 (ja) | ãªã¬ãã£ã³éåäœã®è£œé æ³ | |
| JPS5948044B2 (ja) | ãªã¬ãã€ã³éåè§Šåª | |
| JPS5919568B2 (ja) | ãªã¬ãã€ã³éåçšè§Šåª | |
| JPH08333415A (ja) | αâãªã¬ãã£ã³éåçšè§Šåªãªãã³ã«Î±âãªã¬ãã£ã³éåäœã®è£œé æ¹æ³ |