JPS632897B2 - - Google Patents
Info
- Publication number
- JPS632897B2 JPS632897B2 JP59091034A JP9103484A JPS632897B2 JP S632897 B2 JPS632897 B2 JP S632897B2 JP 59091034 A JP59091034 A JP 59091034A JP 9103484 A JP9103484 A JP 9103484A JP S632897 B2 JPS632897 B2 JP S632897B2
- Authority
- JP
- Japan
- Prior art keywords
- gas
- uranium
- alcohol
- reaction
- uranium hexafluoride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006243 chemical reaction Methods 0.000 claims description 57
- SANRKQGLYCLAFE-UHFFFAOYSA-H uranium hexafluoride Chemical compound F[U](F)(F)(F)(F)F SANRKQGLYCLAFE-UHFFFAOYSA-H 0.000 claims description 46
- 239000007789 gas Substances 0.000 claims description 39
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 25
- WZECUPJJEIXUKY-UHFFFAOYSA-N [O-2].[O-2].[O-2].[U+6] Chemical compound [O-2].[O-2].[O-2].[U+6] WZECUPJJEIXUKY-UHFFFAOYSA-N 0.000 claims description 24
- 229910000439 uranium oxide Inorganic materials 0.000 claims description 24
- 238000002485 combustion reaction Methods 0.000 claims description 15
- 238000010574 gas phase reaction Methods 0.000 claims description 12
- 239000012530 fluid Substances 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000000843 powder Substances 0.000 description 35
- 235000019441 ethanol Nutrition 0.000 description 26
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 22
- 239000001257 hydrogen Substances 0.000 description 20
- 229910052739 hydrogen Inorganic materials 0.000 description 20
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 11
- 229910052731 fluorine Inorganic materials 0.000 description 11
- 239000011737 fluorine Substances 0.000 description 11
- OOAWCECZEHPMBX-UHFFFAOYSA-N oxygen(2-);uranium(4+) Chemical compound [O-2].[O-2].[U+4] OOAWCECZEHPMBX-UHFFFAOYSA-N 0.000 description 10
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 10
- FCTBKIHDJGHPPO-UHFFFAOYSA-N uranium dioxide Inorganic materials O=[U]=O FCTBKIHDJGHPPO-UHFFFAOYSA-N 0.000 description 10
- 229910000442 triuranium octoxide Inorganic materials 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
- 229910001873 dinitrogen Inorganic materials 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 229910001882 dioxygen Inorganic materials 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000004438 BET method Methods 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- KCKICANVXIVOLK-UHFFFAOYSA-L dioxouranium(2+);difluoride Chemical compound [F-].[F-].O=[U+2]=O KCKICANVXIVOLK-UHFFFAOYSA-L 0.000 description 3
- 239000003758 nuclear fuel Substances 0.000 description 3
- MZFRHHGRNOIMLW-UHFFFAOYSA-J uranium(4+);tetrafluoride Chemical compound F[U](F)(F)F MZFRHHGRNOIMLW-UHFFFAOYSA-J 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- 235000012501 ammonium carbonate Nutrition 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- ZAASRHQPRFFWCS-UHFFFAOYSA-P diazanium;oxygen(2-);uranium Chemical compound [NH4+].[NH4+].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[U].[U] ZAASRHQPRFFWCS-UHFFFAOYSA-P 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- RXWCTKVOMOOHCV-UHFFFAOYSA-N dioxouranium;dihydrofluoride Chemical compound F.F.O=[U]=O RXWCTKVOMOOHCV-UHFFFAOYSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910000856 hastalloy Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229940035429 isobutyl alcohol Drugs 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910000601 superalloy Inorganic materials 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
- -1 uranyl ammonium carbonate Chemical compound 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G43/00—Compounds of uranium
- C01G43/01—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G43/00—Compounds of uranium
- C01G43/01—Oxides; Hydroxides
- C01G43/025—Uranium dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Description
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Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ å ããåãŠã©ã³ãšéå°éã®ã¢ã«ã³ãŒã«ãã¬ã¹
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ã600ã800âã«å¶åŸ¡ããæ¹æ³ã
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59091034A JPS60235721A (ja) | 1984-05-09 | 1984-05-09 | é žåãŠã©ã³ç²æ«ã®è£œæ³ |
CA000480570A CA1285372C (en) | 1984-05-09 | 1985-05-02 | Process for manufacturing uranium oxide powder |
FR858506941A FR2564085B1 (fr) | 1984-05-09 | 1985-05-07 | Procede pour la fabrication de poudre d'oxyde d'uranium |
US06/731,984 US4666691A (en) | 1984-05-09 | 1985-05-08 | Process for manufacturing uranium oxide powder |
DE19853516278 DE3516278A1 (de) | 1984-05-09 | 1985-05-08 | Verfahren zur herstellung von uranoxidpulver |
BE0/214977A BE902374A (fr) | 1984-05-09 | 1985-05-08 | Procede de fabrication de poudre d'oxyde d'uranium. |
GB08511787A GB2159135B (en) | 1984-05-09 | 1985-05-09 | A process for the manufacture of uranium oxide powder |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59091034A JPS60235721A (ja) | 1984-05-09 | 1984-05-09 | é žåãŠã©ã³ç²æ«ã®è£œæ³ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60235721A JPS60235721A (ja) | 1985-11-22 |
JPS632897B2 true JPS632897B2 (ja) | 1988-01-21 |
Family
ID=14015221
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59091034A Granted JPS60235721A (ja) | 1984-05-09 | 1984-05-09 | é žåãŠã©ã³ç²æ«ã®è£œæ³ |
Country Status (7)
Country | Link |
---|---|
US (1) | US4666691A (ja) |
JP (1) | JPS60235721A (ja) |
BE (1) | BE902374A (ja) |
CA (1) | CA1285372C (ja) |
DE (1) | DE3516278A1 (ja) |
FR (1) | FR2564085B1 (ja) |
GB (1) | GB2159135B (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0347497U (ja) * | 1989-09-19 | 1991-05-02 | ||
JPH03111699A (ja) * | 1989-09-26 | 1991-05-13 | Suzuki Seisakusho:Kk | ãã³ã |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01126591A (ja) * | 1987-11-12 | 1989-05-18 | Japan Atom Energy Res Inst | æ·»å ç©ã䜿ããªã倧çµæ¶ç²åŸïœïœâïŒçæã®è£œé æ¹æ³ |
JPH0699154B2 (ja) * | 1988-05-25 | 1994-12-07 | äžè±ãããªã¢ã«æ ªåŒäŒç€Ÿ | ïœâ²äžïŒâŒãã¬ããã®è£œé æ¹æ³ |
KR100794071B1 (ko) * | 2006-12-05 | 2008-01-10 | íêµììë ¥ì°êµ¬ì | íµì°ë£ ì결첎ì ì ì¡° ë°©ë² |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3755188A (en) * | 1970-07-17 | 1973-08-28 | Gen Electric | Dehalogenation process |
US3786120A (en) * | 1970-10-02 | 1974-01-15 | Gen Electric | Conversion of uranium hexafluoride to uranium dioxide structures of controlled density and grain size |
US3796672A (en) * | 1970-10-02 | 1974-03-12 | Gen Electric | Process for producing uranium dioxide rich compositions from uranium hexafluoride |
US3923619A (en) * | 1974-09-16 | 1975-12-02 | Us Energy | O{HU 18 {B Enrichment process in UO{HD 2{B F{HD 2 {B utilizing laser light |
US4005042A (en) * | 1975-07-02 | 1977-01-25 | General Electric Company | Process for producing uranium rich compositions from uranium hexafluoride using fluid injection in the post oxidation step |
US4117083A (en) * | 1976-12-21 | 1978-09-26 | Exxon Research & Engineering Co. | Process for increasing the reaction rate of UO2 F2 |
US4120936A (en) * | 1977-02-28 | 1978-10-17 | Exxon Research & Engineering Co. | Process for conversion of UF6 to UO2 |
JPS5692124A (en) * | 1979-12-10 | 1981-07-25 | British Nuclear Fuels Ltd | Conversion to oxide of uranium from uranium hexafluoride |
-
1984
- 1984-05-09 JP JP59091034A patent/JPS60235721A/ja active Granted
-
1985
- 1985-05-02 CA CA000480570A patent/CA1285372C/en not_active Expired - Fee Related
- 1985-05-07 FR FR858506941A patent/FR2564085B1/fr not_active Expired - Fee Related
- 1985-05-08 DE DE19853516278 patent/DE3516278A1/de active Granted
- 1985-05-08 US US06/731,984 patent/US4666691A/en not_active Expired - Fee Related
- 1985-05-08 BE BE0/214977A patent/BE902374A/fr not_active IP Right Cessation
- 1985-05-09 GB GB08511787A patent/GB2159135B/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0347497U (ja) * | 1989-09-19 | 1991-05-02 | ||
JPH03111699A (ja) * | 1989-09-26 | 1991-05-13 | Suzuki Seisakusho:Kk | ãã³ã |
Also Published As
Publication number | Publication date |
---|---|
GB2159135B (en) | 1988-08-10 |
CA1285372C (en) | 1991-07-02 |
JPS60235721A (ja) | 1985-11-22 |
DE3516278A1 (de) | 1985-11-14 |
GB2159135A (en) | 1985-11-27 |
US4666691A (en) | 1987-05-19 |
BE902374A (fr) | 1985-09-02 |
DE3516278C2 (ja) | 1993-03-11 |
GB8511787D0 (en) | 1985-06-19 |
FR2564085B1 (fr) | 1991-04-12 |
FR2564085A1 (fr) | 1985-11-15 |
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