JPS62288837A

JPS62288837A - 生保存後の画像のコントラストの優れた熱現像感光材料

生保存後の画像のコントラストの優れた熱現像感光材料

Info

Publication number: JPS62288837A
Authority: JP; Japan
Prior art keywords: acid; group; silver; layer; dye
Prior art date: 1986-06-07
Legal status : Granted

Application number

JP13247386A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0579977B2 (enrdf_load_stackoverflow

Inventor

Ken Okauchi

謙岡内

Hiroyuki Kakuchi

加口　裕之

Hiroshi Yamazaki

弘山崎

Current Assignee

Konica Minolta Inc

Original Assignee

Konica Minolta Inc

Priority date

1986-06-07

Filing date

1986-06-07

Publication date

1987-12-15

1986-06-07 Application filed by Konica Minolta Inc filed Critical Konica Minolta Inc

1986-06-07 Priority to JP13247386A priority Critical patent/JPS62288837A/ja

1987-12-15 Publication of JPS62288837A publication Critical patent/JPS62288837A/ja

1993-11-05 Publication of JPH0579977B2 publication Critical patent/JPH0579977B2/ja

Status Granted legal-status Critical Current

Links

239000000463 material Substances 0.000 title claims abstract description 100
238000004321 preservation Methods 0.000 title 1
-1 silver halide Chemical class 0.000 claims abstract description 185
239000002253 acid Substances 0.000 claims abstract description 115
229910052709 silver Inorganic materials 0.000 claims abstract description 101
239000004332 silver Substances 0.000 claims abstract description 101
239000003094 microcapsule Substances 0.000 claims abstract description 55
239000002243 precursor Substances 0.000 claims abstract description 49
239000011230 binding agent Substances 0.000 claims abstract description 27
239000003638 chemical reducing agent Substances 0.000 claims abstract description 22
239000011162 core material Substances 0.000 claims abstract description 20
239000000126 substance Substances 0.000 claims description 54
229920000642 polymer Polymers 0.000 abstract description 44
150000007513 acids Chemical class 0.000 abstract description 17
229920001577 copolymer Polymers 0.000 abstract description 17
239000000178 monomer Substances 0.000 abstract description 16
238000010438 heat treatment Methods 0.000 abstract description 11
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract description 9
229920002554 vinyl polymer Polymers 0.000 abstract description 9
229920001519 homopolymer Polymers 0.000 abstract description 3
150000002825 nitriles Chemical class 0.000 abstract description 2
238000006644 Lossen rearrangement reaction Methods 0.000 abstract 1
239000010410 layer Substances 0.000 description 158
150000001875 compounds Chemical class 0.000 description 78
239000000975 dye Substances 0.000 description 77
238000000034 method Methods 0.000 description 62
108010010803 Gelatin Proteins 0.000 description 40
229920000159 gelatin Polymers 0.000 description 40
235000019322 gelatine Nutrition 0.000 description 40
235000011852 gelatine desserts Nutrition 0.000 description 40
239000000839 emulsion Substances 0.000 description 38
239000008273 gelatin Substances 0.000 description 38
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 35
239000011241 protective layer Substances 0.000 description 28
239000006185 dispersion Substances 0.000 description 26
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 26
239000000243 solution Substances 0.000 description 25
239000003795 chemical substances by application Substances 0.000 description 23
125000000217 alkyl group Chemical group 0.000 description 21
238000011161 development Methods 0.000 description 21
239000002904 solvent Substances 0.000 description 21
239000007864 aqueous solution Substances 0.000 description 20
238000002360 preparation method Methods 0.000 description 19
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
229920000036 polyvinylpyrrolidone Polymers 0.000 description 15
239000001267 polyvinylpyrrolidone Substances 0.000 description 15
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 15
125000001424 substituent group Chemical group 0.000 description 15
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
238000000576 coating method Methods 0.000 description 14
125000000623 heterocyclic group Chemical group 0.000 description 14
125000003118 aryl group Chemical group 0.000 description 13
239000011248 coating agent Substances 0.000 description 13
239000006224 matting agent Substances 0.000 description 13
239000002245 particle Substances 0.000 description 13
GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 13
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 12
239000000203 mixture Substances 0.000 description 12
239000004848 polyfunctional curative Substances 0.000 description 12
150000003378 silver Chemical class 0.000 description 11
239000007787 solid Substances 0.000 description 11
229920001223 polyethylene glycol Polymers 0.000 description 10
150000003839 salts Chemical class 0.000 description 10
238000003860 storage Methods 0.000 description 10
238000012546 transfer Methods 0.000 description 10
239000002202 Polyethylene glycol Substances 0.000 description 9
239000004372 Polyvinyl alcohol Substances 0.000 description 9
125000004432 carbon atom Chemical group C* 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 9
150000002148 esters Chemical class 0.000 description 9
238000004519 manufacturing process Methods 0.000 description 9
239000000049 pigment Substances 0.000 description 9
229920002451 polyvinyl alcohol Polymers 0.000 description 9
235000019422 polyvinyl alcohol Nutrition 0.000 description 9
238000011160 research Methods 0.000 description 9
239000004094 surface-active agent Substances 0.000 description 9
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
239000002585 base Substances 0.000 description 8
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 8
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 8
ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 8
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 7
239000000654 additive Substances 0.000 description 7
125000000753 cycloalkyl group Chemical group 0.000 description 7
230000006870 function Effects 0.000 description 7
239000007788 liquid Substances 0.000 description 7
238000002844 melting Methods 0.000 description 7
230000008018 melting Effects 0.000 description 7
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
229910052757 nitrogen Inorganic materials 0.000 description 7
229920000139 polyethylene terephthalate Polymers 0.000 description 7
239000005020 polyethylene terephthalate Substances 0.000 description 7
230000001235 sensitizing effect Effects 0.000 description 7
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
125000004429 atom Chemical group 0.000 description 6
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
125000004435 hydrogen atom Chemical group [H]* 0.000 description 6
150000007524 organic acids Chemical class 0.000 description 6
230000036961 partial effect Effects 0.000 description 6
229920000515 polycarbonate Polymers 0.000 description 6
239000004417 polycarbonate Substances 0.000 description 6
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 6
229940124530 sulfonamide Drugs 0.000 description 6
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
206010070834 Sensitisation Diseases 0.000 description 5
230000002378 acidificating effect Effects 0.000 description 5
125000003545 alkoxy group Chemical group 0.000 description 5
239000008119 colloidal silica Substances 0.000 description 5
239000000470 constituent Substances 0.000 description 5
235000014113 dietary fatty acids Nutrition 0.000 description 5
239000012153 distilled water Substances 0.000 description 5
239000000194 fatty acid Substances 0.000 description 5
229930195729 fatty acid Natural products 0.000 description 5
150000004820 halides Chemical group 0.000 description 5
239000004816 latex Substances 0.000 description 5
229920000126 latex Polymers 0.000 description 5
125000001624 naphthyl group Chemical group 0.000 description 5
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 5
229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 5
229920005989 resin Polymers 0.000 description 5
239000011347 resin Substances 0.000 description 5
230000008313 sensitization Effects 0.000 description 5
125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 5
238000012360 testing method Methods 0.000 description 5
QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 4
KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 4
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 4
DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 4
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 4
229910021612 Silver iodide Inorganic materials 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
125000002947 alkylene group Chemical group 0.000 description 4
150000001412 amines Chemical class 0.000 description 4
239000002216 antistatic agent Substances 0.000 description 4
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
229920002301 cellulose acetate Polymers 0.000 description 4
238000005859 coupling reaction Methods 0.000 description 4
239000013078 crystal Substances 0.000 description 4
230000006866 deterioration Effects 0.000 description 4
238000009826 distribution Methods 0.000 description 4
230000000694 effects Effects 0.000 description 4
235000019441 ethanol Nutrition 0.000 description 4
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
229910052751 metal Chemical group 0.000 description 4
239000002184 metal Chemical group 0.000 description 4
150000002894 organic compounds Chemical class 0.000 description 4
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 4
229920003229 poly(methyl methacrylate) Polymers 0.000 description 4
238000006116 polymerization reaction Methods 0.000 description 4
239000004926 polymethyl methacrylate Substances 0.000 description 4
239000011342 resin composition Substances 0.000 description 4
239000004576 sand Substances 0.000 description 4
230000035945 sensitivity Effects 0.000 description 4
229940045105 silver iodide Drugs 0.000 description 4
239000002356 single layer Substances 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
239000011734 sodium Substances 0.000 description 4
239000003381 stabilizer Substances 0.000 description 4
150000003456 sulfonamides Chemical class 0.000 description 4
150000003512 tertiary amines Chemical class 0.000 description 4
QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 3
150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 3
WXTMDXOMEHJXQO-UHFFFAOYSA-N 2,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC=C1O WXTMDXOMEHJXQO-UHFFFAOYSA-N 0.000 description 3
IBWXIFXUDGADCV-UHFFFAOYSA-N 2h-benzotriazole;silver Chemical compound [Ag].C1=CC=C2NN=NC2=C1 IBWXIFXUDGADCV-UHFFFAOYSA-N 0.000 description 3
LRUDIIUSNGCQKF-UHFFFAOYSA-N 5-methyl-1H-benzotriazole Chemical compound C1=C(C)C=CC2=NNN=C21 LRUDIIUSNGCQKF-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
238000012695 Interfacial polymerization Methods 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
239000004793 Polystyrene Substances 0.000 description 3
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical class CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
239000012190 activator Substances 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
125000003342 alkenyl group Chemical group 0.000 description 3
150000001408 amides Chemical class 0.000 description 3
125000000129 anionic group Chemical group 0.000 description 3
QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 3
229910001864 baryta Inorganic materials 0.000 description 3
150000001565 benzotriazoles Chemical class 0.000 description 3
238000009835 boiling Methods 0.000 description 3
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
239000004327 boric acid Substances 0.000 description 3
239000004202 carbamide Substances 0.000 description 3
239000011247 coating layer Substances 0.000 description 3
230000008878 coupling Effects 0.000 description 3
238000010168 coupling process Methods 0.000 description 3
230000003247 decreasing effect Effects 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
238000010894 electron beam technology Methods 0.000 description 3
125000004185 ester group Chemical group 0.000 description 3
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
229910052737 gold Inorganic materials 0.000 description 3
239000010931 gold Substances 0.000 description 3
125000005843 halogen group Chemical group 0.000 description 3
125000001841 imino group Chemical class [H]N=* 0.000 description 3
229910052738 indium Inorganic materials 0.000 description 3
239000000693 micelle Substances 0.000 description 3
238000002156 mixing Methods 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
239000003921 oil Substances 0.000 description 3
125000000962 organic group Chemical group 0.000 description 3
239000003960 organic solvent Substances 0.000 description 3
LFSXCDWNBUNEEM-UHFFFAOYSA-N phthalazine Chemical compound C1=NN=CC2=CC=CC=C21 LFSXCDWNBUNEEM-UHFFFAOYSA-N 0.000 description 3
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
229920002223 polystyrene Polymers 0.000 description 3
239000004800 polyvinyl chloride Substances 0.000 description 3
229920000915 polyvinyl chloride Polymers 0.000 description 3
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
238000006722 reduction reaction Methods 0.000 description 3
230000002829 reductive effect Effects 0.000 description 3
239000010948 rhodium Substances 0.000 description 3
229910001961 silver nitrate Inorganic materials 0.000 description 3
125000005504 styryl group Chemical group 0.000 description 3
150000005846 sugar alcohols Polymers 0.000 description 3
125000004964 sulfoalkyl group Chemical group 0.000 description 3
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
239000001993 wax Substances 0.000 description 3
TUMNHQRORINJKE-UHFFFAOYSA-N 1,1-diethylurea Chemical compound CCN(CC)C(N)=O TUMNHQRORINJKE-UHFFFAOYSA-N 0.000 description 2
LUBJCRLGQSPQNN-UHFFFAOYSA-N 1-Phenylurea Chemical compound NC(=O)NC1=CC=CC=C1 LUBJCRLGQSPQNN-UHFFFAOYSA-N 0.000 description 2
SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 description 2
SGWZVZZVXOJRAQ-UHFFFAOYSA-N 2,6-Dimethyl-1,4-benzenediol Chemical compound CC1=CC(O)=CC(C)=C1O SGWZVZZVXOJRAQ-UHFFFAOYSA-N 0.000 description 2
DYNQKTWPOTTWGS-UHFFFAOYSA-N 2-(1-bromo-6-methylcyclohexa-2,4-dien-1-yl)sulfonylacetamide Chemical compound CC1C=CC=CC1(Br)S(=O)(=O)CC(N)=O DYNQKTWPOTTWGS-UHFFFAOYSA-N 0.000 description 2
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
MARXMDRWROUXMD-UHFFFAOYSA-N 2-bromoisoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(Br)C(=O)C2=C1 MARXMDRWROUXMD-UHFFFAOYSA-N 0.000 description 2
JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
WVKWKEWFTVEVCF-UHFFFAOYSA-N 2h-benzotriazole-4-sulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC2=NNN=C12 WVKWKEWFTVEVCF-UHFFFAOYSA-N 0.000 description 2
SGVOTZVQRDVUOV-UHFFFAOYSA-N 3-(2,5-dioxopyrrol-1-yl)propylazanium;chloride Chemical compound [Cl-].[NH3+]CCCN1C(=O)C=CC1=O SGVOTZVQRDVUOV-UHFFFAOYSA-N 0.000 description 2
244000215068 Acacia senegal Species 0.000 description 2
239000004925 Acrylic resin Substances 0.000 description 2
229920000178 Acrylic resin Polymers 0.000 description 2
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
235000008733 Citrus aurantifolia Nutrition 0.000 description 2
ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
239000001856 Ethyl cellulose Substances 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
229920000084 Gum arabic Polymers 0.000 description 2
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
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QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
239000000015 trinitrotoluene Substances 0.000 description 1
JBWKIWSBJXDJDT-UHFFFAOYSA-N triphenylmethyl chloride Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(Cl)C1=CC=CC=C1 JBWKIWSBJXDJDT-UHFFFAOYSA-N 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
ASTWEMOBIXQPPV-UHFFFAOYSA-K trisodium;phosphate;dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[Na+].[O-]P([O-])([O-])=O ASTWEMOBIXQPPV-UHFFFAOYSA-K 0.000 description 1
238000000108 ultra-filtration Methods 0.000 description 1
238000001132 ultrasonic dispersion Methods 0.000 description 1
239000006097 ultraviolet radiation absorber Substances 0.000 description 1
150000003672 ureas Chemical class 0.000 description 1
229910052724 xenon Inorganic materials 0.000 description 1
FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
239000001043 yellow dye Substances 0.000 description 1
229910052727 yttrium Inorganic materials 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1