JPS63260973A - 微球状感圧性接着剤の製造方法 - Google Patents
微球状感圧性接着剤の製造方法Info
- Publication number
- JPS63260973A JPS63260973A JP9602787A JP9602787A JPS63260973A JP S63260973 A JPS63260973 A JP S63260973A JP 9602787 A JP9602787 A JP 9602787A JP 9602787 A JP9602787 A JP 9602787A JP S63260973 A JPS63260973 A JP S63260973A
- Authority
- JP
- Japan
- Prior art keywords
- meth
- acrylate
- soluble
- adhesive
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004820 Pressure-sensitive adhesive Substances 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 239000000178 monomer Substances 0.000 claims abstract description 30
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 21
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 239000002245 particle Substances 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 9
- 239000007900 aqueous suspension Substances 0.000 claims description 5
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 5
- 239000003505 polymerization initiator Substances 0.000 claims description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 44
- 239000000853 adhesive Substances 0.000 abstract description 42
- 238000006243 chemical reaction Methods 0.000 abstract description 18
- 229920000642 polymer Polymers 0.000 abstract description 9
- 239000003999 initiator Substances 0.000 abstract description 7
- 238000006116 polymerization reaction Methods 0.000 description 13
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 238000004132 cross linking Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 8
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 6
- -1 2-ethylhexyl Chemical group 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 238000006276 transfer reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920006112 polar polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9602787A JPS63260973A (ja) | 1987-04-17 | 1987-04-17 | 微球状感圧性接着剤の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9602787A JPS63260973A (ja) | 1987-04-17 | 1987-04-17 | 微球状感圧性接着剤の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63260973A true JPS63260973A (ja) | 1988-10-27 |
| JPH0579273B2 JPH0579273B2 (enrdf_load_stackoverflow) | 1993-11-01 |
Family
ID=14153893
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9602787A Granted JPS63260973A (ja) | 1987-04-17 | 1987-04-17 | 微球状感圧性接着剤の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63260973A (enrdf_load_stackoverflow) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03504775A (ja) * | 1988-12-20 | 1991-10-17 | ウニヴェルザーレ グルントバウ ゲゼルシャフト エムベーハー | スロット状立て穴の壁の傾斜測定方式 |
| JPH04117478A (ja) * | 1990-09-07 | 1992-04-17 | Sekisui Chem Co Ltd | スプレー性粘着剤組成物 |
| US5719247A (en) * | 1991-12-17 | 1998-02-17 | Minnesota Mining And Manufacturing Company | Tack-free elastomeric acrylate microspheres |
| US6296932B1 (en) | 1998-12-14 | 2001-10-02 | 3M Innovative Properties Company | Microsphere adhesive coated article for use with coated papers |
| USRE37563E1 (en) | 1996-01-16 | 2002-02-26 | 3M Innovative Properties Company | Partially crosslinked microspheres |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61148279A (ja) * | 1984-12-22 | 1986-07-05 | Hoechst Gosei Kk | 感圧性接着シート |
| JPS61148278A (ja) * | 1984-12-22 | 1986-07-05 | Hoechst Gosei Kk | 粘着性微細球水性懸濁液 |
| JPS61152779A (ja) * | 1984-12-27 | 1986-07-11 | Toyo Ink Mfg Co Ltd | 再剥離型粘着剤組成物 |
-
1987
- 1987-04-17 JP JP9602787A patent/JPS63260973A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61148279A (ja) * | 1984-12-22 | 1986-07-05 | Hoechst Gosei Kk | 感圧性接着シート |
| JPS61148278A (ja) * | 1984-12-22 | 1986-07-05 | Hoechst Gosei Kk | 粘着性微細球水性懸濁液 |
| JPS61152779A (ja) * | 1984-12-27 | 1986-07-11 | Toyo Ink Mfg Co Ltd | 再剥離型粘着剤組成物 |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03504775A (ja) * | 1988-12-20 | 1991-10-17 | ウニヴェルザーレ グルントバウ ゲゼルシャフト エムベーハー | スロット状立て穴の壁の傾斜測定方式 |
| JPH04117478A (ja) * | 1990-09-07 | 1992-04-17 | Sekisui Chem Co Ltd | スプレー性粘着剤組成物 |
| US5719247A (en) * | 1991-12-17 | 1998-02-17 | Minnesota Mining And Manufacturing Company | Tack-free elastomeric acrylate microspheres |
| USRE37563E1 (en) | 1996-01-16 | 2002-02-26 | 3M Innovative Properties Company | Partially crosslinked microspheres |
| US6296932B1 (en) | 1998-12-14 | 2001-10-02 | 3M Innovative Properties Company | Microsphere adhesive coated article for use with coated papers |
| US6905763B2 (en) | 1998-12-14 | 2005-06-14 | 3M Innovative Properties Company | Microsphere adhesive coated article for use with coated papers |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0579273B2 (enrdf_load_stackoverflow) | 1993-11-01 |
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