JPS62170484A - ステンレス鋼の冷間加工用潤滑処理方法 - Google Patents
ステンレス鋼の冷間加工用潤滑処理方法Info
- Publication number
- JPS62170484A JPS62170484A JP61010752A JP1075286A JPS62170484A JP S62170484 A JPS62170484 A JP S62170484A JP 61010752 A JP61010752 A JP 61010752A JP 1075286 A JP1075286 A JP 1075286A JP S62170484 A JPS62170484 A JP S62170484A
- Authority
- JP
- Japan
- Prior art keywords
- stainless steel
- film
- cold working
- oxalate
- oxalic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910001220 stainless steel Inorganic materials 0.000 title claims abstract description 36
- 239000010935 stainless steel Substances 0.000 title claims abstract description 34
- 238000005482 strain hardening Methods 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims abstract description 12
- 230000001050 lubricating effect Effects 0.000 title abstract description 5
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 50
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 9
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims abstract description 7
- 235000019345 sodium thiosulphate Nutrition 0.000 claims abstract description 7
- 238000005461 lubrication Methods 0.000 claims description 10
- 229920003169 water-soluble polymer Polymers 0.000 claims description 7
- VGYYSIDKAKXZEE-UHFFFAOYSA-L hydroxylammonium sulfate Chemical compound O[NH3+].O[NH3+].[O-]S([O-])(=O)=O VGYYSIDKAKXZEE-UHFFFAOYSA-L 0.000 claims description 6
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 claims description 6
- 239000000344 soap Substances 0.000 abstract description 9
- 239000000314 lubricant Substances 0.000 abstract description 6
- 229910000831 Steel Inorganic materials 0.000 abstract description 4
- 239000010959 steel Substances 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 3
- 238000007598 dipping method Methods 0.000 abstract description 2
- VRXOQUOGDYKXFA-UHFFFAOYSA-N hydroxylamine;sulfuric acid Chemical compound ON.ON.OS(O)(=O)=O VRXOQUOGDYKXFA-UHFFFAOYSA-N 0.000 abstract 2
- -1 PVA Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 13
- 238000012545 processing Methods 0.000 description 10
- 238000005260 corrosion Methods 0.000 description 9
- 230000007797 corrosion Effects 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 150000001805 chlorine compounds Chemical class 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 206010010904 Convulsion Diseases 0.000 description 4
- 150000002222 fluorine compounds Chemical class 0.000 description 4
- 238000005755 formation reaction Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 230000006911 nucleation Effects 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 230000001603 reducing effect Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 241000272814 Anser sp. Species 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000010622 cold drawing Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 101150000426 ftcd gene Proteins 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- RBLWMQWAHONKNC-UHFFFAOYSA-N hydroxyazanium Chemical compound O[NH3+] RBLWMQWAHONKNC-UHFFFAOYSA-N 0.000 description 1
- 229910001293 incoloy Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- BEJNERDRQOWKJM-UHFFFAOYSA-N kojic acid Chemical compound OCC1=CC(=O)C(O)=CO1 BEJNERDRQOWKJM-UHFFFAOYSA-N 0.000 description 1
- 229960004705 kojic acid Drugs 0.000 description 1
- WZNJWVWKTVETCG-UHFFFAOYSA-N kojic acid Natural products OC(=O)C(N)CN1C=CC(=O)C(O)=C1 WZNJWVWKTVETCG-UHFFFAOYSA-N 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/46—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing oxalates
Landscapes
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Metal Extraction Processes (AREA)
- Chemical Treatment Of Metals (AREA)
- Lubricants (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61010752A JPS62170484A (ja) | 1986-01-21 | 1986-01-21 | ステンレス鋼の冷間加工用潤滑処理方法 |
DE19873700933 DE3700933A1 (de) | 1986-01-21 | 1987-01-15 | Verfahren zur erleichterung der kaltumformung von edelstahl |
AT87200060T ATE51423T1 (de) | 1986-01-21 | 1987-01-16 | Verfahren zur erleichterung der kaltumformung von edelstahl. |
EP87200060A EP0232929B1 (de) | 1986-01-21 | 1987-01-16 | Verfahren zur Erleichterung der Kaltumformung von Edelstahl |
DE8787200060T DE3762053D1 (de) | 1986-01-21 | 1987-01-16 | Verfahren zur erleichterung der kaltumformung von edelstahl. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61010752A JPS62170484A (ja) | 1986-01-21 | 1986-01-21 | ステンレス鋼の冷間加工用潤滑処理方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62170484A true JPS62170484A (ja) | 1987-07-27 |
JPH0129872B2 JPH0129872B2 (enrdf_load_html_response) | 1989-06-14 |
Family
ID=11759045
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61010752A Granted JPS62170484A (ja) | 1986-01-21 | 1986-01-21 | ステンレス鋼の冷間加工用潤滑処理方法 |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0232929B1 (enrdf_load_html_response) |
JP (1) | JPS62170484A (enrdf_load_html_response) |
AT (1) | ATE51423T1 (enrdf_load_html_response) |
DE (2) | DE3700933A1 (enrdf_load_html_response) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002088387A (ja) * | 2000-09-14 | 2002-03-27 | Sakai Chem Ind Co Ltd | 非塩素系潤滑油組成物を使用する金属加工 |
JP2009530499A (ja) * | 2006-03-23 | 2009-08-27 | ジルコトゥビ・ソシエタ・ア・レスポンサビリタ・リミタータ | 高強度を有する溶接可能でステンレスの管状構造体の製造システム及びそれから得られた製品 |
CN111500955A (zh) * | 2020-04-17 | 2020-08-07 | 抚顺特殊钢股份有限公司 | 一种核电蒸发器用n06625合金异型材制造工艺 |
US11607929B2 (en) | 2018-08-09 | 2023-03-21 | Hanon Systems | Thermal cycle resistant fastening system for refrigerant fitting |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA3128951A1 (en) * | 2019-02-14 | 2020-08-20 | Chemetall Gmbh | Simplified process for the pretreatment of metallic substrates for cold forming and a reactive lubricant for this purpose |
CA3168959A1 (en) | 2020-02-25 | 2021-09-02 | Yinfeng SHI | One-step pretreatment method of metallic substrates for metal cold forming |
US20230106175A1 (en) | 2020-02-25 | 2023-04-06 | Chemetall Gmbh | One-step pretreatment method of metallic substrates for metal cold forming |
WO2022207901A1 (en) | 2021-04-01 | 2022-10-06 | Chemetall Gmbh | One-step pretreatment method of metallic substrates at non-neutral ph values for metal cold forming |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2759862A (en) * | 1952-03-11 | 1956-08-21 | Devex Corp | Coating compositions and method of treating ferrous surfaces therewith |
CA930651A (en) * | 1971-01-12 | 1973-07-24 | Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Energy, Mines, And Resources | Forming oxalate conversion coatings on iron or steel |
JPS524255B2 (enrdf_load_html_response) * | 1972-08-26 | 1977-02-02 | ||
DE2424382A1 (de) * | 1974-05-20 | 1975-12-04 | Metallgesellschaft Ag | Verfahren zur vorbereitung von metallischen werkstuecken fuer die spanlose kaltumformung |
-
1986
- 1986-01-21 JP JP61010752A patent/JPS62170484A/ja active Granted
-
1987
- 1987-01-15 DE DE19873700933 patent/DE3700933A1/de not_active Withdrawn
- 1987-01-16 DE DE8787200060T patent/DE3762053D1/de not_active Expired - Lifetime
- 1987-01-16 AT AT87200060T patent/ATE51423T1/de not_active IP Right Cessation
- 1987-01-16 EP EP87200060A patent/EP0232929B1/de not_active Expired - Lifetime
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002088387A (ja) * | 2000-09-14 | 2002-03-27 | Sakai Chem Ind Co Ltd | 非塩素系潤滑油組成物を使用する金属加工 |
JP2009530499A (ja) * | 2006-03-23 | 2009-08-27 | ジルコトゥビ・ソシエタ・ア・レスポンサビリタ・リミタータ | 高強度を有する溶接可能でステンレスの管状構造体の製造システム及びそれから得られた製品 |
US11607929B2 (en) | 2018-08-09 | 2023-03-21 | Hanon Systems | Thermal cycle resistant fastening system for refrigerant fitting |
CN111500955A (zh) * | 2020-04-17 | 2020-08-07 | 抚顺特殊钢股份有限公司 | 一种核电蒸发器用n06625合金异型材制造工艺 |
Also Published As
Publication number | Publication date |
---|---|
JPH0129872B2 (enrdf_load_html_response) | 1989-06-14 |
EP0232929A1 (de) | 1987-08-19 |
ATE51423T1 (de) | 1990-04-15 |
DE3762053D1 (de) | 1990-05-03 |
EP0232929B1 (de) | 1990-03-28 |
DE3700933A1 (de) | 1987-07-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |