JPS62176903A - 沃素の製造法 - Google Patents
沃素の製造法Info
- Publication number
- JPS62176903A JPS62176903A JP61242198A JP24219886A JPS62176903A JP S62176903 A JPS62176903 A JP S62176903A JP 61242198 A JP61242198 A JP 61242198A JP 24219886 A JP24219886 A JP 24219886A JP S62176903 A JPS62176903 A JP S62176903A
- Authority
- JP
- Japan
- Prior art keywords
- iodine
- nai
- copper
- molar ratio
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 title claims description 21
- 229910052740 iodine Inorganic materials 0.000 title claims description 21
- 239000011630 iodine Substances 0.000 title claims description 21
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 17
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 14
- 235000009518 sodium iodide Nutrition 0.000 claims description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 239000010949 copper Substances 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 229910052802 copper Inorganic materials 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 7
- 239000001569 carbon dioxide Substances 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 238000000605 extraction Methods 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- 229910052723 transition metal Inorganic materials 0.000 claims description 6
- 150000003624 transition metals Chemical class 0.000 claims description 6
- 229910001516 alkali metal iodide Inorganic materials 0.000 claims description 5
- YCOXTKKNXUZSKD-UHFFFAOYSA-N as-o-xylenol Natural products CC1=CC=C(O)C=C1C YCOXTKKNXUZSKD-UHFFFAOYSA-N 0.000 claims description 5
- SNHMUERNLJLMHN-UHFFFAOYSA-N iodobenzene Chemical compound IC1=CC=CC=C1 SNHMUERNLJLMHN-UHFFFAOYSA-N 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 3
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 229910052707 ruthenium Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
- 230000007062 hydrolysis Effects 0.000 claims description 2
- 238000006460 hydrolysis reaction Methods 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 239000012429 reaction media Substances 0.000 claims description 2
- 229910052715 tantalum Inorganic materials 0.000 claims description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 2
- 239000002638 heterogeneous catalyst Substances 0.000 claims 1
- 239000002815 homogeneous catalyst Substances 0.000 claims 1
- SNHMUERNLJLMHN-IDEBNGHGSA-N iodobenzene Chemical group I[13C]1=[13CH][13CH]=[13CH][13CH]=[13CH]1 SNHMUERNLJLMHN-IDEBNGHGSA-N 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 15
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 7
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 4
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910021595 Copper(I) iodide Inorganic materials 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000004694 iodide salts Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
- LSXDOTMGLUJQCM-UHFFFAOYSA-M copper(i) iodide Chemical compound I[Cu] LSXDOTMGLUJQCM-UHFFFAOYSA-M 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 229960003280 cupric chloride Drugs 0.000 description 1
- 229940045803 cuprous chloride Drugs 0.000 description 1
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 1
- 229940112669 cuprous oxide Drugs 0.000 description 1
- 238000006114 decarboxylation reaction Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- ICIWUVCWSCSTAQ-UHFFFAOYSA-M iodate Chemical compound [O-]I(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-M 0.000 description 1
- -1 iodide ions Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Inorganic materials [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- GCZKMPJFYKFENV-UHFFFAOYSA-K triiodogold Chemical compound I[Au](I)I GCZKMPJFYKFENV-UHFFFAOYSA-K 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- 239000002349 well water Substances 0.000 description 1
- 235000020681 well water Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/13—Iodine; Hydrogen iodide
- C01B7/14—Iodine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT22497A/85 | 1985-10-15 | ||
| IT8522497A IT1207506B (it) | 1985-10-15 | 1985-10-15 | Processo per il recupero dello iodio dallo ioduro sodico. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62176903A true JPS62176903A (ja) | 1987-08-03 |
| JPH0530761B2 JPH0530761B2 (enExample) | 1993-05-10 |
Family
ID=11197067
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61242198A Granted JPS62176903A (ja) | 1985-10-15 | 1986-10-14 | 沃素の製造法 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4857295A (enExample) |
| EP (1) | EP0218998B1 (enExample) |
| JP (1) | JPS62176903A (enExample) |
| AU (1) | AU583155B2 (enExample) |
| CA (1) | CA1287477C (enExample) |
| DE (1) | DE3662384D1 (enExample) |
| ES (1) | ES2007556B3 (enExample) |
| IL (1) | IL80292A0 (enExample) |
| IT (1) | IT1207506B (enExample) |
| ZA (1) | ZA867751B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010215469A (ja) * | 2009-03-18 | 2010-09-30 | Daikin Ind Ltd | ヨウ素の精製方法ならびにヨウ素の製造方法 |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4863710A (en) * | 1988-07-15 | 1989-09-05 | Eastman Kodak Company | Oxidation hydrolysis of iodoalkanes |
| US6004465A (en) * | 1996-06-11 | 1999-12-21 | Pall Corporation | System and process for iodine recovery |
| RU2186721C2 (ru) * | 1999-12-20 | 2002-08-10 | Российский научный центр "Прикладная химия" | Способ извлечения йода из буровых вод |
| RU2210532C1 (ru) * | 2002-06-24 | 2003-08-20 | Талановский Владимир Федорович | Способ получения йодида калия |
| RU2210533C1 (ru) * | 2002-06-24 | 2003-08-20 | Талановский Владимир Федорович | Способ получения йодата калия (варианты) |
| RU2210531C1 (ru) * | 2002-07-25 | 2003-08-20 | Талановский Владимир Федорович | Установка для получения йодированной соли |
| JP5134951B2 (ja) * | 2005-05-02 | 2013-01-30 | 日宝化学株式会社 | ヨウ素の回収方法 |
| JP4948006B2 (ja) * | 2006-03-16 | 2012-06-06 | 合同資源産業株式会社 | 揮発性有機ヨウ素化合物からヨウ素の回収方法 |
| RU2717508C1 (ru) * | 2019-07-22 | 2020-03-23 | Федеральное государственное автономное образовательное учреждение высшего образования «Северный (Арктический) федеральный университет имени М. В. Ломоносова» | Способ извлечения йода |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6021801A (ja) * | 1983-07-14 | 1985-02-04 | Asahi Chem Ind Co Ltd | ヨウ素化芳香族ヒドロキシ化合物の製法 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA815975A (en) * | 1969-06-24 | G. Baur Karl | Recovery of iodine | |
| GB820142A (en) * | 1956-08-06 | 1959-09-16 | Bataafsche Petroleum | Process for the conversion of hydrogen iodide to iodine |
| GB824471A (en) * | 1956-10-18 | 1959-12-02 | Bataafsche Petroleum | Process for the conversion of hydrogen iodide to iodine |
| US2892686A (en) * | 1956-10-26 | 1959-06-30 | Shell Dev | Conversion of hydrogen iodide to iodine |
| US2874031A (en) * | 1956-11-19 | 1959-02-17 | Shell Dev | Conversion of hydrogen iodide to iodine |
| US2892687A (en) * | 1957-01-17 | 1959-06-30 | Shell Dev | Conversion of hydrogen iodide to iodine |
| US3006731A (en) * | 1957-10-29 | 1961-10-31 | Shell Oil Co | Process for the recovery of iodine |
| GB843599A (en) * | 1959-01-29 | 1960-08-04 | Bataafsche Petroleum | A process for the preparation of iodine |
| US3114607A (en) * | 1959-09-01 | 1963-12-17 | Kellogg M W Co | Halogen production |
| GB1005476A (en) * | 1964-01-28 | 1965-09-22 | Shell Int Research | Process for the oxidative preparation of iodine |
| NL134068C (enExample) * | 1964-08-12 | |||
| BR6789382D0 (pt) * | 1966-06-22 | 1973-01-11 | Pechiney Saint Gobain | Processo para a preparacao do amoniaco e do cloro a partir do cloreto de amonio e massas liquidas reagentes utilizadas |
| DE1252180B (de) * | 1967-08-15 | 1967-10-19 | Farbenfabriken Bayer Aktiengesellschaft, Leverkusen | Verwendung von Chromdioxid bzw. Chromdioxidmischphasen als Oxydationskatalysatoren |
| US3760067A (en) * | 1968-06-18 | 1973-09-18 | Velsicol Chemical Corp | Process for the production of elemental halogen |
| FR2244760B1 (enExample) * | 1973-09-25 | 1980-06-27 | Ile De France | |
| JPS51143569A (en) * | 1975-06-06 | 1976-12-09 | Mitsubishi Heavy Ind Ltd | A wet exhaust gas treatment process |
| US4107280A (en) * | 1977-08-01 | 1978-08-15 | Battelle Memorial Institute | Oxidation of hydrogen halides to elemental halogens with catalytic molten salt mixtures |
| JPS53124190A (en) * | 1977-02-18 | 1978-10-30 | Battelle Memorial Institute | Method of reprodcing halogen elements selected from chlorine* bromine and iodine from corresponding hydrogen hologenide |
| US4537835A (en) * | 1977-02-18 | 1985-08-27 | Battelle Memorial Institute | Oxidation of hydrogen halides to elemental halogens |
| IT1152493B (it) * | 1982-08-09 | 1986-12-31 | Bracco Ind Chimica Spa | Metodo per il recupero dello iodio da acque madri ed effluenti contenenti iodio organico |
| DE3369308D1 (en) * | 1982-08-10 | 1987-02-26 | Asahi Chemical Ind | A method for producing iodine or iodine derivatives |
-
1985
- 1985-10-15 IT IT8522497A patent/IT1207506B/it active
-
1986
- 1986-10-02 EP EP86113551A patent/EP0218998B1/en not_active Expired
- 1986-10-02 DE DE8686113551T patent/DE3662384D1/de not_active Expired
- 1986-10-02 ES ES86113551T patent/ES2007556B3/es not_active Expired - Lifetime
- 1986-10-10 IL IL80292A patent/IL80292A0/xx not_active IP Right Cessation
- 1986-10-10 AU AU63813/86A patent/AU583155B2/en not_active Ceased
- 1986-10-13 ZA ZA867751A patent/ZA867751B/xx unknown
- 1986-10-14 JP JP61242198A patent/JPS62176903A/ja active Granted
- 1986-10-14 CA CA000520419A patent/CA1287477C/en not_active Expired - Fee Related
-
1988
- 1988-07-15 US US07/219,818 patent/US4857295A/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6021801A (ja) * | 1983-07-14 | 1985-02-04 | Asahi Chem Ind Co Ltd | ヨウ素化芳香族ヒドロキシ化合物の製法 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010215469A (ja) * | 2009-03-18 | 2010-09-30 | Daikin Ind Ltd | ヨウ素の精製方法ならびにヨウ素の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| IT1207506B (it) | 1989-05-25 |
| DE3662384D1 (en) | 1989-04-20 |
| US4857295A (en) | 1989-08-15 |
| ZA867751B (en) | 1987-05-27 |
| JPH0530761B2 (enExample) | 1993-05-10 |
| ES2007556B3 (es) | 1991-06-16 |
| EP0218998A1 (en) | 1987-04-22 |
| EP0218998B1 (en) | 1989-03-15 |
| CA1287477C (en) | 1991-08-13 |
| IT8522497A0 (it) | 1985-10-15 |
| AU583155B2 (en) | 1989-04-20 |
| IL80292A0 (en) | 1987-01-30 |
| AU6381386A (en) | 1987-04-16 |
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