JPS6331484B2 - - Google Patents
Info
- Publication number
- JPS6331484B2 JPS6331484B2 JP53160286A JP16028678A JPS6331484B2 JP S6331484 B2 JPS6331484 B2 JP S6331484B2 JP 53160286 A JP53160286 A JP 53160286A JP 16028678 A JP16028678 A JP 16028678A JP S6331484 B2 JPS6331484 B2 JP S6331484B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- benzole
- photopolymerizable
- dichloromethyl
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 claims description 29
- -1 benzole compound Chemical class 0.000 claims description 27
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 15
- 239000012965 benzophenone Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 9
- 125000004772 dichloromethyl group Chemical group [H]C(Cl)(Cl)* 0.000 claims description 9
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 8
- 238000006116 polymerization reaction Methods 0.000 claims description 8
- 230000005855 radiation Effects 0.000 claims description 8
- 150000002894 organic compounds Chemical class 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 4
- 150000008282 halocarbons Chemical class 0.000 claims description 3
- UFJYKWQUTDGGPV-UHFFFAOYSA-N 1,2-bis(dichloromethyl)benzene Chemical compound ClC(Cl)C1=CC=CC=C1C(Cl)Cl UFJYKWQUTDGGPV-UHFFFAOYSA-N 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 239000000463 material Substances 0.000 description 22
- 238000007639 printing Methods 0.000 description 22
- 239000000178 monomer Substances 0.000 description 16
- 239000000243 solution Substances 0.000 description 14
- 239000002966 varnish Substances 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 239000011230 binding agent Substances 0.000 description 12
- 229920001577 copolymer Polymers 0.000 description 12
- 239000012190 activator Substances 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 238000000576 coating method Methods 0.000 description 7
- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 239000000975 dye Substances 0.000 description 6
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
- 229920000058 polyacrylate Polymers 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- VOWDXSFJQOEFSH-UHFFFAOYSA-N 1,4-bis(dichloromethyl)benzene Chemical compound ClC(Cl)C1=CC=C(C(Cl)Cl)C=C1 VOWDXSFJQOEFSH-UHFFFAOYSA-N 0.000 description 4
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 150000008366 benzophenones Chemical class 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 239000000976 ink Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229920006267 polyester film Polymers 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- ISAOCJYIOMOJEB-UHFFFAOYSA-N desyl alcohol Natural products C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000009429 electrical wiring Methods 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229920002120 photoresistant polymer Polymers 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 2
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 2
- AYFZLXIPQYMONU-UHFFFAOYSA-N 1,4-dichloro-2,5-bis(dichloromethyl)benzene Chemical compound ClC(Cl)C1=CC(Cl)=C(C(Cl)Cl)C=C1Cl AYFZLXIPQYMONU-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 244000028419 Styrax benzoin Species 0.000 description 2
- 235000000126 Styrax benzoin Nutrition 0.000 description 2
- 235000008411 Sumatra benzointree Nutrition 0.000 description 2
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 2
- 150000003926 acrylamides Chemical class 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000008365 aromatic ketones Chemical class 0.000 description 2
- 229960002130 benzoin Drugs 0.000 description 2
- 230000008033 biological extinction Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 235000019439 ethyl acetate Nutrition 0.000 description 2
- 239000011152 fibreglass Substances 0.000 description 2
- 235000019382 gum benzoic Nutrition 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 238000007645 offset printing Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 150000002896 organic halogen compounds Chemical class 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 150000003384 small molecules Chemical class 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 150000003673 urethanes Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- OTEKOJQFKOIXMU-UHFFFAOYSA-N 1,4-bis(trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=C(C(Cl)(Cl)Cl)C=C1 OTEKOJQFKOIXMU-UHFFFAOYSA-N 0.000 description 1
- QPYKYDBKQYZEKG-UHFFFAOYSA-N 2,2-dimethylpropane-1,1-diol Chemical compound CC(C)(C)C(O)O QPYKYDBKQYZEKG-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- QUASZQPLPKGIJY-UHFFFAOYSA-N 2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound OCCOCCOCCOCCOC(=O)C=C QUASZQPLPKGIJY-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 description 1
- VTLKLYJOUVMHIY-UHFFFAOYSA-N 3-ethenylpenta-1,3-diene;urea Chemical compound NC(N)=O.CC=C(C=C)C=C VTLKLYJOUVMHIY-UHFFFAOYSA-N 0.000 description 1
- MWKAGZWJHCTVJY-UHFFFAOYSA-N 3-hydroxyoctadecan-2-one Chemical compound CCCCCCCCCCCCCCCC(O)C(C)=O MWKAGZWJHCTVJY-UHFFFAOYSA-N 0.000 description 1
- DLYLVPHSKJVGLG-UHFFFAOYSA-N 4-(cyclohexylmethyl)cyclohexane-1,1-diamine Chemical compound C1CC(N)(N)CCC1CC1CCCCC1 DLYLVPHSKJVGLG-UHFFFAOYSA-N 0.000 description 1
- BGNGWHSBYQYVRX-UHFFFAOYSA-N 4-(dimethylamino)benzaldehyde Chemical compound CN(C)C1=CC=C(C=O)C=C1 BGNGWHSBYQYVRX-UHFFFAOYSA-N 0.000 description 1
- CAHQGWAXKLQREW-UHFFFAOYSA-N Benzal chloride Chemical compound ClC(Cl)C1=CC=CC=C1 CAHQGWAXKLQREW-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- FRPHFZCDPYBUAU-UHFFFAOYSA-N Bromocresolgreen Chemical compound CC1=C(Br)C(O)=C(Br)C=C1C1(C=2C(=C(Br)C(O)=C(Br)C=2)C)C2=CC=CC=C2S(=O)(=O)O1 FRPHFZCDPYBUAU-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- UBUCNCOMADRQHX-UHFFFAOYSA-N N-Nitrosodiphenylamine Chemical compound C=1C=CC=CC=1N(N=O)C1=CC=CC=C1 UBUCNCOMADRQHX-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- YCZVNBQAIZENBU-UHFFFAOYSA-N NC(=O)N.C(=C)C=CC=C Chemical compound NC(=O)N.C(=C)C=CC=C YCZVNBQAIZENBU-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 102000006463 Talin Human genes 0.000 description 1
- 108010083809 Talin Proteins 0.000 description 1
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 235000005811 Viola adunca Nutrition 0.000 description 1
- 240000009038 Viola odorata Species 0.000 description 1
- 235000013487 Viola odorata Nutrition 0.000 description 1
- 235000002254 Viola papilionacea Nutrition 0.000 description 1
- 244000172533 Viola sororia Species 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 150000003934 aromatic aldehydes Chemical class 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical compound [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- KNMYFELONYRSHT-UHFFFAOYSA-N bis[4-(bromomethyl)phenyl]methanone Chemical compound C1=CC(CBr)=CC=C1C(=O)C1=CC=C(CBr)C=C1 KNMYFELONYRSHT-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- JXCHMDATRWUOAP-UHFFFAOYSA-N diisocyanatomethylbenzene Chemical compound O=C=NC(N=C=O)C1=CC=CC=C1 JXCHMDATRWUOAP-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002168 ethanoic acid esters Chemical class 0.000 description 1
- ZIOLTJBZBPZMDC-UHFFFAOYSA-N ethanol;propan-1-ol;hydrate Chemical compound O.CCO.CCCO ZIOLTJBZBPZMDC-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000007644 letterpress printing Methods 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 229910001511 metal iodide Inorganic materials 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- STZCRXQWRGQSJD-GEEYTBSJSA-M methyl orange Chemical compound [Na+].C1=CC(N(C)C)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-GEEYTBSJSA-M 0.000 description 1
- 229940012189 methyl orange Drugs 0.000 description 1
- LXCJGJYAOVCKLO-UHFFFAOYSA-N n-cyclohexyl-n-hydroxynitrous amide Chemical compound O=NN(O)C1CCCCC1 LXCJGJYAOVCKLO-UHFFFAOYSA-N 0.000 description 1
- VXLFYNFOITWQPM-UHFFFAOYSA-N n-phenyl-4-phenyldiazenylaniline Chemical compound C=1C=C(N=NC=2C=CC=CC=2)C=CC=1NC1=CC=CC=C1 VXLFYNFOITWQPM-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000008055 phosphate buffer solution Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000002491 polymer binding agent Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004250 tert-Butylhydroquinone Substances 0.000 description 1
- 235000019281 tert-butylhydroquinone Nutrition 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- OACSUWPJZKGHHK-UHFFFAOYSA-N tribenzyl phosphate Chemical compound C=1C=CC=CC=1COP(OCC=1C=CC=CC=1)(=O)OCC1=CC=CC=C1 OACSUWPJZKGHHK-UHFFFAOYSA-N 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
- G03F7/0295—Photolytic halogen compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/031—Organic compounds not covered by group G03F7/029
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
æ¬çºæã¯ãååŠç·ã«ããç
§å°ã«éããŠæ¹è¯ãã
ã硬床ãéæããããã«ãå éå§å€ã®ã»ãã«ç¹å®
ã®ææ©ããã²ã³ååç©ãå«æãããå°ãªããšãïŒ
çš®ã®å éåå¯èœãªãªã¬ãã€ã³æ§äžé£œåææ©ååç©
ãå«æããå éåå¯èœãªçµæç©ã«é¢ããããã®çµ
æç©ã¯å éåå¯èœãªè¢«èŠææåã³èšé²ææãšããŠ
çšããããå°å·æ¿ãæå æ§ã¯ãã¹è»¢åãã€ã«ã å
ã³éäžå«ã®æå æ§éåäœåç補ççšãã€ã«ã ã®è£œ
é ã®ããã®ææãšããŠç¹ã«é©ããã åèšäœ¿çšç®çã®ããå éåå¯èœãªè¢«èŠææåã³
èšé²ææèªäœã¯æ¢ç¥ã§ãã€ãŠã玫å€ç·ç §å°ã«ãã
ææã®ç¡¬åºŠæ¹åçšã®ååç©ã®å€æ°ã®çµåãããã§
ã«æç®ã«èšèŒãããŠããã宀枩ã§åºäœã®æ¢ç¥ã®è¢«
èŠææåã³èšé²ææã«ãããŠãã°ãã°çããæ¬ ç¹
ã¯ãååŠç·ç §å°ã«ããèªèµ·ãããéåã®é床ãã
ç¹ã«ææã®éæ§åã¯ç²æ§ãé«ããšãã«åå¿ã®çµäº
æã«èããäœäžãããããŠæ®éã®ç §å°æéã«ãã
ãŠã¯ååšãããªã¬ãã€ã³æ§äžé£œåçµåã®å®éäžå®
å šãªéååã¯æ¶æ©ãéæãããªãããšã§ãããã
ããã€ãŠå®éäžã¯ãç¹ã«ç»åã«ããç §å°ã®ã®ã¡ã«
éç §å°éšåã溶å€ã«ããæŽåºããå Žåã«åã¯å é
åã®çšåºŠã«ãã€ãŠè¡šé¢ç²çæ§åã¯å¹³ããåºäœãžã®
æ¥çå€ãå€ããå Žåã«ã¯ããã®çš®ã®è¢«èŠææåã¯
èšé²ææãé·æéç §å°ããã°ãªããªãã ãã€ãç¹èš±åºé¡å ¬é1947194å·ãç±³åœç¹èš±
4040923å·åã³å4043887å·åæ现æžã«ããã°ãå
éåå¯èœãªååç©ã®ããã®å éå§å€ãšããŠãè³éŠ
æç°ã«å¡©çŽ åãããã¯èçŽ åãããã¡ãã«åºãæ
ãããã³ãŸããšãã³èªå°äœãããšãã°ïŒâã¯ãã«
ã¡ãã«ãã³ãŸããšãã³ãïŒïŒïŒâãããã¯ïŒïŒ
4â²âãã¹âïŒã¯ãã«ã¡ãã«ïŒâãã³ãŸããšãã³åã¯
ïŒïŒ4â²âãã¹âïŒããã ã¡ãã«ïŒâãã³ãŸããšãã³
ãçšããããšãå ¬ç¥ã§ãããããããã®ç³»ã®æå
æ§ã¯ãªãäžæºè¶³ã§ãããããã«æŽ»æ§åå€ã«å¯Ÿãã
å éå§å€ã®æ¯çãå€æŽã§ããªãããšãæ¬ ç¹ã§ã
ãããã€ãç¹èš±åºé¡å ¬é2404156å·ãç±³åœç¹èš±
3933682å·ãå3966573å·åã³ãã«ã®ãŒç¹èš±853935
å·åæ现æžã«ããã°ãå éå§å€ç³»ãšããŠã(a)ã¢ã·
ãã€ã³åã¯è³éŠæã±ãã³ãã(b)ããAsãBi
åã¯Sbãå«æããååç©äŸãã°ã¢ãã³ããã¹ã
ã€ã³åã¯ã¢ã«ã·ã³ãªãã³ã«(c)ããã²ã³åãããè
èªæãèç°æåã¯è³éŠæã®çåæ°ŽçŽ ãçµåããã
ã®ã䜿çšããããšãç¥ãããŠãããããããã®ç³»
ãå«ãèšé²ææã®è²¯èµå®å®æ§ã¯å€ãã®å Žåã«äžæº
足ã§ããããããã¢ãã³ã®ãããªå¡©åºæ§ã®ååç©
(b)ã®äœ¿çšã«éããŠã¯ãæ®éã«æ·»å ãããæææ瀺
è¬ã®å€è²ã«ãããç §å°ãããç»åãšéç §å°ã®ç»å
ãšã®äžè¬æ§è³ªãåºå¥ããããšãå€ãã®å Žåã«äžå¯
èœã§ããã æ¬çºæã®èª²é¡ã¯ãå éåå¯èœãªãªã¬ãã€ã³æ§äž
飜åã®ææ©ååç©ãå«ããç¹ã«å®€æž©ã§åºäœã®å é
åå¯èœãªçµæç©ã®ããã«ãéåžžã®ç §å°æéã§æ¹è¯
ããã硬åã®éæãå¯èœã§ããããã€æº¶å€ã«ãã
éç §å°éšåã®æŽåºã®éã®é©æ£ãªæŽåºæéã«é¢ã
ãŠãããå¶éã®ãªãæäœãéåžžã®ç §å°æéã®é©çš
ã«ãã€ãŠãå¯èœã§ããããããŠåèšæ¢ç¥ã®ç³»ã®æ¬
ç¹ãã»ãšãã©ãªããåã¯å šããªãå éå§å€â掻æ§
å€ç³»ãèŠåºãããšã§ãã€ãã æ¬çºæè ãã¯ãå éå§å€ç³»ãããã²ã³åçåæ°Ž
çŽ ãšããŠããã³ãŸãŒã«æ žã«çµåããïŒå以äžã®ãž
ã¯ãã«ã¡ãã«åºãæãããã³ãŸãŒã«ååç©ãå«æ
ãããšããåžæããæ¹è¯ãéæãããããšãèŠåº
ããã æ¬çºæã¯ãå°ãªããšãïŒçš®ã®å éåå¯èœãªãªã¬
ãã€ã³æ§äžé£œåææ©ååç©ããªãã³ã«æŽ»æ§åãã
ãå éå§å€ç³»ãšããŠ(a)ååŠç·ã®ç §å°ã«éãéåã
éå§ããã©ãžã«ã«ã圢æããå°ãªããšãïŒçš®ã®è³
éŠæã«ã«ããã«ååç©åã³(b)ãã³ãŸãŒã«æ žã«çµå
ããïŒå以äžã®ãžã¯ãã«ã¡ãã«åºãæãããã³ãŸ
ãŒã«ååç©ãå«æããããšãç¹åŸŽãšãããå éå
å¯èœãªçµæç©ã§ããã æ¬çºæã®çµæç©ã¯ãé žã®æ·»å ã«éããŠãã®è²ã
å€åããæ瀺è¬ææãè¿œå çã«å«æããããšã奜
ãŸããã æ¬çºæã«ãããŠæŽ»æ§åãããå éå§å€ç³»äžã«å«
æãããããã³ãŸãŒã«æ žã«çµåããå°ãªããšãïŒ
åã®ãžã¯ãã«ã¡ãã«åºïŒâCHCl2ïŒãæãããã³
ãŸãŒã«ååç©ãšããŠã¯ãæ¬¡åŒ ã§è¡šããããååç©ãçšããããããã®åŒäžã®çœ®
æåºR1ãR6ã¯åäžã§ãç°ãªã€ãŠãããããã®ã
ã¡å°ãªããšãïŒåã®çœ®æåºã¯âCHCl2ã§ãããæ®
ãã®åºã¯åäžã§ãç°ãªã€ãŠãããä»»æã«éžã°ãã
ãã ããã®åºã¯ãžã¯ãã«ã¡ãã«åºã«å¯ŸããŠäžæŽ»æ§
ã«æåããå éåã劚ãããã€ååŠç·ã®ç¯å²ã§åŒ·
ãåžåã瀺ãããããªãã¡10åã®åžå ä¿æ°ã¯å¥œãŸ
ããã¯Î»ïŒ315ã400nmã®ç¯å²ã«ãããŠ20ããªãã
ã«ã»ã¢ã«-1ã»cm-1ãããå°ã§ããããšãåæãšã
ãã奜ãŸããã¯æ®ãã®åºãšããŠäžèšã®ãã®ããã
ããããæ°ŽçŽ ååãããã²ã³ååç¹ã«å¡©çŽ ååã
C1ãC10âçåæ°ŽçŽ æ®åºãããã²ã³åãããC1ã
C10ã¢ã«ãã«åºåã¯å Žåã«ããããã²ã³åããã
C1ãC10âã¢ã«ã³ãã·åºããžã¯ãã«ã¡ãã«åºãæ
ãã奜é©ãªãã³ãŸãŒã«ååç©ãšããŠã¯ããã¹â
ïŒãžã¯ãã«ã¡ãã«ïŒâãã³ãŸãŒã«ãäŸãã°ïŒïŒïŒâ
ãã¹ïŒãžã¯ãã«ã¡ãã«ïŒâãã³ãŸãŒã«åã³ïŒïŒïŒ
âãžã¯ãã«âïŒïŒïŒâãã¹ïŒãžã¯ãã«ã¡ãã«ïŒâ
ãã³ãŸãŒã«ããããããã ãžã¯ãã«ã¡ãã«ãã³ãŸãŒã«ååç©ã®æ·»å éã¯ã
äžè¬ã«å éåéå§å€(a)ã®ïŒéééšã«å¯Ÿã掻æ§åå€
(b)0.2ã12éééšã§ãããããã®å Žå掻æ§åå€ã®
æ¿åºŠã¯çµæç©å šéã®0.5ééïŒ ä»¥äžã§ããã ååŠç §å°ç·ã«ããéåéå§æ§ã©ãžã«ã«ãçæã
ãå°ãªããšãïŒçš®ã®è³éŠæã«ã«ããã«ååç©(a)ãš
ããŠã¯ãå éå§å€ãšããŠæ¢ç¥ã®è³éŠæã«ã«ããã«
ååç©äŸãã°è³éŠæã¢ã«ãããåã³è³éŠæã±ãã³
ãçšãããããç¹ã«å ã«ãããç±³åœç¹èš±3933682
å·æ现æžç¬¬ïŒæ¬35è¡ãªãã第ïŒæ¬19è¡åã³ãžãš
ãŒã»ã¯ã€ã¬ã€ç€ŸããŠãŒãšãŒã¯1965幎çºè¡ã®ã³ãŒã¶
ãŒèãã©ã€ãã»ã»ã³ã·ãã€ãã»ã·ã¹ãã ãºã158
ã193é ã«åŒçšããã察å¿ååç©ãåç §ãããã
ããã¯ãã®æ··åç©ãšããŠåã¯ä»ã®å éå§å€ãšçµå
ããŠçšããããšãã§ãããç¹ã«ãå Žåã«ãã眮æ
ããããã³ãŸããšãã³é¡äŸãã°ãã³ãŸããšãã³å
ã³ããã©ãŒã®ã±ãã³ããã³ãŸã€ã³ãšãŒãã«ãäŸã
ã°ãã³ãŸã€ã³âã€ãœãããã«ãšãŒãã«ãαäœã§
C1ãC8âããããã·ã¢ã«ãã«åºãC2ãC8âã¢ã«
ã³ãã·ã¢ã«ãã«åºåã¯C1ãC7âçåæ°ŽçŽ æ®åºã«
ãã眮æããããã³ãŸã€ã³ã®ãšãŒãã«ãäŸãã°Î±
âããããã·ã¡ãã«ãã³ãŸã€ã³âã¡ãã«ãšãŒã
ã«ããã³ãžã«ã±ã¿ãŒã«äŸãã°ãã³ãžã«ã¡ãã«ã±ã¿
ãŒã«ãã¢ã³ãã©ããã³åã³ãã®èªå°äœãããªããµ
ã³ãã³åã³ãã®èªå°äœããªãã³ã«ãã³ãŸããšãã³
èªå°äœäŸãã°ãã³ãŸããšãã³ãšããã©ãŒã®ã±ãã³
ãšã®çµåããæšå¥šããããç¹å®ã®å éå§å€ïŒçµå
ãïŒã®åã ã®é©åæ§ã¯ãæ¬çºæã®æ瀺ãç¥ã€ããª
ãã°ç°¡åãªæåè©Šéšã«ãã容æã«å®ããããã å°ãªããšãïŒçš®ã®å éåå¯èœãªãªã¬ãã€ã³æ§äž
飜åææ©ååç©ãå«æããææãšããŠã¯ã被èã
å°å·æ¿ãããªãã¬ãžã¹ãææãæå æ§ã¯ãã¹è»¢å
ãã€ã«ã ãéäžå«ã®å éåæ§ãã€ã«ã ã®è£œé åã³
é¡äŒŒç®çã®ããã«èšèŒãããŠããèªäœæ¢ç¥ã®å é
åå¯èœãªææãçšããããããã®ææã¯ããªã¬ã
ã€ã³æ§äžé£œåææ©ååç©ãããªã¬ãã€ã³æ§äžé£œå
ã®ïŒ£âäºéçµåãæãããªã¬ãã€ã³æ§äžé£œåã®
åéäœãåæéåäœåã¯éåäœã®åœ¢ã§å«æããã
ãªã¬ãã€ã³æ§äžé£œåååç©ã¯ãå°ãªãšãšãïŒåã®
æ«ç«¯CH2ïŒïŒ£åºãå«æãã倧æ°å§äžã§100â以
äžã®æ²žç¹ã瀺ãããã€å éå§æ§éååå¿ã«ããé
åäœã®çæãå¯èœã§ããããšãå¿ èŠãšããã奜é©
ãªææã¯ãäŸãã°ç±³åœç¹èš±2760863å·ãå3966573
å·ããã€ãç¹èš±åºé¡å ¬å1622297å·ããã€ãç¹èš±
åºé¡å ¬é1522444å·ãå2215090å·åã¯ãã«ã®ãŒç¹
èš±560154å·åæ现æžã«èšèŒãããŠããããã®å Žå
æ¬çºæã®æ瀺ã¯ã硬åïŒç §å°ïŒã®åã«å®€æž©ã§åºäœ
ã§ããããåã¯å éåå¯èœãªãªã¬ãã€ã³æ§äžé£œå
âäºéçµåãçŽ50ïŒ åå¿ããã®ã¡å®€æž©ã§åºäœ
ã®ææã圢æããå éåå¯èœãªææã®ããã«ãã
ãªãã¡ç¡¬åã®çµæã§é«ãéæ§åã¯ç²åºŠã瀺ããã
ãã«ãã€ãŠåå¿ç©è³ªã«å¯Ÿãäœãå¯åæ§ãäžããå
éåå¯èœãªææã®ããã«ç¹ã«æå©ã§ããã åªããçµæç©ã¯ãçµåå€æåãšããŠå éåå¯èœ
ãªåéäœã®ã»ãã«éåçæç©ãå«æããããã®æ
æ©éåäœçµåå€ã¯äœµçšãããåéäœãšäžè¬ã«èŠªå
æ§ã§ããã¹ãã§ããããŠå°é家ã«èªæã§ãããã
ã«ãç»åã«ããç §å°ã®å Žåã«ãå éåå¯èœãªææ
ã®å±€ã®éç §å°ã®æ¶æ©ãããªãéšåãæŽåºããããš
ãå¯èœã«ããããã«ãçŸåçšæº¶å€ã«å¯æº¶åã¯åæ£
å¯èœã§ãªããã°ãªããªãã奜é©ãªéåãããªã¬ã
ã€ã³æ§é£œååã¯äžé£œåã®çµåå€ãšããŠã¯ãç·ç¶ã
ãªã¢ããåã³ç¹ã«ã¢ã«ã³ãŒã«å¯æº¶ãªã³ããªã¢ã
ããäŸãã°ãã©ã³ã¹ç¹èš±1520856å·æ现æžã«èšèŒ
ã®äžèšã®ãã®ãããããããç¹ç¶çŽ èªå°äœç¹ã«æ°Ž
æ§ã¢ã«ã«ãªã«ããæŽåºå¯èœãªç¹ç¶çŽ èªå°äœããã
ã«ã¢ã«ã³ãŒã«éåäœåã³ïŒãïŒåã®ççŽ ååãæ
ããèèªæã¢ãã«ã«ãã³é žã®ããã«ãšã¹ãã«ã®é
åäœåã³å ±éåäœãäŸãã°çš®ã ã®é¹žå床ãæãã
é ¢é žããã«ã®éåäœåã³å ±éåäœãããã«ãããª
ãã³ãå¡©åããã«åã¯ã¹ãããŒã«ã®åç¬éåç©å
ã³å ±éåç©ãããªãŠã¬ã¿ã³ãããªãšãŒãã«ãŠã¬ã¿
ã³ãããªãšã¹ãã«ãŠã¬ã¿ã³ãããªãšã¹ãã«æš¹èã
ã¢ã¯ãªã«é žâåãŒã¡ã¿ã¯ãªã«é žãšã¹ãã«ã®å ±éå
ç©ãäŸãã°ã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãã¢ã¯ãªã«
ã¢ããåã³ïŒåã¯ããããã·ã¢ã«ãã«ã¢ã¯ãªã¬ãŒ
ãåã¯ããããã·ã¢ã«ãã«ã¡ã¿ã¯ãªã¬ãŒããšã¡ã
ã«ã¡ã¿ã¯ãªã¬ãŒããšã®å ±éåäœãåã³ãšã©ã¹ãã
ãŒãžãšã³éåäœåã³âå ±éåäœãäŸãã°ãã¿ãžãš
ã³åã³ïŒåã¯ã€ãœãã¬ã³ã®åç¬åã¯å ±éåäœãã
ãã¯åã³ã¹ãããŒã«åã¯Î±âã¡ãã«ã¹ãããŒã«ã®
éåäœãããã¯ããã®ãããã¯å ±éåäœã å°ãªããšãïŒåã®å éåå¯èœãªãªã¬ãã€ã³æ§äž
飜åäºéçµåãæããäœååååç©ã®ãã¡ã§ã¯ã
ïŒååã¯ãã以äžã®ãªã¬ãã€ã³æ§äžé£œåçµåãæ
ããå éåå¯èœãªäºéçµåãæããåéäœèªäœã
åã¯ãã®åéäœãšãå éåå¯èœãªãªã¬ãã€ã³æ§äž
飜åäºéçµåãïŒåã®ã¿æããåéäœãšã®æ··åç©
ãåªããŠãããçšããããåéäœã®çš®é¡ã¯ã䜿çš
ç®çãšäœµçšãããéåäœçµåå€ã®çš®é¡ã«åºç¯å²ã«
äŸåãããããªãã¡äžé£œåããªãšã¹ãã«æš¹èãšã®
æ··åç©ã®å Žåã¯ãç¹ã«ïŒå以äžã®äºéçµåãæã
ãã¢ãªã«ååç©äŸãã°ãã¬ã€ã³é žãžã¢ã«ãã«ãšã¹
ãã«ãã¢ãªã«ã¢ã¯ãªã¬ãŒãããžã¢ãªã«ãã¿ã¬ãŒ
ããããªã¡ãªããé žã®ãžâåã³ããªã¢ãªã«ãšã¹ã
ã«åã¯ãšãã¬ã³ã°ãªã³ãŒã«ãã¹ã¢ãªã«ã«ãŒãããŒ
ãããªãã³ã«ãžâåã³ããªã¢ã¯ãªã¬ãŒãåã³âã¡
ã¿ã¯ãªã¬ãŒãïŒã¢ã¯ãªã«é žåã¯ã¡ã¿ã¯ãªã«é žãšã®
ãžãªãŒã«åã¯ããªãªãŒã«ã®ãšã¹ãã«åã«ãã補é
ããããã®ïŒãäŸãã°ãšãã¬ã³ã°ãªã³ãŒã«ããžãš
ãã¬ã³ã°ãªã³ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ãçŽ
500ãŸã§ã®ååéãæããããªãšãã¬ã³ã°ãªã³ãŒ
ã«ãïŒïŒïŒâãããã³ãžãªãŒã«ãïŒïŒïŒâããã
ã³ãžãªãŒã«ãããªãã³ãã«ã°ãªã³ãŒã«ïŒïŒïŒïŒâ
ãžã¡ãã«âãããã³ãžãªãŒã«ïŒãïŒïŒïŒâãã¿ã³
ãžãªãŒã«ãïŒïŒïŒïŒïŒâããªã¡ãããŒã«ããã
ã³ãã°ãªã»ãªã³åã¯ãã³ã¿ãšãªããªããã®ãžâå
ã³ããªã¢ã¯ãªã¬ãŒãïŒåã¯ã¡ã¿ã¯ãªã¬ãŒãïŒã奜
é©ã§ãããããã«ãã®çš®ã®ãžãªãŒã«åã³ããªãªãŒ
ã«ã®ã¢ãã¢ã¯ãªã¬ãŒãåã³ã¢ãã¡ã¿ã¯ãªã¬ãŒãã
äŸãã°ãšãã¬ã³ã°ãªã³ãŒã«âåã¯ãžâãããªâã
ããã¯ããã©ãšãã¬ã³ã°ãªã³ãŒã«âã¢ãã¢ã¯ãªã¬
ãŒãããŠã¬ã¿ã³åºåã³ïŒåã¯ã¢ããåºãå«æãã
ïŒå以äžã®ãªã¬ãã€ã³æ§äžé£œåçµåãæããåé
äœãäŸãã°åèšçš®é¡ã®èèªæãžãªãŒã«ãææ©ãžã€
ãœã·ã¢ããŒãåã³ããããã·ã¢ã«ãã«ã¢ã¯ãªã¬ãŒ
ãïŒåã¯ã¡ã¿ã¯ãªã¬ãŒãïŒãã補é ãããäœåå
ååç©ãé©ããããŸãã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é ž
åã³ãã®èªå°äœãäŸãã°ã¢ã¯ãªã«ïŒåã¯ã¡ã¿ã¯ãª
ã«ïŒã¢ãããâããããã·ã¡ãã«ã¢ã¯ãªã«ïŒå
ã¯ã¡ã¿ã¯ãªã«ïŒã¢ããåã¯ïŒãïŒåã®ççŽ ååã
æããã¢ãã¢ã«ã³ãŒã«ã®ã¢ã¯ãªã¬ãŒãåã¯ã¡ã¿ã¯
ãªã¬ãŒããããããããã¢ãªã«åéäœãšãžâåã¯
ããªã¢ã¯ãªã¬ãŒãã®æ··åç©ã¯ç¹ã«é©ããŠãããé
åäœçµåå€ãšããŠã®ããªã¢ãããšã®æ··åç©ãéžæ
ãããªãã°ããžâåã³ããªã¢ã¯ãªã¬ãŒãã®ã»ãå
èšåéäœã®çš®é¡ã®ãã¡ã§ã¯ãäºéçµåã®ã»ããã
ã«ã¢ããåºåã³ïŒåã¯ãŠã¬ã¿ã³åºãå«æããåé
äœãäŸãã°ã¢ã¯ãªã«ã¢ããã®èªå°äœãäŸãã°ãšã
ã¬ã³ã°ãªã³ãŒã«çã®èèªæãžãªãŒã«ïŒã¢ã«ãšïŒ®â
ããããã·ã¡ãã«ã¢ã¯ãªã«ïŒåã¯ã¡ã¿ã¯ãªã«ïŒã¢
ããïŒã¢ã«ãšã®åå¿çæç©ããã·ãªã¬ã³âãã¹â
ã¢ã¯ãªã«ã¢ããã¯ã¢ã«ãã¬ã³åºäžã«ïŒãïŒåã®ç
çŽ ååãæããã¢ã«ãã¬ã³âãã¹âã¢ã¯ãªã«ã¢ã
ããé©ããŠãããéåäœçµåå€ãšããŠããªããã«
ã¢ã«ã³ãŒã«ãçšããŠæ°Žâã¢ã«ã«ãªæ§ã§çŸåå¯èœãª
å°å·æ¿ã補é ããããã«ã¯ãç¹ã«æ°Žã«å¯æº¶ãªåé
äœäŸãã°ããããã·ãšãã«ã¢ã¯ãªã¬ãŒãïŒåã¯ã¡
ã¿ã¯ãªã¬ãŒãïŒåã³çŽ200ãªãã500ã®ååéãæ
ããããªãšãã¬ã³ã°ãªã³ãŒã«ã®ã¢ãâåã³ãžã¢ã¯
ãªã¬ãŒãïŒåã¯ã¡ã¿ã¯ãªã¬ãŒãïŒãé©ããŠããã
éåäœçµåå€ãšããŠã¢ã¯ãªã¬ãŒãåã¯ã¡ã¿ã¯ãªã¬
ãŒãã®å ±éåäœãäŸãã°ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãå ±
éåç©ãçšããŠæå æ§ã¯ãã¹å¡è¢«ãã€ã«ã ïŒããª
ãã¬ãžã¹ã補é çšïŒã補é ããããã«ã¯ãå ã«ã
ãªãšã¹ãã«æš¹èã«é¢é£ããŠããããžâåã³ããªã¢
ã¯ãªã¬ãŒãïŒåã¯ã¡ã¿ã¯ãªã¬ãŒãïŒãé©ããŠã
ãã åéäœãšéåäœçµåå€ã®æ··åç©ã«ãããéæ¯ã¯
åºç¯å²ã«å€åãå¯èœã§ãã€ãŠãäžè¬ã«äž¡è ã®åèš
éã«å¯Ÿãåéäœã10ã55ééïŒ ç¹ã«25ã50éé
ïŒ ããããŠéåäœçµåå€ã45ã90ééïŒ ç¹ã«50ã
75ééïŒ ã§ããã åèšæ¯çã®å éå§å€(a)åã³æŽ»æ§åå€(b)ããã®æŽ»
æ§åå éå§å€ç³»ã®æ·»å éã¯ãå éåå¯èœãªçµæç©
ã®å šééãããªãã¡å šæåéã®åèšã«å¯Ÿããäžè¬
ã«ïŒã25ééïŒ ç¹ã«ïŒã20ééïŒ ã§ãããå éå§
å€ã®äœ¿çšéã¯ããã®åžå ä¿æ°åã³ç¡¬åã®éã®ææ
å±€ã®åãã«äŸåããéåžžã¯çµæç©ã®å šéã«å¯Ÿã
0.5ã10ééïŒ ç¹ã«çŽïŒãïŒééïŒ ã§ããã掻æ§
åå€(b)ã®éã¯ãå šçµæç©ã®0.5ééïŒ ä»¥äžç¹ã«çŽ
ïŒã12ééïŒ ã§ããããããŠææå±€ã®åžæãã硬
åæ§ã«ãã圱é¿ãåãããå€ãã®å Žåã«åäžã®å
éå§å€â掻æ§åå€ã®é åã«ãããŠãããåãææ
å±€ã«ç§»è¡ããå Žåã«ã¯ããã®ããåãææå±€ã«ã
ããŠçŽ«å€ç·ç §å°ã®ãã匷ãåžåãé¿ãããããå
éå§å€ã®æ¿åºŠãäœãããŠãã掻æ§åå€ã®æ¿åºŠãäž
å€ã«ä¿ã€ããšãç¹ã«æå©ã§ããã æ¬çºæã®çµæç©ã¯ãå éåå¯èœãªååç©ãéå
äœçµåå€ãå éå§å€åã³æŽ»æ§åå€ã®ã»ããããã«
æ®éã®éã§æ®éã®æ·»å ç©ãäŸãã°ç¡æ©åã¯ææ©ã®
é¡æåã¯ææãç¡æ©åã¯ææ©ã®å å¡«æãéåæå¶
å€äŸãã°ãã€ããããã³åã¯äžçŽããã«ãã€ãã
ããã³ãç®åŒµãé²æ¢å€äŸãã°ãã©ãã€ã³ãæµåå©
å€äŸãã°ã·ãªã³ãŒã³æ²¹ãã€ãæ¶ãå€åã¯æ»å€äŸã
ã°ã¯ãã¯ã¹ãææ©æº¶å€äŸãã°ã¢ã«ã³ãŒã«ãçåæ°Ž
çŽ åã¯ã±ãã³ãå«æããããšãã§ããã æ¬çºæã®å éåå¯èœãªçµæç©ã¯ãææãšããŠå¥œ
ãŸããã¯é žãæ·»å ãããšãã«è²ãå€ããæ瀺æ
æãäŸãã°3â²âããšãã«âïŒâãžãšãã«ã¢ããâ
ïŒïŒ2â²âã¹ãããžâïŒ2HâïŒâãã³ãŸããã³ïŒã
ããã ã¯ã¬ãŸãŒã«ã°ãªãŒã³åã¯ã¡ãã«ãªã¬ã³ãžã
äžè¬ã«0.05ãïŒééïŒ ã®éã§å«æãããé žãšã¢ã³
ã¢ããŠã å¡©ã圢æããŠæ¿è²åããã¢ããåºãæã
ãªãææããããããŠé©ããŠããã å éåãéå§ãããã2300ã4500â«ã®æ³¢é·ã®å
ç¹ã«3000ã4200â«ã®çºå 極倧ãæããå ãçšãã
ãããç §å°æºãšããŠã¯ãæ°Žéé«å§ç¯ãè¶ ååŠç·çº
å äœç®¡ããã»ãã³âã€ã³ãã«ã¹ç¯ãéå±æ²åç©äŸ
絊ç¯åã³ççŽ åŒ§å ç¯ãé©ããŠããã æ¬çºæã®çµæç©ã¯èªäœæ¢ç¥ã®æ段ã§å¡èã玫å€
ç·ç¡¬åæ§ã®å°åã€ã³ãåã³æºæã®ããæå æ§éå
äœå°å·çãããªãã¬ãžã¹ããæå æ§ã¯ãã¹è»¢åã
ã€ã«ã åã³éäžå«ã®æå æ§éåäœåç補ççšãã€
ã«ã ã«å å·¥ãããã æ¬çºæã®çµæç©äžã«å«æãããããžã¯ãã«ã¡ã
ã«åºãæããç¹æ®ãªãã³ãŸãŒã«ååç©(b)ãã匷å
ãªæŽ»æ§åå¹æãå¥ããåæã«å€ãã®çµåå€åã³å
éäœã«å¯ŸããŠããããŠè¯å¥œãªèŠªåæ§ã瀺ãããã
ãŠæå€ãªã»ã©é«åºŠã«ååŠçã«äžæŽ»æ§ã§ããããš
ã¯ãäŸãã°æ§é äžé¡äŒŒã®å¡©åãã³ã¶ã«ã«æ¯ããŠã
å šãäºæž¬äžå¯èœã§ãã€ãããžã¯ãã«ã¡ãã«åºå«æ
ãã³ãŸãŒã«ååç©(b)ã®ã¡ã¿ããŒã«æº¶æ¶²ã«ãæ°Žãå
ããŠç¡é žéãæ·»å ããããšã«ãããå¡©åéã®æ²æ®¿
ã¯å šãèµ·ãããªãã掻æ§åå€(b)ã¯310nm以äžã§ã»
ãšãã©å åžåã瀺ããªãã®ã§ãããã¯å éå§å€å
ã¯ææã®åžåã劚ããªãã äžèšã®å®æœäŸåã³æ¯èŒäŸäžã®éšåã³ïŒ ã¯ãç¹ã«
æ瀺ããªãéãééã«é¢ããéšã¯å®¹ééšã«å¯ŸããŠ
Kg察ã®é¢ä¿ã«ããã æ¯èŒäŸ ïŒ ã¢ãžãã³é žããããµã¡ãã¬ã³ãžã¢ãã³ãïŒïŒ
4â²âãžã¢ãããžã·ã¯ãããã·ã«ã¡ã¿ã³åã³Îµâã«
ããã©ã¯ã¿ã ã®å ±éçž®åã«ãã補é ãããã¢ã«ã³
ãŒã«å¯æº¶æ§ã®å ±ããªã¢ãã100éšããªãã³ã«ïœâ
ãã·ãªã¬ã³ãã¹ã¢ã¯ãªã«ã¢ãã15éšãããªãšãã¬
ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒã10éšãâã¡ãããŒ
ã«ã¡ã¿ã¯ãªã«ã¡ãã«ãšãŒãã«17éšããã³ãŸã€ã³ã¡
ãã«ãšãŒãã«ïŒéšåã³ïŒ®âããããœã·ã¯ãããã·
ã«ããããã·ã«ã¢ãã³ã®CerïŒïŒå¡©0.1éšããã¡
ã¿ããŒã«300éšã«60âã§æº¶è§£ããããã®ç²çš 溶液
ãããŒã«è£ 眮ã«ãã60ã80âã®æž©åºŠã§ä¹ŸçžããŒã«
åŠçããããã®ããŒã«ã§åŠçããã·ãŒããç ŽçŽ°
ããå§æŸæ©ã«ãã170âã§200KgïŒcm2ã®å§åäžã«å§
æŸããŠå§ã0.8mmã®ç¡è²éæãªæ¿ã«ããããã®æ¿
ãäž¡é¢æ¥çãã€ã«ã ã«ããã¢ã«ãããŠã æ¿äžã«æ¥
çããã ããããŠè£œé ãããå éåæ§æžç±å°å·æ¿ãé»å
åççšè©Šéšé°ç»ïŒ48ç·ïŒcmïŒã«ãããå20Wã®äœ
å§è¢å 管ïŒæ¬ãåããæ®éåžè²©ã®å°å·æ¿âç §å°è£
眮å ã§ãçš®ã ã®ç°ãªãæéã§ç §å°ããã24æéã®
貯èµã®ã®ã¡ãå°å·æ¿ã®éç §å°éšåããããããŒã«
âãšã¿ããŒã«âæ°Žæ··åç©ïŒïŒïŒïŒïŒïŒïŒã«ããã
æŽåºè£ 眮ïŒããã¯ãã³ããšå€æ°ã®åŽå°ããºã«ãã
æããïŒæ°å§ã®å§åãæãã溶å€ãæŽåºãã¹ãæ¿
äžã«åŽå°ããïŒå ã§æŽåºããã10ååŸã«æŽåºå·¥çš
ãäžæããæ°é®®ãªãããããŒã«ã§æ¿ãæŽæµããä»
çãã溶å€ãå§æŸç©ºæ°ã«ããé€å»ãããã¬ãªãŒã
ã«ãããïŒïŒ ã¹ã¯ãªãŒã³èª¿åå€ãå®å šã«åœ¢æãã
ããã«å¿ èŠãªç §å°æéãã第ïŒè¡šã«ç€ºãã å®æœäŸ ïŒ æ¯èŒäŸïŒãšåæ§ã«æäœãããã ãæžç±å°å·æ¿è£œ
é ã®ããã®ç²çš 液ã«ãïŒïŒïŒâãã¹ïŒãžã¯ãã«ã¡
ãã«ïŒâãã³ãŸãŒã«ïŒéšãããã«æ·»å ãããæ¯èŒ
äŸïŒãšåæ§ã«è¡ã€ãç §å°è©Šéšã®çµæã第ïŒè¡šã«ç€º
ãã
ã硬床ãéæããããã«ãå éå§å€ã®ã»ãã«ç¹å®
ã®ææ©ããã²ã³ååç©ãå«æãããå°ãªããšãïŒ
çš®ã®å éåå¯èœãªãªã¬ãã€ã³æ§äžé£œåææ©ååç©
ãå«æããå éåå¯èœãªçµæç©ã«é¢ããããã®çµ
æç©ã¯å éåå¯èœãªè¢«èŠææåã³èšé²ææãšããŠ
çšããããå°å·æ¿ãæå æ§ã¯ãã¹è»¢åãã€ã«ã å
ã³éäžå«ã®æå æ§éåäœåç補ççšãã€ã«ã ã®è£œ
é ã®ããã®ææãšããŠç¹ã«é©ããã åèšäœ¿çšç®çã®ããå éåå¯èœãªè¢«èŠææåã³
èšé²ææèªäœã¯æ¢ç¥ã§ãã€ãŠã玫å€ç·ç §å°ã«ãã
ææã®ç¡¬åºŠæ¹åçšã®ååç©ã®å€æ°ã®çµåãããã§
ã«æç®ã«èšèŒãããŠããã宀枩ã§åºäœã®æ¢ç¥ã®è¢«
èŠææåã³èšé²ææã«ãããŠãã°ãã°çããæ¬ ç¹
ã¯ãååŠç·ç §å°ã«ããèªèµ·ãããéåã®é床ãã
ç¹ã«ææã®éæ§åã¯ç²æ§ãé«ããšãã«åå¿ã®çµäº
æã«èããäœäžãããããŠæ®éã®ç §å°æéã«ãã
ãŠã¯ååšãããªã¬ãã€ã³æ§äžé£œåçµåã®å®éäžå®
å šãªéååã¯æ¶æ©ãéæãããªãããšã§ãããã
ããã€ãŠå®éäžã¯ãç¹ã«ç»åã«ããç §å°ã®ã®ã¡ã«
éç §å°éšåã溶å€ã«ããæŽåºããå Žåã«åã¯å é
åã®çšåºŠã«ãã€ãŠè¡šé¢ç²çæ§åã¯å¹³ããåºäœãžã®
æ¥çå€ãå€ããå Žåã«ã¯ããã®çš®ã®è¢«èŠææåã¯
èšé²ææãé·æéç §å°ããã°ãªããªãã ãã€ãç¹èš±åºé¡å ¬é1947194å·ãç±³åœç¹èš±
4040923å·åã³å4043887å·åæ现æžã«ããã°ãå
éåå¯èœãªååç©ã®ããã®å éå§å€ãšããŠãè³éŠ
æç°ã«å¡©çŽ åãããã¯èçŽ åãããã¡ãã«åºãæ
ãããã³ãŸããšãã³èªå°äœãããšãã°ïŒâã¯ãã«
ã¡ãã«ãã³ãŸããšãã³ãïŒïŒïŒâãããã¯ïŒïŒ
4â²âãã¹âïŒã¯ãã«ã¡ãã«ïŒâãã³ãŸããšãã³åã¯
ïŒïŒ4â²âãã¹âïŒããã ã¡ãã«ïŒâãã³ãŸããšãã³
ãçšããããšãå ¬ç¥ã§ãããããããã®ç³»ã®æå
æ§ã¯ãªãäžæºè¶³ã§ãããããã«æŽ»æ§åå€ã«å¯Ÿãã
å éå§å€ã®æ¯çãå€æŽã§ããªãããšãæ¬ ç¹ã§ã
ãããã€ãç¹èš±åºé¡å ¬é2404156å·ãç±³åœç¹èš±
3933682å·ãå3966573å·åã³ãã«ã®ãŒç¹èš±853935
å·åæ现æžã«ããã°ãå éå§å€ç³»ãšããŠã(a)ã¢ã·
ãã€ã³åã¯è³éŠæã±ãã³ãã(b)ããAsãBi
åã¯Sbãå«æããååç©äŸãã°ã¢ãã³ããã¹ã
ã€ã³åã¯ã¢ã«ã·ã³ãªãã³ã«(c)ããã²ã³åãããè
èªæãèç°æåã¯è³éŠæã®çåæ°ŽçŽ ãçµåããã
ã®ã䜿çšããããšãç¥ãããŠãããããããã®ç³»
ãå«ãèšé²ææã®è²¯èµå®å®æ§ã¯å€ãã®å Žåã«äžæº
足ã§ããããããã¢ãã³ã®ãããªå¡©åºæ§ã®ååç©
(b)ã®äœ¿çšã«éããŠã¯ãæ®éã«æ·»å ãããæææ瀺
è¬ã®å€è²ã«ãããç §å°ãããç»åãšéç §å°ã®ç»å
ãšã®äžè¬æ§è³ªãåºå¥ããããšãå€ãã®å Žåã«äžå¯
èœã§ããã æ¬çºæã®èª²é¡ã¯ãå éåå¯èœãªãªã¬ãã€ã³æ§äž
飜åã®ææ©ååç©ãå«ããç¹ã«å®€æž©ã§åºäœã®å é
åå¯èœãªçµæç©ã®ããã«ãéåžžã®ç §å°æéã§æ¹è¯
ããã硬åã®éæãå¯èœã§ããããã€æº¶å€ã«ãã
éç §å°éšåã®æŽåºã®éã®é©æ£ãªæŽåºæéã«é¢ã
ãŠãããå¶éã®ãªãæäœãéåžžã®ç §å°æéã®é©çš
ã«ãã€ãŠãå¯èœã§ããããããŠåèšæ¢ç¥ã®ç³»ã®æ¬
ç¹ãã»ãšãã©ãªããåã¯å šããªãå éå§å€â掻æ§
å€ç³»ãèŠåºãããšã§ãã€ãã æ¬çºæè ãã¯ãå éå§å€ç³»ãããã²ã³åçåæ°Ž
çŽ ãšããŠããã³ãŸãŒã«æ žã«çµåããïŒå以äžã®ãž
ã¯ãã«ã¡ãã«åºãæãããã³ãŸãŒã«ååç©ãå«æ
ãããšããåžæããæ¹è¯ãéæãããããšãèŠåº
ããã æ¬çºæã¯ãå°ãªããšãïŒçš®ã®å éåå¯èœãªãªã¬
ãã€ã³æ§äžé£œåææ©ååç©ããªãã³ã«æŽ»æ§åãã
ãå éå§å€ç³»ãšããŠ(a)ååŠç·ã®ç §å°ã«éãéåã
éå§ããã©ãžã«ã«ã圢æããå°ãªããšãïŒçš®ã®è³
éŠæã«ã«ããã«ååç©åã³(b)ãã³ãŸãŒã«æ žã«çµå
ããïŒå以äžã®ãžã¯ãã«ã¡ãã«åºãæãããã³ãŸ
ãŒã«ååç©ãå«æããããšãç¹åŸŽãšãããå éå
å¯èœãªçµæç©ã§ããã æ¬çºæã®çµæç©ã¯ãé žã®æ·»å ã«éããŠãã®è²ã
å€åããæ瀺è¬ææãè¿œå çã«å«æããããšã奜
ãŸããã æ¬çºæã«ãããŠæŽ»æ§åãããå éå§å€ç³»äžã«å«
æãããããã³ãŸãŒã«æ žã«çµåããå°ãªããšãïŒ
åã®ãžã¯ãã«ã¡ãã«åºïŒâCHCl2ïŒãæãããã³
ãŸãŒã«ååç©ãšããŠã¯ãæ¬¡åŒ ã§è¡šããããååç©ãçšããããããã®åŒäžã®çœ®
æåºR1ãR6ã¯åäžã§ãç°ãªã€ãŠãããããã®ã
ã¡å°ãªããšãïŒåã®çœ®æåºã¯âCHCl2ã§ãããæ®
ãã®åºã¯åäžã§ãç°ãªã€ãŠãããä»»æã«éžã°ãã
ãã ããã®åºã¯ãžã¯ãã«ã¡ãã«åºã«å¯ŸããŠäžæŽ»æ§
ã«æåããå éåã劚ãããã€ååŠç·ã®ç¯å²ã§åŒ·
ãåžåã瀺ãããããªãã¡10åã®åžå ä¿æ°ã¯å¥œãŸ
ããã¯Î»ïŒ315ã400nmã®ç¯å²ã«ãããŠ20ããªãã
ã«ã»ã¢ã«-1ã»cm-1ãããå°ã§ããããšãåæãšã
ãã奜ãŸããã¯æ®ãã®åºãšããŠäžèšã®ãã®ããã
ããããæ°ŽçŽ ååãããã²ã³ååç¹ã«å¡©çŽ ååã
C1ãC10âçåæ°ŽçŽ æ®åºãããã²ã³åãããC1ã
C10ã¢ã«ãã«åºåã¯å Žåã«ããããã²ã³åããã
C1ãC10âã¢ã«ã³ãã·åºããžã¯ãã«ã¡ãã«åºãæ
ãã奜é©ãªãã³ãŸãŒã«ååç©ãšããŠã¯ããã¹â
ïŒãžã¯ãã«ã¡ãã«ïŒâãã³ãŸãŒã«ãäŸãã°ïŒïŒïŒâ
ãã¹ïŒãžã¯ãã«ã¡ãã«ïŒâãã³ãŸãŒã«åã³ïŒïŒïŒ
âãžã¯ãã«âïŒïŒïŒâãã¹ïŒãžã¯ãã«ã¡ãã«ïŒâ
ãã³ãŸãŒã«ããããããã ãžã¯ãã«ã¡ãã«ãã³ãŸãŒã«ååç©ã®æ·»å éã¯ã
äžè¬ã«å éåéå§å€(a)ã®ïŒéééšã«å¯Ÿã掻æ§åå€
(b)0.2ã12éééšã§ãããããã®å Žå掻æ§åå€ã®
æ¿åºŠã¯çµæç©å šéã®0.5ééïŒ ä»¥äžã§ããã ååŠç §å°ç·ã«ããéåéå§æ§ã©ãžã«ã«ãçæã
ãå°ãªããšãïŒçš®ã®è³éŠæã«ã«ããã«ååç©(a)ãš
ããŠã¯ãå éå§å€ãšããŠæ¢ç¥ã®è³éŠæã«ã«ããã«
ååç©äŸãã°è³éŠæã¢ã«ãããåã³è³éŠæã±ãã³
ãçšãããããç¹ã«å ã«ãããç±³åœç¹èš±3933682
å·æ现æžç¬¬ïŒæ¬35è¡ãªãã第ïŒæ¬19è¡åã³ãžãš
ãŒã»ã¯ã€ã¬ã€ç€ŸããŠãŒãšãŒã¯1965幎çºè¡ã®ã³ãŒã¶
ãŒèãã©ã€ãã»ã»ã³ã·ãã€ãã»ã·ã¹ãã ãºã158
ã193é ã«åŒçšããã察å¿ååç©ãåç §ãããã
ããã¯ãã®æ··åç©ãšããŠåã¯ä»ã®å éå§å€ãšçµå
ããŠçšããããšãã§ãããç¹ã«ãå Žåã«ãã眮æ
ããããã³ãŸããšãã³é¡äŸãã°ãã³ãŸããšãã³å
ã³ããã©ãŒã®ã±ãã³ããã³ãŸã€ã³ãšãŒãã«ãäŸã
ã°ãã³ãŸã€ã³âã€ãœãããã«ãšãŒãã«ãαäœã§
C1ãC8âããããã·ã¢ã«ãã«åºãC2ãC8âã¢ã«
ã³ãã·ã¢ã«ãã«åºåã¯C1ãC7âçåæ°ŽçŽ æ®åºã«
ãã眮æããããã³ãŸã€ã³ã®ãšãŒãã«ãäŸãã°Î±
âããããã·ã¡ãã«ãã³ãŸã€ã³âã¡ãã«ãšãŒã
ã«ããã³ãžã«ã±ã¿ãŒã«äŸãã°ãã³ãžã«ã¡ãã«ã±ã¿
ãŒã«ãã¢ã³ãã©ããã³åã³ãã®èªå°äœãããªããµ
ã³ãã³åã³ãã®èªå°äœããªãã³ã«ãã³ãŸããšãã³
èªå°äœäŸãã°ãã³ãŸããšãã³ãšããã©ãŒã®ã±ãã³
ãšã®çµåããæšå¥šããããç¹å®ã®å éå§å€ïŒçµå
ãïŒã®åã ã®é©åæ§ã¯ãæ¬çºæã®æ瀺ãç¥ã€ããª
ãã°ç°¡åãªæåè©Šéšã«ãã容æã«å®ããããã å°ãªããšãïŒçš®ã®å éåå¯èœãªãªã¬ãã€ã³æ§äž
飜åææ©ååç©ãå«æããææãšããŠã¯ã被èã
å°å·æ¿ãããªãã¬ãžã¹ãææãæå æ§ã¯ãã¹è»¢å
ãã€ã«ã ãéäžå«ã®å éåæ§ãã€ã«ã ã®è£œé åã³
é¡äŒŒç®çã®ããã«èšèŒãããŠããèªäœæ¢ç¥ã®å é
åå¯èœãªææãçšããããããã®ææã¯ããªã¬ã
ã€ã³æ§äžé£œåææ©ååç©ãããªã¬ãã€ã³æ§äžé£œå
ã®ïŒ£âäºéçµåãæãããªã¬ãã€ã³æ§äžé£œåã®
åéäœãåæéåäœåã¯éåäœã®åœ¢ã§å«æããã
ãªã¬ãã€ã³æ§äžé£œåååç©ã¯ãå°ãªãšãšãïŒåã®
æ«ç«¯CH2ïŒïŒ£åºãå«æãã倧æ°å§äžã§100â以
äžã®æ²žç¹ã瀺ãããã€å éå§æ§éååå¿ã«ããé
åäœã®çæãå¯èœã§ããããšãå¿ èŠãšããã奜é©
ãªææã¯ãäŸãã°ç±³åœç¹èš±2760863å·ãå3966573
å·ããã€ãç¹èš±åºé¡å ¬å1622297å·ããã€ãç¹èš±
åºé¡å ¬é1522444å·ãå2215090å·åã¯ãã«ã®ãŒç¹
èš±560154å·åæ现æžã«èšèŒãããŠããããã®å Žå
æ¬çºæã®æ瀺ã¯ã硬åïŒç §å°ïŒã®åã«å®€æž©ã§åºäœ
ã§ããããåã¯å éåå¯èœãªãªã¬ãã€ã³æ§äžé£œå
âäºéçµåãçŽ50ïŒ åå¿ããã®ã¡å®€æž©ã§åºäœ
ã®ææã圢æããå éåå¯èœãªææã®ããã«ãã
ãªãã¡ç¡¬åã®çµæã§é«ãéæ§åã¯ç²åºŠã瀺ããã
ãã«ãã€ãŠåå¿ç©è³ªã«å¯Ÿãäœãå¯åæ§ãäžããå
éåå¯èœãªææã®ããã«ç¹ã«æå©ã§ããã åªããçµæç©ã¯ãçµåå€æåãšããŠå éåå¯èœ
ãªåéäœã®ã»ãã«éåçæç©ãå«æããããã®æ
æ©éåäœçµåå€ã¯äœµçšãããåéäœãšäžè¬ã«èŠªå
æ§ã§ããã¹ãã§ããããŠå°é家ã«èªæã§ãããã
ã«ãç»åã«ããç §å°ã®å Žåã«ãå éåå¯èœãªææ
ã®å±€ã®éç §å°ã®æ¶æ©ãããªãéšåãæŽåºããããš
ãå¯èœã«ããããã«ãçŸåçšæº¶å€ã«å¯æº¶åã¯åæ£
å¯èœã§ãªããã°ãªããªãã奜é©ãªéåãããªã¬ã
ã€ã³æ§é£œååã¯äžé£œåã®çµåå€ãšããŠã¯ãç·ç¶ã
ãªã¢ããåã³ç¹ã«ã¢ã«ã³ãŒã«å¯æº¶ãªã³ããªã¢ã
ããäŸãã°ãã©ã³ã¹ç¹èš±1520856å·æ现æžã«èšèŒ
ã®äžèšã®ãã®ãããããããç¹ç¶çŽ èªå°äœç¹ã«æ°Ž
æ§ã¢ã«ã«ãªã«ããæŽåºå¯èœãªç¹ç¶çŽ èªå°äœããã
ã«ã¢ã«ã³ãŒã«éåäœåã³ïŒãïŒåã®ççŽ ååãæ
ããèèªæã¢ãã«ã«ãã³é žã®ããã«ãšã¹ãã«ã®é
åäœåã³å ±éåäœãäŸãã°çš®ã ã®é¹žå床ãæãã
é ¢é žããã«ã®éåäœåã³å ±éåäœãããã«ãããª
ãã³ãå¡©åããã«åã¯ã¹ãããŒã«ã®åç¬éåç©å
ã³å ±éåç©ãããªãŠã¬ã¿ã³ãããªãšãŒãã«ãŠã¬ã¿
ã³ãããªãšã¹ãã«ãŠã¬ã¿ã³ãããªãšã¹ãã«æš¹èã
ã¢ã¯ãªã«é žâåãŒã¡ã¿ã¯ãªã«é žãšã¹ãã«ã®å ±éå
ç©ãäŸãã°ã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãã¢ã¯ãªã«
ã¢ããåã³ïŒåã¯ããããã·ã¢ã«ãã«ã¢ã¯ãªã¬ãŒ
ãåã¯ããããã·ã¢ã«ãã«ã¡ã¿ã¯ãªã¬ãŒããšã¡ã
ã«ã¡ã¿ã¯ãªã¬ãŒããšã®å ±éåäœãåã³ãšã©ã¹ãã
ãŒãžãšã³éåäœåã³âå ±éåäœãäŸãã°ãã¿ãžãš
ã³åã³ïŒåã¯ã€ãœãã¬ã³ã®åç¬åã¯å ±éåäœãã
ãã¯åã³ã¹ãããŒã«åã¯Î±âã¡ãã«ã¹ãããŒã«ã®
éåäœãããã¯ããã®ãããã¯å ±éåäœã å°ãªããšãïŒåã®å éåå¯èœãªãªã¬ãã€ã³æ§äž
飜åäºéçµåãæããäœååååç©ã®ãã¡ã§ã¯ã
ïŒååã¯ãã以äžã®ãªã¬ãã€ã³æ§äžé£œåçµåãæ
ããå éåå¯èœãªäºéçµåãæããåéäœèªäœã
åã¯ãã®åéäœãšãå éåå¯èœãªãªã¬ãã€ã³æ§äž
飜åäºéçµåãïŒåã®ã¿æããåéäœãšã®æ··åç©
ãåªããŠãããçšããããåéäœã®çš®é¡ã¯ã䜿çš
ç®çãšäœµçšãããéåäœçµåå€ã®çš®é¡ã«åºç¯å²ã«
äŸåãããããªãã¡äžé£œåããªãšã¹ãã«æš¹èãšã®
æ··åç©ã®å Žåã¯ãç¹ã«ïŒå以äžã®äºéçµåãæã
ãã¢ãªã«ååç©äŸãã°ãã¬ã€ã³é žãžã¢ã«ãã«ãšã¹
ãã«ãã¢ãªã«ã¢ã¯ãªã¬ãŒãããžã¢ãªã«ãã¿ã¬ãŒ
ããããªã¡ãªããé žã®ãžâåã³ããªã¢ãªã«ãšã¹ã
ã«åã¯ãšãã¬ã³ã°ãªã³ãŒã«ãã¹ã¢ãªã«ã«ãŒãããŒ
ãããªãã³ã«ãžâåã³ããªã¢ã¯ãªã¬ãŒãåã³âã¡
ã¿ã¯ãªã¬ãŒãïŒã¢ã¯ãªã«é žåã¯ã¡ã¿ã¯ãªã«é žãšã®
ãžãªãŒã«åã¯ããªãªãŒã«ã®ãšã¹ãã«åã«ãã補é
ããããã®ïŒãäŸãã°ãšãã¬ã³ã°ãªã³ãŒã«ããžãš
ãã¬ã³ã°ãªã³ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ãçŽ
500ãŸã§ã®ååéãæããããªãšãã¬ã³ã°ãªã³ãŒ
ã«ãïŒïŒïŒâãããã³ãžãªãŒã«ãïŒïŒïŒâããã
ã³ãžãªãŒã«ãããªãã³ãã«ã°ãªã³ãŒã«ïŒïŒïŒïŒâ
ãžã¡ãã«âãããã³ãžãªãŒã«ïŒãïŒïŒïŒâãã¿ã³
ãžãªãŒã«ãïŒïŒïŒïŒïŒâããªã¡ãããŒã«ããã
ã³ãã°ãªã»ãªã³åã¯ãã³ã¿ãšãªããªããã®ãžâå
ã³ããªã¢ã¯ãªã¬ãŒãïŒåã¯ã¡ã¿ã¯ãªã¬ãŒãïŒã奜
é©ã§ãããããã«ãã®çš®ã®ãžãªãŒã«åã³ããªãªãŒ
ã«ã®ã¢ãã¢ã¯ãªã¬ãŒãåã³ã¢ãã¡ã¿ã¯ãªã¬ãŒãã
äŸãã°ãšãã¬ã³ã°ãªã³ãŒã«âåã¯ãžâãããªâã
ããã¯ããã©ãšãã¬ã³ã°ãªã³ãŒã«âã¢ãã¢ã¯ãªã¬
ãŒãããŠã¬ã¿ã³åºåã³ïŒåã¯ã¢ããåºãå«æãã
ïŒå以äžã®ãªã¬ãã€ã³æ§äžé£œåçµåãæããåé
äœãäŸãã°åèšçš®é¡ã®èèªæãžãªãŒã«ãææ©ãžã€
ãœã·ã¢ããŒãåã³ããããã·ã¢ã«ãã«ã¢ã¯ãªã¬ãŒ
ãïŒåã¯ã¡ã¿ã¯ãªã¬ãŒãïŒãã補é ãããäœåå
ååç©ãé©ããããŸãã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é ž
åã³ãã®èªå°äœãäŸãã°ã¢ã¯ãªã«ïŒåã¯ã¡ã¿ã¯ãª
ã«ïŒã¢ãããâããããã·ã¡ãã«ã¢ã¯ãªã«ïŒå
ã¯ã¡ã¿ã¯ãªã«ïŒã¢ããåã¯ïŒãïŒåã®ççŽ ååã
æããã¢ãã¢ã«ã³ãŒã«ã®ã¢ã¯ãªã¬ãŒãåã¯ã¡ã¿ã¯
ãªã¬ãŒããããããããã¢ãªã«åéäœãšãžâåã¯
ããªã¢ã¯ãªã¬ãŒãã®æ··åç©ã¯ç¹ã«é©ããŠãããé
åäœçµåå€ãšããŠã®ããªã¢ãããšã®æ··åç©ãéžæ
ãããªãã°ããžâåã³ããªã¢ã¯ãªã¬ãŒãã®ã»ãå
èšåéäœã®çš®é¡ã®ãã¡ã§ã¯ãäºéçµåã®ã»ããã
ã«ã¢ããåºåã³ïŒåã¯ãŠã¬ã¿ã³åºãå«æããåé
äœãäŸãã°ã¢ã¯ãªã«ã¢ããã®èªå°äœãäŸãã°ãšã
ã¬ã³ã°ãªã³ãŒã«çã®èèªæãžãªãŒã«ïŒã¢ã«ãšïŒ®â
ããããã·ã¡ãã«ã¢ã¯ãªã«ïŒåã¯ã¡ã¿ã¯ãªã«ïŒã¢
ããïŒã¢ã«ãšã®åå¿çæç©ããã·ãªã¬ã³âãã¹â
ã¢ã¯ãªã«ã¢ããã¯ã¢ã«ãã¬ã³åºäžã«ïŒãïŒåã®ç
çŽ ååãæããã¢ã«ãã¬ã³âãã¹âã¢ã¯ãªã«ã¢ã
ããé©ããŠãããéåäœçµåå€ãšããŠããªããã«
ã¢ã«ã³ãŒã«ãçšããŠæ°Žâã¢ã«ã«ãªæ§ã§çŸåå¯èœãª
å°å·æ¿ã補é ããããã«ã¯ãç¹ã«æ°Žã«å¯æº¶ãªåé
äœäŸãã°ããããã·ãšãã«ã¢ã¯ãªã¬ãŒãïŒåã¯ã¡
ã¿ã¯ãªã¬ãŒãïŒåã³çŽ200ãªãã500ã®ååéãæ
ããããªãšãã¬ã³ã°ãªã³ãŒã«ã®ã¢ãâåã³ãžã¢ã¯
ãªã¬ãŒãïŒåã¯ã¡ã¿ã¯ãªã¬ãŒãïŒãé©ããŠããã
éåäœçµåå€ãšããŠã¢ã¯ãªã¬ãŒãåã¯ã¡ã¿ã¯ãªã¬
ãŒãã®å ±éåäœãäŸãã°ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãå ±
éåç©ãçšããŠæå æ§ã¯ãã¹å¡è¢«ãã€ã«ã ïŒããª
ãã¬ãžã¹ã補é çšïŒã補é ããããã«ã¯ãå ã«ã
ãªãšã¹ãã«æš¹èã«é¢é£ããŠããããžâåã³ããªã¢
ã¯ãªã¬ãŒãïŒåã¯ã¡ã¿ã¯ãªã¬ãŒãïŒãé©ããŠã
ãã åéäœãšéåäœçµåå€ã®æ··åç©ã«ãããéæ¯ã¯
åºç¯å²ã«å€åãå¯èœã§ãã€ãŠãäžè¬ã«äž¡è ã®åèš
éã«å¯Ÿãåéäœã10ã55ééïŒ ç¹ã«25ã50éé
ïŒ ããããŠéåäœçµåå€ã45ã90ééïŒ ç¹ã«50ã
75ééïŒ ã§ããã åèšæ¯çã®å éå§å€(a)åã³æŽ»æ§åå€(b)ããã®æŽ»
æ§åå éå§å€ç³»ã®æ·»å éã¯ãå éåå¯èœãªçµæç©
ã®å šééãããªãã¡å šæåéã®åèšã«å¯Ÿããäžè¬
ã«ïŒã25ééïŒ ç¹ã«ïŒã20ééïŒ ã§ãããå éå§
å€ã®äœ¿çšéã¯ããã®åžå ä¿æ°åã³ç¡¬åã®éã®ææ
å±€ã®åãã«äŸåããéåžžã¯çµæç©ã®å šéã«å¯Ÿã
0.5ã10ééïŒ ç¹ã«çŽïŒãïŒééïŒ ã§ããã掻æ§
åå€(b)ã®éã¯ãå šçµæç©ã®0.5ééïŒ ä»¥äžç¹ã«çŽ
ïŒã12ééïŒ ã§ããããããŠææå±€ã®åžæãã硬
åæ§ã«ãã圱é¿ãåãããå€ãã®å Žåã«åäžã®å
éå§å€â掻æ§åå€ã®é åã«ãããŠãããåãææ
å±€ã«ç§»è¡ããå Žåã«ã¯ããã®ããåãææå±€ã«ã
ããŠçŽ«å€ç·ç §å°ã®ãã匷ãåžåãé¿ãããããå
éå§å€ã®æ¿åºŠãäœãããŠãã掻æ§åå€ã®æ¿åºŠãäž
å€ã«ä¿ã€ããšãç¹ã«æå©ã§ããã æ¬çºæã®çµæç©ã¯ãå éåå¯èœãªååç©ãéå
äœçµåå€ãå éå§å€åã³æŽ»æ§åå€ã®ã»ããããã«
æ®éã®éã§æ®éã®æ·»å ç©ãäŸãã°ç¡æ©åã¯ææ©ã®
é¡æåã¯ææãç¡æ©åã¯ææ©ã®å å¡«æãéåæå¶
å€äŸãã°ãã€ããããã³åã¯äžçŽããã«ãã€ãã
ããã³ãç®åŒµãé²æ¢å€äŸãã°ãã©ãã€ã³ãæµåå©
å€äŸãã°ã·ãªã³ãŒã³æ²¹ãã€ãæ¶ãå€åã¯æ»å€äŸã
ã°ã¯ãã¯ã¹ãææ©æº¶å€äŸãã°ã¢ã«ã³ãŒã«ãçåæ°Ž
çŽ åã¯ã±ãã³ãå«æããããšãã§ããã æ¬çºæã®å éåå¯èœãªçµæç©ã¯ãææãšããŠå¥œ
ãŸããã¯é žãæ·»å ãããšãã«è²ãå€ããæ瀺æ
æãäŸãã°3â²âããšãã«âïŒâãžãšãã«ã¢ããâ
ïŒïŒ2â²âã¹ãããžâïŒ2HâïŒâãã³ãŸããã³ïŒã
ããã ã¯ã¬ãŸãŒã«ã°ãªãŒã³åã¯ã¡ãã«ãªã¬ã³ãžã
äžè¬ã«0.05ãïŒééïŒ ã®éã§å«æãããé žãšã¢ã³
ã¢ããŠã å¡©ã圢æããŠæ¿è²åããã¢ããåºãæã
ãªãææããããããŠé©ããŠããã å éåãéå§ãããã2300ã4500â«ã®æ³¢é·ã®å
ç¹ã«3000ã4200â«ã®çºå 極倧ãæããå ãçšãã
ãããç §å°æºãšããŠã¯ãæ°Žéé«å§ç¯ãè¶ ååŠç·çº
å äœç®¡ããã»ãã³âã€ã³ãã«ã¹ç¯ãéå±æ²åç©äŸ
絊ç¯åã³ççŽ åŒ§å ç¯ãé©ããŠããã æ¬çºæã®çµæç©ã¯èªäœæ¢ç¥ã®æ段ã§å¡èã玫å€
ç·ç¡¬åæ§ã®å°åã€ã³ãåã³æºæã®ããæå æ§éå
äœå°å·çãããªãã¬ãžã¹ããæå æ§ã¯ãã¹è»¢åã
ã€ã«ã åã³éäžå«ã®æå æ§éåäœåç補ççšãã€
ã«ã ã«å å·¥ãããã æ¬çºæã®çµæç©äžã«å«æãããããžã¯ãã«ã¡ã
ã«åºãæããç¹æ®ãªãã³ãŸãŒã«ååç©(b)ãã匷å
ãªæŽ»æ§åå¹æãå¥ããåæã«å€ãã®çµåå€åã³å
éäœã«å¯ŸããŠããããŠè¯å¥œãªèŠªåæ§ã瀺ãããã
ãŠæå€ãªã»ã©é«åºŠã«ååŠçã«äžæŽ»æ§ã§ããããš
ã¯ãäŸãã°æ§é äžé¡äŒŒã®å¡©åãã³ã¶ã«ã«æ¯ããŠã
å šãäºæž¬äžå¯èœã§ãã€ãããžã¯ãã«ã¡ãã«åºå«æ
ãã³ãŸãŒã«ååç©(b)ã®ã¡ã¿ããŒã«æº¶æ¶²ã«ãæ°Žãå
ããŠç¡é žéãæ·»å ããããšã«ãããå¡©åéã®æ²æ®¿
ã¯å šãèµ·ãããªãã掻æ§åå€(b)ã¯310nm以äžã§ã»
ãšãã©å åžåã瀺ããªãã®ã§ãããã¯å éå§å€å
ã¯ææã®åžåã劚ããªãã äžèšã®å®æœäŸåã³æ¯èŒäŸäžã®éšåã³ïŒ ã¯ãç¹ã«
æ瀺ããªãéãééã«é¢ããéšã¯å®¹ééšã«å¯ŸããŠ
Kg察ã®é¢ä¿ã«ããã æ¯èŒäŸ ïŒ ã¢ãžãã³é žããããµã¡ãã¬ã³ãžã¢ãã³ãïŒïŒ
4â²âãžã¢ãããžã·ã¯ãããã·ã«ã¡ã¿ã³åã³Îµâã«
ããã©ã¯ã¿ã ã®å ±éçž®åã«ãã補é ãããã¢ã«ã³
ãŒã«å¯æº¶æ§ã®å ±ããªã¢ãã100éšããªãã³ã«ïœâ
ãã·ãªã¬ã³ãã¹ã¢ã¯ãªã«ã¢ãã15éšãããªãšãã¬
ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒã10éšãâã¡ãããŒ
ã«ã¡ã¿ã¯ãªã«ã¡ãã«ãšãŒãã«17éšããã³ãŸã€ã³ã¡
ãã«ãšãŒãã«ïŒéšåã³ïŒ®âããããœã·ã¯ãããã·
ã«ããããã·ã«ã¢ãã³ã®CerïŒïŒå¡©0.1éšããã¡
ã¿ããŒã«300éšã«60âã§æº¶è§£ããããã®ç²çš 溶液
ãããŒã«è£ 眮ã«ãã60ã80âã®æž©åºŠã§ä¹ŸçžããŒã«
åŠçããããã®ããŒã«ã§åŠçããã·ãŒããç ŽçŽ°
ããå§æŸæ©ã«ãã170âã§200KgïŒcm2ã®å§åäžã«å§
æŸããŠå§ã0.8mmã®ç¡è²éæãªæ¿ã«ããããã®æ¿
ãäž¡é¢æ¥çãã€ã«ã ã«ããã¢ã«ãããŠã æ¿äžã«æ¥
çããã ããããŠè£œé ãããå éåæ§æžç±å°å·æ¿ãé»å
åççšè©Šéšé°ç»ïŒ48ç·ïŒcmïŒã«ãããå20Wã®äœ
å§è¢å 管ïŒæ¬ãåããæ®éåžè²©ã®å°å·æ¿âç §å°è£
眮å ã§ãçš®ã ã®ç°ãªãæéã§ç §å°ããã24æéã®
貯èµã®ã®ã¡ãå°å·æ¿ã®éç §å°éšåããããããŒã«
âãšã¿ããŒã«âæ°Žæ··åç©ïŒïŒïŒïŒïŒïŒïŒã«ããã
æŽåºè£ 眮ïŒããã¯ãã³ããšå€æ°ã®åŽå°ããºã«ãã
æããïŒæ°å§ã®å§åãæãã溶å€ãæŽåºãã¹ãæ¿
äžã«åŽå°ããïŒå ã§æŽåºããã10ååŸã«æŽåºå·¥çš
ãäžæããæ°é®®ãªãããããŒã«ã§æ¿ãæŽæµããä»
çãã溶å€ãå§æŸç©ºæ°ã«ããé€å»ãããã¬ãªãŒã
ã«ãããïŒïŒ ã¹ã¯ãªãŒã³èª¿åå€ãå®å šã«åœ¢æãã
ããã«å¿ èŠãªç §å°æéãã第ïŒè¡šã«ç€ºãã å®æœäŸ ïŒ æ¯èŒäŸïŒãšåæ§ã«æäœãããã ãæžç±å°å·æ¿è£œ
é ã®ããã®ç²çš 液ã«ãïŒïŒïŒâãã¹ïŒãžã¯ãã«ã¡
ãã«ïŒâãã³ãŸãŒã«ïŒéšãããã«æ·»å ãããæ¯èŒ
äŸïŒãšåæ§ã«è¡ã€ãç §å°è©Šéšã®çµæã第ïŒè¡šã«ç€º
ãã
ãè¡šã
ïŒè¯å¥œ
æ¯èŒäŸ ïŒ ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã70ïŒ ãïŒâãšãã«ããã·
ã«ã¢ã¯ãªã¬ãŒãïŒïŒ ãã¹ãããŒã«ïŒïŒ åã³ã¡ã¿ã¯
ãªã«é ž20ïŒ ããã®å ±éåç©60éšïŒé ¢é žãšã¹ãã«äž
ã§ã¢ãŸã€ãœããããããªã«ãéåéå§å€ãšããŠæº¶
液éåã«ãã補é ãããïŒããã³ã¿ãšãªããªãã
âããã©ã¢ã¯ãªã¬ãŒã25éšããããµã³ãžãªãŒã«â
ïŒïŒïŒãžã¡ã¿ã¯ãªã¬ãŒãïŒéšãããã©ãŒã®ã±ãã³
ïŒéšããã³ãŸããšãã³2.5éšããã€ããããã³ã¢
ãã¡ãã«ãšãŒãã«0.2éšåã³ãã€ã¹ããŒã¹ãã«ãŒ
148ã®0.5éšã®é ¢é ž300éšäžã®æº¶æ¶²ããäºçåïŒïŒ¡
åã³ïŒ¢ïŒããã溶液ã®ïŒ¡éšã¯ãåžè²©ã®éœæ¥µé žåã«
ããç²é¢åãããã¢ã«ãããŠã æ¿äžã«ã也ç¥åŸã«
0.006mmã®å±€ãæ®çããããã«æµžæŒ¬ã«ããå¡åžã
ãã次ãã§åæ§ã«æµžæŒ¬ã«ããã氎溶液ãã6ÎŒmå
ãã®ããªããã«ã¢ã«ã³ãŒã«å±€ã圢æãããŠä¹Ÿç¥ã
ããããããŠåŸããããªãã»ããå°å·æ¿ããé»å
åççšã®14段éã°ã¬ãŒã¹ã±ãŒã«ãçšããŠå šé¢ã«ç §
å°ããããã®ã°ã¬ãŒã¹ã±ãŒã«ã¯ã370nmã§0.4ã®
æå°å åŠå¯åºŠãæããå段éã¯å段éã®20ïŒ ã ã
å åŠå¯åºŠãæžå°ããããã®å°å·æ¿ã¯å åãª65ç§ã®
ç §å°æéã®ã®ã¡ïŒãã®ãšãæå æ§ã¯ãã¹ã¯æãé
è²ããæããéè²ã«å€è²ããïŒããããŠPH10ãæ
ããçé žå¡©ç·©è¡æ¶²ã«ããçŸåã®ã®ã¡ãå°åãªãã»
ããå°å·æ©ã«ãããŠè¯å¥œãªå°å·æ§èœã瀺ããã ããã«æ®µéã®åœ¢æãïŒã10åéã®ç¹å®ç §å°æé
ã§è©äŸ¡ããã å®æœäŸ ïŒ æ¯èŒäŸïŒã«èšèŒã®æº¶æ¶²ã®ïŒ¢éšã«ãïŒïŒïŒâãžã¯
ãã«âïŒïŒïŒâãã¹ïŒãžã¯ãã«ã¡ãã«ïŒâãã³ãŸ
ãŒã«2.5éšã溶解ããããã®ä»ã®å å·¥ãšè©Šéšã¯ã
æ¯èŒäŸïŒãšåæ§ã«è¡ãããã50ç§ã®ç §å°æéã§ç §
å°ãããããŠçŸåãããå°å·æ¿ã¯ãæ¯èŒäŸïŒã®æ¿
ïŒç §å°æé65ç§ïŒãšåæ§ãªè¯å¥œãªå°å·æ§èœã瀺ã
ããïŒã10åéã®ç §å°æéã«ããã段é圢æã®è©
䟡ã¯ãæ¯èŒäŸïŒã®å¯Ÿå¿ããè©Šéšãšæ¯èŒãããšãå
ãç §å°æéã«ãããŠãå®æœäŸïŒã®æ¿ã¯æ¯èŒäŸïŒã®
æ¿ãããããããïŒãïŒæ®µéå€ã圢æãããããš
ãç¥ãããã å®æœäŸ ïŒåã³ïŒ ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã97ïŒ åã³ã¢ã¯ãªã«ã¢ãã
ïŒïŒ ããå ±éåç©54éšïŒé ¢é žãšã¹ãã«äžã®éé žå
ãã³ãŸã€ã«ãéå§å€ãšããŠã®éåã«ãã補é ã
ããé ¢é žãšã¹ãã«äžã®ïŒïŒ 溶液ãšããŠããã€ã±ã³
ãã€ãŒã®ããšã«ããŒãŒããâ13å·»1932幎60é ã«ã
ãå€ã24ã§ããïŒãïŒïŒïŒïŒïŒâããªã¡ãããŒ
ã«ãããã³âããªã¢ã¯ãªã¬ãŒã38.5éšããžããã«
ãšãã¬ã³å°¿çŽ 1.5éšããã³ãŸããšãã³2.5éšãâ
ããããœãžããšãã«ã¢ãã³0.025éšãã¯ãªã¹ã¿ã«
ãã€ãªã¬ãã0.011éšã3â²âããšãã«âïŒâãžãš
ãã«ã¢ããâïŒïŒ2â²âã¹ãããžâïŒ2HâïŒâãã³
ãŸããã³ïŒ0.3éšãã¢ãžãã³é žåã³ïŒïŒïŒâãã
ãã¬ã³ã°ãªã³ãŒã«ããã®ããªãšã¹ãã«ïŒ7paã»
secïŒ20âã®ç²åºŠãæããïŒ3.5éšãæ®éåžè²©ã®ã·
ãªã³ãŒã³æ²¹0.3éšåã³ïŒïŒïŒâãã¹ïŒãžã¯ãã«ã¡
ãã«ïŒâãã³ãŸãŒã«1.5éšããé ¢é žãšã¹ãã«140éš
ã«æº¶è§£ããããã®æº¶æ¶²ãååŸ1ÎŒmã®å§åšã«ãã
éãããããŠ0.023mmåãã®ããªãšã¹ãã«ãã€
ã«ã äžã«ãç±é¢šäžã§0.048mmã®æå æ§ã¯ãã¹ãæ®
çããéã§ç©å±€ããããã«æµå»¶ããããã®æå æ§
ã¯ãã¹ãã€ã«ã ã30ÎŒmåãã®ããªãšãã¬ã³ãã€
ã«ã ã§è¢«èŠããããã®äžå±€ãã€ã«ã ã50cmå¹ ã«è£
æããæ¿çŽã®å¿ã«å·»ãåããå·»ãç©ãšããŠææã«
貯èµããã也ç¥è²Œçå¯èœãªæå æ§ã¯ãã¹ãšããŠäœ¿
çšããåã«ãããªãšãã¬ã³è¢«èŠãã€ã«ã ãæ®éã®
åžè²©ã®è²Œåãæ©äžã§ã¯ããããããŠã¯ãã¹ããã
ããããã©ã·ãããããé âçœéåãããšããã·
æš¹èâã¬ã©ã¹ç¹ç¶æ¿äžã«1mïŒåã®é床ã§110âã§
貌çããããã®æ¿ãé¢åãããŠåãããããäžèš
ã®ããã«å å·¥ããã å®æœäŸ ïŒ é»æ°çé ç·ç»åã®åçé°ç»åå³ãéããŠãæ¿ã
玫å€ç·ã«ããïŒåéç §å°ãããç §å°ãããç»åéš
åã¯é玫è²ããæéè²ã«å€è²ããŠãåªããã³ã³ã
ã©ã¹ããçãããããã§ããªãšã¹ãã«ãã€ã«ã ã
ã¯ãåããéç §å°ã®ç»åéšåãïŒïŒïŒïŒïŒâããª
ã¯ãã«ãšã¿ã³ã«ããæŽåºããã次ãã§ããŒã¡44床
ã®å¡©åéïŒïŒæº¶æ¶²ãçšããŠè é£ããæ°ŽæŽããŠä¹Ÿ
ç¥ããããã®æ¿ãã¢ã»ãã³ã§ïŒåéæŽæµããããš
ã«ãããç §å°ãããæå æ§ã¯ãã¹ãæŽåºãããŠå°
é»æ§ã®æ¿ãåŸãããã å®æœäŸ ïŒ é»æ°çé ç·ç»åã®éœç»åå³ãéããŠãæ¿ã玫å€
ç·ã«ããïŒåéç §å°ããã次ãã§ããªãšã¹ãã«ã
ã€ã«ã ãã¯ãåããéç §å°ã®ç»åéšåãæŽåºãã
é²åºãããé è¡šé¢äžã«é»æ°ã¡ããã«ããé 次ã«é
0.035mmãããã±ã«0.005mmåã³é0.002mmãæ²çã
ããã次ãã§æ®ãã®æå æ§ã¯ãã¹ãå¡©åã¡ãã¬ã³
æŽæµã«ããæŽåºãããããŠæåŸã«ã¢ã³ã¢ãã¢æ§ç¡
é žé 溶液ãçšããŠé²åºããé ãè é£ãããšãå°é»
åè·¯ã®é®®é床ãåªããå°é»æ§ããªã³ãé ç·æ¿ãåŸ
ãããã æ¯èŒäŸ ïŒåã³ïŒ å®æœäŸïŒåã³ïŒãšåæ§ã«æäœãããã ãã¯ãã¹
溶液ã®è£œé ã«éããŠïŒïŒïŒâãã¹âïŒãžã¯ãã«ã¡
ãã«ïŒâãã³ãŸãŒã«ã®æ·»å ãçç¥ãããå®æœäŸïŒ
åã³ïŒãšæ¯èŒã§ããçµæãåŸãããã«ã¯ãïŒåé
ã®å¿ èŠç §å°æéãïŒå35ç§ã«å»¶é·ããã°ãªããª
ããããã«ç §å°åŸã«æéè²ã«ãªãå€è²ã¯ã¿ãããª
ãã å®æœäŸïŒåã³ïŒåã³æ¯èŒäŸïŒã11 å®æœäŸïŒã«èšèŒã®å ±éåç©53éšãããªã¡ãããŒ
ã«ãããã³ããªã¢ã¯ãªã¬ãŒã20éšãïŒïŒïŒâãã¿
ã³ãžãªãŒã«ãžã°ãªã·ããšã¹ãã«ãšã¢ã¯ãªã«é žã®åœ
éãšã®åå¿çæç©10éšãããªãšãã¬ã³ã°ãªã³ãŒã«
ãžã¢ã¯ãªã¬ãŒãïŒéšããžããã«ãããã¬ã³å°¿çŽ
0.5éšããã³ãŸããšãã³2.5éšãããã©ãŒã®ã±ãã³
0.4éšãïŒïŒïŒâãžäžçŽããã«âïŒâã¡ãã«ããš
ããŒã«0.05éšãããªãã³ãžã«ãã¹ããšãŒã3.5éš
åã³3â²âããšãã«âïŒâãžãšãã«ã¢ããâïŒïŒ
2â²âã¹ãããžâïŒ2HâïŒâãã³ãŸããã³ïŒ0.3éšã
ãã®é ¢é žãšã¹ãã«200éšäžã®æº¶æ¶²ã補é ããã ãã®çš®ã®åäžã®å溶液ã«ã第ïŒè¡šã«èšèŒã®å¡©çŽ
ååç©ãåè¡šã«èšèŒã®éã§æ··åãããããããŠè£œ
é ããã28çš®ã®ç°ãªã溶液ããå®æœäŸïŒåã³ïŒã«
èšèŒã®ããã«æäœããŠæå æ§ã¯ãã¹ãã€ã«ã ã«å
å·¥ããã次ãã§ãããé ã¡ãããããšããã·æš¹è
âã¬ã©ã¹ç¹ç¶æ¿äžã«ç©å±€ãããå¹ 0.1mmã®å°é»å
è·¯ãæããé ç·ã¢ããŒãã®åçé°ç»ãéããŠçŽ«å€
ç·ãç §å°ãããå å·¥ã®ããã«ã¯å¿ èŠãªïŒåéãšã
ãæéã®ä»£ããã«ç §å°æéã¯ããã45ç§ã§ããã
ïŒæéã®è²¯èµãšããªãšã¹ãã«ãã€ã«ã ã®å¥é¢ã®ã®
ã¡ïŒïŒïŒïŒïŒâäžå¡©åãšã¿ã³ãçšããŠçŸåããã
ãã®éãããã®å Žåãé ç·ç»åã®äžããæ©æ¢°çã«
é§åããããã©ã·ãã³å·æ¯ã絶ããäžžãåããã
ããå¿ èŠãšããçŸåã®æå°æéã¯ãã¹ãŠã®äŸã§10
ã15ç§ã§ããã ãã¹ãŠã®è©Šæã«ãããŠãæ倧蚱容æéïŒãã®æ
éåŸã¯é è¡šé¢äžã®ã¯ãã¹å±€ã®ç §å°ãããç»åéšå
ã溶解ããïŒã枬å®ããããã®çµæã第ïŒè¡šã«ç€º
ããããã¯æ¬çºæã«ããååç©ã®å éåã«å¯Ÿãã
äœçšãæããã«ç€ºããŠãããïŒåéã®ç §å°æéã«
ãããŠã¯å·®ç°ããããã§ãããã10åã®éå€§ç §å°
ïŒ600ç§ïŒã«ãããŠããªããã®å¹æã¯è¯å¥œã«æž¬å®å¯
èœã§ããã
æ¯èŒäŸ ïŒ ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã70ïŒ ãïŒâãšãã«ããã·
ã«ã¢ã¯ãªã¬ãŒãïŒïŒ ãã¹ãããŒã«ïŒïŒ åã³ã¡ã¿ã¯
ãªã«é ž20ïŒ ããã®å ±éåç©60éšïŒé ¢é žãšã¹ãã«äž
ã§ã¢ãŸã€ãœããããããªã«ãéåéå§å€ãšããŠæº¶
液éåã«ãã補é ãããïŒããã³ã¿ãšãªããªãã
âããã©ã¢ã¯ãªã¬ãŒã25éšããããµã³ãžãªãŒã«â
ïŒïŒïŒãžã¡ã¿ã¯ãªã¬ãŒãïŒéšãããã©ãŒã®ã±ãã³
ïŒéšããã³ãŸããšãã³2.5éšããã€ããããã³ã¢
ãã¡ãã«ãšãŒãã«0.2éšåã³ãã€ã¹ããŒã¹ãã«ãŒ
148ã®0.5éšã®é ¢é ž300éšäžã®æº¶æ¶²ããäºçåïŒïŒ¡
åã³ïŒ¢ïŒããã溶液ã®ïŒ¡éšã¯ãåžè²©ã®éœæ¥µé žåã«
ããç²é¢åãããã¢ã«ãããŠã æ¿äžã«ã也ç¥åŸã«
0.006mmã®å±€ãæ®çããããã«æµžæŒ¬ã«ããå¡åžã
ãã次ãã§åæ§ã«æµžæŒ¬ã«ããã氎溶液ãã6ÎŒmå
ãã®ããªããã«ã¢ã«ã³ãŒã«å±€ã圢æãããŠä¹Ÿç¥ã
ããããããŠåŸããããªãã»ããå°å·æ¿ããé»å
åççšã®14段éã°ã¬ãŒã¹ã±ãŒã«ãçšããŠå šé¢ã«ç §
å°ããããã®ã°ã¬ãŒã¹ã±ãŒã«ã¯ã370nmã§0.4ã®
æå°å åŠå¯åºŠãæããå段éã¯å段éã®20ïŒ ã ã
å åŠå¯åºŠãæžå°ããããã®å°å·æ¿ã¯å åãª65ç§ã®
ç §å°æéã®ã®ã¡ïŒãã®ãšãæå æ§ã¯ãã¹ã¯æãé
è²ããæããéè²ã«å€è²ããïŒããããŠPH10ãæ
ããçé žå¡©ç·©è¡æ¶²ã«ããçŸåã®ã®ã¡ãå°åãªãã»
ããå°å·æ©ã«ãããŠè¯å¥œãªå°å·æ§èœã瀺ããã ããã«æ®µéã®åœ¢æãïŒã10åéã®ç¹å®ç §å°æé
ã§è©äŸ¡ããã å®æœäŸ ïŒ æ¯èŒäŸïŒã«èšèŒã®æº¶æ¶²ã®ïŒ¢éšã«ãïŒïŒïŒâãžã¯
ãã«âïŒïŒïŒâãã¹ïŒãžã¯ãã«ã¡ãã«ïŒâãã³ãŸ
ãŒã«2.5éšã溶解ããããã®ä»ã®å å·¥ãšè©Šéšã¯ã
æ¯èŒäŸïŒãšåæ§ã«è¡ãããã50ç§ã®ç §å°æéã§ç §
å°ãããããŠçŸåãããå°å·æ¿ã¯ãæ¯èŒäŸïŒã®æ¿
ïŒç §å°æé65ç§ïŒãšåæ§ãªè¯å¥œãªå°å·æ§èœã瀺ã
ããïŒã10åéã®ç §å°æéã«ããã段é圢æã®è©
䟡ã¯ãæ¯èŒäŸïŒã®å¯Ÿå¿ããè©Šéšãšæ¯èŒãããšãå
ãç §å°æéã«ãããŠãå®æœäŸïŒã®æ¿ã¯æ¯èŒäŸïŒã®
æ¿ãããããããïŒãïŒæ®µéå€ã圢æãããããš
ãç¥ãããã å®æœäŸ ïŒåã³ïŒ ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã97ïŒ åã³ã¢ã¯ãªã«ã¢ãã
ïŒïŒ ããå ±éåç©54éšïŒé ¢é žãšã¹ãã«äžã®éé žå
ãã³ãŸã€ã«ãéå§å€ãšããŠã®éåã«ãã補é ã
ããé ¢é žãšã¹ãã«äžã®ïŒïŒ 溶液ãšããŠããã€ã±ã³
ãã€ãŒã®ããšã«ããŒãŒããâ13å·»1932幎60é ã«ã
ãå€ã24ã§ããïŒãïŒïŒïŒïŒïŒâããªã¡ãããŒ
ã«ãããã³âããªã¢ã¯ãªã¬ãŒã38.5éšããžããã«
ãšãã¬ã³å°¿çŽ 1.5éšããã³ãŸããšãã³2.5éšãâ
ããããœãžããšãã«ã¢ãã³0.025éšãã¯ãªã¹ã¿ã«
ãã€ãªã¬ãã0.011éšã3â²âããšãã«âïŒâãžãš
ãã«ã¢ããâïŒïŒ2â²âã¹ãããžâïŒ2HâïŒâãã³
ãŸããã³ïŒ0.3éšãã¢ãžãã³é žåã³ïŒïŒïŒâãã
ãã¬ã³ã°ãªã³ãŒã«ããã®ããªãšã¹ãã«ïŒ7paã»
secïŒ20âã®ç²åºŠãæããïŒ3.5éšãæ®éåžè²©ã®ã·
ãªã³ãŒã³æ²¹0.3éšåã³ïŒïŒïŒâãã¹ïŒãžã¯ãã«ã¡
ãã«ïŒâãã³ãŸãŒã«1.5éšããé ¢é žãšã¹ãã«140éš
ã«æº¶è§£ããããã®æº¶æ¶²ãååŸ1ÎŒmã®å§åšã«ãã
éãããããŠ0.023mmåãã®ããªãšã¹ãã«ãã€
ã«ã äžã«ãç±é¢šäžã§0.048mmã®æå æ§ã¯ãã¹ãæ®
çããéã§ç©å±€ããããã«æµå»¶ããããã®æå æ§
ã¯ãã¹ãã€ã«ã ã30ÎŒmåãã®ããªãšãã¬ã³ãã€
ã«ã ã§è¢«èŠããããã®äžå±€ãã€ã«ã ã50cmå¹ ã«è£
æããæ¿çŽã®å¿ã«å·»ãåããå·»ãç©ãšããŠææã«
貯èµããã也ç¥è²Œçå¯èœãªæå æ§ã¯ãã¹ãšããŠäœ¿
çšããåã«ãããªãšãã¬ã³è¢«èŠãã€ã«ã ãæ®éã®
åžè²©ã®è²Œåãæ©äžã§ã¯ããããããŠã¯ãã¹ããã
ããããã©ã·ãããããé âçœéåãããšããã·
æš¹èâã¬ã©ã¹ç¹ç¶æ¿äžã«1mïŒåã®é床ã§110âã§
貌çããããã®æ¿ãé¢åãããŠåãããããäžèš
ã®ããã«å å·¥ããã å®æœäŸ ïŒ é»æ°çé ç·ç»åã®åçé°ç»åå³ãéããŠãæ¿ã
玫å€ç·ã«ããïŒåéç §å°ãããç §å°ãããç»åéš
åã¯é玫è²ããæéè²ã«å€è²ããŠãåªããã³ã³ã
ã©ã¹ããçãããããã§ããªãšã¹ãã«ãã€ã«ã ã
ã¯ãåããéç §å°ã®ç»åéšåãïŒïŒïŒïŒïŒâããª
ã¯ãã«ãšã¿ã³ã«ããæŽåºããã次ãã§ããŒã¡44床
ã®å¡©åéïŒïŒæº¶æ¶²ãçšããŠè é£ããæ°ŽæŽããŠä¹Ÿ
ç¥ããããã®æ¿ãã¢ã»ãã³ã§ïŒåéæŽæµããããš
ã«ãããç §å°ãããæå æ§ã¯ãã¹ãæŽåºãããŠå°
é»æ§ã®æ¿ãåŸãããã å®æœäŸ ïŒ é»æ°çé ç·ç»åã®éœç»åå³ãéããŠãæ¿ã玫å€
ç·ã«ããïŒåéç §å°ããã次ãã§ããªãšã¹ãã«ã
ã€ã«ã ãã¯ãåããéç §å°ã®ç»åéšåãæŽåºãã
é²åºãããé è¡šé¢äžã«é»æ°ã¡ããã«ããé 次ã«é
0.035mmãããã±ã«0.005mmåã³é0.002mmãæ²çã
ããã次ãã§æ®ãã®æå æ§ã¯ãã¹ãå¡©åã¡ãã¬ã³
æŽæµã«ããæŽåºãããããŠæåŸã«ã¢ã³ã¢ãã¢æ§ç¡
é žé 溶液ãçšããŠé²åºããé ãè é£ãããšãå°é»
åè·¯ã®é®®é床ãåªããå°é»æ§ããªã³ãé ç·æ¿ãåŸ
ãããã æ¯èŒäŸ ïŒåã³ïŒ å®æœäŸïŒåã³ïŒãšåæ§ã«æäœãããã ãã¯ãã¹
溶液ã®è£œé ã«éããŠïŒïŒïŒâãã¹âïŒãžã¯ãã«ã¡
ãã«ïŒâãã³ãŸãŒã«ã®æ·»å ãçç¥ãããå®æœäŸïŒ
åã³ïŒãšæ¯èŒã§ããçµæãåŸãããã«ã¯ãïŒåé
ã®å¿ èŠç §å°æéãïŒå35ç§ã«å»¶é·ããã°ãªããª
ããããã«ç §å°åŸã«æéè²ã«ãªãå€è²ã¯ã¿ãããª
ãã å®æœäŸïŒåã³ïŒåã³æ¯èŒäŸïŒã11 å®æœäŸïŒã«èšèŒã®å ±éåç©53éšãããªã¡ãããŒ
ã«ãããã³ããªã¢ã¯ãªã¬ãŒã20éšãïŒïŒïŒâãã¿
ã³ãžãªãŒã«ãžã°ãªã·ããšã¹ãã«ãšã¢ã¯ãªã«é žã®åœ
éãšã®åå¿çæç©10éšãããªãšãã¬ã³ã°ãªã³ãŒã«
ãžã¢ã¯ãªã¬ãŒãïŒéšããžããã«ãããã¬ã³å°¿çŽ
0.5éšããã³ãŸããšãã³2.5éšãããã©ãŒã®ã±ãã³
0.4éšãïŒïŒïŒâãžäžçŽããã«âïŒâã¡ãã«ããš
ããŒã«0.05éšãããªãã³ãžã«ãã¹ããšãŒã3.5éš
åã³3â²âããšãã«âïŒâãžãšãã«ã¢ããâïŒïŒ
2â²âã¹ãããžâïŒ2HâïŒâãã³ãŸããã³ïŒ0.3éšã
ãã®é ¢é žãšã¹ãã«200éšäžã®æº¶æ¶²ã補é ããã ãã®çš®ã®åäžã®å溶液ã«ã第ïŒè¡šã«èšèŒã®å¡©çŽ
ååç©ãåè¡šã«èšèŒã®éã§æ··åãããããããŠè£œ
é ããã28çš®ã®ç°ãªã溶液ããå®æœäŸïŒåã³ïŒã«
èšèŒã®ããã«æäœããŠæå æ§ã¯ãã¹ãã€ã«ã ã«å
å·¥ããã次ãã§ãããé ã¡ãããããšããã·æš¹è
âã¬ã©ã¹ç¹ç¶æ¿äžã«ç©å±€ãããå¹ 0.1mmã®å°é»å
è·¯ãæããé ç·ã¢ããŒãã®åçé°ç»ãéããŠçŽ«å€
ç·ãç §å°ãããå å·¥ã®ããã«ã¯å¿ èŠãªïŒåéãšã
ãæéã®ä»£ããã«ç §å°æéã¯ããã45ç§ã§ããã
ïŒæéã®è²¯èµãšããªãšã¹ãã«ãã€ã«ã ã®å¥é¢ã®ã®
ã¡ïŒïŒïŒïŒïŒâäžå¡©åãšã¿ã³ãçšããŠçŸåããã
ãã®éãããã®å Žåãé ç·ç»åã®äžããæ©æ¢°çã«
é§åããããã©ã·ãã³å·æ¯ã絶ããäžžãåããã
ããå¿ èŠãšããçŸåã®æå°æéã¯ãã¹ãŠã®äŸã§10
ã15ç§ã§ããã ãã¹ãŠã®è©Šæã«ãããŠãæ倧蚱容æéïŒãã®æ
éåŸã¯é è¡šé¢äžã®ã¯ãã¹å±€ã®ç §å°ãããç»åéšå
ã溶解ããïŒã枬å®ããããã®çµæã第ïŒè¡šã«ç€º
ããããã¯æ¬çºæã«ããååç©ã®å éåã«å¯Ÿãã
äœçšãæããã«ç€ºããŠãããïŒåéã®ç §å°æéã«
ãããŠã¯å·®ç°ããããã§ãããã10åã®éå€§ç §å°
ïŒ600ç§ïŒã«ãããŠããªããã®å¹æã¯è¯å¥œã«æž¬å®å¯
èœã§ããã
ãè¡šã
ã¿ãªã³
å®æœäŸ ïŒ ãããµã¡ãã¬ã³ãžã€ãœã·ã¢ããŒãïŒã¢ã«åã³ã
ãããã·ãããã«ã¢ã¯ãªã¬ãŒãïŒã¢ã«ããã®åå¿
çæç©49éšããã«ã€ã¬ã³ãžã€ãœã·ã¢ããŒãïŒã¢ã«
åã³ããããã·ãããã«ã¢ã¯ãªã¬ãŒãïŒã¢ã«ãã
ã®åå¿çæç©ããã³ã¿ãšãªããªããâããã©ã¢ã¯
ãªã¬ãŒãïŒéšãïœïŒïœâãã¹âïŒãžãšãã«ã¢ããïŒ
âãã³ãŸããšãã³ïŒéšãïœâãžã¡ãã«ã¢ãããã³
ãºã¢ã«ãããïŒéšããã³ãŸããšãã³ïŒéšãïŒâã
ãšãã«ã¢ããâã¢ãŸãã³ãŸãŒã«ïŒéšåã³ïŒïŒïŒâ
ãžã¯ãã«âïŒïŒïŒâãã¹ïŒãžã¯ãã«ã¡ãã«ïŒâã
ã³ãŸãŒã«10éšãããå 硬åæ§å°å·ã€ã³ãçµåå€ã
補é ããã æ¹è£ ãããæžç±å°å·æ©ã«ããããã®çµåå€ãçš
ããŠé ã¡ãããšããã·æš¹èæ¿äžã«åïŒåå°å·ãã
ãã®éå°å·å·¥çšã®éã«1000ã¯ããæ°Žéé«å§ç¯ã«ã
ã0.6ç§éç §å°ããããšã«ãããå1.5ÎŒmã®ã€ã³ã
å±€ã也ç¥ãããå°å·æ¿ãšããŠã¯ãæ®éåžè²©ã®ããª
ã¢ãããåºç€ãšããæå æ§éåäœåžæ¿å°å·æ¿ãçš
ããã¢ããŒããšããŠé»æ°çé ç·ã®ç»åãå°å·ã
ããæ¿äžã«å°å·ã€ã³ã7.5ÎŒmãå¡åžãããã®ã¡ã
0.5æé也ç¥ãã次ãã§é²åºããŠããé è¡šé¢ãã
ããŒã¡44床ã®å¡©åéïŒïŒæ°Žæº¶æ¶²ãçšããŠè é£ã
ããåŸãããããªã³ãé ç·æ¿ã¯ãå°å·æ°1000æã«
éããã®ã¡ã«ãã埮现ãªèŒªéç·ãåªããçšã®é®®é
床ããªãã³ã«ããããŠè¯å¥œãªç»å寞æ³å®å®æ§ã瀺
ãããåç©ãšã®å·®ç°ã¯2ÎŒmãè¶ããªãã€ãããã
ã«å¯Ÿãã¹ã¯ãªãŒã³å°å·ã§è£œé ãããããªã³ãé ç·
æ¿ã¯ãåãå°å·æ°ã§éåžžã¯25ÎŒmãŸã§ã®åå·®ã枬
å®ãããã æ¯èŒäŸ 12 å®æœäŸïŒãšåæ§ã«æäœãããã ãïŒïŒïŒâãžã¯
ãã«âïŒïŒïŒâãã¹ïŒãžã¯ãã«ã¡ãã«ïŒâãã³ãŸ
ãŒã«ã®ä»£ããã«ãïŒïŒïŒâãã¹âïŒããªã¯ãã«ã¡
ãã«ïŒâãã³ãŸãŒã«ã®åéãçšããŠæžç±å°å·æ¿ã
補é ããããã®ãã®ã¯åæ§ã«ããªã³ãé ç·ã®å°å·
ã®ããåžçå°å·æ³ã«ãã䜿çšããããšãã§ããã
ãããåå°å·ã«ãããã1.1ç§éç §å°ããã°ãªã
ãªãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãã溶液ããç¹ããã網ç®ç¶åºæã®
äžã«å¡èãšããŠåã20ÎŒmã®å±€ã«å¡åžãããååŠ
ç·ã«ããç»åã«åŸãç §å°ãšæ°Žâã¢ã«ã«ãªæ§æº¶æ¶²äž
ã§ã®çŸåã®ã®ã¡ããã®å éåããåã®éšåã¯ã¹ã¯
ãªãŒã³å°å·çšã®åªãããã¹ã¯ãšããŠçšããããã
å®æœäŸ ïŒ ãããµã¡ãã¬ã³ãžã€ãœã·ã¢ããŒãïŒã¢ã«åã³ã
ãããã·ãããã«ã¢ã¯ãªã¬ãŒãïŒã¢ã«ããã®åå¿
çæç©49éšããã«ã€ã¬ã³ãžã€ãœã·ã¢ããŒãïŒã¢ã«
åã³ããããã·ãããã«ã¢ã¯ãªã¬ãŒãïŒã¢ã«ãã
ã®åå¿çæç©ããã³ã¿ãšãªããªããâããã©ã¢ã¯
ãªã¬ãŒãïŒéšãïœïŒïœâãã¹âïŒãžãšãã«ã¢ããïŒ
âãã³ãŸããšãã³ïŒéšãïœâãžã¡ãã«ã¢ãããã³
ãºã¢ã«ãããïŒéšããã³ãŸããšãã³ïŒéšãïŒâã
ãšãã«ã¢ããâã¢ãŸãã³ãŸãŒã«ïŒéšåã³ïŒïŒïŒâ
ãžã¯ãã«âïŒïŒïŒâãã¹ïŒãžã¯ãã«ã¡ãã«ïŒâã
ã³ãŸãŒã«10éšãããå 硬åæ§å°å·ã€ã³ãçµåå€ã
補é ããã æ¹è£ ãããæžç±å°å·æ©ã«ããããã®çµåå€ãçš
ããŠé ã¡ãããšããã·æš¹èæ¿äžã«åïŒåå°å·ãã
ãã®éå°å·å·¥çšã®éã«1000ã¯ããæ°Žéé«å§ç¯ã«ã
ã0.6ç§éç §å°ããããšã«ãããå1.5ÎŒmã®ã€ã³ã
å±€ã也ç¥ãããå°å·æ¿ãšããŠã¯ãæ®éåžè²©ã®ããª
ã¢ãããåºç€ãšããæå æ§éåäœåžæ¿å°å·æ¿ãçš
ããã¢ããŒããšããŠé»æ°çé ç·ã®ç»åãå°å·ã
ããæ¿äžã«å°å·ã€ã³ã7.5ÎŒmãå¡åžãããã®ã¡ã
0.5æé也ç¥ãã次ãã§é²åºããŠããé è¡šé¢ãã
ããŒã¡44床ã®å¡©åéïŒïŒæ°Žæº¶æ¶²ãçšããŠè é£ã
ããåŸãããããªã³ãé ç·æ¿ã¯ãå°å·æ°1000æã«
éããã®ã¡ã«ãã埮现ãªèŒªéç·ãåªããçšã®é®®é
床ããªãã³ã«ããããŠè¯å¥œãªç»å寞æ³å®å®æ§ã瀺
ãããåç©ãšã®å·®ç°ã¯2ÎŒmãè¶ããªãã€ãããã
ã«å¯Ÿãã¹ã¯ãªãŒã³å°å·ã§è£œé ãããããªã³ãé ç·
æ¿ã¯ãåãå°å·æ°ã§éåžžã¯25ÎŒmãŸã§ã®åå·®ã枬
å®ãããã æ¯èŒäŸ 12 å®æœäŸïŒãšåæ§ã«æäœãããã ãïŒïŒïŒâãžã¯
ãã«âïŒïŒïŒâãã¹ïŒãžã¯ãã«ã¡ãã«ïŒâãã³ãŸ
ãŒã«ã®ä»£ããã«ãïŒïŒïŒâãã¹âïŒããªã¯ãã«ã¡
ãã«ïŒâãã³ãŸãŒã«ã®åéãçšããŠæžç±å°å·æ¿ã
補é ããããã®ãã®ã¯åæ§ã«ããªã³ãé ç·ã®å°å·
ã®ããåžçå°å·æ³ã«ãã䜿çšããããšãã§ããã
ãããåå°å·ã«ãããã1.1ç§éç §å°ããã°ãªã
ãªãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãã溶液ããç¹ããã網ç®ç¶åºæã®
äžã«å¡èãšããŠåã20ÎŒmã®å±€ã«å¡åžãããååŠ
ç·ã«ããç»åã«åŸãç §å°ãšæ°Žâã¢ã«ã«ãªæ§æº¶æ¶²äž
ã§ã®çŸåã®ã®ã¡ããã®å éåããåã®éšåã¯ã¹ã¯
ãªãŒã³å°å·çšã®åªãããã¹ã¯ãšããŠçšããããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ å°ãªããšãïŒçš®ã®å éåå¯èœãªãªã¬ãã€ã³æ§
äžé£œåææ©ååç©ããªãã³ã«æŽ»æ§åãããå éå§
å€ç³»ãšããŠ(a)ååŠç·ã®ç §å°ã«éãéåãéå§ãã
ã©ãžã«ã«ã圢æããå°ãªããšãïŒçš®ã®è³éŠæã«ã«
ããã«ååç©åã³(b)ãã³ãŸãŒã«æ žã«çµåããïŒå
以äžã®ãžã¯ãã«ã¡ãã«åºãæãããã³ãŸãŒã«åå
ç©ãå«æããããšãç¹åŸŽãšãããå éåå¯èœãªçµ
æç©ã ïŒ ããã²ã³åçåæ°ŽçŽ (b)ãšããŠããã¹âïŒãžã¯
ãã«ã¡ãã«ïŒâãã³ãŸãŒã«ãå«æããããšãç¹åŸŽ
ãšãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®å éåå¯
èœãªçµæç©ã ïŒ ããã²ã³åçåæ°ŽçŽ (b)ãšããŠãïŒïŒïŒâãžã¯
ãã«ã¡ãã«âïŒïŒïŒâãã¹ïŒãžã¯ãã«ã¡ãã«ïŒâ
ãã³ãŸãŒã«ãå«æããããšãç¹åŸŽãšãããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®å éåå¯èœãªçµæç©ã ïŒ ãžã¯ãã«ã¡ãã«åºãæãããã³ãŸãŒã«ååç©
(b)ã®å«éããçµæç©ã®å šéã«å¯Ÿã0.5ééïŒ ä»¥äž
ã§ããããããŠè³éŠæã«ã«ããã«ååç©(a)ã®ïŒé
ééšã«å¯Ÿãåèšååç©(b)0.2ã12éééšãå«æã
ãããšãç¹åŸŽãšãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒãªãã
ïŒé ã®ããããã«èšèŒã®å éåå¯èœãªçµæç©ã ïŒ è³éŠæã«ã«ããã«ååç©(a)ãšããŠãã³ãŸããš
ãã³åã¯çœ®æåºãæãããã³ãŸããšãã³ãå«æã
ãããšãç¹åŸŽãšãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒãªãã
ïŒé ã®ããããã«èšèŒã®å éåå¯èœãªçµæç©ã ïŒ é žã®æ·»å ã«éããŠãã®è²ãå€åããæ瀺è¬æ
æãå«æããããšãç¹åŸŽãšãããç¹èš±è«æ±ã®ç¯å²
第ïŒãªããïŒé ã®ããããã«èšèŒã®å éåå¯èœãª
çµæç©ã
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19772759164 DE2759164A1 (de) | 1977-12-31 | 1977-12-31 | Photopolymerisierbare ueberzugs- und aufzeichnungsmaterialien, enthaltend einen photoinitiator und eine organische halogenverbindung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS54100483A JPS54100483A (en) | 1979-08-08 |
| JPS6331484B2 true JPS6331484B2 (ja) | 1988-06-24 |
Family
ID=6027869
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16028678A Granted JPS54100483A (en) | 1977-12-31 | 1978-12-27 | Photoinitiator and organic halogen compounddcontaining photopolymerizable coating material * recording material |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4239609A (ja) |
| EP (1) | EP0002805B1 (ja) |
| JP (1) | JPS54100483A (ja) |
| DE (2) | DE2759164A1 (ja) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4500608A (en) * | 1980-11-03 | 1985-02-19 | Minnesota Mining And Manufacturing Company | Anaerobically-curing compositions |
| US4447588A (en) * | 1980-11-03 | 1984-05-08 | Minnesota Mining & Manufacturing Company | Anaerobically-curing compositions |
| DE3047126A1 (de) * | 1980-12-13 | 1982-07-29 | Basf Ag, 6700 Ludwigshafen | Photopolymerisierbares aufzeichnungsmaterial und verfahren zur herstellung von reliefformen mittels dieses aufzeichnungsmaterials |
| US4341860A (en) * | 1981-06-08 | 1982-07-27 | E. I. Du Pont De Nemours And Company | Photoimaging compositions containing substituted cyclohexadienone compounds |
| US4404345A (en) * | 1981-09-16 | 1983-09-13 | Minnesota Mining And Manufacturing Company | Novel adhesive compositions |
| JP2728665B2 (ja) * | 1987-07-02 | 1998-03-18 | æ¥ç«åæå·¥æ¥ æ ªåŒäŒç€Ÿ | æå æ§æš¹èçµæç© |
| DE3939389A1 (de) * | 1989-11-29 | 1991-06-06 | Basf Ag | Lichtempfindliche zubereitung und verfahren zur herstellung von photoresisten und druckplatten |
| EP0620500A3 (en) * | 1993-04-16 | 1996-01-03 | Hitachi Ltd | Reserve and method for obtaining structures with this reserve. |
| US5885746A (en) * | 1994-12-29 | 1999-03-23 | Tokyo Ohka Kogyo Co., Ltd. | Photosensitive resin composition, photosensitive printing plate using the same and method of manufacturing printing master plate |
| DE69736351D1 (de) | 1996-05-08 | 2006-08-31 | Cyclacel Ltd | Methoden und mittel zur hemmung der cdk4-aktivitÀt |
| US20080125404A1 (en) | 2004-08-27 | 2008-05-29 | Cyclacel Limited | Purine and Pyrimidine Cdk Inhitbitors and Their use for The Treatment of Autoimmune Diseases |
| JP2017504827A (ja) * | 2013-12-20 | 2017-02-09 | ã³ãã¹ããããã€ãã¥ã©ã³ããã¢ã¯ããšã³ã²ãŒã«ã·ã£ããïœïœïœ ïœïœïœïœ ïŒ€ïœ ïœïœïœïœïœïœïœïœïœ ïŒ¡ïœ | æ¹åãããå æåæ§ãåããããã°ã©ãã£ãã¯åªäœ |
| CN103730330A (zh) * | 2013-12-31 | 2014-04-16 | 詹äºç¿ | äžç§ç¯æ³¡å°å£æºçææ¶è£ 眮 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5153539A (en) * | 1973-03-30 | 1976-05-12 | Scm Corp | Hikarijugoseisoseibutsuoyobi hikarijugohoho |
| JPS5183683A (en) * | 1974-12-26 | 1976-07-22 | Scm Corp | Hifukuyososeibutsu oyobi sonojugohoho |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1949010C3 (de) * | 1969-09-27 | 1979-11-29 | Bayer Ag, 5090 Leverkusen | Verwendung von halogenmethylierten Benzophenonen als Photopolymerisationsinitiatoren |
| GB1467645A (en) * | 1973-01-31 | 1977-03-16 | Sun Chemical Corp | Photoinitiator systems |
| US3878075A (en) * | 1973-03-30 | 1975-04-15 | Scm Corp | Photopolymerization of pigmented binders using combinations of organic carbonyls and halogenated naphthalenes |
| US3857769A (en) * | 1973-11-08 | 1974-12-31 | Scm Corp | Photopolymerizable coating compositions and process for making same which contains a thioxanthone and an activated halogenated azine compound as sensitizers |
| US4113592A (en) * | 1975-04-14 | 1978-09-12 | Celanese Corporation | Trihalogenated hydrocarbons as co-photoinitiators |
| US3988228A (en) * | 1975-08-29 | 1976-10-26 | Eastman Kodak Company | Photopolymerizable polymeric compositions containing halogen containing aromatic ketones |
| US4040923A (en) * | 1976-06-03 | 1977-08-09 | Eastman Kodak Company | Photopolymerizable polymeric compositions containing halogen containing aromatic ketones |
| US4043887A (en) * | 1977-01-17 | 1977-08-23 | Eastman Kodak Company | Benzophenone initiators for the photopolymerization of unsaturated compounds |
-
1977
- 1977-12-31 DE DE19772759164 patent/DE2759164A1/de not_active Withdrawn
-
1978
- 1978-12-21 EP EP78101799A patent/EP0002805B1/de not_active Expired
- 1978-12-21 DE DE7878101799T patent/DE2860452D1/de not_active Expired
- 1978-12-27 US US05/974,622 patent/US4239609A/en not_active Expired - Lifetime
- 1978-12-27 JP JP16028678A patent/JPS54100483A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5153539A (en) * | 1973-03-30 | 1976-05-12 | Scm Corp | Hikarijugoseisoseibutsuoyobi hikarijugohoho |
| JPS5183683A (en) * | 1974-12-26 | 1976-07-22 | Scm Corp | Hifukuyososeibutsu oyobi sonojugohoho |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0002805A1 (de) | 1979-07-11 |
| JPS54100483A (en) | 1979-08-08 |
| US4239609A (en) | 1980-12-16 |
| DE2860452D1 (en) | 1981-02-26 |
| DE2759164A1 (de) | 1979-07-12 |
| EP0002805B1 (de) | 1981-01-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4517279A (en) | Photosensitive elastomeric polymer composition for flexographic printing plates - processable in semi-aqueous basic solution or solvent systems | |
| US5254429A (en) | Photopolymerizable coating composition and lithographic printing plate produced therefrom | |
| US4632897A (en) | Photopolymerizable recording material suitable for the production of photoresist layers | |
| JP2792889B2 (ja) | å°å·çäœè£œé ã«é©ããå éåæ§å°å·æ¿ | |
| JPH0419540B2 (ja) | ||
| JP3347171B2 (ja) | åžçå°å·ç補é çšã®æå æ§æ··åç© | |
| JPS6340141A (ja) | æå æ§èšé²çŽ å | |
| EP0164270B1 (en) | Photo-polymerizable compositon and printing plate prepared therefrom | |
| JPS6331484B2 (ja) | ||
| JPS60247638A (ja) | æå æ§èšé²ææ | |
| JPS63172152A (ja) | å±€æ¯æäœããã³æå æ§å±€ãæããæå æ§è€åææããã³ãã®è£œæ³ | |
| US4816379A (en) | Production of relief plates and printing plates by a positive-working method | |
| JPH0374381B2 (ja) | ||
| US4164421A (en) | Photocurable composition containing an o-quinonodiazide for printing plate | |
| JPS58144824A (ja) | ãã©ãã¬ãžã¹ã補å | |
| US3732106A (en) | Light-sensitive copying compositions | |
| JPS62141005A (ja) | ã€ãªã³ç³»éåäœ | |
| CA1058943A (en) | Light sensitive copying composition comprising a synergistic initiator system | |
| JPS5922219B2 (ja) | ãã¬ããœå°å·ççšæå æ§æš¹èçµæç© | |
| EP0104751A2 (en) | Photosensitive elastomeric polymer composition for flexographic printing plates | |
| JPH02213849A (ja) | 溶解æ§äžéå±€ãåããããã¬ãžã¹ããã£ã«ã | |
| US5041357A (en) | Radiation-polymerizable mixture and recording material containing it | |
| US4101327A (en) | Light-sensitive copying compositions and photoinitiators contained therein | |
| AU629271B2 (en) | Process for producing an ozone-resistant flexographic printing form | |
| EP0351628A2 (de) | LichthÀrtbares elastomeres Gemisch und daraus erhaltenes Aufzeichnungsmaterial fÌr die Herstellung von Reliefdruckplatten |