JPS6132439B2 - - Google Patents
Info
- Publication number
- JPS6132439B2 JPS6132439B2 JP53096286A JP9628678A JPS6132439B2 JP S6132439 B2 JPS6132439 B2 JP S6132439B2 JP 53096286 A JP53096286 A JP 53096286A JP 9628678 A JP9628678 A JP 9628678A JP S6132439 B2 JPS6132439 B2 JP S6132439B2
- Authority
- JP
- Japan
- Prior art keywords
- formula
- dyeing
- phthalate ester
- ester represented
- carried out
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 phthalate ester Chemical class 0.000 claims description 53
- 238000004043 dyeing Methods 0.000 claims description 43
- 239000000975 dye Substances 0.000 claims description 37
- 229920000728 polyester Polymers 0.000 claims description 28
- 239000000835 fiber Substances 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 21
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 239000000986 disperse dye Substances 0.000 claims description 5
- 230000002829 reductive effect Effects 0.000 claims description 5
- 238000010186 staining Methods 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 238000007796 conventional method Methods 0.000 claims description 2
- 125000004185 ester group Chemical group 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 23
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 9
- 239000002657 fibrous material Substances 0.000 description 9
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
- 239000004744 fabric Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 239000003112 inhibitor Substances 0.000 description 6
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 150000002009 diols Chemical class 0.000 description 4
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 4
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 3
- 235000011130 ammonium sulphate Nutrition 0.000 description 3
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 230000032050 esterification Effects 0.000 description 3
- 238000005886 esterification reaction Methods 0.000 description 3
- 235000019253 formic acid Nutrition 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- CDMGNVWZXRKJNS-UHFFFAOYSA-N 2-benzylphenol Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1 CDMGNVWZXRKJNS-UHFFFAOYSA-N 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 238000010533 azeotropic distillation Methods 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical class OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- 235000013351 cheese Nutrition 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 125000005498 phthalate group Chemical class 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- BPDZDPZLOCOSSP-UHFFFAOYSA-N (1,2,2,2-tetrachloro-1-phenoxyethyl) hypochlorite Chemical compound ClOC(Cl)(C(Cl)(Cl)Cl)OC1=CC=CC=C1 BPDZDPZLOCOSSP-UHFFFAOYSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- XDGKEKZKZIAFNK-UHFFFAOYSA-N 2,2,2-trichloro-1-phenoxyethanol Chemical compound ClC(Cl)(Cl)C(O)OC1=CC=CC=C1 XDGKEKZKZIAFNK-UHFFFAOYSA-N 0.000 description 1
- PQSMEVPHTJECDZ-UHFFFAOYSA-N 2,3-dimethylheptan-2-ol Chemical compound CCCCC(C)C(C)(C)O PQSMEVPHTJECDZ-UHFFFAOYSA-N 0.000 description 1
- RYRZSXJVEILFRR-UHFFFAOYSA-N 2,3-dimethylterephthalic acid Chemical compound CC1=C(C)C(C(O)=O)=CC=C1C(O)=O RYRZSXJVEILFRR-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- CYCRZLRIJWDWCM-UHFFFAOYSA-N 2-aminonaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(N)=CC(=O)C2=C1 CYCRZLRIJWDWCM-UHFFFAOYSA-N 0.000 description 1
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 description 1
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 1
- LHYQAEFVHIZFLR-UHFFFAOYSA-L 4-(4-diazonio-3-methoxyphenyl)-2-methoxybenzenediazonium;dichloride Chemical compound [Cl-].[Cl-].C1=C([N+]#N)C(OC)=CC(C=2C=C(OC)C([N+]#N)=CC=2)=C1 LHYQAEFVHIZFLR-UHFFFAOYSA-L 0.000 description 1
- JKOCGAMDKVAHCI-UHFFFAOYSA-N 6,7-Benzocoumarin Chemical compound C1=CC=C2C=C(OC(=O)C=C3)C3=CC2=C1 JKOCGAMDKVAHCI-UHFFFAOYSA-N 0.000 description 1
- GDALETGZDYOOGB-UHFFFAOYSA-N Acridone Natural products C1=C(O)C=C2N(C)C3=CC=CC=C3C(=O)C2=C1O GDALETGZDYOOGB-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 241000519995 Stachys sylvatica Species 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- FZEYVTFCMJSGMP-UHFFFAOYSA-N acridone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3NC2=C1 FZEYVTFCMJSGMP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 description 1
- XJHABGPPCLHLLV-UHFFFAOYSA-N benzo[de]isoquinoline-1,3-dione Chemical compound C1=CC(C(=O)NC2=O)=C3C2=CC=CC3=C1 XJHABGPPCLHLLV-UHFFFAOYSA-N 0.000 description 1
- 125000004541 benzoxazolyl group Chemical group O1C(=NC2=C1C=CC=C2)* 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- 229960000956 coumarin Drugs 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000003493 decenyl group Chemical group [H]C([*])=C([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 125000005066 dodecenyl group Chemical group C(=CCCCCCCCCCC)* 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 244000144992 flock Species 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- DBNYMXPUYZOHQN-UHFFFAOYSA-N n'-[2-(octadecylamino)ethyl]ethane-1,2-diamine Chemical compound CCCCCCCCCCCCCCCCCCNCCNCCN DBNYMXPUYZOHQN-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 239000001005 nitro dye Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 150000004893 oxazines Chemical class 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000004289 sodium hydrogen sulphite Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 125000001425 triazolyl group Chemical group 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 238000009976 warp beam dyeing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65125—Compounds containing ester groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
æ¬çºæã¯ç¹ã«é©åœãªãã¿ã«é
žãšã¹ãã«ã®é©çšã®
äžã§èŠèªã§ãããããªãªãªãŽããŒã®æ²æããã³ãª
ãªãŽããŒã«ããæ©æŠãé¿ããããŸãã¯éåžžã«æžå°
ããããããªãšã¹ãã«ç¹ç¶ã®æè²ãŸãã¯åŸåŠçæ³
ã«é¢ããã
äžã§èŠèªã§ãããããªãªãªãŽããŒã®æ²æããã³ãª
ãªãŽããŒã«ããæ©æŠãé¿ããããŸãã¯éåžžã«æžå°
ããããããªãšã¹ãã«ç¹ç¶ã®æè²ãŸãã¯åŸåŠçæ³
ã«é¢ããã
ããªãšã¹ãã«ç¹ç¶ã®è£œé ã«ãããŠã¯ãäžè¬ã«90
ééïŒ ä»¥äžãç°åŒïŒéäœãããªããªãªãŽããŒãç
æããããã®ãªãªãŽããŒã¯é«æž©æ¡ä»¶ãäŸãã°110
ã140âã®äžã§ã®æè²ã«ãããŠç¹ç¶è¡šé¢äžãŸãã¯
æè²æµŽäžã«ç§»è¡ãããšãããå·åŽã«éãçµæ¶å
ããïŒéšã¯ããã«ç¹ç¶è¡šé¢ã«ããããŠïŒéšã¯è£ 眮
ã®å£ã«æ²çããããã®ãªãªãŽããŒã¯æºè¶³ã«ã¯æè²
ã§ããªãã®ã§ãèŠãããšãã§ããçµæ¶ãšããŠç¹ç¶
è¡šé¢ã«æ®åãããããæ ç¹ç¶ã®ãã以åŸã®å å·¥äŸ
ãã°çŽ¡ç³žãæŽçµãç·šæãç¹æã«ãããŠãç¹ç¶è¡šé¢
ã«ä»çããçµæ¶ãæ©æŠæµæãå¢å€§ããäŸãã°ç³žè£
ãã®åå ãšãªããå°é£æ§ãçããããŸãé«æž©æè²
ãããç¹ç¶ã¯é«ãæ©æŠã瀺ããããã¯ãã®ç¹ç¶ã
æ¡å è£ çœ®ãšæ¥è§Šãããããªãã¡æ©æ¢°çãªã¹ãã¬ã¹
ãè² è·ããããšããã§ã¯åžžã«äžå¿«ã«ç®ç«ã€ãã¹ã
ãäžããã
ééïŒ ä»¥äžãç°åŒïŒéäœãããªããªãªãŽããŒãç
æããããã®ãªãªãŽããŒã¯é«æž©æ¡ä»¶ãäŸãã°110
ã140âã®äžã§ã®æè²ã«ãããŠç¹ç¶è¡šé¢äžãŸãã¯
æè²æµŽäžã«ç§»è¡ãããšãããå·åŽã«éãçµæ¶å
ããïŒéšã¯ããã«ç¹ç¶è¡šé¢ã«ããããŠïŒéšã¯è£ 眮
ã®å£ã«æ²çããããã®ãªãªãŽããŒã¯æºè¶³ã«ã¯æè²
ã§ããªãã®ã§ãèŠãããšãã§ããçµæ¶ãšããŠç¹ç¶
è¡šé¢ã«æ®åãããããæ ç¹ç¶ã®ãã以åŸã®å å·¥äŸ
ãã°çŽ¡ç³žãæŽçµãç·šæãç¹æã«ãããŠãç¹ç¶è¡šé¢
ã«ä»çããçµæ¶ãæ©æŠæµæãå¢å€§ããäŸãã°ç³žè£
ãã®åå ãšãªããå°é£æ§ãçããããŸãé«æž©æè²
ãããç¹ç¶ã¯é«ãæ©æŠã瀺ããããã¯ãã®ç¹ç¶ã
æ¡å è£ çœ®ãšæ¥è§Šãããããªãã¡æ©æ¢°çãªã¹ãã¬ã¹
ãè² è·ããããšããã§ã¯åžžã«äžå¿«ã«ç®ç«ã€ãã¹ã
ãäžããã
ãã€ãç¹èš±å
¬é第2403859å·ã«ããã°ã130â以
äžã«ãããããªãšã¹ãã«ç¹ç¶ã®æè²ã®éã®ãªãªãŽ
ããŒæ²æã¯ããã®æè²ãççŽ ååïŒã10åãæã€
èèªæããã³è³éŠæ眮æèèªæïŒäŸ¡ã¢ã«ã³ãŒã«ã®
ãã¿ã«é žãžãšã¹ãã«ã®ååšã®äžã«è¡ãããšã«ãã€
ãŠé¿ãããããããããããã®ãšã¹ãã«é©çšã®äž
ã§æè²ãããç¹ç¶ã¯ãç¹ã«ä¹Ÿç¥æ±ãã«å¯Ÿã匷ãæ±
ãæãã瀺ãã
äžã«ãããããªãšã¹ãã«ç¹ç¶ã®æè²ã®éã®ãªãªãŽ
ããŒæ²æã¯ããã®æè²ãççŽ ååïŒã10åãæã€
èèªæããã³è³éŠæ眮æèèªæïŒäŸ¡ã¢ã«ã³ãŒã«ã®
ãã¿ã«é žãžãšã¹ãã«ã®ååšã®äžã«è¡ãããšã«ãã€
ãŠé¿ãããããããããããã®ãšã¹ãã«é©çšã®äž
ã§æè²ãããç¹ç¶ã¯ãç¹ã«ä¹Ÿç¥æ±ãã«å¯Ÿã匷ãæ±
ãæãã瀺ãã
æ¬çºæè
ã¯ç 究ã®çµæãåèšã®ãªãªãŽããŒåé¡
ãå æãããšåæã«ç¹ç¶ååã®æ±ãæå¶ã«ã¯å ã«
ãã圱é¿ããªãé©åœãªãã¿ã«é žãšã¹ãã«ãèŠåºã
ãã
ãå æãããšåæã«ç¹ç¶ååã®æ±ãæå¶ã«ã¯å ã«
ãã圱é¿ããªãé©åœãªãã¿ã«é žãšã¹ãã«ãèŠåºã
ãã
åŸã€ãŠæ¬çºæã¯åŒ
ïŒãã®åŒã§ãã¯ããããççŽ ååïŒã22åããš
ããã12ã18åããã€ã¢ã«ãã«åºãŸãã¯ã¢ã«ã±ã
ã«åºã§ãããX1ãšX2ãšã®äžïŒã€ã¯æ°ŽçŽ ååãŸã
ã¯ã¡ãã«åºã§ãã€ãŠãä»ã¯æ°ŽçŽ ååã§ãããã¯
æ°ŽçŽ ååãŸãã¯ççŽ ååïŒãïŒåããã€ã¢ã«ãã«
åºãç¹ã«ã¡ãã«åºãŸãã¯ãšãã«åºã§ãããïœã¯ïŒ
ãïŒããšãããïŒãŸãã¯ïŒã§ããïŒ ã§è¡šãããããã¿ã«é žãšã¹ãã«ããæè²ã®éãŸã
ã¯åŸã«é©çšããããã¿ã«é žãšã¹ãã«ååšã®äžã«ã
ããããªãšã¹ãã«ç¹ç¶ã®æè²ãŸãã¯åŸåŠçã®ãã
ã®æ¹æ³ã«é¢ããã
ããã12ã18åããã€ã¢ã«ãã«åºãŸãã¯ã¢ã«ã±ã
ã«åºã§ãããX1ãšX2ãšã®äžïŒã€ã¯æ°ŽçŽ ååãŸã
ã¯ã¡ãã«åºã§ãã€ãŠãä»ã¯æ°ŽçŽ ååã§ãããã¯
æ°ŽçŽ ååãŸãã¯ççŽ ååïŒãïŒåããã€ã¢ã«ãã«
åºãç¹ã«ã¡ãã«åºãŸãã¯ãšãã«åºã§ãããïœã¯ïŒ
ãïŒããšãããïŒãŸãã¯ïŒã§ããïŒ ã§è¡šãããããã¿ã«é žãšã¹ãã«ããæè²ã®éãŸã
ã¯åŸã«é©çšããããã¿ã«é žãšã¹ãã«ååšã®äžã«ã
ããããªãšã¹ãã«ç¹ç¶ã®æè²ãŸãã¯åŸåŠçã®ãã
ã®æ¹æ³ã«é¢ããã
åŒ(1)ã§è¡šãããããã¿ã«é
žãšã¹ãã«ã®æ·»å ã¯ã
ãªãšã¹ãã«ç¹ç¶ã®æè²ã®éã奜ãŸããã
ãªãšã¹ãã«ç¹ç¶ã®æè²ã®éã奜ãŸããã
ãšã¹ãã«åºâCOORã¯ïœâäœãïœâäœãŸãã¯ïœ
âäœã«ååšããããšãã§ããããšããããããïœ
âäœã«ãããããæ ïœâãã¿ã«é žãžãšã¹ãã«ã圢
æããŠããããšã奜ãŸãããããã察å¿ãããã¬
ãã¿ã«é žãžãšã¹ãã«ãç¹ã«å¥œãŸããã
âäœã«ååšããããšãã§ããããšããããããïœ
âäœã«ãããããæ ïœâãã¿ã«é žãžãšã¹ãã«ã圢
æããŠããããšã奜ãŸãããããã察å¿ãããã¬
ãã¿ã«é žãžãšã¹ãã«ãç¹ã«å¥œãŸããã
ãšãããåŒ(1)ã«ãããŠã¯ïŒ²ã¯ççŽ ååïŒã22
åãç¹ã«12ã18åããã€ã¢ã«ãã«åºã§ãããX1
ãšX2ãšã¯ããããæ°ŽçŽ ååã§ãããã¯ãšãã
ãæ°ŽçŽ ååã§ããã
åãç¹ã«12ã18åããã€ã¢ã«ãã«åºã§ãããX1
ãšX2ãšã¯ããããæ°ŽçŽ ååã§ãããã¯ãšãã
ãæ°ŽçŽ ååã§ããã
ãã¢ã«ãã«åºã®å ŽååºäŸãã°ïœâããã·ã«
åºãïœâãªã¯ãã«åºãïŒâãšãã«ããã·ã«åºãïœ
âãã·ã«åºãïœâããã·ã«åºãããªã¹ãã«åºãïœ
âãããµãã·ã«åºãïœâããã¿ãã·ã«åºãïœâãª
ã¯ã¿ãã·ã«åºãŸãã¯ãããã«åºãåé¡ã«ãªãã
ã«ã€ããŠã¢ã«ã±ãã«åºãšããŠã¯äŸãã°ãã»ãã«
åºãããã»ãã«åºããããµãã»ãã«åºãŸãã¯ãªã¬
ã€ã«åºãèããããã
åºãïœâãªã¯ãã«åºãïŒâãšãã«ããã·ã«åºãïœ
âãã·ã«åºãïœâããã·ã«åºãããªã¹ãã«åºãïœ
âãããµãã·ã«åºãïœâããã¿ãã·ã«åºãïœâãª
ã¯ã¿ãã·ã«åºãŸãã¯ãããã«åºãåé¡ã«ãªãã
ã«ã€ããŠã¢ã«ã±ãã«åºãšããŠã¯äŸãã°ãã»ãã«
åºãããã»ãã«åºããããµãã»ãã«åºãŸãã¯ãªã¬
ã€ã«åºãèããããã
åŒ(1)ã§è¡šãããããæ¬çºæã«åŸã€ãŠé©çšããã
ãšã¹ãã«ã¯ïŒéšã¯ç©è³ªãšããŠå ¬ç¥ã§ãããããèª
äœå ¬ç¥ã®æ¹æ³ã«åŸã€ãŠè£œé ããŠããããäŸãã°è£œ
é ã¯ããªã«ãœãã¿ã«é žãã€ãœãã¿ã«é žãŸãã¯ãã¬
ãã¿ã«é žãããã¯ç¹ã«ãã¿ã«é žç¡æ°Žç©ãä»»æã®é
åºã§åŒ âOH (2) ã§è¡šããããã¢ã«ã³ãŒã«ããã³å Žåã«ãã€ãŠã¯åŒ ïŒãããã®åŒã§ããšX1ãšX2ãšïŒºãšïœãšã¯åèšã®
æå³ããã€ïŒ ã§è¡šããããã¢ããšãŒãã«åãããŠãããžãªãŒã«
ãšãåå¿ãããŠè¡ãããšãã§ããã
ãšã¹ãã«ã¯ïŒéšã¯ç©è³ªãšããŠå ¬ç¥ã§ãããããèª
äœå ¬ç¥ã®æ¹æ³ã«åŸã€ãŠè£œé ããŠããããäŸãã°è£œ
é ã¯ããªã«ãœãã¿ã«é žãã€ãœãã¿ã«é žãŸãã¯ãã¬
ãã¿ã«é žãããã¯ç¹ã«ãã¿ã«é žç¡æ°Žç©ãä»»æã®é
åºã§åŒ âOH (2) ã§è¡šããããã¢ã«ã³ãŒã«ããã³å Žåã«ãã€ãŠã¯åŒ ïŒãããã®åŒã§ããšX1ãšX2ãšïŒºãšïœãšã¯åèšã®
æå³ããã€ïŒ ã§è¡šããããã¢ããšãŒãã«åãããŠãããžãªãŒã«
ãšãåå¿ãããŠè¡ãããšãã§ããã
ãã¿ã«é
žç¡æ°Žç©é©çšã®éã¯ãšã¹ãã«åã段éç
ã«è¡ãã®ãæå©ã§ããããã®å Žå第ïŒã«ã¢ãã¢ã«
ã³ãŒã«ïŒ²âOHãããŠãã®åŸåŒ(3)ã§è¡šãããããž
ãªãŒã«ãšåå¿ãããã®ã奜ãŸããã
ã«è¡ãã®ãæå©ã§ããããã®å Žå第ïŒã«ã¢ãã¢ã«
ã³ãŒã«ïŒ²âOHãããŠãã®åŸåŒ(3)ã§è¡šãããããž
ãªãŒã«ãšåå¿ãããã®ã奜ãŸããã
åŒ(2)ãš(3)ã§è¡šããããã¢ã«ã³ãŒã«ãåå¥ã§ãã
ãã¯æ··åç©ã§é©çšããŠãããã
ãã¯æ··åç©ã§é©çšããŠãããã
åŒ(2)ã§è¡šããããé«çŽèèªæã¢ã«ã³ãŒã«ã«ãã
ãŠã¯äŸãã°ãšãããççŽ ååïŒã22åããã€æ°Žäž
溶æ§ã®èèªæã¢ãã¢ã«ã³ãŒã«ãåé¡ã«ãªãããã
ãã®ã¢ã«ã³ãŒã«ã¯é£œåãããã¯äžé£œåã§ããããŠ
åæéãããã¯çŽéã§ãããããããŠããã®ã¿ã
ããã¯æ··åããŠçšããŠãããã倩ç¶ã®èèªæã¢ã«
ã³ãŒã«äŸãã°ã©ãŠãªã«ã¢ã«ã³ãŒã«ãããªã¹ãã«ã¢
ã«ã³ãŒã«ãã»ãã«ã¢ã«ã³ãŒã«ããªã¬ã€ã«ã¢ã«ã³ãŒ
ã«ãã¹ãã¢ãªã«ã¢ã«ã³ãŒã«ãã¢ã©ãã«ã¢ã«ã³ãŒã«
ãŸãã¯ãããã«ã¢ã«ã³ãŒã«ãããã¯åæã®èèªæ
ã¢ã«ã³ãŒã«äŸãã°ç¹ã«ïŒâãšãã«ãããµããŒã«ã
ããã«ããªã¡ãã«ãããµããŒã«ãããªã¡ãã«ãã
ã«ã¢ã«ã³ãŒã«ããããµãã·ã«ã¢ã«ã³ãŒã«ãŸãã¯ã¢
ã«ããªãŒã«ãé©çšããŠããããã¢ã«ããªãŒã«ã«ã
ããŠã¯çŽé第ïŒã¢ã«ã³ãŒã«ãåé¡ã«ãªãããã®å
ã®åŸã®æ°ãã¢ã«ã³ãŒã«ã®å¹³åççŽ ååæ°ãäžã
ãããã®ã¢ã«ããªãŒã«ã®å¹Ÿã€ãã®äŸã¯ã¢ã«ããªãŒ
ã«ïŒâ10ïŒ10â14ïŒ16â18ããã³20â22ã§ããã
ãŠã¯äŸãã°ãšãããççŽ ååïŒã22åããã€æ°Žäž
溶æ§ã®èèªæã¢ãã¢ã«ã³ãŒã«ãåé¡ã«ãªãããã
ãã®ã¢ã«ã³ãŒã«ã¯é£œåãããã¯äžé£œåã§ããããŠ
åæéãããã¯çŽéã§ãããããããŠããã®ã¿ã
ããã¯æ··åããŠçšããŠãããã倩ç¶ã®èèªæã¢ã«
ã³ãŒã«äŸãã°ã©ãŠãªã«ã¢ã«ã³ãŒã«ãããªã¹ãã«ã¢
ã«ã³ãŒã«ãã»ãã«ã¢ã«ã³ãŒã«ããªã¬ã€ã«ã¢ã«ã³ãŒ
ã«ãã¹ãã¢ãªã«ã¢ã«ã³ãŒã«ãã¢ã©ãã«ã¢ã«ã³ãŒã«
ãŸãã¯ãããã«ã¢ã«ã³ãŒã«ãããã¯åæã®èèªæ
ã¢ã«ã³ãŒã«äŸãã°ç¹ã«ïŒâãšãã«ãããµããŒã«ã
ããã«ããªã¡ãã«ãããµããŒã«ãããªã¡ãã«ãã
ã«ã¢ã«ã³ãŒã«ããããµãã·ã«ã¢ã«ã³ãŒã«ãŸãã¯ã¢
ã«ããªãŒã«ãé©çšããŠããããã¢ã«ããªãŒã«ã«ã
ããŠã¯çŽé第ïŒã¢ã«ã³ãŒã«ãåé¡ã«ãªãããã®å
ã®åŸã®æ°ãã¢ã«ã³ãŒã«ã®å¹³åççŽ ååæ°ãäžã
ãããã®ã¢ã«ããªãŒã«ã®å¹Ÿã€ãã®äŸã¯ã¢ã«ããªãŒ
ã«ïŒâ10ïŒ10â14ïŒ16â18ããã³20â22ã§ããã
ãšãããççŽ åå12ã18åããã€ã¢ã«ã³ãŒã«ã
é©çšããããã®å Žåç¹ã«ã¹ãã¢ãªã«ã¢ã«ã³ãŒã«ãš
ã¢ã«ããªãŒã«10â14ãšãè¯å¥œã§ããããšã蚌æã
ããŠããã
é©çšããããã®å Žåç¹ã«ã¹ãã¢ãªã«ã¢ã«ã³ãŒã«ãš
ã¢ã«ããªãŒã«10â14ãšãè¯å¥œã§ããããšã蚌æã
ããŠããã
åŒ(3)ã§è¡šãããããžãªãŒã«ãšããŠã¯ç¹ã«ãšãã¬
ã³ã°ãªã³ãŒã«ãïŒïŒïŒâãããã¬ã³ã°ãªã³ãŒã«ã
ãžãšãã¬ã³ã°ãªã³ãŒã«ãŸãã¯å¹³åååé150ã194
ã®ãªãªãŽãšãã¬ã³ã°ãªã³ãŒã«ãèããããããžãš
ãã¬ã³ã°ãªã³ãŒã«ã奜ãŸãããåŒ(3)ã§è¡šãããã
ãžãªãŒã«ã®ã¢ãC1âC4ã¢ã«ãã«ãšãŒãã«ãç¹ã«
ãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ãŸãã¯â
ã¢ããšãã«ãšãŒãã«ããžãšãã¬ã³ã°ãªã³ãŒã«ã¢ã
ã¡ãã«ãšãŒãã«ãŸãã¯âã¢ããšãã«ãšãŒãã«ããŸ
ãããŸãé©çšã§ããã
ã³ã°ãªã³ãŒã«ãïŒïŒïŒâãããã¬ã³ã°ãªã³ãŒã«ã
ãžãšãã¬ã³ã°ãªã³ãŒã«ãŸãã¯å¹³åååé150ã194
ã®ãªãªãŽãšãã¬ã³ã°ãªã³ãŒã«ãèããããããžãš
ãã¬ã³ã°ãªã³ãŒã«ã奜ãŸãããåŒ(3)ã§è¡šãããã
ãžãªãŒã«ã®ã¢ãC1âC4ã¢ã«ãã«ãšãŒãã«ãç¹ã«
ãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ãŸãã¯â
ã¢ããšãã«ãšãŒãã«ããžãšãã¬ã³ã°ãªã³ãŒã«ã¢ã
ã¡ãã«ãšãŒãã«ãŸãã¯âã¢ããšãã«ãšãŒãã«ããŸ
ãããŸãé©çšã§ããã
åŒ(2)ãš(3)ãšã§è¡šããããã¢ã«ã³ãŒã«ã§ã®ãã¿ã«
é žã®ãšã¹ãã«åã¯æº¶å€ãªããŸãã¯åå¿æåã«å¯Ÿã
ãŠäžæŽ»æ§ã®æº¶å€äŸãã°ãã³ãŒã³ããã«ãšã³ãã¯ã
ããã³ãŒã³ãŸãã¯ããããã³ãŒã³äžããšããã80
ã120âã§æå©ã«è¡ããããã®å Žåçž®åæ°Žãå ±æ²ž
èžçã§é€å»ããããšãã§ããããã®ãšã¹ãã«åã®
觊åªã«ã¯è§Šåªéã®åŒ·é žäŸãã°ç¡«é žãŸãã¯ïœâãã«
ãšã³ã¹ã«ãã³é žãé žè§ŠåªãšããŠæ·»å ããŠãããã
é žã®ãšã¹ãã«åã¯æº¶å€ãªããŸãã¯åå¿æåã«å¯Ÿã
ãŠäžæŽ»æ§ã®æº¶å€äŸãã°ãã³ãŒã³ããã«ãšã³ãã¯ã
ããã³ãŒã³ãŸãã¯ããããã³ãŒã³äžããšããã80
ã120âã§æå©ã«è¡ããããã®å Žåçž®åæ°Žãå ±æ²ž
èžçã§é€å»ããããšãã§ããããã®ãšã¹ãã«åã®
觊åªã«ã¯è§Šåªéã®åŒ·é žäŸãã°ç¡«é žãŸãã¯ïœâãã«
ãšã³ã¹ã«ãã³é žãé žè§ŠåªãšããŠæ·»å ããŠãããã
æ¬çºæã«é©çšã§ãããã¿ã«é
žãšã¹ãã«ã¯çµæã«
ãã€ãŠãããªãã¡èŠªæ°Žåºå¯ŸèŠªæ²¹åºã®æ¯ã«ãã€ãŠå¯
溶æ§ãŸãã¯ä¹³åæ§ã§ãããäžè¬ã«30ã60ééïŒ æ°Ž
æ§æº¶æ¶²ãŸãã¯ä¹³å液ã補é ã§ããããã®ä¹³å液ã¯
䟿å®çãªæ·»å ç©äŸãã°ä¹³åå€ãŸãã¯æ¹¿æœ€å€ãå«æ
ããŠããããé©åœãªä¹³åå€ã¯äŸãã°é žæ§ãšã¹ãã«
äŸãã°ççŽ ååïŒã22åããã€ã¢ã«ã³ãŒã«ãããš
ãã«ããšããŒã«ãŸãã¯ã¢ã«ãã«éšåã«ççŽ ååïŒ
ã16åããã€ã¢ã«ãã«ããšããŒã«ãžã®ãšãã¬ã³ãª
ãã·ãããã³ïŒãŸãã¯ïŒãããã¬ã³ãªãã·ãïŒâ
12ã¢ã«ä»å çæç©ã®ãªã³é žãšã¹ãã«ãŸãã¯ç¹ã«ç¡«
é žãšã¹ãã«ã§ããããããã¯éé¢ã®é žãããã¯ç¹
ã«ã¢ã³ã¢ããŠã å¡©ãŸãã¯ã¢ã«ã«ãªéå±å¡©ãšããŠå
åšããŠããŠãããã
ãã€ãŠãããªãã¡èŠªæ°Žåºå¯ŸèŠªæ²¹åºã®æ¯ã«ãã€ãŠå¯
溶æ§ãŸãã¯ä¹³åæ§ã§ãããäžè¬ã«30ã60ééïŒ æ°Ž
æ§æº¶æ¶²ãŸãã¯ä¹³å液ã補é ã§ããããã®ä¹³å液ã¯
䟿å®çãªæ·»å ç©äŸãã°ä¹³åå€ãŸãã¯æ¹¿æœ€å€ãå«æ
ããŠããããé©åœãªä¹³åå€ã¯äŸãã°é žæ§ãšã¹ãã«
äŸãã°ççŽ ååïŒã22åããã€ã¢ã«ã³ãŒã«ãããš
ãã«ããšããŒã«ãŸãã¯ã¢ã«ãã«éšåã«ççŽ ååïŒ
ã16åããã€ã¢ã«ãã«ããšããŒã«ãžã®ãšãã¬ã³ãª
ãã·ãããã³ïŒãŸãã¯ïŒãããã¬ã³ãªãã·ãïŒâ
12ã¢ã«ä»å çæç©ã®ãªã³é žãšã¹ãã«ãŸãã¯ç¹ã«ç¡«
é žãšã¹ãã«ã§ããããããã¯éé¢ã®é žãããã¯ç¹
ã«ã¢ã³ã¢ããŠã å¡©ãŸãã¯ã¢ã«ã«ãªéå±å¡©ãšããŠå
åšããŠããŠãããã
æ¬çºæã«åŸã€ãŠé©çšããããã¿ã«é
žãšã¹ãã«ã®
å žåçäŸã¯æ¬¡ã®åŒã«å¯Ÿå¿ãããã®ã§ããã
å žåçäŸã¯æ¬¡ã®åŒã«å¯Ÿå¿ãããã®ã§ããã
R1ïŒã¢ã«ããªãŒã« 10â14ã®æ®åº
R2ïŒã¢ã«ããªãŒã« 16â18ã®æ®åº
R3ïŒã¢ã«ããªãŒã« 16â18 80ééïŒ
ãšã¢ã«
ããªãŒã« 10â14 20ééïŒ ãšã®æ··åç©ã®æ®åº R1ïŒã¢ã«ããªãŒã« 10â14ã®æ®åº R1ïŒã¢ã«ããªãŒã« 10â14ã®æ®åº R1ïŒã¢ã«ããªãŒã« 10â14ã®æ®åº R1ïŒã¢ã«ããªãŒã« 10â14ã®æ®åº R1ïŒã¢ã«ããªãŒã« 10â14ã®æ®åº ãã¿ã«é žãšã¹ãã«ã®äœ¿çšéã¯æ¬çºæã«åŸãæå©ã«
ã¯æ°Žæ§æ液ãŸãã¯åŸåŠç浞液ïŒåœã0.1ãïŒ
ïœããšãããïŒãïŒïœã®éãå€åããã
ããªãŒã« 10â14 20ééïŒ ãšã®æ··åç©ã®æ®åº R1ïŒã¢ã«ããªãŒã« 10â14ã®æ®åº R1ïŒã¢ã«ããªãŒã« 10â14ã®æ®åº R1ïŒã¢ã«ããªãŒã« 10â14ã®æ®åº R1ïŒã¢ã«ããªãŒã« 10â14ã®æ®åº R1ïŒã¢ã«ããªãŒã« 10â14ã®æ®åº ãã¿ã«é žãšã¹ãã«ã®äœ¿çšéã¯æ¬çºæã«åŸãæå©ã«
ã¯æ°Žæ§æ液ãŸãã¯åŸåŠç浞液ïŒåœã0.1ãïŒ
ïœããšãããïŒãïŒïœã®éãå€åããã
ããªãšã¹ãã«ææãšããŠã¯ãäŸãã°ãã¬ãã¿ã«
é žãšãšãã¬ã³ã°ãªã³ãŒã«ãããã¯ã€ãœãã¿ã«é žãŸ
ãã¯ãã¬ãã¿ã«é žãšïŒïŒïŒâãã¹âïŒããããã·
ã¡ãã«âïŒã·ã¯ããããµã³ãšã®ããªçž®åã«ãã€ãŠ
åŸãããããããã¯ãã¬ãã¿ã«é žãšã€ãœãã¿ã«é ž
ããã³ãšãã¬ã³ã°ãªã³ãŒã«ãšããåŸãããæ··åã
ãªããŒã§ããç·ç¶ããªãšã¹ãã«ã®ç¹ç¶ææãèã
ããããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãããã®ç¹ç¶
ã奜ãŸããã
é žãšãšãã¬ã³ã°ãªã³ãŒã«ãããã¯ã€ãœãã¿ã«é žãŸ
ãã¯ãã¬ãã¿ã«é žãšïŒïŒïŒâãã¹âïŒããããã·
ã¡ãã«âïŒã·ã¯ããããµã³ãšã®ããªçž®åã«ãã€ãŠ
åŸãããããããã¯ãã¬ãã¿ã«é žãšã€ãœãã¿ã«é ž
ããã³ãšãã¬ã³ã°ãªã³ãŒã«ãšããåŸãããæ··åã
ãªããŒã§ããç·ç¶ããªãšã¹ãã«ã®ç¹ç¶ææãèã
ããããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãããã®ç¹ç¶
ã奜ãŸããã
åèšç¹ç¶ææã¯ãŸãããèªèº«ã®ãŸãã¯ä»ã®ç¹ç¶
ãšã®æ··ç¹åžäŸãã°ããªã¢ã¯ãªããããªã«ïŒããªãš
ã¹ãã«ãããªã¢ããïŒããªãšã¹ãã«ãããªãšã¹ã
ã«ïŒãã¹ã³ãŒã¹ããã³ããªãšã¹ãã«ïŒçŸæ¯ãšãã
ã®æ··åç©ãšããŠé©çšããŠãããã
ãšã®æ··ç¹åžäŸãã°ããªã¢ã¯ãªããããªã«ïŒããªãš
ã¹ãã«ãããªã¢ããïŒããªãšã¹ãã«ãããªãšã¹ã
ã«ïŒãã¹ã³ãŒã¹ããã³ããªãšã¹ãã«ïŒçŸæ¯ãšãã
ã®æ··åç©ãšããŠé©çšããŠãããã
åèšç¹ç¶ææã¯ãã®éçš®é¡ã®å 工段éäŸãã°ã
ããã¯ãããŠã糞ãç·šåžãäŸãã°äžç¹ã®ãŸãã¯ç¹
æã®åæåãŸãã¯ç·šæåãšããŠååšããããšãã§
ããã
ããã¯ãããŠã糞ãç·šåžãäŸãã°äžç¹ã®ãŸãã¯ç¹
æã®åæåãŸãã¯ç·šæåãšããŠååšããããšãã§
ããã
åèšããªãšã¹ãã«ç¹ç¶ææã¯æå©ã«åæ£ææã§
æè²ããããåæ£ææãšããŠã¯æ¹æ³ã«ããç·ç¶ã
ãªãšã¹ãã«ããã§ããŠããç¹ç¶ææã®æè²ã«ã¯å ¬
ç¥ã®ãäžè¬ã«æ°Žæº¶æ§ã«ããåºããªãæ液äžã§åŸ®çŽ°
ãªåæ£ã®åœ¢ã§ååšããæ°Žã«é£æº¶ã®ææãèããã
ãã
æè²ããããåæ£ææãšããŠã¯æ¹æ³ã«ããç·ç¶ã
ãªãšã¹ãã«ããã§ããŠããç¹ç¶ææã®æè²ã«ã¯å ¬
ç¥ã®ãäžè¬ã«æ°Žæº¶æ§ã«ããåºããªãæ液äžã§åŸ®çŽ°
ãªåæ£ã®åœ¢ã§ååšããæ°Žã«é£æº¶ã®ææãèããã
ãã
ãã®ææã¯çš®é¡äŸãã°ã¢ã¯ãªãã³ææãããã
ææãã¡ãã³ææãããªã¡ãã³ææãã¹ããªã«æ
æãã¢ãŸã¹ããªã«ææãããµã³ãã³ææããªããµ
ãžã³ææãããªãã³ææãã¢ãããããããã³æ
æãã¯ããªã³ææããããŠç¹ã«ã¢ã³ãã©ããã³æ
æãšã¢ãŸææäŸãã°ã¢ãã¢ãŸææãšãžã¢ãŸææã«
å±ããŠããŠãããã
ææãã¡ãã³ææãããªã¡ãã³ææãã¹ããªã«æ
æãã¢ãŸã¹ããªã«ææãããµã³ãã³ææããªããµ
ãžã³ææãããªãã³ææãã¢ãããããããã³æ
æãã¯ããªã³ææããããŠç¹ã«ã¢ã³ãã©ããã³æ
æãšã¢ãŸææäŸãã°ã¢ãã¢ãŸææãšãžã¢ãŸææã«
å±ããŠããŠãããã
ãããã®ææã®æ··åç©ã䜿çšããŠãããã
æ¬çºæã«é©çšããããã¿ã«é
žãšã¹ãã«ã¯ãŸãæ
è²ãããŠããªãããªãšã¹ãã«ç¹ç¶ææã®éå³ä»ã
ã®å Žåæ°Žäžã«é£æº¶ã®å åŠçå¢çœå€ãšå ±ã«çšããŠã
ããã
è²ãããŠããªãããªãšã¹ãã«ç¹ç¶ææã®éå³ä»ã
ã®å Žåæ°Žäžã«é£æº¶ã®å åŠçå¢çœå€ãšå ±ã«çšããŠã
ããã
åŸè
ã¯ä»»æã®å¢çœå€ã®çš®é¡ã«å±ãããç¹ã«ãã
ã¯ã¯ããªã³ç³»ããã³ãŸã¯ããªã³ç³»ããã©ãžã³ç³»ã
ãã©ãŸãªã³ç³»ããªããµãžã³ç³»ãããªã¢ãŸãªã«ç³»ã
ãã³ãŸãªããµãŸãªã«ç³»ããã³ãŸãã©ã³ç³»ãŸãã¯ã
ã³ãŸã€ãããŸãªã«ç³»ãŸãã¯ããã¿ã«ã€ããç³»ã®å
åŠçå¢çœå€ãåé¡ã«ãªãã
ã¯ã¯ããªã³ç³»ããã³ãŸã¯ããªã³ç³»ããã©ãžã³ç³»ã
ãã©ãŸãªã³ç³»ããªããµãžã³ç³»ãããªã¢ãŸãªã«ç³»ã
ãã³ãŸãªããµãŸãªã«ç³»ããã³ãŸãã©ã³ç³»ãŸãã¯ã
ã³ãŸã€ãããŸãªã«ç³»ãŸãã¯ããã¿ã«ã€ããç³»ã®å
åŠçå¢çœå€ãåé¡ã«ãªãã
æ液ã«å ããææã®éã¯ææã®æè²åŒ·åºŠã«åŸ
ããäžè¬ã«ã¯äœ¿çšããç¹ç¶ææã«å¯Ÿã0.01ã10é
éïŒ ã®éãç¶æãããã
ããäžè¬ã«ã¯äœ¿çšããç¹ç¶ææã«å¯Ÿã0.01ã10é
éïŒ ã®éãç¶æãããã
ææã®å Žåã¯æ济ã¯ææãšãªãªãŽããŒé²æ¢å€ã®
ä»ã«ããªãšã¹ãã«ç¹ç¶ã®æè²ã«å¯Ÿãæè²ä¿é²å€ãš
ããŠåããã€ãªã€ãŒãŸãã¯ãã€ãªã€ãŒæ··åç©ãå«
æãããå Žåã«ãã€ãŠã¯ïŒç·ã«é©çšããããã€ãª
ã€ãŒãšããŠã¯äŸãã°ããšãã«ããšããŒã«ããã³ãž
ã«ããšããŒã«ãããªã¯ãããã³ãŒã³ããã·ã¬ã³ã
ããªã¡ãã«ãã³ãŒã³ãããã¿ãªã³ããžããšãã«ã
ãžããšãã«ãšãŒãã«ããžã¡ãã«ãžããšãã«ãšãŒã
ã«ãå®æ¯éŠé žã¢ã«ãã«ãå®æ¯éŠé žã¢ãªãŒã«äŸãã°
å®æ¯éŠé žããšãã«ããã³å®æ¯éŠé žïŒâãšãã«ããš
ãã«ãããã«ãã¿ã«é žãžã¡ãã«ããã³ãžã«ã¢ã«ã³
ãŒã«ãã¢ãâããžâããã³ããªã¯ããããšããã·
ãšã¿ããŒã«ãŸãã¯âãããããŒã«ãããã¯ãã³ã¿
ã¯ããããšããã·ãšã¿ããŒã«ãæããããã
ä»ã«ããªãšã¹ãã«ç¹ç¶ã®æè²ã«å¯Ÿãæè²ä¿é²å€ãš
ããŠåããã€ãªã€ãŒãŸãã¯ãã€ãªã€ãŒæ··åç©ãå«
æãããå Žåã«ãã€ãŠã¯ïŒç·ã«é©çšããããã€ãª
ã€ãŒãšããŠã¯äŸãã°ããšãã«ããšããŒã«ããã³ãž
ã«ããšããŒã«ãããªã¯ãããã³ãŒã³ããã·ã¬ã³ã
ããªã¡ãã«ãã³ãŒã³ãããã¿ãªã³ããžããšãã«ã
ãžããšãã«ãšãŒãã«ããžã¡ãã«ãžããšãã«ãšãŒã
ã«ãå®æ¯éŠé žã¢ã«ãã«ãå®æ¯éŠé žã¢ãªãŒã«äŸãã°
å®æ¯éŠé žããšãã«ããã³å®æ¯éŠé žïŒâãšãã«ããš
ãã«ãããã«ãã¿ã«é žãžã¡ãã«ããã³ãžã«ã¢ã«ã³
ãŒã«ãã¢ãâããžâããã³ããªã¯ããããšããã·
ãšã¿ããŒã«ãŸãã¯âãããããŒã«ãããã¯ãã³ã¿
ã¯ããããšããã·ãšã¿ããŒã«ãæããããã
åèšæ济ã¯ãã€ãªã€ãŒã0.1ã10ïœ/ãæå©ã«
ã¯0.3ãïŒïœ/å«æããŠãããã
ã¯0.3ãïŒïœ/å«æããŠãããã
åèšæ济ã¯é±é
žäŸãã°ç¡«é
žãŸãã¯ãªã³é
žãææ©
é žãæå©ã«ã¯äœçŽèèªæã«ã«ãã³é žäŸãã°ã®é žã
é ¢é žããŸãã¯ã·ãŠãŠé žããã³ïŒãŸãã¯ïŒå¡©äŸãã°
é ¢é žã¢ã³ã¢ããŠã ãç¡«é žã¢ã³ã¢ããŠã ãŸãã¯é ¢é ž
ãããªãŠã ãå«æããŠãããããããã®é žã¯ãšã
ããæ¬çºæã§é©çšãããæ液ã®pHå€ããäžè¬ã«
ã¯ïŒãïŒããšããã4.5ã6.5ã«èª¿ç¯ããã®ã«åœ¹ç«
ã€ã
é žãæå©ã«ã¯äœçŽèèªæã«ã«ãã³é žäŸãã°ã®é žã
é ¢é žããŸãã¯ã·ãŠãŠé žããã³ïŒãŸãã¯ïŒå¡©äŸãã°
é ¢é žã¢ã³ã¢ããŠã ãç¡«é žã¢ã³ã¢ããŠã ãŸãã¯é ¢é ž
ãããªãŠã ãå«æããŠãããããããã®é žã¯ãšã
ããæ¬çºæã§é©çšãããæ液ã®pHå€ããäžè¬ã«
ã¯ïŒãïŒããšããã4.5ã6.5ã«èª¿ç¯ããã®ã«åœ¹ç«
ã€ã
ããã«åèšæ济ã¯åæ£å€ãšãããé°ã€ãªã³æ§ãŸ
ãã¯éã€ãªã³æ§ã®åæ£å€ãå«æããŠãããããã
ãã¯ãšãããåæ£ææã®è¯å¥œãªåŸ®çŽ°ãªåé éæã«
圹ç«ã€ãããã¯åæ£ææãçšããæè²ã«ãããŠäž
è¬çã«äœ¿çšãããåæ£å€ãåé¡ã«ãªãã
ãã¯éã€ãªã³æ§ã®åæ£å€ãå«æããŠãããããã
ãã¯ãšãããåæ£ææã®è¯å¥œãªåŸ®çŽ°ãªåé éæã«
圹ç«ã€ãããã¯åæ£ææãçšããæè²ã«ãããŠäž
è¬çã«äœ¿çšãããåæ£å€ãåé¡ã«ãªãã
åèšæ济ã¯ããã«éåžžã®é»è§£è³ªãåæå€ã湿最
å€ãæè»åå€ãããã³ããç«é²æ¢å€ãå«æããŠã
ãããå Žåã«ãã€ãŠã¯ãªãªãŽããŒé²æ¢å€ããæ济
ãžã®æ·»å ã®åã«æ¹¿æœ€å€äŸãã°ã¹ã«ãã³é žèèªæã¢
ã«ãã«ãèèªæã¢ã«ãã«ããªã°ãªã³ãŒã«ãšãŒãã«
ããã³ã·ãªã³ã³ããç«é²æ¢å€ãšäžç·ã«ãŸãã¯ã¢ã«
ãã«ããšããŒã«ãžã®ãšãã¬ã³ãªãã·ãä»å ç©ã®é ž
æ§ãšã¹ãã«ãšïŒç·ã«æ°Žã®äžã«æº¶è§£ãŸãã¯ä¹³åãã
ãããšãã§ããã
å€ãæè»åå€ãããã³ããç«é²æ¢å€ãå«æããŠã
ãããå Žåã«ãã€ãŠã¯ãªãªãŽããŒé²æ¢å€ããæ济
ãžã®æ·»å ã®åã«æ¹¿æœ€å€äŸãã°ã¹ã«ãã³é žèèªæã¢
ã«ãã«ãèèªæã¢ã«ãã«ããªã°ãªã³ãŒã«ãšãŒãã«
ããã³ã·ãªã³ã³ããç«é²æ¢å€ãšäžç·ã«ãŸãã¯ã¢ã«
ãã«ããšããŒã«ãžã®ãšãã¬ã³ãªãã·ãä»å ç©ã®é ž
æ§ãšã¹ãã«ãšïŒç·ã«æ°Žã®äžã«æº¶è§£ãŸãã¯ä¹³åãã
ãããšãã§ããã
åèšã®æè²ã¯æ°Žæ§æ液ããåžå°œæ³ã«ãã€ãŠæå©
ã«è¡ãããããšãããããããé«æž©æ³ã«ããå¯é
ãããŠããå§åäžå®ã®è£ 眮äžæž©åºŠ106â以äžãæ
å©ã«ã¯110ã140âããšããã125ã135âãå å§ã®
äžã§æè²ãããå¯é容åšãšããŠã¯äŸãã°åŸªç°è£ 眮
äŸãã°ããŒãºæãè£ çœ®ãŸãã¯ããŒã æãè£ çœ®ããŠ
ã€ã³ã¹ããããããºã«æãè£ çœ®ãŸãã¯ãã©ã æã
è£ çœ®ãããã«æãè£ çœ®ãããã¯ãžãã¬ãŒæãè£ çœ®
ãé©åœã§ããã
ã«è¡ãããããšãããããããé«æž©æ³ã«ããå¯é
ãããŠããå§åäžå®ã®è£ 眮äžæž©åºŠ106â以äžãæ
å©ã«ã¯110ã140âããšããã125ã135âãå å§ã®
äžã§æè²ãããå¯é容åšãšããŠã¯äŸãã°åŸªç°è£ 眮
äŸãã°ããŒãºæãè£ çœ®ãŸãã¯ããŒã æãè£ çœ®ããŠ
ã€ã³ã¹ããããããºã«æãè£ çœ®ãŸãã¯ãã©ã æã
è£ çœ®ãããã«æãè£ çœ®ãããã¯ãžãã¬ãŒæãè£ çœ®
ãé©åœã§ããã
æ液æ¯ã¯ããæ
åºãç¯å²äžã§ãäŸãã°ïŒïŒïŒã
ïŒïŒ100ããšãããïŒïŒ10ãïŒïŒ50ã®ç¯å²å ã§éž
æã§ããã
ïŒïŒ100ããšãããïŒïŒ10ãïŒïŒ50ã®ç¯å²å ã§éž
æã§ããã
åèšã®æ¹æ³ã¯æè²ç©ããŸããªãªãŽããŒé²æ¢å€ãš
å Žåã«ãã€ãŠã¯ãã€ãªã€ãŒãšã§åŠçããã€ãã§æ
è²ããŠè¡ããããæè²ç©ããªãªãŽããŒé²æ¢å€ãšæ
æãšäœ¿çšããããšãããããå©å€ãšåæã«åŠçã
ãŠè¡ãããšãã§ããã
å Žåã«ãã€ãŠã¯ãã€ãªã€ãŒãšã§åŠçããã€ãã§æ
è²ããŠè¡ããããæè²ç©ããªãªãŽããŒé²æ¢å€ãšæ
æãšäœ¿çšããããšãããããå©å€ãšåæã«åŠçã
ãŠè¡ãããšãã§ããã
ãšãããç¹ç©ææã¯ãªãªãŽããŒé²æ¢å€ãšãã€ãª
ã€ãŒãšãå«æãã枩床60ã80âã瀺ãæ液äžã«å ¥
ãããã®ææããã®æž©åºŠã§ïŒã15åéåŠçããã
ãã®åŸ60ã90âã§ææãå ããæ液ã®æž©åºŠãåŸã
ã«ã枩床ç¯å²110ã140âã«ãããŠ60ã90åããšã
ãã45ã60åã§æè²ããããã«äžæãããã
ã€ãŒãšãå«æãã枩床60ã80âã瀺ãæ液äžã«å ¥
ãããã®ææããã®æž©åºŠã§ïŒã15åéåŠçããã
ãã®åŸ60ã90âã§ææãå ããæ液ã®æž©åºŠãåŸã
ã«ã枩床ç¯å²110ã140âã«ãããŠ60ã90åããšã
ãã45ã60åã§æè²ããããã«äžæãããã
çµãã«ãã®æ液ãçŽ70ã90âã«å·åŽããæè²ã
ããææãéåžžã®ããã«ãããã也ç¥ãããå¿ èŠ
ã®å Žåã¯ãã®æè²ç©ãéåžžã®éå çåŸæŽæµã«ãã
ãããšãã§ããã
ããææãéåžžã®ããã«ãããã也ç¥ãããå¿ èŠ
ã®å Žåã¯ãã®æè²ç©ãéåžžã®éå çåŸæŽæµã«ãã
ãããšãã§ããã
ããªãšã¹ãã«ç¹ç¶ææã®ãåŒ(1)ã§è¡šãããããš
ã¹ãã«ã§ã®åŸåŠçã¯äžè¬ã«é«æž©æ¡ä»¶ã§éæããã
ããªãšã¹ãã«ææã®æè²ã«åŒãã€ã¥ãè¡ãããã
ãšãããããã¯äŸãã°æž©åºŠ50ã100âããšããã
70ã90âã§è¡ãã
ã¹ãã«ã§ã®åŸåŠçã¯äžè¬ã«é«æž©æ¡ä»¶ã§éæããã
ããªãšã¹ãã«ææã®æè²ã«åŒãã€ã¥ãè¡ãããã
ãšãããããã¯äŸãã°æž©åºŠ50ã100âããšããã
70ã90âã§è¡ãã
åèšåŸåŠçã¯ä»ã®åŸåŠçæäœãšé£çµãããšæå©
ã«ã§ãããäŸãã°åèšããªãšã¹ãã«æè²ç©ãéåžž
ã®æ¹æ³ã«ããäºç¡«é žæ°ŽçŽ ãããªãŠã ãçšãéå ç
ã«åŸæŽæµããã¢ã«ã«ãªæ§æµŽã«åŒ(1)ã§è¡šãããããš
ã¹ãã«ãæ·»å ããéå çæŽæµãšãªãªãŽããŒé²æ¢å€
ãçšããåŸåŠçãšãïŒã€ã®å 工工çšã§è¡ãããšã
ã§ããã
ã«ã§ãããäŸãã°åèšããªãšã¹ãã«æè²ç©ãéåžž
ã®æ¹æ³ã«ããäºç¡«é žæ°ŽçŽ ãããªãŠã ãçšãéå ç
ã«åŸæŽæµããã¢ã«ã«ãªæ§æµŽã«åŒ(1)ã§è¡šãããããš
ã¹ãã«ãæ·»å ããéå çæŽæµãšãªãªãŽããŒé²æ¢å€
ãçšããåŸåŠçãšãïŒã€ã®å 工工çšã§è¡ãããšã
ã§ããã
æ¬çºæã®æ¹æ³ã®å©ãã«ããããªãšã¹ãã«ç¹ç¶ã®
é«æž©æè²ã«ãããŠç°¡åãªæ¹æ³ã§äžæ§ãªæè²ãéæ
ã§ããåæã«ç¹ç©ååäžãªãã³ã«æè²è£ 眮ãžã®ãª
ãªãŽããŒã®æ²çãé²æ¢ããããšã«æåããããã®
äžç¹ç¶ååã®æ±ãæå¶ã¯æ¬çºæã«é©çšããããã¿
ã«é žãšã¹ãã«ã«ããã»ãã®å ãã害ãããªããåŒ
(1)ã§è¡šãããããã¿ã«é žãšã¹ãã«ã®äœçšã¯ãªãªãŽ
ããŒãïŒéšã¯ä¹³åããïŒéšã¯ç¹ç¶ã«çµåããããš
ã«ããã
é«æž©æè²ã«ãããŠç°¡åãªæ¹æ³ã§äžæ§ãªæè²ãéæ
ã§ããåæã«ç¹ç©ååäžãªãã³ã«æè²è£ 眮ãžã®ãª
ãªãŽããŒã®æ²çãé²æ¢ããããšã«æåããããã®
äžç¹ç¶ååã®æ±ãæå¶ã¯æ¬çºæã«é©çšããããã¿
ã«é žãšã¹ãã«ã«ããã»ãã®å ãã害ãããªããåŒ
(1)ã§è¡šãããããã¿ã«é žãšã¹ãã«ã®äœçšã¯ãªãªãŽ
ããŒãïŒéšã¯ä¹³åããïŒéšã¯ç¹ç¶ã«çµåããããš
ã«ããã
æ¬çºæã«åŸãæè²ãããç¹ç¶ã¯ãã®æ©æŠãäœäž
ãããããšã§ããç«ã€ãŠããããªãªãŽããŒã®æ²æ
ãããã¯æ©æŠã®æžå°ã¯çŽ¡çžŸç³žã«ãããŠã糞巻ã®é
æè²ããã玡瞟糞ãããéãéããŠå ãé»è²ã®å
çŽã«å°ããšäºãããšã§ç€ºãããããã®é玡瞟糞ã®
è¡šé¢ã«æ»çãããªãªãŽããŒã¯è±èœãããããã§ãª
ãªãŽããŒå«æéãåŸãããçœè²ã®æç¹ã®å€§ãããš
å¯åºŠãšã«åºãèŠèŠã§å€æãããããããªãªãŽããŒ
ã®éã¯ãŸãééçã«æž¬å®ãã§ããã
ãããããšã§ããç«ã€ãŠããããªãªãŽããŒã®æ²æ
ãããã¯æ©æŠã®æžå°ã¯çŽ¡çžŸç³žã«ãããŠã糞巻ã®é
æè²ããã玡瞟糞ãããéãéããŠå ãé»è²ã®å
çŽã«å°ããšäºãããšã§ç€ºãããããã®é玡瞟糞ã®
è¡šé¢ã«æ»çãããªãªãŽããŒã¯è±èœãããããã§ãª
ãªãŽããŒå«æéãåŸãããçœè²ã®æç¹ã®å€§ãããš
å¯åºŠãšã«åºãèŠèŠã§å€æãããããããªãªãŽããŒ
ã®éã¯ãŸãééçã«æž¬å®ãã§ããã
æ¬çºæã«åŸãæ¹æ³ã§æè²ãããã¯åŸåŠçãããŠ
ããããªãšã¹ãã«ç¹ç¶ã®çŽ¡çžŸç³žã¯ãŸãããããæ
糞ãããŠããããç¹ã«ç³žã®ç Žãã®æ°ã®äœäžã§æ糞
è£ çœ®ã®çšŒåçãèããåäžãããæãããªæå©ã
ã¯ãŸã玡瞟äŸãã°ããªãšã¹ãã«ããŠã®çŽ¡çžŸã®éã«
瀺ãããé害ãšãªãæ©æŠãåºç¯å²ã«æžå°ããã
ããããªãšã¹ãã«ç¹ç¶ã®çŽ¡çžŸç³žã¯ãŸãããããæ
糞ãããŠããããç¹ã«ç³žã®ç Žãã®æ°ã®äœäžã§æ糞
è£ çœ®ã®çšŒåçãèããåäžãããæãããªæå©ã
ã¯ãŸã玡瞟äŸãã°ããªãšã¹ãã«ããŠã®çŽ¡çžŸã®éã«
瀺ãããé害ãšãªãæ©æŠãåºç¯å²ã«æžå°ããã
ãã®ä»ã®æå©ãã¯åŒ(1)ã§è¡šãããããã¿ã«é
žãš
ã¹ãã«ã¯ããªãšã¹ãã«ç¹ç¶ææã«ãŸãæ°žç¶çãªåž¯
é»é²æ¢ãªãã³ã«æè»åäœçšãäžããããšãããª
ãã
ã¹ãã«ã¯ããªãšã¹ãã«ç¹ç¶ææã«ãŸãæ°žç¶çãªåž¯
é»é²æ¢ãªãã³ã«æè»åäœçšãäžããããšãããª
ãã
以äžã®äŸã«ãããŠéšãªãã³ã«ããŒã»ã³ãã¯éé
ã«ããã
ã«ããã
äŸ ïŒ
ããŒã æè²è£
眮äžã§ãäºã60âã®ããŒã¯ãããš
ãã¬ã³äžã§æŽæµããããªãšã¹ãã«ãããç¹ç©100
Kgã次ã®ããã«æè²ããã
ãã¬ã³äžã§æŽæµããããªãšã¹ãã«ãããç¹ç©100
Kgã次ã®ããã«æè²ããã
第ïŒæ济容åšäžã§æ°Ž1500ã60âã«å æž©ããã
ãã®ç¬¬ïŒæ济äžã« ç¡«é žã¢ã³ã¢ããŠã 3000ïœ ã® é ž 200ïœããã³ åŒ(4)ã§è¡šãããããã¿ã«é žãšã¹ãã« 2500ïœ ãå ããã
ãã®ç¬¬ïŒæ济äžã« ç¡«é žã¢ã³ã¢ããŠã 3000ïœ ã® é ž 200ïœããã³ åŒ(4)ã§è¡šãããããã¿ã«é žãšã¹ãã« 2500ïœ ãå ããã
ãããããã®ç¬¬ïŒæ济ãæè²è£
眮äžã«ãã³ãã§
å ¥ãã80âã«å ç±ãããããã§ãã³ãžã«ããšããŒ
ã«ãã€ãªã€ãŒ6000ïœãããããŠ10ååŸåŒ ã§è¡šããããææ4000ïœãæè²è£ 眮äžã«å ããã
ããã«10ååŸãã®æž©åºŠã20åéã§130âã«äžæã
ãããã®æž©åºŠã§60åéæè²ãããæ济80âã«å·åŽ
åŸãããæè²è£ 眮ããåãåºãã
å ¥ãã80âã«å ç±ãããããã§ãã³ãžã«ããšããŒ
ã«ãã€ãªã€ãŒ6000ïœãããããŠ10ååŸåŒ ã§è¡šããããææ4000ïœãæè²è£ 眮äžã«å ããã
ããã«10ååŸãã®æž©åºŠã20åéã§130âã«äžæã
ãããã®æž©åºŠã§60åéæè²ãããæ济80âã«å·åŽ
åŸãããæè²è£ 眮ããåãåºãã
ã€ãã§ãã®åžå°ã75âã§20åééåžžã®æ¹æ³ã«ã
ãéå çã«ïŒäºç¡«é žæ°ŽçŽ ãããªãŠã ãå«æããæ°Ž
æ§ã§ãæ°Žé žåãããªãŠã ã§ã¢ã«ã«ãªæ§ãšãã浞
液ïŒåŸåŠçããããããããã®åžå°ããããã也
ç¥ããã
ãéå çã«ïŒäºç¡«é žæ°ŽçŽ ãããªãŠã ãå«æããæ°Ž
æ§ã§ãæ°Žé žåãããªãŠã ã§ã¢ã«ã«ãªæ§ãšãã浞
液ïŒåŸåŠçããããããããã®åžå°ããããã也
ç¥ããã
åäžã«éè²ã®ããªãªãŽããŒæ²çã瀺ããªãæè²
ç©ãåŸããããã«å¯ŸããŠãåãæ¹æ³ã§ãããåŒ(4)
ã§è¡šãããããã¿ã«é žãšã¹ãã«ã®ä»å ãªãã§æè²
ãããšãæãããªãªãªãŽããŒæ²çãèŠããã
ç©ãåŸããããã«å¯ŸããŠãåãæ¹æ³ã§ãããåŒ(4)
ã§è¡šãããããã¿ã«é žãšã¹ãã«ã®ä»å ãªãã§æè²
ãããšãæãããªãªãªãŽããŒæ²çãèŠããã
åŒ(4)ã§è¡šãããããã¿ã«é
žãšã¹ãã«ã¯æ¬¡ã®ãã
ã«è£œé ã§ããã
ã«è£œé ã§ããã
ã¹ãã¢ãªã«ã¢ã«ã³ãŒã«81ïœããããŸããªããã
ããŠçªçŽ å°å ¥ã®äžã«100âã§çèãããããã§ã
ã¿ã«é žç¡æ°Žç©44.4ïœããåžžã«éæãªçèç©ãçæ
ããŠããããã«20åéã§å°éãã€å ¥ããããã®ç
èç©ã100âã«ïŒæéä¿ã€ããã«ãšã³100ïœãšãžãš
ãã¬ã³ã°ãªã³ãŒã«31.8ïœãšç¡«é ž0.4ïœãšãæ·»å åŸ
åŸããã溶液ã沞ãšããããŸã§å ç±ãããããã§
æ°Ž5.8ïœãå ±æ²žèžçã«ããïŒæéã§çå»ãããã
ã®æº¶æ¶²ã宀枩ã«å·åŽããçé žãããªãŠã ïŒïœãå
ãã20åéãããŸãããå¡©ããå¥ãããã®ã液ã
ã溶å€ãç空ã§çå»ãããæ®æž£ãšããŠåŒ(4)ã§è¡šã
ããããã¿ã«é žãšã¹ãã«152ïœãæ·¡é»è²ã®æ²¹ã®åœ¢
ã§æ®ããæŸçœ®ãããšããŒã¹ãã«åºåããã
ããŠçªçŽ å°å ¥ã®äžã«100âã§çèãããããã§ã
ã¿ã«é žç¡æ°Žç©44.4ïœããåžžã«éæãªçèç©ãçæ
ããŠããããã«20åéã§å°éãã€å ¥ããããã®ç
èç©ã100âã«ïŒæéä¿ã€ããã«ãšã³100ïœãšãžãš
ãã¬ã³ã°ãªã³ãŒã«31.8ïœãšç¡«é ž0.4ïœãšãæ·»å åŸ
åŸããã溶液ã沞ãšããããŸã§å ç±ãããããã§
æ°Ž5.8ïœãå ±æ²žèžçã«ããïŒæéã§çå»ãããã
ã®æº¶æ¶²ã宀枩ã«å·åŽããçé žãããªãŠã ïŒïœãå
ãã20åéãããŸãããå¡©ããå¥ãããã®ã液ã
ã溶å€ãç空ã§çå»ãããæ®æž£ãšããŠåŒ(4)ã§è¡šã
ããããã¿ã«é žãšã¹ãã«152ïœãæ·¡é»è²ã®æ²¹ã®åœ¢
ã§æ®ããæŸçœ®ãããšããŒã¹ãã«åºåããã
äŸ ïŒ
ããŒãºæãè£
眮äžã§ããç¶å
è£
ã«ããããªãšã¹
ãã«çŽ¡çžŸç³ž100Kgã次ã®ããã«æè²ããã
ãã«çŽ¡çžŸç³ž100Kgã次ã®ããã«æè²ããã
第ïŒæ济容åšäžã§æ°Ž1300ã60âã«å æž©ããã
ãã®ç¬¬ïŒæ济ã«ã ç¡«é žã¢ã³ã¢ããŠã 2600ïœ ã®é žïŒ85ïŒ ïŒ 200ïœ åŒ(5)ã§è¡šãããããã¿ã«é žãšã¹ãã« 2000ïœ ãŸã㯠ããªã¯ãããã³ãŒã³ã®40ïŒ ä¹³åç© 2000ïœ ãå ããã
ãã®ç¬¬ïŒæ济ã«ã ç¡«é žã¢ã³ã¢ããŠã 2600ïœ ã®é žïŒ85ïŒ ïŒ 200ïœ åŒ(5)ã§è¡šãããããã¿ã«é žãšã¹ãã« 2000ïœ ãŸã㯠ããªã¯ãããã³ãŒã³ã®40ïŒ ä¹³åç© 2000ïœ ãå ããã
ãã®ç¬¬ïŒæ济ãæè²è£
眮äžã«ãã³ãã§å
¥ããã
æ液ã®åŸªç°ãåšæçã«åæããïŒåéããå éšã
ãããå€éšãžãããããïŒåééæ¹åã«ãã³ãã§
ãããã15ååŸã«åŒïŒ14ïŒã§è¡šããããææïŒ60
âã®æ°Žäžã«åæ£ãããŠããïŒ4000ïœãæè²è£ 眮äž
ã«æ·»å ãããã€ãã§30åéã§ãã®æž©åºŠã130âã«
ãŸã§é«ãã60åéãã®æž©åºŠã§æè²ãããæ济ã90
âã«å·åŽåŸæè²è£ 眮ããåãåºããã€ãã§ãã®çŽ¡
瞟糞ã20åéã80ã90âã§ã次ã®çµæã®æµžæ¶²ãçš
ããŠåŸåŠçããã
æ液ã®åŸªç°ãåšæçã«åæããïŒåéããå éšã
ãããå€éšãžãããããïŒåééæ¹åã«ãã³ãã§
ãããã15ååŸã«åŒïŒ14ïŒã§è¡šããããææïŒ60
âã®æ°Žäžã«åæ£ãããŠããïŒ4000ïœãæè²è£ 眮äž
ã«æ·»å ãããã€ãã§30åéã§ãã®æž©åºŠã130âã«
ãŸã§é«ãã60åéãã®æž©åºŠã§æè²ãããæ济ã90
âã«å·åŽåŸæè²è£ 眮ããåãåºããã€ãã§ãã®çŽ¡
瞟糞ã20åéã80ã90âã§ã次ã®çµæã®æµžæ¶²ãçš
ããŠåŸåŠçããã
90âã®æ°Ž 1300
æ°Žé
žåãããªãŠã 溶液ïŒ30ïŒ
ïŒ 6500ïœããã³
éäºç¡«é
žãããªãŠã 1300ïœ
ããã§æž©æããã³å·æ培åºçã«ããããåæãã
ãŠå ç¢ãªéè²ã®æè²ç©ãåŸãããªãªãŽããŒæ²çã«
é¢ããè©Šéšã¯ãåèšçŽ¡çžŸç³žãå ãé»è²ã®çŽã®éé
ãéããŠå°ããããã§çŽ¡çžŸç³žè¡šé¢ã«æ²çããŠãã
ãªãªãŽããŒãã¯ãåããåèšã®çŽã«éããŠè¡ãã
ããããŠè¡ãããè©Šéšã®çµæåèšæ液ã§æè²ãã
ã玡瞟糞ã¯ãªãªãŽããŒæ²çããªãããåŒ(5)ã§è¡šã
ãããåèšã®ãã¿ã«é žãšã¹ãã«ãå«æããªãæè²
ããå Žåæçœãªæ²çãããã
ãŠå ç¢ãªéè²ã®æè²ç©ãåŸãããªãªãŽããŒæ²çã«
é¢ããè©Šéšã¯ãåèšçŽ¡çžŸç³žãå ãé»è²ã®çŽã®éé
ãéããŠå°ããããã§çŽ¡çžŸç³žè¡šé¢ã«æ²çããŠãã
ãªãªãŽããŒãã¯ãåããåèšã®çŽã«éããŠè¡ãã
ããããŠè¡ãããè©Šéšã®çµæåèšæ液ã§æè²ãã
ã玡瞟糞ã¯ãªãªãŽããŒæ²çããªãããåŒ(5)ã§è¡šã
ãããåèšã®ãã¿ã«é žãšã¹ãã«ãå«æããªãæè²
ããå Žåæçœãªæ²çãããã
åŒ(5)ã§è¡šãããããã¿ã«é
žãšã¹ãã«ã¯äŸïŒã«èš
èŒã®è£œæ³ã«åŸãããããã§é©çšããã¹ãã¢ãªã«ã¢
ã«ã³ãŒã«ã®ä»£ãã«ã©ãŠãªã«ã¢ã«ã³ãŒã«55.8ïœãé©
çšããŠåŸããããæ·¡é»è²ã®æ²¹128ïœãåŸãã
èŒã®è£œæ³ã«åŸãããããã§é©çšããã¹ãã¢ãªã«ã¢
ã«ã³ãŒã«ã®ä»£ãã«ã©ãŠãªã«ã¢ã«ã³ãŒã«55.8ïœãé©
çšããŠåŸããããæ·¡é»è²ã®æ²¹128ïœãåŸãã
äŸ ïŒ
äŸïŒãŸãã¯ïŒã«ãããŠåèšããåŒ(4)ãŸãã¯åŒ(5)
ã§è¡šãããããã¿ã«é žãšã¹ãã«ã次ã®ãã®ãããª
ã補å€ã®ïŒåéã§ããã åŒ(6)ã§è¡šãããããã¿ã«é žãšã¹ãã« 47éš ããã«ããšããŒã«ïŒã¢ã«ãžã®ãšãã¬ã³ãªãã·ã
ïŒã¢ã«ä»å çæç©ã®é žæ§ãªã³é žãšã¹ãã«ã®ã¢
ã³ã¢ããŠã å¡© ïŒéšããã³ æ°Ž 50éš ãããŠä»ã¯äŸïŒãŸãã¯ïŒã«èšèŒã®ããã«è¡ããšã
åæ§ã«åæããããªãªãŽããŒæ²çã瀺ãããªãé
è²ã®æè²ç©ãåŸãã
ã§è¡šãããããã¿ã«é žãšã¹ãã«ã次ã®ãã®ãããª
ã補å€ã®ïŒåéã§ããã åŒ(6)ã§è¡šãããããã¿ã«é žãšã¹ãã« 47éš ããã«ããšããŒã«ïŒã¢ã«ãžã®ãšãã¬ã³ãªãã·ã
ïŒã¢ã«ä»å çæç©ã®é žæ§ãªã³é žãšã¹ãã«ã®ã¢
ã³ã¢ããŠã å¡© ïŒéšããã³ æ°Ž 50éš ãããŠä»ã¯äŸïŒãŸãã¯ïŒã«èšèŒã®ããã«è¡ããšã
åæ§ã«åæããããªãªãŽããŒæ²çã瀺ãããªãé
è²ã®æè²ç©ãåŸãã
äŸ ïŒ
äŸïŒãŸãã¯ïŒã«ãããŠåèšããåŒ(4)ãŸãã¯åŒ(5)
ã§è¡šãããããã¿ã«é žãšã¹ãã«ã次ã®ãã®ãããª
ã補å€ã®ïŒåéã§ä»£ãã åŒ(6)ã§è¡šãããããã¿ã«é žãšã¹ãã« 40éš ããã«ããšããŒã«ïŒã¢ã«ãžã®ãšãã¬ã³ãªãã·ã
ïŒã¢ã«ä»å çæç©ã®é žæ§ç¡«é žãšã¹ãã«ã®ã¢ã³
ã¢ããŠã å¡©ïŒ40ïŒ ïŒ 10éšããã³ æ°Ž 50éš ãããŠä»ã¯äŸïŒãŸãã¯ïŒã«èšèŒã®ããã«è¡ããšã
åæ§ã«åæãããããªãªãŽããŒæ²çã瀺ããªãé
è²ã®æè²ç©ãåŸãã
ã§è¡šãããããã¿ã«é žãšã¹ãã«ã次ã®ãã®ãããª
ã補å€ã®ïŒåéã§ä»£ãã åŒ(6)ã§è¡šãããããã¿ã«é žãšã¹ãã« 40éš ããã«ããšããŒã«ïŒã¢ã«ãžã®ãšãã¬ã³ãªãã·ã
ïŒã¢ã«ä»å çæç©ã®é žæ§ç¡«é žãšã¹ãã«ã®ã¢ã³
ã¢ããŠã å¡©ïŒ40ïŒ ïŒ 10éšããã³ æ°Ž 50éš ãããŠä»ã¯äŸïŒãŸãã¯ïŒã«èšèŒã®ããã«è¡ããšã
åæ§ã«åæãããããªãªãŽããŒæ²çã瀺ããªãé
è²ã®æè²ç©ãåŸãã
äŸ ïŒ
äŸïŒãŸãã¯ïŒã«åèšããåŒ(4)ãŸãã¯åŒ(5)ã§è¡šã
ããããã¿ã«é žãšã¹ãã«ãåŒ(9)ïŒ(1)ïŒãïŒããŸã
ã¯ãã§è¡šãããããã¿ã«é žãšã¹ãã«ã®åéã§ä»£
ããä»ã¯äŸïŒãŸãã¯ïŒã«èšèŒã®ããã«è¡ããšãå
æ§ã«åæãããŠããããªãªãŽããŒæ²çã瀺ãããª
ãéè²ã®æè²ç©ãåŸãã
ããããã¿ã«é žãšã¹ãã«ãåŒ(9)ïŒ(1)ïŒãïŒããŸã
ã¯ãã§è¡šãããããã¿ã«é žãšã¹ãã«ã®åéã§ä»£
ããä»ã¯äŸïŒãŸãã¯ïŒã«èšèŒã®ããã«è¡ããšãå
æ§ã«åæãããŠããããªãªãŽããŒæ²çã瀺ãããª
ãéè²ã®æè²ç©ãåŸãã
åŒ(9)ããã§è¡šãããããã¿ã«é
žãšã¹ãã«ã¯äŸïŒ
ã«èšèŒã®è£œæ³ã«ããããããããããããã§é©çš
ãããŠãããžãšãã¬ã³ã°ãªã³ãŒã«ã®ä»£ãã«ä»¥äžã®
ãã®ã®é©çšããŠåŸãŠãããã
ã«èšèŒã®è£œæ³ã«ããããããããããããã§é©çš
ãããŠãããžãšãã¬ã³ã°ãªã³ãŒã«ã®ä»£ãã«ä»¥äžã®
ãã®ã®é©çšããŠåŸãŠãããã
ãããã¬ã³ã°ãªã³ãŒã« 22.8ïœ
ãšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã« 27ïœ
ãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«
36ïœãŸã㯠ãžãšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«
40.2ïœ åŒãã§è¡šãããããã¿ã«é žãšã¹ãã«ã¯æ¬¡ã®ããã«
補é ã§ããã
36ïœãŸã㯠ãžãšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«
40.2ïœ åŒãã§è¡šãããããã¿ã«é žãšã¹ãã«ã¯æ¬¡ã®ããã«
補é ã§ããã
ãžã¡ãã«ãã¬ãã¿ã«é
ž 58.2ïœ
ã¢ã«ããªãŒã«1014 57ïœ
ãžãšãã¬ã³ã°ãªã³ãŒã« 31.8ïœ
ç¡æ°Žé
¢é
žã«ã«ã·ãŠã 0.08ïœããã³
ïŒé
žåã¢ã³ãã¢ã³ 0.16ïœ
ããããŸããªããçªçŽ å°å
¥ã®äžã«170âã«å ç±ã
ããããã§ã¡ã¿ããŒã«20cm3ã170ã200âã«ãããŠ
11æéã§çå»ãããå·åŽåŸåŒãã§è¡šããããåå
ç©91ïŒ ãå«æããç¡è²ã®ããŒã¹ã128ïœãåŸãã
ããããã§ã¡ã¿ããŒã«20cm3ã170ã200âã«ãããŠ
11æéã§çå»ãããå·åŽåŸåŒãã§è¡šããããåå
ç©91ïŒ ãå«æããç¡è²ã®ããŒã¹ã128ïœãåŸãã
äŸ ïŒ
äŸïŒã«èšèŒããããã«ããããåŒ(4)ã§è¡šããã
ããã¿ã«é žãšã¹ãã«ãé©çšããæè²ãããããŠé
åžžã®æ¹æ³ã«ããéå çã«åŸåŠçãè¡ã€ãããªãšã¹
ãã«åžå°100Kgãæ°ããªæµŽã§ã70âã20åéã åŒ(4)ã§è¡šãããããã¿ã«é žãšã¹ãã« 3000ïœ ã§åŸåŠçããã浞液æ¯ã¯ïŒïŒ15ã§ããããããã
åžå°ããããã也ç¥ãããåã³ããªãªãŽããŒæ²ç
ã瀺ããªãéè²ã®æè²ç©ãåŸãã
ããã¿ã«é žãšã¹ãã«ãé©çšããæè²ãããããŠé
åžžã®æ¹æ³ã«ããéå çã«åŸåŠçãè¡ã€ãããªãšã¹
ãã«åžå°100Kgãæ°ããªæµŽã§ã70âã20åéã åŒ(4)ã§è¡šãããããã¿ã«é žãšã¹ãã« 3000ïœ ã§åŸåŠçããã浞液æ¯ã¯ïŒïŒ15ã§ããããããã
åžå°ããããã也ç¥ãããåã³ããªãªãŽããŒæ²ç
ã瀺ããªãéè²ã®æè²ç©ãåŸãã
äŸ ïŒ
äŸïŒã«èšèŒã®ããã«ããããåŒ(4)ã§è¡šãããã
ãã¿ã«é žãšã¹ãã«ã®é©çšãªãã«æè²ããããªãšã¹
ãã«åžå°100Kgãã æ°Žé žåãããªãŠã 溶液ïŒ30ïŒ ïŒ ïŒïœ/ äºç¡«é žæ°ŽçŽ ãããªãŠã ïŒïœ/ ãªã¯ã¿ãã·ã«âãžãšãã¬ã³ããªã¢ãã³ïŒã¢ã«ãš
ãšãã¬ã³ãªãã·ã18ã¢ã«ãšããã®ä»å ç©
ïŒïœ/ããã³ åŒ(5)ã§è¡šãããããã¿ã«é žãšã¹ãã« 3000ïœ ãå«æãã浞液ã§åŸåŠçããã浞液æ¯ã¯ïŒïŒ15ã§
ãããåæ§ã«ãªãªãŽããŒæ²çã瀺ãããªãéè²ã®
æè²ç©ãåŸãã
ãã¿ã«é žãšã¹ãã«ã®é©çšãªãã«æè²ããããªãšã¹
ãã«åžå°100Kgãã æ°Žé žåãããªãŠã 溶液ïŒ30ïŒ ïŒ ïŒïœ/ äºç¡«é žæ°ŽçŽ ãããªãŠã ïŒïœ/ ãªã¯ã¿ãã·ã«âãžãšãã¬ã³ããªã¢ãã³ïŒã¢ã«ãš
ãšãã¬ã³ãªãã·ã18ã¢ã«ãšããã®ä»å ç©
ïŒïœ/ããã³ åŒ(5)ã§è¡šãããããã¿ã«é žãšã¹ãã« 3000ïœ ãå«æãã浞液ã§åŸåŠçããã浞液æ¯ã¯ïŒïŒ15ã§
ãããåæ§ã«ãªãªãŽããŒæ²çã瀺ãããªãéè²ã®
æè²ç©ãåŸãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æè²ã®éãŸãã¯åŸã«ãåŒ ïŒãã®åŒã§ãã¯ççŽ ååïŒã22åããã€ã¢ã«ã
ã«åºãŸãã¯ã¢ã«ã±ãã«åºã§ããX1ãšX2ãšã®äžïŒ
ã€ã¯æ°ŽçŽ ååãŸãã¯ã¡ãã«åºã§ãã€ãŠãä»ã¯æ°ŽçŽ
ååã§ãããã¯æ°ŽçŽ ååãŸãã¯ççŽ ååïŒãïŒ
åããã€ã¢ã«ãã«åºã§ãããïœã¯ïŒãïŒã§ããïŒ ã§è¡šãããããã¿ã«é žãšã¹ãã«ãé©çšããããšã
ç¹åŸŽãšããããã¿ã«é žãšã¹ãã«ã®ååšã®äžã§è¡ã
ããªãšã¹ãã«ç¹ç¶ã®æè²ãŸãã¯åŸåŠçæ³ã ïŒ ãšã¹ãã«åºâCOORãïŒâäœã«ããåŒ(1)ã§è¡š
ãããããã¿ã«é žãšã¹ãã«ãé©çšããç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé ã«èšèŒã®æ¹æ³ã ïŒ ïŒºãæ°ŽçŽ ååã§ããåŒ(1)ã§è¡šãããããã¿ã«
é žãšã¹ãã«ãé©çšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èš
èŒã®æ¹æ³ã ïŒ ïŒ²ãççŽ ååïŒã22åãç¹ã«12ã18åããã€
ã¢ã«ãã«åºã§ããX1ãšX2ãšãããããæ°ŽçŽ åå
ã§ããåŒ(1)ã§è¡šãããããã¿ã«é žãšã¹ãã«ãé©çš
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ä¹è³ç¬¬ïŒé ã®ãããã
ã«èšèŒã®æ¹æ³ã ïŒ æè²ã®éãåŒ(1)ã§è¡šãããããã¿ã«é žãšã¹ã
ã«ãé©çšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ä¹è³ç¬¬ïŒé ã®
ããããã«èšèŒã®æ¹æ³ã ïŒ æè²ãåæ£ææãçšããŠè¡ãç¹èš±è«æ±ã®ç¯å²
第ïŒé ã«èšèŒã®æ¹æ³ã ïŒ æè²ãåžå°œæ³ã«ããæ°Žæ§æ液ããè¡ãç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®æ¹æ³ã ïŒ æè²ã枩床110ã140âã§è¡ãç¹èš±è«æ±ã®ç¯å²
第ïŒé ã«èšèŒã®æ¹æ³ã ïŒ åŒ(1)ã§è¡šãããããã¿ã«é žãšã¹ãã«ãæè²ã®
åŸé©çšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®æ¹æ³ã ïŒïŒ åŸåŠçããæè²ãããããªãšã¹ãã«ç¹ç¶ã®
éåžžã®æ¹æ³ã«ããéå çæŽæµãšåæã«è¡ãç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®æ¹æ³ã ïŒïŒ åŸåŠçã枩床50ã100âã§è¡ãç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé åã¯ç¬¬ïŒïŒé ã®ããããã«èšèŒã®æ¹
æ³ã
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH980077A CH636991B (de) | 1977-08-10 | 1977-08-10 | Verfahren zum faerben oder nachbehandeln von polyesterfasern. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5430984A JPS5430984A (en) | 1979-03-07 |
| JPS6132439B2 true JPS6132439B2 (ja) | 1986-07-26 |
Family
ID=4355778
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9628678A Granted JPS5430984A (en) | 1977-08-10 | 1978-08-09 | Dyeing and post treating of polyester fiber |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4229176A (ja) |
| JP (1) | JPS5430984A (ja) |
| BE (1) | BE869628A (ja) |
| BR (1) | BR7805092A (ja) |
| CA (1) | CA1117708A (ja) |
| CH (1) | CH636991B (ja) |
| DE (1) | DE2834412A1 (ja) |
| ES (1) | ES472454A1 (ja) |
| FR (1) | FR2400079A1 (ja) |
| GB (1) | GB2002821B (ja) |
| NL (1) | NL7808263A (ja) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5717310A (en) * | 1980-07-03 | 1982-01-29 | Ishikawajima Harima Heavy Ind Co Ltd | Work roll bending device |
| EP0058637A1 (de) * | 1981-02-12 | 1982-08-25 | Ciba-Geigy Ag | Stabile PrÀparation eines Behandlungsmittels fÌr textile Substrate |
| US4559150A (en) * | 1982-08-11 | 1985-12-17 | Ciba Geigy Corporation | Stable composition for treating textile substrates |
| DE3308673A1 (de) * | 1983-03-11 | 1984-09-20 | SMS Schloemann-Siemag AG, 4000 DÃŒsseldorf | Mehrwalzengeruest |
| US6844307B1 (en) | 2002-02-04 | 2005-01-18 | Jeffrey Todd Sumner | Compositions to reduce textile contaminants and associated processing methods |
| CN109912412B (zh) * | 2019-03-06 | 2020-11-10 | 西å®äº€éå€§åŠ | äžç§éæ¥åå¢æº¶çšéååå ¶å¶å€æ¹æ³ååºçš |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1274464A (fr) * | 1959-08-01 | 1961-10-27 | Hoechst Ag | Procédé de préparation de produits d'oxéthylation |
| DE2056694C3 (de) * | 1970-11-18 | 1975-08-14 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Erzeugung egaler FÀrbungen auf Fasermaterialien aus linearen Polyestern und deren Mischungen mit Cellulose- bzw. stickstoffhaltigen Fasern |
| NL7211820A (ja) * | 1971-09-02 | 1973-03-06 | ||
| CH566433A (ja) * | 1972-10-13 | 1975-09-15 | ||
| US4060387A (en) * | 1972-10-13 | 1977-11-29 | Sandoz Ltd. | Aromatic carboxylic acid esters and amides as fixing agents |
| DE2403859A1 (de) * | 1974-01-28 | 1975-08-14 | Basf Ag | Verfahren zum faerben von polyesterfasern |
| DE2412427A1 (de) * | 1974-03-15 | 1975-10-16 | Bayer Ag | Verfahren zum faerben von natuerlichen und/oder synthetischen polyamidfasermaterialien unterhalb der kochtemperatur |
-
1977
- 1977-08-10 CH CH980077A patent/CH636991B/de unknown
-
1978
- 1978-08-05 DE DE19782834412 patent/DE2834412A1/de active Granted
- 1978-08-07 NL NL787808263A patent/NL7808263A/xx not_active Application Discontinuation
- 1978-08-07 US US05/931,579 patent/US4229176A/en not_active Expired - Lifetime
- 1978-08-07 FR FR7823288A patent/FR2400079A1/fr active Granted
- 1978-08-08 CA CA000308934A patent/CA1117708A/en not_active Expired
- 1978-08-08 GB GB7832575A patent/GB2002821B/en not_active Expired
- 1978-08-09 ES ES472454A patent/ES472454A1/es not_active Expired
- 1978-08-09 BR BR7805092A patent/BR7805092A/pt unknown
- 1978-08-09 BE BE78189789A patent/BE869628A/xx not_active IP Right Cessation
- 1978-08-09 JP JP9628678A patent/JPS5430984A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| BE869628A (fr) | 1979-02-09 |
| NL7808263A (nl) | 1979-02-13 |
| US4229176A (en) | 1980-10-21 |
| DE2834412A1 (de) | 1979-02-22 |
| FR2400079A1 (fr) | 1979-03-09 |
| JPS5430984A (en) | 1979-03-07 |
| FR2400079B1 (ja) | 1980-07-04 |
| BR7805092A (pt) | 1979-04-17 |
| GB2002821B (en) | 1982-06-30 |
| ES472454A1 (es) | 1980-05-16 |
| GB2002821A (en) | 1979-02-28 |
| DE2834412C2 (ja) | 1988-01-14 |
| CH636991B (de) | |
| CH636991GA3 (ja) | 1983-07-15 |
| CA1117708A (en) | 1982-02-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4430261A (en) | Propylene oxide reaction products and process for their manufacture | |
| KR940000792B1 (ko) | ìì©ì± ëë ì-ë¶ì°ì± ê·žëííž ì€í©ì²Žì ì ì¡°ë°©ë² | |
| JPH062271A (ja) | æªæè²ãããã¯æè²ãŸãã¯æºæãããããªãšã¹ãã«ç¹ç¶ææã®å ååŠçããã³ç±çå®å®åæ¹æ³ | |
| US5009668A (en) | Mixture of assistants and its use in the dyeing of synthetic fibre materials: acid ester of oxyalkylated phendl, nonionic surfactant and dye carrier | |
| NL8520041A (nl) | Kleurstofmengsel alsmede werkwijze voor het kleuren van thermoplastische materialen onder toepassing van dat mengsel. | |
| US4715863A (en) | Process for dyeing hydrophobic fibre material from aqueous bath containing untreated disperse dye and to adjust the exhausted dye bath for further use | |
| US4994089A (en) | Carrier mixture for the dyeing of polyester materials: n-alkylphthalimide and aromatic ester or ether | |
| JPS6132439B2 (ja) | ||
| JPS60173186A (ja) | çæ°Žæ§ç¹ç¶ææã®æè²æ¹æ³ | |
| US3752649A (en) | Dye levelling on and oligomer removal from polyester fibers and cellulose or polyamide blends with fatty acid diester of butanediol-ethylene oxide condensate | |
| US4155856A (en) | Process for aftertreating dyed textile material containing polyester fibres | |
| US4294576A (en) | Removal of oligomer deposits from textile materials | |
| US3684431A (en) | Process for after-washing freshly dyed textile material | |
| AU605705B2 (en) | Mixture of assistants and its use in the dyeing of polyester fibre materials | |
| JP2612945B2 (ja) | çæ°Žæ§ç¹ç¶ææã®æè²çšæ äœ | |
| US3897207A (en) | Carrier composition and process for dyeing and printing | |
| US4200585A (en) | Acid esters of propylene oxide poly-adducts | |
| EP0064029B1 (de) | Hilfsmittelgemisch und seine Verwendung als Faltenfreimittel beim FÀrben oder optischen Aufhellen von Polyesterfasern enthaltenden Textilmaterialien | |
| CA1051614A (en) | Process for dyeing materials which contain synthetic fibres | |
| US4132525A (en) | Process for dyeing materials which contain synthetic fibres using polyadducts of propylene oxide and polyhydric alcohols | |
| CA1069919A (en) | Acid esters of propylene oxide poly-adducts | |
| SU1712504A1 (ru) | СПÑÑав Ўл вÑÑПкПÑеЌпеÑаÑÑÑМПгП пеÑОПЎОÑеÑкПгП кÑаÑеМО ÑекÑÑÑÑОÑПваММÑÑ Ð¿ÐŸÐ»ÐžÑÑОÑÐœÑÑ ÐœÐžÑей | |
| KR820002253B1 (ko) | "íŽëŠ¬ìì€í 륎 ì¬ì ëë ìŽë€ì íšì íë ì¬ì ì§ë¬Œì ìŒìíë ë°©ë²" | |
| JPS6088187A (ja) | æè²æ¹æ³ | |
| DE2521106C3 (de) | Verfahren zum FÀrben von synthetische Fasern enthaltenden Materialien |