JPS6342616B2 - - Google Patents
Info
- Publication number
- JPS6342616B2 JPS6342616B2 JP55139985A JP13998580A JPS6342616B2 JP S6342616 B2 JPS6342616 B2 JP S6342616B2 JP 55139985 A JP55139985 A JP 55139985A JP 13998580 A JP13998580 A JP 13998580A JP S6342616 B2 JPS6342616 B2 JP S6342616B2
- Authority
- JP
- Japan
- Prior art keywords
- urethane
- group
- acid
- polyphenyl
- polymethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 62
- 238000006243 chemical reaction Methods 0.000 claims description 51
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 48
- 239000003054 catalyst Substances 0.000 claims description 46
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 43
- LBKPGNUOUPTQKA-UHFFFAOYSA-N ethyl n-phenylcarbamate Chemical compound CCOC(=O)NC1=CC=CC=C1 LBKPGNUOUPTQKA-UHFFFAOYSA-N 0.000 claims description 38
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 28
- 239000002904 solvent Substances 0.000 claims description 28
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 24
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 23
- 239000002253 acid Substances 0.000 claims description 23
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 22
- 239000004202 carbamide Substances 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 16
- 239000002184 metal Substances 0.000 claims description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- 229920006389 polyphenyl polymer Polymers 0.000 claims description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 238000009833 condensation Methods 0.000 claims description 12
- 230000005494 condensation Effects 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 229910021529 ammonia Inorganic materials 0.000 claims description 11
- LSWFBJLZNDQCQB-UHFFFAOYSA-N prop-1-en-2-yl n,n-diphenylcarbamate Chemical compound C=1C=CC=CC=1N(C(=O)OC(=C)C)C1=CC=CC=C1 LSWFBJLZNDQCQB-UHFFFAOYSA-N 0.000 claims description 11
- 229920001228 polyisocyanate Polymers 0.000 claims description 10
- 239000005056 polyisocyanate Substances 0.000 claims description 10
- 229910052725 zinc Inorganic materials 0.000 claims description 10
- 239000011701 zinc Substances 0.000 claims description 10
- 150000007513 acids Chemical class 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 238000009835 boiling Methods 0.000 claims description 8
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 8
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 239000007791 liquid phase Substances 0.000 claims description 7
- 239000010936 titanium Chemical class 0.000 claims description 7
- 229910052719 titanium Chemical class 0.000 claims description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical class [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 150000001735 carboxylic acids Chemical class 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 238000000197 pyrolysis Methods 0.000 claims description 5
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 claims description 4
- 150000001768 cations Chemical class 0.000 claims description 4
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims description 4
- 239000012071 phase Substances 0.000 claims description 4
- 230000001588 bifunctional effect Effects 0.000 claims description 3
- 229940098779 methanesulfonic acid Drugs 0.000 claims description 3
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 claims description 3
- 150000003751 zinc Chemical class 0.000 claims description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- 229960005215 dichloroacetic acid Drugs 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 150000002892 organic cations Chemical class 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 claims description 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims 1
- 125000002252 acyl group Chemical group 0.000 claims 1
- 230000008030 elimination Effects 0.000 claims 1
- 238000003379 elimination reaction Methods 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 30
- -1 N-substituted urethanes Chemical class 0.000 description 22
- 235000013877 carbamide Nutrition 0.000 description 18
- 239000011541 reaction mixture Substances 0.000 description 17
- 239000012948 isocyanate Substances 0.000 description 16
- 238000000354 decomposition reaction Methods 0.000 description 15
- 150000002513 isocyanates Chemical class 0.000 description 15
- 238000004821 distillation Methods 0.000 description 13
- 150000002148 esters Chemical class 0.000 description 13
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 150000001298 alcohols Chemical class 0.000 description 8
- GTCAXTIRRLKXRU-UHFFFAOYSA-N methyl carbamate Chemical compound COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 description 8
- 238000000926 separation method Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 150000003673 urethanes Chemical class 0.000 description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- UZILCZKGXMQEQR-UHFFFAOYSA-N decyl-Benzene Chemical compound CCCCCCCCCCC1=CC=CC=C1 UZILCZKGXMQEQR-UHFFFAOYSA-N 0.000 description 6
- PVFSDGKDKFSOTB-UHFFFAOYSA-K iron(3+);triacetate Chemical compound [Fe+3].CC([O-])=O.CC([O-])=O.CC([O-])=O PVFSDGKDKFSOTB-UHFFFAOYSA-K 0.000 description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- XSXLCQLOFRENHC-UHFFFAOYSA-N ethyl n-benzylcarbamate Chemical compound CCOC(=O)NCC1=CC=CC=C1 XSXLCQLOFRENHC-UHFFFAOYSA-N 0.000 description 5
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 4
- QPRQEDXDYOZYLA-UHFFFAOYSA-N 2-methylbutan-1-ol Chemical compound CCC(C)CO QPRQEDXDYOZYLA-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 229930040373 Paraformaldehyde Natural products 0.000 description 4
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 4
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 description 4
- 229910001873 dinitrogen Inorganic materials 0.000 description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 4
- 229920002866 paraformaldehyde Polymers 0.000 description 4
- 229910052711 selenium Inorganic materials 0.000 description 4
- 239000011669 selenium Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Natural products CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 239000002841 Lewis acid Substances 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 150000001241 acetals Chemical class 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 235000011089 carbon dioxide Nutrition 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 229940112021 centrally acting muscle relaxants carbamic acid ester Drugs 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- WXDDBYFBIIAYSM-UHFFFAOYSA-N ethyl n-(2-phenylethyl)carbamate Chemical compound CCOC(=O)NCCC1=CC=CC=C1 WXDDBYFBIIAYSM-UHFFFAOYSA-N 0.000 description 3
- 238000004817 gas chromatography Methods 0.000 description 3
- 238000004128 high performance liquid chromatography Methods 0.000 description 3
- 239000012442 inert solvent Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 150000007517 lewis acids Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- 239000012808 vapor phase Substances 0.000 description 3
- XHLHPRDBBAGVEG-UHFFFAOYSA-N 1-tetralone Chemical compound C1=CC=C2C(=O)CCCC2=C1 XHLHPRDBBAGVEG-UHFFFAOYSA-N 0.000 description 2
- WWGUMAYGTYQSGA-UHFFFAOYSA-N 2,3-dimethylnaphthalene Chemical compound C1=CC=C2C=C(C)C(C)=CC2=C1 WWGUMAYGTYQSGA-UHFFFAOYSA-N 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- QIMMUPPBPVKWKM-UHFFFAOYSA-N 2-methylnaphthalene Chemical compound C1=CC=CC2=CC(C)=CC=C21 QIMMUPPBPVKWKM-UHFFFAOYSA-N 0.000 description 2
- HTSABYAWKQAHBT-UHFFFAOYSA-N 3-methylcyclohexanol Chemical compound CC1CCCC(O)C1 HTSABYAWKQAHBT-UHFFFAOYSA-N 0.000 description 2
- MQWCXKGKQLNYQG-UHFFFAOYSA-N 4-methylcyclohexan-1-ol Chemical compound CC1CCC(O)CC1 MQWCXKGKQLNYQG-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- BPGDAMSIGCZZLK-UHFFFAOYSA-N acetyloxymethyl acetate Chemical compound CC(=O)OCOC(C)=O BPGDAMSIGCZZLK-UHFFFAOYSA-N 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- QPUYECUOLPXSFR-UHFFFAOYSA-N alpha-methyl-naphthalene Natural products C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 229940011182 cobalt acetate Drugs 0.000 description 2
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 210000004209 hair Anatomy 0.000 description 2
- NDJKXXJCMXVBJW-UHFFFAOYSA-N heptadecane Chemical compound CCCCCCCCCCCCCCCCC NDJKXXJCMXVBJW-UHFFFAOYSA-N 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 229940071125 manganese acetate Drugs 0.000 description 2
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- YHJBFHUDYWUFIJ-UHFFFAOYSA-N methyl n-[(methoxycarbonylamino)-diphenylmethyl]carbamate Chemical compound C=1C=CC=CC=1C(NC(=O)OC)(NC(=O)OC)C1=CC=CC=C1 YHJBFHUDYWUFIJ-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- KPSSIOMAKSHJJG-UHFFFAOYSA-N neopentyl alcohol Chemical compound CC(C)(C)CO KPSSIOMAKSHJJG-UHFFFAOYSA-N 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- YCOZIPAWZNQLMR-UHFFFAOYSA-N pentadecane Chemical compound CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 2
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 description 2
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 2
- 150000003672 ureas Chemical class 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- URBLVRAVOIVZFJ-UHFFFAOYSA-N (3-methylphenyl)-phenylmethanone Chemical compound CC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1 URBLVRAVOIVZFJ-UHFFFAOYSA-N 0.000 description 1
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
- LXSMILGNHYBUCG-UHFFFAOYSA-N 1,2,3,4,5,6-hexaethylbenzene Chemical compound CCC1=C(CC)C(CC)=C(CC)C(CC)=C1CC LXSMILGNHYBUCG-UHFFFAOYSA-N 0.000 description 1
- JHBKHLUZVFWLAG-UHFFFAOYSA-N 1,2,4,5-tetrachlorobenzene Chemical compound ClC1=CC(Cl)=C(Cl)C=C1Cl JHBKHLUZVFWLAG-UHFFFAOYSA-N 0.000 description 1
- FQERLIOIVXPZKH-UHFFFAOYSA-N 1,2,4-trioxane Chemical compound C1COOCO1 FQERLIOIVXPZKH-UHFFFAOYSA-N 0.000 description 1
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 1
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 1
- XKEFYDZQGKAQCN-UHFFFAOYSA-N 1,3,5-trichlorobenzene Chemical compound ClC1=CC(Cl)=CC(Cl)=C1 XKEFYDZQGKAQCN-UHFFFAOYSA-N 0.000 description 1
- WJYMPXJVHNDZHD-UHFFFAOYSA-N 1,3,5-triethylbenzene Chemical compound CCC1=CC(CC)=CC(CC)=C1 WJYMPXJVHNDZHD-UHFFFAOYSA-N 0.000 description 1
- AUHZEENZYGFFBQ-UHFFFAOYSA-N 1,3,5-trimethylbenzene Chemical compound CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 1
- HDFQKJQEWGVKCQ-UHFFFAOYSA-N 1,3-dimethyl-2-nitrobenzene Chemical compound CC1=CC=CC(C)=C1[N+]([O-])=O HDFQKJQEWGVKCQ-UHFFFAOYSA-N 0.000 description 1
- BYFNZOKBMZKTSC-UHFFFAOYSA-N 1,3-dimethyl-5-nitrobenzene Chemical compound CC1=CC(C)=CC([N+]([O-])=O)=C1 BYFNZOKBMZKTSC-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- LFMWZTSOMGDDJU-UHFFFAOYSA-N 1,4-diiodobenzene Chemical compound IC1=CC=C(I)C=C1 LFMWZTSOMGDDJU-UHFFFAOYSA-N 0.000 description 1
- YZUPZGFPHUVJKC-UHFFFAOYSA-N 1-bromo-2-methoxyethane Chemical compound COCCBr YZUPZGFPHUVJKC-UHFFFAOYSA-N 0.000 description 1
- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 description 1
- APWZAIZNWQFZBK-UHFFFAOYSA-N 1-ethoxynaphthalene Chemical compound C1=CC=C2C(OCC)=CC=CC2=C1 APWZAIZNWQFZBK-UHFFFAOYSA-N 0.000 description 1
- ZMXIYERNXPIYFR-UHFFFAOYSA-N 1-ethylnaphthalene Chemical compound C1=CC=C2C(CC)=CC=CC2=C1 ZMXIYERNXPIYFR-UHFFFAOYSA-N 0.000 description 1
- MBDUIEKYVPVZJH-UHFFFAOYSA-N 1-ethylsulfonylethane Chemical compound CCS(=O)(=O)CC MBDUIEKYVPVZJH-UHFFFAOYSA-N 0.000 description 1
- AXFGIVCBFDCPPE-UHFFFAOYSA-N 1-fluoronaphthalene Chemical compound C1=CC=C[C]2C(F)=CC=C=C21 AXFGIVCBFDCPPE-UHFFFAOYSA-N 0.000 description 1
- NHPPIJMARIVBGU-UHFFFAOYSA-N 1-iodonaphthalene Chemical compound C1=CC=C2C(I)=CC=CC2=C1 NHPPIJMARIVBGU-UHFFFAOYSA-N 0.000 description 1
- RZTDESRVPFKCBH-UHFFFAOYSA-N 1-methyl-4-(4-methylphenyl)benzene Chemical group C1=CC(C)=CC=C1C1=CC=C(C)C=C1 RZTDESRVPFKCBH-UHFFFAOYSA-N 0.000 description 1
- HZAWPPRBCALFRN-UHFFFAOYSA-N 1-methyl-4-[(4-methylphenyl)methyl]benzene Chemical compound C1=CC(C)=CC=C1CC1=CC=C(C)C=C1 HZAWPPRBCALFRN-UHFFFAOYSA-N 0.000 description 1
- AOPDRZXCEAKHHW-UHFFFAOYSA-N 1-pentoxypentane Chemical compound CCCCCOCCCCC AOPDRZXCEAKHHW-UHFFFAOYSA-N 0.000 description 1
- CGYGETOMCSJHJU-UHFFFAOYSA-N 2-chloronaphthalene Chemical compound C1=CC=CC2=CC(Cl)=CC=C21 CGYGETOMCSJHJU-UHFFFAOYSA-N 0.000 description 1
- TZYRSLHNPKPEFV-UHFFFAOYSA-N 2-ethyl-1-butanol Chemical compound CCC(CC)CO TZYRSLHNPKPEFV-UHFFFAOYSA-N 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- BAGQBTMEEISJLK-UHFFFAOYSA-N 2-fluoronaphthalene Chemical compound C1=CC=CC2=CC(F)=CC=C21 BAGQBTMEEISJLK-UHFFFAOYSA-N 0.000 description 1
- FRNLBIWVMVNNAZ-UHFFFAOYSA-N 2-iodonaphthalene Chemical compound C1=CC=CC2=CC(I)=CC=C21 FRNLBIWVMVNNAZ-UHFFFAOYSA-N 0.000 description 1
- PFNHSEQQEPMLNI-UHFFFAOYSA-N 2-methyl-1-pentanol Chemical compound CCCC(C)CO PFNHSEQQEPMLNI-UHFFFAOYSA-N 0.000 description 1
- NDVWOBYBJYUSMF-UHFFFAOYSA-N 2-methylcyclohexan-1-ol Chemical compound CC1CCCCC1O NDVWOBYBJYUSMF-UHFFFAOYSA-N 0.000 description 1
- RFYZVBMZNJOXNP-UHFFFAOYSA-N 2-oxopropyl acetate;vanadium Chemical compound [V].CC(=O)COC(C)=O RFYZVBMZNJOXNP-UHFFFAOYSA-N 0.000 description 1
- IWTBVKIGCDZRPL-LURJTMIESA-N 3-Methylbutanol Natural products CC[C@H](C)CCO IWTBVKIGCDZRPL-LURJTMIESA-N 0.000 description 1
- QZYHIOPPLUPUJF-UHFFFAOYSA-N 3-nitrotoluene Chemical compound CC1=CC=CC([N+]([O-])=O)=C1 QZYHIOPPLUPUJF-UHFFFAOYSA-N 0.000 description 1
- ZPQAKYPOZRXKFA-UHFFFAOYSA-N 6-Undecanone Chemical compound CCCCCC(=O)CCCCC ZPQAKYPOZRXKFA-UHFFFAOYSA-N 0.000 description 1
- JRHWZRMEBGIBHP-UHFFFAOYSA-L C(C)(=O)[O-].[Zn+2].C(C)#N.C(C)(=O)[O-] Chemical compound C(C)(=O)[O-].[Zn+2].C(C)#N.C(C)(=O)[O-] JRHWZRMEBGIBHP-UHFFFAOYSA-L 0.000 description 1
- CKDWPUIZGOQOOM-UHFFFAOYSA-N Carbamyl chloride Chemical compound NC(Cl)=O CKDWPUIZGOQOOM-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910021555 Chromium Chloride Inorganic materials 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- BNUHAJGCKIQFGE-UHFFFAOYSA-N Nitroanisol Chemical compound COC1=CC=C([N+]([O-])=O)C=C1 BNUHAJGCKIQFGE-UHFFFAOYSA-N 0.000 description 1
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical compound CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- COQLPRJCUIATTQ-UHFFFAOYSA-N Uranyl acetate Chemical compound O.O.O=[U]=O.CC(O)=O.CC(O)=O COQLPRJCUIATTQ-UHFFFAOYSA-N 0.000 description 1
- 229910021550 Vanadium Chloride Inorganic materials 0.000 description 1
- VYWQTJWGWLKBQA-UHFFFAOYSA-N [amino(hydroxy)methylidene]azanium;chloride Chemical compound Cl.NC(N)=O VYWQTJWGWLKBQA-UHFFFAOYSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000004411 aluminium Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 150000008365 aromatic ketones Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 125000005337 azoxy group Chemical group [N+]([O-])(=N*)* 0.000 description 1
- UDEWPOVQBGFNGE-UHFFFAOYSA-N benzoic acid n-propyl ester Natural products CCCOC(=O)C1=CC=CC=C1 UDEWPOVQBGFNGE-UHFFFAOYSA-N 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
- AMJQWGIYCROUQF-UHFFFAOYSA-N calcium;methanolate Chemical compound [Ca+2].[O-]C.[O-]C AMJQWGIYCROUQF-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- AOGYCOYQMAVAFD-UHFFFAOYSA-M carbonochloridate Chemical compound [O-]C(Cl)=O AOGYCOYQMAVAFD-UHFFFAOYSA-M 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 229940106681 chloroacetic acid Drugs 0.000 description 1
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- 229940044175 cobalt sulfate Drugs 0.000 description 1
- 229910000361 cobalt sulfate Inorganic materials 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 1
- IKUPISAYGBGQDT-UHFFFAOYSA-N copper;dioxido(dioxo)molybdenum Chemical compound [Cu+2].[O-][Mo]([O-])(=O)=O IKUPISAYGBGQDT-UHFFFAOYSA-N 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- CGZZMOTZOONQIA-UHFFFAOYSA-N cycloheptanone Chemical compound O=C1CCCCCC1 CGZZMOTZOONQIA-UHFFFAOYSA-N 0.000 description 1
- XCIXKGXIYUWCLL-UHFFFAOYSA-N cyclopentanol Chemical compound OC1CCCC1 XCIXKGXIYUWCLL-UHFFFAOYSA-N 0.000 description 1
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- 238000006114 decarboxylation reaction Methods 0.000 description 1
- 229940019778 diethylene glycol diethyl ether Drugs 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- JXCHMDATRWUOAP-UHFFFAOYSA-N diisocyanatomethylbenzene Chemical compound O=C=NC(N=C=O)C1=CC=CC=C1 JXCHMDATRWUOAP-UHFFFAOYSA-N 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- OPTDDWCXQQYKGU-UHFFFAOYSA-N diphenyldichloromethane Chemical compound C=1C=CC=CC=1C(Cl)(Cl)C1=CC=CC=C1 OPTDDWCXQQYKGU-UHFFFAOYSA-N 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 1
- SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- KLKFAASOGCDTDT-UHFFFAOYSA-N ethoxymethoxyethane Chemical compound CCOCOCC KLKFAASOGCDTDT-UHFFFAOYSA-N 0.000 description 1
- MMXKVMNBHPAILY-UHFFFAOYSA-N ethyl laurate Chemical class CCCCCCCCCCCC(=O)OCC MMXKVMNBHPAILY-UHFFFAOYSA-N 0.000 description 1
- LYOZZZFLUKKEIG-UHFFFAOYSA-N ethyl n-[(ethoxycarbonylamino)-diphenylmethyl]carbamate Chemical compound C=1C=CC=CC=1C(NC(=O)OCC)(NC(=O)OCC)C1=CC=CC=C1 LYOZZZFLUKKEIG-UHFFFAOYSA-N 0.000 description 1
- QHGZFCAIXRVHID-UHFFFAOYSA-N ethyl n-methyl-n-phenylcarbamate Chemical class CCOC(=O)N(C)C1=CC=CC=C1 QHGZFCAIXRVHID-UHFFFAOYSA-N 0.000 description 1
- VEPSWGHMGZQCIN-UHFFFAOYSA-H ferric oxalate Chemical compound [Fe+3].[Fe+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O VEPSWGHMGZQCIN-UHFFFAOYSA-H 0.000 description 1
- 238000001640 fractional crystallisation Methods 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- OTCKNHQTLOBDDD-UHFFFAOYSA-K gold(3+);triacetate Chemical compound [Au+3].CC([O-])=O.CC([O-])=O.CC([O-])=O OTCKNHQTLOBDDD-UHFFFAOYSA-K 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000011551 heat transfer agent Substances 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- YUWFEBAXEOLKSG-UHFFFAOYSA-N hexamethylbenzene Chemical compound CC1=C(C)C(C)=C(C)C(C)=C1C YUWFEBAXEOLKSG-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910000398 iron phosphate Inorganic materials 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- GYCHYNMREWYSKH-UHFFFAOYSA-L iron(ii) bromide Chemical compound [Fe+2].[Br-].[Br-] GYCHYNMREWYSKH-UHFFFAOYSA-L 0.000 description 1
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229940046892 lead acetate Drugs 0.000 description 1
- HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- JILPJDVXYVTZDQ-UHFFFAOYSA-N lithium methoxide Chemical compound [Li+].[O-]C JILPJDVXYVTZDQ-UHFFFAOYSA-N 0.000 description 1
- LTRVAZKHJRYLRJ-UHFFFAOYSA-N lithium;butan-1-olate Chemical compound [Li+].CCCC[O-] LTRVAZKHJRYLRJ-UHFFFAOYSA-N 0.000 description 1
- AZVCGYPLLBEUNV-UHFFFAOYSA-N lithium;ethanolate Chemical compound [Li+].CC[O-] AZVCGYPLLBEUNV-UHFFFAOYSA-N 0.000 description 1
- MXIRPJHGXWFUAE-UHFFFAOYSA-N lithium;propan-1-olate Chemical compound [Li+].CCC[O-] MXIRPJHGXWFUAE-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- CRGZYKWWYNQGEC-UHFFFAOYSA-N magnesium;methanolate Chemical compound [Mg+2].[O-]C.[O-]C CRGZYKWWYNQGEC-UHFFFAOYSA-N 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- OLXYLDUSSBULGU-UHFFFAOYSA-N methyl pyridine-4-carboxylate Chemical compound COC(=O)C1=CC=NC=C1 OLXYLDUSSBULGU-UHFFFAOYSA-N 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- UIEKYBOPAVTZKW-UHFFFAOYSA-L naphthalene-2-carboxylate;nickel(2+) Chemical compound [Ni+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 UIEKYBOPAVTZKW-UHFFFAOYSA-L 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229940078494 nickel acetate Drugs 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- WSGCRAOTEDLMFQ-UHFFFAOYSA-N nonan-5-one Chemical compound CCCCC(=O)CCCC WSGCRAOTEDLMFQ-UHFFFAOYSA-N 0.000 description 1
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 1
- ZPIRTVJRHUMMOI-UHFFFAOYSA-N octoxybenzene Chemical compound CCCCCCCCOC1=CC=CC=C1 ZPIRTVJRHUMMOI-UHFFFAOYSA-N 0.000 description 1
- 150000005677 organic carbonates Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- CEOCDNVZRAIOQZ-UHFFFAOYSA-N pentachlorobenzene Chemical compound ClC1=CC(Cl)=C(Cl)C(Cl)=C1Cl CEOCDNVZRAIOQZ-UHFFFAOYSA-N 0.000 description 1
- RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 description 1
- 150000004707 phenolate Chemical class 0.000 description 1
- BOTNYLSAWDQNEX-UHFFFAOYSA-N phenoxymethylbenzene Chemical compound C=1C=CC=CC=1COC1=CC=CC=C1 BOTNYLSAWDQNEX-UHFFFAOYSA-N 0.000 description 1
- DGTNSSLYPYDJGL-UHFFFAOYSA-N phenyl isocyanate Chemical compound O=C=NC1=CC=CC=C1 DGTNSSLYPYDJGL-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- KRIOVPPHQSLHCZ-UHFFFAOYSA-N propiophenone Chemical compound CCC(=O)C1=CC=CC=C1 KRIOVPPHQSLHCZ-UHFFFAOYSA-N 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 1
- 229960001755 resorcinol Drugs 0.000 description 1
- DPZNOMCNRMUKPS-UHFFFAOYSA-N resorcinol dimethyl ether Natural products COC1=CC=CC(OC)=C1 DPZNOMCNRMUKPS-UHFFFAOYSA-N 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 229940065287 selenium compound Drugs 0.000 description 1
- 150000003343 selenium compounds Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 description 1
- 229940071536 silver acetate Drugs 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 150000003555 thioacetals Chemical class 0.000 description 1
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- DPNUIZVZBWBCPB-UHFFFAOYSA-J titanium(4+);tetraphenoxide Chemical compound [Ti+4].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 DPNUIZVZBWBCPB-UHFFFAOYSA-J 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- CYIFVRUOHKNECG-UHFFFAOYSA-N tridecan-2-one Chemical compound CCCCCCCCCCCC(C)=O CYIFVRUOHKNECG-UHFFFAOYSA-N 0.000 description 1
- DAOVYDBYKGXFOB-UHFFFAOYSA-N tris(2-methylpropoxy)alumane Chemical compound [Al+3].CC(C)C[O-].CC(C)C[O-].CC(C)C[O-] DAOVYDBYKGXFOB-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
- GAAKLDANOSASAM-UHFFFAOYSA-N undec-10-enoic acid;zinc Chemical compound [Zn].OC(=O)CCCCCCCCC=C GAAKLDANOSASAM-UHFFFAOYSA-N 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229940118257 zinc undecylenate Drugs 0.000 description 1
- JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 description 1
- RVXKJRWBHPHVOV-UHFFFAOYSA-L zinc;oct-2-enoate Chemical compound [Zn+2].CCCCCC=CC([O-])=O.CCCCCC=CC([O-])=O RVXKJRWBHPHVOV-UHFFFAOYSA-L 0.000 description 1
- ZPEJZWGMHAKWNL-UHFFFAOYSA-L zinc;oxalate Chemical compound [Zn+2].[O-]C(=O)C([O-])=O ZPEJZWGMHAKWNL-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/04—Preparation of derivatives of isocyanic acid from or via carbamates or carbamoyl halides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
æ¬çºæã¯ã
 ã¢ããªã³ãšãâã¢ã«ãã«ã¢ã«ãããé
žãšã¹
ãã«åã³å Žåã«ãã€ãŠã¯å°¿çŽ åã³ã¢ã«ã³ãŒã«ãš
ããæå©ã«è§Šåªã®ååšäžã«åå¿ãããŠïŒ®âããš
ãã«ãŠã¬ã¿ã³ã«ãã  åŸãããâããšãã«ãŠã¬ã¿ã³ããã«ã ã¢ã«
ãããããã«ã ã¢ã«ãããè±é¢ååç©åã¯åŒïŒ
âCH2âïŒäœããã¯ROâãRSâåã¯
ROCOåºãè¡šããããããã®ïŒ²ã¯ã¢ã«ãã«åºã
è¡šããïŒã®äºå®èœååç©ãšãé žåã¯ã«ã«ãã³é ž
ã®ååšäžã«çž®åããŠã¡ãã¬ã³âãã¹âããšãã«
ãŠã¬ã¿ã³ãšããªã¡ãã¬ã³âããªããšãã«ãŠã¬ã¿
ã³ãšãããªãæ··åç©ïŒç²è£œMDUïŒã«ãã  ãã®ç²è£œMDUã175âã600âã§ãæå©ã«æ¶²
çžäžã§175âã350âã®æž©åºŠã§åã³æå©ã«è§Šåªãš
ããŠã®äžåäžçžäžã«ååšããäžé£ã®äºéãã¢ã«
ãããŠã ããã¿ã³ãéãã¯ãã ãã³ãã«ãåã³
ããã±ã«ããã®éå±ã®ååšäžã«ç±å解ããããš
ã«ãã€ãŠãžããšãã«ã¡ã¿ã³âãžã€ãœã·ã¢ããŒã
ãšããªããšãã«âããªã¡ãã¬ã³âããªã€ãœã·ã¢
ããŒããšãããªãæ··åç©ïŒç²è£œMDIïŒã補é
ããæ¹æ³ã«é¢ããã
ãã«åã³å Žåã«ãã€ãŠã¯å°¿çŽ åã³ã¢ã«ã³ãŒã«ãš
ããæå©ã«è§Šåªã®ååšäžã«åå¿ãããŠïŒ®âããš
ãã«ãŠã¬ã¿ã³ã«ãã  åŸãããâããšãã«ãŠã¬ã¿ã³ããã«ã ã¢ã«
ãããããã«ã ã¢ã«ãããè±é¢ååç©åã¯åŒïŒ
âCH2âïŒäœããã¯ROâãRSâåã¯
ROCOåºãè¡šããããããã®ïŒ²ã¯ã¢ã«ãã«åºã
è¡šããïŒã®äºå®èœååç©ãšãé žåã¯ã«ã«ãã³é ž
ã®ååšäžã«çž®åããŠã¡ãã¬ã³âãã¹âããšãã«
ãŠã¬ã¿ã³ãšããªã¡ãã¬ã³âããªããšãã«ãŠã¬ã¿
ã³ãšãããªãæ··åç©ïŒç²è£œMDUïŒã«ãã  ãã®ç²è£œMDUã175âã600âã§ãæå©ã«æ¶²
çžäžã§175âã350âã®æž©åºŠã§åã³æå©ã«è§Šåªãš
ããŠã®äžåäžçžäžã«ååšããäžé£ã®äºéãã¢ã«
ãããŠã ããã¿ã³ãéãã¯ãã ãã³ãã«ãåã³
ããã±ã«ããã®éå±ã®ååšäžã«ç±å解ããããš
ã«ãã€ãŠãžããšãã«ã¡ã¿ã³âãžã€ãœã·ã¢ããŒã
ãšããªããšãã«âããªã¡ãã¬ã³âããªã€ãœã·ã¢
ããŒããšãããªãæ··åç©ïŒç²è£œMDIïŒã補é
ããæ¹æ³ã«é¢ããã
ãžããšãã«ã¡ã¿ã³âãžã€ãœã·ã¢ããŒããšããªã
ãšãã«âããªã¡ãã¬ã³âããªã€ãœã·ã¢ããŒããšã
ããªãæ··åç©ïŒä»¥äžç²è£œMDIãšç¥èšããïŒã補
é ããããã«ã¯ãåžžæ³ã§ãžããšãã«ã¡ã¿ã³âãžã¢
ãã³ãšããªããšãã«âããªã¡ãã¬ã³âããªã¢ãã³
ãšãããªãæ··åç©ïŒä»¥äžç²è£œMDAãšç¥èšããïŒ
ããã¹ã²ã³ã§çžå¿ããã«ã«ãããé žã¯ããªãã«å€
ãã該ã¯ããªãããã®åŸã«å Žåã«ãã€ãŠã¯è§Šåªã®
ååšäžã«ç±å解ããã
ãšãã«âããªã¡ãã¬ã³âããªã€ãœã·ã¢ããŒããšã
ããªãæ··åç©ïŒä»¥äžç²è£œMDIãšç¥èšããïŒã補
é ããããã«ã¯ãåžžæ³ã§ãžããšãã«ã¡ã¿ã³âãžã¢
ãã³ãšããªããšãã«âããªã¡ãã¬ã³âããªã¢ãã³
ãšãããªãæ··åç©ïŒä»¥äžç²è£œMDAãšç¥èšããïŒ
ããã¹ã²ã³ã§çžå¿ããã«ã«ãããé žã¯ããªãã«å€
ãã該ã¯ããªãããã®åŸã«å Žåã«ãã€ãŠã¯è§Šåªã®
ååšäžã«ç±å解ããã
ç²è£œMDAã¯ããèªèº«ãäŸãã°ãã«ã®ãŒç¹èš±ç¬¬
648787å·æ现æžåã³ã«ããç¹èš±ç¬¬700026å·æ现æž
ã®èšèŒã«ããã°ãã¢ããªã³ããã«ã ã¢ã«ããã
ãšãé žè§Šåªã®ååšäžã«çž®åããããšã«ãã€ãŠè£œé
ããããå·¥æ¥çã«ã¯ã倧éã®å¡©é žã觊åªãšããŠäœ¿
çšããããã®å¡©é žã¯éäŸåçž®åŸã«å¡©åºã§äžåãã
ãã€åå¿æ··åç©ããåé¢ãããããã®åé¡ãšãªã
ã®ã¯ãç¹ã«æ¬¡ã®ç¹ã§ããïŒå¡©åæ°ŽçŽ äžã®ãã¹ã²ã³
åã³ã«ã«ãããã¯ããªãã«ããå¡©çŽ ã®é«ãå€æ
çããã¹ã²ã³ã®æ害æ§ãªãã³ã«é«äŸ¡ãªææè²»åã³
å®å®æ§ã®ããã®æè¡çè²»çšãšçµã³ä»ããåå¿æ··å
ç©ã®è èæ§ã
648787å·æ现æžåã³ã«ããç¹èš±ç¬¬700026å·æ现æž
ã®èšèŒã«ããã°ãã¢ããªã³ããã«ã ã¢ã«ããã
ãšãé žè§Šåªã®ååšäžã«çž®åããããšã«ãã€ãŠè£œé
ããããå·¥æ¥çã«ã¯ã倧éã®å¡©é žã觊åªãšããŠäœ¿
çšããããã®å¡©é žã¯éäŸåçž®åŸã«å¡©åºã§äžåãã
ãã€åå¿æ··åç©ããåé¢ãããããã®åé¡ãšãªã
ã®ã¯ãç¹ã«æ¬¡ã®ç¹ã§ããïŒå¡©åæ°ŽçŽ äžã®ãã¹ã²ã³
åã³ã«ã«ãããã¯ããªãã«ããå¡©çŽ ã®é«ãå€æ
çããã¹ã²ã³ã®æ害æ§ãªãã³ã«é«äŸ¡ãªææè²»åã³
å®å®æ§ã®ããã®æè¡çè²»çšãšçµã³ä»ããåå¿æ··å
ç©ã®è èæ§ã
ãããè³éŠæååç©åã³äžé
žåççŽ ããã®ãäŸ
ãã°è±åœç¹èš±ç¬¬1025436å·æ现æžããã€ãé£éŠå ±
ååœç¹èš±åºé¡å ¬é第1815517å·æ现æžïŒç±³åœç¹èš±
第3576835å·æ现æžïŒããã€ãé£éŠå ±ååœç¹èš±åºé¡
å ¬é第1931212å·æ现æžïŒç±³åœç¹èš±ç¬¬3654279å·æ
现æžåã³å第3781321å·æ现æžïŒã®èšèŒã«ããã
å¡©çŽ ãæããªãã貎éå±è§Šåªãçšããæè¡çã«å
æ§ã«åé¡ç¹ã®ããã€ãœã·ã¢ããŒãã®çŽæ¥åæã¯ã
å ¬ç¥æè¡ã«ãããã§ã«ãããããªãããâããªã
ãšãã«âã¡ã¿ã³ã補é ããããã®é©åœãªåæãç
ããªãã€ãã®ã§ç²è£œMDIã«ãšã€ãŠã¯èæ ®ãããª
ããã®ã§ããã
ãã°è±åœç¹èš±ç¬¬1025436å·æ现æžããã€ãé£éŠå ±
ååœç¹èš±åºé¡å ¬é第1815517å·æ现æžïŒç±³åœç¹èš±
第3576835å·æ现æžïŒããã€ãé£éŠå ±ååœç¹èš±åºé¡
å ¬é第1931212å·æ现æžïŒç±³åœç¹èš±ç¬¬3654279å·æ
现æžåã³å第3781321å·æ现æžïŒã®èšèŒã«ããã
å¡©çŽ ãæããªãã貎éå±è§Šåªãçšããæè¡çã«å
æ§ã«åé¡ç¹ã®ããã€ãœã·ã¢ããŒãã®çŽæ¥åæã¯ã
å ¬ç¥æè¡ã«ãããã§ã«ãããããªãããâããªã
ãšãã«âã¡ã¿ã³ã補é ããããã®é©åœãªåæãç
ããªãã€ãã®ã§ç²è£œMDIã«ãšã€ãŠã¯èæ ®ãããª
ããã®ã§ããã
ã€ãœã·ã¢ããŒãã補é ããããã«ããã€ããã
ããã€ãœã·ã¢ããŒããšèŠãªããããŠã¬ã¿ã³ãç±å
解ããããšãææ¡ãããã
ããã€ãœã·ã¢ããŒããšèŠãªããããŠã¬ã¿ã³ãç±å
解ããããšãææ¡ãããã
ã¡ãã¬ã³âãã¹âããšãã«ãŠã¬ã¿ã³ãšããªã¡ã
ã¬ã³âããªããšãã«ãŠã¬ã¿ã³ãšã®åæïŒç²è£œ
MDUïŒã¯ããã€ãé£éŠå ±ååœç¹èš±ç¬¬1042891å·
æ现æžïŒç±³åœç¹èš±ç¬¬2946768å·æ现æžïŒã®èšèŒã«
ããããšãã«ãŠã¬ã¿ã³ããã«ã ã¢ã«ããããšçž®å
ããããšã«ãã€ãŠå¯èœã§ãããããããåèšæ¹æ³
ã¯å·¥æ¥çææããããããªãããããšããã®ãã
ïŒããšãã«ãŠã¬ã¿ã³ã補é ããããã«ã¢ããªã³ãš
ã¯ãã«çé žãšã¹ãã«ãªããã¯ããšãã«ã€ãœã·ã¢ã
ãŒããšã¢ã«ã³ãŒã«ãšãåå¿ãããããšãæãŸãã
ãã¹ã²ã³ã䜿çšããããšã®åé¡ã¯ç¡èŠãããïŒã
ã€ãé£éŠå ±ååœç¹èš±ç¬¬1042891å·æ现æžã®èšèŒã«
ããããšãã«ãŠã¬ã¿ã³ãšãã«ã ã¢ã«ãããããã®
çž®åçæç©ã¯ãéé¢ã¢ããåºãæããå æ°Žå解ç
æç©åã³ç²è£œMDIã«å解ããããšã®ã§ããªã
âçµåæåã®èéå«éïŒ15ã50ïŒ ïŒãå«æãã
ããã§ããã
ã¬ã³âããªããšãã«ãŠã¬ã¿ã³ãšã®åæïŒç²è£œ
MDUïŒã¯ããã€ãé£éŠå ±ååœç¹èš±ç¬¬1042891å·
æ现æžïŒç±³åœç¹èš±ç¬¬2946768å·æ现æžïŒã®èšèŒã«
ããããšãã«ãŠã¬ã¿ã³ããã«ã ã¢ã«ããããšçž®å
ããããšã«ãã€ãŠå¯èœã§ãããããããåèšæ¹æ³
ã¯å·¥æ¥çææããããããªãããããšããã®ãã
ïŒããšãã«ãŠã¬ã¿ã³ã補é ããããã«ã¢ããªã³ãš
ã¯ãã«çé žãšã¹ãã«ãªããã¯ããšãã«ã€ãœã·ã¢ã
ãŒããšã¢ã«ã³ãŒã«ãšãåå¿ãããããšãæãŸãã
ãã¹ã²ã³ã䜿çšããããšã®åé¡ã¯ç¡èŠãããïŒã
ã€ãé£éŠå ±ååœç¹èš±ç¬¬1042891å·æ现æžã®èšèŒã«
ããããšãã«ãŠã¬ã¿ã³ãšãã«ã ã¢ã«ãããããã®
çž®åçæç©ã¯ãéé¢ã¢ããåºãæããå æ°Žå解ç
æç©åã³ç²è£œMDIã«å解ããããšã®ã§ããªã
âçµåæåã®èéå«éïŒ15ã50ïŒ ïŒãå«æãã
ããã§ããã
ç±³åœç¹èš±ç¬¬2409712å·æ现æžåã³å第2806051å·
æ现æžã«ãããå®éã«ã¢ããªã³ãå°¿çŽ åã³ã¢ã«ã³
ãŒã«ã®åå¿ã«ãããå¡©çŽ ãæããªãããšãã«ãŠã¬
ã¿ã³ã®è£œé æ³ãå ¬ç¥ã§ããããããããã®æ¹æ³ã¯
ã¢ããªã³ããã¹ã²ã³åããã€åŒç¶ãã¢ã«ã³ãŒã«ãš
åå¿ãããããšã«å¯ŸããŠæ¯èŒçå°ãªãåçã®ãã
ã«ææãæåŸ ããããšãã§ããããããã€ãŠåŸã«
èšèŒãããŠã¬ã¿ã³ã®è£œé æ³ã«çµå±èšåããªãã€
ãã
æ现æžã«ãããå®éã«ã¢ããªã³ãå°¿çŽ åã³ã¢ã«ã³
ãŒã«ã®åå¿ã«ãããå¡©çŽ ãæããªãããšãã«ãŠã¬
ã¿ã³ã®è£œé æ³ãå ¬ç¥ã§ããããããããã®æ¹æ³ã¯
ã¢ããªã³ããã¹ã²ã³åããã€åŒç¶ãã¢ã«ã³ãŒã«ãš
åå¿ãããããšã«å¯ŸããŠæ¯èŒçå°ãªãåçã®ãã
ã«ææãæåŸ ããããšãã§ããããããã€ãŠåŸã«
èšèŒãããŠã¬ã¿ã³ã®è£œé æ³ã«çµå±èšåããªãã€
ãã
ãŸãããã€ãé£éŠå
±ååœç¹èš±åºé¡å
¬é第
2160111å·æ现æžïŒç±³åœç¹èš±ç¬¬3763217å·æ现æžïŒ
ã«èšèŒã®ïŒ®â眮æãŠã¬ã¿ã³ãäŸãã°ã«ã€ã¹é žã®å
åšäžã«ææ©çé žå¡©ãšã¢ããªã³ãšãåå¿ãããããš
ã«ããããšãã«ãŠã¬ã¿ã³ã®è£œé æ³ã¯ã決å®çãªé²
æ©ããããããªãã€ãããã®æ¹æ³ã®æ¬ ç¹ã¯ããžã¢
ã«ãã«çé žå¡©ã¯ãã¹ã²ã³åã³ã¢ã«ã³ãŒã«ãããã
ãã¯å·¥æ¥çã«ãªãåé¡ã®ãã觊åªåå¿ã«ããäžé ž
åççŽ åã³ã¢ã«ã³ãŒã«ã®å ±é žåã«ãã€ãŠè£œé ããª
ããã°ãªããããªãé«äŸ¡ãªãã®ãšãªããåå¿é床
ãå®éã«äœãããã€ïŒ®âã¢ã«ãã«âã¢ããªã³ã®ç«¶
äºçæã«ããéžææ§ãäžæºè¶³ãªãã®ã§ããããšã«
ããã
2160111å·æ现æžïŒç±³åœç¹èš±ç¬¬3763217å·æ现æžïŒ
ã«èšèŒã®ïŒ®â眮æãŠã¬ã¿ã³ãäŸãã°ã«ã€ã¹é žã®å
åšäžã«ææ©çé žå¡©ãšã¢ããªã³ãšãåå¿ãããããš
ã«ããããšãã«ãŠã¬ã¿ã³ã®è£œé æ³ã¯ã決å®çãªé²
æ©ããããããªãã€ãããã®æ¹æ³ã®æ¬ ç¹ã¯ããžã¢
ã«ãã«çé žå¡©ã¯ãã¹ã²ã³åã³ã¢ã«ã³ãŒã«ãããã
ãã¯å·¥æ¥çã«ãªãåé¡ã®ãã觊åªåå¿ã«ããäžé ž
åççŽ åã³ã¢ã«ã³ãŒã«ã®å ±é žåã«ãã€ãŠè£œé ããª
ããã°ãªããããªãé«äŸ¡ãªãã®ãšãªããåå¿é床
ãå®éã«äœãããã€ïŒ®âã¢ã«ãã«âã¢ããªã³ã®ç«¶
äºçæã«ããéžææ§ãäžæºè¶³ãªãã®ã§ããããšã«
ããã
æŽã«ãæ°ããææ¡ã«ããã°ãã¢ãªãŒã«ãŠã¬ã¿ã³
ã¯ãã¹ã²ã³ãçšããããšãªãã«ãããè³éŠæåå
ç©ãã¢ã«ã³ãŒã«åã³äžé žåççŽ ããåŸãããšãã§
ãã次ã«ããè¯å¥œãªæåçã§ã€ãœã·ã¢ããŒãã«å€
ããããšãã§ããïŒè±åœç¹èš±ç¬¬1247451å·æ现
æžïŒã
ã¯ãã¹ã²ã³ãçšããããšãªãã«ãããè³éŠæåå
ç©ãã¢ã«ã³ãŒã«åã³äžé žåççŽ ããåŸãããšãã§
ãã次ã«ããè¯å¥œãªæåçã§ã€ãœã·ã¢ããŒãã«å€
ããããšãã§ããïŒè±åœç¹èš±ç¬¬1247451å·æ现
æžïŒã
ãã€ãé£éŠå
±ååœç¹èš±åºé¡å
¬é第1568044å·æ
现æžïŒç±³åœç¹èš±ç¬¬3467694å·æ现æžïŒã®èšèŒã«ã
ãããŠã¬ã¿ã³ã¯ãææ©ãããååç©ãäžé žåççŽ
åã³ããããã·ã«åºå«æååç©ãã貎éå±åã³ã«
ã€ã¹é žãããªã觊åªã®ååšäžã«å®éã«æ°Žãæããª
ãæ¡ä»¶äžã§æ°ŽçŽ ã®äžåšäžã«é«ããããå§ååã³
150â以äžã®æž©åºŠã§åå¿ãããããšã«ãã€ãŠè£œé
ãããããã€ãé£éŠå ±ååœç¹èš±åºé¡å ¬é第
2343826å·æ现æžïŒç±³åœç¹èš±ç¬¬3895054å·æ现æžïŒ
ã«ããã°ããŠã¬ã¿ã³ã¯ãããããã·ã«åºå«æåå
ç©ãäžé žåççŽ ãªãã³ã«ãããâãããããœâã
ã¢ãŸâåã³ã¢ãŸãã·åºãæããååç©ããç¡«é»ã
ã»ã¬ã³ãç¡«é»ååç©åã³ïŒåã¯ã»ã¬ã³ååç©ãªã
ã³ã«å°ãªããšãïŒã€ã®å¡©åºåã³ïŒåã¯æ°Žã®ååšäž
ã«åŸãããããã€ãé£éŠå ±ååœç¹èš±åºé¡å ¬é第
2623694å·æ现æžïŒç±³åœç¹èš±ç¬¬4080365å·æ现æžïŒ
ã«ã¯ãã»ã¬ã³å«æ觊åªç³»ãªãã³ã«ç¹æ®ãªè³éŠæã¢
ããâåã³å°¿çŽ ååç©ã®ååšäžã§ã®åèšéå§å€çµ
æç©ããã®è³éŠæãŠã¬ã¿ã³ã®è£œé ãèšèŒãããŠã
ãã
现æžïŒç±³åœç¹èš±ç¬¬3467694å·æ现æžïŒã®èšèŒã«ã
ãããŠã¬ã¿ã³ã¯ãææ©ãããååç©ãäžé žåççŽ
åã³ããããã·ã«åºå«æååç©ãã貎éå±åã³ã«
ã€ã¹é žãããªã觊åªã®ååšäžã«å®éã«æ°Žãæããª
ãæ¡ä»¶äžã§æ°ŽçŽ ã®äžåšäžã«é«ããããå§ååã³
150â以äžã®æž©åºŠã§åå¿ãããããšã«ãã€ãŠè£œé
ãããããã€ãé£éŠå ±ååœç¹èš±åºé¡å ¬é第
2343826å·æ现æžïŒç±³åœç¹èš±ç¬¬3895054å·æ现æžïŒ
ã«ããã°ããŠã¬ã¿ã³ã¯ãããããã·ã«åºå«æåå
ç©ãäžé žåççŽ ãªãã³ã«ãããâãããããœâã
ã¢ãŸâåã³ã¢ãŸãã·åºãæããååç©ããç¡«é»ã
ã»ã¬ã³ãç¡«é»ååç©åã³ïŒåã¯ã»ã¬ã³ååç©ãªã
ã³ã«å°ãªããšãïŒã€ã®å¡©åºåã³ïŒåã¯æ°Žã®ååšäž
ã«åŸãããããã€ãé£éŠå ±ååœç¹èš±åºé¡å ¬é第
2623694å·æ现æžïŒç±³åœç¹èš±ç¬¬4080365å·æ现æžïŒ
ã«ã¯ãã»ã¬ã³å«æ觊åªç³»ãªãã³ã«ç¹æ®ãªè³éŠæã¢
ããâåã³å°¿çŽ ååç©ã®ååšäžã§ã®åèšéå§å€çµ
æç©ããã®è³éŠæãŠã¬ã¿ã³ã®è£œé ãèšèŒãããŠã
ãã
ããããªããããããã®æ¹æ³ããªãé倧ãªæ¬ ç¹
ãæãããææ¯ãªäžé žåççŽ åã³ææ¯ã§ãããã
ããã¯åå¿ã®çµéäžã«ææ¯ãªååç©ãçæãã觊
åªãäŸãã°ã»ã¬ã³âåã³ç¡«åæ°ŽçŽ åã¯æ¥µããŠé«äŸ¡
ã§ãããã€ååãå°é£ãªè§ŠåªãäŸãã°ãã©ãžãŠã
ã¯ãé«ãå·¥æ¥çè²»çšåã³è²»çšããããå®å šæªçœ®ã
å¿ èŠãšããã
ãæãããææ¯ãªäžé žåççŽ åã³ææ¯ã§ãããã
ããã¯åå¿ã®çµéäžã«ææ¯ãªååç©ãçæãã觊
åªãäŸãã°ã»ã¬ã³âåã³ç¡«åæ°ŽçŽ åã¯æ¥µããŠé«äŸ¡
ã§ãããã€ååãå°é£ãªè§ŠåªãäŸãã°ãã©ãžãŠã
ã¯ãé«ãå·¥æ¥çè²»çšåã³è²»çšããããå®å šæªçœ®ã
å¿ èŠãšããã
ããããŠè£œé å¯èœãªããšãã«ãŠã¬ã¿ã³ãåèšã®
ãã€ãé£éŠå ±ååœç¹èš±ç¬¬1042891å·æ现æžã®èšèŒ
ãšåæ§ã«ããŠãã«ã ã¢ã«ãããã§åŸåŠçããããš
ã¯ãåŸãããåçž®ç©ãè±æ°Žãããã€ïŒ®ââçµå
çæç©ãââçµåçæç©ã«å®å šã«è»¢ç§»ããã
ãã«é žã§åŠçããããšã«ããããã奜é©ãªç²è£œ
MDUãäŸçµŠããã䜿çšããã倧ããé žéåã³ç
æãããå¯çæç©ãäŸãã°ã¢ãã³ãã¯é倧ãªå»æ°Ž
è² è·ã瀺ããåŸã€ãŠããã€ãé£éŠå ±ååœç¹èš±åºé¡
å ¬é第2832379å·æ现æžã«ããç²è£œMDUã®æ¹å
ãããå質ã¯ãããã«å¢å€§ããå·¥æ¥çè²»çšã«ãã€
ãŠåŸãªããã°ãªããªãã
ãã€ãé£éŠå ±ååœç¹èš±ç¬¬1042891å·æ现æžã®èšèŒ
ãšåæ§ã«ããŠãã«ã ã¢ã«ãããã§åŸåŠçããããš
ã¯ãåŸãããåçž®ç©ãè±æ°Žãããã€ïŒ®ââçµå
çæç©ãââçµåçæç©ã«å®å šã«è»¢ç§»ããã
ãã«é žã§åŠçããããšã«ããããã奜é©ãªç²è£œ
MDUãäŸçµŠããã䜿çšããã倧ããé žéåã³ç
æãããå¯çæç©ãäŸãã°ã¢ãã³ãã¯é倧ãªå»æ°Ž
è² è·ã瀺ããåŸã€ãŠããã€ãé£éŠå ±ååœç¹èš±åºé¡
å ¬é第2832379å·æ现æžã«ããç²è£œMDUã®æ¹å
ãããå質ã¯ãããã«å¢å€§ããå·¥æ¥çè²»çšã«ãã€
ãŠåŸãªããã°ãªããªãã
ãã§ã«èª¬æããããã«ãâ眮æãŠã¬ã¿ã³ã¯åŒ
ç¶ããŠã€ãœã·ã¢ããŒãã«ç±å解å¯èœã§ãããç±å
解ããå Žåãåæã«çš®ã ã®å¥œãŸãããªãå¯åå¿ã
çãããäŸãã°ã次ã®ããšãæããããïŒïŒçŽã¢
ãã³åã³ïŒçŽã¢ãã³ãªãã³ã«ãªã¬ãã€ã³ãçæã
ãããšã«ãã€ãŠé䌎ããããŠã¬ã¿ã³ã®è±ã«ã«ãã
ã·ã«ååå¿ïŒçæãããã€ãœã·ã¢ããŒããšãŠã¬ã¿
ã³ãšãåå¿ãããããšã«ãã€ãŠã¢ããã¢ããŒãã«
ããåå¿åã¯çæãããã€ãœã·ã¢ããŒããšã¢ãã³
ãšãåå¿ãããããšã«ãã€ãŠå°¿çŽ ã«ããåå¿åã³
ã€ãœã·ã¢ããŒããã€ãœã·ã¢ãã¬ãŒãã«ããéåã
ç¶ããŠã€ãœã·ã¢ããŒãã«ç±å解å¯èœã§ãããç±å
解ããå Žåãåæã«çš®ã ã®å¥œãŸãããªãå¯åå¿ã
çãããäŸãã°ã次ã®ããšãæããããïŒïŒçŽã¢
ãã³åã³ïŒçŽã¢ãã³ãªãã³ã«ãªã¬ãã€ã³ãçæã
ãããšã«ãã€ãŠé䌎ããããŠã¬ã¿ã³ã®è±ã«ã«ãã
ã·ã«ååå¿ïŒçæãããã€ãœã·ã¢ããŒããšãŠã¬ã¿
ã³ãšãåå¿ãããããšã«ãã€ãŠã¢ããã¢ããŒãã«
ããåå¿åã¯çæãããã€ãœã·ã¢ããŒããšã¢ãã³
ãšãåå¿ãããããšã«ãã€ãŠå°¿çŽ ã«ããåå¿åã³
ã€ãœã·ã¢ããŒããã€ãœã·ã¢ãã¬ãŒãã«ããéåã
èžæ°çžïŒãã®å Žåãèžæ°çžã¯ãå Žåã«ãã€ãŠã¯
溶å€ãå«ããŠçæç©æ··åç©ãèžæ°çžäžã§ã®åé¢åŸ
ã«ãåé¢ãã¹ããŠã¬ã¿ã³ãã¬ã¹ç¶ã液ç¶åã¯åºäœ
ç¶ã§äŸçµŠããããšããŠãç¬ç«ããŠååšãããšãã
ããã«å®çŸ©ãããïŒäžã§ã®ãŠã¬ã¿ã³ã®ç±å解ã¯ã
ãã€ãé£éŠå ±ååœç¹èš±åºé¡å ¬é第1944719å·æ现
æžïŒè±åœç¹èš±ç¬¬1247451å·æ现æžïŒã®èšèŒã«ãã
400âã600âã®æž©åºŠã§è§ŠåªãšããŠã®ã«ã€ã¹é žã®å
åšäžã«å®æœããããã®å Žåã€ãœã·ã¢ããŒããšã¢ã«
ã³ãŒã«ã¯åå¥åçž®ã«ãã€ãŠåé¢ãããããã«ã€ã¬
ã³ãžã€ãœã·ã¢ããŒãã¯ãäŸãã°å¡©åéïŒïŒã®å
åšäžã«ãã«ã€ã¬ã³âïŒïŒïŒâãžãšãã«ãŠã¬ã¿ã³ã
ç±å解ããããšã«ãã€ãŠåŸãããããã®åå¿ã®æ¬
ç¹ã¯ããšãã«èéã®éåäœå¯çæç©ã觊åªã®å解
åã³è èæ§ãšçµã³ä»ããäœãåçã«ããããã€ã
é£éŠå ±ååœç¹èš±åºé¡å ¬é第2410505å·æ现æžïŒç±³
åœç¹èš±ç¬¬3870739å·æ现æžïŒã«ã¯ããŠã¬ã¿ã³ã350
âã550âã®æž©åºŠåã³ã€ãœã·ã¢ããŒãèžæ°å§ã®
ïŒïœïŒïŒïŒåãããå°ãªãå§åã§è§Šåªãæããªã
ç±å解垯åäžã§15ç§éå解ããæ¹æ³ãèšèŒãããŠ
ããããã®æ¹æ³ã®æ¬ ç¹ã¯ããšãã«çºç±å解ã«å¿ èŠ
ãªå€§ããç±éã極ããŠçãæéå ã§ç²æ«ç¶ãŠã¬ã¿
ã³ã«äŸçµŠããªããã°ãªãããå¯çæç©ãšããŠçã
ãåºäœéåäœåã³ãã®åé¢ãé£ç¶çæ¹æ³ã®å®æœã
å°é£ã«ããããšã«ããã
溶å€ãå«ããŠçæç©æ··åç©ãèžæ°çžäžã§ã®åé¢åŸ
ã«ãåé¢ãã¹ããŠã¬ã¿ã³ãã¬ã¹ç¶ã液ç¶åã¯åºäœ
ç¶ã§äŸçµŠããããšããŠãç¬ç«ããŠååšãããšãã
ããã«å®çŸ©ãããïŒäžã§ã®ãŠã¬ã¿ã³ã®ç±å解ã¯ã
ãã€ãé£éŠå ±ååœç¹èš±åºé¡å ¬é第1944719å·æ现
æžïŒè±åœç¹èš±ç¬¬1247451å·æ现æžïŒã®èšèŒã«ãã
400âã600âã®æž©åºŠã§è§ŠåªãšããŠã®ã«ã€ã¹é žã®å
åšäžã«å®æœããããã®å Žåã€ãœã·ã¢ããŒããšã¢ã«
ã³ãŒã«ã¯åå¥åçž®ã«ãã€ãŠåé¢ãããããã«ã€ã¬
ã³ãžã€ãœã·ã¢ããŒãã¯ãäŸãã°å¡©åéïŒïŒã®å
åšäžã«ãã«ã€ã¬ã³âïŒïŒïŒâãžãšãã«ãŠã¬ã¿ã³ã
ç±å解ããããšã«ãã€ãŠåŸãããããã®åå¿ã®æ¬
ç¹ã¯ããšãã«èéã®éåäœå¯çæç©ã觊åªã®å解
åã³è èæ§ãšçµã³ä»ããäœãåçã«ããããã€ã
é£éŠå ±ååœç¹èš±åºé¡å ¬é第2410505å·æ现æžïŒç±³
åœç¹èš±ç¬¬3870739å·æ现æžïŒã«ã¯ããŠã¬ã¿ã³ã350
âã550âã®æž©åºŠåã³ã€ãœã·ã¢ããŒãèžæ°å§ã®
ïŒïœïŒïŒïŒåãããå°ãªãå§åã§è§Šåªãæããªã
ç±å解垯åäžã§15ç§éå解ããæ¹æ³ãèšèŒãããŠ
ããããã®æ¹æ³ã®æ¬ ç¹ã¯ããšãã«çºç±å解ã«å¿ èŠ
ãªå€§ããç±éã極ããŠçãæéå ã§ç²æ«ç¶ãŠã¬ã¿
ã³ã«äŸçµŠããªããã°ãªãããå¯çæç©ãšããŠçã
ãåºäœéåäœåã³ãã®åé¢ãé£ç¶çæ¹æ³ã®å®æœã
å°é£ã«ããããšã«ããã
液çžäžã§ã®ãŠã¬ã¿ã³ã®ç±å解ã¯ãäŸãã°ãã€ã
é£éŠå ±ååœç¹èš±åºé¡å ¬å第2421503å·æ现æžïŒç±³
åœç¹èš±ç¬¬3962302å·æ现æžïŒåã³ãã€ãé£éŠå ±å
åœç¹èš±åºé¡å ¬å第2530001å·æ现æžïŒç±³åœç¹èš±ç¬¬
3919280å·æ现æžïŒã«èšèŒãããŠããããã€ãé£
éŠå ±ååœç¹èš±åºé¡å ¬å第2421503å·æ现æžã®èšèŒ
ã«ããããŠã¬ã¿ã³ãäžæŽ»æ§æº¶å€ãäŸãã°ã¢ã«ãã«
ãã³ãŸãŒã«ãçŽéç¶åã³ç°åŒã®çåæ°ŽçŽ åã³ïŒå
ã¯ãã¿ã«é žãšã¹ãã«ã«æº¶è§£ãããã€åžžå§äžåã¯é
å§äžã§175âã350âã§å解ãããåŸãããã€ãœã·
ã¢ããŒãåã³ã¢ã«ã³ãŒã«ã®åé¢åã³åé¢ã¯ãæ æ
å€ãšããŠã®æº¶å€ã«ããåã³ïŒåã¯æ æå€ãšããŠã®
äžæŽ»æ§ã¬ã¹ã䜿çšããŠè¡ãªãããããã€ãé£éŠå ±
ååœç¹èš±åºé¡å ¬å第2530001å·æ现æžã«ããã°ã
åå¿åªäœãšããŠã¯é«ååã®ãå Žåã«ãã€ãŠã¯çœ®æ
ãããèèªæãèç°åŒåã¯è³éŠæã®çåæ°ŽçŽ ããš
ãŒãã«ããšã¹ãã«åã¯ã±ãã³ã䜿çšããããå解
çæç©ãåé¢ããããã«ã¯ãèžçã®ã¿ãèšèŒãã
ãŠããããã®å Žåå¡é ãä»ããŠã€ãœã·ã¢ããŒãã
ã¢ã«ã³ãŒã«åã³æ æææãçå»ãããåå¿åªäœã¯
å¡åºçåãšããŠæ®åããã
é£éŠå ±ååœç¹èš±åºé¡å ¬å第2421503å·æ现æžïŒç±³
åœç¹èš±ç¬¬3962302å·æ现æžïŒåã³ãã€ãé£éŠå ±å
åœç¹èš±åºé¡å ¬å第2530001å·æ现æžïŒç±³åœç¹èš±ç¬¬
3919280å·æ现æžïŒã«èšèŒãããŠããããã€ãé£
éŠå ±ååœç¹èš±åºé¡å ¬å第2421503å·æ现æžã®èšèŒ
ã«ããããŠã¬ã¿ã³ãäžæŽ»æ§æº¶å€ãäŸãã°ã¢ã«ãã«
ãã³ãŸãŒã«ãçŽéç¶åã³ç°åŒã®çåæ°ŽçŽ åã³ïŒå
ã¯ãã¿ã«é žãšã¹ãã«ã«æº¶è§£ãããã€åžžå§äžåã¯é
å§äžã§175âã350âã§å解ãããåŸãããã€ãœã·
ã¢ããŒãåã³ã¢ã«ã³ãŒã«ã®åé¢åã³åé¢ã¯ãæ æ
å€ãšããŠã®æº¶å€ã«ããåã³ïŒåã¯æ æå€ãšããŠã®
äžæŽ»æ§ã¬ã¹ã䜿çšããŠè¡ãªãããããã€ãé£éŠå ±
ååœç¹èš±åºé¡å ¬å第2530001å·æ现æžã«ããã°ã
åå¿åªäœãšããŠã¯é«ååã®ãå Žåã«ãã€ãŠã¯çœ®æ
ãããèèªæãèç°åŒåã¯è³éŠæã®çåæ°ŽçŽ ããš
ãŒãã«ããšã¹ãã«åã¯ã±ãã³ã䜿çšããããå解
çæç©ãåé¢ããããã«ã¯ãèžçã®ã¿ãèšèŒãã
ãŠããããã®å Žåå¡é ãä»ããŠã€ãœã·ã¢ããŒãã
ã¢ã«ã³ãŒã«åã³æ æææãçå»ãããåå¿åªäœã¯
å¡åºçåãšããŠæ®åããã
è³éŠæã€ãœã·ã¢ããŒãã補é ããããã«ããŠã¬
ã¿ã³ã¯ããã€ãé£éŠå ±ååœç¹èš±åºé¡å ¬é第
2635490å·æ现æžã®èšèŒã«ãã150âã350âã®æž©
床ã§æžå§äžã§è§ŠåªïŒããã¯ã沞ç¹200âãæãã
äžæŽ»æ§æº¶å€äžã«æº¶å€ã«å¯ŸããŠå°ãªããšã0.001é
éïŒ ã®éå±æ¿åºŠã§æº¶è§£ãããŠããïŒãšããŠã®å°ãª
ããšãïŒã€ã®éå±ã€ãªã³ãäŸãã°é ãäºéãã¢ã«
ãããŠã ãé«ããã¿ã³ããããžãŠã ãéãã³ãã«
ãåã³ããã±ã«ã®ã€ãªã³ããã®æº¶æ¶²ãšæ¥è§Šãã
ããåŸãããå解çæç©ã®åé¢ã¯ãåå¥åçž®ã«ã
ã€ãŠè¡ãªããããåèšæ¹æ³ã«ããããŠã¬ã¿ã³ã¯æ§
é ã«å¿ããŠéšåçã«æ¥µããŠè¯å¥œãªåçã§ã€ãœã·ã¢
ããŒãã«å€ããããšãã§ããããã®ç¹èš±æ现æžã«
ã¯ãç²è£œMDIã®è£œé ã¯ãäŸç€ºçã«ãèšèŒãããŠ
ãªãã
ã¿ã³ã¯ããã€ãé£éŠå ±ååœç¹èš±åºé¡å ¬é第
2635490å·æ现æžã®èšèŒã«ãã150âã350âã®æž©
床ã§æžå§äžã§è§ŠåªïŒããã¯ã沞ç¹200âãæãã
äžæŽ»æ§æº¶å€äžã«æº¶å€ã«å¯ŸããŠå°ãªããšã0.001é
éïŒ ã®éå±æ¿åºŠã§æº¶è§£ãããŠããïŒãšããŠã®å°ãª
ããšãïŒã€ã®éå±ã€ãªã³ãäŸãã°é ãäºéãã¢ã«
ãããŠã ãé«ããã¿ã³ããããžãŠã ãéãã³ãã«
ãåã³ããã±ã«ã®ã€ãªã³ããã®æº¶æ¶²ãšæ¥è§Šãã
ããåŸãããå解çæç©ã®åé¢ã¯ãåå¥åçž®ã«ã
ã€ãŠè¡ãªããããåèšæ¹æ³ã«ããããŠã¬ã¿ã³ã¯æ§
é ã«å¿ããŠéšåçã«æ¥µããŠè¯å¥œãªåçã§ã€ãœã·ã¢
ããŒãã«å€ããããšãã§ããããã®ç¹èš±æ现æžã«
ã¯ãç²è£œMDIã®è£œé ã¯ãäŸç€ºçã«ãèšèŒãããŠ
ãªãã
äŸç€ºãããã€ãœã·ã¢ããŒããšã¯ç°ãªããç²è£œ
MDIã¯ãæ æäœãšããŠã®æº¶å€ã«ããå®å šã«èžç
ã§ããªãããããã€ãŠåèšã®ããã«è§Šåªåã³å Žå
ã«ãã€ãŠã¯éåå¿åºçºç©è³ªãªãã³ã«äžçŽç©ããå
é¢ããããšã¯ã§ããªãã
MDIã¯ãæ æäœãšããŠã®æº¶å€ã«ããå®å šã«èžç
ã§ããªãããããã€ãŠåèšã®ããã«è§Šåªåã³å Žå
ã«ãã€ãŠã¯éåå¿åºçºç©è³ªãªãã³ã«äžçŽç©ããå
é¢ããããšã¯ã§ããªãã
æ¬çºæã®èª²é¡ã¯ãç²è£œMDIãçµæžçåã³çæ
åŠçã«æå©ã«å®¹æã«å ¥æãããåºçºç©è³ªããæ害
ãªæåã®ãã¹ã²ã³ãäžé žåççŽ ãå¡©çŽ åã³å¡©åæ°Ž
çŽ ãªãã«ãªãã³ã«é«äŸ¡ã§ææ¯ãªè§ŠåªãäŸãã°ãã©
ãžãŠã åã¯ã»ã¬ã³ãªãã«ååŸããããšã«ããã
åŠçã«æå©ã«å®¹æã«å ¥æãããåºçºç©è³ªããæ害
ãªæåã®ãã¹ã²ã³ãäžé žåççŽ ãå¡©çŽ åã³å¡©åæ°Ž
çŽ ãªãã«ãªãã³ã«é«äŸ¡ã§ææ¯ãªè§ŠåªãäŸãã°ãã©
ãžãŠã åã¯ã»ã¬ã³ãªãã«ååŸããããšã«ããã
ãã®èª²é¡ã¯ã
 ã¢ããªã³ãšãâã¢ã«ãã«ã«ã«ãããé
žãšã¹
ãã«åã³å Žåã«ãã€ãŠã¯å°¿çŽ åã³ã¢ã«ã³ãŒã«ãš
ãã觊åªã®ååšäžã§ããããã¯è§Šåªã®äžåšäžã§
åå¿ãããŠïŒ®âããšãã«ãŒãŠã¬ã¿ã³ã«ãããã®
å Žåçæããã¢ã³ã¢ãã¢ãå Žåã«ãã€ãŠã¯åé¢
ãã  åŸãããâããšãã«âãŠã¬ã¿ã³ããã«ã ã¢
ã«ãããåã¯æå©ã«åŒïŒ âCH2â ãåŒäžãã¯ROâãRSâåã¯ROCOåºãè¡š
ããããããã®ïŒ²ã¯ã¢ã«ãã«åºãè¡šãããã§ç€º
ãããäºå®èœååç©ãšãé žåã¯ã«ã«ãã³é žã®å
åšäžã«çž®åããŠã¡ãã¬ã³âãã¹âããšãã«ãŠã¬
ã¿ã³ãšããªã¡ãã¬ã³âããªããšãã«ãŠã¬ã¿ã³ãš
ãããªãæ··åç©ã«ããã〠 ã¡ãã¬ã³âãã¹âããšãã«ãŠã¬ã¿ã³ãšããªã¡
ãã¬ã³âããªããšãã«ãŠã¬ã¿ã³ãšãããªãæ··å
ç©ãå Žåã«ãã€ãŠã¯è§Šåªã®ååšäžã«175âã600
âã®æž©åºŠã§ç±å解ããããšã«ãã€ãŠãžããšãã«
ã¡ã¿ã³âãžã€ãœã·ã¢ããŒããšããªããšãã«âã
ãªã¡ãã¬ã³âããªã€ãœã·ã¢ããŒããšãããªãæ··
åç©ã«å€ãã ããšãç¹åŸŽãšãããå€æ°ã®åå¿å·¥çšã§ãžããšãã«
ã¡ã¿ã³âãžã€ãœã·ã¢ããŒããšããªããšãã«âããª
ã¡ãã¬ã³âããªã€ãœã·ã¢ããŒããšãããªãæ··åç©
ïŒç²è£œMDIïŒã補é ããæ¹æ³ã«ãã€ãŠè§£æ±ºãã
ãã
ãã«åã³å Žåã«ãã€ãŠã¯å°¿çŽ åã³ã¢ã«ã³ãŒã«ãš
ãã觊åªã®ååšäžã§ããããã¯è§Šåªã®äžåšäžã§
åå¿ãããŠïŒ®âããšãã«ãŒãŠã¬ã¿ã³ã«ãããã®
å Žåçæããã¢ã³ã¢ãã¢ãå Žåã«ãã€ãŠã¯åé¢
ãã  åŸãããâããšãã«âãŠã¬ã¿ã³ããã«ã ã¢
ã«ãããåã¯æå©ã«åŒïŒ âCH2â ãåŒäžãã¯ROâãRSâåã¯ROCOåºãè¡š
ããããããã®ïŒ²ã¯ã¢ã«ãã«åºãè¡šãããã§ç€º
ãããäºå®èœååç©ãšãé žåã¯ã«ã«ãã³é žã®å
åšäžã«çž®åããŠã¡ãã¬ã³âãã¹âããšãã«ãŠã¬
ã¿ã³ãšããªã¡ãã¬ã³âããªããšãã«ãŠã¬ã¿ã³ãš
ãããªãæ··åç©ã«ããã〠 ã¡ãã¬ã³âãã¹âããšãã«ãŠã¬ã¿ã³ãšããªã¡
ãã¬ã³âããªããšãã«ãŠã¬ã¿ã³ãšãããªãæ··å
ç©ãå Žåã«ãã€ãŠã¯è§Šåªã®ååšäžã«175âã600
âã®æž©åºŠã§ç±å解ããããšã«ãã€ãŠãžããšãã«
ã¡ã¿ã³âãžã€ãœã·ã¢ããŒããšããªããšãã«âã
ãªã¡ãã¬ã³âããªã€ãœã·ã¢ããŒããšãããªãæ··
åç©ã«å€ãã ããšãç¹åŸŽãšãããå€æ°ã®åå¿å·¥çšã§ãžããšãã«
ã¡ã¿ã³âãžã€ãœã·ã¢ããŒããšããªããšãã«âããª
ã¡ãã¬ã³âããªã€ãœã·ã¢ããŒããšãããªãæ··åç©
ïŒç²è£œMDIïŒã補é ããæ¹æ³ã«ãã€ãŠè§£æ±ºãã
ãã
æ¬çºæã«ããæ¹æ³ã¯ã次ã®æ¹çšåŒïŒïŒã
ïŒïŒã«ãã€ãŠæŠç¥çã«èª¬æããããšãã§ããã
ïŒïŒã«ãã€ãŠæŠç¥çã«èª¬æããããšãã§ããã
äžèšåŒäžïŒ²ã¯ã¢ã«ãã«åºããã¯ROâïŒRS
âïŒROCâãè¡šããïœïŒïœïŒïœåã³ïœã¯ããã
ãæŽæ°ãè¡šãããã®å ŽååŒïŒïŒã«ããïœïŒïœã¯
ïœã§ãããïœïŒïœã¯1.5ãïŒã§ãããåŒïŒïŒå
ã³ïŒïŒã«ããïœã¯ïŒãïŒåã³ãã以äžã§ããã
âïŒROCâãè¡šããïœïŒïœïŒïœåã³ïœã¯ããã
ãæŽæ°ãè¡šãããã®å ŽååŒïŒïŒã«ããïœïŒïœã¯
ïœã§ãããïœïŒïœã¯1.5ãïŒã§ãããåŒïŒïŒå
ã³ïŒïŒã«ããïœã¯ïŒãïŒåã³ãã以äžã§ããã
åŠçå·¥çšã§ã®åã³è¯å¥œãªåçã§ã®ïŒ®âããšãã«
âãŠã¬ã¿ã³ã®çæã¯ãé©ç°çãªãã®ã§ãããå ¬ç¥
ã®ææ³ã«ãããã«ã«ãããé žãšã¹ãã«åã³è³éŠæ
ã¢ãã³ããïŒïŒ®âãžã¢ãªãŒã«å°¿çŽ ãåŸããã該
å°¿çŽ ã¯å€ãã®å Žåã¢ã«ã³ãŒã«ããåçµæ¶ãããã
é眮æãŠã¬ã¿ã³ã¯ãè³éŠæã¢ãã³ã®ååšäžã«ãã
ã«ã¢ã«ã³ãŒã«äžã§åŸåå¿ããŠæ¥µããŠç°¡åã«ïŒ®ïŒïŒ®
âãžã¢ãªãŒã«å°¿çŽ ã«å€ããïŒããŠãã³âãã€ã«
ïŒHoubenâWeylïŒãâã¡ãâãã³ã»ãã«ã»ãªã«ã¬
ããã·ãšã³ã»ããšããŒïŒMethoden der
organischen ChemieïŒâã第ïŒå·»ã第152é ã第
140é åã³ç¬¬161é ãGeorg Thieme Verlag
ïŒStuttgartïŒç€Ÿåã1952幎ïŒã
âãŠã¬ã¿ã³ã®çæã¯ãé©ç°çãªãã®ã§ãããå ¬ç¥
ã®ææ³ã«ãããã«ã«ãããé žãšã¹ãã«åã³è³éŠæ
ã¢ãã³ããïŒïŒ®âãžã¢ãªãŒã«å°¿çŽ ãåŸããã該
å°¿çŽ ã¯å€ãã®å Žåã¢ã«ã³ãŒã«ããåçµæ¶ãããã
é眮æãŠã¬ã¿ã³ã¯ãè³éŠæã¢ãã³ã®ååšäžã«ãã
ã«ã¢ã«ã³ãŒã«äžã§åŸåå¿ããŠæ¥µããŠç°¡åã«ïŒ®ïŒïŒ®
âãžã¢ãªãŒã«å°¿çŽ ã«å€ããïŒããŠãã³âãã€ã«
ïŒHoubenâWeylïŒãâã¡ãâãã³ã»ãã«ã»ãªã«ã¬
ããã·ãšã³ã»ããšããŒïŒMethoden der
organischen ChemieïŒâã第ïŒå·»ã第152é ã第
140é åã³ç¬¬161é ãGeorg Thieme Verlag
ïŒStuttgartïŒç€Ÿåã1952幎ïŒã
âããšãã«âãŠã¬ã¿ã³ãã¢ããªã³åã³ïŒ¯âã¢
ã«ãã«ã«ã«ãããé žãšã¹ãã«ããæ¬çºæã«ãã觊
åªåå¿ã§ãã§ã«ã¢ã«ã³ãŒã«ã®äžåšäžã«åŸãããé
å°ã®ïŒ¯âã¢ã«ãã«ã«ã«ãããé žãšã¹ãã«ãé倧ãª
å解åã³éçž®åããŸããããåå¿ãåèšè§Šåªã®æ·»
å ã«ãã€ãŠæ¯èŒçäœã枩床ã§å·¥æ¥çã«å®æœããã
ãšãã§ããã€ãã®éžææ§ã«ãããŠãæ¹åããããš
ãã§ããå°¿çŽ åã³ã¢ã«ã³ãŒã«ãšã®åå¿ããããã
ã倧éã®ïŒ¯âã¢ã«ãã«ã«ã«ãããé žãšã¹ãã«ãšäž
ç·ã«å®æœããããšã«ããå°ãªããšãïŒã€ã®åèšè§Š
åªã®ååšäžã«ãã§ã«æ¯èŒçäœã枩床ã§å·¥æ¥çã«è
ããæå¹ã§ããããšã¯é©ç°çãªããšã§ããããã®
å Žåãâã¢ã«ãã«ã«ã«ãããé žãšã¹ãã«ãå¥å
ã«è£œé ããããšã¯å¿ èŠã§ãªããç°¡åã«å®éã«è¡ãª
ãããšãã§ããæå©ã«é©çšãããå®æœæ æ§ã§ã¯ã
âã¢ã«ãã«ã«ã«ãããé žãšã¹ãã«ã¯ãå°¿çŽ åã³
ã¢ã«ã³ãŒã«ãšäžç·ã«äœ¿çšããããã€ã¢ããªã³ãå
åã«ãªããå®å šã«åå¿ããåŸã«èžçããããšã«ã
ã€ãŠåé¢ãããå Žåã«ãã€ãŠã¯æ»ããããæ¹æ³ã¯
é£ç¶çã«å®æœããŠãããã
ã«ãã«ã«ã«ãããé žãšã¹ãã«ããæ¬çºæã«ãã觊
åªåå¿ã§ãã§ã«ã¢ã«ã³ãŒã«ã®äžåšäžã«åŸãããé
å°ã®ïŒ¯âã¢ã«ãã«ã«ã«ãããé žãšã¹ãã«ãé倧ãª
å解åã³éçž®åããŸããããåå¿ãåèšè§Šåªã®æ·»
å ã«ãã€ãŠæ¯èŒçäœã枩床ã§å·¥æ¥çã«å®æœããã
ãšãã§ããã€ãã®éžææ§ã«ãããŠãæ¹åããããš
ãã§ããå°¿çŽ åã³ã¢ã«ã³ãŒã«ãšã®åå¿ããããã
ã倧éã®ïŒ¯âã¢ã«ãã«ã«ã«ãããé žãšã¹ãã«ãšäž
ç·ã«å®æœããããšã«ããå°ãªããšãïŒã€ã®åèšè§Š
åªã®ååšäžã«ãã§ã«æ¯èŒçäœã枩床ã§å·¥æ¥çã«è
ããæå¹ã§ããããšã¯é©ç°çãªããšã§ããããã®
å Žåãâã¢ã«ãã«ã«ã«ãããé žãšã¹ãã«ãå¥å
ã«è£œé ããããšã¯å¿ èŠã§ãªããç°¡åã«å®éã«è¡ãª
ãããšãã§ããæå©ã«é©çšãããå®æœæ æ§ã§ã¯ã
âã¢ã«ãã«ã«ã«ãããé žãšã¹ãã«ã¯ãå°¿çŽ åã³
ã¢ã«ã³ãŒã«ãšäžç·ã«äœ¿çšããããã€ã¢ããªã³ãå
åã«ãªããå®å šã«åå¿ããåŸã«èžçããããšã«ã
ã€ãŠåé¢ãããå Žåã«ãã€ãŠã¯æ»ããããæ¹æ³ã¯
é£ç¶çã«å®æœããŠãããã
æŽã«ãåŸãããâããšãã«âãŠã¬ã¿ã³ããã«
ã ã¢ã«ãããåã¯åŒïŒCH2ïŒORïŒ2åã³CH2
ïŒOCORïŒ2ã®ã¢ã»ã¿ãŒã«åã³ã¢ã·ã©ãŒã«ã§æ°Žã®äž
åšäžåã³é žåã¯ã«ã«ãã³é žã®ååšäžã«åæ»ã«è¯å¥œ
ãªåçã§åã³é«ãçŽåºŠã§ç²è£œMDUã«å€ããããš
ãã§ããããšã¯é©ç°çãªããšã§ããã
ã ã¢ã«ãããåã¯åŒïŒCH2ïŒORïŒ2åã³CH2
ïŒOCORïŒ2ã®ã¢ã»ã¿ãŒã«åã³ã¢ã·ã©ãŒã«ã§æ°Žã®äž
åšäžåã³é žåã¯ã«ã«ãã³é žã®ååšäžã«åæ»ã«è¯å¥œ
ãªåçã§åã³é«ãçŽåºŠã§ç²è£œMDUã«å€ããããš
ãã§ããããšã¯é©ç°çãªããšã§ããã
âããšãã«ãŠã¬ã¿ã³ã補é ããããã«ã¯ã
âã¢ã«ãã«ã«ã«ãããé žãšã¹ãã«ãæ¬çºææ¹æ³ã«
ããã¢ããªã³ãšã觊åªã®äžåšäžã«ããããã¯æå©
ã«è§Šåªåã³å Žåã«ãã€ãŠã¯å°¿çŽ åã³ã¢ã«ã³ãŒã«ã®
ååšäžã«åå¿ãããã
âã¢ã«ãã«ã«ã«ãããé žãšã¹ãã«ãæ¬çºææ¹æ³ã«
ããã¢ããªã³ãšã觊åªã®äžåšäžã«ããããã¯æå©
ã«è§Šåªåã³å Žåã«ãã€ãŠã¯å°¿çŽ åã³ã¢ã«ã³ãŒã«ã®
ååšäžã«åå¿ãããã
é©åœãªïŒ¯âã¢ã«ãã«ã«ã«ãããé
žãšã¹ãã«ã¯ã
åŒïŒH2NâCOORãæãããã®å Žåã¯å Žåã«
ãã€ãŠã¯çœ®æãããèèªæãèç°åŒåã¯è³éŠæè
èªæã®åºãè¡šãããäŸãã°ãïŒã20åã®ççŽ å
åãæå©ã«ïŒã10åã®ççŽ ååãæããïŒçŽã®å Ž
åã«ãã€ãŠã¯çœ®æãããèèªæã¢ãã¢ã«ã³ãŒã«ã
äž»äœãšããâã¢ã«ãã«âã«ã«ãããé žãšã¹ãã«
ã«ã¯ãäŸãã°ã«ã«ãããé žâã¡ãã«ãšã¹ãã«ãâ
ãšãã«ãšã¹ãã«ãâãããã«ãšã¹ãã«ãâïœâã
ãã«ãšã¹ãã«ãâã€ãœããã«ãšã¹ãã«ãâïŒâã
ã€âïŒâã¡ãã«ããã«ãšã¹ãã«ãâããªãã³ãã«
ãšã¹ãã«ãâãã³ãã«ãšã¹ãã«ãâïŒâã¡ãã«â
ãã³ãã«ãšã¹ãã«ãâïœâããã·ã«ãšã¹ãã«ãâ
ïŒâãšããã·ããã·ã«ãšã¹ãã«ãâãããã«ãšã¹
ãã«ãâïœâãªã¯ãã«ãšã¹ãã«ãâïœâããã«ãš
ã¹ãã«ãâïœâãã·ã«ãšã¹ãã«åã³âïœâããã·
ã«ãšã¹ãã«ãâïŒâããšãã«ãããã«ãšã¹ãã«å
ã³âãã³ãžã«ãšã¹ãã«ãããã«è©²åœããïŒã15å
ã®ççŽ ååãæå©ã«ïŒãïŒåã®ççŽ ååãæãã
ïŒçŽã®èèªæåã³èç°åŒã®ã¢ãã¢ã«ã³ãŒã«ãäž»äœ
ãšããâã¢ã«ãã«âã«ã«ãããé žãšã¹ãã«ã«
ã¯ãäŸãã°ã«ã«ãããé žâã€ãœãããã«ãšã¹ã
ã«ãâïœâããã«ãšã¹ãã«ãâïœâã€ãœã¢ãã«ãš
ã¹ãã«ãâã·ã¯ããã³ãã«ãšã¹ãã«ãâã·ã¯ãã
ãã·ã«ãšã¹ãã«ãâãã·ã¯ãïŒïŒïŒïŒïŒïŒïŒâã
ããã«ãšã¹ãã«åã³ïœâããã«âã·ã¯ãããã·ã«
ãšã¹ãã«ãããã«è©²åœããã奜ãŸããã¯ãã«ã«ã
ããé žâã¡ãã«ãšã¹ãã«ãâãšãã«ãšã¹ãã«ãâ
ãããã«ãšã¹ãã«ãâããã«ãšã¹ãã«ãâã€ãœã
ãã«ãšã¹ãã«ãâïŒâãã€âïŒâã¡ãã«ããã«ãš
ã¹ãã«ãâãã³ãã«ãšã¹ãã«ãâããã·ã«ãšã¹ã
ã«ãâïŒâãšãã«ããã·ã«ãšã¹ãã«ãâãããã«
ãšã¹ãã«ãâãªã¯ãã«ãšã¹ãã«åã³âã·ã¯ããã
ã·ã«ãšã¹ãã«ã䜿çšãããã
åŒïŒH2NâCOORãæãããã®å Žåã¯å Žåã«
ãã€ãŠã¯çœ®æãããèèªæãèç°åŒåã¯è³éŠæè
èªæã®åºãè¡šãããäŸãã°ãïŒã20åã®ççŽ å
åãæå©ã«ïŒã10åã®ççŽ ååãæããïŒçŽã®å Ž
åã«ãã€ãŠã¯çœ®æãããèèªæã¢ãã¢ã«ã³ãŒã«ã
äž»äœãšããâã¢ã«ãã«âã«ã«ãããé žãšã¹ãã«
ã«ã¯ãäŸãã°ã«ã«ãããé žâã¡ãã«ãšã¹ãã«ãâ
ãšãã«ãšã¹ãã«ãâãããã«ãšã¹ãã«ãâïœâã
ãã«ãšã¹ãã«ãâã€ãœããã«ãšã¹ãã«ãâïŒâã
ã€âïŒâã¡ãã«ããã«ãšã¹ãã«ãâããªãã³ãã«
ãšã¹ãã«ãâãã³ãã«ãšã¹ãã«ãâïŒâã¡ãã«â
ãã³ãã«ãšã¹ãã«ãâïœâããã·ã«ãšã¹ãã«ãâ
ïŒâãšããã·ããã·ã«ãšã¹ãã«ãâãããã«ãšã¹
ãã«ãâïœâãªã¯ãã«ãšã¹ãã«ãâïœâããã«ãš
ã¹ãã«ãâïœâãã·ã«ãšã¹ãã«åã³âïœâããã·
ã«ãšã¹ãã«ãâïŒâããšãã«ãããã«ãšã¹ãã«å
ã³âãã³ãžã«ãšã¹ãã«ãããã«è©²åœããïŒã15å
ã®ççŽ ååãæå©ã«ïŒãïŒåã®ççŽ ååãæãã
ïŒçŽã®èèªæåã³èç°åŒã®ã¢ãã¢ã«ã³ãŒã«ãäž»äœ
ãšããâã¢ã«ãã«âã«ã«ãããé žãšã¹ãã«ã«
ã¯ãäŸãã°ã«ã«ãããé žâã€ãœãããã«ãšã¹ã
ã«ãâïœâããã«ãšã¹ãã«ãâïœâã€ãœã¢ãã«ãš
ã¹ãã«ãâã·ã¯ããã³ãã«ãšã¹ãã«ãâã·ã¯ãã
ãã·ã«ãšã¹ãã«ãâãã·ã¯ãïŒïŒïŒïŒïŒïŒïŒâã
ããã«ãšã¹ãã«åã³ïœâããã«âã·ã¯ãããã·ã«
ãšã¹ãã«ãããã«è©²åœããã奜ãŸããã¯ãã«ã«ã
ããé žâã¡ãã«ãšã¹ãã«ãâãšãã«ãšã¹ãã«ãâ
ãããã«ãšã¹ãã«ãâããã«ãšã¹ãã«ãâã€ãœã
ãã«ãšã¹ãã«ãâïŒâãã€âïŒâã¡ãã«ããã«ãš
ã¹ãã«ãâãã³ãã«ãšã¹ãã«ãâããã·ã«ãšã¹ã
ã«ãâïŒâãšãã«ããã·ã«ãšã¹ãã«ãâãããã«
ãšã¹ãã«ãâãªã¯ãã«ãšã¹ãã«åã³âã·ã¯ããã
ã·ã«ãšã¹ãã«ã䜿çšãããã
ã¢ã«ã³ãŒã«ãšããŠã¯ãä»»æã®ãå Žåã«ãã€ãŠã¯
眮æãããïŒçŽåã¯ïŒçŽã®èèªæã¢ã«ã³ãŒã«åã³
ãã®æ··åç©ã䜿çšããããšãã§ãããâã¢ã«ã
ã«ã«ã«ãããé žãšã¹ãã«ã«çžå¿ããã¢ã«ã³ãŒã«ã
䜿çšããã®ãæå©ã§ããã
眮æãããïŒçŽåã¯ïŒçŽã®èèªæã¢ã«ã³ãŒã«åã³
ãã®æ··åç©ã䜿çšããããšãã§ãããâã¢ã«ã
ã«ã«ã«ãããé žãšã¹ãã«ã«çžå¿ããã¢ã«ã³ãŒã«ã
䜿çšããã®ãæå©ã§ããã
äŸãã°ãïŒã20åã®ççŽ ååãæå©ã«ïŒã10å
ã®ççŽ ååãæããïŒçŽèèªæã¢ã«ã³ãŒã«ã«ã¯ã
äŸãã°ã¡ã¿ããŒã«ããšã¿ããŒã«ããããããŒã«ã
ïœâãã¿ããŒã«ãïœâãã³ã¿ããŒã«ãããªãã³ã
ã«ã¢ã«ã³ãŒã«ãïŒâã¡ãã«âãã¿ããŒã«ãïŒâã¡
ãã«âãã³ã¿ããŒã«ãïœâãããµããŒã«ãïœâã
ãã¿ããŒã«ãïœâãªã¯ã¿ããŒã«ãããããŒã«ãïœ
âãã«ããŒã«åã³ïœâããã«ããŒã«ãããã«è©²åœ
ããïŒã15åã®ççŽ ååãæå©ã«ïŒãïŒåã®ççŽ
ååãæããïŒçŽã®èèªæã¢ã«ã³ãŒã«åã³èç°åŒ
ã¢ã«ã³ãŒã«ã«ã¯ãäŸãã°ã€ãœãããããŒã«ãïœâ
ãã¿ããŒã«ãïœâã€ãœã¢ãã«ã¢ã«ã³ãŒã«ãã·ã¯ã
ãã³ã¿ããŒã«ãïŒâãïŒâåã¯ïŒâã¡ãã«âã·ã¯
ããããµããŒã«ãã·ã¯ããããµããŒã«åã³ãã·ã¯
ãïŒïŒïŒïŒïŒïŒïŒâããã¿ããŒã«ãããã«è©²åœã
ããã¢ãã¢ã«ã³ãŒã«ãšããŠã¯ãã¡ã¿ããŒã«ããšã¿
ããŒã«ããããããŒã«ãã€ãœãããããŒã«ãïœâ
ãã¿ããŒã«ãïŒâãšãã«âãã¿ããŒã«ãïŒâãã€
ïŒâã¡ãã«ãã¿ããŒã«ãïœâãã³ã¿ããŒã«ãïœâ
ãããµããŒã«ãïŒâãšãã«âãããµããŒã«ããã
ã¿ããŒã«ããªã¯ã¿ããŒã«åã³ã·ã¯ããããµããŒã«
ã䜿çšããã®ãæå©ã§ããã
ã®ççŽ ååãæããïŒçŽèèªæã¢ã«ã³ãŒã«ã«ã¯ã
äŸãã°ã¡ã¿ããŒã«ããšã¿ããŒã«ããããããŒã«ã
ïœâãã¿ããŒã«ãïœâãã³ã¿ããŒã«ãããªãã³ã
ã«ã¢ã«ã³ãŒã«ãïŒâã¡ãã«âãã¿ããŒã«ãïŒâã¡
ãã«âãã³ã¿ããŒã«ãïœâãããµããŒã«ãïœâã
ãã¿ããŒã«ãïœâãªã¯ã¿ããŒã«ãããããŒã«ãïœ
âãã«ããŒã«åã³ïœâããã«ããŒã«ãããã«è©²åœ
ããïŒã15åã®ççŽ ååãæå©ã«ïŒãïŒåã®ççŽ
ååãæããïŒçŽã®èèªæã¢ã«ã³ãŒã«åã³èç°åŒ
ã¢ã«ã³ãŒã«ã«ã¯ãäŸãã°ã€ãœãããããŒã«ãïœâ
ãã¿ããŒã«ãïœâã€ãœã¢ãã«ã¢ã«ã³ãŒã«ãã·ã¯ã
ãã³ã¿ããŒã«ãïŒâãïŒâåã¯ïŒâã¡ãã«âã·ã¯
ããããµããŒã«ãã·ã¯ããããµããŒã«åã³ãã·ã¯
ãïŒïŒïŒïŒïŒïŒïŒâããã¿ããŒã«ãããã«è©²åœã
ããã¢ãã¢ã«ã³ãŒã«ãšããŠã¯ãã¡ã¿ããŒã«ããšã¿
ããŒã«ããããããŒã«ãã€ãœãããããŒã«ãïœâ
ãã¿ããŒã«ãïŒâãšãã«âãã¿ããŒã«ãïŒâãã€
ïŒâã¡ãã«ãã¿ããŒã«ãïœâãã³ã¿ããŒã«ãïœâ
ãããµããŒã«ãïŒâãšãã«âãããµããŒã«ããã
ã¿ããŒã«ããªã¯ã¿ããŒã«åã³ã·ã¯ããããµããŒã«
ã䜿çšããã®ãæå©ã§ããã
ã¢ã«ã³ãŒã«ã¯ãå Žåã«ããä»ã®åå¿æ¡ä»¶äžã§äž
掻æ§ã®ææ©æº¶å€ãšæ··åããããšãã§ããã
掻æ§ã®ææ©æº¶å€ãšæ··åããããšãã§ããã
觊åªã®äžåšäžã§ïŒ®âããšãã«âãŠã¬ã¿ã³ã補é
ããããã«ã¯ãã¢ããªã³ãâã¢ã«ãã«ã«ã«ãã
ãé žãšã¹ãã«åã³å Žåã«ãã€ãŠã¯ã¢ã«ã³ãŒã«ãã¢
ã«æ¯ïŒïŒ0.5ã20ïŒïŒã100ãæå©ã«ïŒïŒ0.8ã
10ïŒïŒã50ãæ®ã«ïŒïŒïŒãïŒïŒïŒãïŒã§åå¿ãã
ããããããåå¿ã觊åªã®ååšäžã§è¡ãªãå Žåã
ã¢ããªã³ãšïŒ¯âã¢ã«ãã«ã«ã«ãããé žãšã¹ãã«ãš
å Žåã«ãã€ãŠã¯ã¢ã«ã³ãŒã«ãšã®ã¢ã«æ¯ã¯ãïŒïŒ
0.5ã20ïŒïŒã100ãæå©ã«ïŒïŒ0.8ã10ïŒïŒã30ã
æ®ã«ïŒïŒïŒãïŒïŒïŒãïŒã§ããã®ãç¹ã«è¯å¥œã§ã
ãããšãç«èšŒãããã
ããããã«ã¯ãã¢ããªã³ãâã¢ã«ãã«ã«ã«ãã
ãé žãšã¹ãã«åã³å Žåã«ãã€ãŠã¯ã¢ã«ã³ãŒã«ãã¢
ã«æ¯ïŒïŒ0.5ã20ïŒïŒã100ãæå©ã«ïŒïŒ0.8ã
10ïŒïŒã50ãæ®ã«ïŒïŒïŒãïŒïŒïŒãïŒã§åå¿ãã
ããããããåå¿ã觊åªã®ååšäžã§è¡ãªãå Žåã
ã¢ããªã³ãšïŒ¯âã¢ã«ãã«ã«ã«ãããé žãšã¹ãã«ãš
å Žåã«ãã€ãŠã¯ã¢ã«ã³ãŒã«ãšã®ã¢ã«æ¯ã¯ãïŒïŒ
0.5ã20ïŒïŒã100ãæå©ã«ïŒïŒ0.8ã10ïŒïŒã30ã
æ®ã«ïŒïŒïŒãïŒïŒïŒãïŒã§ããã®ãç¹ã«è¯å¥œã§ã
ãããšãç«èšŒãããã
ãã§ã«èª¬æããããã«ãâããšãã«ãŠã¬ã¿ã³
ã補é ããããã«ã¯ãæå©ã«ïŒ¯âã¢ã«ãã«ã«ã«ã
ããé žãšã¹ãã«ã®ä»ã«ä»å çã«å°¿çŽ åã³ã¢ã«ã³ãŒ
ã«ãå ±çšãããã®å Žåã¢ããªã³ãšïŒ¯âã¢ã«ãã«ã«
ã«ãããé žãšã¹ãã«åã³å°¿çŽ ããã®åèšãšã®æ¯ç
ã¯ãåæ§ã«ïŒïŒ0.5ã20ãæå©ã«ïŒïŒ0.8ã10ãæ®
ã«ïŒïŒïŒãïŒã§ãããå°¿çŽ å¯Ÿã¢ããªã³ã®ã¢ã«æ¯
ã¯ãåäžãåã¯1.5æªæºãæå©ã«1.25ã0.75ã§ã
ãããã€å°¿çŽ 察ã¢ã«ã³ãŒã«ã®ã¢ã«æ¯ã¯ãåäžãå
ã¯ïŒæªæºã§ããã
ã補é ããããã«ã¯ãæå©ã«ïŒ¯âã¢ã«ãã«ã«ã«ã
ããé žãšã¹ãã«ã®ä»ã«ä»å çã«å°¿çŽ åã³ã¢ã«ã³ãŒ
ã«ãå ±çšãããã®å Žåã¢ããªã³ãšïŒ¯âã¢ã«ãã«ã«
ã«ãããé žãšã¹ãã«åã³å°¿çŽ ããã®åèšãšã®æ¯ç
ã¯ãåæ§ã«ïŒïŒ0.5ã20ãæå©ã«ïŒïŒ0.8ã10ãæ®
ã«ïŒïŒïŒãïŒã§ãããå°¿çŽ å¯Ÿã¢ããªã³ã®ã¢ã«æ¯
ã¯ãåäžãåã¯1.5æªæºãæå©ã«1.25ã0.75ã§ã
ãããã€å°¿çŽ 察ã¢ã«ã³ãŒã«ã®ã¢ã«æ¯ã¯ãåäžãå
ã¯ïŒæªæºã§ããã
å°¿çŽ ã¯ãæå©ã«åžè²©ã®åœ¢åã³çŽåºŠã§äœ¿çšãã
ãã
ãã
åå¿é床ãäžæãããã€åçãæ¹åãããã
ã«ãåå¿ã¯æå©ã«ïŒã€ä»¥äžã®è§Šåªã®ååšäžã§å®æœ
ãããã觊åªãšããŠã¯ãâãã³ãããã¯ã»ãªãã»
ã±ãã¹ããªãŒã»ã¢ã³ãã»ãã€ãºã€ãã¯ã¹
ïŒHandbook of Chemistry and PhysicsïŒâã第
14çãChemical Rubber Publishing Co.
ïŒ2310Superior Aue.N.E.ClevelandãOhioïŒç€Ÿ
åãã«å®çŸ©ããããåšæåŸã®ç¬¬ïŒ¡æã第
æã第æã第æã第æã第æã
第æã第æã第æã第æã第
æã第æåã³ç¬¬ïŒ¢æã®çŸ€ã®éå±ã®ïŒã€ä»¥
äžã®ãæå©ã«ïŒã€ã®ã«ããªã³ãå«æããç¡æ©åå
ç©åã³ææ©ååç©ãäŸãã°ããã²ã³åç©ãäŸãã°
å¡©åç©åã³èåç©ãç¡«é žå¡©ãçé žå¡©ãç¡é žå¡©ãç¡Œ
é žå¡©ãã¢ã«ã³ã©ãŒããããšãã©ãŒããã¹ã«ãã³é ž
å¡©ãé žåç©ããªãã·ãæ°Žåç©ãæ°Žé žåç©ãã«ã«ã
ã³é žå¡©ããã¬ãŒããçé žå¡©åã³ããªâåã¯ãžããª
ã«ã«ããã³é žå¡©ã奜é©ã§ãããäŸãã°ã次ã®éå±
ã®ã«ããªã³ãæããããïŒãªããŠã ããããªãŠ
ã ãã«ãªãŠã ããã°ãã·ãŠã ãã«ã«ã·ãŠã ãã¢ã«
ãããŠã ãã¬ãªãŠã ãé«ãéãèŒéãã¢ã³ãã¢
ã³ãé ãéãéãäºéãæ°Žéãã»ãªãŠã ããã¿
ã³ããããžãŠã ãã¯ãã ãã¢ãªããã³ããã³ã¬
ã³ãéãã³ãã«ãåã³ããã±ã«ã奜ãŸããã¯ããª
ããŠã ãã«ã«ã·ãŠã ãã¢ã«ãããŠã ãé«ãèŒéã
ã¢ã³ãã¢ã³ãé ãäºéããã¿ã³ããããžãŠã ãã¯
ãã ãã¢ãªããã³ããã³ã¬ã³ãéåã³ã³ãã«ãã®
ã«ããªã³ã䜿çšãããã觊åªã¯ãèªãåŸãæãã
ãªæ¬ ç¹ãªãã«æ°Žåç©åã¯ã¢ã³ã¢ãã¢åç©ã®åœ¢ã§äœ¿
çšããããšãã§ããã
ã«ãåå¿ã¯æå©ã«ïŒã€ä»¥äžã®è§Šåªã®ååšäžã§å®æœ
ãããã觊åªãšããŠã¯ãâãã³ãããã¯ã»ãªãã»
ã±ãã¹ããªãŒã»ã¢ã³ãã»ãã€ãºã€ãã¯ã¹
ïŒHandbook of Chemistry and PhysicsïŒâã第
14çãChemical Rubber Publishing Co.
ïŒ2310Superior Aue.N.E.ClevelandãOhioïŒç€Ÿ
åãã«å®çŸ©ããããåšæåŸã®ç¬¬ïŒ¡æã第
æã第æã第æã第æã第æã
第æã第æã第æã第æã第
æã第æåã³ç¬¬ïŒ¢æã®çŸ€ã®éå±ã®ïŒã€ä»¥
äžã®ãæå©ã«ïŒã€ã®ã«ããªã³ãå«æããç¡æ©åå
ç©åã³ææ©ååç©ãäŸãã°ããã²ã³åç©ãäŸãã°
å¡©åç©åã³èåç©ãç¡«é žå¡©ãçé žå¡©ãç¡é žå¡©ãç¡Œ
é žå¡©ãã¢ã«ã³ã©ãŒããããšãã©ãŒããã¹ã«ãã³é ž
å¡©ãé žåç©ããªãã·ãæ°Žåç©ãæ°Žé žåç©ãã«ã«ã
ã³é žå¡©ããã¬ãŒããçé žå¡©åã³ããªâåã¯ãžããª
ã«ã«ããã³é žå¡©ã奜é©ã§ãããäŸãã°ã次ã®éå±
ã®ã«ããªã³ãæããããïŒãªããŠã ããããªãŠ
ã ãã«ãªãŠã ããã°ãã·ãŠã ãã«ã«ã·ãŠã ãã¢ã«
ãããŠã ãã¬ãªãŠã ãé«ãéãèŒéãã¢ã³ãã¢
ã³ãé ãéãéãäºéãæ°Žéãã»ãªãŠã ããã¿
ã³ããããžãŠã ãã¯ãã ãã¢ãªããã³ããã³ã¬
ã³ãéãã³ãã«ãåã³ããã±ã«ã奜ãŸããã¯ããª
ããŠã ãã«ã«ã·ãŠã ãã¢ã«ãããŠã ãé«ãèŒéã
ã¢ã³ãã¢ã³ãé ãäºéããã¿ã³ããããžãŠã ãã¯
ãã ãã¢ãªããã³ããã³ã¬ã³ãéåã³ã³ãã«ãã®
ã«ããªã³ã䜿çšãããã觊åªã¯ãèªãåŸãæãã
ãªæ¬ ç¹ãªãã«æ°Žåç©åã¯ã¢ã³ã¢ãã¢åç©ã®åœ¢ã§äœ¿
çšããããšãã§ããã
å
žåçãªè§ŠåªãšããŠã¯ãäŸãã°æ¬¡ã®ååç©ãæ
ããããïŒãªããŠã ã¡ããã·ãããªããŠã ãšãã
ã·ãããªããŠã ããããã·ãããªããŠã ãããã·
ãããããªãŠã ã¡ããã·ããïœâã«ãªãŠã ããã
ã·ãããã°ãã·ãŠã ã¡ããã·ããã«ã«ã·ãŠã ã¡ã
ãã·ããå¡©åé«ïŒïŒãå¡©åé«ïŒïŒãé ¢é žéãç
é žå¡©ãå¡©åã¢ã³ãã¢ã³ïŒïŒãå¡©åã¢ã³ãã¢ã³
ïŒïŒãã¢ã«ãããŠã ã€ãœãããã·ããäžå¡©åã¢ã«
ãããŠã ãå¡©åèŒéïŒïŒãé ¢é žé ïŒïŒãç¡«é žé
ïŒïŒãç¡é žé ïŒïŒããã¹âïŒããªããšãã«ãã¹
ãã€ã³ãªãã·ãïŒãé ïŒïŒâã¯ããªããã¢ãªã
ãã³é žé ãé ¢é žéãé ¢é žéãé žåäºéãå¡©åäº
éãé ¢é žäºéãã¢ã»ããããªã«é ¢é žäºéããªã¯ã
ã³é žäºéãèé žäºéãããã·ã«é žäºéãå®æ¯éŠé ž
äºéããŠã³ãã·ã¬ã³é žäºéãé žåã»ãªãŠã ïŒïŒã
é ¢é žãŠã©ãã«ããã¿ã³ããã©ãããã·ããåå¡©å
ãã¿ã³ããã¿ã³ããã©ããšããã·ãããããã³é ž
ãã¿ã³ãå¡©åãããžãŠã ïŒïŒãã¢ã»ããã«é ¢é ž
ãããžãŠã ãå¡©åã¯ãã ïŒïŒãé žåã¢ãªããã³
ïŒïŒãã¢ã»ãã«ã¢ã»ãã³é žã¢ãªããã³ãé žåã¿ã³
ã°ã¹ãã³ïŒïŒãå¡©åãã³ã¬ã³ïŒïŒãé ¢é žãã³ã¬
ã³ïŒïŒãé ¢é žãã³ã¬ã³ïŒïŒãé ¢é žéïŒïŒãé ¢
é žéïŒïŒãçé žéãèé žéãå¡©åéïŒïŒãèå
éïŒïŒãé ¢é žã³ãã«ããå¡©åã³ãã«ããç¡«é žã³
ãã«ãããããã³é žã³ãã«ããå¡©åããã±ã«ãé ¢
é žããã±ã«åã³ãããã³é žããã±ã«ãªãã³ã«ãã
ãã®æ··åç©ã
ããããïŒãªããŠã ã¡ããã·ãããªããŠã ãšãã
ã·ãããªããŠã ããããã·ãããªããŠã ãããã·
ãããããªãŠã ã¡ããã·ããïœâã«ãªãŠã ããã
ã·ãããã°ãã·ãŠã ã¡ããã·ããã«ã«ã·ãŠã ã¡ã
ãã·ããå¡©åé«ïŒïŒãå¡©åé«ïŒïŒãé ¢é žéãç
é žå¡©ãå¡©åã¢ã³ãã¢ã³ïŒïŒãå¡©åã¢ã³ãã¢ã³
ïŒïŒãã¢ã«ãããŠã ã€ãœãããã·ããäžå¡©åã¢ã«
ãããŠã ãå¡©åèŒéïŒïŒãé ¢é žé ïŒïŒãç¡«é žé
ïŒïŒãç¡é žé ïŒïŒããã¹âïŒããªããšãã«ãã¹
ãã€ã³ãªãã·ãïŒãé ïŒïŒâã¯ããªããã¢ãªã
ãã³é žé ãé ¢é žéãé ¢é žéãé žåäºéãå¡©åäº
éãé ¢é žäºéãã¢ã»ããããªã«é ¢é žäºéããªã¯ã
ã³é žäºéãèé žäºéãããã·ã«é žäºéãå®æ¯éŠé ž
äºéããŠã³ãã·ã¬ã³é žäºéãé žåã»ãªãŠã ïŒïŒã
é ¢é žãŠã©ãã«ããã¿ã³ããã©ãããã·ããåå¡©å
ãã¿ã³ããã¿ã³ããã©ããšããã·ãããããã³é ž
ãã¿ã³ãå¡©åãããžãŠã ïŒïŒãã¢ã»ããã«é ¢é ž
ãããžãŠã ãå¡©åã¯ãã ïŒïŒãé žåã¢ãªããã³
ïŒïŒãã¢ã»ãã«ã¢ã»ãã³é žã¢ãªããã³ãé žåã¿ã³
ã°ã¹ãã³ïŒïŒãå¡©åãã³ã¬ã³ïŒïŒãé ¢é žãã³ã¬
ã³ïŒïŒãé ¢é žãã³ã¬ã³ïŒïŒãé ¢é žéïŒïŒãé ¢
é žéïŒïŒãçé žéãèé žéãå¡©åéïŒïŒãèå
éïŒïŒãé ¢é žã³ãã«ããå¡©åã³ãã«ããç¡«é žã³
ãã«ãããããã³é žã³ãã«ããå¡©åããã±ã«ãé ¢
é žããã±ã«åã³ãããã³é žããã±ã«ãªãã³ã«ãã
ãã®æ··åç©ã
觊åªã¯ãæå©ã«ã¢ããªã³ã«å¯ŸããŠ0.0001ã0.1
åœéãæå©ã«0.0005ã0.05åœéã®éå±ã«ããªã³ã«
çžåœããéã§äœ¿çšããããéå±ã€ãªã³ã¯ãäžåäž
çžäžã®ã€ãªã³äº€æäœã䌎ãªã€ãŠäœ¿çšããŠãããã
åœéãæå©ã«0.0005ã0.05åœéã®éå±ã«ããªã³ã«
çžåœããéã§äœ¿çšããããéå±ã€ãªã³ã¯ãäžåäž
çžäžã®ã€ãªã³äº€æäœã䌎ãªã€ãŠäœ¿çšããŠãããã
åå¿ã¯ãé«ãããã枩床ã§ãäŸãã°è§Šåªã®ååš
äžã«160âã300âãæå©ã«170âã230âãæ®ã«
175âã210âã®æž©åºŠã§åã³è§Šåªã®ååšäžã«100â
ã250âãæå©ã«120âã210âãæ®ã«135âã190
âã®æž©åºŠã§ãªãã³ã«0.1ã120ããŒã«ãæå©ã«0.5
ã60ããŒã«ãæ®ã«ïŒã40ããŒã«ã®å§åã§å®æœã
ãããã®å Žåçæããã¢ã³ã¢ãã¢ãåå¿æ··åç©ã
ããäŸãã°èžçããããšã«ãã€ãŠåé¢ããã®ãæ
å©ã§ããããšãå€æãããæŽã«ãåå¿ã¯ãåèšæž©
床ã§ãçæããã¢ã³ã¢ãã¢ãéžæçã«åå¿æ··åç©
ããçå»ããããšãã§ããå å§äžã§æå©ã«å®æœã
ãããé©åœãªå€ã¯ãã¢ã³ã¢ãã¢åã³ã¢ã«ã³ãŒã«ã®
ç©ççç¹æ§å€ãæããè¡šããç¥ãããšãã§ããã
åèšã®æž©åºŠç¯å²ã«é¢ããŠã¯ã0.5ã100æéãæå©
ã«ïŒã50æéãæ®ã«ïŒã25æéã®ååå¿æéãåŸ
ãããã
äžã«160âã300âãæå©ã«170âã230âãæ®ã«
175âã210âã®æž©åºŠã§åã³è§Šåªã®ååšäžã«100â
ã250âãæå©ã«120âã210âãæ®ã«135âã190
âã®æž©åºŠã§ãªãã³ã«0.1ã120ããŒã«ãæå©ã«0.5
ã60ããŒã«ãæ®ã«ïŒã40ããŒã«ã®å§åã§å®æœã
ãããã®å Žåçæããã¢ã³ã¢ãã¢ãåå¿æ··åç©ã
ããäŸãã°èžçããããšã«ãã€ãŠåé¢ããã®ãæ
å©ã§ããããšãå€æãããæŽã«ãåå¿ã¯ãåèšæž©
床ã§ãçæããã¢ã³ã¢ãã¢ãéžæçã«åå¿æ··åç©
ããçå»ããããšãã§ããå å§äžã§æå©ã«å®æœã
ãããé©åœãªå€ã¯ãã¢ã³ã¢ãã¢åã³ã¢ã«ã³ãŒã«ã®
ç©ççç¹æ§å€ãæããè¡šããç¥ãããšãã§ããã
åèšã®æž©åºŠç¯å²ã«é¢ããŠã¯ã0.5ã100æéãæå©
ã«ïŒã50æéãæ®ã«ïŒã25æéã®ååå¿æéãåŸ
ãããã
âããšãã«ãŠã¬ã¿ã³ã¯ãæ¬çºææ¹æ³ã«ããæ
å©ã«æ¬¡ã®ããã«è£œé ãããïŒã¢ããªã³ãâã¢ã«
ãã«ã«ã«ãããé žãšã¹ãã«åã³å Žåã«ãã€ãŠã¯ã¢
ã«ã³ãŒã«åã¯æå©ã«ã¢ããªã³ãâã¢ã«ãã«ã«ã«
ãããé žãšã¹ãã«ãå°¿çŽ åã³ã¢ã«ã³ãŒã«ããåèš
ã®ã¢ã«æ¯ã§æ··åããæå©ã«è§Šåªã®ååšäžã«ã¢ã³ã¢
ãã¢ãåé¢ããããã®è£ 眮ãè£ åããåå¿å®¹åšäž
ã§å ç±ãããçæããã¢ã³ã¢ãã¢ã¯ãåå¿ãå®çµ
ããåŸã«åé¢ãããããæå©ã«ã¯åå¿ã®çµéäžã«
é£ç¶çã«ãåã¯ååçã«çå»ãããããã®å Žåã
æ®ã«äœååã¢ã«ã³ãŒã«ã®ååšäžã«å å§äžã§åå¿ã
ããéã«ã¯ãã¢ã³ã¢ãã¢ãåå¿æ¡ä»¶äžã§äžæŽ»æ§ã®
é£è¡å€ãäŸãã°çªçŽ ã¬ã¹ã®ãããªã¬ã¹ã«ãããã
ãã¯ã¢ã«ã³ãŒã«ã®äžéšãšäžç·ã«åé¢ããã®ãæå©
ã§ãããåŸãããåå¿æ··åç©ãããåŒç¶ããå Žå
ã«ãã€ãŠã¯è§Šåªãåé¢ããã€åºäœãæ¿Ÿå¥ããåŸ
ã«ãäŸãã°åå¥èžçã«ãã€ãŠãéå°ã®ïŒ¯âã¢ã«ã
ã«ã«ã«ãããé žãšã¹ãã«åã³ïŒåã¯ã¢ã«ã³ãŒã«ã
çå»ããããšã«ãã€ãŠãéå°ã®ïŒ¯âã¢ã«ãã«ã«ã«
ãããé žãšã¹ãã«åã³ïŒåã¯ã¢ã«ã³ãŒã«ãéšåç
ã«çå»ããã€ïŒ®âããšãã«ãŠã¬ã¿ã³ãæ¶åºããã
ããšã«ãã€ãŠãä»ã®æº¶å€ã§æ²æ®¿ãããããšã«ãã€
ãŠãåã¯ä»ã®æº¶å€ããåçµæ¶ãããããšã«ãã€ãŠ
âããšãã«ãŠã¬ã¿ã³ãåé¢ããã觊åªã¯ãå Žå
ã«ãã€ãŠã¯ãäŸãã°æ²æ®¿ãæ¿Ÿå¥ãæŽæµé€å»åã¯ã€
ãªã³äº€æäœãšã®çµåã«ãã€ãŠåé¢ããããšãã§ã
ãã
å©ã«æ¬¡ã®ããã«è£œé ãããïŒã¢ããªã³ãâã¢ã«
ãã«ã«ã«ãããé žãšã¹ãã«åã³å Žåã«ãã€ãŠã¯ã¢
ã«ã³ãŒã«åã¯æå©ã«ã¢ããªã³ãâã¢ã«ãã«ã«ã«
ãããé žãšã¹ãã«ãå°¿çŽ åã³ã¢ã«ã³ãŒã«ããåèš
ã®ã¢ã«æ¯ã§æ··åããæå©ã«è§Šåªã®ååšäžã«ã¢ã³ã¢
ãã¢ãåé¢ããããã®è£ 眮ãè£ åããåå¿å®¹åšäž
ã§å ç±ãããçæããã¢ã³ã¢ãã¢ã¯ãåå¿ãå®çµ
ããåŸã«åé¢ãããããæå©ã«ã¯åå¿ã®çµéäžã«
é£ç¶çã«ãåã¯ååçã«çå»ãããããã®å Žåã
æ®ã«äœååã¢ã«ã³ãŒã«ã®ååšäžã«å å§äžã§åå¿ã
ããéã«ã¯ãã¢ã³ã¢ãã¢ãåå¿æ¡ä»¶äžã§äžæŽ»æ§ã®
é£è¡å€ãäŸãã°çªçŽ ã¬ã¹ã®ãããªã¬ã¹ã«ãããã
ãã¯ã¢ã«ã³ãŒã«ã®äžéšãšäžç·ã«åé¢ããã®ãæå©
ã§ãããåŸãããåå¿æ··åç©ãããåŒç¶ããå Žå
ã«ãã€ãŠã¯è§Šåªãåé¢ããã€åºäœãæ¿Ÿå¥ããåŸ
ã«ãäŸãã°åå¥èžçã«ãã€ãŠãéå°ã®ïŒ¯âã¢ã«ã
ã«ã«ã«ãããé žãšã¹ãã«åã³ïŒåã¯ã¢ã«ã³ãŒã«ã
çå»ããããšã«ãã€ãŠãéå°ã®ïŒ¯âã¢ã«ãã«ã«ã«
ãããé žãšã¹ãã«åã³ïŒåã¯ã¢ã«ã³ãŒã«ãéšåç
ã«çå»ããã€ïŒ®âããšãã«ãŠã¬ã¿ã³ãæ¶åºããã
ããšã«ãã€ãŠãä»ã®æº¶å€ã§æ²æ®¿ãããããšã«ãã€
ãŠãåã¯ä»ã®æº¶å€ããåçµæ¶ãããããšã«ãã€ãŠ
âããšãã«ãŠã¬ã¿ã³ãåé¢ããã觊åªã¯ãå Žå
ã«ãã€ãŠã¯ãäŸãã°æ²æ®¿ãæ¿Ÿå¥ãæŽæµé€å»åã¯ã€
ãªã³äº€æäœãšã®çµåã«ãã€ãŠåé¢ããããšãã§ã
ãã
æ¬çºæã«ãã€ãŠè£œé ãããâããšãã«ãŠã¬ã¿
ã³ã¯ããã«ã ã¢ã«ãããããã«ã ã¢ã«ãããå解
ååç©åã¯æå©ã«åŒïŒïŒžâCH2âïŒäœããã¯
ROâãRSâåã¯ROCOåºãè¡šããããããã®ïŒ²
ã¯ã¢ã«ãã«åºãè¡šããïŒã®ååç©ãšãé žåã¯ã«ã«
ãã³é žã®ååšäžã«çž®åããŠã¡ãã¬ã³âãã¹âããš
ãã«ãŠã¬ã¿ã³ãšããªã¡ãã¬ã³âããªããšãã«ãŠã¬
ã¿ã³ãšãããªãæ··åç©ïŒç²è£œMDUïŒã«å€ããã
ã³ã¯ããã«ã ã¢ã«ãããããã«ã ã¢ã«ãããå解
ååç©åã¯æå©ã«åŒïŒïŒžâCH2âïŒäœããã¯
ROâãRSâåã¯ROCOåºãè¡šããããããã®ïŒ²
ã¯ã¢ã«ãã«åºãè¡šããïŒã®ååç©ãšãé žåã¯ã«ã«
ãã³é žã®ååšäžã«çž®åããŠã¡ãã¬ã³âãã¹âããš
ãã«ãŠã¬ã¿ã³ãšããªã¡ãã¬ã³âããªããšãã«ãŠã¬
ã¿ã³ãšãããªãæ··åç©ïŒç²è£œMDUïŒã«å€ããã
ç²è£œMDUã®è£œé ã¯ãäŸãã°å
¬ç¥æè¡ã«ããã°
ïŒå·¥çšã§ããã€ãé£éŠå ±ååœç¹èš±ç¬¬1042891å·æ
现æžã®èšèŒã«ããâããšãã«ãŠã¬ã¿ã³åã³ãã«
ã ã¢ã«ããããçž®åããã€ãã€ãé£éŠå ±ååœç¹èš±
åºé¡å ¬é第2832379å·æ现æžã®èšèŒã«ããå®å šã«
転移ããããšã«ãã€ãŠè¡ãªãããšãã§ããã
ïŒå·¥çšã§ããã€ãé£éŠå ±ååœç¹èš±ç¬¬1042891å·æ
现æžã®èšèŒã«ããâããšãã«ãŠã¬ã¿ã³åã³ãã«
ã ã¢ã«ããããçž®åããã€ãã€ãé£éŠå ±ååœç¹èš±
åºé¡å ¬é第2832379å·æ现æžã®èšèŒã«ããå®å šã«
転移ããããšã«ãã€ãŠè¡ãªãããšãã§ããã
ããããªãããâããšãã«ãŠã¬ã¿ã³ã®çž®å
ã¯ãæ¬çºæã«ããã°ïŒå·¥çšã§ã溶å€ãšããŠã®å Žå
ã«ãã€ãŠã¯çœ®æãããã«ã«ãã³é žãäŸãã°ããã
ãªã³é žãã¯ãã«é ¢é žåã¯é ¢é žãæå©ã«ïŒæªæºã®
pkså€ãæããã«ã«ãã³é žãäŸãã°è»é žãèé žã
ãžã¯ãã«é ¢é žãããªã¯ãã«é ¢é žåã¯ããªãã«ãªã«
é ¢é žäžã®ãã«ã ã¢ã«ãããåã¯ãã«ã ã¢ã«ããã
è±é¢ååç©ãäŸãã°ããªãªããµã³åã¯ãã©ãã«ã
ã¢ã«ããããçšããŠïŒBASF
Aktiengesellschaft瀟åºé¡ã®ãã€ãé£éŠå ±ååœç¹
èš±åºé¡ç¬¬P2942137.2å·æ现æžã®èšèŒã«ããïŒãå
ã¯æ®ã«åŒïŒCH2ïŒSRïŒ2ãCH2ïŒORïŒ2åã¯CH2
ïŒOCORïŒ2ïŒäœããã¯ïŒãïŒåã®ççŽ ååãæå©
ã«ïŒãïŒåã®ççŽ ååãæããã¢ã«ãã«åºãè¡šã
ãïŒã§ç€ºãããäºå®èœååç©ã§åŒ·é žã®ååšäžã«å®
æœããã®ãæå©ã§ãããããªã¢ã»ã¿ãŒã«ãã¢ã»ã¿
ãŒã«åã¯ã¢ã·ã©ãŒã«ã¯ãåå¿æ¡ä»¶äžã§å®éã«éé¢
ãã«ã ã¢ã«ããããçæãããã€åå¿æ°Žã®çæã
äžå¯èœã«ãããã¢ã»ã¿ãŒã«åã³ã¢ã·ã©ãŒã«ã®äœ¿çš
ã¯ãç¹ã«å·¥æ¥çã«éèŠã§ãããæå©ã«ã¯ãã¢ã«ã
ã«åºãâããšãã«ãŠã¬ã¿ã³ãåºç€ã«ããã¢ã«ã³
ãŒã«ãšäžèŽããåèšããçš®é¡ã®ååç©ã䜿çšãã
ããäŸãã°ããã«ã ã¢ã«ããããžã¡ãã«ã¢ã»ã¿ãŒ
ã«ïŒïŒãžã¡ãã«ãã«ãã«ïŒããžãšãã«ãã«ãã«å
ã³ãžã¢ã»ããã·ã¡ã¿ã³ãæããããããžã¡ãã«ã
ã«ãã«ã®äœ¿çšã¯ããããæ°Žæ§ãã«ã ã¢ã«ãããå
ã³ã¡ã¿ããŒã«ããç°¡åãã€çµæžçã«åŸãããã®
ã§ãç¹ã«æå©ã§ããã
ã¯ãæ¬çºæã«ããã°ïŒå·¥çšã§ã溶å€ãšããŠã®å Žå
ã«ãã€ãŠã¯çœ®æãããã«ã«ãã³é žãäŸãã°ããã
ãªã³é žãã¯ãã«é ¢é žåã¯é ¢é žãæå©ã«ïŒæªæºã®
pkså€ãæããã«ã«ãã³é žãäŸãã°è»é žãèé žã
ãžã¯ãã«é ¢é žãããªã¯ãã«é ¢é žåã¯ããªãã«ãªã«
é ¢é žäžã®ãã«ã ã¢ã«ãããåã¯ãã«ã ã¢ã«ããã
è±é¢ååç©ãäŸãã°ããªãªããµã³åã¯ãã©ãã«ã
ã¢ã«ããããçšããŠïŒBASF
Aktiengesellschaft瀟åºé¡ã®ãã€ãé£éŠå ±ååœç¹
èš±åºé¡ç¬¬P2942137.2å·æ现æžã®èšèŒã«ããïŒãå
ã¯æ®ã«åŒïŒCH2ïŒSRïŒ2ãCH2ïŒORïŒ2åã¯CH2
ïŒOCORïŒ2ïŒäœããã¯ïŒãïŒåã®ççŽ ååãæå©
ã«ïŒãïŒåã®ççŽ ååãæããã¢ã«ãã«åºãè¡šã
ãïŒã§ç€ºãããäºå®èœååç©ã§åŒ·é žã®ååšäžã«å®
æœããã®ãæå©ã§ãããããªã¢ã»ã¿ãŒã«ãã¢ã»ã¿
ãŒã«åã¯ã¢ã·ã©ãŒã«ã¯ãåå¿æ¡ä»¶äžã§å®éã«éé¢
ãã«ã ã¢ã«ããããçæãããã€åå¿æ°Žã®çæã
äžå¯èœã«ãããã¢ã»ã¿ãŒã«åã³ã¢ã·ã©ãŒã«ã®äœ¿çš
ã¯ãç¹ã«å·¥æ¥çã«éèŠã§ãããæå©ã«ã¯ãã¢ã«ã
ã«åºãâããšãã«ãŠã¬ã¿ã³ãåºç€ã«ããã¢ã«ã³
ãŒã«ãšäžèŽããåèšããçš®é¡ã®ååç©ã䜿çšãã
ããäŸãã°ããã«ã ã¢ã«ããããžã¡ãã«ã¢ã»ã¿ãŒ
ã«ïŒïŒãžã¡ãã«ãã«ãã«ïŒããžãšãã«ãã«ãã«å
ã³ãžã¢ã»ããã·ã¡ã¿ã³ãæããããããžã¡ãã«ã
ã«ãã«ã®äœ¿çšã¯ããããæ°Žæ§ãã«ã ã¢ã«ãããå
ã³ã¡ã¿ããŒã«ããç°¡åãã€çµæžçã«åŸãããã®
ã§ãç¹ã«æå©ã§ããã
ã«ã«ãã³é
žäžã®ãã«ã ã¢ã«ããããšã®ãããã¯
é žã®ååšäžã§ã®äºå®èœååç©ãšã®ïŒ®âããšãã«ãŠ
ã¬ã¿ã³ã®çž®åã¯ã50âã160âãæå©ã«90âã140
âãæ®ã«90âã120âã®æž©åºŠã§å®æœãããã
é žã®ååšäžã§ã®äºå®èœååç©ãšã®ïŒ®âããšãã«ãŠ
ã¬ã¿ã³ã®çž®åã¯ã50âã160âãæå©ã«90âã140
âãæ®ã«90âã120âã®æž©åºŠã§å®æœãããã
ãã«ã ã¢ã«ããããšäºå®èœååç©ãšïŒ®âããšã
ã«ãŠã¬ã¿ã³ãšã®ã¢ã«æ¯ã¯ãäžè¬ã«ïŒïŒ0.5ãïŒïŒ
10ãæå©ã«ïŒïŒ1.5ãïŒïŒïŒã§ãããã¡ãã¬ã³â
ããªããšãã«ãŠã¬ã¿ã³ã®çæãååã«é»æ¢ããªã
ãäž»ãšããŠã¡ãã¬ã³âãã¹âããšãã«ãŠã¬ã¿ã³ã
補é ããå Žåãæå©ã«ã¯ïŒïŒïŒãïŒïŒïŒã®æ¯çã
䜿çšããããå Žåã«ãã€ãŠã¯çœ®æãããã«ã«ãã³
é žã溶å€ãšããŠäœ¿çšããå Žåã«ã¯ããã®ã«ã«ãã³
é žãâããšãã«ãŠã¬ã¿ã³ïŒã¢ã«åœã50ã500ïœã
æå©ã«100ã200ïœã®éã§äœ¿çšããã
ã«ãŠã¬ã¿ã³ãšã®ã¢ã«æ¯ã¯ãäžè¬ã«ïŒïŒ0.5ãïŒïŒ
10ãæå©ã«ïŒïŒ1.5ãïŒïŒïŒã§ãããã¡ãã¬ã³â
ããªããšãã«ãŠã¬ã¿ã³ã®çæãååã«é»æ¢ããªã
ãäž»ãšããŠã¡ãã¬ã³âãã¹âããšãã«ãŠã¬ã¿ã³ã
補é ããå Žåãæå©ã«ã¯ïŒïŒïŒãïŒïŒïŒã®æ¯çã
䜿çšããããå Žåã«ãã€ãŠã¯çœ®æãããã«ã«ãã³
é žã溶å€ãšããŠäœ¿çšããå Žåã«ã¯ããã®ã«ã«ãã³
é žãâããšãã«ãŠã¬ã¿ã³ïŒã¢ã«åœã50ã500ïœã
æå©ã«100ã200ïœã®éã§äœ¿çšããã
äŸãã°ãâããšãã«ãŠã¬ã¿ã³ã«å¯ŸããŠïŒã
100ã¢ã«ïŒ ãæå©ã«20ã60ã¢ã«ïŒ ã®éã§äœ¿çšãã
ãé žãšããŠã¯ãäŸãã°çé žãç¡«é žãå¡©åæ°ŽçŽ é žã
ã¢ã«ãã«ã¹ã«ãã³é žäŸãã°ã¡ã¿ã³ã¹ã«ãã³é žåã³
ããªãã«ãªã«ã¡ã¿ã³ã¹ã«ãã³é žåã¯ã¢ãªãŒã«ã¹ã«
ãã³é žäŸãã°ïœâãã«ãªãŒã«ã¹ã«ãã³é žã奜é©ã§
ãããåªããå®æœæ æ§ã«å¿ããŠãåå¿æ··åç©ãã
èžçåé¢ããããšãã§ããåŒ·é žãäŸãã°ã¡ã¿ã³ã¹
ã«ãã³é žåã³ããªãã«ãªã«ã¡ã¿ã³ã¹ã«ãã³é žã䜿
çšããããã®æ¹æ³ã§ã¯ãåå¿æ··åç©ãæ°Žåã¯å¡©åº
ã§åŸåŠçããããšã¯çç¥ãããé žã¯æ¹ããŠåå¿ã«
çŽæ¥ã«äŸçµŠããããšãã§ããã
100ã¢ã«ïŒ ãæå©ã«20ã60ã¢ã«ïŒ ã®éã§äœ¿çšãã
ãé žãšããŠã¯ãäŸãã°çé žãç¡«é žãå¡©åæ°ŽçŽ é žã
ã¢ã«ãã«ã¹ã«ãã³é žäŸãã°ã¡ã¿ã³ã¹ã«ãã³é žåã³
ããªãã«ãªã«ã¡ã¿ã³ã¹ã«ãã³é žåã¯ã¢ãªãŒã«ã¹ã«
ãã³é žäŸãã°ïœâãã«ãªãŒã«ã¹ã«ãã³é žã奜é©ã§
ãããåªããå®æœæ æ§ã«å¿ããŠãåå¿æ··åç©ãã
èžçåé¢ããããšãã§ããåŒ·é žãäŸãã°ã¡ã¿ã³ã¹
ã«ãã³é žåã³ããªãã«ãªã«ã¡ã¿ã³ã¹ã«ãã³é žã䜿
çšããããã®æ¹æ³ã§ã¯ãåå¿æ··åç©ãæ°Žåã¯å¡©åº
ã§åŸåŠçããããšã¯çç¥ãããé žã¯æ¹ããŠåå¿ã«
çŽæ¥ã«äŸçµŠããããšãã§ããã
ä»ã®åªããå®æœæ
æ§ã«ããã°ãé
žãšããŠã¯åŒ·é
ž
ã®ææ©ã«ããªã³äº€æäœãäŸãã°ã¹ã«ãã³é žäº€ææš¹
èã䜿çšããããäŸãã°ã次ã®ãã®ãæããã
ãïŒã¬ã¯ãŸã«ãïŒLewasorbïŒACâ10ïŒBayer
AG瀟補ïŒãã¬ã¯ãããïŒLewatitïŒSPCâ108
ïŒBayer AG瀟補ïŒãã¢ã³ããŒãªã¹ã
ïŒAmberlystïŒâ15ïŒRohm and HaasïŒCo.瀟補ïŒ
åã¯ããã€ãªã³é žïŒDupont de NemoursïŒãã
ã®ã€ãªã³äº€æäœã¯ãèªäœå ¬ç¥ã®æ¹æ³ã«ããåå¿æ··
åç©äžã«æžæ¿ãããããããã¯åºäœåºäžã«é 眮ã
ããã
ã®ææ©ã«ããªã³äº€æäœãäŸãã°ã¹ã«ãã³é žäº€ææš¹
èã䜿çšããããäŸãã°ã次ã®ãã®ãæããã
ãïŒã¬ã¯ãŸã«ãïŒLewasorbïŒACâ10ïŒBayer
AG瀟補ïŒãã¬ã¯ãããïŒLewatitïŒSPCâ108
ïŒBayer AG瀟補ïŒãã¢ã³ããŒãªã¹ã
ïŒAmberlystïŒâ15ïŒRohm and HaasïŒCo.瀟補ïŒ
åã¯ããã€ãªã³é žïŒDupont de NemoursïŒãã
ã®ã€ãªã³äº€æäœã¯ãèªäœå ¬ç¥ã®æ¹æ³ã«ããåå¿æ··
åç©äžã«æžæ¿ãããããããã¯åºäœåºäžã«é 眮ã
ããã
çž®åã¯ãæå©ã«æ°Žã®äžåšäžã§ãããªãã¡å®éã«
æ°Žãå«æããªãé žã®äœ¿çšäžã§å®æœããããéæ°Žæ§
溶å€ãäŸãã°ãã³ãŸãŒã«ãã¡ãã«ã·ã¯ããããµ
ã³ãé ¢é žãã¹ã«ãã©ã³ãã¡ã¿ããŒã«ãé ¢é žã¡ã
ã«ãããããã³ãŸãŒã«ãã¯ãã«ãã³ãŸãŒã«ããžã¯
ãã«ãã³ãŸãŒã«åã¯å¡©çŽ åèèªæçåæ°ŽçŽ ãååš
ãããªããŠãååšãããŠãäœæ¥ããããšãã§ã
ãã
æ°Žãå«æããªãé žã®äœ¿çšäžã§å®æœããããéæ°Žæ§
溶å€ãäŸãã°ãã³ãŸãŒã«ãã¡ãã«ã·ã¯ããããµ
ã³ãé ¢é žãã¹ã«ãã©ã³ãã¡ã¿ããŒã«ãé ¢é žã¡ã
ã«ãããããã³ãŸãŒã«ãã¯ãã«ãã³ãŸãŒã«ããžã¯
ãã«ãã³ãŸãŒã«åã¯å¡©çŽ åèèªæçåæ°ŽçŽ ãååš
ãããªããŠãååšãããŠãäœæ¥ããããšãã§ã
ãã
çŽ0.5ã20æéåŸã«å®çµããåå¿ã¯ãäžè¬ã«ïŒ®
âããšãã«ãŠã¬ã¿ã³ãšé žåã³ïŒåã¯ã«ã«ãã³é žãš
ãããªãæ··åç©ã«æ¹æäžã§åå¿æž©åºŠã§äŸãã°ãã©
ãã«ã ã¢ã«ããããšã«ã«ãã³é žåã¯äºå®èœååç©
ãšãããªãæ··åç©ãé€ã ã«æ·»å ããããåã¯ïŒ®â
ããšãã«ãŠã¬ã¿ã³ããã©ãã«ã ã¢ã«ããããšã«ã«
ãã³é žãšãããªãæ··åç©ãããã¯äºå®èœååç©ãš
é žãšãããªãæ··åç©ãæ¹æäžã«å ç±ããã€è©²æ··å
ç©ãé©åœãªæéåå¿æž©åºŠã«ä¿æããããã«å®æœã
ãããåå¿çæç©ã®åé¢ã¯ãåŸæ¥ã®æ¹æ³ã«ããã
äŸãã°æº¶å€ãèžçåé¢ããã€è§Šåªãæ°Žã§æœåºãã
ããããã¯å¡©åºã§äžåããããšã«ãã€ãŠè¡ãªãã
ããå Žåã«ãã€ãŠã¯ååšããéåå¿åæç©è³ªã¯ã
ç空èžçã«ããåé¢ããããšãã§ããã
âããšãã«ãŠã¬ã¿ã³ãšé žåã³ïŒåã¯ã«ã«ãã³é žãš
ãããªãæ··åç©ã«æ¹æäžã§åå¿æž©åºŠã§äŸãã°ãã©
ãã«ã ã¢ã«ããããšã«ã«ãã³é žåã¯äºå®èœååç©
ãšãããªãæ··åç©ãé€ã ã«æ·»å ããããåã¯ïŒ®â
ããšãã«ãŠã¬ã¿ã³ããã©ãã«ã ã¢ã«ããããšã«ã«
ãã³é žãšãããªãæ··åç©ãããã¯äºå®èœååç©ãš
é žãšãããªãæ··åç©ãæ¹æäžã«å ç±ããã€è©²æ··å
ç©ãé©åœãªæéåå¿æž©åºŠã«ä¿æããããã«å®æœã
ãããåå¿çæç©ã®åé¢ã¯ãåŸæ¥ã®æ¹æ³ã«ããã
äŸãã°æº¶å€ãèžçåé¢ããã€è§Šåªãæ°Žã§æœåºãã
ããããã¯å¡©åºã§äžåããããšã«ãã€ãŠè¡ãªãã
ããå Žåã«ãã€ãŠã¯ååšããéåå¿åæç©è³ªã¯ã
ç空èžçã«ããåé¢ããããšãã§ããã
ãã«ã ã¢ã«ãããããã«ã ã¢ã«ãããè±é¢åå
ç©åã¯åèšãã«ã ã¢ã«ãããèªå°äœãšã®ïŒ®âããš
ãã«ãŠã¬ã¿ã³ã®çž®åã¯ãåã ã®ãããäžã§ããã
ã¯é£ç¶çæ¹æ³ãšããŠå®æœããããšãã§ããã
ç©åã¯åèšãã«ã ã¢ã«ãããèªå°äœãšã®ïŒ®âããš
ãã«ãŠã¬ã¿ã³ã®çž®åã¯ãåã ã®ãããäžã§ããã
ã¯é£ç¶çæ¹æ³ãšããŠå®æœããããšãã§ããã
æ¬çºæã«ããçž®åæ³ã«ãããâããšãã«ãŠã¬
ã¿ã³ãšãã«ã ã¢ã«ããããšäºå®èœååç©ãšã®éžæ
ãããã¢ã«æ¯ã«å¿ããŠå šééã«å¯ŸããŠ20ã90éé
ïŒ ãæå©ã«40ã80ééïŒ ã®éã®ã¡ãã¬ã³âãã¹â
ããšãã«ãŠã¬ã¿ã³ãæããç²è£œMDUãåŸããã
ããã¯æ¬¡ã®ç°æ§äœååžãæããïŒã¡ãã¬ã³âãã¹
âããšãã«ãŠã¬ã¿ã³ã®å šééã«å¯ŸããŠããããã
ã¡ãã¬ã³âãã¹âïŒïŒâããšãã«ãŠã¬ã¿ã³ïŒ70ã
95ééïŒ ãæå©ã«80ã95ééïŒ åã³ã¡ãã¬ã³â
ïŒïŒâããšãã«ãŠã¬ã¿ã³ïŒâïŒâããšãã«ãŠã¬ã¿
ã³30ãïŒééïŒ ãæå©ã«ïŒã20ééïŒ ã
ã¿ã³ãšãã«ã ã¢ã«ããããšäºå®èœååç©ãšã®éžæ
ãããã¢ã«æ¯ã«å¿ããŠå šééã«å¯ŸããŠ20ã90éé
ïŒ ãæå©ã«40ã80ééïŒ ã®éã®ã¡ãã¬ã³âãã¹â
ããšãã«ãŠã¬ã¿ã³ãæããç²è£œMDUãåŸããã
ããã¯æ¬¡ã®ç°æ§äœååžãæããïŒã¡ãã¬ã³âãã¹
âããšãã«ãŠã¬ã¿ã³ã®å šééã«å¯ŸããŠããããã
ã¡ãã¬ã³âãã¹âïŒïŒâããšãã«ãŠã¬ã¿ã³ïŒ70ã
95ééïŒ ãæå©ã«80ã95ééïŒ åã³ã¡ãã¬ã³â
ïŒïŒâããšãã«ãŠã¬ã¿ã³ïŒâïŒâããšãã«ãŠã¬ã¿
ã³30ãïŒééïŒ ãæå©ã«ïŒã20ééïŒ ã
å Žåã«ãã€ãŠã¯ãç²è£œMDUããã¡ãã¬ã³âã
ã¹âããšãã«ãŠã¬ã¿ã³ãå šäœçã«ãåã¯æå©ã«éš
åçã«åé¢ããå Žåã«ãã€ãŠã¯ç°æ§äœã«åé¢ãã
ã®ãæå©ã§ãããããã¯ãäŸãã°åå¥çµæ¶ã«ãã€
ãŠè¡ãªãããšãã§ããã
ã¹âããšãã«ãŠã¬ã¿ã³ãå šäœçã«ãåã¯æå©ã«éš
åçã«åé¢ããå Žåã«ãã€ãŠã¯ç°æ§äœã«åé¢ãã
ã®ãæå©ã§ãããããã¯ãäŸãã°åå¥çµæ¶ã«ãã€
ãŠè¡ãªãããšãã§ããã
æ¬çºæã«ãã€ãŠè£œé ãããç²è£œMDUã¯ãèªäœ
å ¬ç¥ã®æ¹æ³ã«ãã175âã600âã®æž©åºŠã§ã觊åªã®
äžåšäžã«ïŒäŸãã°ããã€ãé£éŠå ±ååœç¹èš±åºé¡å ¬
é第2410505å·æ现æžïŒç±³åœç¹èš±ç¬¬3870739å·æ现
æžïŒã®èšèŒã«ããïŒãåã¯è§Šåªã®ååšäžã«ïŒäŸã
ã°ããã€ãé£éŠå ±ååœç¹èš±åºé¡å ¬é第1944719å·
æ现æžïŒè±åœç¹èš±ç¬¬1247451å·æ现æžïŒã®èšèŒã«
ããïŒç±å解ããŠçžå¿ããç²è£œMDIã«å€ããã
ãšãã§ãããç±å解ã¯ã液çžäžã§ãäŸãã°ãã€ã
é£éŠå ±ååœç¹èš±åºé¡å ¬å第2421503å·æ现æžïŒç±³
åœç¹èš±ç¬¬3962302å·æ现æžïŒåã¯ãã€ãé£éŠå ±å
åœç¹èš±åºé¡å ¬å第2530001å·æ现æžïŒç±³åœç¹èš±ç¬¬
3919280å·æ现æžåã³å第3919279å·æ现æžïŒã®èš
èŒãšåãã溶å€ã®ååšäžã«è§Šåªãªãã«ãããã¯äŸ
ãã°ãã€ãé£éŠå ±ååœç¹èš±åºé¡å ¬é第2635490å·
æ现æžã®èšèŒãšåããæ®ã«æº¶å€åã³æº¶è§£ãã觊åª
ã®ååšäžã«175âã350âã®æž©åºŠã§å®æœããã®ãæ
å©ã§ããã
å ¬ç¥ã®æ¹æ³ã«ãã175âã600âã®æž©åºŠã§ã觊åªã®
äžåšäžã«ïŒäŸãã°ããã€ãé£éŠå ±ååœç¹èš±åºé¡å ¬
é第2410505å·æ现æžïŒç±³åœç¹èš±ç¬¬3870739å·æ现
æžïŒã®èšèŒã«ããïŒãåã¯è§Šåªã®ååšäžã«ïŒäŸã
ã°ããã€ãé£éŠå ±ååœç¹èš±åºé¡å ¬é第1944719å·
æ现æžïŒè±åœç¹èš±ç¬¬1247451å·æ现æžïŒã®èšèŒã«
ããïŒç±å解ããŠçžå¿ããç²è£œMDIã«å€ããã
ãšãã§ãããç±å解ã¯ã液çžäžã§ãäŸãã°ãã€ã
é£éŠå ±ååœç¹èš±åºé¡å ¬å第2421503å·æ现æžïŒç±³
åœç¹èš±ç¬¬3962302å·æ现æžïŒåã¯ãã€ãé£éŠå ±å
åœç¹èš±åºé¡å ¬å第2530001å·æ现æžïŒç±³åœç¹èš±ç¬¬
3919280å·æ现æžåã³å第3919279å·æ现æžïŒã®èš
èŒãšåãã溶å€ã®ååšäžã«è§Šåªãªãã«ãããã¯äŸ
ãã°ãã€ãé£éŠå ±ååœç¹èš±åºé¡å ¬é第2635490å·
æ现æžã®èšèŒãšåããæ®ã«æº¶å€åã³æº¶è§£ãã觊åª
ã®ååšäžã«175âã350âã®æž©åºŠã§å®æœããã®ãæ
å©ã§ããã
溶解ãã觊åªãåå¿æ··åç©ããé€å»ããããšã¯
åé¡ã§ããã®ã§ãæ¬çºæã«ããã°ãå ¬ç¥æ¹æ³ãã
æå©ã«é觊åªåå¿ã«ããå解ãèšèŒããããšãæ
ãŸãããããããæå€ãªããšã«ãç±å解ã¯ãè¡šé¢
å¯æã®åœ¢ãäŸãã°éå±ç²æ«ãå¹³åçŽåŸïŒã10mmã
æããéå±é¡ç²ãéå±å±åã¯éå±æ¯ã®åœ¢ã®äžé£ã®
äºéãã¢ã«ãããŠã ããã¿ã³ãéãã¯ãã ãã³ã
ã«ãåã³ããã±ã«ïŒãã®å Žåãäºéåã³ã¢ã«ãã
ãŠã ã䜿çšããã®ãæå©ã§ããïŒããã®éå±åã¯
該éå±ããå Žåã«ãã€ãŠã¯ä»ã®éå±ãäŸãã°ãã
ãžãŠã åã³ã¿ã³ã°ã¹ãã³ãšçµåããŠå«æããåé
ã§äžåäžç³»è§Šåªåå¿ããããšã«ãã€ãŠä¿é²ããã
ã®ãæå©ã§ããããšãå€æãããéå±ã¯ãè¯å¥œãª
ç±éäŒäœã§ããã ãã§ãªããããã«å·¥æ¥çã«æå©
ã«äœ¿çšã§ããè¯å¥œãªè§Šåªåå¿äœçšãæããã€åå¿
枩床åã³åå¿æéã®æãããªäœäžãå¯èœã«ããã®
ã§å¯åå¿ãäŸãã°éåã¯æ®ãã©çããªãã
åé¡ã§ããã®ã§ãæ¬çºæã«ããã°ãå ¬ç¥æ¹æ³ãã
æå©ã«é觊åªåå¿ã«ããå解ãèšèŒããããšãæ
ãŸãããããããæå€ãªããšã«ãç±å解ã¯ãè¡šé¢
å¯æã®åœ¢ãäŸãã°éå±ç²æ«ãå¹³åçŽåŸïŒã10mmã
æããéå±é¡ç²ãéå±å±åã¯éå±æ¯ã®åœ¢ã®äžé£ã®
äºéãã¢ã«ãããŠã ããã¿ã³ãéãã¯ãã ãã³ã
ã«ãåã³ããã±ã«ïŒãã®å Žåãäºéåã³ã¢ã«ãã
ãŠã ã䜿çšããã®ãæå©ã§ããïŒããã®éå±åã¯
該éå±ããå Žåã«ãã€ãŠã¯ä»ã®éå±ãäŸãã°ãã
ãžãŠã åã³ã¿ã³ã°ã¹ãã³ãšçµåããŠå«æããåé
ã§äžåäžç³»è§Šåªåå¿ããããšã«ãã€ãŠä¿é²ããã
ã®ãæå©ã§ããããšãå€æãããéå±ã¯ãè¯å¥œãª
ç±éäŒäœã§ããã ãã§ãªããããã«å·¥æ¥çã«æå©
ã«äœ¿çšã§ããè¯å¥œãªè§Šåªåå¿äœçšãæããã€åå¿
枩床åã³åå¿æéã®æãããªäœäžãå¯èœã«ããã®
ã§å¯åå¿ãäŸãã°éåã¯æ®ãã©çããªãã
觊åªã¯ãçš®ã
ã®é
眮ã§ãäŸãã°åºå®åºãšããŠã
äŸãã°ç®¡âåã¯éåå¿åšã«éå±é¡ç²ãâç°ãâå±
åã¯âæ¯ãè£ å ¥ããããšã«ãã€ãŠäœ¿çšããããšã
ã§ãããããã€ãŠåå¿æ··åç©ã¯ãé£ç¶çã«è§Šåªâ
åºå®åºãéãããšãã§ããããããã¯æ¹æåå¿åš
ã®æžæ¿æ¶²äžã«å°ãããšãã§ããã
äŸãã°ç®¡âåã¯éåå¿åšã«éå±é¡ç²ãâç°ãâå±
åã¯âæ¯ãè£ å ¥ããããšã«ãã€ãŠäœ¿çšããããšã
ã§ãããããã€ãŠåå¿æ··åç©ã¯ãé£ç¶çã«è§Šåªâ
åºå®åºãéãããšãã§ããããããã¯æ¹æåå¿åš
ã®æžæ¿æ¶²äžã«å°ãããšãã§ããã
溶å€ãšããŠã¯ãæ¬çºæã«ããåªãã液çžäžã§ã®
ç±å解ã®éã«ãã€ãœã·ã¢ããŒãåã³ãã®ä»ã®æå
ã«å¯ŸããŠåå¿æ¡ä»¶äžã§äžæŽ»æ§ã§ãããã€æ²žç¹ã
ïŒïŒ4â²âãžããšãã«ã¡ã¿ã³âãžã€ãœã·ã¢ããŒãã®
沞ç¹ä»¥äžãæå©ã«è±é¢ãã¹ãã¢ã«ã³ãŒã«ã®æ²žç¹ã
ããé«ã溶å€ã䜿çšããããæŽã«ã溶å€ã®éèŠãª
枩床ã¯ã175â以äžã§ãã€ãŠã¯ãªããªããæŽã«ã
ç²è£œMDUã溶å€ã«å¯æº¶æ§ã§ããããšã¯ããã®ã
ãšãå¿ ãããå¿ èŠãªããšããŠãæå©ãªããšã§ã
ããäŸãã°ã次ã®æº¶å€ãæããããïŒèèªæçå
æ°ŽçŽ ãäŸãã°é«çŽã¢ã«ã«ã³ããã«ã³ããŠã³ãã«
ã³ãããã«ã³ãããªãã«ã³ãããã©ãã«ã³ããã³
ã¿ãã«ã³ããããµãã«ã³ãããã¿ãã«ã³åã³ãã«
ãªã³ãå Žåã«ãã€ãŠã¯çœ®æãããè³éŠæçåæ°Ž
çŽ ãäŸãã°ããã¿ãªã³ãïŒâãã€ïŒâã¡ãã«ãã
ã¿ãªã³ãïŒïŒïŒâãïŒïŒïŒâãïŒïŒïŒâãïŒïŒïŒ
âãïŒïŒïŒâãã€ïŒïŒïŒâãžã¡ãã«ããã¿ãªã³ã
ïŒâãšãã«ããã¿ãªã³ããã«ãªãŒã«ãïŒïŒïŒâã
ïŒïŒïŒâãã€ïŒïŒïŒâãžã¡ãã«ãã³ãŸãŒã«ãïŒïŒ
ïŒïŒïŒâãã€ïŒïŒïŒïŒïŒâããªã¡ãã«ãã³ãŸãŒ
ã«ãïŒïŒïŒïŒïŒïŒïŒâãã€ïŒïŒïŒïŒïŒïŒïŒâãã
ã©ã¡ãã«ãã³ãŸãŒã«ãïŒïŒïŒïŒïŒâããªãšãã«ã
ã³ãŸãŒã«ãããã·ã«âããããã«âããªã¯ãã«
âãããã«âããã·ã«âåã³ããã·ã«ãã³ãŸãŒ
ã«ããããµã¡ãã«ãã³ãŸãŒã«ããããµãšãã«ãã³
ãŸãŒã«ããžããšãã«ãïŒïŒ4â²âãžã¡ãã«ãžããšã
ã«ããžãã³ãžã«ããžããšãã«ã¡ã¿ã³åã³ïŒïŒ4â²â
ãžã¡ãã«âãžããšãã«ã¡ã¿ã³ãããã²ã³çœ®æè³éŠ
æçåæ°ŽçŽ ãäŸãã°ã¯ãã«ãã³ãŸãŒã«ãïŒïŒïŒâ
ãã€ïŒïŒïŒâãžã¯ãã«ãã³ãŸãŒã«ãïŒïŒïŒâãžãš
ãŒããã³ãŸãŒã«ãïŒïŒïŒïŒïŒâãã€ïŒïŒïŒïŒïŒâ
ããªã¯ãã«ãã³ãŸãŒã«ãïŒïŒïŒïŒïŒïŒïŒâãïŒïŒ
ïŒïŒïŒïŒïŒâãã€ïŒïŒïŒïŒïŒïŒïŒâããã©ã¯ãã«
ãã³ãŸãŒã«ããã³ã¿ã¯ãã«ãã³ãŸãŒã«ãïŒâãã€
ïŒâãã«ãªã«ããã¿ãªã³ãïŒâãã€ïŒâã¯ãã«ã
ãã¿ãªã³ãïŒâãã€ïŒâãšãŒãããã¿ãªã³åã³ãž
ããšãã«âãžã¯ãã«ã¡ã¿ã³ïŒãããåºå«æè³éŠæ
çåæ°ŽçŽ ãäŸãã°ããããã³ãŸãŒã«ãïŒâããã
ãã«ãªãŒã«ãïŒâãããâïœâãã·ããŒã«ãïŒâ
ãããâïœâãã·ããŒã«åã³ïŒâãããã¢ããœãŒ
ã«ãèèªæã±ãã³åã³è³éŠæã±ãã³ãäŸãã°ã·ã¯
ããããµãã³ãã·ã¯ãããã¿ãã³ããžâïœâãã
ã«ã±ãã³ããžâïœâã¢ãã«ã±ãã³ãαâããã©ã
ã³ãã¢ã»ãããšãã³ãããããªããšãã³ããã³ãŸ
ããšãã³ãïŒâã¡ãã«ãã³ãŸããšãã³ãããã«ã
ã³âïŒåã³ããªãã«ãã³âïŒãã¹ã«ãã³åã³ã«ã«
ãã³é žãšã¹ãã«ãäŸãã°ã¹ã«ãã©ã³ããžãšãã«ã¹
ã«ãã³ããã¿ã«é žãžã¡ãã«ãšã¹ãã«ããã¿ã«é žãž
ãšãã«ãšã¹ãã«ãå®æ¯éŠé žãããã«ãšã¹ãã«åã³
ã©ãŠãªã³é žãšãã«ãšã¹ãã«åã³ãšãŒãã«ãäŸãã°
ãžãšãã¬ã³ã°ãªã³ãŒã«âãžã¡ãã«ãšãŒãã«ããžãš
ãã¬ã³ã°ãªã³ãŒã«âãžãšãã«ãšãŒãã«ããžã€ãœã¢
ãã«ãšãŒãã«ããžâïœâã¢ãã«ãšãŒãã«ãã¬ãŸã«
ã·ã³ãžã¡ãã«ãšãŒãã«ãã¬ãŸã«ã·ã³ãžãšãã«ãšãŒ
ãã«ãããšãã«ãªã¯ãã«ãšãŒãã«ãããšãã«ãã³
ãžã«ãšãŒãã«ããžãã³ãžã«ãšãŒãã«ããžããšãã«
ãšãŒãã«ãαâã¡ãã«ãããã«ãšãŒãã«åã³Î²â
ãšãã«ãããã«ãšãŒãã«ã
ç±å解ã®éã«ãã€ãœã·ã¢ããŒãåã³ãã®ä»ã®æå
ã«å¯ŸããŠåå¿æ¡ä»¶äžã§äžæŽ»æ§ã§ãããã€æ²žç¹ã
ïŒïŒ4â²âãžããšãã«ã¡ã¿ã³âãžã€ãœã·ã¢ããŒãã®
沞ç¹ä»¥äžãæå©ã«è±é¢ãã¹ãã¢ã«ã³ãŒã«ã®æ²žç¹ã
ããé«ã溶å€ã䜿çšããããæŽã«ã溶å€ã®éèŠãª
枩床ã¯ã175â以äžã§ãã€ãŠã¯ãªããªããæŽã«ã
ç²è£œMDUã溶å€ã«å¯æº¶æ§ã§ããããšã¯ããã®ã
ãšãå¿ ãããå¿ èŠãªããšããŠãæå©ãªããšã§ã
ããäŸãã°ã次ã®æº¶å€ãæããããïŒèèªæçå
æ°ŽçŽ ãäŸãã°é«çŽã¢ã«ã«ã³ããã«ã³ããŠã³ãã«
ã³ãããã«ã³ãããªãã«ã³ãããã©ãã«ã³ããã³
ã¿ãã«ã³ããããµãã«ã³ãããã¿ãã«ã³åã³ãã«
ãªã³ãå Žåã«ãã€ãŠã¯çœ®æãããè³éŠæçåæ°Ž
çŽ ãäŸãã°ããã¿ãªã³ãïŒâãã€ïŒâã¡ãã«ãã
ã¿ãªã³ãïŒïŒïŒâãïŒïŒïŒâãïŒïŒïŒâãïŒïŒïŒ
âãïŒïŒïŒâãã€ïŒïŒïŒâãžã¡ãã«ããã¿ãªã³ã
ïŒâãšãã«ããã¿ãªã³ããã«ãªãŒã«ãïŒïŒïŒâã
ïŒïŒïŒâãã€ïŒïŒïŒâãžã¡ãã«ãã³ãŸãŒã«ãïŒïŒ
ïŒïŒïŒâãã€ïŒïŒïŒïŒïŒâããªã¡ãã«ãã³ãŸãŒ
ã«ãïŒïŒïŒïŒïŒïŒïŒâãã€ïŒïŒïŒïŒïŒïŒïŒâãã
ã©ã¡ãã«ãã³ãŸãŒã«ãïŒïŒïŒïŒïŒâããªãšãã«ã
ã³ãŸãŒã«ãããã·ã«âããããã«âããªã¯ãã«
âãããã«âããã·ã«âåã³ããã·ã«ãã³ãŸãŒ
ã«ããããµã¡ãã«ãã³ãŸãŒã«ããããµãšãã«ãã³
ãŸãŒã«ããžããšãã«ãïŒïŒ4â²âãžã¡ãã«ãžããšã
ã«ããžãã³ãžã«ããžããšãã«ã¡ã¿ã³åã³ïŒïŒ4â²â
ãžã¡ãã«âãžããšãã«ã¡ã¿ã³ãããã²ã³çœ®æè³éŠ
æçåæ°ŽçŽ ãäŸãã°ã¯ãã«ãã³ãŸãŒã«ãïŒïŒïŒâ
ãã€ïŒïŒïŒâãžã¯ãã«ãã³ãŸãŒã«ãïŒïŒïŒâãžãš
ãŒããã³ãŸãŒã«ãïŒïŒïŒïŒïŒâãã€ïŒïŒïŒïŒïŒâ
ããªã¯ãã«ãã³ãŸãŒã«ãïŒïŒïŒïŒïŒïŒïŒâãïŒïŒ
ïŒïŒïŒïŒïŒâãã€ïŒïŒïŒïŒïŒïŒïŒâããã©ã¯ãã«
ãã³ãŸãŒã«ããã³ã¿ã¯ãã«ãã³ãŸãŒã«ãïŒâãã€
ïŒâãã«ãªã«ããã¿ãªã³ãïŒâãã€ïŒâã¯ãã«ã
ãã¿ãªã³ãïŒâãã€ïŒâãšãŒãããã¿ãªã³åã³ãž
ããšãã«âãžã¯ãã«ã¡ã¿ã³ïŒãããåºå«æè³éŠæ
çåæ°ŽçŽ ãäŸãã°ããããã³ãŸãŒã«ãïŒâããã
ãã«ãªãŒã«ãïŒâãããâïœâãã·ããŒã«ãïŒâ
ãããâïœâãã·ããŒã«åã³ïŒâãããã¢ããœãŒ
ã«ãèèªæã±ãã³åã³è³éŠæã±ãã³ãäŸãã°ã·ã¯
ããããµãã³ãã·ã¯ãããã¿ãã³ããžâïœâãã
ã«ã±ãã³ããžâïœâã¢ãã«ã±ãã³ãαâããã©ã
ã³ãã¢ã»ãããšãã³ãããããªããšãã³ããã³ãŸ
ããšãã³ãïŒâã¡ãã«ãã³ãŸããšãã³ãããã«ã
ã³âïŒåã³ããªãã«ãã³âïŒãã¹ã«ãã³åã³ã«ã«
ãã³é žãšã¹ãã«ãäŸãã°ã¹ã«ãã©ã³ããžãšãã«ã¹
ã«ãã³ããã¿ã«é žãžã¡ãã«ãšã¹ãã«ããã¿ã«é žãž
ãšãã«ãšã¹ãã«ãå®æ¯éŠé žãããã«ãšã¹ãã«åã³
ã©ãŠãªã³é žãšãã«ãšã¹ãã«åã³ãšãŒãã«ãäŸãã°
ãžãšãã¬ã³ã°ãªã³ãŒã«âãžã¡ãã«ãšãŒãã«ããžãš
ãã¬ã³ã°ãªã³ãŒã«âãžãšãã«ãšãŒãã«ããžã€ãœã¢
ãã«ãšãŒãã«ããžâïœâã¢ãã«ãšãŒãã«ãã¬ãŸã«
ã·ã³ãžã¡ãã«ãšãŒãã«ãã¬ãŸã«ã·ã³ãžãšãã«ãšãŒ
ãã«ãããšãã«ãªã¯ãã«ãšãŒãã«ãããšãã«ãã³
ãžã«ãšãŒãã«ããžãã³ãžã«ãšãŒãã«ããžããšãã«
ãšãŒãã«ãαâã¡ãã«ãããã«ãšãŒãã«åã³Î²â
ãšãã«ãããã«ãšãŒãã«ã
éå±ã®ååšäžã§ã®ç²è£œMDUã®ç±å解ã¯ã175
âã600âã®æž©åºŠã§ãæå©ã«æº¶å€äžã§175âã350
âã§ãæ®ã«230âã350âã§æžå§äžãåžžå§äžåã¯é«
ããããå§åäžã§éé£ç¶çã«ãåã¯æå©ã«é£ç¶ç
ã«å®æœããããçæç©ã®å解åã³åé¢ã¯ãé 次ã«
ãåã¯æå©ã«åæã«è¡ãªãããšãã§ãããç²è£œ
MDUã¯ãäŸãã°æº¶è§£ç²æ«ãšããŠãããã¯äžæŽ»æ§
溶å€äžã®æžæ¿æ¶²åã¯æº¶æ¶²ãšããŠãéžæçã«äžå®ã®
枩床åã³äžå®ã®å§åã«ä¿æãããåå¿åšã«äŸçµŠã
ãããšãã§ãããäŸãã°ãç²è£œMDUã®æº¶æ¶²ã¯ã
亀äºã«åçå¡ãšåé¢å¡ãšãããªãã«ã¹ã±ãŒãã«é
ãããšãã§ãããåªããå®æœæ æ§ã§ã¯ãç²è£œ
MDUã®æº¶æ¶²ã¯æ¯æïŒåœããŠã¬ã¿ã³0.1ãïŒåœ
éãæå©ã«0.2ãïŒåœéã«å¿ããŠé£ç¶çã«åå¿åš
åã¯åå¿åšã«ã¹ã±ãŒãäžã«ã¢ã«ã³ãŒã«ãåæã«å
解ããã€åé¢ããªããïŒã€ä»¥äžã®åé¢å¡ãä»ããŠ
å°ããããã®å Žå枩床ïŒå§åæ¯ã¯æå©ã«æº¶å€ãé
æµäžã«ç¶æãããããããã¯éšåçã«ã¢ã«ã³ãŒã«
ãšäžç·ã«çå»ãããããã«éžæããããæåŸã«ã
溶å€ã¯æ³šææ·±ãèžçããããšã«ãã€ãŠå Žåã«ãã€
ãŠã¯æãåãããªãããæå©ã«çãæ»çæéãæ
ããè¡šé¢å¯æã®èžçºåšãä»ããŠçå»ããïŒãã®å Ž
åã«ã¯ããžããšãã«ã¡ã¿ã³âãžã€ãœã·ã¢ããŒãã¯
æ æææãšããŠäœçšããïŒãç²è£œMDIã¯å¡åºçå
ãšããŠåãåºãããããã®å Žåããžããšãã«ã¡ã¿
ã³âãžã€ãœã·ã¢ããŒãã®åéã溶å€ãšäžç·ã«çå»
ããŠåŸªç°ããŠæ»ãã®ãæå©ã§ããããšãå€æã
ãã
âã600âã®æž©åºŠã§ãæå©ã«æº¶å€äžã§175âã350
âã§ãæ®ã«230âã350âã§æžå§äžãåžžå§äžåã¯é«
ããããå§åäžã§éé£ç¶çã«ãåã¯æå©ã«é£ç¶ç
ã«å®æœããããçæç©ã®å解åã³åé¢ã¯ãé 次ã«
ãåã¯æå©ã«åæã«è¡ãªãããšãã§ãããç²è£œ
MDUã¯ãäŸãã°æº¶è§£ç²æ«ãšããŠãããã¯äžæŽ»æ§
溶å€äžã®æžæ¿æ¶²åã¯æº¶æ¶²ãšããŠãéžæçã«äžå®ã®
枩床åã³äžå®ã®å§åã«ä¿æãããåå¿åšã«äŸçµŠã
ãããšãã§ãããäŸãã°ãç²è£œMDUã®æº¶æ¶²ã¯ã
亀äºã«åçå¡ãšåé¢å¡ãšãããªãã«ã¹ã±ãŒãã«é
ãããšãã§ãããåªããå®æœæ æ§ã§ã¯ãç²è£œ
MDUã®æº¶æ¶²ã¯æ¯æïŒåœããŠã¬ã¿ã³0.1ãïŒåœ
éãæå©ã«0.2ãïŒåœéã«å¿ããŠé£ç¶çã«åå¿åš
åã¯åå¿åšã«ã¹ã±ãŒãäžã«ã¢ã«ã³ãŒã«ãåæã«å
解ããã€åé¢ããªããïŒã€ä»¥äžã®åé¢å¡ãä»ããŠ
å°ããããã®å Žå枩床ïŒå§åæ¯ã¯æå©ã«æº¶å€ãé
æµäžã«ç¶æãããããããã¯éšåçã«ã¢ã«ã³ãŒã«
ãšäžç·ã«çå»ãããããã«éžæããããæåŸã«ã
溶å€ã¯æ³šææ·±ãèžçããããšã«ãã€ãŠå Žåã«ãã€
ãŠã¯æãåãããªãããæå©ã«çãæ»çæéãæ
ããè¡šé¢å¯æã®èžçºåšãä»ããŠçå»ããïŒãã®å Ž
åã«ã¯ããžããšãã«ã¡ã¿ã³âãžã€ãœã·ã¢ããŒãã¯
æ æææãšããŠäœçšããïŒãç²è£œMDIã¯å¡åºçå
ãšããŠåãåºãããããã®å Žåããžããšãã«ã¡ã¿
ã³âãžã€ãœã·ã¢ããŒãã®åéã溶å€ãšäžç·ã«çå»
ããŠåŸªç°ããŠæ»ãã®ãæå©ã§ããããšãå€æã
ãã
å®æœäŸäžã«èšèŒããéšã¯ãééã«å¯Ÿãããã®ã§
ããã
ããã
å®æœäŸ ïŒ
ã¢ããªã³93éšãã«ã«ãããé
žã¡ãã«ãšã¹ãã«
450éšãé ¢é žéïŒïŒ0.9éšåã³ã¡ã¿ããŒã«95éšãš
äžç·ã«ïŒæé175âã180âã«å ç±ãããã®å Žåå
å¿å®¹åšã®å§ååŒãä»ããŠå§åãïŒãïŒããŒã«ã«èª¿
ç¯ãããåå¿ã®éã«çæããã¢ã³ã¢ãã¢ãæ¯æå
å¿æ··åç©ïŒåœãçªçŽ ã¬ã¹15ãé£è¡å€ãšããŠäœ¿
çšããªããé£ç¶çã«çå»ãããåå¿ã®çµçµåŸãé
åå¿ã¢ããªã³ãéå°ã®ã¡ã¿ããŒã«åã³éå°ã®ã«ã«
ãããé žã¡ãã«ãšã¹ãã«ãçŽ20ããªããŒã«ã§çå»
ãã110âã113âåã³0.1ããªããŒã«ã§èžçãã
ããšã«ãã€ãŠïŒ®âããšãã«ã¡ãã«ãŠã¬ã¿ã³127éš
ïŒåå¿ããã¢ããªã³ã«å¯ŸããŠçè«å€ã®88.5ïŒ ïŒã
åŸããèžçæ®æ»äžã«ã¯ãä»ã®ïŒ®âããšãã«âã¡ã
ã«âãŠã¬ã¿ã³ãååšãããã¢ããªã³ã®å€æçã¯95
ïŒ ã§ããïŒã¬ã¹ã¯ãããã°ã©ãã€ãŒã«ãã枬å®ïŒã
450éšãé ¢é žéïŒïŒ0.9éšåã³ã¡ã¿ããŒã«95éšãš
äžç·ã«ïŒæé175âã180âã«å ç±ãããã®å Žåå
å¿å®¹åšã®å§ååŒãä»ããŠå§åãïŒãïŒããŒã«ã«èª¿
ç¯ãããåå¿ã®éã«çæããã¢ã³ã¢ãã¢ãæ¯æå
å¿æ··åç©ïŒåœãçªçŽ ã¬ã¹15ãé£è¡å€ãšããŠäœ¿
çšããªããé£ç¶çã«çå»ãããåå¿ã®çµçµåŸãé
åå¿ã¢ããªã³ãéå°ã®ã¡ã¿ããŒã«åã³éå°ã®ã«ã«
ãããé žã¡ãã«ãšã¹ãã«ãçŽ20ããªããŒã«ã§çå»
ãã110âã113âåã³0.1ããªããŒã«ã§èžçãã
ããšã«ãã€ãŠïŒ®âããšãã«ã¡ãã«ãŠã¬ã¿ã³127éš
ïŒåå¿ããã¢ããªã³ã«å¯ŸããŠçè«å€ã®88.5ïŒ ïŒã
åŸããèžçæ®æ»äžã«ã¯ãä»ã®ïŒ®âããšãã«âã¡ã
ã«âãŠã¬ã¿ã³ãååšãããã¢ããªã³ã®å€æçã¯95
ïŒ ã§ããïŒã¬ã¹ã¯ãããã°ã©ãã€ãŒã«ãã枬å®ïŒã
ããããŠåŸãããâããšãã«ã¡ãã«ãŠã¬ã¿ã³
ãæ¹æãªãŒãã¯ã¬ãŒãäžã§ãžã¡ãã«ãã«ãã«32
éšãããããã³ãŸãŒã«93éšåã³ç¡«é ž17éšãšäžç·ã«
æ¹æäžã§100âã«å ç±ãããã€10æéãã®æž©åºŠã§
æ¹æãããåå¿ãçµçµããã€é žãæ°Žã§æœåºãã
åŸãæžå§äžã§æº¶å€åã³éåå¿åæç©è³ªãçå»ã
ããé«å§æ¶²äœã¯ãããã°ã©ãã€ãŒåæã«å¿ããŠãž
âïŒã¡ããã·ã«ã«ããã«ã¢ããïŒâãžããšãã«ã¡
ã¿ã³52ïŒ ãïŒâæ ž30ïŒ åã³é«çŽæ žããªã¡ãã¬ã³â
ããªããšãã«ãŠã¬ã¿ã³18ïŒ ïŒç²è£œMDUïŒãããª
ãèžçæ®æ»126éšãåŸãããã
ãæ¹æãªãŒãã¯ã¬ãŒãäžã§ãžã¡ãã«ãã«ãã«32
éšãããããã³ãŸãŒã«93éšåã³ç¡«é ž17éšãšäžç·ã«
æ¹æäžã§100âã«å ç±ãããã€10æéãã®æž©åºŠã§
æ¹æãããåå¿ãçµçµããã€é žãæ°Žã§æœåºãã
åŸãæžå§äžã§æº¶å€åã³éåå¿åæç©è³ªãçå»ã
ããé«å§æ¶²äœã¯ãããã°ã©ãã€ãŒåæã«å¿ããŠãž
âïŒã¡ããã·ã«ã«ããã«ã¢ããïŒâãžããšãã«ã¡
ã¿ã³52ïŒ ãïŒâæ ž30ïŒ åã³é«çŽæ žããªã¡ãã¬ã³â
ããªããšãã«ãŠã¬ã¿ã³18ïŒ ïŒç²è£œMDUïŒãããª
ãèžçæ®æ»126éšãåŸãããã
ããããŠåŸãããç²è£œMDU126ïœãã¹ã«ãã©
ã³550ïœã«æº¶è§£ãããããæ¯æåå¿å®¹ç©ïŒåœã
300ïœã®äŸçµŠé床ã§äºéå±ã§å å¡«ããã300âã«å
ç±ããç³è±ã¬ã©ã¹ãããªã管ç¶åå¿åšäžã«ãã³ã
äœçšã§æ¬å ¥ãããå解ã®éã«çæããã¡ã¿ããŒã«
ãã¬ã¹ç¶ã§åé¢ãããã©ã€ã¢ã€ã¹ã§å·åŽããååš
äžã§åçž®ããããåå¿æ··åç©658ïœãåŸããã®æ··
åç©ãã90âã95âåã³0.1ããªããŒã«ã§å解溶
å€ã¹ã«ãã©ã³ãçå»ããããžããšãã«ã¡ã¿ã³âãž
ã€ãœã·ã¢ããŒã57ïŒ ãïŒâæ ž31ïŒ åã³é«çŽæ žããª
ããšãã«âããªã¡ãã¬ã³ããªã€ãœã·ã¢ããŒã12ïŒ
ã®æ··åç©112ïœãæ®çããã
ã³550ïœã«æº¶è§£ãããããæ¯æåå¿å®¹ç©ïŒåœã
300ïœã®äŸçµŠé床ã§äºéå±ã§å å¡«ããã300âã«å
ç±ããç³è±ã¬ã©ã¹ãããªã管ç¶åå¿åšäžã«ãã³ã
äœçšã§æ¬å ¥ãããå解ã®éã«çæããã¡ã¿ããŒã«
ãã¬ã¹ç¶ã§åé¢ãããã©ã€ã¢ã€ã¹ã§å·åŽããååš
äžã§åçž®ããããåå¿æ··åç©658ïœãåŸããã®æ··
åç©ãã90âã95âåã³0.1ããªããŒã«ã§å解溶
å€ã¹ã«ãã©ã³ãçå»ããããžããšãã«ã¡ã¿ã³âãž
ã€ãœã·ã¢ããŒã57ïŒ ãïŒâæ ž31ïŒ åã³é«çŽæ žããª
ããšãã«âããªã¡ãã¬ã³ããªã€ãœã·ã¢ããŒã12ïŒ
ã®æ··åç©112ïœãæ®çããã
å®æœäŸ ïŒ
ã¢ããªã³60éšãã«ã«ãããé
žãšãã«ãšã¹ãã«
172éšãå°¿çŽ 38éšãé ¢é žã³ãã«ã0.75éšåã³ãšã¿
ããŒã«90éšãšäžç·ã«ïŒæé175âã180âã«å ç±
ãããã®å Žååå¿å®¹åšäžã®å§ååŒãä»ããŠå§åã
ïŒãïŒããŒã«ã«èª¿ç¯ãããåå¿ã®éã«çæããã¢
ã³ã¢ãã¢ãæ¯æåå¿æ··åç©ïŒåœãçªçŽ ã¬ã¹12
ãé£è¡å€ãšããŠäœ¿çšããªããé£ç¶çã«çå»ããã
åå¿ã®çµçµåŸãéåå¿ã¢ããªã³ãéå°ã®ãšã¿ããŒ
ã«åã³éå°ã®ã«ã«ãããé žãšãã«ãšã¹ãã«ãçŽ12
ããªããŒã«ã§çå»ãã123âã126âåã³0.1ããª
ããŒã«ã§èžçããããšã«ãã€ãŠïŒ®âããšãã«ãšã
ã«ãŠã¬ã¿ã³89éšïŒåå¿ããã¢ããªã³ã«å¯ŸããŠçè«
å€ã®86.2ïŒ ïŒãåŸããèžçæ®æ»ã«ã¯ããªãä»ã®ã
ãšãã«ãšãã«ãŠã¬ã¿ã³ãååšãããã¢ããªã³ã®å€
æçã¯ã97ïŒ ã§ããïŒã¬ã¹ã¯ãããã°ã©ãã€ãŒã«
ãã枬å®ïŒã
172éšãå°¿çŽ 38éšãé ¢é žã³ãã«ã0.75éšåã³ãšã¿
ããŒã«90éšãšäžç·ã«ïŒæé175âã180âã«å ç±
ãããã®å Žååå¿å®¹åšäžã®å§ååŒãä»ããŠå§åã
ïŒãïŒããŒã«ã«èª¿ç¯ãããåå¿ã®éã«çæããã¢
ã³ã¢ãã¢ãæ¯æåå¿æ··åç©ïŒåœãçªçŽ ã¬ã¹12
ãé£è¡å€ãšããŠäœ¿çšããªããé£ç¶çã«çå»ããã
åå¿ã®çµçµåŸãéåå¿ã¢ããªã³ãéå°ã®ãšã¿ããŒ
ã«åã³éå°ã®ã«ã«ãããé žãšãã«ãšã¹ãã«ãçŽ12
ããªããŒã«ã§çå»ãã123âã126âåã³0.1ããª
ããŒã«ã§èžçããããšã«ãã€ãŠïŒ®âããšãã«ãšã
ã«ãŠã¬ã¿ã³89éšïŒåå¿ããã¢ããªã³ã«å¯ŸããŠçè«
å€ã®86.2ïŒ ïŒãåŸããèžçæ®æ»ã«ã¯ããªãä»ã®ã
ãšãã«ãšãã«ãŠã¬ã¿ã³ãååšãããã¢ããªã³ã®å€
æçã¯ã97ïŒ ã§ããïŒã¬ã¹ã¯ãããã°ã©ãã€ãŒã«
ãã枬å®ïŒã
ããããŠåŸãããâããšãã«ãšãã«ãŠã¬ã¿ã³
ãæ¹æåå¿åšäžã§ãã©ãã«ã ã¢ã«ãããïŒéšãé ¢
é ž60éšåã³ã¬ã¯ãããïŒLewatitïŒSPCâ108 18
éšãšäžç·ã«æ¹æäžã§100âã«å ç±ãããã€10æé
ãã®æž©åºŠã§æ¹æãããåå¿ã®çµçµåŸã觊åªãæ¿Ÿå¥
ãã溶å€åã³éåå¿åæç©è³ªãæžå§äžã§çå»ã
ããé«å§æ¶²äœã¯ãããã°ã©ãã€ãŒåæã«å¿ããŠãž
âïŒãšããã·ã«ã«ããã«ã¢ããïŒâãžããšãã«ã¡
ã¿ã³55ïŒ ãïŒâæ ž29ïŒ åã³é«çŽæ žããªã¡ãã¬ã³â
ããªããšãã«ãŠã¬ã¿ã³16ïŒ ïŒç²è£œMDUïŒãããª
ãèžçæ®æ»88éšãåŸãããã
ãæ¹æåå¿åšäžã§ãã©ãã«ã ã¢ã«ãããïŒéšãé ¢
é ž60éšåã³ã¬ã¯ãããïŒLewatitïŒSPCâ108 18
éšãšäžç·ã«æ¹æäžã§100âã«å ç±ãããã€10æé
ãã®æž©åºŠã§æ¹æãããåå¿ã®çµçµåŸã觊åªãæ¿Ÿå¥
ãã溶å€åã³éåå¿åæç©è³ªãæžå§äžã§çå»ã
ããé«å§æ¶²äœã¯ãããã°ã©ãã€ãŒåæã«å¿ããŠãž
âïŒãšããã·ã«ã«ããã«ã¢ããïŒâãžããšãã«ã¡
ã¿ã³55ïŒ ãïŒâæ ž29ïŒ åã³é«çŽæ žããªã¡ãã¬ã³â
ããªããšãã«ãŠã¬ã¿ã³16ïŒ ïŒç²è£œMDUïŒãããª
ãèžçæ®æ»88éšãåŸãããã
ããããŠåŸãããç²è£œMDU 88ïœããã·ã«ã
ã³ãŸãŒã«500ïœã«æº¶è§£ãããããæ¯æåå¿å®¹ç©ïŒ
åœã300ïœã®äŸçµŠé床ã§ã¢ã«ãããŠã é¡ç²ã§å
å¡«ããã320âã«å ç±ããç³è±ã¬ã©ã¹ãããªã管
ç¶åå¿åšäžã«ãã³ãäœçšã§æ¬å ¥ãããå解ã®éã«
çæãããšã¿ããŒã«ãã¬ã¹ç¶ã§åé¢ãããã©ã€ã¢
ã€ã¹ã§å·åŽããååšäžã§åçž®ãããã
ã³ãŸãŒã«500ïœã«æº¶è§£ãããããæ¯æåå¿å®¹ç©ïŒ
åœã300ïœã®äŸçµŠé床ã§ã¢ã«ãããŠã é¡ç²ã§å
å¡«ããã320âã«å ç±ããç³è±ã¬ã©ã¹ãããªã管
ç¶åå¿åšäžã«ãã³ãäœçšã§æ¬å ¥ãããå解ã®éã«
çæãããšã¿ããŒã«ãã¬ã¹ç¶ã§åé¢ãããã©ã€ã¢
ã€ã¹ã§å·åŽããååšäžã§åçž®ãããã
åå¿æ··åç©545ïœãåŸããã®æ··åç©ãã85âã
95âåã³0.2ããªããŒã«ã§å解溶å€ãã·ã«ãã³ãŸ
ãŒã«ãçå»ããããžããšãã«ã¡ã¿ã³âãžã€ãœã·ã¢
ããŒã58ïŒ ãïŒâæ ž29ïŒ åã³é«çŽæ žããªããšãã«
âããªã¡ãã¬ã³âããªã€ãœã·ã¢ããŒã13ïŒ ã®æ··å
ç©69ïœãæ®çããã
95âåã³0.2ããªããŒã«ã§å解溶å€ãã·ã«ãã³ãŸ
ãŒã«ãçå»ããããžããšãã«ã¡ã¿ã³âãžã€ãœã·ã¢
ããŒã58ïŒ ãïŒâæ ž29ïŒ åã³é«çŽæ žããªããšãã«
âããªã¡ãã¬ã³âããªã€ãœã·ã¢ããŒã13ïŒ ã®æ··å
ç©69ïœãæ®çããã
å®æœäŸ ïŒ
ã¢ããªã³93éšãã«ã«ãããé
žãšãã«ãšã¹ãã«
450éšãé ¢é žéïŒïŒ0.9éšåã³ã¡ã¿ããŒã«95éšãš
äžç·ã«ïŒæé175âã180âã«å ç±ãããã®å Žåå
å¿å®¹åšã®å§å調ç¯åŒãä»ããŠå§åãïŒãïŒããŒã«
ã«èª¿ç¯ãããåå¿ã®éã«çæããã¢ã³ã¢ãã¢ãæ¯
æåå¿æ··åç©ïŒåœãçªçŽ ã¬ã¹15ãé£è¡å€ãšã
ãŠäœ¿çšããªããé£ç¶çã«çå»ãããåå¿ã®çµçµ
åŸãéåå¿ã¢ããªã³ãéå°ã®ã¡ã¿ããŒã«åã³éå°
ã®ã«ã«ãããé žãšãã«ãšã¹ãã«ãçŽ20ããªããŒã«
ã§çå»ãã109âã113âåã³0.1ããªããŒã«ã§èž
çããããšã«ãã€ãŠïŒ®âããšãã«ã¡ãã«ãŠã¬ã¿ã³
133éšïŒåå¿ããã¢ããªã³ã«å¯ŸããŠçè«å€ã®93.7
ïŒ ïŒãåŸããèžçæ®æ»ã«ã¯ããªãä»ã®ããšãã«ã¡
ãã«ãŠã¬ã¿ã³ãååšãããã¢ããªã³ã®å€æçã¯94
ïŒ ã§ããïŒã¬ã¹ã¯ãããã°ã©ãã€ãŒã«ãã枬å®ïŒã
450éšãé ¢é žéïŒïŒ0.9éšåã³ã¡ã¿ããŒã«95éšãš
äžç·ã«ïŒæé175âã180âã«å ç±ãããã®å Žåå
å¿å®¹åšã®å§å調ç¯åŒãä»ããŠå§åãïŒãïŒããŒã«
ã«èª¿ç¯ãããåå¿ã®éã«çæããã¢ã³ã¢ãã¢ãæ¯
æåå¿æ··åç©ïŒåœãçªçŽ ã¬ã¹15ãé£è¡å€ãšã
ãŠäœ¿çšããªããé£ç¶çã«çå»ãããåå¿ã®çµçµ
åŸãéåå¿ã¢ããªã³ãéå°ã®ã¡ã¿ããŒã«åã³éå°
ã®ã«ã«ãããé žãšãã«ãšã¹ãã«ãçŽ20ããªããŒã«
ã§çå»ãã109âã113âåã³0.1ããªããŒã«ã§èž
çããããšã«ãã€ãŠïŒ®âããšãã«ã¡ãã«ãŠã¬ã¿ã³
133éšïŒåå¿ããã¢ããªã³ã«å¯ŸããŠçè«å€ã®93.7
ïŒ ïŒãåŸããèžçæ®æ»ã«ã¯ããªãä»ã®ããšãã«ã¡
ãã«ãŠã¬ã¿ã³ãååšãããã¢ããªã³ã®å€æçã¯94
ïŒ ã§ããïŒã¬ã¹ã¯ãããã°ã©ãã€ãŒã«ãã枬å®ïŒã
ããããŠåŸãããããšãã«ã¡ãã«ãŠã¬ã¿ã³ãæ¹
æåå¿åšäžã§ãžã¢ã»ããã·ã¡ã¿ã³58éšããããã
ã³ãŸãŒã«106éšåã³ã¬ã¯ãããïŒLewatitïŒSPC
â108 44éšãšäžç·ã«æ¹æäžã§100âã«å ç±ããã
ã€ïŒæéãã®æž©åºŠã§æ¹æãããåå¿ã®çµçµåŸã觊
åªãåé¢ããæžå§äžã§ããããã³ãŸãŒã«åã³éå
å¿åæç©è³ªãçå»ãããé«å§æ¶²äœã¯ãããã°ã©ã
ã€ãŒåæã«å¿ããŠãžâïŒã¡ããã·ã«ã«ããã«ã¢ã
ãïŒâãžããšãã«ã¡ã¿ã³76ïŒ ãïŒâæ ž16ïŒ åã³é«
çŽæ žããªã¡ãã¬ã³âããªããšãã«ãŠã¬ã¿ã³ïŒïŒ
ïŒç²è£œMDUïŒãããªãèžçæ®æ»125éšãåŸãã
ãã
æåå¿åšäžã§ãžã¢ã»ããã·ã¡ã¿ã³58éšããããã
ã³ãŸãŒã«106éšåã³ã¬ã¯ãããïŒLewatitïŒSPC
â108 44éšãšäžç·ã«æ¹æäžã§100âã«å ç±ããã
ã€ïŒæéãã®æž©åºŠã§æ¹æãããåå¿ã®çµçµåŸã觊
åªãåé¢ããæžå§äžã§ããããã³ãŸãŒã«åã³éå
å¿åæç©è³ªãçå»ãããé«å§æ¶²äœã¯ãããã°ã©ã
ã€ãŒåæã«å¿ããŠãžâïŒã¡ããã·ã«ã«ããã«ã¢ã
ãïŒâãžããšãã«ã¡ã¿ã³76ïŒ ãïŒâæ ž16ïŒ åã³é«
çŽæ žããªã¡ãã¬ã³âããªããšãã«ãŠã¬ã¿ã³ïŒïŒ
ïŒç²è£œMDUïŒãããªãèžçæ®æ»125éšãåŸãã
ãã
ããããŠåŸãããç²è£œMDU125ïœããã·ã«ã
ã³ãŸãŒã«375ïœã«æº¶è§£ãããããæ¯æåå¿æ··åç©
ïŒåœã320ïœã®äŸçµŠé床ã§äºéå±ã§å å¡«ããã
310âã«å ç±ããç³è±ã¬ã©ã¹ãããªã管ç¶åå¿åš
äžã«ãã³ãäœçšã§æ¬å ¥ãããå解ã®éã«çæãã
ã¡ã¿ããŒã«ãã¬ã¹ç¶ã§åé¢ãããã©ã€ã¢ã€ã¹ã§å·
åŽããååšäžã§åçž®ããããåå¿æ··åç©427ïœã
åŸããã®æ··åç©ãã85âã90âåã³0.1ã0.2ããª
ããŒã«ã§å解溶å€ãã·ã«ãã³ãŸãŒã«ãçå»ããã
ãžããšãã«ã¡ã¿ã³âãžã€ãœã·ã¢ããŒã78ïŒ ãïŒâ
æ ž17ïŒ åã³é«çŽæ žããªããšãã«âããªã¡ãã¬ã³â
ããªã€ãœã·ã¢ããŒãïŒïŒ ã®æ··åç©102ïœãæ®çã
ãã
ã³ãŸãŒã«375ïœã«æº¶è§£ãããããæ¯æåå¿æ··åç©
ïŒåœã320ïœã®äŸçµŠé床ã§äºéå±ã§å å¡«ããã
310âã«å ç±ããç³è±ã¬ã©ã¹ãããªã管ç¶åå¿åš
äžã«ãã³ãäœçšã§æ¬å ¥ãããå解ã®éã«çæãã
ã¡ã¿ããŒã«ãã¬ã¹ç¶ã§åé¢ãããã©ã€ã¢ã€ã¹ã§å·
åŽããååšäžã§åçž®ããããåå¿æ··åç©427ïœã
åŸããã®æ··åç©ãã85âã90âåã³0.1ã0.2ããª
ããŒã«ã§å解溶å€ãã·ã«ãã³ãŸãŒã«ãçå»ããã
ãžããšãã«ã¡ã¿ã³âãžã€ãœã·ã¢ããŒã78ïŒ ãïŒâ
æ ž17ïŒ åã³é«çŽæ žããªããšãã«âããªã¡ãã¬ã³â
ããªã€ãœã·ã¢ããŒãïŒïŒ ã®æ··åç©102ïœãæ®çã
ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ãžããšãã«ã¡ã¿ã³âãžã€ãœã·ã¢ããŒããšããª
ããšãã«âããªã¡ãã¬ã³âããªã€ãœã·ã¢ããŒããš
ãããªãæ··åç©ã補é ããã«åœãã  ã¢ããªã³ãšãâã¢ã«ãã«ã«ã«ãããé žãšã¹
ãã«åã³å Žåã«ãã€ãŠã¯å°¿çŽ åã³ã¢ã«ã³ãŒã«ãš
ãã觊åªã®ååšäžã§ãåã¯è§Šåªã®äžåšäžã§åå¿
ãããŠïŒ®âããšãã«ãŠã¬ã¿ã³ã«ãããã®éã«ç
æãããã¢ã³ã¢ãã¢ãå Žåã«ãã€ãŠã¯åé¢ãã  åŸãããâããšãã«ãŠã¬ã¿ã³ããã«ã ã¢ã«
ãããåã¯åŒïŒ âCH2â ãåŒäžãã¯ROâãRSâåã¯ROCOåºãè¡š
ãããã¯ã¢ã«ãã«åºãè¡šãããã§ç€ºãããäº
å®èœååç©ãšãé žåã¯ã«ã«ãã³é žã®ååšäžã§çž®
åããŠã¡ãã¬ã³âãã¹âããšãã«ãŠã¬ã¿ã³ãšã
ãªã¡ãã¬ã³âããªããšãã«ãŠã¬ã¿ã³ãšãããªã
æ··åç©ã«ãã  ã¡ãã¬ã³âãã¹âããšãã«ãŠã¬ã¿ã³ãšããªã¡
ãã¬ã³âããªããšãã«ãŠã¬ã¿ã³ãšãããªãæ··å
ç©ããå Žåã«ãã€ãŠã¯è§Šåªã®ååšäžã§ã175â
ã600âã®æž©åºŠã§ç±å解ããããšã«ãã€ãŠãžã
ãšãã«ã¡ã¿ã³âãžã€ãœã·ã¢ããŒããšããªããšã
ã«âããªã¡ãã¬ã³âããªã€ãœã·ã¢ããŒããšãã
ãªãæ··åç©ã«å€ããããšãç¹åŸŽãšããããžããš
ãã«ã¡ã¿ã³âãžã€ãœã·ã¢ããŒããšããªããšãã«
âããªã¡ãã¬ã³âããªã€ãœã·ã¢ããŒããšãããª
ãæ··åç©ã®è£œé æ³ã ïŒ ïŒ®âããšãã«ãŠã¬ã¿ã³(A)ãåšæåŸã®ç¬¬ïŒ¡æ
第æã第æã第æã第æã第
æã第æã第æã第æã第
æã第æã第æãåã³ç¬¬ïŒ¢æã®çŸ€ãã
ã®éå±ã®ïŒå以äžã®ã«ããªã³ãæãã觊åªãšããŠ
ã®å°ãªããšãïŒã€ã®ååç©ã®ååšäžã§è£œé ããã
ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®è£œé æ³ã ïŒ ïŒ®âããšãã«ãŠã¬ã¿ã³(A)ã補é ããããã«åº
çºæåãã¢ããªã³å¯ŸïŒ¯âã¢ã«ãã«ã«ã«ãããé žãš
ã¹ãã«å¯Ÿã¢ã«ã³ãŒã«ã®æ¯çãïŒïŒ0.5ã20ïŒïŒã
100ã§ãããããªéã§åå¿ããããç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒé åã¯ç¬¬ïŒé ã«èšèŒã®è£œé æ³ã ïŒ ïŒ®âããšãã«ãŠã¬ã¿ã³(A)ã補é ããããã«ïŒ¯
âã¢ã«ãã«ã«ã«ãããé žãšã¹ãã«ã®ä»ã«ä»å çã«
ã¢ããªã³ã«å¯ŸããŠæé«1.5åœéã®å°¿çŽ ãåã³ã¢ã«
ã³ãŒã«ãå ±çšãããã®éã«å°¿çŽ 察ã¢ã«ã³ãŒã«ã®æ¯
çã¯åäžã§ããããããã¯ïŒãããå°ãããç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé ä¹è³ç¬¬ïŒé ã®ããããã«èšèŒã®
補é æ³ã ïŒ ïŒ®âããšãã«ãŠã¬ã¿ã³ãïŒå·¥çšã§ãã«ã ã¢ã«
ãããããã«ã ã¢ã«ãããè±é¢ååç©ãåŒïŒCH2
ïŒORïŒ2ã®ã¢ã»ã¿ãŒã«åã¯åŒïŒCH2ïŒOCORïŒ2ã®ã¢
ã·ã©ãŒã«ïŒäœããã¯ã¢ã«ãã«åºãè¡šããïŒãšã
ïŒæªæºã®pkså€ãæããé žåã¯ã«ã«ãã³é žã®ååš
äžã«50âã150âã®æž©åºŠã§çž®åããŠã¡ãã¬ã³âã
ã¹âããšãã«ãŠã¬ã¿ã³ãšããªã¡ãã¬ã³âããªããš
ãã«ãŠã¬ã¿ã³ãšãããªãæ··åç©(B)ã«ãããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®è£œé æ³ã ïŒ ïŒ®âããšãã«ãŠã¬ã¿ã³ã«å¯Ÿãã(B)ã®çž®åã®ã
ãã«é žãšããŠç¡«é žãã¡ã¿ã³ã¹ã«ãã³é žãããªãã«
ãªã«ã¡ã¿ã³ã¹ã«ãã³é žåã¯åŒ·é žã®ææ©ã«ããªã³äº€
æäœåã³ã«ã«ãã³é žãšããŠè»é žãèé žããžã¯ãã«
é ¢é žãããªã¯ãã«é ¢é žåã¯ããªãã«ãªã«é ¢é žã䜿
çšãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé åã¯ç¬¬ïŒé ã«èšèŒ
ã®è£œé æ³ã ïŒ ã¡ãã¬ã³âãã¹âããšãã«ãŠã¬ã¿ã³ãšããªã¡
ãã¬ã³âããªããšãã«ãŠã¬ã¿ã³ãšãããªãæ··åç©
ã溶å€ã®æ¶²çžäžã§175âã350âã®æž©åºŠã§è§Šåªãšã
ãŠã®äžåäžçžäžã«ååšããäžé£ã®äºéãã¢ã«ãã
ãŠã ããã¿ã³ãéãã¯ãã ãã³ãã«ãåã³ããã±
ã«ããã®éå±ã®ååšäžã«ç±å解ãããç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé èšèŒã®è£œé æ³ã ïŒ æ¶²çžäžã§ç±å解ããããã«ïŒïŒ4â²âãžããšã
ã«ã¡ã¿ã³âãžã€ãœã·ã¢ããŒãã®æ²žç¹ãšè±é¢ããã¢
ã«ã³ãŒã«ã®æ²žç¹ãšã®éã«æ²žç¹ãååšãã溶å€ã䜿
çšãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®è£œé æ³ã ïŒ è§ŠåªãšããŠäžåäžçžäžã«è¡šé¢å¯æã®åœ¢ã§ååš
ããã¢ã«ãããŠã åã¯äºéã䜿çšãããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé åã¯ç¬¬ïŒé ã«èšèŒã®è£œé æ³ã ïŒïŒ ã¡ãã¬ã³âãã¹âããšãã«ãŠã¬ã¿ã³ãšããª
ã¡ãã¬ã³âããªããšãã«ãŠã¬ã¿ã³ãšãããªãæ··å
ç©ã液çžäžã§ç±å解ããåŸããããžããšãã«ã¡ã¿
ã³âãžã€ãœã·ã¢ããŒãã®äžéšã溶å€ãšäžç·ã«çå»
ããã€åŸªç°ããŠåçå¡ã«æ»ãããžããšãã«ã¡ã¿ã³
âãžã€ãœã·ã¢ããŒãã®æ®åãšããªããšãã«âããª
ã¡ãã¬ã³âããªã€ãœã·ã¢ããŒããšãããªãæ··åç©
ãå¡åºçåãšããŠåãåºããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é åã¯ç¬¬ïŒé ã«èšèŒã®è£œé æ³ã
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19792942542 DE2942542A1 (de) | 1979-10-20 | 1979-10-20 | Verfahen zur herstellung von mischungen aus diphenyl-methan-diisocyanaten und polyphenyl-polymethylen-polyisocyananten |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5665856A JPS5665856A (en) | 1981-06-03 |
| JPS6342616B2 true JPS6342616B2 (ja) | 1988-08-24 |
Family
ID=6084021
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13998580A Granted JPS5665856A (en) | 1979-10-20 | 1980-10-08 | Manufacture of mixture of diphenylmethanee diisocyanate and polyphenyllpolymethylenee polyisocyanate |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4349484A (ja) |
| EP (1) | EP0028337B1 (ja) |
| JP (1) | JPS5665856A (ja) |
| DE (2) | DE2942542A1 (ja) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5679657A (en) * | 1979-12-04 | 1981-06-30 | Mitsui Toatsu Chem Inc | Novel preparation of polyisocyanate |
| JPS5721356A (en) * | 1980-07-11 | 1982-02-04 | Mitsui Toatsu Chem Inc | Production of aromatic polyisocyanate |
| JPS59172451A (ja) * | 1983-03-18 | 1984-09-29 | Asahi Chem Ind Co Ltd | ããªã€ãœã·ã¢ãâãé¡ã®è£œé æ¹æ³ |
| US5171468A (en) * | 1988-03-10 | 1992-12-15 | Mitsui Toatsu Chemicals, Incorporated | Aromatic polyisocyanate |
| JPH04100415U (ja) * | 1991-01-31 | 1992-08-31 | ||
| CN101962348A (zh) * | 2009-07-23 | 2011-02-02 | äžåœç§åŠé¢å °å·ååŠç©çç 究æ | äžç§æ¶²çžçè£è§£å¶å€åŒæ°°é žé ¯çæ¹æ³ |
| KR101348229B1 (ko) | 2011-12-14 | 2014-01-08 | 겜í¬ëíêµ ì°ííë ¥ëš | ì§ë°©ì¡± ëìŽìììë€ìŽížì ì ì¡°ë°©ë² |
| US11406964B2 (en) * | 2018-03-28 | 2022-08-09 | Covestro Intellectual Property Gmbh & Co. Kg | Heterogeneous catalysts for the synthesis of carbamates |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2806051A (en) * | 1955-11-01 | 1957-09-10 | Goodrich Co B F | Method for preparing urethanes by reacting urea, amines and an alcohol |
| US4014914A (en) * | 1970-01-12 | 1977-03-29 | Badische Anilin- & Soda-Fabrik Aktiengesellschaft | Manufacture of 4,4'-diphenylmethane diisocyanate and a mixture of diisocyanates and polyisocyanates |
| US4118410A (en) * | 1971-02-04 | 1978-10-03 | Gottfried Reuter Gmbh I.L. | Polyphenyl-polymethylene-polyisocyanate mixtures |
| GB1398975A (en) * | 1971-08-16 | 1975-06-25 | Ici Ltd | Heat treatment and distillation of methylene bridged polyphenyl polyisocyanates |
| DE2356828C2 (de) * | 1973-11-14 | 1982-10-21 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Polyaminen und ihre Verwendung als Ausgangsmaterial zur Herstellung von Polyisocyanaten |
| GB1483957A (en) * | 1975-05-19 | 1977-08-24 | Ici Ltd | Diphenylmethane diisocyanate compositions |
| CA1121374A (en) * | 1979-04-30 | 1982-04-06 | Franz Merger | Process for the preparation of an aryl mono-, di-, and/or polyurethane |
| US4375000A (en) * | 1979-04-30 | 1983-02-22 | Basf Aktiengesellschaft | Process for the preparation of an aryl mono-, di-, and/or polyurethane |
-
1979
- 1979-10-20 DE DE19792942542 patent/DE2942542A1/de not_active Withdrawn
-
1980
- 1980-10-08 JP JP13998580A patent/JPS5665856A/ja active Granted
- 1980-10-16 DE DE8080106297T patent/DE3070173D1/de not_active Expired
- 1980-10-16 EP EP80106297A patent/EP0028337B1/de not_active Expired
- 1980-10-17 US US06/197,890 patent/US4349484A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE2942542A1 (de) | 1981-05-07 |
| EP0028337A3 (en) | 1981-08-26 |
| US4349484A (en) | 1982-09-14 |
| EP0028337A2 (de) | 1981-05-13 |
| DE3070173D1 (en) | 1985-03-28 |
| JPS5665856A (en) | 1981-06-03 |
| EP0028337B1 (de) | 1985-02-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS6317820B2 (ja) | ||
| EP0566925B1 (de) | Mehrstufiges Verfahren zur kontinuierlichen Herstellung von organischen Polyisocyanaten | |
| JPH0574584B2 (ja) | ||
| JPH0439456B2 (ja) | ||
| JPH02290840A (ja) | ã«ã«ããã³é žãšã¹ãã«ã®è£œæ³ | |
| US6410778B2 (en) | Method of producing organic diurethanes and/or polyurethanes and their use in the production of di and/or polyisocyanates | |
| JPS6342616B2 (ja) | ||
| JPH0246576B2 (ja) | ||
| JP2005068146A (ja) | èç°åŒãžã€ãœã·ã¢ããŒããé£ç¶çã«è£œé ããå€æ®µæ³ | |
| DE3327824A1 (de) | Verfahren zur herstellung von n,o-substituierten mono- und/oder polyurethanen | |
| EP0088223B1 (en) | Manufacture of isocyanates | |
| JPH0246575B2 (ja) | ||
| US5679825A (en) | Process for the production of aryl carbonates | |
| JPH0925262A (ja) | è³éŠæãŠã¬ã¿ã³ã®è£œé æ¹æ³ | |
| US6222065B1 (en) | Process for the production of 1,5-naphtylenediisocyanate | |
| JPS6412266B2 (ja) | ||
| EP0410684B1 (en) | Method of condensing N-phenylcarbamates | |
| EP0048368B1 (de) | Verfahren zur Herstellung von N- und O-substituierten Mono- oder Bis-urethanen | |
| EP0261604B1 (de) | Neue 2-(Alkoximethyl)-pentan-1,5-diisocyanate, - diurethane und dicarbamidsÀurechloride, Verfahren zu ihrer Herstellung und deren Verwendung | |
| JPS59118745A (ja) | ã¢ãã³ã®è£œæ³ | |
| TW201704202A (zh) | 補åèèªæäºç°æ°°é žé ¯ä¹äºæ¥æ³åäžéååææ³ | |
| KR100275793B1 (ko) | ì ë ë-íì° ì칌늬 ìŽë§€ê³ë¥Œ ìŽì©í n,n'-ì¹í ì°ë ìì ì ì¡°ë°©ë² | |
| US4415745A (en) | Process for the preparation of aromatic carbamates and isocyanates | |
| JP2014524892A (ja) | ããªã€ãœã·ã¢ããŒãã®è£œé æ³ | |
| JP2000344730A (ja) | ïŒïŒïŒâãããã¬ã³ãžã€ãœã·ã¢ããŒãã®è£œé æ³ |