JPS62223141A - アリルエ−テル類の製法 - Google Patents
アリルエ−テル類の製法Info
- Publication number
- JPS62223141A JPS62223141A JP61068137A JP6813786A JPS62223141A JP S62223141 A JPS62223141 A JP S62223141A JP 61068137 A JP61068137 A JP 61068137A JP 6813786 A JP6813786 A JP 6813786A JP S62223141 A JPS62223141 A JP S62223141A
- Authority
- JP
- Japan
- Prior art keywords
- allyl
- reaction
- pentaerythritol
- added
- alkali metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 title abstract description 14
- 238000006243 chemical reaction Methods 0.000 claims abstract description 53
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 claims abstract description 29
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 25
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims abstract description 24
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 13
- 239000007864 aqueous solution Substances 0.000 claims abstract description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 4
- -1 allyl ethers Chemical class 0.000 claims description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 21
- 238000000034 method Methods 0.000 abstract description 9
- 239000002994 raw material Substances 0.000 abstract description 8
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract description 4
- 239000006227 byproduct Substances 0.000 abstract description 3
- 238000007605 air drying Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 229920000728 polyester Polymers 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 238000010992 reflux Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000000243 solution Substances 0.000 description 7
- 239000010410 layer Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 238000005937 allylation reaction Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61068137A JPS62223141A (ja) | 1986-03-25 | 1986-03-25 | アリルエ−テル類の製法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61068137A JPS62223141A (ja) | 1986-03-25 | 1986-03-25 | アリルエ−テル類の製法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62223141A true JPS62223141A (ja) | 1987-10-01 |
| JPH044303B2 JPH044303B2 (enrdf_load_stackoverflow) | 1992-01-27 |
Family
ID=13365060
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61068137A Granted JPS62223141A (ja) | 1986-03-25 | 1986-03-25 | アリルエ−テル類の製法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62223141A (enrdf_load_stackoverflow) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003104177A1 (ja) * | 2002-06-07 | 2003-12-18 | ダイソー株式会社 | アリルエーテル類の製法 |
| CN111848366A (zh) * | 2020-07-28 | 2020-10-30 | 浙江皇马科技股份有限公司 | 季戊四醇二烯丙基醚及其所采用的催化剂的制备方法 |
| CN112645804A (zh) * | 2020-12-21 | 2021-04-13 | 深圳市普利凯新材料股份有限公司 | 季戊四醇三烯丙基醚的合成方法 |
| CN114874075A (zh) * | 2022-05-31 | 2022-08-09 | 浙江皇马科技股份有限公司 | 一种由多元醇烯丙基醚的副产物精制高纯度烯丙醇的方法 |
-
1986
- 1986-03-25 JP JP61068137A patent/JPS62223141A/ja active Granted
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003104177A1 (ja) * | 2002-06-07 | 2003-12-18 | ダイソー株式会社 | アリルエーテル類の製法 |
| JPWO2003104177A1 (ja) * | 2002-06-07 | 2005-10-06 | ダイソー株式会社 | アリルエーテル類の製法 |
| US7157608B2 (en) | 2002-06-07 | 2007-01-02 | Daiso Co., Ltd. | Process for producing allyl ether |
| CN111848366A (zh) * | 2020-07-28 | 2020-10-30 | 浙江皇马科技股份有限公司 | 季戊四醇二烯丙基醚及其所采用的催化剂的制备方法 |
| CN111848366B (zh) * | 2020-07-28 | 2022-08-30 | 浙江皇马科技股份有限公司 | 季戊四醇二烯丙基醚及其所采用的催化剂的制备方法 |
| CN112645804A (zh) * | 2020-12-21 | 2021-04-13 | 深圳市普利凯新材料股份有限公司 | 季戊四醇三烯丙基醚的合成方法 |
| CN114874075A (zh) * | 2022-05-31 | 2022-08-09 | 浙江皇马科技股份有限公司 | 一种由多元醇烯丙基醚的副产物精制高纯度烯丙醇的方法 |
| CN114874075B (zh) * | 2022-05-31 | 2024-01-02 | 浙江皇马科技股份有限公司 | 一种由多元醇烯丙基醚的副产物精制高纯度烯丙醇的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH044303B2 (enrdf_load_stackoverflow) | 1992-01-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |