JPS634595B2 - - Google Patents
Info
- Publication number
- JPS634595B2 JPS634595B2 JP13013680A JP13013680A JPS634595B2 JP S634595 B2 JPS634595 B2 JP S634595B2 JP 13013680 A JP13013680 A JP 13013680A JP 13013680 A JP13013680 A JP 13013680A JP S634595 B2 JPS634595 B2 JP S634595B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- parts
- acrylate
- acrylic
- meth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004925 Acrylic resin Substances 0.000 claims description 20
- 229920000178 Acrylic resin Polymers 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 19
- 239000008199 coating composition Substances 0.000 claims description 17
- 229920005672 polyolefin resin Polymers 0.000 claims description 13
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 6
- 239000003999 initiator Substances 0.000 claims description 4
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- -1 polyethylene Polymers 0.000 description 35
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 28
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 26
- 238000006243 chemical reaction Methods 0.000 description 22
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
- 230000015572 biosynthetic process Effects 0.000 description 21
- 238000003786 synthesis reaction Methods 0.000 description 21
- 239000002253 acid Substances 0.000 description 20
- 239000003973 paint Substances 0.000 description 20
- 239000000203 mixture Substances 0.000 description 17
- 239000000178 monomer Substances 0.000 description 17
- 239000011248 coating agent Substances 0.000 description 13
- 238000000576 coating method Methods 0.000 description 13
- 229920000098 polyolefin Polymers 0.000 description 13
- 239000010408 film Substances 0.000 description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 12
- 229920000728 polyester Polymers 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 10
- 239000004743 Polypropylene Substances 0.000 description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
- 150000007513 acids Chemical class 0.000 description 10
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical group CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 8
- 229910052753 mercury Inorganic materials 0.000 description 8
- 229920001155 polypropylene Polymers 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 239000000976 ink Substances 0.000 description 7
- 229920006305 unsaturated polyester Polymers 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000539 dimer Substances 0.000 description 3
- 229910001873 dinitrogen Inorganic materials 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 239000005056 polyisocyanate Substances 0.000 description 3
- 229920001228 polyisocyanate Polymers 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- DKEGCUDAFWNSSO-UHFFFAOYSA-N 1,8-dibromooctane Chemical compound BrCCCCCCCCBr DKEGCUDAFWNSSO-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- PLPWVWFSNRMXMT-UHFFFAOYSA-N 2-[3-(2-methylprop-2-enoyloxy)propoxycarbonyl]cyclohex-3-ene-1-carboxylic acid Chemical compound CC(=C)C(=O)OCCCOC(=O)C1C=CCCC1C(O)=O PLPWVWFSNRMXMT-UHFFFAOYSA-N 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- WXUAQHNMJWJLTG-UHFFFAOYSA-N 2-methylbutanedioic acid Chemical compound OC(=O)C(C)CC(O)=O WXUAQHNMJWJLTG-UHFFFAOYSA-N 0.000 description 2
- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 2
- YYROPELSRYBVMQ-UHFFFAOYSA-N 4-toluenesulfonyl chloride Chemical compound CC1=CC=C(S(Cl)(=O)=O)C=C1 YYROPELSRYBVMQ-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical class C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 229940126062 Compound A Drugs 0.000 description 2
- GUUVPOWQJOLRAS-UHFFFAOYSA-N Diphenyl disulfide Chemical compound C=1C=CC=CC=1SSC1=CC=CC=C1 GUUVPOWQJOLRAS-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- AUNGANRZJHBGPY-SCRDCRAPSA-N Riboflavin Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-SCRDCRAPSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 125000004386 diacrylate group Chemical group 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- OKJPEAGHQZHRQV-UHFFFAOYSA-N iodoform Chemical compound IC(I)I OKJPEAGHQZHRQV-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 150000002763 monocarboxylic acids Chemical class 0.000 description 2
- TXXHDPDFNKHHGW-UHFFFAOYSA-N muconic acid Chemical compound OC(=O)C=CC=CC(O)=O TXXHDPDFNKHHGW-UHFFFAOYSA-N 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical group OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- HJUGFYREWKUQJT-UHFFFAOYSA-N tetrabromomethane Chemical compound BrC(Br)(Br)Br HJUGFYREWKUQJT-UHFFFAOYSA-N 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- RKLJSBNBBHBEOT-UHFFFAOYSA-N (3-hydroxy-2,2-dimethylpropanoyl) 3-hydroxy-2,2-dimethylpropanoate Chemical compound OCC(C)(C)C(=O)OC(=O)C(C)(C)CO RKLJSBNBBHBEOT-UHFFFAOYSA-N 0.000 description 1
- SZCWBURCISJFEZ-UHFFFAOYSA-N (3-hydroxy-2,2-dimethylpropyl) 3-hydroxy-2,2-dimethylpropanoate Chemical compound OCC(C)(C)COC(=O)C(C)(C)CO SZCWBURCISJFEZ-UHFFFAOYSA-N 0.000 description 1
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 1
- POJPQMDDRCILHJ-UHFFFAOYSA-N 1,1,1,2,2,2-hexabromoethane Chemical compound BrC(Br)(Br)C(Br)(Br)Br POJPQMDDRCILHJ-UHFFFAOYSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 description 1
- VZXPHDGHQXLXJC-UHFFFAOYSA-N 1,6-diisocyanato-5,6-dimethylheptane Chemical compound O=C=NC(C)(C)C(C)CCCCN=C=O VZXPHDGHQXLXJC-UHFFFAOYSA-N 0.000 description 1
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical class CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 description 1
- XLTMWFMRJZDFFD-UHFFFAOYSA-N 1-[(2-chloro-4-nitrophenyl)diazenyl]naphthalen-2-ol Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C([N+]([O-])=O)C=C1Cl XLTMWFMRJZDFFD-UHFFFAOYSA-N 0.000 description 1
- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 description 1
- WVUYYXUATWMVIT-UHFFFAOYSA-N 1-bromo-4-ethoxybenzene Chemical compound CCOC1=CC=C(Br)C=C1 WVUYYXUATWMVIT-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- GZBSIABKXVPBFY-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO GZBSIABKXVPBFY-UHFFFAOYSA-N 0.000 description 1
- BTUDGPVTCYNYLK-UHFFFAOYSA-N 2,2-dimethylglutaric acid Chemical compound OC(=O)C(C)(C)CCC(O)=O BTUDGPVTCYNYLK-UHFFFAOYSA-N 0.000 description 1
- GOHPTLYPQCTZSE-UHFFFAOYSA-N 2,2-dimethylsuccinic acid Chemical compound OC(=O)C(C)(C)CC(O)=O GOHPTLYPQCTZSE-UHFFFAOYSA-N 0.000 description 1
- KLZYRCVPDWTZLH-UHFFFAOYSA-N 2,3-dimethylsuccinic acid Chemical compound OC(=O)C(C)C(C)C(O)=O KLZYRCVPDWTZLH-UHFFFAOYSA-N 0.000 description 1
- MOBNLCPBAMKACS-UHFFFAOYSA-N 2-(1-chloroethyl)oxirane Chemical compound CC(Cl)C1CO1 MOBNLCPBAMKACS-UHFFFAOYSA-N 0.000 description 1
- KQEKPFRJQVRENQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxycarbonyl)cyclohex-3-ene-1-carboxylic acid Chemical compound OC(=O)C1CCC=CC1C(=O)OCCOC(=O)C=C KQEKPFRJQVRENQ-UHFFFAOYSA-N 0.000 description 1
- UECGJSXCVLTIMQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxycarbonyl)cyclohexane-1-carboxylic acid Chemical compound OC(=O)C1CCCCC1C(=O)OCCOC(=O)C=C UECGJSXCVLTIMQ-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- BXPKASQEUYICBF-UHFFFAOYSA-N 2-(3-prop-2-enoyloxypropoxycarbonyl)benzoic acid Chemical compound OC(=O)C1=CC=CC=C1C(=O)OCCCOC(=O)C=C BXPKASQEUYICBF-UHFFFAOYSA-N 0.000 description 1
- DLBGDYWVGFRLNJ-UHFFFAOYSA-N 2-(3-prop-2-enoyloxypropoxycarbonyl)cyclohexane-1-carboxylic acid Chemical compound OC(=O)C1CCCCC1C(=O)OCCCOC(=O)C=C DLBGDYWVGFRLNJ-UHFFFAOYSA-N 0.000 description 1
- SYEWHONLFGZGLK-UHFFFAOYSA-N 2-[1,3-bis(oxiran-2-ylmethoxy)propan-2-yloxymethyl]oxirane Chemical compound C1OC1COCC(OCC1OC1)COCC1CO1 SYEWHONLFGZGLK-UHFFFAOYSA-N 0.000 description 1
- HDPLHDGYGLENEI-UHFFFAOYSA-N 2-[1-(oxiran-2-ylmethoxy)propan-2-yloxymethyl]oxirane Chemical class C1OC1COC(C)COCC1CO1 HDPLHDGYGLENEI-UHFFFAOYSA-N 0.000 description 1
- FVCHRIQAIOHAIC-UHFFFAOYSA-N 2-[1-[1-[1-(oxiran-2-ylmethoxy)propan-2-yloxy]propan-2-yloxy]propan-2-yloxymethyl]oxirane Chemical compound C1OC1COC(C)COC(C)COC(C)COCC1CO1 FVCHRIQAIOHAIC-UHFFFAOYSA-N 0.000 description 1
- FIQBJLHOPOSODG-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxycarbonyl]benzoic acid Chemical compound CC(=C)C(=O)OCCOC(=O)C1=CC=CC=C1C(O)=O FIQBJLHOPOSODG-UHFFFAOYSA-N 0.000 description 1
- PUGPJMKMJBWZBC-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxycarbonyl]cyclohex-3-ene-1-carboxylic acid Chemical compound CC(=C)C(=O)OCCOC(=O)C1C=CCCC1C(O)=O PUGPJMKMJBWZBC-UHFFFAOYSA-N 0.000 description 1
- GWFCWZQFUSJPRE-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxycarbonyl]cyclohexane-1-carboxylic acid Chemical compound CC(=C)C(=O)OCCOC(=O)C1CCCCC1C(O)=O GWFCWZQFUSJPRE-UHFFFAOYSA-N 0.000 description 1
- VSRMIIBCXRHPCC-UHFFFAOYSA-N 2-[2-[2-[2-[2-(oxiran-2-ylmethoxy)ethoxy]ethoxy]ethoxy]ethoxymethyl]oxirane Chemical class C1OC1COCCOCCOCCOCCOCC1CO1 VSRMIIBCXRHPCC-UHFFFAOYSA-N 0.000 description 1
- HJUYCLIQJYAIKG-UHFFFAOYSA-N 2-[3-(2-methylprop-2-enoyloxy)propoxycarbonyl]benzoic acid Chemical compound CC(=C)C(=O)OCCCOC(=O)C1=CC=CC=C1C(O)=O HJUYCLIQJYAIKG-UHFFFAOYSA-N 0.000 description 1
- YMFWPQPFCWTQAN-UHFFFAOYSA-N 2-[3-(2-methylprop-2-enoyloxy)propoxycarbonyl]cyclohexane-1-carboxylic acid Chemical compound CC(=C)C(=O)OCCCOC(=O)C1CCCCC1C(O)=O YMFWPQPFCWTQAN-UHFFFAOYSA-N 0.000 description 1
- WTYYGFLRBWMFRY-UHFFFAOYSA-N 2-[6-(oxiran-2-ylmethoxy)hexoxymethyl]oxirane Chemical compound C1OC1COCCCCCCOCC1CO1 WTYYGFLRBWMFRY-UHFFFAOYSA-N 0.000 description 1
- KUAUJXBLDYVELT-UHFFFAOYSA-N 2-[[2,2-dimethyl-3-(oxiran-2-ylmethoxy)propoxy]methyl]oxirane Chemical compound C1OC1COCC(C)(C)COCC1CO1 KUAUJXBLDYVELT-UHFFFAOYSA-N 0.000 description 1
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- UPZFLZYXYGBAPL-UHFFFAOYSA-N 2-ethyl-2-methyl-1,3-dioxolane Chemical compound CCC1(C)OCCO1 UPZFLZYXYGBAPL-UHFFFAOYSA-N 0.000 description 1
- CYVMBANVYOZFIG-UHFFFAOYSA-N 2-ethylbutane-1,4-diol Chemical compound CCC(CO)CCO CYVMBANVYOZFIG-UHFFFAOYSA-N 0.000 description 1
- ZJVMHPVIAUKERS-UHFFFAOYSA-N 2-hexylbutanedioic acid Chemical compound CCCCCCC(C(O)=O)CC(O)=O ZJVMHPVIAUKERS-UHFFFAOYSA-N 0.000 description 1
- DIVXVZXROTWKIH-UHFFFAOYSA-N 2-hydroxy-1,2-diphenylpropan-1-one Chemical compound C=1C=CC=CC=1C(O)(C)C(=O)C1=CC=CC=C1 DIVXVZXROTWKIH-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 description 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 description 1
- VFZKVQVQOMDJEG-UHFFFAOYSA-N 2-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(=O)C=C VFZKVQVQOMDJEG-UHFFFAOYSA-N 0.000 description 1
- WZHHYIOUKQNLQM-UHFFFAOYSA-N 3,4,5,6-tetrachlorophthalic acid Chemical compound OC(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C(O)=O WZHHYIOUKQNLQM-UHFFFAOYSA-N 0.000 description 1
- BUZICZZQJDLXJN-UHFFFAOYSA-N 3-azaniumyl-4-hydroxybutanoate Chemical compound OCC(N)CC(O)=O BUZICZZQJDLXJN-UHFFFAOYSA-N 0.000 description 1
- AERZMMNNWVZSNB-UHFFFAOYSA-N 3-dodec-1-ynyloxolane-2,5-dione Chemical compound CCCCCCCCCCC#CC1CC(=O)OC1=O AERZMMNNWVZSNB-UHFFFAOYSA-N 0.000 description 1
- WOHXXIWTEHLCQK-UHFFFAOYSA-N 3-methylpentane-1,4-diol Chemical compound CC(O)C(C)CCO WOHXXIWTEHLCQK-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- RZJKZTPKSRPUFJ-UHFFFAOYSA-N 5,5-dimethyl-1,3-bis(oxiran-2-ylmethyl)imidazolidine-2,4-dione Chemical compound O=C1N(CC2OC2)C(=O)C(C)(C)N1CC1CO1 RZJKZTPKSRPUFJ-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- PHJSGFJLYCTAIY-UHFFFAOYSA-N C(C=O)(=O)OCCOCCCC Chemical compound C(C=O)(=O)OCCOCCCC PHJSGFJLYCTAIY-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- AUNGANRZJHBGPY-UHFFFAOYSA-N D-Lyxoflavin Natural products OCC(O)C(O)C(O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical group CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- TXXHDPDFNKHHGW-CCAGOZQPSA-N Muconic acid Natural products OC(=O)\C=C/C=C\C(O)=O TXXHDPDFNKHHGW-CCAGOZQPSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 244000028419 Styrax benzoin Species 0.000 description 1
- 235000000126 Styrax benzoin Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 235000008411 Sumatra benzointree Nutrition 0.000 description 1
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 1
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 1
- 108010076830 Thionins Proteins 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- UMILHIMHKXVDGH-UHFFFAOYSA-N Triethylene glycol diglycidyl ether Chemical class C1OC1COCCOCCOCCOCC1CO1 UMILHIMHKXVDGH-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- RVWADWOERKNWRY-UHFFFAOYSA-N [2-(dimethylamino)phenyl]-phenylmethanone Chemical compound CN(C)C1=CC=CC=C1C(=O)C1=CC=CC=C1 RVWADWOERKNWRY-UHFFFAOYSA-N 0.000 description 1
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
- HSZUHSXXAOWGQY-UHFFFAOYSA-N [2-methyl-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(C)(COC(=O)C=C)COC(=O)C=C HSZUHSXXAOWGQY-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 229940091181 aconitic acid Drugs 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229940072049 amyl acetate Drugs 0.000 description 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 230000000181 anti-adherent effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- POJOORKDYOPQLS-UHFFFAOYSA-L barium(2+) 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O POJOORKDYOPQLS-UHFFFAOYSA-L 0.000 description 1
- YBGQXNZTVFEKEN-UHFFFAOYSA-N benzene-1,2-disulfonyl chloride Chemical compound ClS(=O)(=O)C1=CC=CC=C1S(Cl)(=O)=O YBGQXNZTVFEKEN-UHFFFAOYSA-N 0.000 description 1
- 229960002130 benzoin Drugs 0.000 description 1
- JRPRCOLKIYRSNH-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) benzene-1,2-dicarboxylate Chemical compound C=1C=CC=C(C(=O)OCC2OC2)C=1C(=O)OCC1CO1 JRPRCOLKIYRSNH-UHFFFAOYSA-N 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- FGKXKAATQIZYLU-UHFFFAOYSA-N butyl 2-oxo-2-phenylacetate Chemical compound CCCCOC(=O)C(=O)C1=CC=CC=C1 FGKXKAATQIZYLU-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- JNGZXGGOCLZBFB-IVCQMTBJSA-N compound E Chemical compound N([C@@H](C)C(=O)N[C@@H]1C(N(C)C2=CC=CC=C2C(C=2C=CC=CC=2)=N1)=O)C(=O)CC1=CC(F)=CC(F)=C1 JNGZXGGOCLZBFB-IVCQMTBJSA-N 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- KQWGXHWJMSMDJJ-UHFFFAOYSA-N cyclohexyl isocyanate Chemical compound O=C=NC1CCCCC1 KQWGXHWJMSMDJJ-UHFFFAOYSA-N 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 125000005594 diketone group Chemical group 0.000 description 1
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- YQGOJNYOYNNSMM-UHFFFAOYSA-N eosin Chemical compound [Na+].OC(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C(O)=C(Br)C=C21 YQGOJNYOYNNSMM-UHFFFAOYSA-N 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- QKLCQKPAECHXCQ-UHFFFAOYSA-N ethyl phenylglyoxylate Chemical compound CCOC(=O)C(=O)C1=CC=CC=C1 QKLCQKPAECHXCQ-UHFFFAOYSA-N 0.000 description 1
- 229960005237 etoglucid Drugs 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 description 1
- PTCGDEVVHUXTMP-UHFFFAOYSA-N flutolanil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C(F)(F)F)=C1 PTCGDEVVHUXTMP-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 1
- 229940035429 isobutyl alcohol Drugs 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000010187 litholrubine BK Nutrition 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- AYLRODJJLADBOB-QMMMGPOBSA-N methyl (2s)-2,6-diisocyanatohexanoate Chemical compound COC(=O)[C@@H](N=C=O)CCCCN=C=O AYLRODJJLADBOB-QMMMGPOBSA-N 0.000 description 1
- YLHXLHGIAMFFBU-UHFFFAOYSA-N methyl phenylglyoxalate Chemical compound COC(=O)C(=O)C1=CC=CC=C1 YLHXLHGIAMFFBU-UHFFFAOYSA-N 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- JAYXSROKFZAHRQ-UHFFFAOYSA-N n,n-bis(oxiran-2-ylmethyl)aniline Chemical compound C1OC1CN(C=1C=CC=CC=1)CC1CO1 JAYXSROKFZAHRQ-UHFFFAOYSA-N 0.000 description 1
- ICXMVMOJRRHROE-UHFFFAOYSA-N n-benzyl-1-(oxiran-2-yl)-n-(oxiran-2-ylmethyl)methanamine Chemical compound C1OC1CN(CC=1C=CC=CC=1)CC1CO1 ICXMVMOJRRHROE-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- DASJFYAPNPUBGG-UHFFFAOYSA-N naphthalene-1-sulfonyl chloride Chemical compound C1=CC=C2C(S(=O)(=O)Cl)=CC=CC2=C1 DASJFYAPNPUBGG-UHFFFAOYSA-N 0.000 description 1
- OPECTNGATDYLSS-UHFFFAOYSA-N naphthalene-2-sulfonyl chloride Chemical compound C1=CC=CC2=CC(S(=O)(=O)Cl)=CC=C21 OPECTNGATDYLSS-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- AFEQENGXSMURHA-UHFFFAOYSA-N oxiran-2-ylmethanamine Chemical class NCC1CO1 AFEQENGXSMURHA-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- WIDYZOXBOLTJJB-UHFFFAOYSA-N phenyl 2-oxo-2-phenylacetate Chemical class C=1C=CC=CC=1C(=O)C(=O)OC1=CC=CC=C1 WIDYZOXBOLTJJB-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- DWYFUJJWTRPARQ-UHFFFAOYSA-N phenyl(thiophen-2-yl)methanone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CS1 DWYFUJJWTRPARQ-UHFFFAOYSA-N 0.000 description 1
- FSDNTQSJGHSJBG-UHFFFAOYSA-N piperidine-4-carbonitrile Chemical compound N#CC1CCNCC1 FSDNTQSJGHSJBG-UHFFFAOYSA-N 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Chemical class 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- KRIOVPPHQSLHCZ-UHFFFAOYSA-N propiophenone Chemical compound CCC(=O)C1=CC=CC=C1 KRIOVPPHQSLHCZ-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 238000007342 radical addition reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 239000002151 riboflavin Substances 0.000 description 1
- 235000019192 riboflavin Nutrition 0.000 description 1
- 229960002477 riboflavin Drugs 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- YHGNXQAFNHCBTK-OWOJBTEDSA-N trans-3-hexenedioic acid Chemical compound OC(=O)C\C=C\CC(O)=O YHGNXQAFNHCBTK-OWOJBTEDSA-N 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- NIUZJTWSUGSWJI-UHFFFAOYSA-M triethyl(methyl)azanium;chloride Chemical compound [Cl-].CC[N+](C)(CC)CC NIUZJTWSUGSWJI-UHFFFAOYSA-M 0.000 description 1
- ILWRPSCZWQJDMK-UHFFFAOYSA-N triethylazanium;chloride Chemical compound Cl.CCN(CC)CC ILWRPSCZWQJDMK-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Description
æ¬çºæã¯ããªãªã¬ãã€ã³ç³»æš¹èã®è¡šé¢ã«å¡è£
ãããŸãã¯å°å·ããã®ã«é©ãã玫å€ç·ç¡¬åå被èŠ
çµæç©ã«é¢ããã ããªãªã¬ãã€ã³ãããšãã°ããªãšãã¬ã³ïŒããª
ãããã¬ã³çã¯ç¡æ¥µæ§ã§ãã€çµæ¶æ§ã§ããè¬åïŒ
溶å€ãªã©ã«å¯ŸããŠã極ããŠå®å®ã§ããããéåžžã®
被èŠçµæç©ã§ã¯ä»çããå¡è£ ïŒå°å·ãå°é£ã§ã
ãããã®ããåŸæ¥ããããªãªã¬ãã€ã³æš¹èè¡šé¢ãž
ã®è¢«èŠçµæç©ã®ä»çæ§ãæ¹è¯ããããã«äŸãã°ç«
çåŠçæ³ïŒã³ããæŸé»ïŒé åå€åŠçæ³ïŒãµã³ãã
ã©ã¹ãæ³ïŒæŸå°ç·åŠçæ³ãªã©ã®ååŠçãè¡ãªãã
ãŠãããããããææ³ã¯è¢«å¡ç©ã®åœ¢ç¶ã«ãã€ãŠã¯
é©çšãå°é£ã§ãããåäžãªè¡šé¢åŠçãåŸããã«ã
ããä»çæ§ãååã«æºè¶³ã§ãããã®ã§ã¯ãªããäž
æ¹ãæè¿ãããã®ååŠçãªãã«ããªãªã¬ãã€ã³ã«
ä»çæ§ã®ãã被èŠçµæç©ãåŸãããšã«ã€ããŠã®è©Š
ã¿ããªãããç³æ²¹ç³»æš¹èãšç°åãŽã ãããªãçµæ
ç©ãšããå€æ§ã¢ã«ãããæš¹èïŒã¢ã¯ãªã«æš¹èïŒãš
ãã¬ã³âé ¢é žããã«å ±éåæš¹èçãšå¡©çŽ åãªã¬ã
ã€ã³æš¹èãšãããªãçµæç©ãææ¡ããããããã
ãã¯ä»çæ§ã¯è¯å¥œã§ããããè¡šé¢ç¡¬åºŠãååã§ãª
ãããã®ããèæ²¹æ§ïŒè溶å€æ§ãã»ãšãã©ãªãã
ãå®çšçã«å€§ããªå¶çŽãåããäžå¡ãå¡æãšããŠ
äžéšçšããããŠããã«ãããªããããªãªã¬ãã€ã³
系暹èã«å¯ŸããŠä»çæ§ãæãããã€è¯å¥œãªå¡è硬
床ãèæ²¹æ§ãè溶å€æ§ãèè¬åæ§ãå Œåãã被èŠ
çµæç©ãåŸãããã«ã¯ãå¡©çŽ åãªã¬ãã€ã³ïŒç°å
ãŽã ãäž»æåãšããæš¹èçµæç©äžã«æ¶æ©æåãå°
å ¥ããæ¹æ³ãèããããããäžè¬ã«ããªã€ãœã·ã¢
ããŒãååç©ãã¡ã©ãã³æš¹èïŒãšããã·æš¹èãªã©
ã®æ¶æ©æ§ãæããæ¢ç¥ã®ååç©ã¯å¡©çŽ åãªã¬ãã€
ã³ãç°åãŽã ãšã®çžæº¶æ§ãæªã被èŠçµæç©ãšããŠ
ã¯äžé©åœã§ãããåæ²¹å€æ§ã¢ã«ãããæš¹èããã€
ã«åããªãã¿ãžãšã³ã®ãããªé žåéååã®æš¹èæ
åã¯ãå¡©çŽ åãªã¬ãã€ã³ãšçžæº¶ã¯ãããããªãªã¬
ãã€ã³ã®å€åœ¢ãããããªã枩床ç¯å²ã§ã¯ååãªæ¶
æ©å¹æãæåŸ ã§ãã奜ãŸãããªããããã§ãããª
ãªã¬ãã€ã³ãå€åœ¢ããããšãªãã«å®¹æã«æ¶æ©å¡è
ãåŸãæ¹æ³ãšããŠã¯çŽ«å€ç·ç¡¬ååçµæç©ãèãã
ããããäžè¬ã«çŸåšå®çšåãããŠãããã®ã¯ãã
ãªãªã¬ãã€ã³ã«å¯ŸããŠãŸã€ããä»çæ§ããªããã
ããæ¹è¯ããããã«ãã®çŽ«å€ç·ç¡¬ååçµæç©ã«å¡©
çŽ åããªãªã¬ãã€ã³ãå°å ¥ãä»çæ§ãåºãããšã
è©Šã¿ãããããäžè¬ã«çŽ«å€ç·ç¡¬ååçµæç©ãšå¡©çŽ
åããªãªã¬ãã€ã³ãšã¯çžæº¶æ§ãæªãããã被èŠçµ
æç©ãšããŠå®çšã«äŸããããã®ã¯åŸãããŠããª
ãã æ¬çºæè ãã¯äžèšç¶æ³ã«éã¿ãæªåŠçã®ããªãª
ã¬ãã€ã³ãšã®ä»çæ§ãè¯ãããã®ããåžžæž©çæé
ã§æ¶æ©ç¡¬åããè¡šé¢ç¡¬åºŠïŒèæ²¹æ§ïŒè溶å€æ§ïŒè
è¬åæ§ã®è¯å¥œãªå¡èãæäŸãã被èŠçµæç©ã«ã€ã
ãŠéææ€èšãéããçµæãæ¬çºæãå®æããã æ¬çºæ㯠(A) ïŒååäžã«ãšãã¬ã³æ§äžé£œåäºéçµåãïŒå
以äžæããååç© 10ã80ééïŒ (B) å¡©çŽ åããªãªã¬ãã€ã³ç³»æš¹è ïŒã80ééïŒ (C) ã¡ã¿ã¯ãªã«é žã€ãœããã«åäœã50ééïŒ ä»¥äž
ããã³æ¬¡åŒãã ïŒR1ã¯ïŒšåã¯CH3ïŒR2ã¯ïŒšåã¯CH3ïŒã§è¡š
ããããåäœãïŒã40ééïŒ å«ãã¢ã¯ãªã«ç³»æš¹
è 10ã70ééïŒ ãäž»æåãšããå éåéå§å€å«æããªãªã¬ãã€ã³
系暹èçšçŽ«å€ç·ç¡¬åå被èŠçµæç©ã§ããã æ¬çºæã®ç¹åŸŽã¯åžžæž©ïŒçæéã§ç¡¬åãã玫å€ç·
硬åå被èŠçµæç©ã«ãããªãªã¬ãã€ã³ã«ä»çæ§ã
æããå¡©çŽ åããªãªã¬ãã€ã³ãå°å ¥ããã«ãã
ããäž¡è éã®çžæº¶æ§äžè¯ãæ¹è¯ããããäž¡è ãšçž
溶æ§ã®ããã¡ã¿ã¯ãªã«é žã€ãœããã«ãšæ°Žé žåºãæ
ããã¢ã¯ãªã«ã¢ãããŒãšãå ±éåããã¢ã¯ãªã«æš¹
èã第äžæåãšããŠå°å ¥ããããšã«ããã æ¬çºæã®(A)æåã§ãããïŒååäžã«ãšãã¬ã³ç³»
äžé£œåäºéçµåãïŒå以äžæããååç©ãšã¯åå
äžã«ïŒå以äžã®ãšãã¬ã³ç³»äžé£œåãå«ã¿ããã€å
åŠç·ã§ç §å°ãããšãå éåéå§å€ãšã®çžäºäœçšã«
ãã€ãŠããªãŒã©ãžã«ã«ã«ããä»å éåãè¡ãªãèœ
åãããååç©ãæå³ãããå ·äœçã«ã¯è€æ°ã®ãš
ãã¬ã³ç³»äžé£œåãå«ãäžé£œåããªãšã¹ãã«ïŒè€æ°
ã®ã¢ã¯ãªã«ç³»äžé£œåãæããååç©ãªã©ãããã
ããã æ¬çºæã«çšãåŸãäžé£œåããªãšã¹ãã«ã¯ãéåžž
ãšãã¬ã³ç³»äžé£œåããªã«ã«ãã³é žãšå€äŸ¡ã¢ã«ã³ãŒ
ã«ãšã®ãšã¹ãã«åçæç©ã§ãããäžè¬ã«ãšãã¬ã³
ç³»äžé£œåã¯Î±ïŒÎ²äœã«ããããšãã¬ã³ç³»äžé£œåã
ãªã«ã«ãã³é žãšããŠã¯ãã¬ã€ã³é žïŒããã«é žïŒã¢
ã³ãããé žïŒã€ã¿ã³ã³é žïŒã·ãã©ã³ã³é žïŒã¡ãµã³
ã³é žïŒã ã³ã³é žããã³ãžãããã ã³ã³é žãªãã³ã«
ãããé žã®ããããã³ã¢ã«ãã«èªå°äœãå«ãŸãã
ããã¬ã€ã³é žããã³ããã«é žãç¹ã«å¥œãŸããããš
ãã¬ã³ç³»äžé£œåããªã«ã«ãã³é žã¯åç¬ã§ããæ··å
ç©ãšããŠäœ¿çšããŠããããŸãããããã®é žã®ç¡æ°Ž
ç©ãåæ§ã«äœ¿çšããããäžé£œåããªãšã¹ãã«ã®è£œ
é ã«éããŠã¯ãšãã¬ã³ç³»äžé£œåããªã«ã«ãã³é žãš
çµåãããŠãç®çã«å¿ããïŒçš®ä»¥äžã®é£œåããªã«
ã«ãã³é žãé«æ䜿çšããããšãã§ãããæçšãªé£œ
åããªã«ã«ãã³é žã®äŸãšããŠã¯ã·ãŠãŠé žïŒã³ãã¯
é žïŒããã³é žïŒã¡ãã«ã³ãã¯é žïŒ2.2âãžã¡ãã«
ã³ãã¯é žïŒ2.3âãžã¡ãã«ã³ãã¯é žïŒããã·ã«ã³
ãã¯é žïŒã°ã«ã¿ã«é žïŒïŒâã¡ãã«ã°ã«ã¿ã«é žïŒïŒ
âã¡ãã«ã°ã«ã¿ã«é žïŒ2.2âãžã¡ãã«ã°ã«ã¿ã«é žïŒ
3.3âãžã¡ãã«ã°ã«ã¿ã«é žïŒ3.3âãžãšãã«ã°ã«ã¿
ã«é žïŒã¢ãžãã³é žïŒãã¡ãªã³é žïŒã¹ããªã³é žïŒã¢
ãŒã©ã€ã³é žïŒã»ãã·ã³é žïŒãã¿ã«é žïŒã€ãœãã¿ã«
é žïŒãã¬ãã¿ã«é žïŒããã©ã¯ãã«ãã¿ã«é žïŒ1.2
âãããµããããã¿ã«é žïŒ1.3âãããµãããã
ã¿ã«é žïŒ1.4âãããµããããã¿ã«é žïŒ1.1âã·ã¯
ããã¿ã³ãžã«ã«ãã³é žããã³ãã©ã³ã¹â1.4âã·
ã¯ããããµãžã«ã«ãã³é žãå«ãŸããããããã®é ž
ã®ç¡æ°Žç©ãåæ§ã«äœ¿çšãããã ãšãã¬ã³ç³»äžé£œåããªãšã¹ãã«ã®è£œé ã«æçšãª
å€äŸ¡ã¢ã«ã³ãŒã«ã«ã¯ããšãã¬ã³ã°ãªã³ãŒã«ïŒ1.3
âãããã³ãžãªãŒã«ïŒãããã¬ã³ã°ãªã³ãŒã«ïŒ
2.3âãã¿ã³ãžãªãŒã«ïŒ1.4âãã¿ã³ãžãªãŒã«ïŒïŒ
âãšãã«ãã¿ã³1.4âãžãªãŒã«ïŒ1.5âãã³ã¿ã³ãž
ãªãŒã«ïŒ1.6âãããµã³ãžãªãŒã«ïŒ1.7âããã¿ã³
ãžãªãŒã«ïŒ1.8âãªã¯ã¿ã³ãžãªãŒã«ïŒ1.9âããã³
ãžãªãŒã«ïŒ1.10âãã«ã³ãžãªãŒã«ïŒ2.2âãžãšã
ã«ãããã³â1.3âãžãªãŒã«ïŒ2.2âãžã¡ãã«ãã
ãã³â1.3âãžãªãŒã«ïŒïŒâã¡ãã«ãã³ã¿ã³â1.4
âãžãªãŒã«ïŒ2.2âãžãšãã«ãã¿ã³â1.3âãžãªãŒ
ã«ïŒ4.5âããã³ãžãªãŒã«ïŒãžãšãã¬ã³ã°ãªã³ãŒ
ã«ïŒããªãšãã¬ã³ã°ãªã³ãŒã«ïŒãžãããã¬ã³ã°ãª
ã³ãŒã«ïŒã°ãªã»ãªã³ïŒãã³ã¿ãšãªããªããïŒãšãª
ããªããïŒãœã«ãããïŒãã³ãããïŒ1.1.1âã
ãªã¡ãããŒã«ãããã³ïŒããªã¡ãããŒã«ãšã¿ã³ïŒ
ããã³2.2âãžã¡ãã«âïŒâããããã·ããããª
ã³é ž2.2âãžã¡ãã«âïŒâããããã·ãããã«ãª
ã©ãå«ãŸããã äžé£œåããªãšã¹ãã«ãšåæ§ã«ããäžã€ã®æçšãª
(A)æåã¯è€æ°ã®ã¢ã¯ãªã«ç³»äžé£œåãæããååç©
ã§ãå ·äœçã«ã¯äžèšã®ãã®ããããããšãã§ã
ãã (a) åŒããããã³ããã§ç€ºãããã¢ã¯ãªã«ç³»
ããªãšã¹ãã«ããã³ã¢ã¯ãªã«ç³»ããªã¢ããã§å¥œ
ãŸããã¯åŒäžã®ãã¹ãŠã®ïŒ¡ãé žçŽ ã§ãããã®ã ïŒäžèšåŒããã³äžãïœã¯ïŒãïŒã®æŽæ°ã§
ãããåã¯ããããç¬ç«ã«ïŒã10åã®ççŽ å
åãæããïŒäŸ¡ã®èèªæïŒã·ã¯ãèèªæãŸãã¯
è³éŠæçåæ°ŽçŽ åºã瀺ããåRâ²ã¯ããããç¬
ç«ã«æ°ŽçŽ ïŒã¡ãã«ãŸãã¯ãšãã«ã瀺ããåã¯
ããããç¬ç«ã«é žçŽ ãŸãã¯NHã瀺ãïŒ åŒããã§ç€ºãããããªãšã¹ãã«ããã³ããª
ã¢ãããªãªãŽããŒã¯ãžã«ã«ãã³é žãŸãã¯é žã¢ã
ããšïŒäŸ¡ã¢ã«ã³ãŒã«ãŸãã¯ãžã¢ãã³ãšãåå¿ã
ãã次ã«çæç©ãã¢ã¯ãªã«é žãŸãã¯Î±â眮æã¢
ã¯ãªã«é žãšåå¿ãããããšã«ãã€ãŠè£œé ããã
ãšãã§ãããåŒããã§ç€ºãããã¢ã¯ãªã«ç³»ã
ãªãšã¹ãã«ããã³ããªã¢ãããªãªãŽããŒã¯ãã
ããã·å®èœæ§ã¢ãã«ã«ãã³é žãŸãã¯ãããé žã®
ïŒéäœïŒïŒéäœãŸãã¯ïŒéäœãã¢ããå®èœæ§ã¢
ãã«ã«ãã³é žãŸãã¯ãããé žã®ïŒéäœïŒïŒéäœ
ãŸãã¯ïŒéäœãšã¢ã¯ãªã«é žãŸãã¯Î±â眮æã¢ã¯
ãªã«é žãšãåå¿ãããŠè£œé ããããšãã§ããã (b) ïŒååäžã«ïŒå以äžã®ãšããã·åºãæããå
åç©ã«ã«ã«ããã·ã«åºãæããéåæ§åéäœã
éç°ãšã¹ãã«ååå¿ã«ãã€ãŠä»å ãããŠè£œé ã
ããšããã·å€æ§ã¢ã¯ãªã«ãªãªãŽããŒãå ·äœçã«
ã¯ïŒååäžã«ïŒå以äžã®ãšããã·åºãæããå
åç©ãäŸãã°ãšãã¬ã³ã°ãªã³ãŒã«ãžã°ãªã·ãžã«
ãšãŒãã«ïŒããªãšãã¬ã³ã°ãªã³ãŒã«ãžã°ãªã·ãž
ã«ãšãŒãã«ïŒããã©ãšãã¬ã³ã°ãªã³ãŒã«ãžã°ãª
ã·ãžã«ãšãŒãã«ãªã©ã®ããªãšãã¬ã³ã°ãªã³ãŒã«
èªå°äœããããã¬ã³ã°ãªã³ãŒã«ãžã°ãªã·ãžã«ãš
ãŒãã«ïŒããªãããã¬ã³ã°ãªã³ãŒã«ãžã°ãªã·ãž
ã«ãšãŒãã«ãªã©ã®ããªãããã¬ã³ã°ãªã³ãŒã«èª
å°äœãããªãã³ãã«ã°ãªã³ãŒã«ãžã°ãªã·ãžã«ãš
ãŒãã«ïŒ1.6âãããµã³ãžãªãŒã«ãžã°ãªã·ãžã«
ãšãŒãã«ïŒã°ãªã»ãªã³ããªã°ãªã·ãžã«ãšãŒãã«
ãªã©ã®èèªæèªå°äœãæ°Žæ·»ãã¹ããšããŒã«ïŒ¡ãž
ã°ãªã·ãžã«ãšãŒãã«ïŒã·ã¯ããããµã³ãžãªãŒã«
ãžã°ãªã·ãžã«ãšãŒãã«ãªã©ã®èç°åã°ãªã·ãžã«
èªå°äœããžã°ãªã·ãžã«ã¢ããªã³ïŒãžã°ãªã·ãžã«
ãã³ãžã«ã¢ãã³ïŒ1.3ãžã°ãªã·ãžã«â5.5ãžã¡ã
ã«ããã³ãã€ã³ãªã©ã®ã°ãªã·ãžã«ã¢ãã³èªå°
äœããã¹ããšããŒã«ïŒ¡ãšãšãã¯ãã«ãããªã³ãŸ
ãã¯ã¡ãã«ãšãã¯ãã«ãããªã³ãšã®çž®åçæç©
ã§äŸãã°ãšãã³562ïŒãšãã³828ïŒãšãã³834ïŒ
ãšãã³864ïŒãšãã³1001ïŒãšãã³1004ïŒä»¥äžã·ãš
ã«ååŠç€Ÿè£œïŒçãšããŠåžè²©ãããŠãããã®ç
ãšãã«ã«ããã·ã«åºãæããéåæ§åéäœãäŸ
ãã°ã¢ã¯ãªã«é žïŒã¡ã¿ã¯ãªã«é žïŒã¯ããã³é žïŒ
ãã¿ã«é žã¢ãã¡ã¿ã¯ãªããã·ãšãã«ïŒãã¿ã«é ž
ã¢ãã¢ã¯ãªããã·ãããã«ïŒãã¿ã«é žã¢ãã¡ã¿
ã¯ãªããã·ãããã«ïŒããã©ããããã¿ã«é žã¢
ãã¢ã¯ãªããã·ãšãã«ïŒããã©ããããã¿ã«é ž
ã¢ãã¡ã¿ã¯ãªããã·ãšãã«ïŒããã©ããããã¿
ã«é žã¢ãã¡ã¿ã¯ãªããã·ãããã«ïŒããã©ãã
ããã¿ã«é žã¢ãã¢ã¯ãªããã·ãããã«ïŒããã©
ããããã¿ã«é žã¢ãã¡ã¿ã¯ãªããã·ãããã«ïŒ
ãããµããããã¿ã«é žã¢ãã¢ã¯ãªããã·ãšã
ã«ïŒãããµããããã¿ã«é žã¢ãã¡ã¿ã¯ãªããã·
ãšãã«ïŒãããµããããã¿ã«é žã¢ãã¢ã¯ãªãã
ã·ãããã«ïŒãããµããããã¿ã«é žã¢ãã¡ã¿ã¯
ãªããã·ãããã«çãšãåå¿ãããããšã«ãã€
ãŠè£œé ãããååç©ã (c) ããªã€ãœã·ã¢ããŒãååç©ãšãæ°Žé žåºãæã
ãã¢ã¯ãªã«åéäœãšã®ä»å ç©ãïŒå以äžã®æ°Žé ž
åºãæããååç©ã«ãŠã¬ã¿ã³ååå¿ã«ãã€ãŠä»
å ãããŠè£œé ã§ãããŠã¬ã¿ã³å€æ§ã¢ã¯ãªã«ãªãª
ãŽããŒããã®è£œé ã«çšããåæã®ããªã€ãœã·ã¢
ããŒãååç©ãšããŠã¯äŸãã°ããªã¬ã³ãžã€ãœã·
ã¢ããŒãïŒ4.4â²âãžããšãã«ã¡ã¿ã³ãžã€ãœã·ã¢
ããŒãïŒãã·ãªã¬ã³ãžã€ãœã·ã¢ããŒãïŒãããµ
ã¡ãã¬ã³ãžã€ãœã·ã¢ããŒãïŒãªãžã³ãžã€ãœã·ã¢
ããŒãïŒ4.4â²âã¡ãã¬ã³ãã¹ïŒã·ã¯ãããã·ã«
ã€ãœã·ã¢ããŒãïŒïŒã¡ãã«ã·ã¯ããããµã³2.4
ïŒãŸãã¯2.6ïŒãžã€ãœã·ã¢ããŒãïŒ1.3âïŒã€ãœ
ã·ã¢ããŒãã¡ãã«ïŒã·ã¯ããããµã³ïŒã€ãœãã
ã³ãžã€ãœã·ã¢ããŒãïŒããªã¡ãã«ãããµã¡ãã¬
ã³ãžã€ãœã·ã¢ããŒãïŒãã€ããŒé žãžã€ãœã·ã¢ã
ãŒãçãå«ãŸãããæ°Žé žåºãæããã¢ã¯ãªã«å
éäœã«ã¯ïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâããããã·ãš
ãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâããããã·ãã
ãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâããããã·ïŒâ
ã¡ããã·ãããã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâã
ãããã·ïŒâãããã·ãããã«ïŒïŒã¡ã¿ïŒã¢ã¯
ãªã«é žïŒâããããã·âïŒâïŒïŒâãšãã«ãã
ã·ã«ãªãã·ïŒãããã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒ
âããããã·âïŒâããšãã«ãªãã·ãããã«ç
ãå«ãŸãããïŒå以äžã®æ°Žé žåºãæããååç©
ãšããŠã¯ããªãã³ãã«ã°ãªã³ãŒã«ïŒ2.2.4âã
ãªã¡ãã«â1.3âãã³ã¿ã³ãžãªãŒã«ïŒ1.6âãã
ãµã³ãžãªãŒã«ïŒããªãšãã¬ã³ã°ãªã³ãŒã«ïŒæ°ŽçŽ
æ·»å ãã¹ããšããŒã«ïŒ¡ïŒããªã«ããã©ã¯ãã³ãž
ãªãŒã«ïŒããªããã©ã¡ãã¬ã³ã°ãªã³ãŒã«ïŒãšã¹
ãã«ãžãªãŒã«204ïŒäžè¬åŒããïŒããã§è¡šã
ããããžãªãŒã«ïŒ ïŒåŒäžãïœïŒmâ²ã¯ïŒãïŒã®æŽæ°ãïœïŒnâ²ã¯ïŒ
ãŸãã¯ïŒã瀺ãïŒ ïŒåŒäžãïœïŒmâ²ã¯ïŒãïŒã®æŽæ°ãïœïŒnâ²ã¯ïŒ
ãŸãã¯ïŒã瀺ãïŒ äžè¬åŒããã§è¡šããããããªãšã¹ãã«ãžãªãŒ
ã«ãªã©ãå«ãŸããã HOR1ïŒOOCR2COOR1ïŒnOH ãã ãåŒäžãR1ã¯C2ãC10ã®ã¢ã«ãã¬ã³åºãŸãã¯ïŒâ
CH2CHR3OïŒâoïŒR3ã¯ïŒšãŸãã¯CH3ãïœã¯10以
äžã®æŽæ°ïŒãªãåºããR2ã¯C2ãC10ã®ã¢ã«ãã¬
ã³åºããŸãã¯ããšãã«åºãïœã¯ïŒã10ã®æŽæ°ã
æå³ãããã (d) äžè¿°ã®(a)ïŒ(b)ããã³(c)ã«ã¯å±ããªããè€æ°ã®
ã¢ã¯ãªã«ç³»äžé£œåãæãããªãªãŽããŒãããã
ãªãªãŽããŒã®å ·äœäŸãšããŠã¯äžè¬åŒããã§è¡š
ãããããžã¢ã¯ãªã¬ãŒãååç©ïŒ ïŒåŒäžãã¯ïŒšãŸãã¯CH3ãïœïŒïŒã14ã®æŽ
æ°ïŒ ãããã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãïŒ1.3â
ããã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãïŒ1.4âã
ãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãïŒ1.6âãã
ãµã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãïŒããªãã³ãã«
ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãïŒãžãããã¬ã³ã°ãª
ã³ãŒã«ãžã¢ã¯ãªã¬ãŒãïŒ2.2â²âãã¹ïŒïŒâã¢ã¯
ãªããã·ãããããã·ããšãã«ïŒãããã³ïŒ
2.2â²âãã¹ïŒïŒâã¢ã¯ãªããã·ãžãšããã·ããš
ãã«ïŒãããã³ïŒããªã¡ããâã«ãããã³ããª
ã¢ã¯ãªã¬ãŒãïŒããªã¡ãããŒã«ãšã¿ã³ããªã¢ã¯
ãªã¬ãŒãïŒããã©ã¡ãããŒã«ã¡ã¿ã³ããªã¢ã¯ãª
ã¬ãŒãïŒããªã¡ãããŒã«ãããã³ã¢ãã€ã·æ²¹ã¬
ãŒããžã¢ã¯ãªã¬ãŒãïŒããã©ã¡ãããŒã«ã¡ã¿ã³
ããã©ã¢ã¯ãªã¬ãŒãïŒãžãã³ã¿ãšãªã¹ãªããŒã«
ãããµã¢ã¯ãªã¬ãŒãïŒäžè¬åŒãã ïŒåŒäžãR1ã¯ïŒšåã¯CH3ãR2ïŒR3ïŒR4åã³
R5ã¯ããããïŒC1ãC8ã®çœ®æåºãæããã
ã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºåã¯ã¢ãªãŒã«
åºãR6ïŒR7ïŒR8åã³R9ã¯ããããïŒC1ãC8
ã®ã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºåã¯ã¢ãªãŒã«
åºïŒ ã§è¡šããããïŒã¡ã¿ïŒã¢ã¯ãªã«ç³»äžé£œåãæã
ããªãªãŽããŒçãå«ãŸããã æ¬çºæã®(B)æåã®å¡©çŽ åããªãªã¬ãã€ã³ç³»æš¹è
ãšããŠã¯ãå¡©çŽ åããªãšãã¬ã³ïŒå¡©çŽ åããªãã
ãã¬ã³ïŒå¡©çŽ åããªããã³ïŒå¡©çŽ åãšãã¬ã³ãã
ãã¬ã³ã³ããªããŒçãå«ãŸããããåŸããã被èŠ
çµæç©ã®å¡æäœæ¥æ§ãªãã³ã«ç¡¬åå¡èã®ä»çæ§ã
èåæ§ãèæ ®ããéã«ã¯å¡©çŽ å«æéã15ã50éé
ïŒ ã®ãã®ãç¹ã«20ã40ééïŒ ã®äœå¡©çŽ åããªãã
ãã¬ã³ã奜é©ã§ããã æ¬çºæã®(C)æåã®ã¢ã¯ãªã«ç³»æš¹èã¯ã¡ã¿ã¯ãªã«
é žã€ãœããã«ãäž»åæãšããæ°Žé žåºãæããã¢ã¯
ãªã«ç³»åéäœãå«ã¿ãä»ã®å ±éåå¯èœãªåéäœãš
ãå ±éåããŠè£œé ããããã®ã§ãããæ°Žé žåºãæ
ããã¢ã¯ãªã«ç³»åéäœã«ã¯ïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒ
âããããã·ãšãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâã
ãããã·ãããã«ãå«ãŸãããå ±éåå¯èœãªä»ã®
åéäœãšããŠã¯ãäŸãã°ïŒã¡ã¿ïŒã¢ã¯ãªã«é žã¡ã
ã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žãšãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«
é žïœâããã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâãšãã«ã
ãã·ã«çã®ïŒã¡ã¿ïŒã¢ã¯ãªã«é žã¢ã«ãã«é¡ãã¹ã
ã¬ã³ïŒããã«ãã«ãšã³ïŒé ¢é žããã«ïŒããããªã³
é žããã«åã³Î±ïŒÎ²ã¢ããšãã¬ã³ç³»äžé£œåãžã«ã«
ãã³é žã®ãžã¢ã«ãã«ãšã¹ãã«é¡çãå«ãŸããã該
ã¢ã¯ãªã«ç³»æš¹èã¯ã¡ã¿ã¯ãªã«é žã€ãœããã«åäœã
50ééïŒ ä»¥äžå«æãããã€æ°Žé žåºãæããã¢ã¯ãª
ã«ã¢ãããŒåäœãïŒã40ééïŒ å«æããããå ±é
åããŠè£œé ããå¿ èŠããããã¢ã¯ãªã«ç³»æš¹èäžã®
ã¡ã¿ã¯ãªã«é žã€ãœããã«åäœã®å«æéã50ééïŒ
ã«æºããªãã¢ã¯ãªã«ç³»æš¹èã¯å¡©çŽ åããªãªã¬ãã€
ã³æš¹èããšãã«å¡©çŽ å床ã40ééïŒ ä»¥äžã®äœå¡©çŽ
åããªãªã¬ãã€ã³æš¹èãšã®çžæº¶æ§ãæªã奜ãŸãã
ãªãããŸãã¢ã¯ãªã«ç³»æš¹èäžã®æ°Žé žåºãæããã¢
ã¯ãªã«ã¢ãããŒåäœãïŒééïŒ ã«æºããªããšäžé£œ
åããªãšã¹ãã«åã³ã¢ã¯ãªã«ç³»äžé£œåååç©ãªã©
ã®ææ©éåæ§ç©è³ªãšã®çžæº¶æ§ãæªããäžæ¹40éé
ïŒ ãè¶ãããšå¡©çŽ åããªãªã¬ãã€ã³æš¹èãšã®çžæº¶
æ§ãæªããããããææ©éåæ§ç©è³ªãšå¡©çŽ åããª
ãªã¬ãã€ã³æš¹èãšã®çžæº¶æ§ã®æ©æž¡ããããæš¹èãš
ããŠã¯å¥œãŸãããªãã æ¬çºæã«å«æãããå éåéå§å€ã¯ãäž»ã«çŽ«å€
éšã®å ãåžåããŠå±èµ·ããã€ãªã³ãããã¯æŽ»æ§ã©
ãžã«ã«ãçºçããã¢ãããŒãšåå¿ããŠéåãéå§
ããããããããã¯å ã«ããå±èµ·ããããããã¢
ãããŒååãšè¡çªããŠã¢ãããŒã掻æ§åãéåã
éå§ããããããªç©è³ªãã§ããã°ã©ã®ãããªçš®é¡
ã®ãã®ã§ãã€ãŠãããããã®å ·äœäŸãšããŠã¯ãã
ã³ãŸã€ã³ïŒãã³ãŸã€ã³ã¡ãã«ãšãŒãã«ïŒãã³ãŸã€
ã³ãšãã«ãšãŒãã«ïŒãã³ãŸã€ã³ã€ãœãããã«ãšãŒ
ãã«ïŒãã³ãŸã€ã³ã€ãœããã«ãšãŒãã«ïŒÎ±âã¡ã
ã«ãã³ãŸã€ã³çã®ã¢ã·ãã€ã³ãšãã®èªå°äœãïŒâ
ã¡ãã«ã¢ã³ãœã©ããã³ïŒïŒâãšãã«ã¢ã³ãœã©ãã
ã³ïŒã·ã¯ããããµãã³çã®ã«ã«ããã«ååç©ãã
ã³ãžã«ïŒãžã¢ã»ãã«çã®ãžã±ãã³é¡ãã¢ã»ãããš
ãã³ïŒ2.2âãžãšããã·ã¢ã»ãããšãã³ïŒãã³ãŸ
ããšãã³ïŒããããªããšãã³ïŒããšãã«âïŒâã
ãšãã«ã±ãã³ïŒïŒ°âãžã¡ãã«ã¢ãããã³ãŸããšã
ã³ïŒP.Pâ²âããã©ã¡ãã«ãžã¢ãããã³ãŸããšã
ã³ïŒP.Pâ²âããã©ãšãã«ãžã¢ãããã³ãŸããšãã³
çã®ããšãã³é¡ãããšãã«ã°ãªãªãã·ã«é žã¡ã
ã«ïŒããšãã«ã°ãªãªãã·ã«é žãšãã«ïŒããšãã«ã°
ãªãªãã·ã«é žããã«ïŒããšãã«ã°ãªãªãã·ã«é žã
ããã·ãšãã«çã®ããšãã«ã°ãªãªãã·ã«é žãšã¹ã
ã«é¡ããžããšãã«ã¢ããµã«ãã¢ã€ãïŒãžããšãã«
ãžãµã«ãã¢ã€ãïŒãã·ã«ããšãã«ã¢ããµã«ãã¢ã€
ãïŒããã©ã¡ãã«ããŠã©ã ã¢ããµã«ãã¢ã€ãçã®
ææ©ãµã«ãã¢ã€ãé¡ãâãã«ãšã³ã¹ã«ããã«ã¯
ãã©ã€ãïŒïŒâããã¿ã¬ã³ã¹ã«ããã«ã¯ãã©ã€
ãïŒïŒâããã¿ã¬ã³ã¹ã«ããã«ã¯ãã©ã€ãïŒ1.3
âãã³ãŒã³ãžã¹ã«ããã«ã¯ãã©ã€ãïŒ2.4âãžã
ãããã³ãŒã³ã¹ã«ããã«ãããã€ãïŒïŒ°âã¢ã»ã
ã¢ãžããã³ãŒã³ã¹ã«ããã«ã¯ãã©ã€ãçã®ã¹ã«ã
ãã«ãã©ã€ãé¡ãåå¡©åççŽ ïŒåèåççŽ ïŒãã
ãµããã¢ãšã¿ã³ïŒãšãŒããã«ã ïŒ1.1.2.2âããã©
ããã¢ãšã¿ã³çã®ããã²ã³åçåæ°ŽçŽ é¡ããšãªã·
ã³ïŒããªãã³ïŒãã«ãªã¬ã¹ã»ã€ã³ïŒãªããã©ãã³
çã®ææé¡ãªã©ãå«ãŸããã æ¬çºæã®è¢«èŠçšçµæç©ã¯äžè¿°ã®ïŒæåãäž»æå
ãšãããã(A)ïŒ(B)ïŒ(C)åæåã®åèšééäžã«å ã
ãå²åã¯ã(A)æåã10ã80ééïŒ ã§ããã10ïŒ æª
æºã§ã¯å¡èã®æ¶æ©åºŠåãäžååã§è溶å€æ§ãäœ
ããäžæ¹80ïŒ ãè¶ãããšããªãªã¬ãã€ã³ã«å¯Ÿãã
ä»çæ§ãäžè¯ãšãªãã®ã§å¥œãŸãããªãã(B)æåã¯
ïŒã80ééïŒ ã奜é©ã§ãããïŒïŒ æªæºã§ã¯ããªãª
ã¬ãã€ã³ã«å¯Ÿããä»çæ§ãååã§ãªãããŸã80ïŒ
ãè¶ãããšå¡èã®èåæ§ãèæ²¹æ§ãæªåããã®ã§
奜ãŸãããªãã(C)æåã¯10ã70ééïŒ ã奜é©ã§ã
ãã10ïŒ æªæºã§ã¯å¡èã®çžæº¶æ§ãäžååã§ããŸã
70ïŒ ãè¶ãããšããªãªã¬ãã€ã³ã«å¯Ÿããä»çæ§ã
äœäžããã®ã§å¥œãŸãããªããæ¬çºæã®è¢«èŠçµæç©
ã«å«æãããå éåéå§å€ã¯éåžžã被èŠçµæç©ã®
(A)ïŒ(B)ïŒ(C)åæåã®åèšééã«å¯Ÿã0.1ã20éé
ïŒ ã奜ãŸããã¯0.5ã10ééïŒ ã®ç¯å²ã§äœ¿çšãã
ãã æ¬çºæã®è¢«èŠçµæç©äžã«ã¯ãäžè¿°ããåæåã«
å ããåæåãšæ¶æ©çµåããããã«åºãæããä»
å çåéäœãååšããŠãããããããã®äŸãšããŠ
ã¯ïŒ®âããã«âïŒâãããªãã³ïŒã¹ãã¬ã³ïŒÎ±â
ã¡ãã«ã¹ãã¬ã³ïŒããã«ãã«ãšã³ïŒå®æ¯éŠé žãã
ã«ïŒé ¢é žããã«ïŒããããªã³é žããã«çãããã
ããããç¹ã«å¥œãŸãããã®ã¯ã¢ãã¢ã¯ãªã«å®èœæ§
ãæããåéäœã§ãäŸãã°ïŒã¡ã¿ïŒã¢ã¯ãªã«é žã¡
ãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žãšãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãª
ã«é žãããã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žããã«ïŒïŒã¡
ã¿ïŒã¢ã¯ãªã«é žããã·ã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žã
ããã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žã¡ããã·ãšãã«ïŒïŒã¡
ã¿ïŒã¢ã¯ãªã«é žãšããã·ãšãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãª
ã«é žãããã·ãšãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žã¡ãã
ã·ãšããã·ãšãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žãšããã·
ãšããã·ãšãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žããã©ãã
ããã«ããªã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žããããã·ãš
ãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žããããã·ãããã«ïŒ
ïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâãšãã«ããã·ã«ïŒïŒã¡ã¿ïŒ
ã¢ã¯ãªã«é žã·ã¯ãããã·ã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é ž
ãã³ãžã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žãžã·ã¯ããã³ãã
ã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâãžã·ã¯ããã³ããã
ã·ãšãã«çãããããããããã¯åç¬ã§ãŸãã¯äº
皮以äžã®æ··åç©ãšããŠçšããããããããåéäœ
ã¯æš¹èãšæ··åæ§ã®æ¶²ç¶ååç©ã§ããããšãæãŸã
ãã æ¬çºæçµæç©ã«ã¯ä¿åæã«ãããã²ã«åé²æ¢ã®
ããã«éåçŠæ¢å€ãæ·»å ããããšãã§ãããã®ä»£
è¡šçãªäŸãšããŠã¯ãâãã³ãŸããã³ïŒãã€ãã
ããã³ïŒãã€ããããã³ã¢ãã¡ãã«ãšãŒãã«ïŒïŒ°
âtertâããã«ã«ãã³ãŒã«ïŒã¢ãâtertâããã«
ãã€ããããã³ïŒÎ±âããããŒã«ïŒããã¬ããŒã«
çãå«ãŸããã æ¬çºæã®è¢«èŠçµæç©ã«ãéåžžå¡æãŸãã¯å°å·ã€
ã³ãã«äœ¿çšãããé¡æãæ·»å ããããšãã§ããã
ã®äŸãšããŠã¯ã·ãªã«ãã©ã€ãïŒçé žã«ã«ã·ãŠã ïŒ
ã¿ã«ã¯ïŒã±ã€é žãã°ãã·ãŠã ïŒã±ã€é žã¢ã«ãããŠ
ã ïŒæ²éæ§ç¡«é žããªãŠã çã®äœè³ªé¡æãäºéè¯ïŒ
é¡éïŒçŽºéïŒé žåãã¿ã³ïŒãã³ã¬ã©ïŒã«ãŒãã³ã
ã©ãã¯çã®ç¡æ©é¡æãããªãªã¢ã³ãã«ãŒãã³6BïŒ
ã¬ãŒãã¬ããïŒããŒããã³ãã¬ããïŒããªãŸ
ãŒã«ã¬ããïŒãã³ãžãžã³ã€ãšããŒïŒãã³ã¶ã€ãšã
ãŒïŒãã¿ãã·ã¢ãã³ãã«ãŒïŒã·ã³ã«ã·ã¢ã¬ããç
ã®ææ©é¡æçãå«ãŸããããŸãåæ§ã«ææãéæ
æ·»å ããããšãã§ããã æ¬çºæçµæç©ã«ã¯ãã®ç²åºŠèª¿æŽã®ããã«ïŒçš®ãª
ããïŒçš®ä»¥äžã®äžæŽ»æ§ãªæ®çºæ§ææ©æº¶åªã䜿çšã
ãããšãã§ããäŸãã°ã¢ã»ãã³ïŒã¡ãã«ãšãã«ã±
ãã³ïŒã¡ãã«ã€ãœããã«ã±ãã³ïŒã¡ãã«ã¢ã«ã³ãŒ
ã«ïŒãšãã«ã¢ã«ã³ãŒã«ïŒãããã«ã¢ã«ã³ãŒã«ïŒç¬¬
äºããã«ã¢ã«ã³ãŒã«ïŒã€ãœããã«ã¢ã«ã³ãŒã«ïŒç¬¬
äžããã«ã¢ã«ã³ãŒã«ïŒé ¢é žã¡ãã«ïŒé ¢é žãšãã«ïŒ
é ¢é žããã«ïŒé ¢é žã€ãœããã«ïŒé ¢é žã¢ãã«ïŒãã³
ãŒã³ïŒãã«ãšã³ïŒãã·ã¬ã³ïŒã»ããœã«ãïŒãšãã«
ã»ããœã«ãïŒé ¢é žã»ããœã«ãïŒããã©ããããã©
ã³çãå«ãŸããã æ¬çºæçµæç©ã«ã¯çš®ã ã®ç®çã§å¡æãããã¯å°
å·ã€ã³ãã«æ·»å ãããã·ãªã³ãŒã³çã®æ¶æ³¡å€ãã¬
ããªã³ã°å€ãããå·é²æ¢å€ãããªãªãã·ãšãã¬ã³
ã°ãªã³ãŒã«ã¢ã«ãã«ãšãŒãã«çã®åž¯é»é²æ¢å€ã
2.2â²âãžããããã·âïŒâã¡ããã·ãã³ãŸããšã
ã³çã®çŽ«å€ç·åžåå€ãã¢ã«ãããŠã ãªã¯ããšãŒ
ãïŒã·ãªã«ã²ã«çã®å¢ç²å€ããã®ä»æ²æŸ±é²æ¢å€ã
ããé²æ¢å€ãè²å¥ãé²æ¢å€ãé¡æåæ£å€ãç²çé²
æ¢å€ãç®åŒµãé²æ¢å€ãé£çå€ãé²éå€ãè·æ¶ãå€
ãªã©å皮添å å€ãªããæ·»å å©å€ã®ãããã䜿çšã§
ããã æ¬çºæã®è¢«èŠçµæç©ã¯ä»ãŸã§è¿°ã¹ãŠããçš®ã ã®
æåãéåžžã¯æ··åããã ãã§è£œé ããããæ··åã¯
äžè¬ã«ã¯å®€æž©ã§è¡ãªããå¿ èŠã«å¿ããŠå ç±ããŠè¡
ãªãããšãã§ããã æ¬çºæã®è¢«èŠçµæç©ãåºæã«è¢«èŠããã«ããã€
ãŠã¯å¹ä»ããã«ãŒãã³å¡ãã浞挬ãããŒã«å¡ãã
ã¹ã¯ãªãŒã³å°å·çã®æ¹æ³ãçšããããšãã§ããã
ãŸãæ¬çºæã®çµæç©ã硬åãããããã«ã¯æ°Žéã¢
ãŒã¯ãççŽ ã¢ãŒã¯ãäœå§æ°Žéã©ã³ããäžå§æ°Žéã©
ã³ããé«å§æ°Žéã©ã³ããé«åšæ³¢èªèµ·æ°Žéã©ã³ãã
ãã»ãã³ãã©ãã·ãŠã©ã³ãçã®çŽ«å€ç·ãçºããä»»
æã®ç §å°è£ 眮ãçšããã°ããã æ¬çºæã®è¢«èŠçµæç©ã¯ä»ãŸã§è¿°ã¹ãããšããç¹
å®ã®ã¢ã¯ãªã«ç³»æš¹èã䜿çšããããšã«ãã€ãŠåæ
åéã®çžæº¶æ§ãèããæ¹è¯ããã°ããã§ãªããã
ããããªãªã¬ãã€ã³ç³»æš¹èæååã«å¡è£ ã硬åã
ãå Žåã玫å€ç·ã®ç §å°ã«ãã€ãŠå®€æž©ã§çæéã«ç¡¬
åãããããšãã§ããäžã€åŸãããå¡èã¯è©²æå
åè¡šé¢ã«åŒ·åã«ä»çãã硬床ãå æ²¢ãèåæ§ãè
è¬åæ§ãè溶å€æ§ãèæ©èæ§ãªã©ã«ããããæ§èœ
ãåããã ãŸããæ¬çºæçµæç©ãçšããããšã«ãããåŸæ¥
ããªãªã¬ãã€ã³ç³»æš¹èæååã«å¡è£ ãŸãã¯å°å·ã
ãã«ããã€ãŠäžè¬ã«è¡ãªãããŠãã(1)溶å€è±è(2)
ã¯ãã é žåŠççã®è¡šé¢åŠç(3)æ°ŽæŽã也ç¥(4)äžå¡
ãã也ç¥(5)äžå¡ãã也ç¥ãšããå·¥çšããæååè¡š
é¢äžã®æº¶å€è±èãè¡ãã ããšããããããŠç°¡ç¥ãª
ãã®ã«ããããšãå¯èœã«ããã³ã¹ãçã«ãåŸæ¥æ³
ã«æ¯ã¹åªäœã«ç«ã€ããšãã§ããã äžèšåæäŸãå®æœäŸäžãéšã¯éééšãããã
ãã åæäŸ ïŒ æ¹æåšã枩床èšãåçž®åšãå šçž®åšããã³çªçŽ ã¬
ã¹å°å ¥ç®¡ãè£ åããåå¿å®¹åšã«ç¡æ°Žãã¬ã€ã³é ž
235éšãç¡æ°Žãã¿ã«é ž178éšããããã¬ã³ã°ãªã³ãŒ
ã«230éšããžãšãã¬ã³ã°ãªã³ãŒã«137éšãä»èŸŒã¿ã
çªçŽ ã¬ã¹ãæµããªãã210âã§ïŒæéãçž®åæ°Žã
é€å»ãã€ã€åå¿ãè¡ãªããé žäŸ¡12ã§åå¿ãçµäºã
ããåŸãããäžé£œåããªãšã¹ãã«70éšãã¹ãã¬ã³
30éšã«æº¶è§£ããŠåŸããããã®ãåæç©ïŒ¡ãšããã åæäŸ ïŒ åæäŸïŒãšåäžåå¿å®¹åšã«ç¡æ°Žãã¿ã«é ž207éšã
ããªãã³ãã«ã°ãªã³ãŒã«321éšãä»èŸŒã¿ãçªçŽ ã¬
ã¹ãæµããªãã210âã§ïŒæéãçž®åæ°Žãé€å»ã
ã€ã€åå¿ãè¡ãªããé žäŸ¡0.5ã§åå¿ãçµäºããã
åŸãããããªãšã¹ãã«ã®æ°Žé žåºäŸ¡ã¯376ã§ãã€ãã
ãã®ããªãšã¹ãã«418éšã«ã¢ã¯ãªã«é ž253éšããã€
ããããã³ïŒéšãæ¿ç¡«é ž15.4éšããã«ãšã³100éš
ãå ããæ¹æåšã枩床èšããã³ãã€ãŒã³ã¹ã¿ãŒã¯
åãã©ãããè£ åããåå¿å®¹åšã§95ã100âãæž
å§äžã§çž®åæ°Žãé€å»ããªããïŒæéåå¿ãç¶ãã
çž®åæ°Žãåºãªããªã€ãæç¹ã§åå¿ãçµäºããæªå
å¿ã®ã¢ã¯ãªã«é žããã€ããããã³ãæ¿ç¡«é žãã¢ã«
ã«ãªæŽæµããã³æ°ŽæŽæµã«ãã€ãŠé€å»ããŠããªãšã¹
ãã«ã¢ã¯ãªã¬ãŒããåŸãããããåæç©ïŒ¢ãšã
ãã åæäŸ ïŒ åæäŸïŒãšåäžåå¿å®¹åšã«ãšãã¬ã³ã°ãªã³ãŒã«
273éšãç¡æ°Žãã¿ã«é ž296éšãä»èŸŒã¿ãçªçŽ ãæµã
ãªãã210âã§ïŒæéçž®åæ°Žãé€å»ãã€ã€åå¿ã
è¡ãªããé žäŸ¡0.8ã§åå¿ãçµäºãããåŸãããã
ãªãšã¹ãã«777éšãã¢ã¯ãªã«é ž475éšããã«ãšã³
173éšããã€ããããã³9.6éšãåæäŸïŒãšåäžå
å¿å®¹åšã«ä»èŸŒã¿ã95ã100âãæžå§äžã§çž®åæ°Žã
é€å»ãã€ã€ïŒæéåå¿ãç¶ããçž®åæ°Žãåºãªããª
ã€ãæç¹ã§åå¿ãçµäºãã以äžåæäŸïŒãšåäžåŠ
çã«ãŠããªãšã¹ãã«ã¢ã¯ãªã¬ãŒããåŸããããã
åæç©ïŒ£ãšããã åæäŸ ïŒ åæäŸïŒãšåäžæ¹æ³ã«ãŠã¢ãžãã³é ž292éšãšã
ãããã·ãããªã«ããããã·ããã¬ãŒã898éšã
çšããŠæ°Žé žåºäŸ¡279ã®ããªãšã¹ãã«ãåŸãããã®
ããªãšã¹ãã«ãšã¢ã¯ãªã«é žãšãåæäŸïŒãšåäžæ¹
æ³ã«ãŠçž®åããŠããªãšã¹ãã«ã¢ã¯ãªã¬ãŒããåŸ
ãããããåæç©ïŒ€ãšããã åæäŸ ïŒ æ°Žæ·»ãã¹ããšããŒã«ïŒ¡ãžã°ãªã·ãžã«ãšãŒãã«
ïŒãšããã·åœé260ïŒ260éšãã¢ã¯ãªã«é ž72éšãã
ã€ããããã³ã¢ãã¡ãã«ãšãŒãã«0.1éšãããªãš
ãã«ã¡ãã«ã¢ã³ã¢ããŠã ã¯ããªãïŒéšãçšããŠ95
âã§ïŒæéåå¿ããé žäŸ¡ïŒä»¥äžã®ãšããã·ã¢ã¯ãª
ã¬ãŒããåŸãããããåæç©ïŒ¥ãšããã åæäŸ ïŒ ãã¿ã«é žãžã°ãªã·ãžã«ïŒãšããã·åœé200ïŒ200
éšãã¢ã¯ãªã«é žïŒâããããã·ãšãã«116éšãç¡
æ°Žããã·ãã«ã³ãã¯é ž266éšãããªãšãã«ã¢ã³ã¢
ããŠã ã¯ããªãïŒéšããã€ããããã³ã¢ãã¡ãã«
ãšãŒãã«0.1éšãçšããŠ95âã§ïŒæéåå¿ããé ž
䟡ïŒä»¥äžã®ãšããã·ã¢ã¯ãªã¬ãŒããåŸããããã
åæç©ïŒŠãšããã åæäŸ ïŒ æ°Žæ·»ãã¹ããšããŒã«ïŒ¡ã«ãããã¬ã³ãªããµã€ã
ãä»å ããŠåŸããããžãªãŒã«ååç©ïŒæ°Žé žåºäŸ¡
320ïŒ701éšãšãã€ããããã³ã¢ãã¡ãã«ãšãŒãã«
ïŒéšãšããæ¹æåšã枩床èšããã³æ»ŽäžããŒããè£
åããåå¿å®¹åšãä»èŸŒã¿ã70âã§ãããµã¡ãã¬ã³
ãžã€ãœã·ã¢ããŒã168éšãšã€ãœããã³ãžã€ãœã·ã¢
ããŒã444éšãšãïŒæéã§æ»Žäžããå枩床ã§æŽã«
ïŒæéåå¿ãç¶ãããããåŸã¢ã¯ãªã«é žïŒâãã
ããã·ãããã«260éšãïŒæéã§æ»ŽäžããNCOåº
åå¿çã99ïŒ ä»¥äžãšãªã€ããšããã§åå¿ãçµäº
ãããŠã¬ã¿ã³ã¢ã¯ãªã¬ãŒããåŸãããããåæç©
ãšããã åæäŸ ïŒ ã¡ã¿ã¯ãªã«é žã€ãœããã«67éšãã¡ã¿ã¯ãªã«é žïŒ
âããããã·ãšãã«10éšãã¡ã¿ã¯ãªã«é žã¡ãã«21
éšãã¢ã¯ãªã«é žïŒéšããã³ã¢ãŸãã¹ã€ãœãããã
ããªã«ïŒéšãããªãæ··åç©ã90âã®ã€ãœãããã
ãŒã«15éšããã«ãšã³85éšãããªãæ··å溶å€äžã«æ¹
æããªããïŒæéãããŠæ»ŽäžããæŽã«å枩床ã§ïŒ
æééåããŠã¢ã¯ãªã«æš¹èãåŸãã åæäŸ ïŒ åæäŸïŒãšåäžæ¹æ³ã«ãŠã¡ã¿ã¯ãªã«é žã€ãœãã
ã«60éšãã¹ãã¬ã³20éšãã¡ã¿ã¯ãªã«é žã¡ãã«20éš
ãããªãã¢ã¯ãªã«æš¹èãåŸãã åæäŸ 10 åæäŸïŒãšåäžæ¹æ³ã«ãŠã¡ã¿ã¯ãªã«é žã€ãœãã
ã«20éšãã¡ã¿ã¯ãªã«é žïŒâããããã·ãšãã«15
éšãã¡ã¿ã¯ãªã«é žã¡ãã«40éšããã³ã¹ãã¬ã³25éš
ãããªãã¢ã¯ãªã«æš¹èãåŸãã å®æœäŸ ïŒ åæç©A50éšãããªãã³ãã«ã°ãªã³ãŒã«ãžã¢ã¯
ãªã¬ãŒã10éšãã¢ã¯ãªã«æš¹èA38éšãå¡©çŽ å床27
ïŒ ã®å¡©çŽ åããªãããã¬ã³æš¹è溶液ïŒæ±æŽåææ ª
åŒäŒç€Ÿè£œåã®ããŒãã¬ãžã³14LLBããã«ãšã³æº¶
液ãåºåå15ïŒ ïŒ140éšããã³ãŸã€ã³ã€ãœããã«
ãšãŒãã«ïŒéšããã³ãã·ã¬ã³50éšã調åããŠçŽ«å€
ç·ç¡¬ååå¡æãåŸãããã®å¡æ溶液ã¯å®å šã«ã¯ãª
ã¢ã§ãã€ãããã®å¡æããã«ãšã³ã§æŽæµããç¡åŠ
çã®ããªãããã¬ã³æååããã«ã«ç¡¬åèåã
20ÎŒãšãªãããã«ã¹ãã¬ãŒå¡è£ ãã宀枩ã§ïŒåé
ã»ããã€ã³ã°ããåŸãé«å§æ°Žéç¯ïŒ80ã¯ããïŒcm
匷床ïŒäž20cmã®ãšããã§ç©ºæ°äžã§çŽ«å€ç·ã10ç§é
ç §å°ãããšããå®å šã«ç¡¬åããéæã§å æ²¢ã®ãã
å¡é¢ãåŸãããããã®ããã«ã®æ§èœè©äŸ¡çµæã第
ïŒè¡šã«ç€ºãã å®æœäŸ ïŒãïŒ å®æœäŸïŒãšåäžèŠé ã§ç¬¬ïŒè¡šã«ç€ºãé åã«ãŠèª¿
åãã玫å€ç·ç¡¬ååå¡æããããã第ïŒè¡šã«ç€ºã
åºæã«å®æœäŸïŒãšåäžæ¹æ³ã«ãŠå¡è£ ã硬åãã
ãããããã®æ§èœè©äŸ¡çµæã¯ç¬¬ïŒè¡šã«ç€ºãã
ãããŸãã¯å°å·ããã®ã«é©ãã玫å€ç·ç¡¬åå被èŠ
çµæç©ã«é¢ããã ããªãªã¬ãã€ã³ãããšãã°ããªãšãã¬ã³ïŒããª
ãããã¬ã³çã¯ç¡æ¥µæ§ã§ãã€çµæ¶æ§ã§ããè¬åïŒ
溶å€ãªã©ã«å¯ŸããŠã極ããŠå®å®ã§ããããéåžžã®
被èŠçµæç©ã§ã¯ä»çããå¡è£ ïŒå°å·ãå°é£ã§ã
ãããã®ããåŸæ¥ããããªãªã¬ãã€ã³æš¹èè¡šé¢ãž
ã®è¢«èŠçµæç©ã®ä»çæ§ãæ¹è¯ããããã«äŸãã°ç«
çåŠçæ³ïŒã³ããæŸé»ïŒé åå€åŠçæ³ïŒãµã³ãã
ã©ã¹ãæ³ïŒæŸå°ç·åŠçæ³ãªã©ã®ååŠçãè¡ãªãã
ãŠãããããããææ³ã¯è¢«å¡ç©ã®åœ¢ç¶ã«ãã€ãŠã¯
é©çšãå°é£ã§ãããåäžãªè¡šé¢åŠçãåŸããã«ã
ããä»çæ§ãååã«æºè¶³ã§ãããã®ã§ã¯ãªããäž
æ¹ãæè¿ãããã®ååŠçãªãã«ããªãªã¬ãã€ã³ã«
ä»çæ§ã®ãã被èŠçµæç©ãåŸãããšã«ã€ããŠã®è©Š
ã¿ããªãããç³æ²¹ç³»æš¹èãšç°åãŽã ãããªãçµæ
ç©ãšããå€æ§ã¢ã«ãããæš¹èïŒã¢ã¯ãªã«æš¹èïŒãš
ãã¬ã³âé ¢é žããã«å ±éåæš¹èçãšå¡©çŽ åãªã¬ã
ã€ã³æš¹èãšãããªãçµæç©ãææ¡ããããããã
ãã¯ä»çæ§ã¯è¯å¥œã§ããããè¡šé¢ç¡¬åºŠãååã§ãª
ãããã®ããèæ²¹æ§ïŒè溶å€æ§ãã»ãšãã©ãªãã
ãå®çšçã«å€§ããªå¶çŽãåããäžå¡ãå¡æãšããŠ
äžéšçšããããŠããã«ãããªããããªãªã¬ãã€ã³
系暹èã«å¯ŸããŠä»çæ§ãæãããã€è¯å¥œãªå¡è硬
床ãèæ²¹æ§ãè溶å€æ§ãèè¬åæ§ãå Œåãã被èŠ
çµæç©ãåŸãããã«ã¯ãå¡©çŽ åãªã¬ãã€ã³ïŒç°å
ãŽã ãäž»æåãšããæš¹èçµæç©äžã«æ¶æ©æåãå°
å ¥ããæ¹æ³ãèããããããäžè¬ã«ããªã€ãœã·ã¢
ããŒãååç©ãã¡ã©ãã³æš¹èïŒãšããã·æš¹èãªã©
ã®æ¶æ©æ§ãæããæ¢ç¥ã®ååç©ã¯å¡©çŽ åãªã¬ãã€
ã³ãç°åãŽã ãšã®çžæº¶æ§ãæªã被èŠçµæç©ãšããŠ
ã¯äžé©åœã§ãããåæ²¹å€æ§ã¢ã«ãããæš¹èããã€
ã«åããªãã¿ãžãšã³ã®ãããªé žåéååã®æš¹èæ
åã¯ãå¡©çŽ åãªã¬ãã€ã³ãšçžæº¶ã¯ãããããªãªã¬
ãã€ã³ã®å€åœ¢ãããããªã枩床ç¯å²ã§ã¯ååãªæ¶
æ©å¹æãæåŸ ã§ãã奜ãŸãããªããããã§ãããª
ãªã¬ãã€ã³ãå€åœ¢ããããšãªãã«å®¹æã«æ¶æ©å¡è
ãåŸãæ¹æ³ãšããŠã¯çŽ«å€ç·ç¡¬ååçµæç©ãèãã
ããããäžè¬ã«çŸåšå®çšåãããŠãããã®ã¯ãã
ãªãªã¬ãã€ã³ã«å¯ŸããŠãŸã€ããä»çæ§ããªããã
ããæ¹è¯ããããã«ãã®çŽ«å€ç·ç¡¬ååçµæç©ã«å¡©
çŽ åããªãªã¬ãã€ã³ãå°å ¥ãä»çæ§ãåºãããšã
è©Šã¿ãããããäžè¬ã«çŽ«å€ç·ç¡¬ååçµæç©ãšå¡©çŽ
åããªãªã¬ãã€ã³ãšã¯çžæº¶æ§ãæªãããã被èŠçµ
æç©ãšããŠå®çšã«äŸããããã®ã¯åŸãããŠããª
ãã æ¬çºæè ãã¯äžèšç¶æ³ã«éã¿ãæªåŠçã®ããªãª
ã¬ãã€ã³ãšã®ä»çæ§ãè¯ãããã®ããåžžæž©çæé
ã§æ¶æ©ç¡¬åããè¡šé¢ç¡¬åºŠïŒèæ²¹æ§ïŒè溶å€æ§ïŒè
è¬åæ§ã®è¯å¥œãªå¡èãæäŸãã被èŠçµæç©ã«ã€ã
ãŠéææ€èšãéããçµæãæ¬çºæãå®æããã æ¬çºæ㯠(A) ïŒååäžã«ãšãã¬ã³æ§äžé£œåäºéçµåãïŒå
以äžæããååç© 10ã80ééïŒ (B) å¡©çŽ åããªãªã¬ãã€ã³ç³»æš¹è ïŒã80ééïŒ (C) ã¡ã¿ã¯ãªã«é žã€ãœããã«åäœã50ééïŒ ä»¥äž
ããã³æ¬¡åŒãã ïŒR1ã¯ïŒšåã¯CH3ïŒR2ã¯ïŒšåã¯CH3ïŒã§è¡š
ããããåäœãïŒã40ééïŒ å«ãã¢ã¯ãªã«ç³»æš¹
è 10ã70ééïŒ ãäž»æåãšããå éåéå§å€å«æããªãªã¬ãã€ã³
系暹èçšçŽ«å€ç·ç¡¬åå被èŠçµæç©ã§ããã æ¬çºæã®ç¹åŸŽã¯åžžæž©ïŒçæéã§ç¡¬åãã玫å€ç·
硬åå被èŠçµæç©ã«ãããªãªã¬ãã€ã³ã«ä»çæ§ã
æããå¡©çŽ åããªãªã¬ãã€ã³ãå°å ¥ããã«ãã
ããäž¡è éã®çžæº¶æ§äžè¯ãæ¹è¯ããããäž¡è ãšçž
溶æ§ã®ããã¡ã¿ã¯ãªã«é žã€ãœããã«ãšæ°Žé žåºãæ
ããã¢ã¯ãªã«ã¢ãããŒãšãå ±éåããã¢ã¯ãªã«æš¹
èã第äžæåãšããŠå°å ¥ããããšã«ããã æ¬çºæã®(A)æåã§ãããïŒååäžã«ãšãã¬ã³ç³»
äžé£œåäºéçµåãïŒå以äžæããååç©ãšã¯åå
äžã«ïŒå以äžã®ãšãã¬ã³ç³»äžé£œåãå«ã¿ããã€å
åŠç·ã§ç §å°ãããšãå éåéå§å€ãšã®çžäºäœçšã«
ãã€ãŠããªãŒã©ãžã«ã«ã«ããä»å éåãè¡ãªãèœ
åãããååç©ãæå³ãããå ·äœçã«ã¯è€æ°ã®ãš
ãã¬ã³ç³»äžé£œåãå«ãäžé£œåããªãšã¹ãã«ïŒè€æ°
ã®ã¢ã¯ãªã«ç³»äžé£œåãæããååç©ãªã©ãããã
ããã æ¬çºæã«çšãåŸãäžé£œåããªãšã¹ãã«ã¯ãéåžž
ãšãã¬ã³ç³»äžé£œåããªã«ã«ãã³é žãšå€äŸ¡ã¢ã«ã³ãŒ
ã«ãšã®ãšã¹ãã«åçæç©ã§ãããäžè¬ã«ãšãã¬ã³
ç³»äžé£œåã¯Î±ïŒÎ²äœã«ããããšãã¬ã³ç³»äžé£œåã
ãªã«ã«ãã³é žãšããŠã¯ãã¬ã€ã³é žïŒããã«é žïŒã¢
ã³ãããé žïŒã€ã¿ã³ã³é žïŒã·ãã©ã³ã³é žïŒã¡ãµã³
ã³é žïŒã ã³ã³é žããã³ãžãããã ã³ã³é žãªãã³ã«
ãããé žã®ããããã³ã¢ã«ãã«èªå°äœãå«ãŸãã
ããã¬ã€ã³é žããã³ããã«é žãç¹ã«å¥œãŸããããš
ãã¬ã³ç³»äžé£œåããªã«ã«ãã³é žã¯åç¬ã§ããæ··å
ç©ãšããŠäœ¿çšããŠããããŸãããããã®é žã®ç¡æ°Ž
ç©ãåæ§ã«äœ¿çšããããäžé£œåããªãšã¹ãã«ã®è£œ
é ã«éããŠã¯ãšãã¬ã³ç³»äžé£œåããªã«ã«ãã³é žãš
çµåãããŠãç®çã«å¿ããïŒçš®ä»¥äžã®é£œåããªã«
ã«ãã³é žãé«æ䜿çšããããšãã§ãããæçšãªé£œ
åããªã«ã«ãã³é žã®äŸãšããŠã¯ã·ãŠãŠé žïŒã³ãã¯
é žïŒããã³é žïŒã¡ãã«ã³ãã¯é žïŒ2.2âãžã¡ãã«
ã³ãã¯é žïŒ2.3âãžã¡ãã«ã³ãã¯é žïŒããã·ã«ã³
ãã¯é žïŒã°ã«ã¿ã«é žïŒïŒâã¡ãã«ã°ã«ã¿ã«é žïŒïŒ
âã¡ãã«ã°ã«ã¿ã«é žïŒ2.2âãžã¡ãã«ã°ã«ã¿ã«é žïŒ
3.3âãžã¡ãã«ã°ã«ã¿ã«é žïŒ3.3âãžãšãã«ã°ã«ã¿
ã«é žïŒã¢ãžãã³é žïŒãã¡ãªã³é žïŒã¹ããªã³é žïŒã¢
ãŒã©ã€ã³é žïŒã»ãã·ã³é žïŒãã¿ã«é žïŒã€ãœãã¿ã«
é žïŒãã¬ãã¿ã«é žïŒããã©ã¯ãã«ãã¿ã«é žïŒ1.2
âãããµããããã¿ã«é žïŒ1.3âãããµãããã
ã¿ã«é žïŒ1.4âãããµããããã¿ã«é žïŒ1.1âã·ã¯
ããã¿ã³ãžã«ã«ãã³é žããã³ãã©ã³ã¹â1.4âã·
ã¯ããããµãžã«ã«ãã³é žãå«ãŸããããããã®é ž
ã®ç¡æ°Žç©ãåæ§ã«äœ¿çšãããã ãšãã¬ã³ç³»äžé£œåããªãšã¹ãã«ã®è£œé ã«æçšãª
å€äŸ¡ã¢ã«ã³ãŒã«ã«ã¯ããšãã¬ã³ã°ãªã³ãŒã«ïŒ1.3
âãããã³ãžãªãŒã«ïŒãããã¬ã³ã°ãªã³ãŒã«ïŒ
2.3âãã¿ã³ãžãªãŒã«ïŒ1.4âãã¿ã³ãžãªãŒã«ïŒïŒ
âãšãã«ãã¿ã³1.4âãžãªãŒã«ïŒ1.5âãã³ã¿ã³ãž
ãªãŒã«ïŒ1.6âãããµã³ãžãªãŒã«ïŒ1.7âããã¿ã³
ãžãªãŒã«ïŒ1.8âãªã¯ã¿ã³ãžãªãŒã«ïŒ1.9âããã³
ãžãªãŒã«ïŒ1.10âãã«ã³ãžãªãŒã«ïŒ2.2âãžãšã
ã«ãããã³â1.3âãžãªãŒã«ïŒ2.2âãžã¡ãã«ãã
ãã³â1.3âãžãªãŒã«ïŒïŒâã¡ãã«ãã³ã¿ã³â1.4
âãžãªãŒã«ïŒ2.2âãžãšãã«ãã¿ã³â1.3âãžãªãŒ
ã«ïŒ4.5âããã³ãžãªãŒã«ïŒãžãšãã¬ã³ã°ãªã³ãŒ
ã«ïŒããªãšãã¬ã³ã°ãªã³ãŒã«ïŒãžãããã¬ã³ã°ãª
ã³ãŒã«ïŒã°ãªã»ãªã³ïŒãã³ã¿ãšãªããªããïŒãšãª
ããªããïŒãœã«ãããïŒãã³ãããïŒ1.1.1âã
ãªã¡ãããŒã«ãããã³ïŒããªã¡ãããŒã«ãšã¿ã³ïŒ
ããã³2.2âãžã¡ãã«âïŒâããããã·ããããª
ã³é ž2.2âãžã¡ãã«âïŒâããããã·ãããã«ãª
ã©ãå«ãŸããã äžé£œåããªãšã¹ãã«ãšåæ§ã«ããäžã€ã®æçšãª
(A)æåã¯è€æ°ã®ã¢ã¯ãªã«ç³»äžé£œåãæããååç©
ã§ãå ·äœçã«ã¯äžèšã®ãã®ããããããšãã§ã
ãã (a) åŒããããã³ããã§ç€ºãããã¢ã¯ãªã«ç³»
ããªãšã¹ãã«ããã³ã¢ã¯ãªã«ç³»ããªã¢ããã§å¥œ
ãŸããã¯åŒäžã®ãã¹ãŠã®ïŒ¡ãé žçŽ ã§ãããã®ã ïŒäžèšåŒããã³äžãïœã¯ïŒãïŒã®æŽæ°ã§
ãããåã¯ããããç¬ç«ã«ïŒã10åã®ççŽ å
åãæããïŒäŸ¡ã®èèªæïŒã·ã¯ãèèªæãŸãã¯
è³éŠæçåæ°ŽçŽ åºã瀺ããåRâ²ã¯ããããç¬
ç«ã«æ°ŽçŽ ïŒã¡ãã«ãŸãã¯ãšãã«ã瀺ããåã¯
ããããç¬ç«ã«é žçŽ ãŸãã¯NHã瀺ãïŒ åŒããã§ç€ºãããããªãšã¹ãã«ããã³ããª
ã¢ãããªãªãŽããŒã¯ãžã«ã«ãã³é žãŸãã¯é žã¢ã
ããšïŒäŸ¡ã¢ã«ã³ãŒã«ãŸãã¯ãžã¢ãã³ãšãåå¿ã
ãã次ã«çæç©ãã¢ã¯ãªã«é žãŸãã¯Î±â眮æã¢
ã¯ãªã«é žãšåå¿ãããããšã«ãã€ãŠè£œé ããã
ãšãã§ãããåŒããã§ç€ºãããã¢ã¯ãªã«ç³»ã
ãªãšã¹ãã«ããã³ããªã¢ãããªãªãŽããŒã¯ãã
ããã·å®èœæ§ã¢ãã«ã«ãã³é žãŸãã¯ãããé žã®
ïŒéäœïŒïŒéäœãŸãã¯ïŒéäœãã¢ããå®èœæ§ã¢
ãã«ã«ãã³é žãŸãã¯ãããé žã®ïŒéäœïŒïŒéäœ
ãŸãã¯ïŒéäœãšã¢ã¯ãªã«é žãŸãã¯Î±â眮æã¢ã¯
ãªã«é žãšãåå¿ãããŠè£œé ããããšãã§ããã (b) ïŒååäžã«ïŒå以äžã®ãšããã·åºãæããå
åç©ã«ã«ã«ããã·ã«åºãæããéåæ§åéäœã
éç°ãšã¹ãã«ååå¿ã«ãã€ãŠä»å ãããŠè£œé ã
ããšããã·å€æ§ã¢ã¯ãªã«ãªãªãŽããŒãå ·äœçã«
ã¯ïŒååäžã«ïŒå以äžã®ãšããã·åºãæããå
åç©ãäŸãã°ãšãã¬ã³ã°ãªã³ãŒã«ãžã°ãªã·ãžã«
ãšãŒãã«ïŒããªãšãã¬ã³ã°ãªã³ãŒã«ãžã°ãªã·ãž
ã«ãšãŒãã«ïŒããã©ãšãã¬ã³ã°ãªã³ãŒã«ãžã°ãª
ã·ãžã«ãšãŒãã«ãªã©ã®ããªãšãã¬ã³ã°ãªã³ãŒã«
èªå°äœããããã¬ã³ã°ãªã³ãŒã«ãžã°ãªã·ãžã«ãš
ãŒãã«ïŒããªãããã¬ã³ã°ãªã³ãŒã«ãžã°ãªã·ãž
ã«ãšãŒãã«ãªã©ã®ããªãããã¬ã³ã°ãªã³ãŒã«èª
å°äœãããªãã³ãã«ã°ãªã³ãŒã«ãžã°ãªã·ãžã«ãš
ãŒãã«ïŒ1.6âãããµã³ãžãªãŒã«ãžã°ãªã·ãžã«
ãšãŒãã«ïŒã°ãªã»ãªã³ããªã°ãªã·ãžã«ãšãŒãã«
ãªã©ã®èèªæèªå°äœãæ°Žæ·»ãã¹ããšããŒã«ïŒ¡ãž
ã°ãªã·ãžã«ãšãŒãã«ïŒã·ã¯ããããµã³ãžãªãŒã«
ãžã°ãªã·ãžã«ãšãŒãã«ãªã©ã®èç°åã°ãªã·ãžã«
èªå°äœããžã°ãªã·ãžã«ã¢ããªã³ïŒãžã°ãªã·ãžã«
ãã³ãžã«ã¢ãã³ïŒ1.3ãžã°ãªã·ãžã«â5.5ãžã¡ã
ã«ããã³ãã€ã³ãªã©ã®ã°ãªã·ãžã«ã¢ãã³èªå°
äœããã¹ããšããŒã«ïŒ¡ãšãšãã¯ãã«ãããªã³ãŸ
ãã¯ã¡ãã«ãšãã¯ãã«ãããªã³ãšã®çž®åçæç©
ã§äŸãã°ãšãã³562ïŒãšãã³828ïŒãšãã³834ïŒ
ãšãã³864ïŒãšãã³1001ïŒãšãã³1004ïŒä»¥äžã·ãš
ã«ååŠç€Ÿè£œïŒçãšããŠåžè²©ãããŠãããã®ç
ãšãã«ã«ããã·ã«åºãæããéåæ§åéäœãäŸ
ãã°ã¢ã¯ãªã«é žïŒã¡ã¿ã¯ãªã«é žïŒã¯ããã³é žïŒ
ãã¿ã«é žã¢ãã¡ã¿ã¯ãªããã·ãšãã«ïŒãã¿ã«é ž
ã¢ãã¢ã¯ãªããã·ãããã«ïŒãã¿ã«é žã¢ãã¡ã¿
ã¯ãªããã·ãããã«ïŒããã©ããããã¿ã«é žã¢
ãã¢ã¯ãªããã·ãšãã«ïŒããã©ããããã¿ã«é ž
ã¢ãã¡ã¿ã¯ãªããã·ãšãã«ïŒããã©ããããã¿
ã«é žã¢ãã¡ã¿ã¯ãªããã·ãããã«ïŒããã©ãã
ããã¿ã«é žã¢ãã¢ã¯ãªããã·ãããã«ïŒããã©
ããããã¿ã«é žã¢ãã¡ã¿ã¯ãªããã·ãããã«ïŒ
ãããµããããã¿ã«é žã¢ãã¢ã¯ãªããã·ãšã
ã«ïŒãããµããããã¿ã«é žã¢ãã¡ã¿ã¯ãªããã·
ãšãã«ïŒãããµããããã¿ã«é žã¢ãã¢ã¯ãªãã
ã·ãããã«ïŒãããµããããã¿ã«é žã¢ãã¡ã¿ã¯
ãªããã·ãããã«çãšãåå¿ãããããšã«ãã€
ãŠè£œé ãããååç©ã (c) ããªã€ãœã·ã¢ããŒãååç©ãšãæ°Žé žåºãæã
ãã¢ã¯ãªã«åéäœãšã®ä»å ç©ãïŒå以äžã®æ°Žé ž
åºãæããååç©ã«ãŠã¬ã¿ã³ååå¿ã«ãã€ãŠä»
å ãããŠè£œé ã§ãããŠã¬ã¿ã³å€æ§ã¢ã¯ãªã«ãªãª
ãŽããŒããã®è£œé ã«çšããåæã®ããªã€ãœã·ã¢
ããŒãååç©ãšããŠã¯äŸãã°ããªã¬ã³ãžã€ãœã·
ã¢ããŒãïŒ4.4â²âãžããšãã«ã¡ã¿ã³ãžã€ãœã·ã¢
ããŒãïŒãã·ãªã¬ã³ãžã€ãœã·ã¢ããŒãïŒãããµ
ã¡ãã¬ã³ãžã€ãœã·ã¢ããŒãïŒãªãžã³ãžã€ãœã·ã¢
ããŒãïŒ4.4â²âã¡ãã¬ã³ãã¹ïŒã·ã¯ãããã·ã«
ã€ãœã·ã¢ããŒãïŒïŒã¡ãã«ã·ã¯ããããµã³2.4
ïŒãŸãã¯2.6ïŒãžã€ãœã·ã¢ããŒãïŒ1.3âïŒã€ãœ
ã·ã¢ããŒãã¡ãã«ïŒã·ã¯ããããµã³ïŒã€ãœãã
ã³ãžã€ãœã·ã¢ããŒãïŒããªã¡ãã«ãããµã¡ãã¬
ã³ãžã€ãœã·ã¢ããŒãïŒãã€ããŒé žãžã€ãœã·ã¢ã
ãŒãçãå«ãŸãããæ°Žé žåºãæããã¢ã¯ãªã«å
éäœã«ã¯ïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâããããã·ãš
ãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâããããã·ãã
ãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâããããã·ïŒâ
ã¡ããã·ãããã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâã
ãããã·ïŒâãããã·ãããã«ïŒïŒã¡ã¿ïŒã¢ã¯
ãªã«é žïŒâããããã·âïŒâïŒïŒâãšãã«ãã
ã·ã«ãªãã·ïŒãããã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒ
âããããã·âïŒâããšãã«ãªãã·ãããã«ç
ãå«ãŸãããïŒå以äžã®æ°Žé žåºãæããååç©
ãšããŠã¯ããªãã³ãã«ã°ãªã³ãŒã«ïŒ2.2.4âã
ãªã¡ãã«â1.3âãã³ã¿ã³ãžãªãŒã«ïŒ1.6âãã
ãµã³ãžãªãŒã«ïŒããªãšãã¬ã³ã°ãªã³ãŒã«ïŒæ°ŽçŽ
æ·»å ãã¹ããšããŒã«ïŒ¡ïŒããªã«ããã©ã¯ãã³ãž
ãªãŒã«ïŒããªããã©ã¡ãã¬ã³ã°ãªã³ãŒã«ïŒãšã¹
ãã«ãžãªãŒã«204ïŒäžè¬åŒããïŒããã§è¡šã
ããããžãªãŒã«ïŒ ïŒåŒäžãïœïŒmâ²ã¯ïŒãïŒã®æŽæ°ãïœïŒnâ²ã¯ïŒ
ãŸãã¯ïŒã瀺ãïŒ ïŒåŒäžãïœïŒmâ²ã¯ïŒãïŒã®æŽæ°ãïœïŒnâ²ã¯ïŒ
ãŸãã¯ïŒã瀺ãïŒ äžè¬åŒããã§è¡šããããããªãšã¹ãã«ãžãªãŒ
ã«ãªã©ãå«ãŸããã HOR1ïŒOOCR2COOR1ïŒnOH ãã ãåŒäžãR1ã¯C2ãC10ã®ã¢ã«ãã¬ã³åºãŸãã¯ïŒâ
CH2CHR3OïŒâoïŒR3ã¯ïŒšãŸãã¯CH3ãïœã¯10以
äžã®æŽæ°ïŒãªãåºããR2ã¯C2ãC10ã®ã¢ã«ãã¬
ã³åºããŸãã¯ããšãã«åºãïœã¯ïŒã10ã®æŽæ°ã
æå³ãããã (d) äžè¿°ã®(a)ïŒ(b)ããã³(c)ã«ã¯å±ããªããè€æ°ã®
ã¢ã¯ãªã«ç³»äžé£œåãæãããªãªãŽããŒãããã
ãªãªãŽããŒã®å ·äœäŸãšããŠã¯äžè¬åŒããã§è¡š
ãããããžã¢ã¯ãªã¬ãŒãååç©ïŒ ïŒåŒäžãã¯ïŒšãŸãã¯CH3ãïœïŒïŒã14ã®æŽ
æ°ïŒ ãããã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãïŒ1.3â
ããã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãïŒ1.4âã
ãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãïŒ1.6âãã
ãµã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãïŒããªãã³ãã«
ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãïŒãžãããã¬ã³ã°ãª
ã³ãŒã«ãžã¢ã¯ãªã¬ãŒãïŒ2.2â²âãã¹ïŒïŒâã¢ã¯
ãªããã·ãããããã·ããšãã«ïŒãããã³ïŒ
2.2â²âãã¹ïŒïŒâã¢ã¯ãªããã·ãžãšããã·ããš
ãã«ïŒãããã³ïŒããªã¡ããâã«ãããã³ããª
ã¢ã¯ãªã¬ãŒãïŒããªã¡ãããŒã«ãšã¿ã³ããªã¢ã¯
ãªã¬ãŒãïŒããã©ã¡ãããŒã«ã¡ã¿ã³ããªã¢ã¯ãª
ã¬ãŒãïŒããªã¡ãããŒã«ãããã³ã¢ãã€ã·æ²¹ã¬
ãŒããžã¢ã¯ãªã¬ãŒãïŒããã©ã¡ãããŒã«ã¡ã¿ã³
ããã©ã¢ã¯ãªã¬ãŒãïŒãžãã³ã¿ãšãªã¹ãªããŒã«
ãããµã¢ã¯ãªã¬ãŒãïŒäžè¬åŒãã ïŒåŒäžãR1ã¯ïŒšåã¯CH3ãR2ïŒR3ïŒR4åã³
R5ã¯ããããïŒC1ãC8ã®çœ®æåºãæããã
ã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºåã¯ã¢ãªãŒã«
åºãR6ïŒR7ïŒR8åã³R9ã¯ããããïŒC1ãC8
ã®ã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºåã¯ã¢ãªãŒã«
åºïŒ ã§è¡šããããïŒã¡ã¿ïŒã¢ã¯ãªã«ç³»äžé£œåãæã
ããªãªãŽããŒçãå«ãŸããã æ¬çºæã®(B)æåã®å¡©çŽ åããªãªã¬ãã€ã³ç³»æš¹è
ãšããŠã¯ãå¡©çŽ åããªãšãã¬ã³ïŒå¡©çŽ åããªãã
ãã¬ã³ïŒå¡©çŽ åããªããã³ïŒå¡©çŽ åãšãã¬ã³ãã
ãã¬ã³ã³ããªããŒçãå«ãŸããããåŸããã被èŠ
çµæç©ã®å¡æäœæ¥æ§ãªãã³ã«ç¡¬åå¡èã®ä»çæ§ã
èåæ§ãèæ ®ããéã«ã¯å¡©çŽ å«æéã15ã50éé
ïŒ ã®ãã®ãç¹ã«20ã40ééïŒ ã®äœå¡©çŽ åããªãã
ãã¬ã³ã奜é©ã§ããã æ¬çºæã®(C)æåã®ã¢ã¯ãªã«ç³»æš¹èã¯ã¡ã¿ã¯ãªã«
é žã€ãœããã«ãäž»åæãšããæ°Žé žåºãæããã¢ã¯
ãªã«ç³»åéäœãå«ã¿ãä»ã®å ±éåå¯èœãªåéäœãš
ãå ±éåããŠè£œé ããããã®ã§ãããæ°Žé žåºãæ
ããã¢ã¯ãªã«ç³»åéäœã«ã¯ïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒ
âããããã·ãšãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâã
ãããã·ãããã«ãå«ãŸãããå ±éåå¯èœãªä»ã®
åéäœãšããŠã¯ãäŸãã°ïŒã¡ã¿ïŒã¢ã¯ãªã«é žã¡ã
ã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žãšãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«
é žïœâããã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâãšãã«ã
ãã·ã«çã®ïŒã¡ã¿ïŒã¢ã¯ãªã«é žã¢ã«ãã«é¡ãã¹ã
ã¬ã³ïŒããã«ãã«ãšã³ïŒé ¢é žããã«ïŒããããªã³
é žããã«åã³Î±ïŒÎ²ã¢ããšãã¬ã³ç³»äžé£œåãžã«ã«
ãã³é žã®ãžã¢ã«ãã«ãšã¹ãã«é¡çãå«ãŸããã該
ã¢ã¯ãªã«ç³»æš¹èã¯ã¡ã¿ã¯ãªã«é žã€ãœããã«åäœã
50ééïŒ ä»¥äžå«æãããã€æ°Žé žåºãæããã¢ã¯ãª
ã«ã¢ãããŒåäœãïŒã40ééïŒ å«æããããå ±é
åããŠè£œé ããå¿ èŠããããã¢ã¯ãªã«ç³»æš¹èäžã®
ã¡ã¿ã¯ãªã«é žã€ãœããã«åäœã®å«æéã50ééïŒ
ã«æºããªãã¢ã¯ãªã«ç³»æš¹èã¯å¡©çŽ åããªãªã¬ãã€
ã³æš¹èããšãã«å¡©çŽ å床ã40ééïŒ ä»¥äžã®äœå¡©çŽ
åããªãªã¬ãã€ã³æš¹èãšã®çžæº¶æ§ãæªã奜ãŸãã
ãªãããŸãã¢ã¯ãªã«ç³»æš¹èäžã®æ°Žé žåºãæããã¢
ã¯ãªã«ã¢ãããŒåäœãïŒééïŒ ã«æºããªããšäžé£œ
åããªãšã¹ãã«åã³ã¢ã¯ãªã«ç³»äžé£œåååç©ãªã©
ã®ææ©éåæ§ç©è³ªãšã®çžæº¶æ§ãæªããäžæ¹40éé
ïŒ ãè¶ãããšå¡©çŽ åããªãªã¬ãã€ã³æš¹èãšã®çžæº¶
æ§ãæªããããããææ©éåæ§ç©è³ªãšå¡©çŽ åããª
ãªã¬ãã€ã³æš¹èãšã®çžæº¶æ§ã®æ©æž¡ããããæš¹èãš
ããŠã¯å¥œãŸãããªãã æ¬çºæã«å«æãããå éåéå§å€ã¯ãäž»ã«çŽ«å€
éšã®å ãåžåããŠå±èµ·ããã€ãªã³ãããã¯æŽ»æ§ã©
ãžã«ã«ãçºçããã¢ãããŒãšåå¿ããŠéåãéå§
ããããããããã¯å ã«ããå±èµ·ããããããã¢
ãããŒååãšè¡çªããŠã¢ãããŒã掻æ§åãéåã
éå§ããããããªç©è³ªãã§ããã°ã©ã®ãããªçš®é¡
ã®ãã®ã§ãã€ãŠãããããã®å ·äœäŸãšããŠã¯ãã
ã³ãŸã€ã³ïŒãã³ãŸã€ã³ã¡ãã«ãšãŒãã«ïŒãã³ãŸã€
ã³ãšãã«ãšãŒãã«ïŒãã³ãŸã€ã³ã€ãœãããã«ãšãŒ
ãã«ïŒãã³ãŸã€ã³ã€ãœããã«ãšãŒãã«ïŒÎ±âã¡ã
ã«ãã³ãŸã€ã³çã®ã¢ã·ãã€ã³ãšãã®èªå°äœãïŒâ
ã¡ãã«ã¢ã³ãœã©ããã³ïŒïŒâãšãã«ã¢ã³ãœã©ãã
ã³ïŒã·ã¯ããããµãã³çã®ã«ã«ããã«ååç©ãã
ã³ãžã«ïŒãžã¢ã»ãã«çã®ãžã±ãã³é¡ãã¢ã»ãããš
ãã³ïŒ2.2âãžãšããã·ã¢ã»ãããšãã³ïŒãã³ãŸ
ããšãã³ïŒããããªããšãã³ïŒããšãã«âïŒâã
ãšãã«ã±ãã³ïŒïŒ°âãžã¡ãã«ã¢ãããã³ãŸããšã
ã³ïŒP.Pâ²âããã©ã¡ãã«ãžã¢ãããã³ãŸããšã
ã³ïŒP.Pâ²âããã©ãšãã«ãžã¢ãããã³ãŸããšãã³
çã®ããšãã³é¡ãããšãã«ã°ãªãªãã·ã«é žã¡ã
ã«ïŒããšãã«ã°ãªãªãã·ã«é žãšãã«ïŒããšãã«ã°
ãªãªãã·ã«é žããã«ïŒããšãã«ã°ãªãªãã·ã«é žã
ããã·ãšãã«çã®ããšãã«ã°ãªãªãã·ã«é žãšã¹ã
ã«é¡ããžããšãã«ã¢ããµã«ãã¢ã€ãïŒãžããšãã«
ãžãµã«ãã¢ã€ãïŒãã·ã«ããšãã«ã¢ããµã«ãã¢ã€
ãïŒããã©ã¡ãã«ããŠã©ã ã¢ããµã«ãã¢ã€ãçã®
ææ©ãµã«ãã¢ã€ãé¡ãâãã«ãšã³ã¹ã«ããã«ã¯
ãã©ã€ãïŒïŒâããã¿ã¬ã³ã¹ã«ããã«ã¯ãã©ã€
ãïŒïŒâããã¿ã¬ã³ã¹ã«ããã«ã¯ãã©ã€ãïŒ1.3
âãã³ãŒã³ãžã¹ã«ããã«ã¯ãã©ã€ãïŒ2.4âãžã
ãããã³ãŒã³ã¹ã«ããã«ãããã€ãïŒïŒ°âã¢ã»ã
ã¢ãžããã³ãŒã³ã¹ã«ããã«ã¯ãã©ã€ãçã®ã¹ã«ã
ãã«ãã©ã€ãé¡ãåå¡©åççŽ ïŒåèåççŽ ïŒãã
ãµããã¢ãšã¿ã³ïŒãšãŒããã«ã ïŒ1.1.2.2âããã©
ããã¢ãšã¿ã³çã®ããã²ã³åçåæ°ŽçŽ é¡ããšãªã·
ã³ïŒããªãã³ïŒãã«ãªã¬ã¹ã»ã€ã³ïŒãªããã©ãã³
çã®ææé¡ãªã©ãå«ãŸããã æ¬çºæã®è¢«èŠçšçµæç©ã¯äžè¿°ã®ïŒæåãäž»æå
ãšãããã(A)ïŒ(B)ïŒ(C)åæåã®åèšééäžã«å ã
ãå²åã¯ã(A)æåã10ã80ééïŒ ã§ããã10ïŒ æª
æºã§ã¯å¡èã®æ¶æ©åºŠåãäžååã§è溶å€æ§ãäœ
ããäžæ¹80ïŒ ãè¶ãããšããªãªã¬ãã€ã³ã«å¯Ÿãã
ä»çæ§ãäžè¯ãšãªãã®ã§å¥œãŸãããªãã(B)æåã¯
ïŒã80ééïŒ ã奜é©ã§ãããïŒïŒ æªæºã§ã¯ããªãª
ã¬ãã€ã³ã«å¯Ÿããä»çæ§ãååã§ãªãããŸã80ïŒ
ãè¶ãããšå¡èã®èåæ§ãèæ²¹æ§ãæªåããã®ã§
奜ãŸãããªãã(C)æåã¯10ã70ééïŒ ã奜é©ã§ã
ãã10ïŒ æªæºã§ã¯å¡èã®çžæº¶æ§ãäžååã§ããŸã
70ïŒ ãè¶ãããšããªãªã¬ãã€ã³ã«å¯Ÿããä»çæ§ã
äœäžããã®ã§å¥œãŸãããªããæ¬çºæã®è¢«èŠçµæç©
ã«å«æãããå éåéå§å€ã¯éåžžã被èŠçµæç©ã®
(A)ïŒ(B)ïŒ(C)åæåã®åèšééã«å¯Ÿã0.1ã20éé
ïŒ ã奜ãŸããã¯0.5ã10ééïŒ ã®ç¯å²ã§äœ¿çšãã
ãã æ¬çºæã®è¢«èŠçµæç©äžã«ã¯ãäžè¿°ããåæåã«
å ããåæåãšæ¶æ©çµåããããã«åºãæããä»
å çåéäœãååšããŠãããããããã®äŸãšããŠ
ã¯ïŒ®âããã«âïŒâãããªãã³ïŒã¹ãã¬ã³ïŒÎ±â
ã¡ãã«ã¹ãã¬ã³ïŒããã«ãã«ãšã³ïŒå®æ¯éŠé žãã
ã«ïŒé ¢é žããã«ïŒããããªã³é žããã«çãããã
ããããç¹ã«å¥œãŸãããã®ã¯ã¢ãã¢ã¯ãªã«å®èœæ§
ãæããåéäœã§ãäŸãã°ïŒã¡ã¿ïŒã¢ã¯ãªã«é žã¡
ãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žãšãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãª
ã«é žãããã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žããã«ïŒïŒã¡
ã¿ïŒã¢ã¯ãªã«é žããã·ã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žã
ããã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žã¡ããã·ãšãã«ïŒïŒã¡
ã¿ïŒã¢ã¯ãªã«é žãšããã·ãšãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãª
ã«é žãããã·ãšãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žã¡ãã
ã·ãšããã·ãšãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žãšããã·
ãšããã·ãšãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žããã©ãã
ããã«ããªã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žããããã·ãš
ãã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žããããã·ãããã«ïŒ
ïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâãšãã«ããã·ã«ïŒïŒã¡ã¿ïŒ
ã¢ã¯ãªã«é žã·ã¯ãããã·ã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é ž
ãã³ãžã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žãžã·ã¯ããã³ãã
ã«ïŒïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒâãžã·ã¯ããã³ããã
ã·ãšãã«çãããããããããã¯åç¬ã§ãŸãã¯äº
皮以äžã®æ··åç©ãšããŠçšããããããããåéäœ
ã¯æš¹èãšæ··åæ§ã®æ¶²ç¶ååç©ã§ããããšãæãŸã
ãã æ¬çºæçµæç©ã«ã¯ä¿åæã«ãããã²ã«åé²æ¢ã®
ããã«éåçŠæ¢å€ãæ·»å ããããšãã§ãããã®ä»£
è¡šçãªäŸãšããŠã¯ãâãã³ãŸããã³ïŒãã€ãã
ããã³ïŒãã€ããããã³ã¢ãã¡ãã«ãšãŒãã«ïŒïŒ°
âtertâããã«ã«ãã³ãŒã«ïŒã¢ãâtertâããã«
ãã€ããããã³ïŒÎ±âããããŒã«ïŒããã¬ããŒã«
çãå«ãŸããã æ¬çºæã®è¢«èŠçµæç©ã«ãéåžžå¡æãŸãã¯å°å·ã€
ã³ãã«äœ¿çšãããé¡æãæ·»å ããããšãã§ããã
ã®äŸãšããŠã¯ã·ãªã«ãã©ã€ãïŒçé žã«ã«ã·ãŠã ïŒ
ã¿ã«ã¯ïŒã±ã€é žãã°ãã·ãŠã ïŒã±ã€é žã¢ã«ãããŠ
ã ïŒæ²éæ§ç¡«é žããªãŠã çã®äœè³ªé¡æãäºéè¯ïŒ
é¡éïŒçŽºéïŒé žåãã¿ã³ïŒãã³ã¬ã©ïŒã«ãŒãã³ã
ã©ãã¯çã®ç¡æ©é¡æãããªãªã¢ã³ãã«ãŒãã³6BïŒ
ã¬ãŒãã¬ããïŒããŒããã³ãã¬ããïŒããªãŸ
ãŒã«ã¬ããïŒãã³ãžãžã³ã€ãšããŒïŒãã³ã¶ã€ãšã
ãŒïŒãã¿ãã·ã¢ãã³ãã«ãŒïŒã·ã³ã«ã·ã¢ã¬ããç
ã®ææ©é¡æçãå«ãŸããããŸãåæ§ã«ææãéæ
æ·»å ããããšãã§ããã æ¬çºæçµæç©ã«ã¯ãã®ç²åºŠèª¿æŽã®ããã«ïŒçš®ãª
ããïŒçš®ä»¥äžã®äžæŽ»æ§ãªæ®çºæ§ææ©æº¶åªã䜿çšã
ãããšãã§ããäŸãã°ã¢ã»ãã³ïŒã¡ãã«ãšãã«ã±
ãã³ïŒã¡ãã«ã€ãœããã«ã±ãã³ïŒã¡ãã«ã¢ã«ã³ãŒ
ã«ïŒãšãã«ã¢ã«ã³ãŒã«ïŒãããã«ã¢ã«ã³ãŒã«ïŒç¬¬
äºããã«ã¢ã«ã³ãŒã«ïŒã€ãœããã«ã¢ã«ã³ãŒã«ïŒç¬¬
äžããã«ã¢ã«ã³ãŒã«ïŒé ¢é žã¡ãã«ïŒé ¢é žãšãã«ïŒ
é ¢é žããã«ïŒé ¢é žã€ãœããã«ïŒé ¢é žã¢ãã«ïŒãã³
ãŒã³ïŒãã«ãšã³ïŒãã·ã¬ã³ïŒã»ããœã«ãïŒãšãã«
ã»ããœã«ãïŒé ¢é žã»ããœã«ãïŒããã©ããããã©
ã³çãå«ãŸããã æ¬çºæçµæç©ã«ã¯çš®ã ã®ç®çã§å¡æãããã¯å°
å·ã€ã³ãã«æ·»å ãããã·ãªã³ãŒã³çã®æ¶æ³¡å€ãã¬
ããªã³ã°å€ãããå·é²æ¢å€ãããªãªãã·ãšãã¬ã³
ã°ãªã³ãŒã«ã¢ã«ãã«ãšãŒãã«çã®åž¯é»é²æ¢å€ã
2.2â²âãžããããã·âïŒâã¡ããã·ãã³ãŸããšã
ã³çã®çŽ«å€ç·åžåå€ãã¢ã«ãããŠã ãªã¯ããšãŒ
ãïŒã·ãªã«ã²ã«çã®å¢ç²å€ããã®ä»æ²æŸ±é²æ¢å€ã
ããé²æ¢å€ãè²å¥ãé²æ¢å€ãé¡æåæ£å€ãç²çé²
æ¢å€ãç®åŒµãé²æ¢å€ãé£çå€ãé²éå€ãè·æ¶ãå€
ãªã©å皮添å å€ãªããæ·»å å©å€ã®ãããã䜿çšã§
ããã æ¬çºæã®è¢«èŠçµæç©ã¯ä»ãŸã§è¿°ã¹ãŠããçš®ã ã®
æåãéåžžã¯æ··åããã ãã§è£œé ããããæ··åã¯
äžè¬ã«ã¯å®€æž©ã§è¡ãªããå¿ èŠã«å¿ããŠå ç±ããŠè¡
ãªãããšãã§ããã æ¬çºæã®è¢«èŠçµæç©ãåºæã«è¢«èŠããã«ããã€
ãŠã¯å¹ä»ããã«ãŒãã³å¡ãã浞挬ãããŒã«å¡ãã
ã¹ã¯ãªãŒã³å°å·çã®æ¹æ³ãçšããããšãã§ããã
ãŸãæ¬çºæã®çµæç©ã硬åãããããã«ã¯æ°Žéã¢
ãŒã¯ãççŽ ã¢ãŒã¯ãäœå§æ°Žéã©ã³ããäžå§æ°Žéã©
ã³ããé«å§æ°Žéã©ã³ããé«åšæ³¢èªèµ·æ°Žéã©ã³ãã
ãã»ãã³ãã©ãã·ãŠã©ã³ãçã®çŽ«å€ç·ãçºããä»»
æã®ç §å°è£ 眮ãçšããã°ããã æ¬çºæã®è¢«èŠçµæç©ã¯ä»ãŸã§è¿°ã¹ãããšããç¹
å®ã®ã¢ã¯ãªã«ç³»æš¹èã䜿çšããããšã«ãã€ãŠåæ
åéã®çžæº¶æ§ãèããæ¹è¯ããã°ããã§ãªããã
ããããªãªã¬ãã€ã³ç³»æš¹èæååã«å¡è£ ã硬åã
ãå Žåã玫å€ç·ã®ç §å°ã«ãã€ãŠå®€æž©ã§çæéã«ç¡¬
åãããããšãã§ããäžã€åŸãããå¡èã¯è©²æå
åè¡šé¢ã«åŒ·åã«ä»çãã硬床ãå æ²¢ãèåæ§ãè
è¬åæ§ãè溶å€æ§ãèæ©èæ§ãªã©ã«ããããæ§èœ
ãåããã ãŸããæ¬çºæçµæç©ãçšããããšã«ãããåŸæ¥
ããªãªã¬ãã€ã³ç³»æš¹èæååã«å¡è£ ãŸãã¯å°å·ã
ãã«ããã€ãŠäžè¬ã«è¡ãªãããŠãã(1)溶å€è±è(2)
ã¯ãã é žåŠççã®è¡šé¢åŠç(3)æ°ŽæŽã也ç¥(4)äžå¡
ãã也ç¥(5)äžå¡ãã也ç¥ãšããå·¥çšããæååè¡š
é¢äžã®æº¶å€è±èãè¡ãã ããšããããããŠç°¡ç¥ãª
ãã®ã«ããããšãå¯èœã«ããã³ã¹ãçã«ãåŸæ¥æ³
ã«æ¯ã¹åªäœã«ç«ã€ããšãã§ããã äžèšåæäŸãå®æœäŸäžãéšã¯éééšãããã
ãã åæäŸ ïŒ æ¹æåšã枩床èšãåçž®åšãå šçž®åšããã³çªçŽ ã¬
ã¹å°å ¥ç®¡ãè£ åããåå¿å®¹åšã«ç¡æ°Žãã¬ã€ã³é ž
235éšãç¡æ°Žãã¿ã«é ž178éšããããã¬ã³ã°ãªã³ãŒ
ã«230éšããžãšãã¬ã³ã°ãªã³ãŒã«137éšãä»èŸŒã¿ã
çªçŽ ã¬ã¹ãæµããªãã210âã§ïŒæéãçž®åæ°Žã
é€å»ãã€ã€åå¿ãè¡ãªããé žäŸ¡12ã§åå¿ãçµäºã
ããåŸãããäžé£œåããªãšã¹ãã«70éšãã¹ãã¬ã³
30éšã«æº¶è§£ããŠåŸããããã®ãåæç©ïŒ¡ãšããã åæäŸ ïŒ åæäŸïŒãšåäžåå¿å®¹åšã«ç¡æ°Žãã¿ã«é ž207éšã
ããªãã³ãã«ã°ãªã³ãŒã«321éšãä»èŸŒã¿ãçªçŽ ã¬
ã¹ãæµããªãã210âã§ïŒæéãçž®åæ°Žãé€å»ã
ã€ã€åå¿ãè¡ãªããé žäŸ¡0.5ã§åå¿ãçµäºããã
åŸãããããªãšã¹ãã«ã®æ°Žé žåºäŸ¡ã¯376ã§ãã€ãã
ãã®ããªãšã¹ãã«418éšã«ã¢ã¯ãªã«é ž253éšããã€
ããããã³ïŒéšãæ¿ç¡«é ž15.4éšããã«ãšã³100éš
ãå ããæ¹æåšã枩床èšããã³ãã€ãŒã³ã¹ã¿ãŒã¯
åãã©ãããè£ åããåå¿å®¹åšã§95ã100âãæž
å§äžã§çž®åæ°Žãé€å»ããªããïŒæéåå¿ãç¶ãã
çž®åæ°Žãåºãªããªã€ãæç¹ã§åå¿ãçµäºããæªå
å¿ã®ã¢ã¯ãªã«é žããã€ããããã³ãæ¿ç¡«é žãã¢ã«
ã«ãªæŽæµããã³æ°ŽæŽæµã«ãã€ãŠé€å»ããŠããªãšã¹
ãã«ã¢ã¯ãªã¬ãŒããåŸãããããåæç©ïŒ¢ãšã
ãã åæäŸ ïŒ åæäŸïŒãšåäžåå¿å®¹åšã«ãšãã¬ã³ã°ãªã³ãŒã«
273éšãç¡æ°Žãã¿ã«é ž296éšãä»èŸŒã¿ãçªçŽ ãæµã
ãªãã210âã§ïŒæéçž®åæ°Žãé€å»ãã€ã€åå¿ã
è¡ãªããé žäŸ¡0.8ã§åå¿ãçµäºãããåŸãããã
ãªãšã¹ãã«777éšãã¢ã¯ãªã«é ž475éšããã«ãšã³
173éšããã€ããããã³9.6éšãåæäŸïŒãšåäžå
å¿å®¹åšã«ä»èŸŒã¿ã95ã100âãæžå§äžã§çž®åæ°Žã
é€å»ãã€ã€ïŒæéåå¿ãç¶ããçž®åæ°Žãåºãªããª
ã€ãæç¹ã§åå¿ãçµäºãã以äžåæäŸïŒãšåäžåŠ
çã«ãŠããªãšã¹ãã«ã¢ã¯ãªã¬ãŒããåŸããããã
åæç©ïŒ£ãšããã åæäŸ ïŒ åæäŸïŒãšåäžæ¹æ³ã«ãŠã¢ãžãã³é ž292éšãšã
ãããã·ãããªã«ããããã·ããã¬ãŒã898éšã
çšããŠæ°Žé žåºäŸ¡279ã®ããªãšã¹ãã«ãåŸãããã®
ããªãšã¹ãã«ãšã¢ã¯ãªã«é žãšãåæäŸïŒãšåäžæ¹
æ³ã«ãŠçž®åããŠããªãšã¹ãã«ã¢ã¯ãªã¬ãŒããåŸ
ãããããåæç©ïŒ€ãšããã åæäŸ ïŒ æ°Žæ·»ãã¹ããšããŒã«ïŒ¡ãžã°ãªã·ãžã«ãšãŒãã«
ïŒãšããã·åœé260ïŒ260éšãã¢ã¯ãªã«é ž72éšãã
ã€ããããã³ã¢ãã¡ãã«ãšãŒãã«0.1éšãããªãš
ãã«ã¡ãã«ã¢ã³ã¢ããŠã ã¯ããªãïŒéšãçšããŠ95
âã§ïŒæéåå¿ããé žäŸ¡ïŒä»¥äžã®ãšããã·ã¢ã¯ãª
ã¬ãŒããåŸãããããåæç©ïŒ¥ãšããã åæäŸ ïŒ ãã¿ã«é žãžã°ãªã·ãžã«ïŒãšããã·åœé200ïŒ200
éšãã¢ã¯ãªã«é žïŒâããããã·ãšãã«116éšãç¡
æ°Žããã·ãã«ã³ãã¯é ž266éšãããªãšãã«ã¢ã³ã¢
ããŠã ã¯ããªãïŒéšããã€ããããã³ã¢ãã¡ãã«
ãšãŒãã«0.1éšãçšããŠ95âã§ïŒæéåå¿ããé ž
䟡ïŒä»¥äžã®ãšããã·ã¢ã¯ãªã¬ãŒããåŸããããã
åæç©ïŒŠãšããã åæäŸ ïŒ æ°Žæ·»ãã¹ããšããŒã«ïŒ¡ã«ãããã¬ã³ãªããµã€ã
ãä»å ããŠåŸããããžãªãŒã«ååç©ïŒæ°Žé žåºäŸ¡
320ïŒ701éšãšãã€ããããã³ã¢ãã¡ãã«ãšãŒãã«
ïŒéšãšããæ¹æåšã枩床èšããã³æ»ŽäžããŒããè£
åããåå¿å®¹åšãä»èŸŒã¿ã70âã§ãããµã¡ãã¬ã³
ãžã€ãœã·ã¢ããŒã168éšãšã€ãœããã³ãžã€ãœã·ã¢
ããŒã444éšãšãïŒæéã§æ»Žäžããå枩床ã§æŽã«
ïŒæéåå¿ãç¶ãããããåŸã¢ã¯ãªã«é žïŒâãã
ããã·ãããã«260éšãïŒæéã§æ»ŽäžããNCOåº
åå¿çã99ïŒ ä»¥äžãšãªã€ããšããã§åå¿ãçµäº
ãããŠã¬ã¿ã³ã¢ã¯ãªã¬ãŒããåŸãããããåæç©
ãšããã åæäŸ ïŒ ã¡ã¿ã¯ãªã«é žã€ãœããã«67éšãã¡ã¿ã¯ãªã«é žïŒ
âããããã·ãšãã«10éšãã¡ã¿ã¯ãªã«é žã¡ãã«21
éšãã¢ã¯ãªã«é žïŒéšããã³ã¢ãŸãã¹ã€ãœãããã
ããªã«ïŒéšãããªãæ··åç©ã90âã®ã€ãœãããã
ãŒã«15éšããã«ãšã³85éšãããªãæ··å溶å€äžã«æ¹
æããªããïŒæéãããŠæ»ŽäžããæŽã«å枩床ã§ïŒ
æééåããŠã¢ã¯ãªã«æš¹èãåŸãã åæäŸ ïŒ åæäŸïŒãšåäžæ¹æ³ã«ãŠã¡ã¿ã¯ãªã«é žã€ãœãã
ã«60éšãã¹ãã¬ã³20éšãã¡ã¿ã¯ãªã«é žã¡ãã«20éš
ãããªãã¢ã¯ãªã«æš¹èãåŸãã åæäŸ 10 åæäŸïŒãšåäžæ¹æ³ã«ãŠã¡ã¿ã¯ãªã«é žã€ãœãã
ã«20éšãã¡ã¿ã¯ãªã«é žïŒâããããã·ãšãã«15
éšãã¡ã¿ã¯ãªã«é žã¡ãã«40éšããã³ã¹ãã¬ã³25éš
ãããªãã¢ã¯ãªã«æš¹èãåŸãã å®æœäŸ ïŒ åæç©A50éšãããªãã³ãã«ã°ãªã³ãŒã«ãžã¢ã¯
ãªã¬ãŒã10éšãã¢ã¯ãªã«æš¹èA38éšãå¡©çŽ å床27
ïŒ ã®å¡©çŽ åããªãããã¬ã³æš¹è溶液ïŒæ±æŽåææ ª
åŒäŒç€Ÿè£œåã®ããŒãã¬ãžã³14LLBããã«ãšã³æº¶
液ãåºåå15ïŒ ïŒ140éšããã³ãŸã€ã³ã€ãœããã«
ãšãŒãã«ïŒéšããã³ãã·ã¬ã³50éšã調åããŠçŽ«å€
ç·ç¡¬ååå¡æãåŸãããã®å¡æ溶液ã¯å®å šã«ã¯ãª
ã¢ã§ãã€ãããã®å¡æããã«ãšã³ã§æŽæµããç¡åŠ
çã®ããªãããã¬ã³æååããã«ã«ç¡¬åèåã
20ÎŒãšãªãããã«ã¹ãã¬ãŒå¡è£ ãã宀枩ã§ïŒåé
ã»ããã€ã³ã°ããåŸãé«å§æ°Žéç¯ïŒ80ã¯ããïŒcm
匷床ïŒäž20cmã®ãšããã§ç©ºæ°äžã§çŽ«å€ç·ã10ç§é
ç §å°ãããšããå®å šã«ç¡¬åããéæã§å æ²¢ã®ãã
å¡é¢ãåŸãããããã®ããã«ã®æ§èœè©äŸ¡çµæã第
ïŒè¡šã«ç€ºãã å®æœäŸ ïŒãïŒ å®æœäŸïŒãšåäžèŠé ã§ç¬¬ïŒè¡šã«ç€ºãé åã«ãŠèª¿
åãã玫å€ç·ç¡¬ååå¡æããããã第ïŒè¡šã«ç€ºã
åºæã«å®æœäŸïŒãšåäžæ¹æ³ã«ãŠå¡è£ ã硬åãã
ãããããã®æ§èœè©äŸ¡çµæã¯ç¬¬ïŒè¡šã«ç€ºãã
ãè¡šã
ãè¡šã
å®æœäŸ ïŒ
å®æœäŸïŒãšåäžã®çŽ«å€ç·ç¡¬ååå¡æããã«ãšã³
ã§æŽæµããç¡åŠçããªãããã¬ã³æååã«ç¡¬åè
åã20ÎŒãšãªãããã«ã¹ãã¬ãŒå¡è£ ãã宀枩ã§ïŒ
åéã»ããã€ã³ã°ããåŸãé«å§æ°Žéç¯ïŒ80ã¯ã
ãïŒcm匷床ïŒäž20cmã®ãšããã§ç©ºæ°äžã§çŽ«å€ç·ã
10ç§éç §å°ã被èã硬åãããã次ã«ãã®æåå
ã«ç空èžçæ³ã«ããã¢ã«ãããŠã ã0.2ÎŒã®åã«èž
çå å·¥ããè¡šé¢ã«éå±èèãæããæååãåŸ
ãããã®ãã®ã¯çŸããé«å æ²¢ã®é¡é¢ãæããŠã
ãã80âã§24æéã®é£ç¶ã®èç±ãã¹ããè¡ãªã€ãŠ
ãè¡šé¢ããããããšããªããèç±ãã¹ãåŸã®ä»ç
æ§ãå®å šã§ãããã¯ãé¢ãã¹ãã®å¡é¢åã³éå±è
ã®ã¯ãé¢ã¯å šç¶èŠãããªãã€ãã å®æœäŸ 10 åæç©E40éšããžãã³ã¿ãšãªã¹ãªããŒã«ãããµ
ã¢ã¯ãªã¬ãŒã20éšãã¹ãŒããŒã¯ãã³C40éšãã¢ã¯
ãªã«æš¹èA30éšããã³ãŸããšãã³ïŒéšãããã©ãŒ
ãºã±ãã³ïŒéšãã·ã¢ãã³ãã«ãŒ18éšããã³2.6â
ãžâtertâããã«ïŒ°âã¯ã¬ãŸãŒã«0.2éšãæ··åãïŒ
æ¬ããŒã«ãã«ã§ç·ŽåããŠçŽ«å€ç·ç¡¬ååã€ã³ããã€
ãã€ãããã®ã€ã³ããRIãã¹ã¿ãŒã§ããªããã
ã¬ã³ã·ãŒãäžã«3ÎŒã®èåã§å±è²ããåŸãé«å§æ°Ž
éç¯ïŒ80ã¯ããïŒcm匷床ïŒäž10cmã®ãšããã§çŽ«å€
ç·ãïŒç§éç §å°ãã€ã³ãã硬åãããããã®ã€ã³
ãã¯åºæã«ããä»çããŠãããã¯ãé¢ãã¹ãã§ã
ã€ã³ãã®ã¯ãé¢ã¯èŠãããªãã€ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã®çŽ«å€ç·ç¡¬ååå¡æããã¢ã¯ãªã«æš¹è
ãé€ããå¡æã調åããŠã¿ãããã®å¡æã¯èª¿å
åŸã«ãããèŠãããããã®å¡æãå®æœäŸïŒãšåæ§
ã«ããªãããã¬ã³æåããã«ã«å¡è£ ãã硬åãã
ãŠã¿ããå æ²¢ã®ããå¡é¢ã¯åŸãããªãã€ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã®çŽ«å€ç·ç¡¬ååå¡æã®ã¢ã¯ãªã«æš¹è
ãåæäŸïŒã§è¿°ã¹ãã¢ã¯ãªã«æš¹èãšæããå¡æ
ã調åããããã®å¡æã¯èª¿ååŸã«ãããèŠããã
ãã°ããæŸçœ®ããŠãããæ²æŸ±ç©ãçããã æ¯èŒäŸ ïŒ å®æœäŸïŒã®çŽ«å€ç·ç¡¬ååå¡æã®ã¢ã¯ãªã«æš¹è
ãåæäŸ10ã®ã¢ã¯ãªã«æš¹èã«æããå¡æã調å
ããããã®å¡æã¯èª¿ååŸã«ãããèŠããããã°ã
ãæŸçœ®ããŠãããæ²æŸ±ç©ãçããã
ã§æŽæµããç¡åŠçããªãããã¬ã³æååã«ç¡¬åè
åã20ÎŒãšãªãããã«ã¹ãã¬ãŒå¡è£ ãã宀枩ã§ïŒ
åéã»ããã€ã³ã°ããåŸãé«å§æ°Žéç¯ïŒ80ã¯ã
ãïŒcm匷床ïŒäž20cmã®ãšããã§ç©ºæ°äžã§çŽ«å€ç·ã
10ç§éç §å°ã被èã硬åãããã次ã«ãã®æåå
ã«ç空èžçæ³ã«ããã¢ã«ãããŠã ã0.2ÎŒã®åã«èž
çå å·¥ããè¡šé¢ã«éå±èèãæããæååãåŸ
ãããã®ãã®ã¯çŸããé«å æ²¢ã®é¡é¢ãæããŠã
ãã80âã§24æéã®é£ç¶ã®èç±ãã¹ããè¡ãªã€ãŠ
ãè¡šé¢ããããããšããªããèç±ãã¹ãåŸã®ä»ç
æ§ãå®å šã§ãããã¯ãé¢ãã¹ãã®å¡é¢åã³éå±è
ã®ã¯ãé¢ã¯å šç¶èŠãããªãã€ãã å®æœäŸ 10 åæç©E40éšããžãã³ã¿ãšãªã¹ãªããŒã«ãããµ
ã¢ã¯ãªã¬ãŒã20éšãã¹ãŒããŒã¯ãã³C40éšãã¢ã¯
ãªã«æš¹èA30éšããã³ãŸããšãã³ïŒéšãããã©ãŒ
ãºã±ãã³ïŒéšãã·ã¢ãã³ãã«ãŒ18éšããã³2.6â
ãžâtertâããã«ïŒ°âã¯ã¬ãŸãŒã«0.2éšãæ··åãïŒ
æ¬ããŒã«ãã«ã§ç·ŽåããŠçŽ«å€ç·ç¡¬ååã€ã³ããã€
ãã€ãããã®ã€ã³ããRIãã¹ã¿ãŒã§ããªããã
ã¬ã³ã·ãŒãäžã«3ÎŒã®èåã§å±è²ããåŸãé«å§æ°Ž
éç¯ïŒ80ã¯ããïŒcm匷床ïŒäž10cmã®ãšããã§çŽ«å€
ç·ãïŒç§éç §å°ãã€ã³ãã硬åãããããã®ã€ã³
ãã¯åºæã«ããä»çããŠãããã¯ãé¢ãã¹ãã§ã
ã€ã³ãã®ã¯ãé¢ã¯èŠãããªãã€ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã®çŽ«å€ç·ç¡¬ååå¡æããã¢ã¯ãªã«æš¹è
ãé€ããå¡æã調åããŠã¿ãããã®å¡æã¯èª¿å
åŸã«ãããèŠãããããã®å¡æãå®æœäŸïŒãšåæ§
ã«ããªãããã¬ã³æåããã«ã«å¡è£ ãã硬åãã
ãŠã¿ããå æ²¢ã®ããå¡é¢ã¯åŸãããªãã€ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã®çŽ«å€ç·ç¡¬ååå¡æã®ã¢ã¯ãªã«æš¹è
ãåæäŸïŒã§è¿°ã¹ãã¢ã¯ãªã«æš¹èãšæããå¡æ
ã調åããããã®å¡æã¯èª¿ååŸã«ãããèŠããã
ãã°ããæŸçœ®ããŠãããæ²æŸ±ç©ãçããã æ¯èŒäŸ ïŒ å®æœäŸïŒã®çŽ«å€ç·ç¡¬ååå¡æã®ã¢ã¯ãªã«æš¹è
ãåæäŸ10ã®ã¢ã¯ãªã«æš¹èã«æããå¡æã調å
ããããã®å¡æã¯èª¿ååŸã«ãããèŠããããã°ã
ãæŸçœ®ããŠãããæ²æŸ±ç©ãçããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ (A) ïŒååäžã«ãšãã¬ã³æ§äžé£œåäºéçµåã
ïŒå以äžæããååç© 10ã80ééïŒ (B) å¡©çŽ åããªãªã¬ãã€ã³ç³»æš¹è ïŒã80ééïŒ (C) ã¡ã¿ã¯ãªã«é žã€ãœããã«åäœã50ééïŒ ä»¥äž
ããã³æ¬¡åŒãã ïŒåŒäžãR1ïŒR2ã¯ããããåã¯CH3ïŒã§
è¡šããããåäœãïŒã40ééïŒ å«ãã¢ã¯ãªã«ç³»
æš¹è 10ã70ééïŒ ãäž»æåãšããå éåéå§å€å«æããªãªã¬ãã€ã³
系暹èçšçŽ«å€ç·ç¡¬åå被èŠçµæç©ã
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13013680A JPS5755969A (en) | 1980-09-19 | 1980-09-19 | Uv-curable coat composition for polyolefin resin |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13013680A JPS5755969A (en) | 1980-09-19 | 1980-09-19 | Uv-curable coat composition for polyolefin resin |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5755969A JPS5755969A (en) | 1982-04-03 |
JPS634595B2 true JPS634595B2 (ja) | 1988-01-29 |
Family
ID=15026812
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP13013680A Granted JPS5755969A (en) | 1980-09-19 | 1980-09-19 | Uv-curable coat composition for polyolefin resin |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5755969A (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007269951A (ja) * | 2006-03-31 | 2007-10-18 | Fujikura Kasei Co Ltd | éå±åºæçšããŒã¹ã³ãŒãå¡æçµæç© |
US10787590B2 (en) | 2018-12-26 | 2020-09-29 | Industrial Technology Research Institute | Polymer and coating material |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01117983A (ja) * | 1987-10-30 | 1989-05-10 | Fuji Heavy Ind Ltd | ãšã³ãžã³ã®å§åè£ çœ® |
JP2004128139A (ja) | 2002-10-01 | 2004-04-22 | Sony Corp | ã¬ãŒã¶å çºçè£ çœ®åã³ãã®è£œé æ¹æ³ |
JP5433195B2 (ja) * | 2008-10-01 | 2014-03-05 | äžè±ã¬ã€ãšã³æ ªåŒäŒç€Ÿ | 被èŠæçµæç©ããã³æåå |
JP5282918B2 (ja) * | 2011-02-14 | 2013-09-04 | æ±æŽå·¥æ¥å¡ææ ªåŒäŒç€Ÿ | è»äž¡çšç¯å ·ã«äœ¿çšããããšã¯ã¹ãã³ã·ã§ã³åºæã®ã¢ã³ããŒã³ãŒãçšå¡æãã¢ã³ããŒã³ãŒãçšå¡æãçšããå¡è圢ææ¹æ³ãå¡è圢ææ¹æ³ã«ããåŸããããšã¯ã¹ãã³ã·ã§ã³ãæããè»äž¡çšç¯å · |
-
1980
- 1980-09-19 JP JP13013680A patent/JPS5755969A/ja active Granted
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007269951A (ja) * | 2006-03-31 | 2007-10-18 | Fujikura Kasei Co Ltd | éå±åºæçšããŒã¹ã³ãŒãå¡æçµæç© |
US10787590B2 (en) | 2018-12-26 | 2020-09-29 | Industrial Technology Research Institute | Polymer and coating material |
Also Published As
Publication number | Publication date |
---|---|
JPS5755969A (en) | 1982-04-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4173682A (en) | Process for coating a substrate with a radiation and moisture curable coating composition | |
JP5133481B2 (ja) | è£ä¿®å¡è£ æ¹æ³ | |
US5932282A (en) | Process for producing a repair coating | |
JPS6241982B2 (ja) | ||
US20030059555A1 (en) | Coating composition | |
JPH02292376A (ja) | æ°Žæ§ã®ç±ç¡¬åæ§å¡æç©è³ªããã³ãã®è£œæ³ | |
JPH04311714A (ja) | å 硬åæ§æš¹èçµæç© | |
JPS634595B2 (ja) | ||
US4224357A (en) | Method and composition for forming electron beam curing high build coating | |
JP2012017404A (ja) | å 硬ååæš¹èçµæç©åã³ãããçšããå 硬ååã³ãŒãã£ã³ã°å€ | |
JP5748209B2 (ja) | å¡æçµæç©åã³å¡è£ ç©å | |
JP2002194013A (ja) | ãšãã«ã®ãŒç·ç¡¬ååæš¹èçµæç©ããã³å¡è圢ææ¹æ³ | |
JP4184650B2 (ja) | å 硬ååãã©ã€ããŒçµæç©åã³ãããçšããå¡è£ æ¹æ³ | |
JP2002292334A (ja) | å¡è圢ææ¹æ³ | |
JP2005281412A (ja) | å 硬ååæš¹èçµæç©åã³ãããçšããå 硬ååã³ãŒãã£ã³ã°å€ãå 硬ååãã£ã«ã | |
JP2002038056A (ja) | 掻æ§ãšãã«ã®ãŒç·ç¡¬ååå¡æçšçµæç© | |
KR20020086705A (ko) | ì 잵첎, ì ì°© ë°©ë² ë° íì± ìëì§ì -겜íì± ì¡°ì±ë¬Œ | |
JPH0931362A (ja) | éé»å¡è£ çšå 硬åæ§äžå°å¡æåã³ãããçšããéé»å¡è£ æ¹æ³ | |
JP3828398B2 (ja) | å¡è£ æ¹æ³ | |
JPS5819355B2 (ja) | ãã¢ãããœãŠã·ã¢ã²ããŠã㊠| |
JPH0570534A (ja) | 掻æ§ãšãã«ã®ãŒç·ç¡¬ååæš¹è調補ç©ãªãã³ã«æš¹èçµæç© | |
JPH1180661A (ja) | å¡è£ ä»äžãæ¹æ³ããã³å¡è£ ç©å | |
JP3483304B2 (ja) | 玫å€ç·ç¡¬ååã€ã³ãå°å·çšäžå°å¡æçµæç© | |
JP3730352B2 (ja) | ããçµæç©åã³ãããçšããè£ä¿®å¡è£ æ¹æ³ | |
JP6940720B1 (ja) | å 硬åæ§æš¹èçµæç©ãè»äž¡çšå¡æãåã³ãå¡è£ ç©å |